WO2019229532A1

WO2019229532A1 - Waveguide type photodetector and method of manufacture thereof

Info

Publication number: WO2019229532A1
Application number: PCT/IB2019/000669
Authority: WO
Inventors: Yi Zhang; Hooman ABEDIASL; Aaron John ZILKIE
Original assignee: Rockley Photonics Limited
Priority date: 2018-05-30
Filing date: 2019-05-29
Publication date: 2019-12-05
Also published as: GB2589747B; GB2589747A; CN112534590A; US11735679B2; US20210234058A1; GB202019942D0

Abstract

A silicon based photodetector and method of manufacturing the same. The photodetector comprising: a silicon substrate (201); a buried oxide layer (202), above the silicon substrate; and a waveguide (203), above the buried oxide layer. The waveguide (203) includes a silicon, Si, containing region and a germanium tin, GeSn, containing region (209), both located between a first doped region (206) and a second doped region (207) of the waveguide (203), thereby forming a PIN diode. The first doped region (206) and the second doped region (207) are respectively connected to first and second electrodes (210a, 210b), such that the waveguide (203) is operable as a photodetector.

Description

WAVEGUIDE TYPE PHOTODETECTOR AND METHOD OF MANUFACTURE THEREOF

Field of the Invention

The present invention relates to a silicon based photodetector, and a method of

manufacturing a silicon based photodetector.

Background

Photodetectors are ubiquitous in the context of photonic platforms and networks.

Conventionally, germanium based silicon photodetectors have been used as the light

absorbing material within the photodetector. However, germanium based detectors only work up to a bandgap wavelength of around 1.55 pm. Whereas there are increasing silicon photonic applications at wavelengths beyond 1.55 pm.

Moreover, it is convenient to integrate photodetectors or photodiodes within a photonic circuit (as opposing to bonding them to a part of the circuit). A bonded photodiode incurs coupling losses, and the bonding has a cost in terms of manufacturing (and also in terms of the yield of that process). Further, bonding a photodiode places a restriction on the number of the devices that can be used in a photonic integrated circuit and where they can be

placed. In contrast, an integrated photodetector incurs essentially no coupling loss, and has a high responsivity.

Figure 1 shows a conventional silicon photodetector using a PIN junction. A p doped region and an n doped region extend up the sidewalls of a waveguide ridge, and an intrinsic region is located therebetween. Light passing through the junction is captured by the photodetector, and a signal is provided.

Summary

Accordingly, in a first aspect, embodiments of the present invention provide a silicon based photodetector, comprising:

a silicon substrate;

a buried oxide layer, above the silicon substrate; and

a waveguide, above the buried oxide layer;

wherein the waveguide includes a silicon, Si, containing region and a germanium tin, GeSn, containing region, both located between a first doped region and a second doped region of the waveguide, thereby forming a PIN diode; and wherein the first doped region and the second doped region are respectively connected to first and second electrodes, such that the waveguide is operable as a photodetector.

Such a photodetector can be integrated in a silicon photonic platform, for example in a photonic integrated circuit (PIC) and has a detectable wavelength beyond 1.55 pm. For example, GeSn as a material has a bandgap wavelength of between around 2 pm and around 3 pm.

The silicon based photodetector may have any one or, to the extent that they are compatible, any combination of the following optional features.

The waveguide may be a rib or ridge waveguide, located between a first slab portion and a second slab portion. The first doped region and the second doped region may be located within respective sidewalls of the rib waveguide. The first doped region and the second doped region may respectively extend into the first slab portion and the second slab portion. The first electrode and the second electrode may respectively contact the first doped region and the second doped region in portions of the first doped region and the second doped region which are within the respective slab portions.

The photodetector may have an operating wavelength of at least 1.3 pm. The photodetector may have an operating wavelength of at least 1.55 pm. The photodetector may have an operating wavelength of no more than 3.5 pm.

The germanium tin containing region may be formed of Ge₉₃Sn₇.

The germanium tin containing region may be formed of Ge₉₀Sn₁₀.

A width of the germanium tin containing region, as measured in a direction perpendicular to the guiding direction of the waveguide and parallel to a surface of the substrate, may be at least 40% and more than 60% of a width, measured in the same direction, of the waveguide region.

The germanium tin containing region may be positioned in the waveguide at a point distal to the buried oxide layer. The waveguide may have a height, as measured from a surface of the buried oxide layer adjacent the waveguide to a surface of the waveguide distalmost from the buried oxide layer, of at least 2.5 pm and no more than 3.5 pm.

