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Search Results (17,176)

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27 pages, 1325 KiB  
Article
Research on the Carbon Reduction Potential of the Life Cycle of Building Roofs Retrofit Designs
by Dawei Mu, Wenjin Dai, Yixian Zhang, Yixu Shen, Zhi Luo and Shurui Fan
Buildings 2025, 15(2), 299; https://doi.org/10.3390/buildings15020299 - 20 Jan 2025
Abstract
This study examines existing buildings in Haikou in China under tropical island climate conditions. It presents three retrofit design models for greenhouses roofs (GHR), green roofs (GR) and photovoltaic roofs (PVR). The carbon cost of each retrofit roof model is calculated in the [...] Read more.
This study examines existing buildings in Haikou in China under tropical island climate conditions. It presents three retrofit design models for greenhouses roofs (GHR), green roofs (GR) and photovoltaic roofs (PVR). The carbon cost of each retrofit roof model is calculated in the production and transportation phases of building materials, construction, and demolition. The changes in electricity consumption, water consumption, and plant carbon reduction are coupled to calculate the carbon reduction generated by each phase of the use of the retrofitted roofs. The carbon reduction per unit area for GHR, GR and PVR over the life cycle (20 years) is then comprehensively calculated. The life cycle carbon reduction per unit area is 262.57 kg·m−2 for GHR, 127.41 kg·m−2 for GR and 2567.12 kg·m−2 for PVR. Among the three retrofit methods, PVR has the greatest potential for reducing carbon emissions. The study can as a guide for implementing carbon reduction measures in tropical island areas. Domestic research on rooftop greenhouses also focuses on technology, yield, and energy consumption, mostly for northern regions with cold winters, and less research on rooftop greenhouses applied to regions with hot summers and warm winters. But domestic and foreign studies on the potential of rooftop greenhouses to reduce emissions have not yet been combined with plant cultivation of hydroelectric carbon emissions and plant carbon sequestration. Full article
(This article belongs to the Special Issue Indoor Climate and Energy Efficiency in Buildings)
10 pages, 4309 KiB  
Article
Hot Corrosion Behavior of Yttria-Stabilized Zirconia in the Presence of CMAS and CMAS + NaVO3 Mixture
by Mourui Zhang, Yang Feng, Yong Shang, Hui Peng, Lei Guo, Yanling Pei and Shengkai Gong
Coatings 2025, 15(1), 114; https://doi.org/10.3390/coatings15010114 - 20 Jan 2025
Abstract
The aim of this paper is to study the corrosion mechanism of CaO-MgO-Al2O3-SiO2 (CMAS) powder and CMAS + NaVO3 (hereafter referred to as CN) mixed powder on a yttria-stabilized zirconia (YSZ) block at different temperatures. In this [...] Read more.
The aim of this paper is to study the corrosion mechanism of CaO-MgO-Al2O3-SiO2 (CMAS) powder and CMAS + NaVO3 (hereafter referred to as CN) mixed powder on a yttria-stabilized zirconia (YSZ) block at different temperatures. In this paper, the CMAS and CN corrosion behavior of YSZ at 1200 °C and 1250 °C was studied. The results show that at 1200 °C, CMAS cannot completely melt, causing limited damage to YSZ. However, CN melts completely at this temperature, partially penetrating the YSZ interior and causing surface corrosion. At 1250 °C, both CMAS and CN melt completely. CMAS, characterized by high viscosity and shallow penetration, seriously damaged the YSZ surface layer. In contrast, CN, with its lower viscosity and enhanced penetration capability, induces internal corrosion of YSZ. Through the analysis of the corrosion mechanisms of CMAS and CN, it is concluded that CN poses a more significant threat to the integrity of thermal barrier coatings (TBCs). Full article
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<p>The cross-sectional SEM image of YSZ blocks after corrosion of (<b>a</b>,<b>b</b>) CMAS and (<b>c</b>,<b>d</b>) CN at 1200 °C for 20 h.</p>
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<p>The EDS diagram of YSZ block section after corrosion of (<b>a</b>–<b>c</b>) CMAS and (<b>d</b>–<b>f</b>) CN at 1200 °C for 20 h.</p>
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<p>XRD patterns of the YSZ block surface after CMAS and CN corrosion at 1200 °C for 20 h.</p>
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<p>The surface topography of YSZ blocks after corrosion of (<b>a</b>) CMAS and (<b>b</b>) CN at 1250 °C for 20 h compared with (<b>c</b>) the original surface.</p>
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<p>The cross-sectional SEM image of YSZ blocks after corrosion of (<b>a</b>,<b>b</b>) CMAS and (<b>c</b>,<b>d</b>) CN at 1250 °C for 20 h.</p>
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<p>The EDS diagram of YSZ block section after corrosion of (<b>a</b>–<b>c</b>) CMAS and (<b>d</b>–<b>f</b>) CN at 1250 °C for 20 h.</p>
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<p>XRD patterns of the YSZ block surface after CMAS and CN corrosion at 1250 °C for 20 h.</p>
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13 pages, 2395 KiB  
Article
Research Tendency and Frontiers of Multifocal Lenses in Myopic Control in the Past Two Decades: A Bibliometric Analysis
by Lingli Jiang, Manrong Yu, Jiangxiong Cai, Yingying Wang, Hao Hu and Minjie Chen
Healthcare 2025, 13(2), 204; https://doi.org/10.3390/healthcare13020204 - 20 Jan 2025
Abstract
Background: This study aimed to analyze the research progress on the use of a multifocal lens for myopic control throughout the 21st century, utilizing bibliometric analysis. Methods: Publications related to multifocal lenses from 2001 to 2024 were searched on the Web of Science [...] Read more.
