WO2012175985A1 - Capsules, apparatus and methods for preparing a beverage - Google Patents
Capsules, apparatus and methods for preparing a beverage Download PDFInfo
- Publication number
- WO2012175985A1 WO2012175985A1 PCT/GB2012/051460 GB2012051460W WO2012175985A1 WO 2012175985 A1 WO2012175985 A1 WO 2012175985A1 GB 2012051460 W GB2012051460 W GB 2012051460W WO 2012175985 A1 WO2012175985 A1 WO 2012175985A1
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- WO
- WIPO (PCT)
- Prior art keywords
- capsule
- beverage
- clamp
- beverage preparation
- chamber
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
- B65D85/804—Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
- B65D85/8043—Packages adapted to allow liquid to pass through the contents
- B65D85/8046—Pods, i.e. closed containers made only of filter paper or similar material
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J31/00—Apparatus for making beverages
- A47J31/14—Coffee or tea-making apparatus with filters placed in or behind pouring spouts
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J31/00—Apparatus for making beverages
- A47J31/24—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure
- A47J31/34—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure
- A47J31/36—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure with mechanical pressure-producing means
- A47J31/3666—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure with mechanical pressure-producing means whereby the loading of the brewing chamber with the brewing material is performed by the user
- A47J31/3676—Cartridges being employed
- A47J31/369—Impermeable cartridges being employed
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J31/00—Apparatus for making beverages
- A47J31/24—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure
- A47J31/34—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure
- A47J31/36—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure with mechanical pressure-producing means
- A47J31/3666—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure with mechanical pressure-producing means whereby the loading of the brewing chamber with the brewing material is performed by the user
- A47J31/3676—Cartridges being employed
- A47J31/369—Impermeable cartridges being employed
- A47J31/3695—Cartridge perforating means for creating the hot water inlet
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J31/00—Apparatus for making beverages
- A47J31/40—Beverage-making apparatus with dispensing means for adding a measured quantity of ingredients, e.g. coffee, water, sugar, cocoa, milk, tea
- A47J31/407—Beverage-making apparatus with dispensing means for adding a measured quantity of ingredients, e.g. coffee, water, sugar, cocoa, milk, tea with ingredient-containing cartridges; Cartridge-perforating means
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J31/00—Apparatus for making beverages
- A47J31/44—Parts or details or accessories of beverage-making apparatus
- A47J31/4403—Constructional details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/52—Details
- B65D75/58—Opening or contents-removing devices added or incorporated during package manufacture
- B65D75/5861—Spouts
- B65D75/5872—Non-integral spouts
- B65D75/5883—Non-integral spouts connected to the package at the sealed junction of two package walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
- B65D85/804—Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
- B65D85/8043—Packages adapted to allow liquid to pass through the contents
- B65D85/8052—Details of the outlet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2575/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes or webs of flexible sheet material, e.g. in folded wrappers
- B65D2575/52—Details
- B65D2575/58—Opening or contents-removing devices added or incorporated during package manufacture
- B65D2575/583—Opening or contents-removing devices added or incorporated during package manufacture the non-integral spout having an elongate cross-sectional shape, e.g. canoe or boat shaped
Definitions
- the present invention relates to capsules, apparatus and methods for the preparation of beverages from capsules containing a beverage preparation ingredient.
- Beverage making systems are known in which the beverage is made by inserting a capsule containing a particulate beverage making ingredient, such as ground coffee, into a beverage making station of a beverage making apparatus.
- the apparatus then injects water into the capsule, where the beverage making ingredient dissolves in, or infuses into, the water to form the beverage.
- the beverage flows out of the capsule through a suitable outlet, which may be simply an opening or perforation in the capsule, or it may comprise an outlet tube that pierces an outlet region of the capsule.
- the capsule may incorporate a filter to prevent passage of solid components such as coffee grounds out of the capsule.
- GB-A-2121762, GB-A-2122881, EP-A-0179641 , EP-A-0247841 and WO-A-9905044 describe capsule-based beverage preparation systems of the type that are now widely used and marketed by Mars Drinks under the registered trade mark FLA VI A®.
- An exemplary embodiment of a FLAVIA® capsule according to the state of the art is shown in Figs. 1, 2a and 2b. Similar capsules are described in JP-A-4142266.
- an exemplary FLAVIA®-type beverage preparation capsule 100 comprises front and back sheets 110, 112 of a liquid- and air-impermeable sheet material permanently bonded together around their top and side edges as described in more detail below.
- the front and back sheets are also bonded together along a bottom edge 120 of the capsule, but this bond is releasable under the effect of heat or pressure inside the capsule.
- the bonding of the bottom edge 120 may be by means of a pressure-sensitive adhesive.
- Within the capsule 100 is a folded web of filter material 130 bonded to the inside walls of the front and back sheets.
- the web of filter material supports a beverage preparation ingredient 150, such as ground coffee or leaf tea.
- the capsule 100 further comprises a nozzle 140 having tubular bore 142.
- the nozzle is inserted into the top edge of the capsule and bonded in airtight fashion to the front and back sheets, the nozzle being flanged to assist in locating the capsule 100 correctly with a beverage preparation machine.
- the nozzle bore is initially sealed by a suitable airtight freshness barrier.
- the capsule 100 is introduced into a FLA VIA® dispensing machine, which comprises a clamp to grip the nozzle under the flange, and a hollow injector tube with a mechanism to insert the hollow injector tube into the nozzle bore, thereby piercing the freshness barrier.
- the dispensing machine further comprises a source of hot water and a pump to inject the hot water through the injector tube into the capsule.
- the beverage preparation ingredient 150 contained in the capsule 100 is mixed with the hot water and a beverage is brewed.
- the bottom seam 120 of the capsule 100 opens under the effect of heat and liquid pressure inside the capsule, and the beverage passes through the filter web 130 and the open bottom of the capsule and is collected in a receptacle located at a receptacle station situated directly below the capsule.
- the sheet of web material 130 is folded to form a W in cross-section supporting the infusible beverage preparation ingredient 150.
- the liquid pressure causes the apex 132 of the W to evert to provide a downwardly convex filter bed as shown in Fig.2b.
- the eversion effect assists in the rupture of the pressure-sensitive seal of the bottom seam 120 to dispense a beverage brewed in the capsule.
- Further details and advantages of the everting filter webs may be found in EP-A-0179641.
- the FLA VIA® capsules and method provide beverages of superior quality, and furthermore provide the advantage of avoiding cross- contamination of the beverage preparation apparatus by successive beverages because the beverage does not contact any part of the apparatus after preparation.
- the capsules typically contain a portion of ground coffee, tightly compacted in a capsule having a frustoconical or oblate spheroid shape and formed from air-and moisture-impermeable material.
- the capsule is inserted into a rigid, metal brewing chamber that is normally shaped to fit around the capsule tightly.
- the brewing chamber has a filter element in its base, means to pierce the underside of the capsule, and means to inject hot water at a pressure of 500-1500 kPa (5-15 bar) into the interior of the capsule to brew espresso coffee.
- Espresso coffee brewing capsules and systems of this type are described, for example, in W093/17932 and W094/02059.
