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Search Results (15,613)

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24 pages, 2340 KiB  
Article
Design and Analysis of Combined Vibration Absorbers for Ship Propulsion Shaft Systems
by Dongdong Luo, Qing Ouyang and Hongsheng Hu
Actuators 2025, 14(1), 41; https://doi.org/10.3390/act14010041 (registering DOI) - 20 Jan 2025
Abstract
The vibration of a ship’s propulsion shaft system directly affects the ship’s lifespan, and many studies have designed vibration absorbers only for one of the natural frequencies of a ship’s propulsion shaft system without considering the influence of multiple low-order resonance frequencies. In [...] Read more.
The vibration of a ship’s propulsion shaft system directly affects the ship’s lifespan, and many studies have designed vibration absorbers only for one of the natural frequencies of a ship’s propulsion shaft system without considering the influence of multiple low-order resonance frequencies. In this paper, a vibration absorber combined with a magnetorheological elastomer vibration absorber and a rubber vibration absorber in series is designed, and it can cover two torsional natural frequency band ranges to achieve better vibration reduction performances in multiple different torsional natural frequencies. The torsional natural frequency of the propulsion shafting of a 45 m fishing vessel is determined based on a multiple-degrees-of-freedom equivalent discretization model. Two natural frequencies, 22.4 Hz and 131.4 Hz, of a ship propulsion shaft system are selected as the design goal parameters of the combined vibration absorber. The magnetic field is simulated to ensure that the magnetic field generated by an energized coil can meet requirements. Then, a dynamic simulation of the ship propulsion shaft system with a combined vibration absorber is conducted via co-simulation. Afterward, the device is installed on the intermediate shaft of the ship propulsion shaft system for simulation, and the vibration reduction effect of the device is analyzed at different frequencies by controlling the current. When the device is controlled to operate at the optimal frequency point, the results show that the angular acceleration vibration amplitude reduction around the first and third torsional natural frequencies of the propulsion shaft system reaches 90% and 18%, respectively. This study provides new ideas for the intelligent and controllable vibration damping of ship propulsion shaft systems, especially for the development trend of intelligent ship equipment under complex working conditions. Full article
(This article belongs to the Section Control Systems)
21 pages, 3057 KiB  
Article
Assessing the COVID-19 Lockdown Impact on Global Air Quality: A Transportation Perspective
by Meina Zheng, Feng Liu and Meichang Wang
Atmosphere 2025, 16(1), 113; https://doi.org/10.3390/atmos16010113 (registering DOI) - 20 Jan 2025
Abstract
To address the COVID-19 pandemic, governments worldwide implemented mandatory restrictions. As an unintended consequence of these responses, significant air pollution reductions have been recorded across the world. We provide cross-national evidence on the causal impact of pandemic-induced lockdowns on air quality. Using daily [...] Read more.
To address the COVID-19 pandemic, governments worldwide implemented mandatory restrictions. As an unintended consequence of these responses, significant air pollution reductions have been recorded across the world. We provide cross-national evidence on the causal impact of pandemic-induced lockdowns on air quality. Using daily air pollution data between 1 January and 31 December 2020, covering 596 major cities in 77 countries, we analyzed the data with a generalized difference-in-differences approach. The results show that lockdown restrictions reduced global concentrations of NO2 by 21~35%, PM10 by 14~26%, PM2.5 by 9~18%, CO by 6~16%, and SO2 by 5~16%, while the O3 concentrations increased by 15~29% under eight specific lockdown measures. Furthermore, a simultaneous equations model suggests that reductions in public and private mobility, measured by changes in public transportation and car ridership, partly explain the observed decreases in air pollution. These findings have significant implications for ongoing global efforts to mitigate air pollution and underscore the pivotal role of public transit in achieving this goal. Full article
(This article belongs to the Section Air Quality and Health)
18 pages, 426 KiB  
Review
Reducing Emissions Using Artificial Intelligence in the Energy Sector: A Scoping Review
by Janne Alatalo, Eppu Heilimo, Mika Rantonen, Olli Väänänen and Tuomo Sipola
Appl. Sci. 2025, 15(2), 999; https://doi.org/10.3390/app15020999 (registering DOI) - 20 Jan 2025
Abstract
Global warming is a significant threat to the future of humankind. It is caused by greenhouse gases that accumulate in the atmosphere. CO2 emissions are one of the main drivers of global warming, and the energy sector is one of the main [...] Read more.
Global warming is a significant threat to the future of humankind. It is caused by greenhouse gases that accumulate in the atmosphere. CO2 emissions are one of the main drivers of global warming, and the energy sector is one of the main contributors to CO2 emissions. Recent technological advances in artificial intelligence (AI) have accelerated the adoption of AI in numerous applications to solve many problems. This study carries out a scoping review to understand the use of AI solutions to reduce CO2 emissions in the energy sector. This paper follows the PRISMA-ScR guidelines in reporting the findings. The academic search engine Google Scholar was utilized to find papers that met the review criteria. Our research question was “How is artificial intelligence used in the energy sector to reduce CO2 emissions?” Search phrases and inclusion criteria were decided based on this research question. In total, 186 papers from the search results were screened, and 16 papers fitting our criteria were summarized in this study. The findings indicate that AI is already used in the energy sector to reduce CO2 emissions. Three main areas of application for AI techniques were identified. Firstly, AI models are employed to directly optimize energy generation processes by modeling these processes and determining their optimal parameters. Secondly, AI techniques are utilized for forecasting, which aids in optimizing decision-making, energy transmission, and production planning. Lastly, AI is applied to enhance energy efficiency, particularly in optimizing building performance. The use of AI shows significant promise of reducing CO2 emissions in the energy sector. Full article
(This article belongs to the Section Computing and Artificial Intelligence)
21 pages, 1944 KiB  
Article
Energy Cane Ash: Property Assessment for Its Valorization in Sustainable Cementing Systems
by Gabriela Pitolli Lyra, Lisiane Brichi, Josefa Roselló, María Victoria Borrachero, Lourdes Soriano, Jordi Payá and João Adriano Rossignolo
Sustainability 2025, 17(2), 803; https://doi.org/10.3390/su17020803 (registering DOI) - 20 Jan 2025
Abstract
Cogeneration with energy cane, a highly productive variety compared to conventional sugarcane, significantly increases ash generation, presenting waste management challenges for the sugar and ethanol industries. This study evaluates the potential of energy cane ash as a sustainable alternative material for partial cement [...] Read more.
