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Electronic and photonic technologies have revolutionised our world and fortified many areas of our modern life. Fundamental and applied research spanning from atoms to devices leading to new technology development, including quantum, atomic, spintronic, optics, nuclear, plasma, superconductors, and low-dimensional materials based devices, is crucial to ensure continuous solutions to existing and future global challenges.
The authors propose an expected-actual perception-action loop in soft robots to rapidly and robustly detect contact and distinguish deformation sources. Soft robots enable intelligence to explore and learn through interacting with their surroundings.
Programmable deformation and biomimetic behaviors are achieved by thin-walled soft machines with complex 3D structures and precise magnetization profiles fabricated by spatial uniform magnetic field-assisted stereolithography.
The use of harmful solvents to fabricate stable devices hampers the commercialization of perovskite solar cells. Here, the authors introduce a biorenewable solvent system and precursor-phase engineering to realize stable formamidinium lead triiodide-based solar cells.
Pure CuInSe2 solar cells suffer from strong interfacial carrier recombination. Here, the authors introduce a wide U-shaped double Ga grading with a minimum bandgap of 1.01 eV and achieve certified device efficiency of 20.26%, making it highly suitable for tandem solar cell applications.
Developing electronic skins for sensing the spatial location of objects beyond two-dimensional space is difficult. The authors present a flexible, lightweight, and transparent electronic skin for non-contact accurate 3D motion sensing. This achieves micron-level precision, reducing complexity and power consumption.
The authors present a core–shell fiber moisture-driven electric generator by a synergetic complex coacervation and built-in potential strategy, enabling self-powered human interactive sensors and synaptic devices.
Zhang et al. report a bulky Schottky junction constructed by interpenetrated macroporous-carbon electrode for hole extraction and perovskite network for electron trapping under X-ray irradiation. The efficient extraction of carriers enables a dry battery-powered portable X-ray radiation alarm.
The authors report a nanophotonic architecture consisting of a large-area hexagonal array of triskelia motifs, transferring its chirality to non-chiral materials placed atop and sustaining chiroptical resonances along the entire visible spectrum with luminescence dissymmetry factor up to 1 achieved.
Zhang et al. report non-destructive halide exchange by employing butylammonium halide incorporated post-treatment to achieve perovskite with low trap density and tuneable bandgap for blue LEDs, with external quantum efficiencies of 23.6%, 20.9%, and 15.5% for emission peaks at 488, 478, and 468 nm, respectively.
This work reports a heterogeneous two transistor capacitorless eDRAM combining Si and MoS2 to solve the short data retention problem while preserving a high sense margin. The retention and sense margin show improvements of 1000 and 100 times respectively compared to full Si and MoS2 counterparts.
High voltages/light intensities are typically needed to mimic human visual adaptability. Here, the authors present an image sensor array with low operation voltage that mimics synaptic functions with ultraweak light stimulation and performs image processing tasks accurately.
The authors report a stretchable tactile array with strain insensitivity, and a visual-tactile joint learning framework, achieving high-accuracy force measurement and replicating full states of hand and manipulated objects with fine-grained geometry.
The efficiency of deep-ultraviolet light sources is critical for applications like disinfection. Here, the authors employ a novel decoupling strategy using GaN templates to fabricate 280 nm vertical injection diodes, achieving a light output power of 65.2 mW at 200 mA.
Exceptional points can be realized via engineering gain and loss or unidirectional coupling, as demonstrated in optical platforms. Here, the authors report an EP in unidirectionally coupled LC circuits and demonstrate a square-root scaling of frequency splitting with perturbation.
The use of augmented reality as an in-person collaborative platform could unlock human-centric and service-related experiences. Here a dual-sided transparent display is prototyped, with a transparency of 65%, to display unique images on either side.
The understanding of the origins of device degradation of perovskite solar cells remains limited. Here, the authors establish hysteresis as a diagnostic key to unveil and remedy degradation issues and investigate the relations between characteristic J-V hysteresis features and device deficiencies.
Controlling crystal growth alignment in wide bandgap low-dimensional perovskites has been a persistent challenge. Here, authors induce vertical crystal growth through the addition of chlorine to precursor solution, giving rise to a record power conversion efficiency of 9.4% for 2 eV bandgap devices.
The management of charge carrier recombination and transport in heterojunction back contact solar cells poses significant challenges in achieving a high efficiency. Here, authors analyze various loss mechanisms of devices fabricated by laser patterning, and achieve a certified efficiency of 27.09%.
Wood-based electronics are typically constrained in their ability to undergo complex shape deformation. Here, authors integrate transparent wood film and cellulose-based conductive ink for flexible electronic origami devices that have been demonstrated as a proof-of-concept for human motion sensors.
nip-Type tin-based perovskite solar cells have underperformed largely due to the metal oxide electron transport layers originally designed for lead-based devices. Here, authors employ metal chalcogenide as the electron transport layer, achieving enhanced efficiency up to 11.78% for stable devices.
