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WO2024174315A1 - Thermopile infrared detector and preparation method therefor, and ndir detection system - Google Patents

Thermopile infrared detector and preparation method therefor, and ndir detection system Download PDF

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Publication number
WO2024174315A1
WO2024174315A1 PCT/CN2023/082760 CN2023082760W WO2024174315A1 WO 2024174315 A1 WO2024174315 A1 WO 2024174315A1 CN 2023082760 W CN2023082760 W CN 2023082760W WO 2024174315 A1 WO2024174315 A1 WO 2024174315A1
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WO
WIPO (PCT)
Prior art keywords
thermopile
infrared detector
sensor chip
thermopile infrared
temperature control
Prior art date
Application number
PCT/CN2023/082760
Other languages
French (fr)
Chinese (zh)
Inventor
徐德辉
Original Assignee
上海烨映微电子科技股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 上海烨映微电子科技股份有限公司 filed Critical 上海烨映微电子科技股份有限公司
Publication of WO2024174315A1 publication Critical patent/WO2024174315A1/en

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01Arrangements or apparatus for facilitating the optical investigation
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D23/00Control of temperature
    • G05D23/19Control of temperature characterised by the use of electric means
    • G05D23/20Control of temperature characterised by the use of electric means with sensing elements having variation of electric or magnetic properties with change of temperature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the invention relates to the field of detectors, and in particular to a thermopile infrared detector and a preparation method thereof, and an NDIR detection system.
  • Non-Dispersive InfraRed (NDIR) detection system is a commonly used gas detection method. It is mainly used to measure compounds, such as CH 4 , CO 2 , N 2 O, CO, SO 2 , NH 3 , ethanol, benzene, etc., as well as most organic substances (Hydrocarbon, HC), including volatile organic compounds (Volatile Organic Compounds, VOC).
  • the NDIR detection system is an optical gas sensor composed of an infrared light source (IR source), an optical path (Optics Cell), a thermopile infrared detector (Thermopile IR Detector) (as shown in Figure 1), an electronic circuit (Electronics) and a software algorithm (Algorithm).
  • IR source infrared light source
  • Optics Cell optical path
  • thermopile infrared detector Thermopile IR Detector
  • Electronics Electronics
  • Algorithm software algorithm
  • the entire NDIR detection system is a sealed optical path structure
  • the heat generated by the infrared light source will accumulate in the sealed structure, thereby causing the ambient temperature of the entire NDIR detection system to rise.
  • the greater the power of the infrared light source the greater the temperature rise of the NDIR detection system.
  • the existing technology generally adjusts the infrared light source to shorten the working time of the infrared light source, thereby reducing the power consumption of the NDIR detection system.
  • the infrared light source of the NDIR detection system is constantly turned on and off during operation. Turning on the infrared light source will cause the ambient temperature of the NDIR detection system to rise, while turning off the infrared light source will cause the ambient temperature of the NDIR detection system to drop. Therefore, during the operation of the NDIR detection system, the ambient temperature of the thermopile infrared detector is also constantly changing, which in turn affects the output voltage of the thermopile infrared detector.
  • thermopile infrared sensor will increase rapidly, reducing the resolution of the thermopile infrared detector's response to infrared light, thereby reducing the gas detection accuracy of the NDIR detection system.
  • changes in the external ambient temperature of the NDIR detection system will also cause changes in the response of the thermopile infrared detector, resulting in the characteristics of the NDIR detection system being related to the external ambient temperature, and unable to guarantee stable gas detection accuracy.
  • thermopile infrared detector and a preparation method thereof and an NDIR detection system it is necessary to provide a thermopile infrared detector and a preparation method thereof and an NDIR detection system to solve the problems of the constant change of ambient temperature and detection accuracy of the thermopile infrared detector in the prior art.
  • the object of the present invention is to provide a thermopile infrared detector and a preparation method thereof and an NDIR detection system to solve the problems of the thermopile infrared detector in the prior art such as the constantly changing ambient temperature and the detection accuracy.
  • thermopile infrared detector comprising:
  • a base located below the shell and forming a sealed cavity with the shell;
  • thermopile infrared detector located above the substrate in the cavity, for controlling the temperature of the thermopile infrared detector to keep it in a constant temperature state;
  • An ambient temperature sensor chip located above the TEC temperature control chip in the cavity, for monitoring the temperature of the thermopile infrared detector;
  • thermopile sensor chip is located above the TEC temperature control chip in the cavity and is spaced apart from the ambient temperature sensor chip, and is used to detect the gas to be tested;
  • the infrared filter is located on the top surface of the housing and corresponds to the thermopile sensor chip in a vertical position with a spacing therebetween.
  • the number of the thermopile sensor chips ranges from 1 to 4.
  • the number of the infrared filters is the same as the number of the thermopile sensor chips.
  • the substrate includes a TO metal tube seat and a packaging substrate.
  • the shell is a TO metal tube cap.
  • the shell when the base is a packaging substrate, the shell includes a packaging side wall and a packaging top plate.
  • thermopile infrared detector further includes pins electrically connected to each chip.
  • the present invention also provides a method for preparing a thermopile infrared detector, the method for preparing the thermopile infrared detector comprising:
  • S1 Provide substrate, TEC temperature control chip, thermopile sensor chip, ambient temperature sensor chip, infrared filter and housing;
  • thermopile sensor chip and the ambient temperature sensor chip are spaced apart from each other;
  • thermopile infrared detector mounting the infrared filter on the top surface of the shell, and packaging the shell and the substrate to obtain a complete thermopile infrared detector.
  • the method for preparing the thermopile infrared detector further includes: providing pins, and electrically connecting the pins respectively after wire bonding in step S4.
  • the present invention also provides a NDIR detection system, the NDIR detection system comprising:
  • thermopile infrared detectors any one of the thermopile infrared detectors described above;
  • the infrared light source and the thermopile infrared detector are respectively located on opposite sides of the gas chamber and have a distance therebetween, and the distance is the optical path through which the infrared light emitted by the infrared light source passes; the gas chamber is used to place the gas to be measured;
  • thermopile infrared detector are connected to the circuit respectively.
  • thermopile infrared detector and its preparation method and NDIR detection system of the present invention have the following beneficial effects:
  • thermopile infrared detector of the present invention places the TEC temperature control chip below the thermopile infrared sensor chip and the ambient temperature sensor chip.
  • the TEC temperature control chip can be used to control the temperature, so that the ambient temperature of the thermopile sensor chip is always controlled at a constant temperature, so that the thermopile infrared sensor chip is not affected by the thermal shock when the external light source is turned on, so that the reference output of the thermopile infrared sensor is maintained at a constant value, the resolution of the thermopile infrared sensor is improved, and then the resolution of the gas to be tested is improved;
  • the thermopile infrared detector of the present invention does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock because it integrates the TEC temperature control chip, and the freedom of substrate and shape design is greater, which can not only be more miniaturized, but also reduce the packaging cost; the size of the thermopile infrared detector of the present invention can be consistent with
  • FIG. 1 is a schematic diagram showing the structure of a conventional thermopile infrared detector.
  • FIG. 2 is a schematic diagram showing the structure of a thermopile infrared detector according to a first embodiment of the present invention.
  • FIG. 3 is a schematic structural diagram of a second embodiment of a thermopile infrared detector according to the present invention.
  • FIG. 4 is a schematic structural diagram of a third embodiment of the thermopile infrared detector of the present invention.
  • FIG. 5 is a schematic flow chart showing a method for preparing a thermopile infrared detector according to the present invention.
  • FIG. 6 is a schematic diagram showing the structure of the NDIR detection system of the present invention.
  • thermopile sensor chip 10
  • infrared filter 10
  • wire bonding 20
  • pins 20
  • infrared light source 100
  • gas chamber 110
  • optical path 120
  • gas to be tested 130
  • thermopile infrared detector 100
  • spatial relational terms such as “under”, “below”, “below”, “below”, “above”, “on”, etc. may be used herein to describe the relationship of one structure or feature shown in the drawings to other structures or features. It will be understood that these spatial relational terms are intended to include other directions of the device in use or operation in addition to the directions depicted in the drawings.
  • a layer when referred to as being “between” two layers, it can be the only layer between the two layers, or there may be one or more intervening layers.
  • “between" means including the end point values.
  • a structure in which a first feature is described as being "above" a second feature may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features are formed between the first and second features, such that the first and second features may not be in direct contact.