Cogeneration with energy cane, a highly productive variety compared to conventional sugarcane, significantly increases ash generation, presenting waste management challenges for the sugar and ethanol industries. This study evaluates the potential of energy cane ash as a sustainable alternative material for partial cement replacement in construction, contributing to circular economy practices. A productivity analysis was conducted for planted areas, and the different parts of sugarcane and energy cane were dried and examined using scanning electron microscopy. These parts were calcined at 450 °C and 600 °C and analyzed using scanning electron microscopy, X-ray fluorescence, particle size distribution, and thermal analysis. The reactivity of the ashes was tested in cement mortars with 5%, 10%, and 20% cement replacement using washed ash. The results revealed that energy cane produces approximately four times more ash per hectare than sugarcane, with leaf ash containing up to 60% silica and stalk ash being rich in potassium. The highest compressive strength was observed in a mortar with 10% cement replacement using washed energy cane ash, achieving 102.43% of the reference value after 28 days of curing, indicating excellent pozzolanic reactivity. These findings highlight the potential of energy cane ash to enhance sustainability in cementitious systems by reducing Portland cement use and promoting waste valorization. Furthermore, the reuse of ash can mitigate waste accumulation and support the development of more sustainable construction materials, contributing to a circular economy and a low-carbon society. Full article
17 pages, 5524 KiB  
Article
Osteopenia Metabolomic Biomarkers for Early Warning of Osteoporosis
by Jie Wang, Dandan Yan, Suna Wang, Aihua Zhao, Xuhong Hou, Xiaojiao Zheng, Jingyi Guo, Li Shen, Yuqian Bao, Wei Jia, Xiangtian Yu, Cheng Hu and Zhenlin Zhang
Metabolites 2025, 15(1), 66; https://doi.org/10.3390/metabo15010066 (registering DOI) - 20 Jan 2025
Abstract
Introduction: This study aimed to capture the early metabolic changes before osteoporosis occurs and identify metabolomic biomarkers at the osteopenia stage for the early prevention of osteoporosis. Materials and Methods: Metabolomic data were generated from normal, osteopenia, and osteoporosis groups with [...] Read more.
Introduction: This study aimed to capture the early metabolic changes before osteoporosis occurs and identify metabolomic biomarkers at the osteopenia stage for the early prevention of osteoporosis. Materials and Methods: Metabolomic data were generated from normal, osteopenia, and osteoporosis groups with 320 participants recruited from the Nicheng community in Shanghai. We conducted individual edge network analysis (iENA) combined with a random forest to detect metabolomic biomarkers for the early warning of osteoporosis. Weighted Gene Co-Expression Network Analysis (WGCNA) and mediation analysis were used to explore the clinical impacts of metabolomic biomarkers. Results: Visual separations of the metabolic profiles were observed between three bone mineral density (BMD) groups in both genders. According to the iENA approach, several metabolites had significant abundance and association changes in osteopenia participants, confirming that osteopenia is a critical stage in the development of osteoporosis. Metabolites were further selected to identify osteopenia (nine metabolites in females; eight metabolites in males), and their ability to discriminate osteopenia was improved significantly compared to traditional bone turnover markers (BTMs) (female AUC = 0.717, 95% CI 0.547–0.882, versus BTMs: p = 0.036; male AUC = 0.801, 95% CI 0.636–0.966, versus BTMs: p = 0.007). The roles of the identified key metabolites were involved in the association between total fat-free mass (TFFM) and osteopenia in females. Conclusion: Osteopenia was identified as a tipping point during the development of osteoporosis with metabolomic characteristics. A few metabolites were identified as candidate early-warning biomarkers by machine learning analysis, which could indicate bone loss and provide new prevention guidance for osteoporosis. Full article
(This article belongs to the Section Endocrinology and Clinical Metabolic Research)
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Figure 1

Figure 1
<p>Analysis procedure used in this study. The osteopenia state is critical in distinguishing patients with pre-osteoporosis.</p>
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<p>Differential analysis of metabolite profiles. (<b>A</b>) PCA of the data from females. (<b>B</b>) PCA of the data from males. (<b>C</b>) PLSDA analysis of the data from females. (<b>D</b>) PLSDA analysis of the data from males. (<b>E</b>) A representative metabolite showing a tendency to change levels in the different female groups. (<b>F</b>) A representative metabolite showing a tendency to change levels in the different male groups. (<b>G</b>) Statistics of the differential clinical symptoms and differential metabolites for the different female groups. (<b>H</b>) Statistics of the differential clinical symptoms and differential metabolites for the different male groups.</p>
Full article ">Figure 2 Cont.