The waveguide may have a width, as measured from a first side and a second side of the waveguide which are equidistant from the buried oxide layer, of at least 1.5 pm and no more than 2.5 pm.

The first slab portion and the second slab portion may have a height, as measured from an uppermost surface of the buried oxide layer to a surface of the respective slab portions distalmost from the buried oxide layer, of at least 0.2 pm and no more than 0.6 pm.

The germanium tin containing region may be formed of essentially pure germanium tin.

The germanium tin containing region may contain no silicon.

In a second aspect, embodiments of the invention provide a method of manufacturing a silicon based photodetector, comprising the steps of:

providing a silicon based substrate, a buried oxide layer above the silicon substrate, and a waveguide above the buried oxide layer;

doping a first region with dopants of a first species to form a first doped region;

doping a second region with dopants of a second species to form a second doped region;

etching at least a portion of the waveguide, between the first doped region and the second doped region, to provide a cavity therein; and

depositing germanium tin into the cavity, to provide a germanium tin containing region of the waveguide adjacent to a silicon containing region of the waveguide.

The method may have any one or, to the extent that they are compatible, any combination of the following optional features.

Depositing the germanium tin may be performed through selective epitaxial growth.

The method may further comprise a step of passivating the device by depositing a passivating layer over an uppermost surface thereof.

The method may include a step of depositing a first electrode and a second electrode, respectively in contact with the first doped region and the second doped region. Brief Description of the Drawings

Embodiments of the invention will now be described by way of example with reference to the accompanying drawings in which:

Figure 1 shows a cross-sectional view of a conventional photodetector;

Figures 2A - 2E show various manufacturing steps of an embodiment of the present invention; and

Figure 3 shows a cross-sectional view of a photodetector according to an embodiment of the present invention.

Detailed Description and Further Optional Features

Aspects and embodiments of the present invention will now be discussed with reference to the accompanying figures. Further aspects and embodiments will be apparent to those skilled in the art. All documents mentioned in this text are incorporated herein by reference

Figure 2A to 2E show various manufacturing steps of an embodiment of the present invention. In an initial step shown in Figure 2A, a silicon substrate 201 is provided, with a buried oxide layer 202 above the silicon substrate, and a waveguide 203 above the buried oxide layer. The waveguide 203 guides light in a direction into or out of the plane of Figure 2A. First 206 and second 207 doped regions are then provided in respective slab portions 204a and 204b. The slab and waveguide regions are formed in the device or silicon-on- insulator layer of an SOI wafer from which the device is fabricated. The upper surfaces of the structure are covered in a passivation or passivating layer 208, which may be silicon dioxide. The structure may be substantially the same as that shown in Figure 1 , asides from the exclusion of the electrodes. This step may be a front end of line (FEOL) processing step.

Next, an etch is performed to remove a portion of the waveguide. The result of this is shown in Figure 2B, where cavity 205 is can be seen in an upper portion of the waveguide 207. The cavity is, in this example, trapezoid in shape. After the etch, a selective epitaxial process is used to grow a germanium tin (GeSn) region 209 within the cavity. This is shown in Figure 2C. After the epitaxial growth process has been performed, a passivation process is undertaken so as to provide a contiguous passivating or passivation layer 208 across the upper surface of the device. This is shown in Figure 2D. Finally, as shown in Figure 2E, first 210a and second 210b electrodes are provided which respectively contact the first 206 and second 207 doped regions. This step may be performed in two sub-steps: a first step of etching vias through the passivation layer 208 which exposes uppermost surfaces of the first and second doped regions. Subsequently, a metallization process is used to provide electrical contacts to these exposed surfaces of the doped regions as well as provide electrode pads for connecting to external connectors. The steps shown in Figures 2C - 2E may be back end of line (BEOL) process steps.

The steps 2A - 2E result in a device 300 according to embodiments of the present invention as shown in Figure 3. The substrate 201 is formed from silicon, and the buried oxide layer 202 is formed from silicon dioxide (Si0₂). The waveguide 203, slab portions 204a, 204b, and doped regions 206 and 207 are all formed from silicon. The germanium tin containing region 209 is formed of germanium tin, having relatively low levels of tin. For example, the germanium tin containing region may have the composition Ge₉₀Sn₁₀ or Ge₉₃Sn₇.