The interconversion dynamics between charge transfer state charges and separated charges remains an unresolved issue. Here, the authors spectrally resolve those charges and report a kinetic model to reveal the charge generation, separation, and recombination mechanism in α6T:C60 systems.
The energy disorders in the lateral direction of the junction in large-area photovoltaic modules are largely overlooked. Here, authors employ organic amidinium passivators to suppress the micro-inhomogeneity in the lateral energy landscapes and achieve high performance stable perovskite solar cells.
By using metal-organic compounds as solid precursor photoresist for multi-photon lithography and post-sintering, Cao et al. report ultra-high precision nano additive manufacturing of 2D and 3D metal oxide semiconductors with dimension down to 35 nm.
Lee et al. report blue fin-LEDs with improved brightness and light extraction efficiency comparing to nanorod-LEDs by using a face-selective dielectrophoretic assembly technology. The wafer utilization ratio exceeds 90%, with a vertical assembly ratio of 91.3% and pixel production yield of 99.93%.
Lin et al. report a nanoscale organic-inorganic covalent-ionic hybrid network leveraging the reorganising interaction between siloxanes and fluoride ions, enabling a single layer coating with excellent optical, antistatic, anti-smudge, anti-scratch, and mechanical properties for touch displays.
Guan et al. report a strategy of moisture-triggered selective hydrolysis of Sn4+ into Sn(OH)4, eliminating Sn4 + -induced defects in tin-based perovskites and enhancing the electron injection in NIR-II LED devices with peak emission of 945 nm and external quantum efficiency of 7.6%.
Traditional silicon vision chips often challenge in emulating complex biological behaviors. This work reports birdlike broadband neuromorphic visual sensor arrays with 5 bits of in-memory sensing and computing. The built reservoir computing system achieves motion and UV grayscale information extraction, leading to fusion visual imaging.
Current specialized function gradient computing hardware is not scalable to common higher-order functions. This work reports an approach for massively parallel gradient calculations of high-degree polynomials. Solving a Boolean satisfiability problem was experimentally implemented on an in-memory computing circuit.
Hardware implementation of analog reservoir computing is a challenge. The analog reservoir system in this work contains mixed phase boundary-based transistors with nonlinear short-term memory as physical reservoirs and artificial neuron, and nonvolatile ferroelectric transistors as readout networks.
The authors introduce the concepts of Robo-Matter and Robot-Matter duality, using magnetic spinner micro-robots. A wide range of functionalities and applications beyond the capability of both traditional inert and active materials is enabled.
Fullerene derivatives tend to increase charge recombination losses and charge accumulation at the interface in inverted perovskite solar cells. Here, authors introduce tetramethylthiuram disulfide to induce formation of sulfur radicals for n-doping, achieving efficiency of 26.1% in stable devices.
The high non-radiative energy loss is a bottleneck issue for efficient organic solar cells. Here, the authors regulate the charge transfer state disorder and rate of back charge transfer through a ternary system, achieving low non-radiative energy loss of 0.183 eV and device efficiency of 20.25%.
Wide-bandgap perovskite solar cells suffer from severe open-circuit voltage loss with increasing bromine content. Here, authors tackle this issue through homogeneous halogen-phase distribution realized by bottom-up templated crystallization and demonstrate tandem devices with efficiency of 28.08%.
Exact analytic calculation shows that optimal control protocols for passive molecular systems often involve rapid variations and discontinuities. However, similar analytic baselines are not generally available for active-matter systems, because it is more difficult to treat active systems exactly. Here, the authors use machine learning to derive efficient control protocols for active-matter systems, and find that they are characterized by sharp features similar to those seen in passive systems.
Motility coupled with responsive behavior is essential for microorganisms to establish suitable habitats, with simple responses like reversing motion enabling them to form stable aggregates. Kurjahn et al. show that filamentous cyanobacteria use light gradients and boundary curvature of light stimuli to form ordered, entangled aggregates, revealing how these dynamics could influence adaptive colony architectures.
Yang et al. report in-situ growth of ZnS(Ag)-CsPbBr3 heterostructures through all solid-phase synthesis for X-ray scintillators. The multiple contact sites promote light yield via efficient energy transfer from ZnS(Ag) into CsPbBr3 and enable fast decay for high-speed X-ray imaging at 200 fps.
Xu et al. report reconfigurable phototransistors based on MAPbI3/Bi2O2Se heterostructure, with momentum conservation promotes hot carrier extraction and interlayer carrier transport. Heterotransistor array enables traffic light signal detection under dim light, assisted by YOLOv4 neural network.