- a drawback of existing espresso brewing capsules is that they are adapted for use with conventional espresso machines that have a rigid brewing cavity dimensioned to receive a bed of coffee of specific dimensions and to apply the necessary pressure to such a bed of coffee. There is limited scope for varying the amount of coffee in the capsule, or for varying the degree of compaction of the coffee bed during brewing.
- a further drawback of the existing espresso systems is cross contamination between the successive brews, since the beverages exiting capsule passes through, and therefore contaminates, the base part of the brewing chamber.
- EP-A-0521186 describes a capsule containing a compressed beverage brewing ingredient, such as ground coffee, for use in espresso-type machines.
- the capsule is deformable to assume the shape of the cavity of whichever espresso machine it is used in. This removes the need for a special adapter to adapt existing espresso machines to the exact shape and configuration of the capsule. Unfortunately, it also means that the coffee in the capsule may be insufficiently compacted for optimal espresso coffee brewing. The problem of cross-contamination by successive brews also exists for this configuration.
- EP-A-0821906 describes methods of beverage brewing in which a vacuum pack containing a beverage brewing ingredient is placed in a clamp, hot water is injected into the vacuum pack through a hollow needle, and the brewed beverage is allowed to escape through a closing seam in the vacuum pack.
- the pack includes a movable plate opposite the closing seam of the vacuum pack that is used to compress the vacuum pack in the clamp before brewing.
- the plates making up the brewing cavity are rigid, flat plates. These plates cannot apply high pressure to squeeze the vacuum pack without risk of bursting the pack.
- WO-A-0219875 describes an apparatus for the brewing of a beverage by transmission of an aqueous fluid through a capsule (capsule) containing a beverage brewing ingredient, said apparatus comprising: one or more injectors to inject the aqueous fluid into the capsule during said brewing; and a clamp for the capsule, said clamp comprising one or more members that are movable to open and close the clamp, said members having inner surfaces which in a closed position of the clamp define a cavity adapted to substantially enclose and support the capsule during said brewing and further adapted to define a beverage exit pathway in a lower part of the cavity, and wherein the inner surface of at least one clamp member comprises at least one deformable region mounted on a support that is movable while the clamp is in said closed position, whereby the shape of said cavity or said exit pathway can be changed while the clamp is in said closed position to provide a desired brewing configuration of the capsule.
- the capsule is suitably a capsule of the FLAVIA® type, optionally with modifications.
- Channelling of liquid through the compressed bed of beverage preparation material during brewing may occur when preparing beverages using capsule-based (i.e. capsule- type) systems, especially where relatively high pressures are required such as in the preparation of espresso and espresso-type beverages.
- This channelling directs the liquid through preferred pathways in the compressed bed of beverage preparation material preventing uniform exposure of the beverage preparation material to the liquid and resulting in wasted beverage preparation material and a beverage having reduced concentration of dissolved or infused material.
- Channelling may occur in particular if the beverage ingredient is not uniformly and/or sufficiently compressed in the clamp prior to and during water injection.
- the present invention provides a beverage preparation capsule containing a beverage preparation ingredient, the beverage capsule comprising a body having side walls formed from one or more substantially air- and liquid-impermeable sheet materials defining a chamber containing a beverage preparation ingredient and further defining an outlet channel having an upstream end in fluid communication with said chamber for escape of beverage from said chamber, wherein at least a region of said outlet channel is filled by a filtration material for filtering said beverage escaping from said chamber.
- the present invention provides a clamp assembly for preparing a beverage from a capsule wherein the capsule has at least one flexible wall, the clamp assembly comprising two or more clamp members, at least one clamp member being movable to open and close the clamp assembly, wherein respective inner walls of said clamp members in a closed position define a chamber adapted to substantially enclose and support the capsule during beverage preparation, the chamber having an inlet region for injection of water and an outlet region for escape of a beverage, wherein said inner wall of at least one of said clamp members comprises a concave base surface for receiving said capsule and one or more pressure pads projecting from said concave base surface in a region proximate to said inlet region for selectively constricting a region of said capsule proximate to said inlet region.
- the present invention provides a beverage preparation apparatus comprising: one or more clamp assemblies according to the present invention; an injector for injecting water into a capsule held inside the clamp assembly; and a pump for pumping said water through said injector at a pressure greater than 1 bar gauge.
- the present invention provides a beverage preparation system comprising a beverage preparation apparatus according to the invention, and further comprising a plurality of beverage preparation capsules according to the invention, wherein said plurality of capsules contain different beverage preparation ingredients, respectively.
- the present invention provides a method of making a beverage comprising inserting a beverage preparation capsule according to the present invention into the clamp assembly of a beverage preparation apparatus according to the present invention such that an outlet of said capsule is pinched between the clamp members in said outlet region; injecting an aqueous liquid into said capsule in said inlet region to produce a beverage in said capsule; and allowing said beverage to escape through said outlet region.
- Figs. 1, 2a and 2b show a FLAVIA® type capsule according to the prior art as hereinbefore described;
- Figure 3 shows a plan view, partially cut away, of a first beverage preparation capsule according to the present invention
- Figure 4 shows a plan view of a second beverage preparation capsule according to the present invention
- Figure 5 shows a plan view of a third beverage preparation capsule according to the present invention.
- Figure 6 shows a plan view of a fourth beverage preparation capsule according to the present invention
- Figure 7 shows a plan view of a fifth beverage preparation capsule according to the present invention
- Figure 8 shows a plan view of a sixth beverage preparation capsule according to the present invention.
- Figures 9A, 9B and 9C show a plan view and longitudinal and lateral cross-sectional views of a seventh beverage preparation capsule according to the present invention
- Figure 10 shows a schematic longitudinal sectional view of a capsule according to the invention being used to prepare a beverage in a clamp according to the invention
- Figure 1 1 shows a transverse sectional view through the outlet region of the capsule and clamp assembly of Fig. 10;
- Figure 12 shows a front view of a clamp member for a clamp assembly according to an embodiment of the present invention
- Figure 13 shows a perspective view of the clamp member of figure 12
- Figure 14 shows a side elevation view of the clamp member of figure 12
- Figure 15 shows a schematic longitudinal cross section of the clamp member of figure 12 through line A;
- Figure 16 shows a schematic horizontal cross section of the clamp member of figure 12 through line B;
- Figure 17 shows a general cut-away view of a beverage preparation machine according to the present invention.
- the present invention provides a beverage preparation capsule containing a beverage preparation ingredient, the beverage capsule comprising a body having side walls formed from one or more substantially air- and liquid-impermeable sheet materials defining a chamber containing a beverage preparation ingredient and further defining an outlet channel having an upstream end in fluid communication with said chamber for escape of beverage from said chamber, wherein at least a region of said outlet channel is filled by a filtration material for filtering said beverage escaping from said chamber.
- capsule refers to a suitably sealed container carrying beverage preparation material, typically particulate material such as ground coffee, comprising at least one wall of flexible sheet material, typically two walls of flexible sheet material, such as the FLA VIA® type capsules described herein above and below.