  • thermopile infrared detector 130 As shown in FIG. 2 , this embodiment provides a thermopile infrared detector 130 , and the thermopile infrared detector 130 includes:
  • the base 20 is located below the housing 10 and forms a sealed cavity with the housing 10;
  • a semiconductor refrigerator (TEC) temperature control chip 30 is located above the substrate 20 in the cavity and is used to control the temperature of the thermopile infrared detector 130 to keep it in a constant temperature state;
  • An ambient temperature sensor chip 40 located above the TEC temperature control chip 30 in the cavity, for monitoring the temperature of the thermopile infrared detector 130 ;
  • thermopile sensor chip 50 is located above the TEC temperature control chip 30 in the cavity and is spaced apart from the ambient temperature sensor chip 40 , and is used to detect the gas to be tested;
  • the infrared filter 60 is located on the top surface of the housing 10 , vertically corresponding to the thermopile sensor chip 50 , and has a spacing therebetween.
  • thermopile infrared detector 130 of the present embodiment places the TEC temperature control chip 30 below the thermopile infrared sensor chip 50 and the ambient temperature sensor chip 40.
  • the ambient temperature sensor chip 40 detects that the temperature exceeds the specified temperature range, and the TEC temperature control chip 30 can be used to control the temperature, so that the ambient temperature of the thermopile sensor chip 50 is always controlled at a constant temperature, so that the thermopile infrared sensor chip 50 is not affected by the thermal shock when the external light source is turned on, so that the reference output of the thermopile infrared sensor 130 is maintained at a constant value, the resolution of the thermopile infrared sensor 130 is improved, and then the resolution of the gas to be tested is improved; the thermopile infrared detector 130 of the present embodiment does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock because the TEC temperature control chip 30 is integrated, and the substrate 20 and the shape design have greater freedom, which can not only be more mini
  • the substrate 20 is a TO metal tube seat 21
  • the shell 10 is a TO metal tube cap 11 .
  • the combination of the TO metal tube seat 21 and the TO metal tube cap 11 is a common combination in the prior art (as shown in FIG. 1 ), which has the characteristics of thermal stability, airtightness and reliability, and is used to resist the thermal shock brought by the outside of the thermopile infrared detector 130.
  • This packaging structure can also be used in the present embodiment.
  • the thermopile infrared detector 130 can be cooled and controlled by simply adding the TEC temperature control chip 30, so that the ambient temperature of the thermopile sensor chip 50 is always controlled in a constant temperature state.
  • the TO metal tube socket 21 and the TO metal tube cap 11 are made of iron-nickel-plated material.
  • the TO metal tube socket 21 and the TO metal tube cap 11 can also be made of other metal materials such as copper, aluminum and copper alloy, but the use of iron-nickel-plated material not only has better anti-corrosion and oxidation effects, but also can effectively reduce the surface reflection of the TO metal tube cap 11 and reduce detection interference.
  • the use of the TO metal tube cap 11 made of iron-nickel-plated material not only helps to improve detection accuracy, but also helps to make the thermopile infrared detector 130 suitable for more application scenarios.
  • thermopile infrared detector 130 further includes pins 80 electrically connected to each chip.
  • the TEC temperature control chip 30, the ambient temperature sensor chip 40 and the thermopile sensor chip 50 are electrically connected to the pins 80 through the bonding wires 70.
  • the pins 80 need to be protruded from the The lower surface of the substrate 20 is controlled by an external control chip, or sends electrical signals to other external device structures.
  • the pin 80 may include any number of pins 80, and the distribution of the pins 80 may be any one of a single-row distribution, a double-row distribution, and a circular distribution, which may be set according to actual needs and is not limited here.
  • the substrate 20 itself will also be connected to a pin 80 for conducting static electricity to avoid damaging the chip in the cavity of the thermopile infrared detector 130.
  • this embodiment provides a multi-channel thermopile infrared detector.
  • the multi-channel thermopile infrared detector is different from the first embodiment in that a plurality of thermopile sensor chips 50 are provided.
  • the number of the thermopile sensor chips 50 ranges from 1 to 4.
  • thermopile sensor chips 50 can prepare multiple gas detection channels to be tested. Multiple thermopile sensor chips 50 are arranged at intervals above the TEC temperature control chip 30, which is suitable for more application scenarios.
  • the thermopile infrared detector 130 can be used as a comprehensive detector to detect the gas to be tested. In this embodiment, the number of the thermopile sensor chips 50 is 2, which is used to detect two gases. Because the space in the cavity is limited, the number range of the thermopile sensor chips 50 is also limited. The specific number can be set according to actual needs and is not limited here.
  • the number of the infrared filters 60 is the same as the number of the thermopile sensor chips 50 .
  • the infrared filter 60 and the thermopile sensor chip 50 cooperate with each other, correspond to each other in vertical position, and are provided with a spacing.
  • the number of the thermopile sensor chips 50 is 2, and the number of the infrared filter 60 is also 2.
  • the infrared filter 60 preferably adopts a silicon infrared filter, which filters out stray light in the external environment and only allows thermal radiation waves of the expected wavelength to irradiate the thermopile sensor chip 50, which is conducive to ensuring that the dispersed infrared light within the detection range can be received in a concentrated manner, which helps to improve the gas detection accuracy.
  • the selection of the specific material of the infrared filter 60 can also be selected according to actual needs, and there is no limitation here.
  • this embodiment provides a thermopile infrared detector 130 .
  • the difference between the thermopile infrared detector 130 and the first embodiment is that the packaging structure is different.
  • the base 20 is a packaging substrate 22
  • the housing 10 includes a packaging side wall 12 and a packaging top plate 13 .
  • thermopile infrared detector 110 does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock because it integrates the TEC temperature control chip 30.
  • the packaging substrate 22 and the shape design have greater freedom, which can not only be more miniaturized, but also reduce the packaging cost.
  • the infrared filter 60 is mounted on the packaging top plate 13.
  • there is only one thermopile sensor chip 50 corresponding to one infrared filter 60.
  • a piece of infrared filter 60 can also be directly mounted on the packaging side wall 12.
  • the pins 80 are flush with the lower surface of the packaging substrate 22 and can be directly used as solder joints.
  • the present embodiment can also integrate a plurality of the TEC temperature control chips 30 to form a multi-channel thermopile infrared detector to detect a variety of gases to be tested, with a wider range of applications.
  • a corresponding number of the infrared filters 60 must also be set and mounted on the corresponding positions of the package top plate 13.
  • the substrate 20 and the housing 10 can be made of any suitable material as long as the material can play a supporting role and have an infrared light filtering effect.
  • the substrate 20 and the housing 10 can be made of silicon or germanium. In this embodiment, silicon is preferably used.
  • this embodiment provides a method for preparing a thermopile infrared detector, which is used to prepare the thermopile infrared detector described in any one of Embodiment 1 and Embodiment 3.
  • the method for preparing the thermopile infrared detector includes:
  • step S1 is performed to provide a substrate 20 , a TEC temperature control chip 30 , a thermopile sensor chip 50 , an ambient temperature sensor chip 40 , an infrared filter 60 and a housing 10 .
  • thermopile infrared detector 130 can be provided according to the actual packaging structure or practical application of the thermopile infrared detector 130 , and no limitation is made here as long as the functions and materials can meet the requirements.
  • step S2 is performed to mount the TEC temperature control chip 30 on the substrate 20; and step S3 is performed to mount the thermopile sensor chip 50 and the ambient temperature sensor chip 40 on the TEC temperature control chip 30 using the TEC temperature control chip 30 as a substrate, and the thermopile sensor chip 50 and the ambient temperature sensor chip 40 are spaced apart from each other.
  • the mounting in step S2 and step S3 may both adopt surface mounting technology (Surface Mounted Technology, SMT).
  • SMT Surface Mounted Technology
  • the surface mounting process has the advantages of high precision, light weight, and small area, and can meet the requirements of miniaturization of the thermopile infrared detector 130.
  • the mounting in step S2 and step S3 includes but is not limited to the surface mounting process, and can also be set according to actual needs, which is not limited here.
  • step S4 is performed to bond wires 70 to the TEC temperature control chip 30 , the thermopile sensor chip 50 , and the ambient temperature sensor chip 40 .
  • the method for preparing the thermopile infrared detector 130 further includes: providing pins 80 , and electrically connecting the pins 80 respectively after bonding the wires 70 in step S4 .
  • the pins 80 may be specifically arranged according to different packaging structures.
  • step S5 is performed to mount the infrared filter 60 on the top surface of the housing 10 , and package the housing 10 and the substrate 20 to obtain a complete thermopile infrared detector 130 .