Yuan et al. report a nearly vertical subthreshold swing field-effect transistor consists of a graphene/silicon heterojunction drain and a silicon channel. The device enables nearly hysteresis-free transistors with subthreshold swing of 16 µV dec−1, and a complementary logic inverter with gain of 311.
Physical reservoir computing allows real-time low power information processing. Here, the authors report reservoir computing with magnetic skyrmions able to detect millisecond time-scale hand gestures, matching software neural networks’ performance.
The authors propose an organic thermoelectric device having a new power generation mechanism based on an organic charge transfer interface with carrier transport layers, extracting small-scale thermal energy, i.e., a few tens of millielectronvolts, at room temperature without a temperature gradient.
Achieving highly efficient and stable white organic light-emitting diodes remains challenging. Here, the authors report a strategy to harmonize singlet exciton radiation and triplet exciton up-conversion, attaining power and external quantum efficiency of 190 lm/W and 39% with an extended lifetime.
Flexible organic photovoltaics and energy storage systems have profound implications for future wearable electronics. Here, the authors discuss the transformative potential and challenges associated with the integrative design of these systems for energy harvesting.
Su et al. report a single photon counting technique to trace the electron transport paths at different voltages for QLEDs, revealing the leakage electrons into the hole transport layer or recombination at the interface, providing unambiguous understanding in the device operation and degradation mechanism.
Future bioinspired locomotion systems need design’s agility and adaptiveness. Here, the authors report a musculoskeletal leg design which leverages multi-layered electrohydraulic actuators to achieve highly energy-efficient and versatile motion.
Microbot collectives can cooperate to accomplish complex tasks that are difficult for a single individual. Here, the authors report magnetic and light-driven ant microbot collectives that are capable of reconfiguring multiple assembled architectures.
The realization of intrinsically stretchable fully π-conjugated polymer film is challenging due to their inherent brittle nature. Here, authors apply semiconductor fluid molecular plasticizers to improve stretchable deformability, achieving high performance flexible polymer light-emitting diodes.
Self-assembled monolayers are essential for achieving high performance solar cells by minimizing interfacial energy losses. Here, authors the develop a co-adsorb strategy with a small molecule to provide a favorable heterointerface, realizing high efficiency in p-i-n perovskite and organic devices.
Conventional stretchable optoelectronics suffer from sacrificed area ratio of active components to enhance maximum strain. Here, the authors develop a 3D buckled height-alternant architecture, allowing high initial active-area ratio and maximum system strain in displays with reliable performances.
The migration and hygroscopicity of lithium salt in doped spiro-OMeTAD hampers the device efficiency of perovskite solar cells. Here, the authors employ Eu(TFSI)2 salts to generate superoxide radical for facile pre-oxidation, achieving enhanced efficiency and stability of solar cells and modules.
The lead halide octahedron framework is mainly stabilized via optimization of bonding characteristics and dimensionality. Here, the authors employ bidentate ligands to in-situ form lead iodide chelates layer for surface passivation, achieving device efficiency over 25% in perovskite solar cells.
Integrating chemical-electric behaviors into optoelectronic synapses holds promise for several applications. Here, the authors report a photoelectrochemical synapse with dual-modal plasticity and chemically-regulated neuromorphic functions.
Water and ion ingress are challenging to quantify, especially in miniaturized microsystems. Here, Mariello et al. report a wireless and battery-free flexible water-permeation sensing platform, using backscatter communication and Mg-based microsensors for in-situ monitoring of implantable bioelectronics.
Flexible skins are desired for wind pressure measurement on curved surfaces. Here, the authors report a flexible skin using two iontronic pressure sensors for negative pressure and positive pressure sensing, respectively, and demonstrate its application to pressure measurements in room temperature wind tunnels.
Electrotactile systems can have inconsistent tactile results due to variations in pressure between the device and finger. Here, the authors report a transparent electrotactile device with pressure-sensitive transistors, enabling consistent electrotactility while interference stimulation maximizes the performance.
Existing patterning methods for thin metal films rely on prefabricated rigid masks incompatible with soft substrates. Here, the authors report printable and stretchable metal-vapor-desorption layers that facilitate high-fidelity patterning, enabling circuits and devices on 3D curvilinear and stretchable substrates.
Computer haptics addresses tactile sensation and haptic rendering particularly for the Metaverse. Here, the authors report a design and implantation of a tactile scanner, to collect data used to render haptic feedback and recreate a feeling of touch.
Developing flexible coils for soft robotic applications is challenging due to their sparse structure. Here, the authors present a design of transformable 3D curved high-density liquid metal coils, surpassing the structural density level of enameled wire for soft actuation, sensing, and communication.