- body is used herein in its usual sense of a three-dimensional shape including an enclosure for retaining the beverage brewing ingredient. It will be appreciated that the capsule body may be of any suitable shape in plan view, including circular, square, other regular polygons, or trapezoidal.
- the body defines an ingredient chamber in which the beverage preparation ingredient is stored, and in which the beverage is prepared by infusion or dissolution of the beverage preparation ingredient.
- the ingredient chamber is suitably substantially filled by the ingredient, for example at least about 50% of the volume of the chamber is filled by the ingredient.
- the uncompressed volume of the chamber is suitably from about 5ml to about 100ml.
- outlet channel refers to a channel extending from the beverage ingredient chamber, through which the beverage escapes from the chamber during beverage preparation.
- the outlet channel is substantially free of beverage ingredient.
- the outlet channel has a length in the direction of flow of the beverage, and a cross-section perpendicular to that flow.
- the length of the outlet channel is suitably from about 1mm to about 20mm, for example about 5mm to about 10mm.
- the uncompressed mean cross-section area of the outlet channel is substantially less than that of the beverage ingredient chamber, for example the mean uncompressed cross-sectional area of the outlet channel is suitably no more than about 10% of the mean uncompressed cross- sectional area of the beverage ingredient chamber.
- the outlet channel is normally compressed (pinched) during beverage preparation to further reduce its cross-section.
- the mean width of the outlet channel is suitably from about 5mm to about 30mm, for example about 10mm to about 20mm, and the mean uncompressed depth of the outlet channel is less than about 4mm, for example from about 0.4mm to about 2mm.
- the outlet channel is at least partially filled with the filtration material. That is to say, at least a portion of the length of the outlet channel is substantially completely filled with the filtration material, whereby the beverage escaping from the ingredient chamber must pass through filtration material when transiting the outlet channel.
- the filtration material extends along the whole width and length of the outlet channel, whereby the outlet channel is completely filled by the filtration material in use.
- the capsule is suitably a sealed capsule formed from materials that are substantially impermeable to oxygen and moisture in order to preserve the freshness of the beverage ingredient.
- the capsule is substantially shelf stable. That is to say, it may be stored at ambient temperature and atmospheric conditions for a period of at least 3 months, preferably at least one year, without significant deterioration of the contents.
- the basis of operation of the capsules according to the invention is that the beverage is prepared by injection of water into the beverage ingredient chamber where the beverage is formed, and the beverage is filtered as it escapes from the ingredient chamber through the outlet channel.
- the filtration material fills (plugs) at least a portion of the length of the outlet so that the beverage cannot escape from the body without passing through the filter.
- the filtration material generates a back pressure across the outlet channel, whereby high brewing pressures can be maintained inside the ingredient chamber (e.g. for brewing espresso coffee) without excessively fast escape of beverage.
- This back pressure can be regulated or fixed by applying a pinch to the outlet channel to compress the filtration material, thereby varying the liquid escape cross-section through the outlet channel.
- the filtration material is suitably sufficiently compressible, and preferably resilient, to enable control of the liquid escape cross-section by compressing the filtration material.
- the filtration material is in the form of a plug of filtration material located in said outlet channel, and optionally bonded to the side walls in the outlet channel.
- the filtration material is not normally bonded to the wall of the capsule inside the outlet channel.
- the filtration material projects from the outlet channel into the chamber containing the beverage preparation ingredient, and it may also extend downstream of the outlet channel.
- the filtration material may project from about 5mm to about 100mm into the capsule body, suitably from about 10mm to about 50mm into the capsule body.
- the filtration material is in the form of a resilient filtration pad located in the outlet.
- Suitable materials for forming the filter are water-insoluble but suitably hydrophilic, food-acceptable materials.
- they may comprise a liquid- permeable foam material such as a polyurethane foam or an open-cell polyolefm foam.
- the filter comprises or consists essentially of fibers of substantially water- insoluble material, for example a woven or nonwoven fabric.
- the fibers making up the filter may be any suitable food-acceptable fibers such as cellulose fibers, polyolefm fibers or nylon fibers.
- the filter is built up from multiple layers of a conventional beverage filter sheet material, for example the type of material used to form tea or coffee bags.
- the filter would comprise at least 2, for example 3 to 6, stacked layers of the filter material.
- the filter could be made by rolling or folding a single sheet of filter material into multiple layers.
- the filtration material is formed from a single sheet of beverage filter sheet material having opposed edges bonded to the inside of the beverage ingredient chamber and extending into the outlet chamber, with a V-fold located in or below the outlet channel, whereby the filtration plug in the outlet channel is formed by a double thickness of the filter sheet material in the outlet channel.
- the single sheet is bonded across substantially the entire width of the beverage ingredient chamber.
- each capsule body comprises at least one plastics sheet (e.g. thermoformed or injection molded sheet) and/or flexible film material.
- the sheet or flexible film material will usually be a laminate comprising two or more of the following layers: a thermoplastic sealant layer for bonding the sheet to other members of the package; a substantially gas-impermeable barrier layer, which suitably is a metal film such as aluminium film; adhesion layers to improve adhesion between other layers of the laminate; structural layers, for example to provide puncture resistance; and/or a printing substrate layer.
- the structural layers could be made of polyolefins, polyester, nylons, or other polymers as is well known in the art.
- the front and back of the capsule comprise flexible sheets.
- the capsule may comprise or consist essentially of a compostable material.
- compostable signifies that the material is substantially broken down within a few months, suitably within a few weeks, when it is composted. Typically, the capsule is at least about 90% composted within six months, as determined by the method of IS014855, as in EN13432.
- Thermoplastic compostable polymers that could be used for the capsule include polymers and copolymers of lactic acid and glycolic acid, polyhydroxybutyrates, polyvinyl alcohols (PVOH), ethylene vinyl alcohols (EVOH), starch derivatives, cellulose and cellulose derivatives, and mixtures thereof.
- the capsule may comprise two similar or identical sheets of flexible film material bonded together in face-to-face relation to form a flexible film sachet or capsule.
- materials and methods of manufacture are described, for example, in the already-cited patent specifications relating to the FLA VIA capsule system, for example GB-A-2121762, GB-A-2122881, EP-A-0179641, EP-A-0247841 and WO-A-9905044.
- the capsules may comprise a first sheet that has been formed, e.g. by thermoforming, into a cup or bowl shape with a flanged rim, and a second sheet that is bonded across the flanged rim to form the capsule.
- the first sheet may be a relatively stiff thermoplastic sheet that has been thermoformed into a cup or bowl shape with a flanged rim
- the second sheet is a flat sheet, which may be of flexible film material, that is bonded across the flanged rim.
- Suitable capsule embodiments are described for example in the references listed above.
- the body is fomied from front and back sheets, at least one of which is of flexible film material, said first and second sheets being bonded together in face-to-face relation along a top edge and opposed side edges, further comprising a bond between said said front and back sheets and extending across said capsule between said opposed side edges below said top edge, said bond having a gap defining said outlet.
- the capsule is provided with an outlet from the beverage preparation chamber. Beverage prepared in the chamber can escape from the chamber through the outlet.
- the chamber may be defined by bonding the sheets together in face-to-face relation around a margin, and the outlet may be provided by leaving an unbonded region between the sheets in one of the margins.
