WO2018178845A1

WO2018178845A1 - A method for the manufacture of reduced graphene oxide from kish graphite

Info

Publication number: WO2018178845A1
Application number: PCT/IB2018/052041
Authority: WO
Inventors: Thi Tan VU; Maria CABANAS CORRALES; Abel ALVAREZ-ALVAREZ
Original assignee: Arcelormittal
Priority date: 2017-03-31
Filing date: 2018-03-26
Publication date: 2018-10-04
Also published as: CN110494391B; US11390529B2; CA3057958A1; EP3601163B1; JP6979082B2; EP3601163A1; RU2741045C1; CN110494391A; BR112019019205A2; KR20190118196A; KR102329015B1; UA125228C2; MX2019011546A; MA49291A; JP2020512263A; CA3057958C; ZA201905839B; AU2018242528B2; AU2018242528A1; ES2884773T3

Abstract

The present invention relates to a method for the manufacture of reduced graphene oxide from Kish graphite.

Description

A method for the manufacture of reduced graphene oxide from Kish graphite

The present invention relates to a method for the manufacture of reduced graphene oxide from Kish graphite. In particular, reduced graphene oxide will have applications in metal industries including steel, aluminum, stainless steel, copper, iron, copper alloys, titanium, cobalt, metal composite, nickel industries, for example as coating or as a cooling reagent.

Kish graphite is a byproduct generated in the steelmaking process, especially during the blast furnace process or iron making process. Indeed, Kish graphite is usually produced on the free surface of molten iron during its cooling. It comes from molten iron at 1300-1500°C, which is cooled at a cooling rate between 0.40°C/min and 25°C/h when transported in the torpedo car or at higher cooling rates during the ladle transfer. An extensive tonnage of Kish graphite is produced annually in a steel plant.

Since Kish graphite comprises a high amount of carbon, usually above 50% by weight, it is a good candidate to produce graphene based materials. Usually, Graphene based materials include: graphene, graphene oxide, reduced graphene oxide or nanographite.

Reduced graphene oxide is composed of one or a few layers of graphene sheets containing some oxygen functional groups. Thanks to its interesting properties such as a high thermal conductivity and a high electrical conductivity, reduced graphene oxide, being hydrophobic, has many applications as mentioned above.

Usually, Reduced graphene oxide is synthesized from kish graphite, the intermediate product being graphene oxide. The method comprises the following steps:

- the synthesis of graphene oxide from kish graphite and

- the reduction of graphene oxide to obtain the reduced graphene oxide

The patent KR101 109961 discloses a method of manufacturing graphene, comprising:

- a step of pretreating Kish graphite,

- a step of manufacturing graphite oxide by oxidizing the pretreated Kish graphite with an acid solution; - a step of manufacturing graphene oxide by exfoliating the graphite oxide and

- a step of manufacturing reduced graphene oxide by reducing the graphene oxide with a reducing agent.

In this Korean patent, the pre-treatment of Kish graphite comprises: a flushing process, a process of purification using a chemical pretreatment composition and a mechanical separation process (separation by size). After the process of purification, the purified Kish graphite is separated by size, the Kish graphite having a particle size of 40 mesh or less, i.e. 420μιη or less, is kept for the manufacture of graphene oxide.

However, the pretreatment of Kish graphite comprises 2 steps using a chemical composition: the flushing step and the process of purification step. In the Example of KR101 109961 , the flushing step is performed with an aqueous solution comprising water, hydrochloric acid and nitric acid. Then, the process of purification is performed with a pretreatment composition comprising a chelating agent, an iron oxide remover, a surfactant, an anionic and nonionic polymer dispersant and distilled water. At industrial scale, two chemical treatments are difficult to manage since a lot of chemical waste has to be treated and the stability of such composition is difficult to control. Moreover, the pretreatment composition needs a long time preparation. The productivity is therefore slowed. Additionally, the pre-treatment of Kish graphite including the process of purification using the pretreatment composition is not environmentally friendly. Finally, in the Example, the reduction of graphene oxide into reduced graphene oxide is very long since it is performed during 24 hours.

The purpose of the invention is to provide an easy to implement method for the manufacture of reduced graphene oxide from high purity Kish graphite. In particular, the object is to provide an environmentally friendly method to obtain reduced graphene oxide having good quality.