  • the infrared filter 60 can be attached to the inner surface of the top surface of the housing 10 by means of epoxy resin with high thermal conductivity, thereby preventing water vapor from entering the cavity inside the thermopile infrared detector 130 while fixing the infrared filter 60 .
  • this embodiment provides an NDIR detection system, which includes: an infrared light source 90, an air chamber 100, an optical path 110, a circuit, and a thermopile infrared detector 130 described in any one of Embodiments 1 to 3; the infrared light source 90 and the thermopile infrared detector 130 are respectively located on opposite sides of the air chamber 100 and have a spacing, and the spacing is the optical path 110 through which the infrared light emitted by the infrared light source 90 passes; the air chamber 100 is used to place a gas to be measured 120; the infrared light source 90 and the thermopile infrared detector 130 are respectively connected to the circuit.
  • the working principle of the NDIR detection system is as follows: during the use of the NDIR detection system, the infrared light source 90 radiates infrared light, and the infrared light passes through the gas to be measured 120 along the optical path 110, passes through the infrared filter 60 on the thermopile infrared detector 130, and reaches the thermopile infrared detector 130.
  • the concentration of the gas to be measured 120 is determined by measuring the intensity of the infrared light entering the thermopile infrared detector 130. When there is no gas to be measured 120 in the external environment, the intensity of the infrared light is the strongest.
  • the gas to be measured 120 When the gas to be measured 120 enters the gas chamber 100, the gas to be measured 120 absorbs a part of the infrared light, so that the light intensity reaching the thermopile infrared detector 130 is weakened.
  • the NDIR detection system can calculate the concentration of the gas to be measured 120.
  • thermopile infrared detector comprises: a shell; a substrate, which is located below the shell and forms a sealed cavity with the shell; a TEC temperature control chip, which is located above the substrate in the cavity and is used to control the temperature of the thermopile infrared detector so that it is in a constant temperature state; an ambient temperature sensor chip, which is located above the TEC temperature control chip in the cavity and is used to monitor the temperature of the thermopile infrared detector; a thermopile sensor chip, which is located above the TEC temperature control chip in the cavity and is spaced from the ambient temperature sensor chip and is used to detect a gas to be measured; and an infrared filter, which is located on the top surface of the shell and corresponds to the thermopile sensor chip in a vertical position and has a spacing therebetween.
  • thermopile infrared detector of the present invention places the TEC temperature control chip below the thermopile infrared sensor chip and the ambient temperature sensor chip.
  • the TEC temperature control chip can be used to control the temperature, so that the ambient temperature of the thermopile sensor chip is always controlled at a constant temperature, so that the thermopile infrared sensor chip is not affected by the thermal shock when the external light source is turned on, so that the reference output of the thermopile infrared sensor is maintained at a constant value, the resolution of the thermopile infrared sensor is improved, and then the resolution of the gas to be tested is improved;
  • the thermopile infrared detector of the present invention because the TEC temperature control chip is integrated, does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock, and the freedom of substrate and shape design is greater, which can not only be more miniaturized, but also reduce the packaging cost;
  • the size of the thermopile infrared detector can be consistent with that of the

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Abstract

A thermopile infrared detector (130) and a preparation method therefor, and an NDIR detection system. The thermopile infrared detector (130) comprises a housing (10), a substrate (20), a TEC temperature control chip (30), an ambient temperature sensor chip (40), a thermopile sensor chip (50) and an infrared filter (60). In the thermopile infrared detector (130), the TEC temperature control chip (30) is placed below the thermopile infrared sensor chip (50) and the ambient temperature sensor chip (40), and when an ambient temperature rises, cooling control can be performed by means of the TEC temperature control chip (30), such that the ambient temperature of the thermopile sensor chip (50) is controlled in a constant temperature state all the time, the thermopile infrared sensor chip (50) is not affected by a thermal shock when an external light source is turned on, and a reference output of the thermopile infrared detector (130) is maintained at a constant value, thereby increasing the resolution of the thermopile infrared detector (130), and thus increasing the detection resolution for a gas to be tested.

Description

热电堆红外探测器及其制备方法和NDIR探测系统Thermopile infrared detector and preparation method thereof and NDIR detection system 技术领域Technical Field
本发明涉及探测器领域,特别是涉及一种热电堆红外探测器及其制备方法和NDIR探测系统。The invention relates to the field of detectors, and in particular to a thermopile infrared detector and a preparation method thereof, and an NDIR detection system.
背景技术Background Art
非色散红外(Non-Dispersive InfraRed,NDIR)探测系统是一种常用的气体检测方式。它主要用于测化合物,例如:CH4、CO2、N2O、CO、SO2、NH3、乙醇、苯等,还有绝大多数有机物(Hydrocarbon,HC),其中还包括有机挥发性混合物(Volatile Organic Compounds,VOC)。Non-Dispersive InfraRed (NDIR) detection system is a commonly used gas detection method. It is mainly used to measure compounds, such as CH 4 , CO 2 , N 2 O, CO, SO 2 , NH 3 , ethanol, benzene, etc., as well as most organic substances (Hydrocarbon, HC), including volatile organic compounds (Volatile Organic Compounds, VOC).
NDIR探测系统是一种由红外光源(IR source)、光路(Optics Cell)、热电堆红外探测器(Thermopile IR Detector)(如图1所示)、电路(Electronics)和软件算法(Algorithm)组成的光学气体传感器。在NDIR探测系统的应用中,由于红外光源直接决定辐射出的红外光强度,因此红外光源功率越大,辐射出的红外光强度也就越大。然而,由于整个NDIR探测系统是一个密封的光路结构,红外光源发热会积聚在密封的结构中,从而导致整个NDIR探测系统环境温度的升高。红外光源功率越大,则NDIR探测系统温度升高越多。为了降低NDIR探测系统的功耗,现有技术一般将红外光源进行调整,缩短红外光源的工作时间,从而减少NDIR探测系统的功耗。The NDIR detection system is an optical gas sensor composed of an infrared light source (IR source), an optical path (Optics Cell), a thermopile infrared detector (Thermopile IR Detector) (as shown in Figure 1), an electronic circuit (Electronics) and a software algorithm (Algorithm). In the application of the NDIR detection system, since the infrared light source directly determines the intensity of the radiated infrared light, the greater the power of the infrared light source, the greater the intensity of the radiated infrared light. However, since the entire NDIR detection system is a sealed optical path structure, the heat generated by the infrared light source will accumulate in the sealed structure, thereby causing the ambient temperature of the entire NDIR detection system to rise. The greater the power of the infrared light source, the greater the temperature rise of the NDIR detection system. In order to reduce the power consumption of the NDIR detection system, the existing technology generally adjusts the infrared light source to shorten the working time of the infrared light source, thereby reducing the power consumption of the NDIR detection system.
根据NDIR探测系统的上述工作特点,NDIR探测系统在工作过程中红外光源是不断开启和关闭的,红外光源开启会导致NDIR探测系统的环境温度升高,而红外光源关闭则导致NDIR探测系统的环境温度降低。因此,NDIR探测系统在工作过程中,热电堆红外探测器的环境温度也是不断变化,进而影响热电堆红外探测器的输出电压,热电堆红外传感器的基准输出会快速升高,降低热电堆红外探测器对红外光响应的分辨率,从而降低NDIR探测系统的气体检测精度。此外,对于NDIR探测系统工作的外界环境温度变化,也会导致热电堆红外探测器响应的变化,从而导致NDIR探测系统的特性和外界环境温度相关,无法保证稳定的气体检测精度。According to the above working characteristics of the NDIR detection system, the infrared light source of the NDIR detection system is constantly turned on and off during operation. Turning on the infrared light source will cause the ambient temperature of the NDIR detection system to rise, while turning off the infrared light source will cause the ambient temperature of the NDIR detection system to drop. Therefore, during the operation of the NDIR detection system, the ambient temperature of the thermopile infrared detector is also constantly changing, which in turn affects the output voltage of the thermopile infrared detector. The reference output of the thermopile infrared sensor will increase rapidly, reducing the resolution of the thermopile infrared detector's response to infrared light, thereby reducing the gas detection accuracy of the NDIR detection system. In addition, changes in the external ambient temperature of the NDIR detection system will also cause changes in the response of the thermopile infrared detector, resulting in the characteristics of the NDIR detection system being related to the external ambient temperature, and unable to guarantee stable gas detection accuracy.
鉴于以上,有必要提供一种热电堆红外探测器及其制备方法和NDIR探测系统,以解决现有技术的热电堆红外探测器的环境温度不断变化及检测精度的问题。 In view of the above, it is necessary to provide a thermopile infrared detector and a preparation method thereof and an NDIR detection system to solve the problems of the constant change of ambient temperature and detection accuracy of the thermopile infrared detector in the prior art.