Background: This study aimed to analyze the research progress on the use of a multifocal lens for myopic control throughout the 21st century, utilizing bibliometric analysis. Methods: Publications related to multifocal lenses from 2001 to 2024 were searched on the Web of Science core collection (WoSCC) database. VOSviewer (Version 1.6.19) and Bibliometrix package (Version 4.3.0) were used to perform the bibliometric analysis. Primary information including the publication number per year, country or region, journal, keyword, and title of the literature was extracted and analyzed. Results: A total of 234 articles from 31 countries were retrieved. The number of publications related to multifocal lenses had a rapid growth phase from 2016 to 2024. The United States, Australia, China, and Spain emerged as leading contributors to the research landscape. Ophthalmic and Physiological Optics was the most popular journal in this field, and the most frequently cited article was published in Optometry and Vision Science. Myopic progression was the main topic in this research field as well as the principal keywords of emerging research hotspots. Conclusions: Our bibliometric study provides a pioneering overview of the research trends and evolution in the application of a multifocal lens for myopic control. These findings provide a deep insight into current research frontiers and hot directions, offering a valuable reference for further research. Full article
(This article belongs to the Section School Health)
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<p>Flow chart of scientometric analysis.</p>
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<p>Annual publications between 2001 and 2024.</p>
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<p>(<b>A</b>) Number of publications by country or region. SCP, single-country publication, a publication in which all authors are from the same country; MCP, multiple-country publication, a publication with authors from multiple countries, known as a joint publication. (<b>B</b>) The cooperative relationships between a country or region, where the wider the band, the stronger the cooperation between the two regions.</p>
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<p>Number of publications by journal, with the sidebar using a color-coded system to denote the corresponding counts. The left dendrogram on this heatmap illustrates hierarchical clustering outcomes, organizing journals into a tree structure based on similarity. Vertical lines mark journal cluster merges, with height indicating dissimilarity; greater heights suggest higher dissimilarity. Horizontal lines show journal positions, each linking to a tree node. The tree structure reveals hierarchical journal relationships, from individual terms to the overall cluster.</p>
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<p>Keyword analysis. (<b>A</b>) Annual frequency of keywords, with the sidebar using a color-coded system to denote the corresponding counts. The left dendrogram on this heatmap illustrates hierarchical clustering outcomes, organizing keywords into a tree structure based on similarity. Vertical lines mark keyword cluster merges, with height indicating dissimilarity; greater heights suggest higher dissimilarity. Horizontal lines show keyword positions, each linking to a tree node. The tree structure reveals keyword hierarchical relationships, from individual terms to the overall cluster. (<b>B</b>) Keyword co-occurrence network. The size and coloration of the nodes are representative of the volume of keywords and the clusters they form. The interconnecting lines, varied in color, illustrate instances where pairs of keywords were published within the same article.</p>
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<p>Keyword analysis. (<b>A</b>) Annual frequency of keywords, with the sidebar using a color-coded system to denote the corresponding counts. The left dendrogram on this heatmap illustrates hierarchical clustering outcomes, organizing keywords into a tree structure based on similarity. Vertical lines mark keyword cluster merges, with height indicating dissimilarity; greater heights suggest higher dissimilarity. Horizontal lines show keyword positions, each linking to a tree node. The tree structure reveals keyword hierarchical relationships, from individual terms to the overall cluster. (<b>B</b>) Keyword co-occurrence network. The size and coloration of the nodes are representative of the volume of keywords and the clusters they form. The interconnecting lines, varied in color, illustrate instances where pairs of keywords were published within the same article.</p>
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14 pages, 4669 KiB  
Article
Cool Mix Asphalt—Redefining Warm Mix Asphalt with Implementations in Korea, Italy and Vietnam
by Hosin (David) Lee, Lan Ngoc Nguyen, Elena Sturlini and Young-ik Kim
Infrastructures 2025, 10(1), 24; https://doi.org/10.3390/infrastructures10010024 - 20 Jan 2025
Abstract
During the past decades, to minimize Greenhouse Gas (GHG) emissions and asphalt fumes during the asphalt mix production and construction process, various warm mix asphalt (WMA) additives have been developed and successfully applied. Currently, as production of WMA reaches close to that of [...] Read more.
During the past decades, to minimize Greenhouse Gas (GHG) emissions and asphalt fumes during the asphalt mix production and construction process, various warm mix asphalt (WMA) additives have been developed and successfully applied. Currently, as production of WMA reaches close to that of Hot Mix Asphalt (HMA) in the US, the varied definition of WMA is questioned in this paper. Not only are the temperature reduction ranges from HMA defined by various studies too wide, but also the minimum threshold to be classified as WMA is often too small. In this paper, a new category of “Cool Mix Asphalt (CMA)” is proposed to distinguish it from the newly defined WMA based not on the reduction amount from HMA temperature but its actual production temperature. It is proposed that HMA should be defined as asphalt mixtures produced at temperatures between 140 and 160 °C (between 284 and 320 °F), WMA as production temperatures between 120 and 140 °C (between 248 and 284 °F), and CMA as production temperatures between 100 and 120 °C (212 to 248 °F). By defining their actual production temperatures rather than reduction temperatures from HMA, WMA and CMA will be clearly defined. This paper then presents a new Polymer Cool Mix Asphalt (PCMA) additive called “Zero-M”, which was developed to lower the mixing temperature to around 110 °C (203 °F). Recently, test sections using Zero-M were successfully constructed in Korea, Italy and Vietnam, and their laboratory test results of field cores and production and construction experiences are described in this paper. The chemistry and compositions of Zero-M are discussed along with its mechanism to significantly lower the production temperature of PCMA. All test sections constructed in three countries met the in-place compaction density requirements of their respective countries, which were close to or higher than those of the control HMA test sections. Full article
(This article belongs to the Special Issue Cool Mix Asphalt: Redefining Warm Mix Asphalt)
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<p>Production of WMA mixtures in USA and Europe in 2013–2020 [<a href="#B12-infrastructures-10-00024" class="html-bibr">12</a>].</p>
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<p>Percent production of WMA technologies in the USA [<a href="#B12-infrastructures-10-00024" class="html-bibr">12</a>].</p>
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<p>PCMA additive called “Zero-M” manufactured by Hansoo Road Industry.</p>
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<p>HWT test result of PCMA produced at asphalt plant in Jeju, Korea.</p>
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<p>Seoil asphalt plant to produce Zero-M mixtures in Seogwipo City, Korea.</p>
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<p>Construction of 150 m-long “Zero-M” PCMA test section in Seogwipo City, Korea.</p>
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<p>Mixing process by Bindi, Inc. for building test road construction in Florence, Italy.</p>
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<p>Aggregate temperatures of HMA vs. PCMA at Bindi’s Batch Plant.</p>
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<p>Pictures of compaction process of PCMA surface and PCMA/HMA core.</p>
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<p>Hamburg wheel tracking test results of mixtures with 10% and 13% Zero-M.</p>
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<p>Indirect Tensile Cracking Test (IDEAL-CT) results of laboratory-compacted field mixtures with 10% and 13% Zero-M additives.</p>
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<p>Asphalt batch plant and loading of PCMA mixtures in Vietnam.</p>
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<p>(<b>a</b>) Placement and (<b>b</b>) Compaction of Zero-M PCMA Mixtures.</p>
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28 pages, 643 KiB  
Article
Risk Factors for Treatment Toxicity and High Side Effect Burden Among Breast Cancer Survivors: A Retrospective Chart Review
by Muna Alkhaifi, Elwyn Zhang, Malika Peera, Katarzyna Jerzak, Gregory Czarnota, Andrea Eisen, Amanda Roberts, Carlos Amir Carmona-Gonzalez, Rosanna Pezo and Sonal Gandhi
Cancers 2025, 17(2), 328; https://doi.org/10.3390/cancers17020328 - 20 Jan 2025
Abstract
Background/Objectives: This study describes the sequelae, side effects, and toxicities experienced by Canadian breast cancer survivors at a breast cancer survivorship clinic at a tertiary academic cancer centre and identifies potential risk factors which may be associated with increased side effect burden. Methods: [...] Read more.