This is achieved by providing a method according to claim 1 . The method can also comprise any characteristics of claims 2 to 22 taken alone or in combination.

The invention also covers Pre-treated Kish graphite according to claim 23.

The invention also covers Graphene oxide according to claim 24.

The invention also covers reduced Graphene oxide according to claim 25. The invention also covers the use of reduced graphene oxide obtainable for the deposition on a metallic substrate according to claim 26.

Finally, the invention covers the use of reduced graphene oxide as a cooling reagent according to claim 27.

The following terms are defined:

- Graphene oxide means one or a few layer(s) of graphene comprising at least 25% by weight of oxygen functional groups,

- Reduced graphene oxide means graphene oxide that has been reduced. The reduced graphene oxide comprises one or a few layer(s) of graphene having less than 25% by weight of oxygen functional groups,

- Oxygen functional groups means ketone groups, carboxyl groups, epoxy groups and hydroxyl groups and

- A flotation step means a process for selectively separating Kish graphite which is hydrophobic material from hydrophilic materials.

Other characteristics and advantages of the invention will become apparent from the following detailed description of the invention.

To illustrate the invention, various embodiments and trials of non-limiting examples will be described, particularly with reference to the following Figures:

Figure 1 illustrates an example of one layer of reduced graphene oxide according to the present invention.

Figure 2 illustrates an example of a few layers of reduced graphene oxide according to the present invention.

The invention relates to a method for the manufacture of reduced graphene oxide from kish graphite comprising:

A. The provision of kish graphite,

B. A pre-treatment step of said kish graphite comprising the following successive sub-steps:

i. A sieving step wherein the kish graphite is classified by size as follows:

a) Kish graphite having a size below 50μιη,

b) Kish graphite having a size above or equal to 50μιη, the fraction a) of kish graphite having a size below 50 μιη being removed,

ii. A flotation step with the fraction b) of kish graphite having a size above or equal to 50μιη,

iii. An acid leaching step wherein an acid is added so that the ratio in weight (acid amount)/(kish graphite amount) is between 0.25 and 1 .0,

iv. Optionally, the kish graphite is washed and dried,

C. An oxidation step of the pre-treated kish-graphite obtained after step B) in order to obtain graphene oxide and

D. A reduction of graphene oxide into reduced graphene oxide.

Without willing to be bound by any theory, it seems that the method according to the present invention allows for the production of graphene oxide having good quality from high purity pre-treated Kish graphite. Indeed, the Kish graphite obtained after step B) has a purity of at least 90%. Moreover, the pre- treatment step B) is easy to implement at industrial scale and is more environmentally friendly than conventional methods.

Preferably, in step A), the Kish graphite is a residue of the steelmaking process. For example, it can be found in a blast furnace plant, in an iron making plant, in the torpedo car and during ladle transfer.

In step B.i), the sieving step can be performed with a sieving machine.

After the sieving, the fraction a) of Kish graphite having a size below 50 μιη is removed. Indeed, without willing to bound by any theory, it is believed that the kish graphite having a size below 50μιη contains a very small quantity of graphite, for example less than 10%.

Preferably in step B.ii), the flotation step is performed with a flotation reagent in an aqueous solution. For example, the flotation reagent is a frother selected from among: methyl isobutyl carbinol (MIBC), pine oil, polyglycols, xylenol, S-benzyl-S'-n-butyl trithiocarbonate , S,S'-dimethyl trithiocarbonate and S- ethyl-S'-methyl trithiocarbonate. Advantageously, the flotation step is performed using a flotation device. Preferably, in step B.i), the fraction a) of kish graphite having a size below 55 μιη is removed and in step B.ii), the fraction b) of kish graphite has a size above or equal to 55μιη. More preferably, in step B.i), the fraction a) of kish graphite having a size below 60 μιη is removed and wherein in step B.ii), the fraction b) of kish graphite has a size above or equal to 60μιη.

Preferably, in steps B.i) and B.ii), the fraction b) of kish graphite has a size below or equal to 300 μιη, any fraction of kish graphite having a size above 300 μιη being removed before step B.ii).

More preferably in steps B.i) and B.ii), the fraction b) of kish graphite has a size below or equal to 275 μιη, any fraction of kish graphite having a size above 275 μιη being removed before step B.ii).

Advantageously, in steps B.i) and B.ii), the fraction b) of kish graphite has a size below or equal to 250 μιη, any fraction of kish graphite having a size above 250 μιη being removed before step B.ii).