<p>Differential analysis of metabolite profiles. (<b>A</b>) PCA of the data from females. (<b>B</b>) PCA of the data from males. (<b>C</b>) PLSDA analysis of the data from females. (<b>D</b>) PLSDA analysis of the data from males. (<b>E</b>) A representative metabolite showing a tendency to change levels in the different female groups. (<b>F</b>) A representative metabolite showing a tendency to change levels in the different male groups. (<b>G</b>) Statistics of the differential clinical symptoms and differential metabolites for the different female groups. (<b>H</b>) Statistics of the differential clinical symptoms and differential metabolites for the different male groups.</p>
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<p>Individual edge network analysis. (<b>A</b>) The early-warning index change for the three female groups. (<b>B</b>) The co-expressed metabolite biomarker network for the female control group. (<b>C</b>) The co-expressed metabolite biomarker network for the female osteopenia group. (<b>D</b>) The co-expressed metabolite biomarker network for the female osteoporosis group. (<b>E</b>) The early-warning index change for the three male groups. (<b>F</b>) The co-expressed metabolite biomarker network for the male control group. (<b>G</b>) The co-expressed metabolite biomarker network for the male osteopenia group. (<b>H</b>) The co-expressed metabolite biomarker network for the male osteoporosis group.</p>
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<p>ROC curves of RF models for the diagnosis of osteopenia. (<b>A</b>) Metabolite model and BTM model for females. BTM model: AUC = 0.468, 95% CI 0.278–0.658; female model: AUC = 0.717, 95% CI 0.547–0.882; female model versus BTMs: <span class="html-italic">p</span> = 0.036. ROC: receiver operating characteristic; BTMs: bone turnover markers; AUC: area under the curve; CI: confidence interval. BTMs include osteocalcin, N-terminalprocollagen of type I collagen (PINP), and β-cross-linked C-telopeptide of type I collagen (β-CTX). The female model includes phosphatidylcholine diacyl C34:1, phosphatidylcholine diacyl C38:5, phosphatidylcholine diacyl C40:5, phosphatidylcholine diacyl C40:6, phosphatidylcholine acyl alkyl C36:1, phosphatidylcholine acyl alkyl C36:4, phosphatidylcholine acyl alkyl C38:5, phosphatidylcholine acyl alkyl C40:5, and phosphatidylcholine acyl alkyl C42:2. (<b>B</b>) Metabolite model and BTM model for males. BTM model: AUC = 0.418, 95% CI 0.195–0.642; male model: AUC = 0.801, 95% CI 0.636–0.966; male model versus BTMs: <span class="html-italic">p</span> = 0.007. ROC: receiver operating characteristic; BTMs: bone turnover markers; AUC: area under the curve; CI: confidence interval. BTMs include osteocalcin, N-terminal procollagen of type I collagen (PINP), and β-cross-linked C-telopeptide of type I collagen (β-CTX). The male model includes lyso-phosphatidylcholine acyl C16:0, phosphatidylcholine diacyl C34:1, sphingomyelin C26:1, arginine, glutamine, ornithine, valine, and spermine.</p>
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<p>Association between metabolites and clinical indices. –––(<b>A</b>) Association between metabolomic modules and clinical indices (females). (<b>B</b>) Association between metabolomic modules and clinical indices (males). (<b>C</b>) Association between metabolomic biomarkers and clinical indices (females). (<b>D</b>) Association between metabolomic biomarkers and clinical indices (males). (<b>E</b>) Mediation analysis of metabolites between TFFM and osteopenia in females. BMI, body mass index; GGT, γ-glutamyl transpeptidase; ALT, alanine aminotransferase; AST, aspartate aminotransferase; ALP, alkaline phosphatase; CHE, cholinesterase; PAB, prealbumin; ALB, albumin; TSH, thyroid stimulating hormone; FT3, free tri-Iodothyronine; FT4, free thyroxine; APO, apolipoprotein; TC, total cholesterol; LDL, low-density lipoprotein cholesterol; TG, triglyceride; HDL, high-density lipoprotein cholesterol; FFA, free fatty acid; LPA, Lipoprotein(a); CR, creatinine; BUN, blood urea nitrogen; Ca, calcium; P, phosphorus; ACR, albumin-to-creatinine ratio; GA, glycated albumin; HbA1c, glycated hemoglobin; GSP, glycosylated serum protein; CRP, C-reactive protein; NMID, N-terminal osteocalcin; BFP, body fat percentage; TFM, total fat mass; TFFM, total fat-free mass; 25(OH)D, 25-hydroxyvitamin D3; PTH, parathyroid hormone; β-CTX, β-cross-linked C-telopeptide of type I collagen; PINP, N-terminalprocollagen of type I collagen; UA, uric acid; SFA, subcutaneous fat area; VFA, visceral fat area; SBP, systolic blood pressure; DBP, diastolic blood pressure; WC, waist circumference; HOMA, homeostasis model assessment; STU-1, Stumvoll first-phase insulin secretion index; STU-2, Stumvoll second-phase insulin secretion index; log, log-transformation; ACME, average causal mediation effect; ADE, average direct effect.</p>
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9 pages, 1632 KiB  
Communication
Bifunctional Electromagnetic Manipulation of Surface Waves Using Metasurfaces Under One Circularly Polarized Incidence
by Min Kang, Lixing Chen, Shuaipeng Qin, Liang Ma, Aoxiang Rui and Shiqing Li
Photonics 2025, 12(1), 91; https://doi.org/10.3390/photonics12010091 (registering DOI) - 20 Jan 2025
Abstract
The ability to freely manipulate the wavefronts of surface plasmon polaritons (SPPs) or surface waves (SWs), particularly with multifunctional integration, is of great importance in near-field photonics. However, conventional SPP control devices typically suffer from low efficiency and single-function limitations. Although recent works [...] Read more.
The ability to freely manipulate the wavefronts of surface plasmon polaritons (SPPs) or surface waves (SWs), particularly with multifunctional integration, is of great importance in near-field photonics. However, conventional SPP control devices typically suffer from low efficiency and single-function limitations. Although recent works have proposed metasurfaces that achieve bifunctional SPP manipulation, their implementation relies on the excitations of circularly polarized (CP) light with different helicities. Here, we propose a generic approach to designing bifunctional SPP meta-devices under single-helicity circularly polarized incidence. Constructed using carefully selected and arranged meta-atoms that possess both structural resonance and a geometric phase, this kind of meta-device can exhibit two distinct SPP manipulation functionalities in both co- and cross-polarized output channels under one CP incidence. As proof of this concept, we designed a bifunctional meta-device in the microwave regime and numerically demonstrated that it can convert a normally incident left circularly polarized (LCP) beam into SWs, exhibiting both a focused wavefront in the co-polarized output channel and a deflected wavefront in the cross-polarized output channel. Our findings substantially enrich the capabilities of metasurfaces to manipulate near-field electromagnetic waves, which can find many applications in practice. Full article
(This article belongs to the Special Issue New Perspectives in Optical Design)
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Figure 1

Figure 1
<p>Schematic principle of proposed metasurfaces. Schematic of the designed bifunctional metasurface for near-field SW manipulations in both co- and cross-polarized output channels, as shined using single-helicity circularly polarized (CP) waves. The output SWs can achieve an arbitrary functionality, such as SWs with a focusing wavefront in the co-polarized output channel and SWs with a deflecting wavefront in the cross-polarized output channel.</p>