Background/Objectives: This study describes the sequelae, side effects, and toxicities experienced by Canadian breast cancer survivors at a breast cancer survivorship clinic at a tertiary academic cancer centre and identifies potential risk factors which may be associated with increased side effect burden. Methods: A retrospective chart review was performed of adult patients treated at the Sunnybrook Breast Cancer Survivorship Clinic from 6 July 2022, to 30 September 2023 (n = 435). Results: Most patients (72.6%) reported at least one side effect impacting their quality of life, and a smaller majority (55.4%) reported two or more side effects. The most common symptoms experienced were anxiety (29.4%), chronic pain (23.9%), hot flashes (21.4%), and fear of recurrence (19.8%). Older age was strongly correlated with a lower likelihood of experiencing greater side effect burden (p < 0.01). Patients who underwent chemotherapy were significantly more likely to experience higher side effect burden than patients who did not. Current smokers were more likely than nonsmokers or past smokers to have a higher burden, for both physical (p < 0.01) and psychological side effects (p < 0.01). The multivariate analysis demonstrated that younger age was strongly associated with greater side effect burden, higher likelihood of psychological and physical symptoms, and greater likelihood of requiring close follow-up. Conclusions: The results highlight the need for survivorship resources tailored to survivors under the age of 55 and the importance of referring smokers to smoking cessation programs. Additional research is required to explore the significant reluctance among patients regarding discharge. Future studies should examine the acute needs of younger breast cancer survivors and investigate the impact of smoking and treatment modalities on the side effect burden. Full article
(This article belongs to the Special Issue Beyond Cancer: Enhancing Quality of Life for Cancer Survivors)
17 pages, 2953 KiB  
Review
Cyclodextrins’ Internal Cavity Hydration: Insights from Theory and Experiment
by Silvia Angelova, Stiliyana Pereva, Todor Dudev and Tony Spassov
Inorganics 2025, 13(1), 28; https://doi.org/10.3390/inorganics13010028 - 20 Jan 2025
Abstract
In this short review, recent findings from both theory and experiment regarding the process of hydration of α-, β-, and γ-cyclodextrins are summarized and critically assessed. Key important questions are addressed, including: What factors govern the number of water molecules entrapped in the [...] Read more.
In this short review, recent findings from both theory and experiment regarding the process of hydration of α-, β-, and γ-cyclodextrins are summarized and critically assessed. Key important questions are addressed, including: What factors govern the number of water molecules entrapped in the internal cavity of the host macrocycle? What is the driving force behind this process? What are the “hot spots” for water entrapment inside the host cavity? What is the underlying mechanism of water hydration and dehydration of cyclodextrins? What is the role of the confined water cluster in determining the outcome of the host–guest complexation between cyclodextrins and molecules of inorganic/organic nature? To what extent does water hydration affect the crystalline structure of the cavitand? Full article
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<p>(<b>A</b>) Molecular structure of CDs; (<b>B</b>) Schematic representation of the shape of CDs; (<b>C</b>) M062X/6-31G(d,p) fully optimized non-hydrated CDs (top view from the narrow rim): “closed” configuration—structures with intramolecular hydrogen bonds at both rims with opposite mutual orientation: looking from the narrow rim side the orientation of the wide rim hydrogen bonds is clockwise, while the orientation of the narrow rim hydrogen bonds is counterclockwise, while the orientation of the narrow rim hydrogen bonds is counterclockwise; “open” configuration—the orientation of the wide rim hydrogen bonds is clockwise.</p>
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<p>Electron density of α-CD (isovalue: MO = 0.02, density = 0.0004), mapped with electrostatic potential (color scheme: red/yellow for negative surface map values and blue for positive ones).</p>
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<p>Schematic representation of CD–H<sub>2</sub>O complexes with water molecules/clusters located at three different positions, and M062X/6-311++G(d,p)//M062X/6-31G(d,p) calculated relative enthalpies of the respective complexes.</p>
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<p>Schematic representation of the energetically preferred α-CD–nH<sub>2</sub>O complexes (where n = 1–6).</p>
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<p>Structures of the most densely populated CD hydrates (α-CD—6H<sub>2</sub>O, β-CD—10H<sub>2</sub>O, and γ-CD—7H<sub>2</sub>O).</p>
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<p>Fully optimized geometries of selected β-CD assemblies with water and N<sub>2</sub>O (β-CD—nH2O—N<sub>2</sub>O denotes a complex between β-CD, n water molecules, and N<sub>2</sub>O), and the respective Gibbs free energies of complex formation (in kcal/mol). The hydrogen bond network is visualized in the β-CD—9H<sub>2</sub>O—N<sub>2</sub>O construct (in yellow).</p>
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<p>Thermogravimetric/TG (<b>a</b>) and DSC (<b>b</b>) analysis of as-received α-CD, β-CD, and γ-CD.</p>
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<p>Schematic representation of the possible crystal structure packs of CDs.</p>
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14 pages, 4897 KiB  
Article
Electrochemical Corrosion and Wear Behavior of Hot-Dip Galvanized Steel in Soils of Northern China
by Xiaoyu Jiao, Junhong Jia, Wei Chen and Wenlong Yang
Coatings 2025, 15(1), 112; https://doi.org/10.3390/coatings15010112 - 20 Jan 2025
Abstract
The study examined the corrosion and wear characteristics of hot-dip galvanized steel in complex soil environments. The results showed that hot-dip galvanized steel exhibited improved corrosion resistance characteristics. Additionally, the sliding speed was observed to influence both the coefficient of friction (COF) and [...] Read more.
The study examined the corrosion and wear characteristics of hot-dip galvanized steel in complex soil environments. The results showed that hot-dip galvanized steel exhibited improved corrosion resistance characteristics. Additionally, the sliding speed was observed to influence both the coefficient of friction (COF) and the state of the worn surface. Moreover, the corrosion resistance of hot-dip galvanized steel declined as the immersion period increased. Following the incorporation of friction behavior, the galvanized layer is prone to accelerated degradation. The wear of the galvanized layer resulted in the failure of its electrochemical protection, creating a pathway for corrosion to occur on the substrate as a result of the coupling effect of corrosion and wear. The use of hot-dip galvanized steel presents challenges when exposed to a tribocorrosion environment for a prolonged period. This study lays the groundwork for future research on the maintenance cycle of industrial structures constructed primarily with hot-dip galvanized steel. Full article
(This article belongs to the Special Issue Trends and Advances in Anti-Wear Materials and Coatings)
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<p>The thickness of hot-dip galvanized steel.</p>
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<p>Schematic diagram of electrochemical test sample.</p>
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<p>Flow graphs of (<b>a</b>) sample preparation, (<b>b</b>) electrochemical test and tribocorrosion test, (<b>c</b>) mechanism analysis.</p>
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<p>EIS plots of the samples with Q235 steel and hot-dip galvanized steel immersed in soil extract.</p>
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<p>Equivalent circuit for Q235 steel and hot-dip galvanized steel immersed in soil extract.</p>
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<p>Potential polarization curves of Q235 steel and hot-dip galvanized steel in soil extract.</p>
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<p>Variation of friction coefficient (<b>a</b>) average friction coefficient, (<b>b</b>) wear rate, (<b>c</b>) of Q235 steel and hot-dip galvanized steel at different speeds.</p>
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<p>SEM images of wear surfaces of Q235 steel and hot-dip galvanized steel in soil extract. (<b>a</b>) Q235 steel with a sliding speed of 15 mm/s, (<b>b</b>) Q235 steel with a sliding speed of 20 mm/s, (<b>c</b>) Q235 steel with a sliding speed of 25 mm/s, (<b>d</b>) hot-dip galvanized steel with a sliding speed of 15 mm/s, (<b>e</b>) hot-dip galvanized steel with a sliding speed of 20 mm/s, (<b>f</b>) hot-dip galvanized steel with a sliding speed of 25 mm/s.</p>
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<p>3D topography of wear area and unwear areas of Q235 steel (<b>a</b>–<b>c</b>) and hot-dip galvanized steel (<b>d</b>–<b>f</b>).</p>
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<p>Raman spectra of wear track of Q235 steel and hot-dip galvanized steel at a sliding speed of 25 mm/s.</p>
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<p>XRD patterns of wear tracks of hot-dip galvanized steel in soil extract at different friction rates.</p>
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<p>Schematic diagram of furrow formation and abrasive grains generated by surface crack propagation of hot-dip galvanized steel.</p>
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<p>Corrosion and tribocorrosion of hot-dip galvanized steel in soil extract.</p>
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17 pages, 2133 KiB  
Article
Screening Dominant Species and Exploring Heavy Metals Repair Ability of Wild Vegetation for Phytoremediation in Copper Mine
by Xiaoli Wang, Caihong Tao and Lizhe An
Sustainability 2025, 17(2), 784; https://doi.org/10.3390/su17020784 (registering DOI) - 20 Jan 2025
Viewed by 57
Abstract
Phytoremediation, a sustainable approach, is a hot topic, particularly for harsh mining environments. The Baiyin copper mine, a typical example of massive sulfide deposits, retains value as a national park after closure. Our research on it aimed to explore phytoremediation. By studying the [...] Read more.