发明内容Summary of the invention
鉴于以上所述现有技术的缺点,本发明的目的在于提供一种热电堆红外探测器及其制备方法和NDIR探测系统,以解决现有技术的热电堆红外探测器的环境温度不断变化及检测精度的问题。In view of the above-mentioned shortcomings of the prior art, the object of the present invention is to provide a thermopile infrared detector and a preparation method thereof and an NDIR detection system to solve the problems of the thermopile infrared detector in the prior art such as the constantly changing ambient temperature and the detection accuracy.
为实现上述目的及其他相关目的,本发明提供一种热电堆红外探测器,所述热电堆红外探测器包括:In order to achieve the above-mentioned object and other related objects, the present invention provides a thermopile infrared detector, the thermopile infrared detector comprising:
壳体;case;
基底,位于所述壳体下方,且与所述壳体组成密封腔体;A base, located below the shell and forming a sealed cavity with the shell;
TEC控温芯片,位于所述腔体内的所述基底上方,用于控制所述热电堆红外探测器的温度,使其处于恒温状态;A TEC temperature control chip, located above the substrate in the cavity, for controlling the temperature of the thermopile infrared detector to keep it in a constant temperature state;
环境温度传感器芯片,位于所述腔体内的所述TEC控温芯片上方,用于监测所述热电堆红外探测器的温度;An ambient temperature sensor chip, located above the TEC temperature control chip in the cavity, for monitoring the temperature of the thermopile infrared detector;
热电堆传感器芯片,位于所述腔体内的所述TEC控温芯片上方,与所述环境温度传感器芯片相互间隔,用于检测待测气体;A thermopile sensor chip is located above the TEC temperature control chip in the cavity and is spaced apart from the ambient temperature sensor chip, and is used to detect the gas to be tested;
红外滤光片,位于所述壳体的顶面,且在垂直位置上对应所述热电堆传感器芯片,并具有间距。The infrared filter is located on the top surface of the housing and corresponds to the thermopile sensor chip in a vertical position with a spacing therebetween.
可选地,所述热电堆传感器芯片的数量范围为1个~4个。Optionally, the number of the thermopile sensor chips ranges from 1 to 4.
可选地,所述红外滤光片的数量与所述热电堆传感器芯片的数量相同。Optionally, the number of the infrared filters is the same as the number of the thermopile sensor chips.
可选地,所述基底包括TO金属管座及封装基板。Optionally, the substrate includes a TO metal tube seat and a packaging substrate.
可选地,当所述基底为TO金属管座时,所述壳体为TO金属管帽。Optionally, when the substrate is a TO metal tube socket, the shell is a TO metal tube cap.
可选地,当所述基底为封装基板时,所述壳体包括封装侧壁及封装顶板。Optionally, when the base is a packaging substrate, the shell includes a packaging side wall and a packaging top plate.
可选地,所述热电堆红外探测器还包括引脚,与各个芯片电连接。Optionally, the thermopile infrared detector further includes pins electrically connected to each chip.
本发明还提供一种热电堆红外探测器的制备方法,所述热电堆红外探测器的制备方法包括:The present invention also provides a method for preparing a thermopile infrared detector, the method for preparing the thermopile infrared detector comprising:
S1:提供基底、TEC控温芯片、热电堆传感器芯片、环境温度传感器芯片、红外滤光片及壳体;S1: Provide substrate, TEC temperature control chip, thermopile sensor chip, ambient temperature sensor chip, infrared filter and housing;
S2:于所述基底上贴装所述TEC控温芯片;S2: mounting the TEC temperature control chip on the substrate;
S3:以所述TEC控温芯片为基板,于所述TEC控温芯片上贴装所述热电堆传感器芯片及所述环境温度传感器芯片,且所述热电堆传感器芯片与所述环境温度传感器芯片相互间隔;S3: Using the TEC temperature control chip as a substrate, mounting the thermopile sensor chip and the ambient temperature sensor chip on the TEC temperature control chip, and the thermopile sensor chip and the ambient temperature sensor chip are spaced apart from each other;
S4:对所述TEC控温芯片、所述热电堆传感器芯片及所述环境温度传感器芯片分别打线; S4: bonding wires to the TEC temperature control chip, the thermopile sensor chip, and the ambient temperature sensor chip respectively;
S5:于所述壳体顶面贴装所述红外滤光片,并将所述壳体与所述基底进行封装,以获得完整的热电堆红外探测器。S5: mounting the infrared filter on the top surface of the shell, and packaging the shell and the substrate to obtain a complete thermopile infrared detector.
可选地,所述热电堆红外探测器的制备方法还包括:提供引脚,在步骤S4打线后,分别与所述引脚电连接。Optionally, the method for preparing the thermopile infrared detector further includes: providing pins, and electrically connecting the pins respectively after wire bonding in step S4.
本发明还提供一种NDIR探测系统,所述NDIR探测系统包括:The present invention also provides a NDIR detection system, the NDIR detection system comprising:
红外光源、气室、光路、电路及上述任意一项所述的热电堆红外探测器;Infrared light source, gas chamber, optical path, circuit and any one of the thermopile infrared detectors described above;
所述红外光源及所述热电堆红外探测器分别位于所述气室的相对两侧,并具有间距,所述间距为所述红外光源发出的红外光通过的所述光路;所述气室用于安置待测气体;The infrared light source and the thermopile infrared detector are respectively located on opposite sides of the gas chamber and have a distance therebetween, and the distance is the optical path through which the infrared light emitted by the infrared light source passes; the gas chamber is used to place the gas to be measured;
所述红外光源及所述热电堆红外探测器分别与所述电路相连接。The infrared light source and the thermopile infrared detector are connected to the circuit respectively.
如上所述,本发明的热电堆红外探测器及其制备方法和NDIR探测系统,具有以下有益效果:As described above, the thermopile infrared detector and its preparation method and NDIR detection system of the present invention have the following beneficial effects:
本发明的所述热电堆红外探测器将所述TEC控温芯片放置于所述热电堆红外传感器芯片和所述环境温度传感器芯片的下方,当环境温度升高,可以通过所述TEC控温芯片进行降温控制,从而将所述热电堆传感器芯片的环境温度一直控制在恒温状态,从而使所述热电堆红外传感器芯片不受外界光源开启时热冲击的影响,使得所述热电堆红外传感器的基准输出保持在恒定值,提高所述热电堆红外传感器的分辨率,进而提高待测气体检测的分辨率;本发明的所述热电堆红外探测器由于集成了所述TEC温控芯片,不需要和传统的热电堆红外探测器采用一样的封装形式抵抗热冲击,基底和形状设计的自由度更大,不仅可以更小型化,也可以降低封装成本;本发明的所述热电堆红外探测器尺寸可以和现有NDIR探测系统中热电堆红外探测器的尺寸保持一致,实现兼容应用,降低了替代成本。The thermopile infrared detector of the present invention places the TEC temperature control chip below the thermopile infrared sensor chip and the ambient temperature sensor chip. When the ambient temperature rises, the TEC temperature control chip can be used to control the temperature, so that the ambient temperature of the thermopile sensor chip is always controlled at a constant temperature, so that the thermopile infrared sensor chip is not affected by the thermal shock when the external light source is turned on, so that the reference output of the thermopile infrared sensor is maintained at a constant value, the resolution of the thermopile infrared sensor is improved, and then the resolution of the gas to be tested is improved; the thermopile infrared detector of the present invention does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock because it integrates the TEC temperature control chip, and the freedom of substrate and shape design is greater, which can not only be more miniaturized, but also reduce the packaging cost; the size of the thermopile infrared detector of the present invention can be consistent with the size of the thermopile infrared detector in the existing NDIR detection system, so as to achieve compatible application and reduce the replacement cost.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1显示为传统的热电堆红外探测器的结构示意图。FIG. 1 is a schematic diagram showing the structure of a conventional thermopile infrared detector.
图2显示为本发明的热电堆红外探测器实施例一的结构示意图。FIG. 2 is a schematic diagram showing the structure of a thermopile infrared detector according to a first embodiment of the present invention.
图3显示为本发明的热电堆红外探测器实施例二的结构示意图。FIG. 3 is a schematic structural diagram of a second embodiment of a thermopile infrared detector according to the present invention.
图4显示为本发明的热电堆红外探测器实施例三的结构示意图。FIG. 4 is a schematic structural diagram of a third embodiment of the thermopile infrared detector of the present invention.