- the outlet is in the form of an elongate opening in a bottom edge of the chamber, for example a slit.
- the outlet suitably has a length of from about 0.5cm to about 5cm, more suitably from about 1cm to about 3cm.
- the capsule further comprises a downstream (outlet) chamber located in fluid communication with the downstream end of the outlet channel opposite the beverage ingredient chamber.
- the downstream chamber may be formed by bonding together sheets of capsule material in similar fashion to the beverage ingredient chamber.
- the beverage ingredient chamber, the outlet, and the downstream chamber are all formed by bonding together unitary front and back faces of sheet material.
- the downstream chamber is suitably considerably smaller than the beverage ingredient chamber, for example no more than about 25% of the volume of the beverage ingredient chamber.
- the outlet channel and the downstream chamber (where present) are suitably located at an end of the capsule opposite to the locus of liquid injection, e.g. the injection nozzle of the capsule.
- the capsule is suitably substantially axially symmetric (i.e. has two-fold rotation/reflection symmetry about a longitudinal axis), and suitably the injection nozzle (where present), the outlet channel, and the downstream chamber (where present) lie on the longitudinal axis.
- the downstream chamber may function as a conditioning chamber for the beverage exiting the outlet, that is to say a chamber in which bubbles within the liquid can separate from the liquid to form a "crema" on espresso coffee.
- the downstream chamber may comprise one or more conduits for directing the beverage to one or more beverage outlets.
- the downstream chamber may be bifurcated to direct the beverage to two outlets located adjacent to opposite edges of the capsule.
- the downstream chamber may be funnel-shaped to direct the beverage to a single outlet located centrally.
- the beverage outlet from the downstream chamber (or from the outlet channel where no downstream chamber is present) is suitably sealed with a suitable freshness barrier before use to preserve the freshness of the capsule contents.
- freshness barrier refers to a barrier that is substantially impermeable to air or moisture so as to preserve the freshness of the beverage brewing ingredient by preventing ingress of air or moisture through the liquid guide before brewing commences.
- the freshness barrier may be released by an external mechanical force or thermal field applied during brewing.
- the freshness barrier is preferably releasable by the action of pressure and/or hot water from inside the capsule during brewing.
- the freshness barrier may comprise a layer of a sealant that is released by the action of heat and/or moisture, such as an adhesive as described in EP-A-0179641 or W099/05036.
- the capsule further comprises a nozzle through which liquid can be injected into the chamber containing the beverage preparation ingredient.
- the nozzle is suitably a thermoplastic nozzle having a tubular bore for receiving a liquid injector tube from a beverage preparation machine.
- the bore may be cylindrical, or it may have a non-circular cross-section.
- the nozzle may have a single outlet inside the chamber, or it may have a plurality of outlets inside the chamber, for example an outlet manifold for distributing the beverage making liquid within the enclosure.
- the nozzle outlet or outlets may be located at an edge of the capsule, or they may be located more centrally within the enclosure. Suitable nozzles are described in EP-A-0179641 and WO-A- 9905036.
- the inlet end of the nozzle may comprise an annular seat (recess) around the bore for receiving an O-ring on the injection tube to form a pressure-tight seal between the injection tube and the nozzle.
- the nozzle is sealed by a frangible barrier to prevent escape of the beverage preparation ingredient prior to preparation of the beverage.
- the frangible barrier may comprise, or consist essentially of, a thin sheet of film material that can be pierced by a liquid injector tube on a beverage making machine.
- the frangible barrier may be a thermoplastic barrier molded in one piece with the nozzle, and having at least a peripheral region of weakness to enable the barrier to be pierced by a liquid injector tube on a beverage making machine.
- the amount of ingredient contained in the capsules is sufficient for the preparation of one portion of beverage, i.e. in the case of espresso coffee from about 10 to about 250 ml, suitably from about 25ml to about 125ml of beverage.
- the capsule may contain from about 2 g to about 25 g of ground coffee or from about 1 g to about 9 g of leaf tea.
- the capsule In use, as explained further below, the capsule is substantially completely enclosed by, and in contact with, the inner surfaces of the clamp cavity.
- the cavity supports the beverage brewing capsule enclosed within the cavity, thereby enabling high hydrostatic pressures to be developed inside the capsule without bursting the capsule.
- the capsule could be formed with very thin walls, thereby reducing the amount of plastic waste material that remains after brewing.
- the capsule 30 according to the present invention is a modification of the capsule described in EP-A-0179641 and shown in Figs. 1, 2a and 2b. It comprises two flexible laminate sheets. Each laminate sheet comprises an inner thermoplastic sealing film. The front and back sheets are bonded together along edge seams 31, top seam 32 and bottom seam 33. The bonding of the top and side edges is suitably by heat or ultrasonic bonding, to form a permanent weld between the sheets. At least a central region of the bottom seam 33 is bonded with a peelable adhesive that can be released by the action of heat and/or pressure of liquid inside the capsule, and/or assisted by heat applied from outside the capsule. A nozzle 34 is inserted into the top seam 32 of the capsule.
- the nozzle 34 has a central cylindrical bore sealed at the top by membrane 35.
- a further transverse permanently bonded seam 36 between the front and back sheets extends across the capsule intermediate the top and bottom transverse seals to divide the capsule into a beverage ingredient chamber 37 and a downstream beverage collection/conditioning chamber 38.
- the intermediate seam does not extend completely across the capsule.
- An unbonded gap is left in the intermediate seam to provide the outlet channel from the beverage preparation chamber.
- This gap is filled by a filtration element 39 formed by rolling up and flattening a sheet of filter sheet material.
- the filtration element 39 is bonded to the front and back sheets in the gap. The filtration element projects into the beverage preparation chamber 37 so as to increase the area available for filtration and to prevent filter blocking in use.
- the capsule provides an oxygen and moisture-impermeable enclosure for the coffee until the capsule is used.
- the capsule 40 according to this embodiment is similar to that of Fig. 3, but does not include the beverage collecting/conditioning chamber. Instead, the bottom seam 41 of the capsule is a permanently bonded seam having a central gap similar to the gap in the intermediate seam of Fig. 3 so as to provide an outlet from the beverage chamber 43. A filtration element 42 is bonded in the gap.
- These embodiments may require secondary packaging, such as a pouch or capsule, to maintain ingredient freshness before use.
- the capsule 50 according to this embodiment is similar to that of Fig. 3, having a beverage preparation chamber 51, and intermediate seam 52 with a central outlet gap, and a filter element 53 filling the outlet gap.
- the capsule 50 is characterized by a funnel-shaped beverage collecting/conditioning chamber 54 that directs the beverage more accurately into a receptacle such as a cup.
- a releasable seal 55 in the bottom edge of the conditioning chamber 54 similar to the releasable seal in the bottom edge 34 of the embodiment of Fig. 3, maintains freshness of the capsule ingredients before use.
- the capsule 60 according to this embodiment is similar to that of Fig.
- a beverage preparation chamber 61 having a beverage preparation chamber 61, and intermediate seal 62 with a central gap forming the outlet channel from the beverage preparation chamber, and a filter element 63 filling the outlet gap.