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<p>Characterization of the designed meta−atoms and plasmonic metal. (<b>a</b>) Geometry of the designed meta−atom (sized 7 × 7 mm<sup>2</sup>) composed of the metallic Jerusalem cross structure array and a flat metal mirror separated by a 1.5 mm thick dielectric spacer. (<b>b</b>) Finite element method (FEM) −simulated dispersion relation (red line) of the eigen SWs supported by the plasmonic metal, as depicted in the inset. (<b>c</b>,<b>d</b>) Pseudocolor maps of simulated (<b>c</b>) <math display="inline"><semantics> <mrow> <mn>0.5</mn> <mo>∆</mo> <mi mathvariant="sans-serif">φ</mi> </mrow> </semantics></math> and (<b>d</b>) <math display="inline"><semantics> <mrow> <mn>0.5</mn> <mi mathvariant="sans-serif">Σ</mi> <mi mathvariant="sans-serif">φ</mi> </mrow> </semantics></math> for the structure of (<b>a</b>) in a parameter space spanned by <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> <mfenced separators="|"> <mrow> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> <mo>=</mo> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msub> <mo>+</mo> <msub> <mrow> <mi>b</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msub> </mrow> </mfenced> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mi>y</mi> </mrow> </msub> <mfenced separators="|"> <mrow> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mi>y</mi> </mrow> </msub> <mo>=</mo> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msub> <mo>+</mo> <msub> <mrow> <mi>b</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msub> </mrow> </mfenced> </mrow> </semantics></math> at 10 GHz. The purple lines indicate <math display="inline"><semantics> <mrow> <mn>0.5</mn> <mo>∆</mo> <mi>φ</mi> <mo>=</mo> <mrow> <mrow> <mi>π</mi> </mrow> <mo>/</mo> <mrow> <mn>4</mn> </mrow> </mrow> </mrow> </semantics></math>.</p>
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<p>Structural details of the designed bifunctional meta−device. (<b>a</b>) The proposed meta-device for generating SWs with both hyperbolic and linear phase profiles dictated under LCP wave illumination. (<b>b</b>−<b>d</b>) Distributions of (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mi>x</mi> </mrow> </msub> <mfenced separators="|"> <mrow> <mi>x</mi> <mo>,</mo> <mi>y</mi> </mrow> </mfenced> </mrow> </semantics></math>, (<b>c</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>l</mi> </mrow> <mrow> <mi>y</mi> </mrow> </msub> <mfenced separators="|"> <mrow> <mi>x</mi> <mo>,</mo> <mi>y</mi> </mrow> </mfenced> </mrow> </semantics></math>, and (<b>d</b>) <math display="inline"><semantics> <mrow> <mi>θ</mi> <mfenced separators="|"> <mrow> <mi>x</mi> <mo>,</mo> <mi>y</mi> </mrow> </mfenced> </mrow> </semantics></math> of the designed bifunctional meta-device.</p>
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<p>Bifunctional meta−device for near−field SW manipulations. (<b>a</b>) FEM−simulated near-field Re[<span class="html-italic">Ez</span>] patterns in the whole system, as the meta−device is illuminated by an LCP wave. (<b>b</b>) The near-field <math display="inline"><semantics> <mrow> <mrow> <mrow> <msup> <mrow> <mfenced open="|" close="|" separators="|"> <mrow> <msub> <mrow> <mi>E</mi> </mrow> <mrow> <mi>y</mi> </mrow> </msub> </mrow> </mfenced> </mrow> <mrow> <mn>2</mn> </mrow> </msup> </mrow> <mo stretchy="true">/</mo> <mrow> <msup> <mrow> <mfenced open="|" close="|" separators="|"> <mrow> <msub> <mrow> <mi>E</mi> </mrow> <mrow> <mi>y</mi> <mn>0</mn> </mrow> </msub> </mrow> </mfenced> </mrow> <mrow> <mn>2</mn> </mrow> </msup> </mrow> </mrow> </mrow> </semantics></math> distribution of the SWs at the focal length position versus the y coordinate with <span class="html-italic">F</span> = 196 mm. The inset shows part of the SW focusing in the co−polarized output channel. (<b>c</b>) The simulated near-field Re[<span class="html-italic">Ez</span>] profiles of the SW deflection in the cross−polarized output channel. Here, the frequency is fixed at 10 GHz.</p>
Full article ">
38 pages, 3394 KiB  
Review
A Compact Review of Current Technologies for Carbon Capture as Well as Storing and Utilizing the Captured CO2
by Tim M. Thiedemann and Michael Wark
Processes 2025, 13(1), 283; https://doi.org/10.3390/pr13010283 - 20 Jan 2025
Viewed by 2
Abstract
With the consequences of climate change becoming more urgent, there has never been a more pressing need for technologies that can help to reduce the carbon dioxide (CO2) emissions of the most polluting sectors, such as power generation, steel, cement, and [...] Read more.
With the consequences of climate change becoming more urgent, there has never been a more pressing need for technologies that can help to reduce the carbon dioxide (CO2) emissions of the most polluting sectors, such as power generation, steel, cement, and the chemical industry. This review summarizes the state-of-the-art technologies for carbon capture, for instance, post-combustion, pre-combustion, oxy-fuel combustion, chemical looping, and direct air capture. Moreover, already established carbon capture technologies, such as absorption, adsorption, and membrane-based separation, and emerging technologies like calcium looping or cryogenic separation are presented. Beyond carbon capture technologies, this review also discusses how captured CO2 can be securely stored (CCS) physically in deep saline aquifers or depleted gas and oil reservoirs, stored chemically via mineralization, or used in enhanced oil recovery. The concept of utilizing the captured CO2 (CCU) for producing value-added products, including formic acid, methanol, urea, or methane, towards a circular carbon economy will also be shortly discussed. Real-life applications, e.g., already pilot-scale continuous methane (CH4) production from flue gas CO2, are shown. Actual deployment of the most crucial technologies for the future will be explored in real-life applications. This review aims to provide a compact view of the most crucial technologies that should be considered when choosing to capture, store, or convert CO2, informing future researchers with efforts aimed at mitigating CO2 emissions and tackling the climate crisis. Full article
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Figure 1
<p>Simplified scheme for the post-combustion route for carbon capture (based on [<a href="#B17-processes-13-00283" class="html-bibr">17</a>]).</p>
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<p>Simplified flowsheet of CO<sub>2</sub> absorption via fluid absorbents (based on [<a href="#B19-processes-13-00283" class="html-bibr">19</a>]).</p>
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<p>Simplified flowsheet of CO<sub>2</sub> capture via calcium looping (based on [<a href="#B84-processes-13-00283" class="html-bibr">84</a>]).</p>
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<p>Simplified flowsheet of CO<sub>2</sub> absorption via membrane separation using a hollow fiber membrane: (<b>a</b>) flue gas stream inside the lumen side, (<b>b</b>) fluid absorbent inside the lumen side, and (<b>c</b>) transverse flow of flue gas stream (based on [<a href="#B102-processes-13-00283" class="html-bibr">102</a>]).</p>
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<p>Techniques for cryogenic CO<sub>2</sub> capture in the conventional and unconventional pathways (based on [<a href="#B102-processes-13-00283" class="html-bibr">102</a>]).</p>