Phytoremediation, a sustainable approach, is a hot topic, particularly for harsh mining environments. The Baiyin copper mine, a typical example of massive sulfide deposits, retains value as a national park after closure. Our research on it aimed to explore phytoremediation. By studying the plant community’s phyto-sociological attributes, we found that plants maintained long-term stability, with restoration potential. And the top-level dominant species, Lycium chinense and Nitraria tangutorum, were selected as candidate repair plants based on importance value. Then, we assessed soil heavy metals using pollution indices and found that Pb, As, and Cd were the primary contributors, along with Cu and Zn, causing pollution. Next, we determined the repair ability of two candidate repair plants through their accumulation effect and transport efficiency, finding that both had strong tolerance to these heavy metals and accumulated similar amounts, except for Cu, which was slightly lower than expected; however, Lycium compensated for this with its higher Cu conversion rate, leading to its final recommendation. Lycium has an uncommon advantage: during extraction of active ingredients, it can remove heavy metals as impurities, preserving economic value. This discovery provides the idea, theoretical basis, and pioneer plant for the phytoremediation of sulfide deposits like the Baiyin copper mine, particularly in northwestern China’s mining regions. Full article
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<p>Location of the quadrat sites in Baiyin City, Gansu province, China (source: <a href="http://bzdt.ch.mnr.gov.cn/browse.html?picId=%224o28b0625501ad13015501ad2bfc0273%22" target="_blank">http://bzdt.ch.mnr.gov.cn/browse.html?picId=%224o28b0625501ad13015501ad2bfc0273%22</a> (accessed on 12 January 2025)).</p>
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<p>Plant community composition at the family (<b>a</b>), genus (<b>b</b>), and species (<b>c</b>).</p>
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<p>Plant structure (<b>a</b>) and diversity (<b>b</b>) of community at different levels.</p>
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<p>Screening dominant species in shrubs.</p>
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<p>Concentrations of heavy metals in soil.</p>
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<p>Accumulation effect of <span class="html-italic">Lycium</span> and <span class="html-italic">Nitraria</span> in fruits.</p>
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<p>Transport coefficient of <span class="html-italic">Lycium</span> and <span class="html-italic">Nitraria</span> in fruits.</p>
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12 pages, 1355 KiB  
Article
Diagnosis of Peritonsillar Abscess—A Prospective Study Comparing Clinical with CT Findings in 133 Consecutive Patients
by François Voruz, Rebecca Revol, Christophe Combescure, Yan Monnier, Minerva Becker and Nicolas Dulguerov
Diagnostics 2025, 15(2), 228; https://doi.org/10.3390/diagnostics15020228 - 20 Jan 2025
Viewed by 145
Abstract
Background: Peritonsillar abscess (PTA) is relatively common but challenging to diagnose clinically. Several clinical signs may be used, with unknown performances. We evaluated and compared the diagnostic performance of individual and combined clinical signs (trismus, edema, pharynx immobility, uvula [...] Read more.
Background: Peritonsillar abscess (PTA) is relatively common but challenging to diagnose clinically. Several clinical signs may be used, with unknown performances. We evaluated and compared the diagnostic performance of individual and combined clinical signs (trismus, edema, pharynx immobility, uvula deviation, hot potato voice, and overall clinical impression) assessed by an otolaryngologist and of contrast-enhanced computed tomography (CT) to detect acute PTA. Methods: Prospective study in 133 consecutive adult patients (77 males, mean age = 33 years) with suspected clinical PTA and CT obtained in the emergency setting of a tertiary care hospital between November 2020 and October 2022. The standard of reference consisted of surgically proven pus within 24 h of CT or a favorable clinical evolution at 48 h without surgical intervention. Results: PTA was present in 117/133 (88%) patients, with no difference between mean age or sex distribution between the groups with and without PTA. None of the evaluated clinical signs were associated with PTA (OR = 1.26–5.43, p > 0.05), whereas the CT finding “abscess” was significantly associated with PTA (OR = 67.2, p < 0.0001). The sensitivity of individual clinical signs varied between 19.7% and 73.5%, and the sensitivity of CT was significantly higher for all clinical signs (95.7%, p < 0.0001) except for overall clinical impression (97.4%, p = 0.7266). The specificity of clinical signs varied between 12.5% and 93.8%, and the specificity of CT was significantly higher (75%, p < 0.05) for overall clinical impression and edema. All clinical signs together yielded an area under the curve (AUC) = 0.677. Conclusions: In adults, clinical assessment alone using independent clinical signs and overall clinical impression does not allow a reliable diagnosis of PTA, even when performed by an otolaryngologist. CT is reliable in diagnosing PTA and, whenever available, should be the examination method of choice for diagnosing PTA, especially by a non-specialist. Full article
(This article belongs to the Section Clinical Diagnosis and Prognosis)
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<p>Clinical criteria used for peritonsillar abscess. <span class="html-italic">Hot potato voice</span> may be observed while vocalizing.</p>
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<p>Radiological criteria used for peritonsillar abscess (PTA). Contrast-enhanced axial (<b>A</b>) and coronal (<b>B</b>) CT slices. Here, PTA is defined by fluid collection in the left peritonsillar space with serpiginous, irregular, and thick peripheral rim enhancement.</p>
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<p>Diagnostic performance expressed as sensitivity–specificity pairs for each individual clinical sign, <span class="html-italic">overall clinical impression</span>, and CT, respectively (<b>left</b> panel), and Receiver Operating Characteristic (ROC) curve for the number of clinical signs (<b>right</b> panel). Numbers shown on the ROC curve (<b>right</b> panel) are the thresholds: the sensitivities are the proportions of patients with peritonsillar abscess (PTA) presenting a number of signs greater or equal to the threshold, and the specificities are the proportions of patients without PTA presenting a number of signs lower than the threshold.</p>
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<p>Post-CT probability of peritonsillar abscess (PTA) as a function of pre-CT probability when the CT is positive (solid red curve) and when the CT is negative (solid blue curve). These curves show how the probability of PTA is modified by the CT result. Overall, when the CT is negative (respectively, positive), the probability decreases (respectively, increases) importantly. The dashed curves represent the 95% confidence intervals of the post-CT probability of PTA.</p>
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15 pages, 3754 KiB  
Article
The Effect of Zeolite Na-X and Clinoptilolite as Functional Fillers on the Mechanical, Thermal and Barrier Properties of Thermoplastic Polyurethane
by Nello Russo, Letizia Verdolotti, Giuseppe Cesare Lama, Federica Recupido, Barbara Liguori and Maria Oliviero
Molecules 2025, 30(2), 420; https://doi.org/10.3390/molecules30020420 - 20 Jan 2025
Viewed by 197
Abstract
To obtain sustainable food packaging materials, alternatives to traditional ones must be researched. In this work, two different kinds of zeolites, i.e., a natural one, Clinoptilolite, and a synthetic one, Zeolite Na-X, were mixed with thermoplastic polyurethane for the fabrication of composites. Composite [...] Read more.