图5显示为本发明的热电堆红外探测器制备方法的流程示意图。FIG. 5 is a schematic flow chart showing a method for preparing a thermopile infrared detector according to the present invention.
图6显示为本发明的NDIR探测系统的结构示意图。FIG. 6 is a schematic diagram showing the structure of the NDIR detection system of the present invention.
元件标号说明Component number description
10,壳体;11,TO金属管帽;12,封装侧壁;13,封装顶板;20,基底;21,TO金属 管座;22,封装基板;30,TEC控温芯片;40,环境温度传感器芯片;50,热电堆传感器芯片;60,红外滤光片;70,打线;80,引脚;90,红外光源;100,气室;110,光路;120,待测气体;130,热电堆红外探测器。10, shell; 11, TO metal cap; 12, package side wall; 13, package top plate; 20, base; 21, TO metal Tube socket; 22, packaging substrate; 30, TEC temperature control chip; 40, ambient temperature sensor chip; 50, thermopile sensor chip; 60, infrared filter; 70, wire bonding; 80, pins; 90, infrared light source; 100, gas chamber; 110, optical path; 120, gas to be tested; 130, thermopile infrared detector.
具体实施方式DETAILED DESCRIPTION
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。The following describes the embodiments of the present invention through specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the contents disclosed in this specification. The present invention can also be implemented or applied through other different specific embodiments, and the details in this specification can also be modified or changed in various ways based on different viewpoints and applications without departing from the spirit of the present invention.
如在详述本发明实施例时,为便于说明,表示器件结构的剖面图会不依一般比例作局部放大,而且所述示意图只是示例,其在此不应限制本发明保护的范围。When describing the embodiments of the present invention in detail, for the sake of convenience, the cross-sectional views showing the device structures will not be partially enlarged according to the general scale, and the schematic views are only examples, which should not limit the scope of protection of the present invention.
为了方便描述,此处可能使用诸如“之下”、“下方”、“低于”、“下面”、“上方”、“上”等的空间关系词语来描述附图中所示的一个结构或特征与其他结构或特征的关系。将理解到,这些空间关系词语意图包含使用中或操作中的器件的、除了附图中描绘的方向之外的其他方向。此外,当一层被称为在两层“之间”时,它可以是所述两层之间仅有的层,或者也可以存在一个或多个介于其间的层。本文使用的“介于……之间”表示包括两端点值。For ease of description, spatial relational terms such as "under", "below", "below", "below", "above", "on", etc. may be used herein to describe the relationship of one structure or feature shown in the drawings to other structures or features. It will be understood that these spatial relational terms are intended to include other directions of the device in use or operation in addition to the directions depicted in the drawings. In addition, when a layer is referred to as being "between" two layers, it can be the only layer between the two layers, or there may be one or more intervening layers. As used herein, "between..." means including the end point values.
在本申请的上下文中,所描述的第一特征在第二特征“之上”的结构可以包括第一和第二特征形成为直接接触的实施例,也可以包括另外的特征形成在第一和第二特征之间的实施例,这样第一和第二特征可能不是直接接触。In the context of the present application, a structure in which a first feature is described as being "above" a second feature may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features are formed between the first and second features, such that the first and second features may not be in direct contact.
请参阅图1至图6。需要说明的是,本实施例中所提供的图示仅以示意方式说明本发明的基本构想,遂图示中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,且其组件布局型态也可能更为复杂。Please refer to Figures 1 to 6. It should be noted that the illustrations provided in this embodiment are only schematic illustrations of the basic concept of the present invention, and the illustrations only show components related to the present invention rather than the number, shape and size of components in actual implementation. In actual implementation, the type, quantity and proportion of each component may be changed arbitrarily, and the component layout may also be more complicated.
实施例一Embodiment 1
如图2所示,本实施例提供一种热电堆红外探测器130,所述热电堆红外探测器130包括:As shown in FIG. 2 , this embodiment provides a thermopile infrared detector 130 , and the thermopile infrared detector 130 includes:
壳体10;Housing 10;
基底20,位于所述壳体10下方,且与所述壳体10组成密封腔体;The base 20 is located below the housing 10 and forms a sealed cavity with the housing 10;
半导体制冷器(Thermo Electric Cooler,TEC)控温芯片30,位于所述腔体内的所述基底20上方,用于控制所述热电堆红外探测器130的温度,使其处于恒温状态; A semiconductor refrigerator (TEC) temperature control chip 30 is located above the substrate 20 in the cavity and is used to control the temperature of the thermopile infrared detector 130 to keep it in a constant temperature state;
环境温度传感器芯片40,位于所述腔体内的所述TEC控温芯片30上方,用于监测所述热电堆红外探测器130的温度;An ambient temperature sensor chip 40 , located above the TEC temperature control chip 30 in the cavity, for monitoring the temperature of the thermopile infrared detector 130 ;
热电堆传感器芯片50,位于所述腔体内的所述TEC控温芯片30上方,与所述环境温度传感器芯片40相互间隔,用于检测待测气体;The thermopile sensor chip 50 is located above the TEC temperature control chip 30 in the cavity and is spaced apart from the ambient temperature sensor chip 40 , and is used to detect the gas to be tested;
红外滤光片60,位于所述壳体10的顶面,在垂直位置上对应所述热电堆传感器芯片50,并具有间距。The infrared filter 60 is located on the top surface of the housing 10 , vertically corresponding to the thermopile sensor chip 50 , and has a spacing therebetween.
本实施例的所述热电堆红外探测器130将所述TEC控温芯片30放置于所述热电堆红外传感器芯片50和所述环境温度传感器芯片40的下方,当环境温度升高,所述环境温度传感器芯片40检测到温度超过限定的温度范围,可以通过所述TEC控温芯片30进行降温控制,从而将所述热电堆传感器芯片50的环境温度一直控制在恒温状态,使所述热电堆红外传感器芯片50不受外界光源开启时热冲击的影响,使得所述热电堆红外传感器130的基准输出保持在恒定值,提高所述热电堆红外传感器130的分辨率,进而提高待测气体检测的分辨率;本实施例的所述热电堆红外探测器130由于集成了所述TEC温控芯片30,不需要和传统的热电堆红外探测器采用一样的封装形式抵抗热冲击,所述基底20和形状设计的自由度更大,不仅可以更小型化,也可以降低封装成本。The thermopile infrared detector 130 of the present embodiment places the TEC temperature control chip 30 below the thermopile infrared sensor chip 50 and the ambient temperature sensor chip 40. When the ambient temperature rises, the ambient temperature sensor chip 40 detects that the temperature exceeds the specified temperature range, and the TEC temperature control chip 30 can be used to control the temperature, so that the ambient temperature of the thermopile sensor chip 50 is always controlled at a constant temperature, so that the thermopile infrared sensor chip 50 is not affected by the thermal shock when the external light source is turned on, so that the reference output of the thermopile infrared sensor 130 is maintained at a constant value, the resolution of the thermopile infrared sensor 130 is improved, and then the resolution of the gas to be tested is improved; the thermopile infrared detector 130 of the present embodiment does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock because the TEC temperature control chip 30 is integrated, and the substrate 20 and the shape design have greater freedom, which can not only be more miniaturized, but also reduce the packaging cost.
如图2所示,作为示例,所述基底20为TO金属管座21,所述壳体10为TO金属管帽11。As shown in FIG. 2 , as an example, the substrate 20 is a TO metal tube seat 21 , and the shell 10 is a TO metal tube cap 11 .
所述TO金属管座21与所述TO金属管帽11的结合是现有技术中常见的一种组合(如图1所示),具有热稳定性、气密性和可靠性的特点,用于抵抗所述热电堆红外探测器130外部带来的的热冲击,在本实施例中也可沿用这种封装结构,在不改变原有热电堆红外探测器的基础上,只需通过增加所述TEC控温芯片30,即可对所述热电堆红外探测器130进行降温控制,从而将所述热电堆传感器芯片50的环境温度一直控制在恒温状态。所述TO金属管座21与所述TO金属管帽11为铁镀镍材质的TO金属管座与TO金属管帽,当然,在其他示例中,所述TO金属管座21与所述TO金属管帽11也可以为铜、铝及铜合金等其他金属材质,但选用铁镀镍材质不仅具有较好的防腐蚀氧化等效果,同时可以有效减少所述TO金属管帽11的表面反射,减少探测干扰,采用铁镀镍材质的所述TO金属管帽11不仅有助于提高检测精度,同时有助于使所述热电堆红外探测器130能适用于更多的应用场景。The combination of the TO metal tube seat 21 and the TO metal tube cap 11 is a common combination in the prior art (as shown in FIG. 1 ), which has the characteristics of thermal stability, airtightness and reliability, and is used to resist the thermal shock brought by the outside of the thermopile infrared detector 130. This packaging structure can also be used in the present embodiment. On the basis of not changing the original thermopile infrared detector, the thermopile infrared detector 130 can be cooled and controlled by simply adding the TEC temperature control chip 30, so that the ambient temperature of the thermopile sensor chip 50 is always controlled in a constant temperature state. The TO metal tube socket 21 and the TO metal tube cap 11 are made of iron-nickel-plated material. Of course, in other examples, the TO metal tube socket 21 and the TO metal tube cap 11 can also be made of other metal materials such as copper, aluminum and copper alloy, but the use of iron-nickel-plated material not only has better anti-corrosion and oxidation effects, but also can effectively reduce the surface reflection of the TO metal tube cap 11 and reduce detection interference. The use of the TO metal tube cap 11 made of iron-nickel-plated material not only helps to improve detection accuracy, but also helps to make the thermopile infrared detector 130 suitable for more application scenarios.