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<p>Simplified flowsheet of the pre-combustion route (based on [<a href="#B17-processes-13-00283" class="html-bibr">17</a>]).</p>
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<p>Simplified flowsheet of an integrated gasification combined cycle (based on [<a href="#B149-processes-13-00283" class="html-bibr">149</a>]).</p>
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<p>Simplified flowsheet of the oxy-fuel combustion route (based on [<a href="#B19-processes-13-00283" class="html-bibr">19</a>]).</p>
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<p>Simplified flowsheet of chemical looping combustion route (based on [<a href="#B170-processes-13-00283" class="html-bibr">170</a>,<a href="#B171-processes-13-00283" class="html-bibr">171</a>]).</p>
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<p>Simplified flowsheet of direct air capture.</p>
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<p>Simplified possibilities for carbon storage solutions: (1) depleted oil/gas fields, (2) enhanced oil recovery, (3) coal beds, (4) deep saline aquifers, and (5) carbonate materials (based on [<a href="#B205-processes-13-00283" class="html-bibr">205</a>]).</p>
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<p>Concave-down geometry of a deep saline aquifer with cap rock sealing (based on [<a href="#B211-processes-13-00283" class="html-bibr">211</a>]).</p>
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14 pages, 6246 KiB  
Article
Design and Preparation of ZnIn2S4/g-C3N4 Z-Scheme Heterojunction for Enhanced Photocatalytic CO2 Reduction
by Jinghong Fang, Min Wang, Xiaotong Yang, Qiong Sun and Liyan Yu
Catalysts 2025, 15(1), 95; https://doi.org/10.3390/catal15010095 (registering DOI) - 20 Jan 2025
Viewed by 159
Abstract
In this study, a novel Z-scheme heterojunction photocatalyst was developed by integrating g-C3N4 nanoplates into ZnIn2S4 microspheres. X-ray photoelectron spectroscopy analysis revealed a directional electron transfer from g-C3N4 to ZnIn2S4 upon [...] Read more.
In this study, a novel Z-scheme heterojunction photocatalyst was developed by integrating g-C3N4 nanoplates into ZnIn2S4 microspheres. X-ray photoelectron spectroscopy analysis revealed a directional electron transfer from g-C3N4 to ZnIn2S4 upon heterojunction formation. Under irradiation, electrochemical tests and electron paramagnetic resonance spectroscopy demonstrated significantly enhanced charge generation and separation efficiencies in the ZnIn2S4/g-C3N4 composite, accompanied by reduced charge transfer resistance. In photocatalytic CO2 reduction, the ZnIn2S4/g-C3N4 composite achieved the highest CO yield, 1.92 and 5.83 times higher than those of pristine g-C3N4 and ZnIn2S4, respectively, with a notable CO selectivity of 91.3% compared to H2 (8.7%). The Z-scheme heterojunction mechanism, confirmed in this work, effectively preserved the strong redox capabilities of the photoinduced charge carriers, leading to superior photocatalytic performance and excellent long-term stability. This study offers valuable insights into the design and development of g-C3N4-based heterojunctions for efficient solar-driven CO2 reduction. Full article
(This article belongs to the Special Issue Functional Nanomaterials in Catalysis and Sensing)
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<p>XRD patterns of g-C<sub>3</sub>N<sub>4</sub>, ZnIn<sub>2</sub>S<sub>4</sub> and 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>.</p>
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<p>FESEM images of (<b>a</b>) ZnIn<sub>2</sub>S<sub>4</sub> and (<b>b</b>) 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>, along with (<b>c</b>–<b>h</b>) the corresponding elemental mappings of Zn, In, S, C, and N in 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>.</p>
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<p>XPS spectra of g-C<sub>3</sub>N<sub>4</sub>, ZnIn<sub>2</sub>S<sub>4</sub>, and 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>: (<b>a</b>) survey spectra, (<b>b</b>) C 1s, (<b>c</b>) N 1s, (<b>d</b>) Zn 2p, (<b>e</b>) In 3d, and (<b>f</b>) S 2p spectra.</p>
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<p>(<b>a</b>) UV-vis absorption spectra, (<b>b</b>) Tauc plots, and (<b>c</b>) PL spectra of g-C<sub>3</sub>N<sub>4</sub>, ZnIn<sub>2</sub>S<sub>4</sub>, and 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>.</p>
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<p>Mott–Schottky plots of (<b>a</b>) g-C<sub>3</sub>N<sub>4</sub>, (<b>b</b>) ZnIn<sub>2</sub>S<sub>4</sub>, and (<b>c</b>) 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> measured at different frequencies.</p>
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<p>(<b>a</b>) Transient photocurrent response curves of g-C<sub>3</sub>N<sub>4</sub>, ZnIn<sub>2</sub>S<sub>4</sub>, and 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> under light on/off cycles. (<b>b</b>) Nyquist plots of g-C<sub>3</sub>N<sub>4</sub>, ZnIn<sub>2</sub>S<sub>4</sub>, and 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>.</p>
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<p>CO<sub>2</sub> reduction performance under various conditions: (1) photocatalytic CO<sub>2</sub> reduction using a 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> composite under light irradiation; (2) reaction with light and CO<sub>2</sub> but without the catalyst; (3) reaction without light, but with the catalyst and CO<sub>2</sub>; (4) reaction with light and the catalyst, where CO<sub>2</sub> is replaced by Ar.</p>
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<p>(<b>a</b>) Photocatalytic performance of the catalyst with varying mass ratios of ZnIn<sub>2</sub>S<sub>4</sub> to g-C<sub>3</sub>N<sub>4</sub>; (<b>b</b>) time-dependent gas yield for the 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>; (<b>c</b>) photocatalytic performance of the composite materials at different dosages; (<b>d</b>) results of the cyclic stability experiments.</p>
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<p>TEMPO spin-trapping EPR spectra of g-C<sub>3</sub>N<sub>4</sub> and 1:2 ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>, showing photoinduced electron signals recorded in water.</p>
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<p>Proposed charge transfer mechanism for the efficient photocatalytic CO<sub>2</sub> reduction process facilitated by the ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunction.</p>
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<p>The preparation process of ZnIn<sub>2</sub>S<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>.</p>
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<p>Detailed flow chart of the photocatalytic CO<sub>2</sub> reduction process.</p>
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14 pages, 1435 KiB  
Article
Concise Synthesis of Naphthalene-Based 14-Aza-12-Oxasteroids
by Smriti Srivastava, Jun Luo, Daniel Whalen, Katherine N. Robertson and Amitabh Jha
Molecules 2025, 30(2), 415; https://doi.org/10.3390/molecules30020415 - 19 Jan 2025
Viewed by 340
Abstract
A concise, transition metal-free four-step synthetic pathway has been developed for the synthesis of tetracyclic heterosteroidal compounds, 14-aza-12-oxasteroids, starting from readily available 2-naphthol analogues. After conversion of 2-naphthols to 2-naphthylamines by the Bucherer reaction, subsequent selective C-acetylation was achieved via the Sugasawa reaction [...] Read more.