To obtain sustainable food packaging materials, alternatives to traditional ones must be researched. In this work, two different kinds of zeolites, i.e., a natural one, Clinoptilolite, and a synthetic one, Zeolite Na-X, were mixed with thermoplastic polyurethane for the fabrication of composites. Composite films were prepared via a hot mixing stage and then by means of a hot compression molding process. Several TPU/zeolite composites were produced with a filler concentration ranging from 5% to 10%wt. Finally, the obtained films were characterized by Fourier Transform Spectroscopy (FT-IR, ATR), thermal analysis (TGA and DSC), frequency sweep test, scanning electron microscopy (SEM), mechanical tensile test and oxygen permeability test. For both fillers and at all concentrations, the inclusion of zeolites significantly influenced the analyzed properties. In the TPU/zeolite composites, an overall enhancement was observed compared to the neat polymer, attributed to improved processability, superior barrier properties and the potential to create active materials by loading zeolite combined with various chemicals for specific applications. These findings suggest that the resulting composites hold considerable promise for applications in the food packaging sector. Full article
(This article belongs to the Special Issue Zeolites and Related Materials)
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<p>ATR spectra of (<b>a</b>) TPU + Na-X and (<b>b</b>) TPU + Clinoptilolite composites.</p>
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<p>SEM images of (<b>a</b>) TPU, (<b>b</b>) Zeolite Na-X, (<b>c</b>) CLN, (<b>d</b>) TPU + 5% Na-X, (<b>e</b>) TPU + 7.5% Na-X, (<b>f</b>) TPU + 10% Na-X, (<b>g</b>) TPU + 5% CLN, (<b>h</b>) TPU + 7.5% CLN and (<b>i</b>) TPU + 10% CLN.</p>
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<p>SEM images of (<b>a</b>) TPU, (<b>b</b>) Zeolite Na-X, (<b>c</b>) CLN, (<b>d</b>) TPU + 5% Na-X, (<b>e</b>) TPU + 7.5% Na-X, (<b>f</b>) TPU + 10% Na-X, (<b>g</b>) TPU + 5% CLN, (<b>h</b>) TPU + 7.5% CLN and (<b>i</b>) TPU + 10% CLN.</p>
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<p>DSC curves for (<b>a</b>) TPU+Na-X and (<b>b</b>) TPU+CLN composites.</p>
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<p>(<b>a</b>) TGA and curves of TPU + Na-X, (<b>b</b>) TGA curves of TPU + CLN composites.</p>
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<p>Young’s modulus (<b>a</b>), Stress at break (<b>b</b>) and Elongation at break (<b>c</b>) of the TPU + Na-X and TPU + CLN at different concentrations.</p>
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<p>Complex viscosity |η*| vs. frequency at room temperature of TPU, TPU + 5% Na-X and TPU + 7.5% CLN. The trend lines have been added for each viscosity curve.</p>
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24 pages, 7291 KiB  
Article
Impact of Seasonal Atmospheric Factors and Photoperiod on Floral Biology, Plant–Pollinator Interactions, and Plant Reproduction on Turnera ulmifolia L. (Passifloraceae)
by Ujjwal Layek, Nandita Das, Arabinda Samanta and Prakash Karmakar
Biology 2025, 14(1), 100; https://doi.org/10.3390/biology14010100 - 19 Jan 2025
Viewed by 401
Abstract
Reproductive traits and plant–pollinator interactions largely depend on seasonal weather conditions, which are species-specific. Turnera ulmifolia is an ornamental plant distributed worldwide. There is little information about plant species’ reproductive ecology and environmental factors’ impact on it. Here, we aimed to examine the [...] Read more.
Reproductive traits and plant–pollinator interactions largely depend on seasonal weather conditions, which are species-specific. Turnera ulmifolia is an ornamental plant distributed worldwide. There is little information about plant species’ reproductive ecology and environmental factors’ impact on it. Here, we aimed to examine the effects of seasonal atmospheric factors (e.g., temperature, light, relative humidity, rainfall) and photoperiod on flowering, interactions with flower visitors, and the reproductive success of Turnera ulmifolia in West Bengal, India. Flowering intensity peaked in hot summers and dropped in cold winters, correlating positively with temperature and humidity. Flower opening and closing occurred earlier on hot days, while flower longevity increased in winter, showing a negative correlation with temperature and humidity. Pollen and ovule production were lower in cold weather, positively linked to temperature and humidity. The self-compatible plant was moderately dependent on pollinators and had no pollination deficit in open conditions. Visitor abundance, richness, and diversity varied season-wise, with higher values during spring–summer. Based on pollinating agents, the plant showed multiple pollination modes (e.g., melittophily, myophily, myrmecophily, and psychophily). Effective pollinators were Amegilla zonata, Borbo cinnara, Halictus acrocephalus, Nomia (Curvinomia) strigata, and Tetragonula iridipennis. The fruit set (%) did not differ significantly season-wise, but the seed set remained higher in the hot days of summer than in cold winter. Therefore, it can be concluded that atmospheric factors and photoperiod significantly impact floral traits, plant–pollinator interactions, and plant reproduction. Full article
(This article belongs to the Special Issue Pollination Biology)
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<p>Correlation matrix derived from atmospheric factors and flower traits. DL: day length, FI: flowering intensity, FL: flower longevity, LTH: light intensity, OFR: ovules per flower, PFR: pollens per flower, RH: relative humidity, TEMP: temperature.</p>
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<p>A flowering twig of <span class="html-italic">Turnera ulmifolia</span>.</p>
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<p>Flower parts. (<b>A</b>) Flower, (<b>B</b>) calyx, (<b>C</b>,<b>D</b>) sepal, (<b>E,F</b>) a part of sepal showing hairs, (<b>G</b>) part of a hair, (<b>H</b>,<b>I</b>) petal, (<b>J</b>) stamens, (<b>K</b>) a portion of stamen showing basifixed anther, (<b>L</b>) dehisced anther showing pollen grains, (<b>M</b>) carpels, (<b>N</b>) ovary, (<b>O</b>) t.s. of ovary showing placentation, (<b>P</b>) hairs of ovary surface, and (<b>Q</b>) stigmatic surface.</p>
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<p>Pollen grains of <span class="html-italic">Turnera ulmifolia</span>. (<b>A</b>,<b>B</b>) light microscopy images, (<b>A</b>) polar view, (<b>B</b>) equatorial view. (<b>C</b>–<b>F</b>) scanning electron microscopy images, (<b>C</b>) polar view, (<b>D</b>,<b>E</b>) equatorial view, (<b>F</b>) an enlarged view showing exine ornamentations.</p>
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<p>(<b>A</b>) Pollens stained with TTC, (<b>B</b>) pollens stained with IKI, (<b>C</b>) a germinated pollen, and (<b>D</b>) stigma showing receptivity.</p>