- It is characterized by a bifurcated beverage collecting/conditioning chamber 64 that resembles the outlet of a conventional espresso machine.
- the bifurcated collecting/conditioning chamber 64 has two outlets 65, 66 proximate to opposite edges of the capsule. Each outlet 65,66 is sealed by releasable seal in the bottom edge thereof, similar to the releasable seal in the bottom edge 34 of the embodiment of Fig. 3, to maintain freshness of the capsule ingredients before use.
- the bifurcated chamber 64 directs the beverage accurately into a receptacle such as a cup, and furthermore results in a better conditioned foam "crema" on the resulting coffee. That is to say, a crema with a more uniform, small bubble size.
- the capsule 70 is similar to that of Fig. 3, having a beverage preparation chamber 71, and intermediate seal 72 with a central gap forming the outlet channel from the beverage preparation chamber, and a filter element 73 filling the outlet gap. It is characterized by the filtration element 73 that extends into the ingredient chamber 71 for more than half of the height of the ingredient chamber, thereby achieving more efficient collection of beverage from the ingredient chamber.
- the capsule according to this embodiment is similar to that of Fig. 3, having a beverage preparation chamber 81, and intermediate seal 82 with a central gap forming the outlet channel from the beverage preparation chamber, and a filter element filling the outlet gap. It is characterized by very narrow gap (for example about 1mm to about 10mm wide) in the intermediate transverse seal 82.
- the filtration element is H- shaped, having a narrow part 83 that extends through the gap (outlet channel), and wide portions 84,85 above and below the gap. This configuration ensures that the filtration element is physically retained in the outlet channel, and furthermore increases the area for collection of beverage by the filtration element inside the ingredient chamber. Furthermore, the narrow gap may allow better control over back pressure and beverage flow rate through the outlet channel.
- the capsule 90 is similar to that of Fig. 1.
- the capsule 90 is formed from front and back sheets 91,92 of flexible sheet material bonded together by a permanent heat (or ultrasonic) seal along side edges 93,94 and top edge 95.
- An injection nozzle 96 as hereinbefore described is bonded between the front and back sheets in the center of top edge 95 in air-tight fashion.
- the permanent heat seal also extends across a lower part of the capsule spaced from the bottom of the capsule to define the bottom of the beverage ingredient chamber 96 but with a central gap defining the outlet channel 97, as shown in dashed lines in Fig. 9A.
- the permanent heat seal further comprises curved downward extensions 98, 99 on either side of the longitudinal axis of the capsule below the outlet channel 97 defining the lateral edges of the downstream chamber 100.
- the bottom edge 101 of the capsule is sealed with a linear heat-releasable adhesive seal (also shown in dashed lines in Fig. 9A) providing a freshness barrier prior to use of the capsule.
- the width of the downstream chamber is intermediate the width of the beverage ingredient chamber and the narrower outlet channel 97.
- the filtration material in the outlet channel 97 is provided by a single, rectangular sheet of filter material 102 that is V-folded with opposed edges 103,104 bonded to the inside of the front and back sheets 91,92, respectively in similar fashion to the bonding of the filter sheet in the prior art capsules of Figs. 1-2.
- the V-folded filter sheet extends downwardly through the outlet channel 97, with the bottom 105 of the V located towards the bottom of the downstream chamber 100.
- the outlet channel 97 is thereby filled by a double thickness of filter sheet material.
- the permanent heat seal is formed through the V-folded filter sheet so that the front and back sheets 91,92 and the V-folded filter sheet 102 are all bonded together. This is facilitated by the use of a filter sheet containing thermoplastic fibers, such as polypropylene fibers. However, the filter sheet is not bonded to the front and back faces in the outlet region.
- the above capsules can be manufactured using only minor modification of the methods used to make the capsules of GB-A-2121762, GB-A- 2122881, EP-A-0179641, EP-A-0247841 and WO-A-9905044.
- the invention provides a clamp assembly for preparing a beverage from a capsule wherein the capsule has at least one flexible wall, the clamp assembly comprising two or more clamp members, at least one clamp member being movable to open and close the clamp assembly, wherein respective inner walls of said clamp members in a closed position define a chamber adapted to substantially enclose and support the capsule during beverage preparation, the chamber having an inlet region for injection of water and an outlet region for escape of a beverage, wherein said inner wall of at least one of said clamp members comprises a concave base surface for receiving said capsule and one or more pressure pads projecting from said concave base surface in a region proximate to said inlet region for selectively constricting a region of said capsule proximate to said inlet region.
- the clamp comprises one or more rigid base members, more preferably two such rigid base members, that are movable together in face-to-face or clam-shell fashion to grip the capsule.
- the clamp has a clam shell configuration, whereby two concave base members are releasably pivoted together, preferably about a pivot at the bottom of the clamp, to clamp the capsule therebetween.
- One or more clamp inner surface may be formed of, or covered with a material that is conformable but substantially incompressible, for example a resilient material, such as a layer of elastomer.
- the layer of elastomer is from 5 to 25 mm thick and has Shore hardness of from 10 to 60 Shore, preferably from 20 to 50 Shore.
- the resilience of the inner surface of the brewing cavity may differ in different regions of the surface so as to allow the shape of the cavity to change in response to pressure during brewing.
- the clamp assembly is adapted to apply a pinch force to outlet of the capsule so as to achieve an optimum combination of beverage escape rate from the capsule and back pressure to optimize beverage quality and brewing speed.
- the exit region from the brewing chamber may comprise additional clamp members configured to pinch the bottom of the capsule to provide the constriction.
- Various arrangements are suitable, including (a) a fixed-configuration outlet constriction, (b) an adjustable constriction, and/or (c) a biased constriction.
- the clamp assembly in the closed position has internal surfaces in the outlet channel region that define an opening of fixed size and shape that provides the desired degree of compression to the outlet channel of the capsule.
- one clamp member may have a flat surface in this region and the other clamp member may have a flat surface with a channel of the desired dimensions cut into the surface thereof.
- the desired opening in the bottom of the clamp is formed by said channel.
- the fixed gap provided in the bottom of the clamp has a depth of from about 0.4mm to about 0.8mm, and a width of from about 10mm to about 20mm, for example about 15mm. This provides the desired pinch force on the outlet channel of the capsule.
- the size of the opening formed at the bottom of the clamp where the pinch force is applied to the capsule can be adjusted, for example by mounting the appropriate portion of one of the clamp members on a screw.
- the opening is constricted for high- pressure brewing so as to maintain a high back pressure in the ingredient chamber.
- the opening is widened for low-pressure brewing so as to allow a satisfactory flow rate through the outlet channel while keeping the back pressure in the brewing chamber below about 1.5bar.
- At least one of the members providing said pinch has an inner surface in said fluid exit region that is biased to apply a pinch force to a capsule in the chamber.
- the biasing means compensates for variations in pack shape, and also compensates for deformation of the clamp members as the capsule is pressurized by injected water.
- the said inner surface in the fluid exit region may be biased by being supported on a spring,
- the biasing means may be adjustable to vary the bias force.