In step B.iii), the ratio in weight (acid amount)/(kish graphite amount) is between 0.25 and 1 .0, advantageously between 0.25 and 0.9, more preferably between 0.25 and 0.8. For example, the (acid amount)/(kish graphite amount) ratio in weight is between 0.4 and 1 .0, between 0.4 and 0.9 or between 0.4 and 1 . Indeed, without willing to be bound by any theory, it seems that if the (acid amount)/(kish graphite amount) ratio is below the range of the present invention, there is a risk that the kish graphite comprises a lot of impurities. Moreover, it is believed that if the (acid amount)/(kish graphite amount) ratio is above the range of the present invention, there is a risk that a huge amount of chemical waste is generated.

Preferably, in step B.iii), the acid is selected among the following elements: chloride acid, phosphoric acid, sulfuric acid, nitric acid or a mixture thereof.

The pre-treated Kish graphite obtained after step B) of the method according to the present invention has a size above or equal to 50μιη. The pre- treated Kish graphite has a high purity, i.e. at least of 90%. Moreover, the degree of crystallinity is improved compared to conventional methods allowing higher thermal and electrical conductivities and therefore higher quality.

Preferably, step C) comprises the following sub-steps: i. The preparation of a mixture comprising the pre-treated kish- graphite, an acid and optionally sodium nitrate, the mixture being kept at a temperature below 5°C,

ii. The addition of an oxidizing agent into the mixture obtained in step C.i),

iii. After the targeted level of oxidation is reached, the addition of an element to stop the oxidation reaction, iv. Optionally, the separation of graphene oxide from the mixture obtained in step C.iii),

v. Optionally, the washing of the graphene oxide, vi. Optionally, the drying of the graphene oxide and vii. The exfoliation of graphene oxide.

Preferably in step C.i), the acid is selected among the following elements: chloride acid, phosphoric acid, sulfuric acid, nitric acid or a mixture thereof. In a preferred embodiment, the mixture comprises the pre-treated kish-graphite, sulfuric acid and sodium nitrate. In another preferred embodiment, the mixture comprises the pre-treated kish-graphite, sulfuric acid and phosphoric acid.

Preferably in step C.ii), the oxidizing agent is chosen from: sodium permanganate (KMnO₄), H₂O₂, O₃, H₂S₂O₈, H₂SO₅, KNO₃, NaCIO or a mixture thereof. In a preferred embodiment, the oxidizing agent is sodium permanganate.

Then, advantageously in step C.iii), the element used to stop the oxidation reaction is chosen from: an acid, non-deionized water, deionized water, H₂O₂ or a mixture thereof.

In a preferred embodiment, when at least two elements are used to stop the reaction, they are used successively or simultaneously. Preferably, deionized water is used to stop the reaction and then H₂O₂ is used to eliminate the rest of the oxidizing agent. In another preferred embodiment, hydrochloric acid is used to stop the reaction and then H₂O₂ is used to eliminate the rest of the oxidizing agent. In another preferred embodiment, H₂O₂ is used to stop the reaction and eliminate the rest of the oxidizing agent by this following reaction:

2KMnO₄ + H₂O₂+ 3H₂SO₄ = 2MnSO₄ +O₂ + K₂SO₄ + 4H₂O. Without willing to be bound by any theory, it seems that when the element to stop the reaction is added into the mixture, there is a risk that this addition is too exothermic resulting in explosion or splashing. Thus, preferably in step C.iii), the element used to stop the reaction is slowly added into the mixture obtained in step C.ii). More preferably, the mixture obtained in step C.ii) is gradually pumped into the element used to stop the oxidation reaction. For example, the mixture obtained in step C.ii) is gradually pumped into deionized water to stop the reaction.

Optionally in step Civ), graphite oxide is separated from the mixture obtained in step C.iii). Preferably, the graphene oxide is separated by centrifugation, by decantation or filtration.

Optionally in step C.v), graphite oxide is washed. For example, graphene oxide is washed with an element chosen from among: deionized water, non- deionized water, an acid or a mixture thereof. For example, the acid is selected among the following elements: chloride acid, phosphoric acid, sulfuric acid, nitride acid or a mixture thereof.