A concise, transition metal-free four-step synthetic pathway has been developed for the synthesis of tetracyclic heterosteroidal compounds, 14-aza-12-oxasteroids, starting from readily available 2-naphthol analogues. After conversion of 2-naphthols to 2-naphthylamines by the Bucherer reaction, subsequent selective C-acetylation was achieved via the Sugasawa reaction and reduction of the acetyl group using borohydride, which resulted into the corresponding amino-alcohols. The naphthalene-based amino-alcohols underwent double dehydrations and double intramolecular cyclization with oxo-acids leading to one-pot formation of a C-N bond, a C-O bond and an amide bond in tandem, to generate two additional rings completing the steroidal framework. A series of 14-aza-12-oxasteroids were synthesized using our developed synthetic strategy in moderate yields, and the structure of one of the final products, 12a-Methyl-11-phenyl-11,12a-dihydro-1H-naphtho[2,1-d]pyrrolo[2,1-b][1,3]oxazin-3(2H)-one, was further confirmed by single crystal X-ray crystallography. Full article
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<p>Representative natural steroids and clinically used heterosteroids.</p>
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<p>(<b>a</b>) ORTEP diagram of compound <b>4b</b> drawn in 50% thermal probability ellipsoids as a single (4<span class="html-italic">S</span>,6<span class="html-italic">R</span>) enantiomer; (<b>b</b>) chemical structure of <b>4b</b> with similar numbering and atom colouring patterns as in the X-ray crystal structure.</p>
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<p>Retrosynthetic analysis for the synthesis of 14-aza-12-oxasteroids <b>A</b>.</p>
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<p>Reagents and conditions: (i) (NH<sub>4</sub>)<sub>2</sub>SO<sub>3</sub> (2.0 equiv.), 28% aq. NH<sub>3</sub>, 100 psi, 150 °C, 5–6 h; (ii) (a) R<sup>2</sup>CN (6.5 equiv.), BCl<sub>3</sub> (1.2 equiv.), AlCl<sub>3</sub> (1.2 equiv.), N<sub>2</sub>, toluene, 2–4 h; (b) 1.0 M HCl (1.2 equiv. except for <b>2b</b> and <b>2f</b> where 12 M, 500.0 equiv. used), 30 min–4 h; (iii) NaBH<sub>4</sub> (6.0 equiv., 12.0 equiv. for <b>2b</b> and <b>2f</b>, respectively), MeOH:THF (1:1), N<sub>2</sub>, 1 h; (iv) keto acids [1.5 equiv., levulinic acid/2-carboxybenzaldehyde/4-acetylbutyric acid/(2-oxopropylsulfanyl)-acetic acid], toluene, reflux, Dean–Stark trap, 2 h. “*” represents chiral centers. The yields reported are unoptimized.</p>
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<p>A plausible mechanism for synthesis of 14-aza-12-oxasteroids considering synthesis of <b>4b</b> as the representative example. The intermediates are labelled as <b>I</b>–<b>IV</b>.</p>
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24 pages, 1242 KiB  
Article
As(III) Removal via Combined Addition of Mg- and Ca-Based Adsorbents and Comparison to As(V) Removal via Those Mechanisms
by Hajime Sugita, Kazuya Morimoto, Takeshi Saito and Junko Hara
Sustainability 2025, 17(2), 757; https://doi.org/10.3390/su17020757 (registering DOI) - 19 Jan 2025
Viewed by 249
Abstract
Damage to human health caused by As-contaminated water can be prevented using proper As-removal techniques, such as employing excellent arsenic adsorbents. In this study, the combined addition of Mg- and Ca-based adsorbents was investigated for the efficient removal of As from contaminated water. [...] Read more.
Damage to human health caused by As-contaminated water can be prevented using proper As-removal techniques, such as employing excellent arsenic adsorbents. In this study, the combined addition of Mg- and Ca-based adsorbents was investigated for the efficient removal of As from contaminated water. Following a previous study on As(V), As-removal tests targeting As(III) and several additional tests, including X-ray diffraction analysis, were conducted to clarify the mechanism of the improved performance of the combined-addition As removal. Similarly as for As(V), the combined additions of both MgCO3 + CaO and MgCO3 + Ca(OH)2 improved As(III)-removal performance while inhibiting the leaching of base material components; however, they did not remove As(III) as effectively as As(V). The differences in the removal ratios of As(V) and As(III) in these combined additions were concluded to be primarily due to the different As-removal mechanisms. Mg(OH)2 and CaCO3 were generated, and As(III) was incorporated into the generated precipitate of Mg(OH)2 but not into that of CaCO3. Conversely, As(V) was incorporated into both Mg(OH)2 and CaCO3. Additionally, MgCO3 + Ca(OH)2 was evaluated as a more efficient combined-addition method because MgCO3 + Ca(OH)2 exhibited a higher As-removal ratio value than MgO + CaO. Proposals have been made to remove As(III) using activated carbon modified with heavy metals or transition elements, or concrete waste grafted with polymers, but these methods are complicated to prepare, costly, and involve the risk of leaching of harmful components. Adsorbents that use general Mg and Ca components as their base material do not contain such harmful components. The Mg- and Ca-based adsorbents are readily available and low-cost, and, best of all, there is no concern that they will leach harmful components. Therefore, widespread use of Mg- and Ca-based adsorbents as a measure against arsenic contamination could greatly contribute to a sustainable society. Full article
(This article belongs to the Special Issue Advances in Adsorption for the Removal of Emerging Contaminants)
21 pages, 5699 KiB  
Article
Evaluation of Different Few-Shot Learning Methods in the Plant Disease Classification Domain
by Alexander Uzhinskiy
Biology 2025, 14(1), 99; https://doi.org/10.3390/biology14010099 (registering DOI) - 19 Jan 2025
Viewed by 194
Abstract
Early detection of plant diseases is crucial for agro-holdings, farmers, and smallholders. Various neural network architectures and training methods have been employed to identify optimal solutions for plant disease classification. However, research applying one-shot or few-shot learning approaches, based on similarity determination, to [...] Read more.