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<p>Season-wise seed set (number of seeds) per flower. Values are given in mean ± standard deviation. Different letters indicate significant differences (Dunn’s post hoc test, <span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Floral visitors of <span class="html-italic">Turnera ulmifolia</span> in West Bengal. (<b>A</b>) <span class="html-italic">Acraea terpsicore</span>, (<b>B</b>) <span class="html-italic">Apis cerana</span>, (<b>C</b>) <span class="html-italic">Apis dorsata</span>, (<b>D</b>) <span class="html-italic">Apis florea</span>, (<b>E</b>) <span class="html-italic">Armigeres subalbatus</span>, (<b>F</b>) <span class="html-italic">Aulacophora foveicollis</span>, (<b>G</b>) <span class="html-italic">Borbo cinnara</span>, (<b>H</b>) <span class="html-italic">Braunsapis mixta</span>, (<b>I</b>) <span class="html-italic">Camponotus parius</span>, (<b>J</b>) <span class="html-italic">Catochrysops panormus</span>, (<b>K</b>) <span class="html-italic">Catopsilia pumona</span>, and (<b>L</b>) <span class="html-italic">Crematogastor laestrygon</span>. Scale bars = 10 mm.</p>
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<p>Floral visitors of <span class="html-italic">Turnera ulmifolia</span> in West Bengal. (<b>A</b>) <span class="html-italic">Diacamma indicum</span>, (<b>B</b>) <span class="html-italic">Episyrphus balteatus</span>, (<b>C</b>) <span class="html-italic">Halictus acrocephalus</span>, (<b>D</b>) <span class="html-italic">Helophilus peregrinus</span>, (<b>E</b>) <span class="html-italic">Hycleus phalarantha</span>, (<b>F</b>) <span class="html-italic">Lasioglossum cavernifrons</span>, (<b>G</b>) <span class="html-italic">Myrmicaria brunnea</span>, (<b>H</b>) <span class="html-italic">Nomia</span> (<span class="html-italic">Curvinomia</span>) <span class="html-italic">strigata</span>, (<b>I</b>) <span class="html-italic">Pelopidas mathias</span>, (<b>J</b>) <span class="html-italic">Saustas gremias</span>, (<b>K</b>) <span class="html-italic">Tetragonula iridipennis</span>, and (<b>L</b>) <span class="html-italic">Thyreus nitidulus</span>. Scale bars = 10 mm.</p>
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<p>Violin plot showing the season-wise number of visits received by a flower. Different letters indicate significant differences (Dunn’s post hoc test, <span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Pollinating strategies of floral visitors. (<b>A</b>–<b>D</b>) Butterflies, legs, antennae, proboscis, and wings, respectively; (<b>E</b>) fly touching through legs and ventral side of thorax and abdomen; (<b>F</b>) mosquito touching through legs; (<b>G</b>–<b>I</b>) ants touching through legs and antennae; (<b>J</b>–<b>M</b>) honeybees touching through the ventral side of thorax and abdomen, legs, corbicular pollen loads, and wings; (<b>N</b>,<b>O</b>) <span class="html-italic">Halictus acrocephalus</span> touching through the ventral side of thorax and abdomen, legs, scopal pollen loads; (<b>P</b>–<b>R</b>) <span class="html-italic">Nomia</span> (<span class="html-italic">Curvinomia</span>) <span class="html-italic">strigata</span> touching through the ventral side of the abdomen and legs and showing pulsatory pollination; (<b>S</b>,<b>T</b>) stingless bees touching through the ventral side of thorax and abdomen, legs, and corbicular pollen loads.</p>
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18 pages, 7230 KiB  
Article
An Extensive Study of an Eco-Friendly Fireproofing Process of Lignocellulosic Miscanthus × giganteus Particles and Their Application in Flame-Retardant Panels
by Yasmina Khalaf, Rodolphe Sonnier, Nicolas Brosse and Roland El Hage
Polymers 2025, 17(2), 241; https://doi.org/10.3390/polym17020241 - 19 Jan 2025
Viewed by 461
Abstract
Increasing the flame retardancy of lignocellulosic materials such as Miscanthus × giganteus can effectively enable their wide use. This study examines the fireproofing process of Miscanthus particles using an eco-friendly process by grafting phytic acid and urea in aqueous solution. Miscanthus particles underwent [...] Read more.
Increasing the flame retardancy of lignocellulosic materials such as Miscanthus × giganteus can effectively enable their wide use. This study examines the fireproofing process of Miscanthus particles using an eco-friendly process by grafting phytic acid and urea in aqueous solution. Miscanthus particles underwent a steam explosion step before being grafted. Fireproof binderless particle panels were manufactured from miscanthus particles with or without adding olive pomace by hot-pressing. The effect of the steam explosion and/or the flame-retardant treatment on the morphology, chemical composition and thermal stability of the particles, as well as the thermal stability of the panels, was investigated. The results showed that water impregnation followed by a steam explosion at 210 °C for 8 min resulted in particles that were rich in lignin and more homogeneous in size (length and width). Fireproof particles were produced with relatively low P and N contents. The flame retardancy of the binderless particle panels was significantly improved when using miscanthus particles treated with phytic acid and urea, as shown by a reduced heat release (HRR) and an increased time-to-ignition. However, the presence of olive pomace significantly decreased the flame retardancy of the panels. Binderless particle panels prepared from grafted miscanthus particles showed the best fire properties and are considered fireproof. Full article
(This article belongs to the Section Polymer Applications)
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<p>The different steam exploded miscanthus particles obtained.</p>
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<p>The different panels produced.</p>
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<p>Box plots representing the sizes of raw M and the different M exploded particles: (<b>A</b>) length of particles (mm); (<b>B</b>) width of particles (mm).</p>
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<p>Evolution of the heat release rate (HRR) as a function of temperature for exploded miscanthus particles with and without grafting.</p>
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<p>Binderless particle panels (<b>A</b>) before the flammability test and (<b>B</b>) after the flammability test.</p>
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<p>HRR curves obtained by cone calorimeter at an irradiance of 35 kW/m<sup>2</sup> for all panels.</p>
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<p>Rate of smoke released (RSR) curves obtained by cone calorimeter at an irradiance of 35 kW/m<sup>2</sup> for all panels.</p>
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<p>Photographs of the binderless particle panels after the cone calorimeter test ((<b>A</b>): Mse; (<b>B</b>): MseOP; (<b>C</b>): Mseg; and (<b>D</b>): MsegOP).</p>
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17 pages, 5524 KiB  
Review
A Science Mapping Perspective of the Spectrum of Giant Panda Research (1929–2022)
by Zhongrong Li and Yan Wu
Sustainability 2025, 17(2), 755; https://doi.org/10.3390/su17020755 - 19 Jan 2025
Viewed by 226
Abstract
Nowadays, new data-driven science paradigms have been revolutionizing the way of acquiring knowledge and its derivatives. In addition, understanding the knowledge structure of a specific domain is valuable to the application/transformation of science in practice, especially in the era where biodiversity is given [...] Read more.