作为示例,所述热电堆红外探测器130还包括引脚80,与各个芯片电连接。As an example, the thermopile infrared detector 130 further includes pins 80 electrically connected to each chip.
所述TEC控温芯片30、所述环境温度传感器芯片40及所述热电堆传感器芯片50通过打线70分别与所述引脚80电连接,在本实施例的封装结构中,需要将所述引脚80凸出于所述 基底20的下表面,从而接受外界控制芯片的控制,或者向外界的其他器件结构发出电信号等。这里需要说明的是,根据实际热电堆传感器的封装需求,所述引脚80可以包括任意多个引脚80,而且所述引脚80的分布方式可以为单列分布、双列分布以及圆周分布的任意一种,可根据实际需要进行设置,在此不做限制。此外,通常情况下,所述基底20自身也会连接一个所述引脚80,用于导出静电,避免损伤所述热电堆红外探测器130腔体内的芯片。The TEC temperature control chip 30, the ambient temperature sensor chip 40 and the thermopile sensor chip 50 are electrically connected to the pins 80 through the bonding wires 70. In the packaging structure of this embodiment, the pins 80 need to be protruded from the The lower surface of the substrate 20 is controlled by an external control chip, or sends electrical signals to other external device structures. It should be noted that, according to the actual packaging requirements of the thermopile sensor, the pin 80 may include any number of pins 80, and the distribution of the pins 80 may be any one of a single-row distribution, a double-row distribution, and a circular distribution, which may be set according to actual needs and is not limited here. In addition, under normal circumstances, the substrate 20 itself will also be connected to a pin 80 for conducting static electricity to avoid damaging the chip in the cavity of the thermopile infrared detector 130.
实施例二Embodiment 2
如图3所示,本实施例提供一种多通道的热电堆红外探测器,所述多通道的热电堆红外探测器与实施例一的不同之处在于,所述热电堆传感器芯片50的数量设置有多个。As shown in FIG. 3 , this embodiment provides a multi-channel thermopile infrared detector. The multi-channel thermopile infrared detector is different from the first embodiment in that a plurality of thermopile sensor chips 50 are provided.
作为示例,所述热电堆传感器芯片50的数量范围为1个~4个。As an example, the number of the thermopile sensor chips 50 ranges from 1 to 4.
多个所述热电堆传感器芯片50的设置可以制备多条待测气体检测通道,多个所述热电堆传感器芯片50间隔设置于所述TEC控温芯片30上方,适用于更多的应用场景,可以将所述热电堆红外探测器130作为一个综合性的探测器来检测待测气体。本实施例中,所述热电堆传感器芯片50的数量为2,用于对两种气体进行检测。因为所述腔体内空间有限,所述热电堆传感器芯片50的数量范围也有限,具体数量可根据实际需要进行设置,在此不做限制。The arrangement of multiple thermopile sensor chips 50 can prepare multiple gas detection channels to be tested. Multiple thermopile sensor chips 50 are arranged at intervals above the TEC temperature control chip 30, which is suitable for more application scenarios. The thermopile infrared detector 130 can be used as a comprehensive detector to detect the gas to be tested. In this embodiment, the number of the thermopile sensor chips 50 is 2, which is used to detect two gases. Because the space in the cavity is limited, the number range of the thermopile sensor chips 50 is also limited. The specific number can be set according to actual needs and is not limited here.
作为示例,所述红外滤光片60的数量与所述热电堆传感器芯片50的数量相同。As an example, the number of the infrared filters 60 is the same as the number of the thermopile sensor chips 50 .
所述红外滤光片60与所述热电堆传感器芯片50相互配合工作,在垂直位置上相互对应,且设置有间距,在本实施例中,所述热电堆传感器芯片50的数量为2,所述红外滤光片60的数量也对应为2。所述红外滤光片60优选采用硅材质红外滤光片,通过所述红外滤光片60滤除外界环境中的杂散光线而仅允许预期波长的热辐射波照射到所述热电堆传感器芯片50上,有利于确保探测范围内散布性的红外光能被集中接收,有助于提高气体检测精度。当然,所述红外滤光片60具体材质的选择也可根据实际需要进行选择,在此不做限制。The infrared filter 60 and the thermopile sensor chip 50 cooperate with each other, correspond to each other in vertical position, and are provided with a spacing. In this embodiment, the number of the thermopile sensor chips 50 is 2, and the number of the infrared filter 60 is also 2. The infrared filter 60 preferably adopts a silicon infrared filter, which filters out stray light in the external environment and only allows thermal radiation waves of the expected wavelength to irradiate the thermopile sensor chip 50, which is conducive to ensuring that the dispersed infrared light within the detection range can be received in a concentrated manner, which helps to improve the gas detection accuracy. Of course, the selection of the specific material of the infrared filter 60 can also be selected according to actual needs, and there is no limitation here.
实施例三Embodiment 3
如图4所示,本实施例提供一种热电堆红外探测器130,所述热电堆红外探测器130与实施例一的不同之处在于,封装的结构不同。As shown in FIG. 4 , this embodiment provides a thermopile infrared detector 130 . The difference between the thermopile infrared detector 130 and the first embodiment is that the packaging structure is different.
作为示例,所述基底20为封装基板22,所述壳体10包括封装侧壁12及封装顶板13。As an example, the base 20 is a packaging substrate 22 , and the housing 10 includes a packaging side wall 12 and a packaging top plate 13 .
本实施例中,所述热电堆红外探测器110由于集成了所述TEC温控芯片30,不需要和传统的热电堆红外探测器采用一样的封装形式抵抗热冲击,所述封装基板22和形状设计的自由度更大,不仅可以更小型化,也可以降低封装成本。所述红外滤光片60在所述封装顶板13上贴装,本实施例中只有一个所述热电堆传感器芯片50,对应一个所述红外滤光片60。当只有一个所述红外滤光片60时,也可以直接在所述封装侧壁12上贴装一片所述红外滤光片60。 这里需要注意的是,在本实施例的封装结构中,所述引脚80与所述封装基板22下表面齐平,可直接作为焊点。In this embodiment, the thermopile infrared detector 110 does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock because it integrates the TEC temperature control chip 30. The packaging substrate 22 and the shape design have greater freedom, which can not only be more miniaturized, but also reduce the packaging cost. The infrared filter 60 is mounted on the packaging top plate 13. In this embodiment, there is only one thermopile sensor chip 50, corresponding to one infrared filter 60. When there is only one infrared filter 60, a piece of infrared filter 60 can also be directly mounted on the packaging side wall 12. It should be noted here that, in the packaging structure of this embodiment, the pins 80 are flush with the lower surface of the packaging substrate 22 and can be directly used as solder joints.
当然,本实施例也可集成多个所述TEC温控芯片30,形成多通道的热电堆红外探测器,对多种待测气体进行检测,应用范围更广,当集成多个所述TEC温控芯片30时,所述红外滤光片60也需设置对应的数量,分别贴装在对应位置的所述封装顶板13上。Of course, the present embodiment can also integrate a plurality of the TEC temperature control chips 30 to form a multi-channel thermopile infrared detector to detect a variety of gases to be tested, with a wider range of applications. When a plurality of the TEC temperature control chips 30 are integrated, a corresponding number of the infrared filters 60 must also be set and mounted on the corresponding positions of the package top plate 13.