- beverage preparation systems of the type having a clamp assembly defining a chamber for enclosing a beverage preparation capsule having at least one flexible wall the present inventors have found that improved beverage preparation can be achieved when the surface of one or more of the clamp members comprises one or more pressure pads that protrude into the chamber formed by the clamp assembly when in a closed position.
- the pressure pads assure uniform compression of the beverage ingredient bed inside the capsule.
- the pressure pads may be configured or profiled to optimize the flow of liquid through the beverage ingredient bed.
- the inlet region of the clamp is normally located at a first end of the clamp cavity (also referred to herein as the "upper end") and the outlet region is normally located at the opposite end (also referred to herein as the "lower end”).
- the inlet is suitably located above the outlet, for example substantially directly above the outlet.
- the term “longitudinal” refers to the direction from the inlet end to the outlet end.
- the term “transverse” or “horizontal” herein refers to a direction perpendicular to the longitudinal.
- the term “median line” herein refers to the transverse line located half-way between the inlet and the outlet.
- region proximate to the inlet refers to the region of the clamp cavity located between the median line and the inlet.
- region proximate to the outlet refers to the region of the clamp cavity located between the median line and the outlet.
- the inner surfaces of the clamp members define a chamber for the beverage preparation capsule when the clamp assembly is in a closed position.
- the beverage preparation capsule is supported by and normally substantially completely enclosed by and in contact with the clamp members, thereby enabling high hydrostatic pressures to be developed inside the capsule without bursting the capsule. Indeed, it is envisaged that the capsule could be formed with very thin walls, thereby reducing the amount of plastic waste material that remains after use.
- the one or more pressure pads squeeze an upper part of the enclosed capsule prior to injection of water into the beverage preparation capsule.
- This helps to hold and compress the bed of beverage preparation material (such as coffee) within the capsule, which allows the beverage preparation medium (typically water) to flow uniformly through the bed, thus minimising channelling of liquid through the beverage preparation material during brewing and improving extraction of the beverage preparation material into the beverage preparation medium.
- the pressure pads are resilient. Accordingly, the pressure pads may deform and adjust to compensate for the irregular form of beverage preparation capsules and/or different amounts of ingredient inside the capsules, and may also compensate for variations in pressure during fluid injection thus regulating the hydrostatic pressure within the capsule. This results in a more uniform exposure of the compressed bed of beverage preparation material to the liquid medium (typically water) which improves diffusion. This provides a beverage of increased quality whilst simultaneously reducing waste of beverage preparation material due to channelling.
- this deformability allows the pressure pads to adapt to beverage preparation capsules containing different amounts of ingredients, improving the versatility of the clamp assembly.
- the one or more pressure pads may be formed of, or may be covered with, a material that is conformable but substantially incompressible, for example a resilient material, such as elastomer.
- a resilient material such as elastomer.
- the elastomer has a Shore hardness of from 10 to 60 Shore, preferably from 20 to 50 Shore.
- the one or more pressure pads are formed entirely of a resilient material, such as elastomer.
- the concave base surface of the one or more of the clamp members defining the inner wall of the chamber formed when the clamp assembly is in a closed position is profiled to conform generally to the shape of the capsule.
- This enables the inner surface of the chamber to conform to the outer surface of the beverage preparation capsule and thereby prevent the capsule from bursting when pressurized liquid is injected into the capsule.
- the accurate conformity of the clamp surface to the outer surface of the capsule in use also assists beverage brewing quality by reducing the channelling of liquid through the bed of beverage brewing ingredient, since it promotes uniform compression of the beverage brewing ingredient.
- the pressure pads projecting from the inner surface of the clamp members may be configured to compress the beverage ingredient and to minimise the volume of air or liquid in the beverage preparation capsule during brewing. This advantageously minimises the volume of liquid in the capsule thus assisting in the preparation of more concentrated beverages, such as espresso, by maximising exposure of liquid to the bed and providing a more efficient process of beverage preparation.
- the pressure pad(s) protruding from the inner surface of the clamp members into the chamber formed by the clamp members in a closed position may be of any suitable configuration to achieve the desired object of squeezing out the head space of the capsule and compressing the coffee bed inside the capsule.
- one or more of said pressure pads are of a substantially arcuate transverse and / or longitudinal cross section in the absence of an external force.
- the pressure pads suitably have a rounded (biconvex), cushion-like shape.
- the arcuate pressure pads suitably intersect said concave base surface at a contact angle of from about 2 degrees to about 45 degrees, for example from about 10 degrees to about 30 degrees.
- the arcuate pressure pads suitably have a maximum height (measured from the tangent to the underlying curve of the base surface) of from about 1mm to about 15mm, for example from about 4mm to about 10mm.
- the pressure pads are suitably located principally proximate to the inlet region of the clamp enclosure. That is to say, more than half of the pressure pad volume is located in the upper half of the clamp enclosure. This positioning achieves the objective of squeezing out head space from the capsule and compressing the ingredient bed into the bottom of the capsule. This positioning also allows the profile of the pressure pads to guide the flow of water into the ingredient bed.
- a function of the pressure pads is to squeeze in particular the head space of the capsule so as to eliminate head space inside the capsule and provide a fully compacted ingredient bed inside the capsule.
- at least one of the pressure pads suitably extends close to or even contacting the opposite inside surface of the clamp cavity when the clamp is closed and empty (i.e. does not contain a capsule).
- the apex of at least one of the pressure pads is spaced no more than about 5mm, for example no more than about 2mm from the opposite internal surface of the clamp cavity when the clamp is closed, and it may abut said opposite internal wall. This is effective to pinch a region of the capsule between the pressure pad and the opposite internal wall thus "sealing off said region from liquid flow to achieve the desired liquid flow pathways inside the capsule.
- the pressure pad(s) While squeezing the upper part of the capsule, it remains necessary for the pressure pads to allow passage of liquid to the ingredient bed in the lower part of the capsule. For this reason the pressure pad(s) are suitably profiled in transverse cross-section to define one or more longitudinal channels of lesser height. The liquid can flow through the capsule underneath these channels. Suitably, at least one of the channels is located substantially centrally so as to direct flow centrally onto the ingredient bed.
- the pressure pad(s) may have a generally m-shaped transverse cross-section.
- the one or more pressure pads are elongate in shape and extend generally in a direction from the inlet region towards the outlet region.
- the one or more pressure pads may each independently extend from about 20% to about 80% of the length of the chamber, for example, from about 30% to about 75% of the length of the chamber.
- the pressure pad(s) are located primarily proximate to the inlet region, they may extend beyond the median line of the cavity towards the outlet region.
- a clamp member comprising pressure pads may comprise more than one pressure pad. In some embodiments, from 1 to 10 pressure pads may be present. In another embodiment, from 1 to 4 pressure pads may be present, for example, a clamp member may comprise three pressure pads.
- the clamp members of the present invention may be prepared with the pressure pads integrated with the inner surface of the clamp member as a single-piece structure, such as may be produced by moulding. For example, the inner surface and the pressure pads may be molded in one piece (liner) that is inserted into a recess in the inner side of a rigid base member to form the inner surface of the clamp member.
- the rigid base member suitably includes a circumferential wall ("frame") to enclose the edges of the elastomeric layer to reduce deformation of the layer under pressure.