In a preferred embodiment, steps Civ) and C.v) are performed successively, i.e. step Civ) followed by step C.v). In another preferred embodiment, steps C.v) is performed before Civ).

For example, steps Civ) and C.v) are performed at least two times independently of each other.

Optionally in step C.vi), the graphite oxide is dried, for example with air or at high temperature in the vacuum condition.

Preferably in step C.vii), the exfoliation is performed by using ultrasound or thermal exfoliation. Preferably, the mixture obtained in step C.iii) is exfoliated into one or a few layers of graphene oxide.

After step C), Graphene oxide having an average lateral size between 5 and 50μιτι, preferably between 10 and 40μιη and more preferably between 20 and 35 μιη comprising at least one layer sheet is obtained.

Then, preferably, in step D), the graphene oxide is partially or completely reduced in order to obtain a reduced graphene oxide having from 0.4% to 25% by weight, more preferably from 1 to 20% of oxygen groups.

Preferably, step D) comprises the following sub-steps: i. The reduction of graphene oxide with a reducing agent, ii. The agitation of the mixture obtained in step D.i),

iii. Optionally, the washing of the reduced graphene oxide and iv. Optionally, the drying of the reduced graphene oxide.

In step D.i), preferably, the reducing agent is chosen from: acid ascorbic, urea or hydrazine hydrate. More preferably, the reducing agent is acid ascorbic since the ascorbic acid is more environmentally friendly.

Advantageously, in step D.ii), the mixture is kept at a temperature between 50 and 120°C, more preferably between 60 and 95°C and advantageously between 80 and 95°C. Preferably, the agitation is performed during less 24 hours, more preferably during less than 15 hours and advantageously during 1 to 10 hours.

By applying the method according of the present invention, the reduced graphene oxide having an average lateral size between 5 and 50μιη, preferably between 10 and 40μιη and more preferably between 20 and 35 μιη comprising at least one layer sheet is obtained.

Figure 1 illustrates an example of one layer of reduced graphene oxide according to the present invention. The lateral size means the highest length of the layer through the X axis, the thickness means the height of the layer through the Z axis and the width of the nanoplatelet is illustrated through the Y axis.

Figure 2 illustrates an example of a few layers of reduced graphene oxide according to the present invention. The lateral size means the highest length of the layer through the X axis, the thickness means the height of the layer through the Z axis and the width of the nanoplatelet is illustrated through the Y axis.

The obtained reduced graphene oxide has good quality since it is produced from the pre-treated Kish graphite of the present invention. Moreover, the reduced graphene oxide is hydrophobic, stable at high temperature, due to the loss of most of oxygen functionalities, high thermal and electrical conductivity.

Preferably, reduced graphene oxide is deposited on metallic substrate steel to improve some properties such as corrosion resistance of a metallic substrate.

In another preferred embodiment, reduced graphene oxide is used as cooling reagent. Indeed, graphene oxide can be added to a cooling fluid. Preferably, the cooling fluid can be chosen from among: water, ethylene glycol, ethanol, oil, methanol, silicone, propylene glycol, alkylated aromatics, liquid Ga, liquid In, liquid Sn, potassium formate and a mixture thereof. In this embodiment, the cooling fluid be used to cool down a metallic substrate. For example, the metallic substrate is selected from among: aluminum, stainless steel, copper, iron, copper alloys, titanium, cobalt, metal composite, nickel.

The invention will now be explained in trials carried out for information only. They are not limiting.

Examples:

Trials 1 and 2 were prepared by providing Kish graphite from steelmaking plant. Then, Kish graphite was sieved to be classified by size as follows:

a) Kish graphite having a size below < 63μιη and

b) Kish graphite having a size above or equal to 63μιη.

The fraction a) of Kish graphite having a size below 63 μιη was removed.

For Trial 1 , a flotation step with the fraction b) of Kish graphite having a size above or equal to 63μιη was performed. The flotation step was performed with a Humboldt Wedag flotation machine with MIBC as frother. The following conditions were applied:

- Cell volume (I): 2,

- Rotor speed (rpm): 2000,

- Solid concentration (%): 5-10,

- Frother, type: MIBC,

- Frother, addition (g/T): 40,

- Conditioning time (s): 10 and

- Water conditions: natural pH, room-temperature.

Trials 1 and 2 were then leached with the hydrochloric acid in aqueous solution. Trials were then washed with deionized water and dried in air at 90^Q C.