本实施例中,所述基底20及所述壳体10可以选择任意适合的材质,只要该材质能起到支撑作用以及起到红外光的滤光效果即可。作为示例,所述基底20及所述壳体10的材质可以为硅或锗。本实施例中,优选采用为硅。In this embodiment, the substrate 20 and the housing 10 can be made of any suitable material as long as the material can play a supporting role and have an infrared light filtering effect. As an example, the substrate 20 and the housing 10 can be made of silicon or germanium. In this embodiment, silicon is preferably used.
实施例四Embodiment 4
如图5所示,本实施例提供一种热电堆红外探测器的制备方法,用于制备实施例一实施例三中任意一项所述的热电堆红外探测器,所述热电堆红外探测器的制备方法包括:As shown in FIG5 , this embodiment provides a method for preparing a thermopile infrared detector, which is used to prepare the thermopile infrared detector described in any one of Embodiment 1 and Embodiment 3. The method for preparing the thermopile infrared detector includes:
首先进行步骤S1,提供基底20、TEC控温芯片30、热电堆传感器芯片50、环境温度传感器芯片40、红外滤光片60及壳体10。First, step S1 is performed to provide a substrate 20 , a TEC temperature control chip 30 , a thermopile sensor chip 50 , an ambient temperature sensor chip 40 , an infrared filter 60 and a housing 10 .
可根据实际需要的热电堆红外探测器130封装结构或实际应用,提供相应的器件部件,只要功能及材质能满足需求即可,在此不做限制。Corresponding device components can be provided according to the actual packaging structure or practical application of the thermopile infrared detector 130 , and no limitation is made here as long as the functions and materials can meet the requirements.
接着进行步骤S2,于所述基底20上贴装所述TEC控温芯片30;及步骤S3,以所述TEC控温芯片30为基板,于所述TEC控温芯片30上贴装所述热电堆传感器芯片50及所述环境温度传感器芯片40,且所述热电堆传感器芯片50与所述环境温度传感器芯片40相互间隔。Then, step S2 is performed to mount the TEC temperature control chip 30 on the substrate 20; and step S3 is performed to mount the thermopile sensor chip 50 and the ambient temperature sensor chip 40 on the TEC temperature control chip 30 using the TEC temperature control chip 30 as a substrate, and the thermopile sensor chip 50 and the ambient temperature sensor chip 40 are spaced apart from each other.
作为示例,所述步骤S2及步骤S3中的贴装均可采用表面贴装工艺(Surface Mounted Technology,SMT)。As an example, the mounting in step S2 and step S3 may both adopt surface mounting technology (Surface Mounted Technology, SMT).
表面贴装工艺具有高精密、轻重量,小面积等优势,可以满足所述热电堆红外探测器130小型化的要求。当然所述步骤S2及步骤S3中的贴装包括并不限于表面贴装工艺,也可根据实际需要进行设置,在此不做限制。The surface mounting process has the advantages of high precision, light weight, and small area, and can meet the requirements of miniaturization of the thermopile infrared detector 130. Of course, the mounting in step S2 and step S3 includes but is not limited to the surface mounting process, and can also be set according to actual needs, which is not limited here.
接着进行步骤S4,对所述TEC控温芯片30、所述热电堆传感器芯片50及所述环境温度传感器芯片40分别打线70。Then, step S4 is performed to bond wires 70 to the TEC temperature control chip 30 , the thermopile sensor chip 50 , and the ambient temperature sensor chip 40 .
作为示例,所述热电堆红外探测器130的制备方法还包括:提供引脚80,在步骤S4打线70后,分别与所述引脚80电连接。As an example, the method for preparing the thermopile infrared detector 130 further includes: providing pins 80 , and electrically connecting the pins 80 respectively after bonding the wires 70 in step S4 .
具体所述引脚80的设置可根据不同的封装结构来设置。The pins 80 may be specifically arranged according to different packaging structures.
最后进行步骤S5,于所述壳体10顶面贴装所述红外滤光片60,并将所述壳体10与所述基底20进行封装,以获得完整的热电堆红外探测器130。 Finally, step S5 is performed to mount the infrared filter 60 on the top surface of the housing 10 , and package the housing 10 and the substrate 20 to obtain a complete thermopile infrared detector 130 .
所述红外滤光片60可通过高导热率的环氧树脂贴装于所述壳体10顶面的内表面,在固定所述红外滤光片60的同时避免水汽进入所述热电堆红外探测器130内部的腔体。The infrared filter 60 can be attached to the inner surface of the top surface of the housing 10 by means of epoxy resin with high thermal conductivity, thereby preventing water vapor from entering the cavity inside the thermopile infrared detector 130 while fixing the infrared filter 60 .
实施例五Embodiment 5
如图6所示,本实施例提供一种NDIR探测系统,所述NDIR探测系统包括:红外光源90、气室100、光路110、电路及实施例一至实施例三中任意一项所述的热电堆红外探测器130;所述红外光源90及所述热电堆红外探测器130分别位于所述气室100的相对两侧,并具有间距,所述间距为所述红外光源90发出的红外光通过的所述光路110;所述气室100用于安置待测气体120;所述红外光源90及所述热电堆红外探测器130分别与电路相连接。As shown in FIG6 , this embodiment provides an NDIR detection system, which includes: an infrared light source 90, an air chamber 100, an optical path 110, a circuit, and a thermopile infrared detector 130 described in any one of Embodiments 1 to 3; the infrared light source 90 and the thermopile infrared detector 130 are respectively located on opposite sides of the air chamber 100 and have a spacing, and the spacing is the optical path 110 through which the infrared light emitted by the infrared light source 90 passes; the air chamber 100 is used to place a gas to be measured 120; the infrared light source 90 and the thermopile infrared detector 130 are respectively connected to the circuit.
所述NDIR探测系统的工作原理为:NDIR探测系统在使用过程中,所述红外光源90辐射出红外光,红外光线穿过所述光路110沿途中的待测气体120,透过所述热电堆红外探测器130上的所述红外滤光片60,到达所述热电堆红外探测器130,通过测量进入所述热电堆红外探测器130的红外光的强度,来判断待测气体120的浓度,当外界环境中没有所述待测气体120时,红外光的强度是最强的,当所述待测气体120进入所述气室100时,所述待测气体120吸收掉一部分红外光,这样,到达所述热电堆红外探测器130的光强就减弱了。通过标定零点和测量点红外光吸收的程度和刻度化,所述NDIR探测系统就能够算出所述待测气体120的浓度了。The working principle of the NDIR detection system is as follows: during the use of the NDIR detection system, the infrared light source 90 radiates infrared light, and the infrared light passes through the gas to be measured 120 along the optical path 110, passes through the infrared filter 60 on the thermopile infrared detector 130, and reaches the thermopile infrared detector 130. The concentration of the gas to be measured 120 is determined by measuring the intensity of the infrared light entering the thermopile infrared detector 130. When there is no gas to be measured 120 in the external environment, the intensity of the infrared light is the strongest. When the gas to be measured 120 enters the gas chamber 100, the gas to be measured 120 absorbs a part of the infrared light, so that the light intensity reaching the thermopile infrared detector 130 is weakened. By calibrating the degree and calibration of infrared light absorption at the zero point and the measuring point, the NDIR detection system can calculate the concentration of the gas to be measured 120.