- the insert piece having the pressure pads may be demountable from the rigid base member. This would enable to the operator to easily interchange the clamp surface and / or the pressure pads, if desired.
- each pressure pad may be affixed to the inner surface of a clamp member as a separate piece.
- the layer containing the pressure pads is constrained by a rigid backing and rigid circumferential edges extending upwardly from the rigid backing around the layer, whereby the layer can support a pressure of 5 to 15 bar on the outer surface of the capsule without excessive deformation.
- a resilient region should extend over the whole part of the inner surface of the clamp that will be in contact with any thin film portion of the capsule. More preferably, a layer of elastomer covers substantially the whole of the inner surface of at least one base member of the clamp that defines the cavity.
- the clamp comprises two generally concave clamp members that can be moved together to close the clamp.
- the pressure pads are present on only one of the members.
- the pressure pads consist of three pillow-like (biconvex) elongate pads extending from the inlet towards the outlet. The pads suitably overlap transversely so as to present a corrugated inner surface.
- the outer pads are of higher profile than the central elongate pad.
- the outer pads abut against the opposite internal surface of the clamp when it is closed, but the central pad does not so abut, thereby defining a liquid flow channel between the outer pads.
- the pads do not extend all the way to the outlet, thereby leaving a space in the outlet region of the clamp cavity into which the beverage ingredient is compressed.
- One or both of the clamp members may include a heater to heat the beverage ingredient inside the capsule before and/or during beverage preparation.
- the heater may, for example, comprise an electric heater element inside or on the surface of one or both of the clamp members.
- one or both of the clamp members may be heated by circulation of hot water or steam through conduits inside the member.
- the heater suitably achieves a temperature of 90-110 °C at the surface of the heated clamp member.
- the heating of the beverage ingredient is desirable in order to provide a constant, optimised extraction temperature, for example about 90°C to 95°C for espresso coffee. In the absence of external heating the thermal energy needed to heat up the beverage ingredient can cause an initial drop in the brewing temperature below optimum values, especially for drinks that require a low-volume of hot water, such as espresso coffee.
- the configuration of the clamp cavity is fixed once the clamp elements have been brought into engagement to clamp the capsule.
- the configuration of the clamp cavity may be varied during the beverage preparation cycle, for example as described in WO-A-0219875, the entire content of which is incorporated herein by reference.
- At least one clamp member comprises at least one deformable region.
- at least one region of a member making up the inner surface of the cavity is not entirely rigid.
- At least one of the inner surfaces making up the clamp cavity comprises a deformable region that permits the shape of that surface, and hence of the cavity or of the exit pathway, to vary under independent control after the clamp has been closed so as to conform to a desired brewing configuration of the capsule.
- This change in the shape of one of the cavity surfaces is usually a change in the curvature of the surface.
- the deformable region may be resilient and/or flexible. The deformable region is mounted on a support that is independently movable while the clamp is in said closed position.
- the support for the deformable region is movable independently of the other clamp members to vary the shape of the cavity.
- This enables the shape and volume of the cavity to be controlled by varying an external force applied to the support, for example a mechanical or hydraulic force.
- the deformable region is located on the same side of the clamp as the pressure pads, and in embodiments the pressure pads are deformable.
- the pressure pads and concave surface are formed integrally from a sheet of elastomer that is mounted about its periphery to a rigid frame.
- the bottom of the frame defines the outlet pinch region as discussed herein.
- Behind the elastomer sheet there is mounted one or more supports to support the sheet of elastomer.
- One or more of the supports is movable to displace the sheet of elastomer.
- the movable support is a piston face abutting the back of the elastomer sheet.
- the deformable region is adapted to abut directly against and compress a region of the surface of the capsule during brewing. This enhances the ability to adapt the cavity to capsules of different sizes, for example for brewing different strengths of beverage with the same amount of brewing liquid.
- the deformable region also enables additional pressure to be applied to the capsule, for example to compact a bed of the beverage brewing ingredient in the capsule during brewing. This, of course, is especially useful for brewing espresso style coffee.
- the ability to deform the brewing cavity in the exit region enables the size of the exit aperture to be controlled, and thereby enables the hydrostatic pressure in the brewing cavity during brewing to be controlled in conjunction with control over the rate of escape of the beverage from the cavity.
- the control over the shape of the clamp cavity provided by the deformable region may be static or dynamic. That is to say, the deformable region may be used to preset the shape of the cavity after the capsule has been clamped but before brewing, and to maintain that shape throughout the brewing step. Alternatively, the shape of the brewing cavity may vary in dynamic fashion during the beverage brewing as described in more detail below.
- Dynamic control over the shape of the brewing cavity and exit region can also be achieved where the deformable region comprises a movable region supported on a fluid reservoir.
- the movable region may be an elastomer sheet defining the concave surface and the pressure pads as described above.
- the fluid reservoir is preferably a liquid reservoir and therefore substantially incompressible.
- the apparatus further comprises a conduit to introduce or remove fluid from the reservoir in order to vary the shape of the cavity during or immediately prior to brewing. Control over the amount of fluid in the reservoir can be achieved, for example, by including a mechanical or electromechanical valve, or even an electrorheological fluid in the conduit.
- the conduit is connected to a pump or other mechanical or electromechanical driving means for introducing or removing fluid from the cavity.
- the apparatus may include means to substantially equalising the pressure of a fluid inside the capsule and in the fluid filled reservoir, so as to minimise stress on the wall of the capsule.
- a further degree of control over the shape of the brewing cavity can be obtained when at least one clamping member comprises a plurality of deformable regions that are mounted on a plurality of independently movable supports.
- the support may be independently mechanically movable, or the deformable regions may comprise a plurality of fluid filled reservoirs supporting a plurality of movable regions as hereinbefore described.
- the contents of the plurality of fluid filled reservoirs may be independently controlled.
- the inner surface of clamp may comprise, in addition to the one or more deformable regions supported on independent supports, at least one region of solid elastomer supported on a rigid base part of the clamp.
- the maximum volume of the brewing cavity when the clamp is in the closed position is in the absence of internal pressure is suitably from about 25cm3 to about 250cm3, more suitably from about 30cm3 to about 150cm3.
- the minimum volume when the side walls are fully compressed is preferably 50% or less of the maximum volume, more preferably 25% or less of the maximum volume.
- the drawing shows a schematic section of a clamp assembly being used in an apparatus according to the invention to prepare a beverage from a capsule according to the invention.
- the clamp comprises left and right clamp shells 110,111.
- the right clamp shell 111 is formed of metal or a hard plastic such as polytetrafluorethylene.
- the left clamp shell 110 has a frame 140 of metal or a hard plastic such as polytetrafluorethylene.
- a sheet 112 of resilient elastomer is bonded to the frame around its periphery 143.
- the sheet 112 is supported by a solid piston face 142 that is movable laterally to press the elastomer sheet 112 forward to a first position where it forms a conformable fit around the capsule 130, or further to one or more second forward positions for compression of the coffee bed before or after brewing.
- the right clamp shell 111 has an electrical heating element 113 embedded therein for pre- heating of the capsule contents.