After, Trials 1 and 2 were mixed with sodium nitrate and sulfuric acid in an ice-bath. Potassium permanganate was slowly added into Trials 1 and 2. Then, mixtures were transferred into water bath and kept at 35°C for 3h to oxidize the Kish graphite.

After 3 hours, Trials were gradually pumped into deionized water. The temperature of mixtures was of 70°C.

After stopping the oxidation reaction, the heat was removed and around 10- 15 mL of H₂O₂ in aqueous solution was added until there was no gas producing and mixtures were stirred 10 minutes to eliminate the rest of H2O2.

Then, Trials were exfoliated using ultrasound in order to obtain one or two layer(s) of graphene oxide. Graphene oxide of Trials 1 and 2 were separated from the mixture by centrifugation, washed with water and dried with air.

L-ascorbic acid were mixed with an aqueous solution of Trials 1 and 2. The reaction mixtures were agitated at 90°C during 3 hours to reduce the graphene oxide sheets.

Trials 1 and 2 were then washed and dried to obtain reduced graphene oxide powder.

Trial 3 is the disclosed Example prepared according to the method of the Korean patent KR101 109961 .

Table 1 shows the results obtained with Trial 1 to 3.

Method Trial 1 * Trial 2 Trial 4 (KR101 109961 )

Origin of Kish graphite Steelmaking plant Steelmaking plant Steel-mill byproduct

P re- Sieving step Done, Kish graphite having Done, Kish graphite having Flushing step Done with a solution of treatment a size above or equal to a size above or equal to HCI and HN03 in water of Kish 63μηι kept 63μηι kept

graphite Flotation step Done Not done Process of Done with a preatment purification using solution comprising a Preatment EDTA salt, Na₂S0₃, composition step surfactant, anionic and nonionic polymer dispersant and distilled water

Acid leaching Done with HCI, (the acid Done with HCI, (the acid Mechanical Done, Kish graphite step amount)/(kish graphite amount)/(kish graphite separation step having a size below or amount) ratio in weight is of amount) ratio in weight is of equal to 40 mesh, i.e.

0.78 1 .26 420μηι, kept

Pre-treated kish graphite 95.5% 74.9% At least 90%

purity

Oxidation preparation Done with H2SO4 and Done with H2S0₄ and Done with H₂S0₄ and NaN0₃ step of the NaN0₃ NaN0₃

mixture

Addition of KMn0₄ KMn0₄ KMn0₄ an oxidizing

agent

Element to Water followed by H2O2 Water followed by H2O2 Water followed by H2O2 stop the

reaction

Exfoliation Ultrasound Ultrasound Ultrasound

Graphene oxide Graphene oxide having an Graphene oxide having an Graphene oxide having an average size average Lateral size from average lateral size from between 12 and 20.5μηι and an average 20 to 35 μηι with purity of 20 to 35 μηι with purity of thickness between 5 and 120 nm 99.5% 99.0%

Reduction step Done with acid ascorbic Done with acid ascorbic Done with hydrazine (N₂H₂) during 3 hours during 3 hours during 24 hours

Reduced graphene oxide Reduced Graphene oxide Reduced Graphene oxide Reduced Graphene oxide having an average having an average Lateral having an average Lateral size between 12-25 μηι and an average size from 20 to 30μηι with size from 20 to 30μηι with thickness of 2-120nm purity of 99.5% and an purity of 99.0% and an

average thickness of 1 - average thickness of 1 -6nm

6nm

^* according to the present invention

The pre-treated kish-graphite obtained with Trial 1 , i.e. by applying the method according to the present invention, have a higher purity compared to Trials 2 and 3. Moreover, the method of Trial 1 is more environmentally friendly than the method used for Trial 3. Finally, the reduced graphene oxide obtained with Trial 1 has a high purity and high quality.

Claims

1 . Method for the manufacture of reduced graphene oxide from kish graphite comprising:

A. The provision of kish graphite,

i. A sieving step wherein the kish graphite is classified by size as follows:

a) Kish graphite having a size below 50μιη,

iv. Optionally, the kish graphite is washed and dried,

D. A reduction of graphene oxide into reduced graphene oxide.

2. Method according to claim 1 , wherein in step B.i), the fraction a) of kish graphite having a size below 55 μιη is removed and in step B.ii), the fraction b) of kish graphite has a size above or equal to 55μιη.