综上所述,本发明提供一种热电堆红外探测器及其制备方法和NDIR探测系统,热电堆红外探测器包括:壳体;基底,位于所述壳体下方,且与所述壳体组成密封腔体;TEC控温芯片,位于所述腔体内的所述基底上方,用于控制所述热电堆红外探测器的温度,使其处于恒温状态;环境温度传感器芯片,位于所述腔体内的所述TEC控温芯片上方,用于监测所述热电堆红外探测器的温度;热电堆传感器芯片,位于所述腔体内的所述TEC控温芯片上方,与所述环境温度传感器芯片相互间隔,用于检测待测气体;红外滤光片,位于所述壳体的顶面,在垂直位置上对应所述热电堆传感器芯片,并具有间距。本发明的所述热电堆红外探测器将所述TEC控温芯片放置于所述热电堆红外传感器芯片和所述环境温度传感器芯片的下方,当环境温度升高,可以通过所述TEC控温芯片进行降温控制,从而将所述热电堆传感器芯片的环境温度一直控制在恒温状态,从而使所述热电堆红外传感器芯片不受外界光源开启时热冲击的影响,使得所述热电堆红外传感器的基准输出保持在恒定值,提高所述热电堆红外传感器的分辨率,进而提高待测气体检测的分辨率;本发明的所述热电堆红外探测器由于集成了所述TEC温控芯片,不需要和传统的热电堆红外探测器采用一样的封装形式抵抗热冲击,基底和形状设计的自由度更大,不仅可以更小型化,也可以降低封装成本;本发明的所 述热电堆红外探测器尺寸可以和现有NDIR探测系统中热电堆红外探测器的尺寸保持一致,实现兼容应用,降低了替代成本。所以,本发明有效克服了现有技术中的种种缺点而具高度产业利用价值。In summary, the present invention provides a thermopile infrared detector, a preparation method thereof and an NDIR detection system, wherein the thermopile infrared detector comprises: a shell; a substrate, which is located below the shell and forms a sealed cavity with the shell; a TEC temperature control chip, which is located above the substrate in the cavity and is used to control the temperature of the thermopile infrared detector so that it is in a constant temperature state; an ambient temperature sensor chip, which is located above the TEC temperature control chip in the cavity and is used to monitor the temperature of the thermopile infrared detector; a thermopile sensor chip, which is located above the TEC temperature control chip in the cavity and is spaced from the ambient temperature sensor chip and is used to detect a gas to be measured; and an infrared filter, which is located on the top surface of the shell and corresponds to the thermopile sensor chip in a vertical position and has a spacing therebetween. The thermopile infrared detector of the present invention places the TEC temperature control chip below the thermopile infrared sensor chip and the ambient temperature sensor chip. When the ambient temperature rises, the TEC temperature control chip can be used to control the temperature, so that the ambient temperature of the thermopile sensor chip is always controlled at a constant temperature, so that the thermopile infrared sensor chip is not affected by the thermal shock when the external light source is turned on, so that the reference output of the thermopile infrared sensor is maintained at a constant value, the resolution of the thermopile infrared sensor is improved, and then the resolution of the gas to be tested is improved; the thermopile infrared detector of the present invention, because the TEC temperature control chip is integrated, does not need to use the same packaging form as the traditional thermopile infrared detector to resist thermal shock, and the freedom of substrate and shape design is greater, which can not only be more miniaturized, but also reduce the packaging cost; The size of the thermopile infrared detector can be consistent with that of the thermopile infrared detector in the existing NDIR detection system, achieving compatible application and reducing replacement cost. Therefore, the present invention effectively overcomes various shortcomings in the prior art and has high industrial utilization value.
上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。 The above embodiments are merely illustrative of the principles and effects of the present invention, and are not intended to limit the present invention. Anyone familiar with the art may modify or alter the above embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or alterations made by a person of ordinary skill in the art without departing from the spirit and technical ideas disclosed by the present invention shall still be covered by the claims of the present invention.

Claims (10)

  1. 一种热电堆红外探测器,其特征在于,所述热电堆红外探测器包括:A thermopile infrared detector, characterized in that the thermopile infrared detector comprises:
    壳体;case;
    基底,位于所述壳体下方,且与所述壳体组成密封腔体;A base, located below the shell and forming a sealed cavity with the shell;
    TEC控温芯片,位于所述腔体内的所述基底上方,用于控制所述热电堆红外探测器的温度,使其处于恒温状态;A TEC temperature control chip, located above the substrate in the cavity, for controlling the temperature of the thermopile infrared detector to keep it in a constant temperature state;
    环境温度传感器芯片,位于所述腔体内的所述TEC控温芯片上方,用于监测所述热电堆红外探测器的温度;An ambient temperature sensor chip, located above the TEC temperature control chip in the cavity, for monitoring the temperature of the thermopile infrared detector;
    热电堆传感器芯片,位于所述腔体内的所述TEC控温芯片上方,与所述环境温度传感器芯片相互间隔,用于检测待测气体;A thermopile sensor chip, located above the TEC temperature control chip in the cavity and spaced apart from the ambient temperature sensor chip, for detecting the gas to be tested;
    红外滤光片,位于所述壳体的顶面,在垂直位置上对应所述热电堆传感器芯片,并具有间距。The infrared filter is located on the top surface of the housing, corresponds to the thermopile sensor chip in a vertical position, and has a spacing therebetween.
  2. 根据权利要求1所述的热电堆红外探测器,其特征在于:所述热电堆传感器芯片的数量范围为1个~4个。The thermopile infrared detector according to claim 1 is characterized in that the number of the thermopile sensor chips ranges from 1 to 4.
  3. 根据权利要求2所述的热电堆红外探测器,其特征在于:所述红外滤光片的数量与所述热电堆传感器芯片的数量相同。The thermopile infrared detector according to claim 2 is characterized in that the number of the infrared filters is the same as the number of the thermopile sensor chips.
  4. 根据权利要求1所述的热电堆红外探测器,其特征在于:所述基底包括TO金属管座及封装基板。The thermopile infrared detector according to claim 1 is characterized in that the substrate comprises a TO metal tube holder and a packaging substrate.
  5. 根据权利要求4所述的热电堆红外探测器,其特征在于:当所述基底为TO金属管座时,所述壳体为TO金属管帽。The thermopile infrared detector according to claim 4 is characterized in that when the substrate is a TO metal tube socket, the shell is a TO metal tube cap.
  6. 根据权利要求4所述的热电堆红外探测器,其特征在于:当所述基底为封装基板时,所述壳体包括封装侧壁及封装顶板。The thermopile infrared detector according to claim 4, characterized in that: when the base is a packaging substrate, the shell includes a packaging side wall and a packaging top plate.
  7. 根据权利要求1所述的热电堆红外探测器,其特征在于:所述热电堆红外探测器还包括引脚,与各个芯片电连接。The thermopile infrared detector according to claim 1 is characterized in that: the thermopile infrared detector also includes pins electrically connected to each chip.
  8. 一种热电堆红外探测器的制备方法,其特征在于,所述热电堆红外探测器的制备方法包括: A method for preparing a thermopile infrared detector, characterized in that the method for preparing the thermopile infrared detector comprises:
    S1:提供基底、TEC控温芯片、热电堆传感器芯片、环境温度传感器芯片、红外滤光片及壳体;S1: Provide substrate, TEC temperature control chip, thermopile sensor chip, ambient temperature sensor chip, infrared filter and housing;
    S2:于所述基底上贴装所述TEC控温芯片;S2: mounting the TEC temperature control chip on the substrate;
    S3:以所述TEC控温芯片为基板,于所述TEC控温芯片上贴装所述热电堆传感器芯片及所述环境温度传感器芯片,且所述热电堆传感器芯片与所述环境温度传感器芯片相互间隔;S3: Using the TEC temperature control chip as a substrate, mounting the thermopile sensor chip and the ambient temperature sensor chip on the TEC temperature control chip, and the thermopile sensor chip and the ambient temperature sensor chip are spaced apart from each other;
    S4:对所述TEC控温芯片、所述热电堆传感器芯片及所述环境温度传感器芯片分别打线;S4: bonding wires to the TEC temperature control chip, the thermopile sensor chip, and the ambient temperature sensor chip respectively;
    S5:于所述壳体顶面贴装所述红外滤光片,并将所述壳体与所述基底进行封装,以获得完整的热电堆红外探测器。S5: mounting the infrared filter on the top surface of the shell, and packaging the shell and the substrate to obtain a complete thermopile infrared detector.
  9. 根据权利要求8所述的热电堆红外探测器的制备方法,其特征在于,所述热电堆红外探测器的制备方法还包括:提供引脚,在步骤S4打线后,分别与所述引脚电连接。The method for preparing a thermopile infrared detector according to claim 8 is characterized in that the method for preparing the thermopile infrared detector further comprises: providing pins, and electrically connecting the pins respectively after wire bonding in step S4.
  10. 一种NDIR探测系统,其特征在于,所述NDIR探测系统包括:An NDIR detection system, characterized in that the NDIR detection system comprises:
    红外光源、气室、光路、电路及如权利要求1~7中任意一项所述的热电堆红外探测器;An infrared light source, an air chamber, an optical path, a circuit, and a thermopile infrared detector as claimed in any one of claims 1 to 7;
    所述红外光源及所述热电堆红外探测器分别位于所述气室的相对两侧,并具有间距,所述间距为所述红外光源发出的红外光通过的所述光路;所述气室用于安置待测气体;The infrared light source and the thermopile infrared detector are respectively located on opposite sides of the gas chamber and have a distance therebetween, and the distance is the optical path through which the infrared light emitted by the infrared light source passes; the gas chamber is used to place the gas to be tested;
    所述红外光源及所述热电堆红外探测器分别与所述电路相连接。 The infrared light source and the thermopile infrared detector are connected to the circuit respectively.
PCT/CN2023/082760 2023-02-24 2023-03-21 Thermopile infrared detector and preparation method therefor, and ndir detection system WO2024174315A1 (en)

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