Nowadays, new data-driven science paradigms have been revolutionizing the way of acquiring knowledge and its derivatives. In addition, understanding the knowledge structure of a specific domain is valuable to the application/transformation of science in practice, especially in the era where biodiversity is given top priority. This study combines both performance analysis and science mapping to detect, quantify, and visualize the predominant themes covered by research on giant pandas and their conservation, collected from the Web of Science during the period of 1929–2022. In total, 1456 publications were analyzed with 2090 valid keywords. Twenty-four main themes were detected using co-word analysis. The most productive themes were WOLONG-NATURE-RESERVE, CLIMATE-CHANGE, CARNIVORA, NATURE-RESERVE, and ECOSYSTEM-SERVICES, according to the number of published documents, and the most impacting ones were WOLONG-NATURE-RESERVE, CARNIVORA, CLIMATE-CHANGE, ECOSYSTEM-SERVICES, DNA, and BACTERIA according to the citations, whereas the h-index indicates that the top six themes were: WOLONG-NATURE-RESERVE, CARNIVORA, CLIMATE-CHANGE, ECOSYSTEM-SERVICES, NATURE-RESERVE, and AILURUS-FULGENS. As a result, this indicates worthwhile prospects for the future study of giant panda conservation, which will focus more on the following hot themes: GUT-MICROBIOTA, ECOSYSTEM-SERVICES, HABITAT, and CLIMATE-CHANGE. Meanwhile, WOLONG still takes center stage in giant panda research. Therefore, by building a more comprehensive conceptual structure of giant panda research, this study contributes to current and future developments in this field. Full article
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<p>Flow diagram representing the document selection steps using the PRISMA framework.</p>
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<p>The number of publications per year and total received citations of these publications. The red line in the chart illustrates the total citations that change over the years, as indicated by red dots.</p>
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<p>Strategic diagram based on the number of documents (<b>a</b>) and total citations (<b>b</b>).</p>
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<p>Thematic network for the theme WOLONG-NATURE-RESERVE (<b>a</b>), CLIMATE-CHANGE (<b>b</b>), BACTERIA (<b>c</b>), DNA (<b>d</b>), CARNIVORA (<b>e</b>), ECOSYSTEM-SERVICES (<b>f</b>), NATURE-RESERVE (<b>g</b>), and CRYPTOSPORIDIUM (<b>h</b>), respectively.</p>
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<p>Overlay visualization of a keyword co-occurrence of giant panda publications from 1929 to 2022 using VOSviewer (v1.6.20). The size of nodes is determined by the number of publications. The color bar indicates the average publication year of the documents in which the keywords occur, ranging from blue (older) to green to yellow (recent).</p>
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<p>The influence zone of the giant panda research in 2021 and 2022, as indicated by the shaded part.</p>
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18 pages, 15689 KiB  
Article
Using a Combined FE-CA Approach to Investigate Abnormally Large Grains Formed by the Limited Recrystallization Mechanism in a Powder Metallurgy Nickel-Based Superalloy
by Yanhui Yang, Boyan Zhang, Xiuquan Chen, Xiaoxuan Wang, Yankai Feng, Lidong Su, Zhengfei Liang and Yifan Liu
Crystals 2025, 15(1), 91; https://doi.org/10.3390/cryst15010091 (registering DOI) - 19 Jan 2025
Viewed by 158
Abstract
Powder nickel-based superalloy is the key material for hot-end components such as turbine disks and gas engine disks in aeroengines, and its microstructure uniformity has an important influence on the disks’ service performance. However, thermomechanical treatments make it easy to produce abnormally large [...] Read more.
Powder nickel-based superalloy is the key material for hot-end components such as turbine disks and gas engine disks in aeroengines, and its microstructure uniformity has an important influence on the disks’ service performance. However, thermomechanical treatments make it easy to produce abnormally large grains (ALGs) in powder superalloy disks. In order to investigate the relationship between the hot deformation conditions and ALGs of powder superalloys, isothermal compression experiments under various deformation conditions were carried out and a FE-CA method was constructed to investigate the ALGs formed by the limited recrystallization mechanism. The results indicate a close relationship between the ALGs formed after the supersolvus treatment of this alloy and the equivalent stress after thermal deformation, and the local dissolution of the γ′ phase in supersolvus heat treatment does not produce ALGs. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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<p>The microstructure of the P/M nickel-based superalloy bar at the edge position. (<b>a</b>) The SEM images of the primary and secondary γ′; (<b>b</b>) the IPF map of the alloy grain.</p>
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<p>The schematic diagram of the sampling location for hot compression specimens and the subsequent experimental processes.</p>
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<p>The microstructure at <span class="html-italic">P</span><sub>1</sub> after holding the alloy at 1150 °C for 2 h following separate hot deformation at 1020 °C. The reduction amounts of (<b>a<sub>i</sub></b>–<b>c<sub>i</sub></b>) (i = 1, 2, 3) are 10%, 30%, and 60%, respectively; the reduction rates corresponding to (<b>a<sub>1</sub></b>–<b>a<sub>4</sub></b>) are 0.001 s<sup>−1</sup>, 0.01 s<sup>−1</sup>, 0.1 s<sup>−1</sup>, and 1 s<sup>−1</sup>, respectively; and the meanings of (<b>b<sub>1</sub></b>–<b>b<sub>4</sub></b>,<b>c<sub>1</sub></b>–<b>c<sub>4</sub></b>) are the same as those of (<b>a<sub>1</sub></b>–<b>a<sub>4</sub></b>).</p>
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<p>The microstructure at <span class="html-italic">P</span><sub>1</sub> after holding the alloy at 1150 °C for 2 h following separate hot deformation at 1090 °C. The reduction amounts of (<b>a<sub>i</sub></b>–<b>c<sub>i</sub></b>) (i = 1, 2, 3) are 10%, 30%, and 60%, respectively; the reduction rates corresponding to (<b>a<sub>1</sub></b>–<b>a<sub>4</sub></b>) are 0.001 s<sup>−1</sup>, 0.01 s<sup>−1</sup>, 0.1 s<sup>−1</sup>, and 1 s<sup>−1</sup>, respectively; and the meanings of (<b>b<sub>1</sub></b>–<b>b<sub>4</sub></b>) and (<b>c<sub>1</sub></b>–<b>c<sub>4</sub></b>) are the same as those of (<b>a<sub>1</sub></b>–<b>a<sub>4</sub></b>).</p>
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<p>The microstructure photos and corresponding grain size distributions of the alloy after hot deformation and over-solution treatment. Hot deformation conditions: (<b>a</b>) 1020 °C, reduction 30%, reduction rate 0.005 s<sup>−1</sup>; (<b>b</b>) 1070 °C, reduction 10%, reduction rate 0.1 s<sup>−1</sup>; (<b>c</b>) 1090 °C, reduction 30%, reduction rate 0.005 s<sup>−1</sup>; (<b>d</b>) 1070 °C, reduction 30%, reduction rate 0.3 s<sup>−1</sup>. The grain size distributions of (<b>a</b>–<b>d</b>) correspond to (<b>e</b>–<b>h</b>).</p>
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<p>The displacement–load curve and final dimensions of the specimen obtained by simulation and test under thermal deformation conditions of 1020 °C, a reduction rate of 0.1 s<sup>−1</sup>, and a reduction 60%.</p>
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<p>The distribution nephograms of strain, strain rate, and stress after a deformation temperature of 1020 °C, reduction rate of 1 s<sup>−1</sup> and reduction of 10%, and microstructure photographs after over-solution treatment. (<b>a</b>–<b>c</b>) Nephograms of equivalent stress, equivalent strain, and equivalent strain rate distribution in the shaded area in (<b>d</b>) after thermal deformation, respectively; (<b>e</b>) is the microstructure of the shaded area in (<b>d</b>) after solution treatment; and (<b>f</b>) is the enlarged area of abnormally large grain microstructure in (<b>e</b>).</p>
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<p>The distribution nephograms of strain, strain rate, and stress after a deformation temperature of 1070 °C, reduction rate of 0.3 s<sup>−1</sup> and reduction of 30%, and microstructure photographs after over-solution treatment. (<b>a</b>–<b>c</b>) Nephograms of equivalent stress, equivalent strain, and equivalent strain rate distribution in the shaded area in (<b>d</b>) after thermal deformation, respectively; (<b>e</b>) is the microstructure of the shaded area in (<b>d</b>) after solution treatment; and (<b>f</b>) is the enlarged area of abnormally large grain microstructure in (<b>e</b>).</p>