3. Method according to claim 2, wherein in step B.i), the fraction a) of kish graphite having a size below 60 μιη is removed and wherein in step B.ii), the fraction b) of kish graphite has a size above or equal to 60μιη.

4. Method according to claim 3, wherein in steps B.i) and B.ii), the fraction b) of kish graphite has a size below or equal to 300 μιη, any fraction of kish graphite having a size above 300 μιη being removed before step B.ii)

5. Method according to claim 4, wherein in steps B.i) and B.ii), the fraction b) of kish graphite has a size below or equal to 275 μιη, any fraction of kish graphite having a size above 275 μιη being removed before step B.ii)

6. Method according to claim 5, wherein in steps in steps B.i) and B.ii), the fraction b) of kish graphite has a size below or equal to 250 μιη. , any fraction of kish graphite having a size above 250 μιη being removed before step B.ii).

7. Method according to anyone of claims 1 to 6, wherein in step B.iii), the acid amount/kish graphite amount ratio in weight is between 0.25 and 0.9.

8. Method according to claim 7, wherein in step B.iii), the acid amount/kish graphite amount ratio in weight is between 0.25 and 0.8.

9. Method according to anyone of claims 1 to 8, wherein in step B.iii), the acid is selected among the following elements: chloride acid, phosphoric acid, sulfuric acid, nitric acid or a mixture thereof.

10. Method according to anyone of claims 1 to 9, wherein step C) comprises the following sub-steps:

i. The preparation of a mixture comprising the pre-treated kish- graphite, an acid and optionally sodium nitrate, the mixture being kept at a temperature below 5°C, ii. The addition of an oxidizing agent into the mixture obtained in step C.i),

1 1 . Method according to claim 10, wherein in step C.ii), the oxidizing agent is chosen from: sodium permanganate, H₂O₂, O₃, H₂S₂O₈, H₂SO₅, KNO₃, NaCIO or a mixture thereof.

12. Method according to claim 10 or 1 1 , wherein in step C.iii), the element used to stop the oxidation reaction is chosen from: an acid, non-deionized water, deionized water, H₂O₂ or a mixture thereof.

13. Method according to claim 12, wherein when at least two elements are chosen to stop the reaction, they are used successively or simultaneously.

14. Method according to anyone of claims 10 to 13, wherein in step C.iii), the mixture obtained in step C.ii) is gradually pumped into the element used to stop the oxidation reaction.

15. Method according to anyone of claims 10 to 14, wherein in step C.vii), the exfoliation is performed by using ultrasound or thermal exfoliation.

16. Method according to anyone of claims 10 to 15, wherein in step Civ), the graphene oxide is separated by centrifugation, by decantation or filtration.

17. Method according to anyone of claims 10 to 16, wherein steps Civ) and C.v) are performed at least two times independently of each other.

18. Method according to anyone of claims 10 to 17, wherein in step C.i), the acid is selected among the following elements: chloride acid, phosphoric acid, sulfuric acid, nitric acid or a mixture thereof.

19. Method according to anyone of claims 1 to 18, wherein in step D) comprises the following sub-steps:

i. The reduction of graphene oxide to reduced graphene oxide with a reducing agent,

ii. The agitation of the mixture obtained in step D.i),

20. Method according to claim 19, wherein in step D.i), the acid is chosen from: acid ascorbic, urea or hydrazine hydrate.

21 . Method according to claim 19 or 20, wherein in step D.ii), the mixture is kept at a temperature between 50 and 120°C.

22. Method according to anyone of claims 18 to 21 , wherein in step D.ii), the agitation is performed during less than 24 hours.

23. Pre-treated Kish graphite having an average lateral size above or equal to 50μιη obtainable from the method according to anyone of the claims 1 to 9.

24. Graphene oxide having an average lateral size between 5 and 50 μιη comprising at least one layer sheet obtainable from the method according to anyone of the claims 1 to 18.

25. Reduced graphene oxide having an average lateral size between 5 and 50μιη comprising at least one layer sheet obtainable from the method according to claims 1 to 22.

26. Use of reduced graphene oxide obtainable from the method according to anyone of the claims 1 to 22 or according to claim 25 for the deposition on a metallic substrate.

27. Use of reduced graphene oxide obtainable from the method according to anyone of the claims 1 to 22 or according to claim 25 as a cooling reagent.