Early detection of plant diseases is crucial for agro-holdings, farmers, and smallholders. Various neural network architectures and training methods have been employed to identify optimal solutions for plant disease classification. However, research applying one-shot or few-shot learning approaches, based on similarity determination, to the plantdisease classification domain remains limited. This study evaluates different loss functions used in similarity learning, including Contrastive, Triplet, Quadruplet, SphereFace, CosFace, and ArcFace, alongside various backbone networks, such as MobileNet, EfficientNet, ConvNeXt, and ResNeXt. Custom datasets of real-life images, comprising over 4000 samples across 68 classes of plant diseases, pests, and their effects, were utilized. The experiments evaluate standard transfer learning approaches alongside similarity learning methods based on two classes of loss function. Results demonstrate the superiority of cosine-based methods over Siamese networks in embedding extraction for disease classification. Effective approaches for model organization and training are determined. Additionally, the impact of data normalization is tested, and the generalization ability of the models is assessed using a special dataset consisting of 400 images of difficult-to-identify plant disease cases. Full article
(This article belongs to the Section Theoretical Biology and Biomathematics)
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<p>Examples of images in the database.</p>
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<p>Examples of images in the batch for Contrastive loss.</p>
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<p>Examples of images in the batch for Triplet loss.</p>
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<p>Examples of images in the batch for Quadruplet loss.</p>
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<p>Evaluation of metrics (accuracy and loss) for the models selected during the first stage of the experiment.</p>
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<p>Loss charts for different base networks trained with various loss functions during the second stage of the experiment.</p>
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<p>2D PCA visualization of embeddings extracted by networks trained with Contrastive Loss. Different colors represent different classes.</p>
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<p>2D PCA visualization of embeddings extracted by networks. Different colors represent different classes.</p>
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19 pages, 3390 KiB  
Article
Research on the Sustainability Strategy of Cogeneration Microgrids Based on Supply-Demand Synergy
by Zhilong Yin, Zhiguo Wang, Feng Yu, Yue Long and Na Li
Sustainability 2025, 17(2), 752; https://doi.org/10.3390/su17020752 (registering DOI) - 18 Jan 2025
Viewed by 438
Abstract
With the continuous adjustment of energy structure and the improvement of environmental protection requirements, combined heat and power microgrids (CHP-MG) have received widespread attention as an efficient and economical way of utilizing energy. The complexity of energy supply relationships and energy coupling within [...] Read more.
With the continuous adjustment of energy structure and the improvement of environmental protection requirements, combined heat and power microgrids (CHP-MG) have received widespread attention as an efficient and economical way of utilizing energy. The complexity of energy supply relationships and energy coupling within the microgrid system necessitates optimizing the power output of each equipment unit. In this paper, an optimization strategy for a multi-energy microgrid system is proposed based on the efficient energy supply of cogeneration microgrids: decoupling the thermoelectric connection by using the energy storage equipment on the supply side, utilizing the flexibility of the electrical loads and the diversity of the system’s heating methods, and reducing the electrical loads and changing the selection of the heating methods on the demand side. The optimization model in the paper is mainly based on mixed-integer linear programming and demand-side management theory, which simulates the system operation under different scenarios so as to find the optimal equipment output and load management strategies. Simulation results show that the optimized CHP-MG system can ensure a reliable power supply while effectively reducing operating costs, improving energy utilization and promoting sustainable operation of the energy system. The optimized microgrid system offers significant advantages in terms of economic efficiency and energy management when compared to conventional CHP systems. These findings provide actionable insights for policymakers, system operators, and researchers aimed at driving the development of efficient and sustainable energy management solutions. Full article
16 pages, 3396 KiB  
Article
Estimation of Characteristics, Methane Generated and Sustainability of Municipal Landfill Waste in Urban City, Thailand
by Yaowatat Boongla, Supachai Changphuek and Anuwat Saehuang
Recycling 2025, 10(1), 15; https://doi.org/10.3390/recycling10010015 - 18 Jan 2025
Viewed by 616
Abstract
Many developed and developing countries are concerned about climate change and greenhouse gas (GHG) reduction, with landfills being a major contributor due to the presence of important GHGs such as carbon dioxide (CO2) and methane (CH4) in landfill emissions. [...] Read more.
Many developed and developing countries are concerned about climate change and greenhouse gas (GHG) reduction, with landfills being a major contributor due to the presence of important GHGs such as carbon dioxide (CO2) and methane (CH4) in landfill emissions. The appropriate technology or suitable innovation could result in the extraction of significant amounts of energy from CH4 in landfills. This work used landfill gas emissions (LandGEM) software modeling to analyze the distribution patterns of the gas emissions of two urban landfills in Chonburi and Phuket Provinces, Thailand, from 2013 to 2023. The methane emissions from the Chonburi landfill were 1.063 × 104 Mg/year, and they were 1.077 × 103 Mg/year for the Phuket landfill, in 2023. According to estimates, the Chonburi landfill emitted 2.916 × 104 Mg/year of CO2 in 2023, while Phuket emitted 2.955 × 103 Mg/year. The Chonburi landfill generated 8.67 MWh/year and 195.74 MWh/year of electrical energy potential from CH4 in 2014 and 2023. In 2014 and 2023, the electrical energy potential from CH4 was 1.00 MWh/year and 19.83 MWh/year for the Phuket landfill. This study’s results show that landfills can produce CH4 and that it is possible to collect this gas and stop GHG emissions from entering the atmosphere. This would be beneficial for local authorities considering the potential of landfill gas. Full article
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<p>Emission rates of CH<sub>4</sub>, CO<sub>2</sub>, and other NMOC gases (m<sup>3</sup>/year) in Chonburi landfill.</p>
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<p>Emission rates of CH<sub>4</sub>, CO<sub>2</sub>, and other NMOC gases (m<sup>3</sup>/year) in Phuket landfill.</p>
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<p>Energetic potential of methane from Chonburi landfill.</p>
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<p>Energetic potential of methane from Phuket landfill.</p>
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<p>Locations of municipal solid waste facilities.</p>
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<p>A common flowchart for municipal solid waste-to-energy technologies is presented. LandGEM was used to analyze the processes using biochemical conversion.</p>
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13 pages, 1421 KiB  
Article
Cumulative Energy Demand and Greenhouse Gas Emissions from Potato and Tomato Production in Southeast Brazil
by Breno de Jesus Pereira, Newton La Scala and Arthur Bernardes Cecílio Filho
Agronomy 2025, 15(1), 235; https://doi.org/10.3390/agronomy15010235 - 18 Jan 2025
Viewed by 522
Abstract
Knowing the energy balance in agricultural systems is essential for a holistic understanding of sustainability, productivity and economic return. The aim of this study was to estimate the cumulative energy demand (CED), greenhouse gas (GHG) emissions and carbon footprint in industrial potato and [...] Read more.