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<p>Microstructure of ALGs after over-solution treatment under different heat deformation conditions. (<b>a</b>) #1020-0.5-30; (<b>b</b>) #1020-1-10.</p>
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<p>The CA simulation results of grain growth accompanied by the dissolution of the γ′ phase in supersolvus heat treatment. (<b>a<sub>1</sub></b>–<b>a<sub>4</sub></b>) The CA simulation results of the grain growth accompanied by the local dissolution of the γ′ phase. (<b>b<sub>1</sub></b>–<b>b<sub>4</sub></b>) The CA simulation results of the grain growth accompanied by the complete dissolution of the γ′ phase.</p>
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<p>LM and twin boundary maps for hot-deformed microstructures (#1020-0.5-30) corresponding to ALGs zone before and after over-solution treatment. (<b>a</b>) LM maps before over-solution treatment; (<b>b</b>) LM maps after over-solution treatment; (<b>c</b>) inverse pole figure after over-solution treatment; (<b>d</b>) twin boundary maps after over-solution treatment.</p>
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<p>LM and twin boundary maps for hot-deformed microstructures (#1020-1-10) corresponding to ALGs zone before and after over-solution treatment. (<b>a</b>) LM maps before over-solution treatment; (<b>b</b>) LM maps after over-solution treatment; (<b>c</b>) inverse pole figure after over-solution treatment.</p>
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<p>Stress–strain curve, cross section microstructure, and von Mises equivalent stress distribution diagram of specimen under thermal deformation conditions #1020-1-10. (<b>a</b>) The stress–strain curve. (<b>b</b>) Cross section microstructure and von Mises equivalent stress distribution diagram.</p>
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<p>The CA simulation and experimental results of the formation process of ALGs in the over-solution treatment process of zone A. (<b>a</b>–<b>c</b>) The CA simulation results from the initial, middle, and end of the over-solution treatment, respectively. (<b>d</b>) The microstructure of region A after over-solution treatment.</p>
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<p>The CA simulation and experimental results of the formation process of ALGs in the over-solution treatment process of zone B. (<b>a</b>–<b>c</b>) The CA simulation results from the initial, middle, and end of the over-solution treatment, respectively. (<b>d</b>) The microstructure of region B after over-solution treatment.</p>
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<p>TEM images of region A before and after over-solution treatment under thermal deformation conditions #1020-1-10. (<b>a</b>) Before over-solution treatment; (<b>b</b>) after over-solution treatment.</p>
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19 pages, 31635 KiB  
Article
Reflectance and Thermal Micrometeorological Characteristics of an Urban Green Space in the Mediterranean During July’s 2023 Heatwave
by Nikolaos D. Proutsos, Alexandra D. Solomou, Stefanos P. Stefanidis and Ioannis X. Tsiros
Land 2025, 14(1), 194; https://doi.org/10.3390/land14010194 - 18 Jan 2025
Viewed by 393
Abstract
The thermal and optical behavior of different elements in the urban environment is critical for urban climate regulation and planning. This study investigates the micrometeorological conditions prevailing in an urban green space (UGS) in Greece, during the heatwave of July 2023, addressing the [...] Read more.
The thermal and optical behavior of different elements in the urban environment is critical for urban climate regulation and planning. This study investigates the micrometeorological conditions prevailing in an urban green space (UGS) in Greece, during the heatwave of July 2023, addressing the effects of various surface materials on thermal dynamics and the urban heat island (UHI) phenomenon. The research is based on ground surface temperature and albedo measurements on different materials in the UGS, in the morning and at noon, showing great temperature differences between the different types of materials. The findings highlight the complex interaction between high-albedo surfaces and surface temperature values, suggesting that the proper selection of materials can highly affect the optical and thermal behavior of the urban environment. Artificial materials absorb more heat compared to natural vegetation, leading to high surface temperature values, reaching at noon, for example, 58.9 °C for asphalt. For the natural surfaces, dry bare soil presents similar thermal behavior (64.1 °C at noon), while green surfaces had much lower temperatures (e.g., 38.3 °C for grass). Thermal comfort indices revealed that July 2023 experienced extensive “very hot” conditions, imposing the urgent need for strategic urban planning to mitigate heat impacts. The study highlights that in order to create climate-resilient environments and improve thermal comfort, it is crucial to include suitable materials and a variety of vegetation in urban design. Such insights into the complex nature of urban microclimate indicates also the issue of the careful selection of materials and plant species in urban greening initiatives to help cities face the UHI phenomenon. Full article
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Figure 1

Figure 1
<p>General map of the urban green area in the study site of Amaroussion, depicting also the meteorological station installed in the area and the different types of materials occupying the area.</p>
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<p>Diurnal distribution of (<b>a</b>) the annual hours of 2023 and (<b>b</b>) the monthly hours of July 2023 per thermal comfort categories according to the PET values in the site of Amaroussion.</p>
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<p>Hourly averages of (<b>a</b>) air temperature, (<b>b</b>) relative humidity, (<b>c</b>) wind speed, and (<b>d</b>) soil temperature during the campaign day (26 July 2023) at the urban green site of Amaroussion. The data are presented in conjunction with the July averages of the year 2023 and of the respective average of the period 2020–2023.</p>
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<p>Albedo (reflectance) values of the urban green space in Amaroussion at noon (13:00–15:00 local time).</p>
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<p>Surface temperatures (Tc) in the urban green space of Amaroussion in morning (08:30–10:30 local time) and noon (13:00–15:00 local time).</p>
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<p>Differences between surface (Tc) and air (Tair) temperatures in the urban green space of Amaroussion in morning (08:30–10:30 local time) and noon (13:00–15:00 local time).</p>
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<p>Optical and thermal photographs of the site in the morning and at noon depicting the temperature ranges of the asphalt and the paved and green surfaces of the urban green space in Amaroussion during the 26 July 2023 heatwave. Blue and red cycles indicate the minimum and maximum temperatures, whereas white cycles show the temperature at the center of the photograph.</p>
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<p>Optical and thermal photographs of the site at noon depicting the temperature ranges of the old concrete and dry soil, a human, green trees, and green surfaces of the urban green space in Amaroussion during the 26 July 2023 heatwave. Blue and red cycles indicate the minimum and maximum temperatures, whereas white cycles show the temperature at the center of the photograph.</p>
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<p>Optical and thermal photographs of the site in the morning and at noon depicting the temperature ranges of the old concrete and dry soil and green surfaces of the urban green space in Amaroussion during the 26 July 2023 heatwave. Blue and red cycles indicate the minimum and maximum temperatures, whereas white cycles show the temperature at the center of the photograph.</p>
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<p>Optical and thermal photographs of the site at noon depicting the temperature ranges of the internal paved corridors and green surfaces of the urban green space in Amaroussion during the 26 July 2023 heatwave. Blue and red cycles indicate the minimum and maximum temperatures, whereas white cycles show the temperature at the center of the photograph.</p>
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