The germanium tin containing region 209 has a maximum width (measured in a direction perpendicular to the guiding direction of the waveguide, and to a height direction extending from the substrate 201 to the waveguide 203) of around 1 pm. The germanium tin containing region has a height, as measured perpendicular to the width, of around 1.2 pm. The waveguide 203 itself, formed chiefly of silicon, has a width of around 2 pm and a height, as measured from an uppermost surface of the buried oxide layer to an uppermost surface of the waveguide, of around 3 pm. The slab regions 204a and 204b have a height, as measured from an uppermost surface of the buried oxide layer to an uppermost surface of the slab region(s) of around 0.4 pm. The electrodes are formed from aluminium.

While the invention has been described in conjunction with the exemplary embodiments described above, many equivalent modifications and variations will be apparent to those skilled in the art when given this disclosure. Accordingly, the exemplary embodiments of the invention set forth above are considered to be illustrative and not limiting. Various changes to the described embodiments may be made without departing from the spirit and scope of the invention.

All references referred to above are hereby incorporated by reference.

Claims

1. A silicon based photodetector, comprising:

a silicon substrate;

a buried oxide layer, above the silicon substrate; and

a waveguide, above the buried oxide layer;

wherein the waveguide includes a silicon, Si, containing region and a germanium tin, GeSn, containing region, both located between a first doped region and a second doped region of the waveguide, thereby forming a PIN diode;

and wherein the first doped region and the second doped region are respectively connected to first and second electrodes, such that the waveguide is operable as a photodetector.

2. The silicon based photodetector of claim 1 , wherein the waveguide is a rib waveguide located between a first slab portion and a second slab portion.

3. The silicon based photodetector of claim 2, wherein the first doped region and second doped region are located within respective sidewalls of the rib waveguide.

4. The silicon based photodetector of claim 3, wherein the first doped region and second doped region respectively extend into the first slab portion and second slab portion.

5. The silicon based photodetector of claim 4, wherein the first electrode and second electrode respectively contact the first doped region and second doped region in portions of the first doped region and second doped region which are within the respective slab portions.

6. The silicon based photodetector of any preceding claim, having an operating wavelength of at least 1.3 pm.

7. The silicon based photodetector of any preceding claim, having an operating wavelength of at least 1.55 pm.

8. The silicon based photodetector of any preceding claim, having an operating wavelength of no more than 3.5 pm.

9. The silicon based photodetector of any preceding claim, wherein the germanium tin containing region is formed of Ge₉₃Sn₇.

10. The silicon based photodetector of any of claims 1 - 8, wherein the germanium tin containing region is formed of Ge₉₀Sn₁₀.

11. The silicon based photodetector of any preceding claim, wherein a width of the germanium tin containing region, as measured in a direction perpendicular to the guiding direction of the waveguide and parallel to a surface of the substrate, which is at least 40% and no more than 60% of a width, as measured in the same direction, of the waveguide region.

12. The silicon based photodetector of any preceding claim, wherein the germanium tin containing region is positioned in the waveguide at a point distal to the buried oxide layer.

13. The silicon based photodetector of any preceding claim, wherein the waveguide has a height, as measured from a surface of the buried oxide layer adjacent the waveguide to a surface of the waveguide distalmost from the buried oxide layer, of at least 2.5 pm and no more than 3.5 pm.

14. The silicon based photodetector of any preceding claim, wherein the waveguide has a width, measured from a first side and a second side of the waveguide which are equidistant from the buried oxide layer, of at least 1.5 pm and no more than 2.5 pm.

15. The silicon based photodetector of any of claims 2 - 14, wherein the first slab portion and the second slab portion have a height, as measured from an uppermost surface of the buried oxide layer to a surface of the respective slab portions distalmost from the buried oxide layer, of at least 0.2 pm and no more than 0.6 pm.

16. The silicon based photodetector of any preceding claim, wherein the germanium tin containing region is formed of essentially pure germanium tin.

17. The silicon based photodetector of any preceding claim, wherein the germanium tin containing region does not contain any silicon.

18. A method of manufacturing a silicon based photodetector, comprising the steps of: providing a silicon substrate, a buried oxide layer above the silicon substrate, and a waveguide above the buried oxide layer;

doping a first region with dopants of a first species to form a first doped region; doping a second region with dopants of a second species to form a second doped region; etching at least a portion of the waveguide, between the first doped region and the second doped regions, to provide cavity therein; and

19. The method of claim 18, wherein depositing the germanium tin is performed through selective epitaxial growth.

20. The method of either claim 18 or claim 19, further comprising a step of passivating the device by depositing a passivating layer over an uppermost surface thereof.

21. The method of any of claims 18 - 20, further comprising a step of depositing a first electrode and a second electrode, respectively in contact with the first doped region and the second doped region.