Knowing the energy balance in agricultural systems is essential for a holistic understanding of sustainability, productivity and economic return. The aim of this study was to estimate the cumulative energy demand (CED), greenhouse gas (GHG) emissions and carbon footprint in industrial potato and tomato production systems in the Southeast region of Brazil, identifying mitigation strategies in different scenarios. The Life Cycle Analysis methodology was used, and two functional units were defined: one hectare of cultivation and one kilogram of vegetable produced. The CEDs for tomato and potato production were 59,553.56 MJ ha–1 (or 0.54 MJ kg–1) and 57,992.02 MJ ha–1 (or 1.45 MJ kg–1), respectively. The GHG emissions were 5425.13 kg CO2 eq ha–1 for potato production and 5270.9 kg CO2 eq ha–1 for tomato production, resulting in carbon footprints of 0.135 and 0.042 kg CO2 eq kg–1, respectively. Fertilizers, diesel and pesticides were the main contributors to CED and GHG emissions. Thus, in order to achieve greater sustainability in the production of these vegetables and mitigate the impacts on the environment generated by the high demand for energy and GHG emissions, it is necessary to replace synthetic fertilizers with organic sources, chemical pesticides with biological pesticides, diesel with biodiesel or the use of electric vehicles and tractors, resulting in reductions of up to 39 and 52% in the GHG emissions for potatoes and tomatoes, respectively. Full article
(This article belongs to the Section Agricultural Biosystem and Biological Engineering)
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<p>Flowchart for assessing the cumulative energy demand (CED), greenhouse gas (GHG) emissions and carbon footprint of intensive potato and tomato production during one agricultural year.</p>
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<p>Percentage contribution of each input, material and fuel to the cumulative energy demand (CED) for potato and tomato production in an intensive cultivation system.</p>
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<p>Percentage contribution of each input, material and fuel to total greenhouse gas (GHG) emissions for potato and tomato production in an intensive cultivation system.</p>
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<p>Real condition (CR) of greenhouse gas (GHG) emissions and scenarios (C1—replacement of synthetic N fertilizer with organic sources and chemical pesticides with biological ones; C2—replacement of synthetic N fertilizer with organic sources, chemical pesticides with biological ones and diesel/machinery with electric tractors; and C3—replacement of synthetic N fertilizer with organic sources, chemical pesticides with biological ones and diesel with biodiesel) of alternatives proposed for mitigating emissions associated with the main emission sources used in the production of potatoes and tomatoes, in an intensive cultivation system.</p>
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29 pages, 4950 KiB  
Article
Sustainable Design in Agriculture—Energy Optimization of Solar Greenhouses with Renewable Energy Technologies
by Danijela Nikolić, Saša Jovanović, Nebojša Jurišević, Novak Nikolić, Jasna Radulović, Minja Velemir Radović and Isidora Grujić
Energies 2025, 18(2), 416; https://doi.org/10.3390/en18020416 - 18 Jan 2025
Viewed by 549
Abstract
In modern agriculture today, the cultivation of agricultural products cannot be imagined without greenhouses. This paper presents an energy optimization of a solar greenhouse with a photovoltaic system (PV) and a ground-source heat pump (GSHP). The PV system generates electricity, while the GSHP [...] Read more.
In modern agriculture today, the cultivation of agricultural products cannot be imagined without greenhouses. This paper presents an energy optimization of a solar greenhouse with a photovoltaic system (PV) and a ground-source heat pump (GSHP). The PV system generates electricity, while the GSHP is used for heating and cooling. A greenhouse is designed with an Open Studio plug-in in the Google SketchUp environment, the EnergyPlus software (8.7.1 version) was used for energy simulation, and the GenOpt software (2.0.0 version) was used for optimization of the azimuth angle and PV cell efficiency. Results for different solar greenhouse orientations and different photovoltaic module efficiency are presented in the paper. The obtained optimal azimuth angle of the solar greenhouse was −8°. With the installation of a PV array with higher module efficiency (20–24%), it is possible to achieve annual energy savings of 6.87–101.77%. Also, with the PV module efficiency of 23.94%, a concept of zero-net-energy solar greenhouses (ZNEG) is achieved at optimal azimuth and slope angle. Through the environmental analysis of different greenhouses, CO2 emissions of PV and GSHP are calculated and compared with electricity usage. Saved CO2 emission for a zero-net-energy greenhouse is 6626 kg CO2/year. An economic analysis of installed renewable energy systems was carried out: with the total investment of 19,326 € for ZNEG, the payback period is 8.63 years. Full article
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<p>Model of analyzed solar greenhouse with installed renewable energy systems (winter period).</p>
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<p>Modeled solar greenhouse: (<b>a</b>) side wall; (<b>b</b>) south wall.</p>
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<p>Model of an installed photovoltaic array of a solar greenhouse.</p>
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<p>Monthly heating/cooling load of a solar greenhouse.</p>
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<p>Monthly energy consumption in a referent solar greenhouse.</p>
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<p>The azimuth angle of a solar greenhouse.</p>
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<p>Cooling load of solar greenhouses with different azimuth angles (on 15 July).</p>
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<p>Heating load of solar greenhouses with different azimuth angles (on 15 December).</p>
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<p>Heating and cooling energy consumption in a solar greenhouse with different azimuth angles.</p>
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<p>Generated energy and energy consumption in solar greenhouses with different azimuth angles.</p>
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<p>Energy consumption and generated energy of solar greenhouses with different PV module efficiency.</p>
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<p>Energy consumption, generated energy, and energy surplus in the zero-net-energy greenhouse.</p>
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<p>Emission and total emission of CO<sub>2</sub> (yearly) in different greenhouses.</p>
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<p>Investments, Financial savings and Payback periods of different greenhouses.</p>
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<p>Payback periods for different GSHP and different feed-in tariffs.</p>
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