- the inner surfaces of the shells 110,111 are concave to receive and tightly enclose the capsule during beverage preparation.
- the shells are mounted in parallel and moved directly into abutment by suitable mechanical clamping means such as a vice, lever arm or the like (not shown).
- suitable mechanical clamping means such as a vice, lever arm or the like (not shown).
- the sealed edges 131 of the capsule are gripped by the edges of the clamp shells.
- the bottom of the clamp shells 110,111 is positioned to pinch the intermediate transverse seal 136 and outlet channel of the capsule.
- the downstream chamber 138 of the capsule is therefore positioned outside the clamp during the beverage preparation step.
- the bottom of the clamp shells has elements for applying a controlled pinch force to the outlet channel of the capsule as shown in more detail in Fig. 11.
- the bottom face of the first clamp shell comprises an opening 120 and a piston 121 seated in the opening and capable of reciprocal motion relative to the inside surface of the clamp shell.
- the piston is spring loaded so as to apply a biasing force to the piston to press the front face of the piston against the capsule in the region of the outlet channel with a fixed (but adjustable) force.
- the bottom face of the second clamp shell 111 comprises a shallow recess 124 suitably 0.5-4mm deep situated in the centre of the pinch zone opposite the outlet channel of the capsule.
- the capsule is inserted into the clamp of the beverage brewing machine, where it is gripped by the clamp with sufficient force to resist the pressure of fluid injected into the capsule.
- the capsule is preheated by the heater 1 13 before and during beverage preparation.
- a hollow needle 117 is inserted through the channel in the top of the clamp and into the nozzle bore of the capsule to pierce the membrane seal, and hot water is injected at a pressure of approximately 10 bar gauge to brew coffee inside the capsule.
- An O-ring 116 is fitted in a fixed position on the injection tube and held in said position by flanges on the injection tube for sealing against a complementary annular recess in the top of the capsule nozzle 114.
- the pinch applied to the outlet channel of the capsule is just sufficient to permit the resulting beverage to escape through the outlet channel at the desired rate while maintaining high pressure inside the capsule, without excessive build-up of back pressure in the ingredient chamber.
- the pressure and temperature of the hot coffee in the downstream chamber causes the weakly bonded margin region 133 at the bottom of the capsule to peel apart, releasing the resulting coffee in a controlled fashion.
- the clamp member 200 comprises an outer clamp shell 204 formed of metal or a hard plastic such as polytetrafluorethylene.
- the outer clamp shell 204 has a substantially rectangular recess in an inner side thereof, in which is received a molded integral sheet 205 of resilient solid elastomer to form a capsule-contacting inner surface of the clamp.
- a suitable elastomer is silicone elastomer having a Shore hardness of about 30.
- the inside surface of the elastomer sheet is profiled to tightly enclose the capsule when the clamp is closed for beverage preparation. The profiling of the inside surface is substantially concave to conform to the outer surface of a beverage preparation capsule, with pressure pads as described further below.
- the clamp member has a recess 201 formed in the top of the clamp shell 204 and a cutaway section 202 in the central pressure pad 207 that together form an opening at the top of the clamp assembly dimensioned to enclose the inlet nozzle of the capsule when the clamp assembly is in a closed position, thus defining the inlet region of the chamber.
- the outlet region is defined by a cutaway section 206 in the bottom of the clamp shell and inner surface.
- the inlet region is adapted to allow the injection of water into a beverage preparation capsule enclosed within the chamber formed by two clamp members and the outlet region is adapted to allow the prepared beverage to escape from the bottom of the enclosed capsule and out of the clamp assembly for consumption.
- Three pressure pads 203 and 207 are formed integrally with the rest of the resilient insert 205 and extend longitudinally in a direction from a region proximate to the inlet region 201 / 202 towards the outlet region 206.
- the pressure pads project inwardly from the concave base surface of the resilient member enabling the selective constriction of the region of the capsule proximate to said inlet region.
- all have substantially arcuate longitudinal and transverse cross sections (see Figs 14 and 15 respectively).
- the outer pressure pads 203 have different geometrical dimensions to central pressure pad 207.
- the outer pressure pads 203 are higher than the central pressure pad 207, whereby the outer pressure pads abut against the opposite internal surface of the clamp chamber when closed to direct the flow of water through a gap intermediate the outer pressure pads 203.
- the side view shows in this embodiment the pressure pads 203 and 207 projecting laterally from the cavity of the inner concave base surface 205 to outside of the profile of the outer clamp shell 204.
- the pressure pads may suitably deform to allow two such clamp members 200 to abut in a closed position of a clamp assembly according to the invention.
- the pressure pads are solid projections formed of resilient material.
- the resilient pressure pads may be hollow, whereby a fluid- filled cavity inside one or more of the pressure pads may be inflated to change the shape of the pressure pads before, during, or after beverage preparation in order to achieve compaction of the beverage preparation ingredient before or during beverage preparation and/or dewatering of the ingredient after beverage preparation.
- the clamp base includes one or more channels for pumping fluid into or out of the cavity or cavities, and the apparatus further comprises a source of pressurized fluid, preferably pressurized liquid, for this purpose.
- the present invention provides a beverage preparation apparatus comprising: one or more clamp assemblies according to the present invention; an injector for injecting water into a capsule held inside the clamp assembly; and a pump for pumping said water through said injector at a pressure greater than 1 bar gauge.
- the apparatus suitably comprises an injector tube or tubes for injecting the aqueous fluid into the interior of the capsule when the capsule is held in the brewing cavity.
- the apparatus further comprises a mechanism operatively associated with the clamp to retract the injector tube or tubes when the clamp is opened.
- the injector tube may be inserted into a nozzle on the top of the capsule as described in GB-A-2121762.
- the injector tube suitably communicates with the source of pressurized water through a check valve, such as a ball valve, that opens under pressures greater than for example about 5 bar to allow water to pass through the tube under pressure but that blocks dripping of water from the injector tube when it is not in use, e.g.
- an O-ring is mounted around the injector tube for forming a pressure-tight seal with an inlet nozzle of the capsule as described further below.
- the O-ring may be held in place by a flange or sleeve fixed to the injection tube above and abutting the O-ring.
- the apparatus comprises a pump for supplying water to the injector tube at pressures greater than 5 bar gauge, for example at 10-15 bar gauge.
- a typical pump is a shuttle pump that operates at fixed displacement and fixed speed, whereby the water flow rate decreases as the back pressure increases up to a maximum pressure of typically about 16 bar.
- the apparatus further comprises a heater to supply an aqueous brewing medium such as hot water or steam, suitably hot water at a temperature of suitably about 80 to about 100°C to the pump.
- the apparatus may comprise a pressure sensor to measure the pressure in the liquid inlet line to the capsule in the clamp (the back pressure).
- the apparatus may further comprise control elements to vary the pump output and/or the configuration of the outlet channel region of the clamp in response to the measured back pressure, for example to maintain a substantially constant back pressure during beverage preparation.
- the apparatus may comprise a second clamp assembly for holding a second capsule, an injector for injecting water into a capsule held inside the clamp assembly; and a pump for pumping said water through said injector at a pressure less than about 1 bar gauge.
- the second clamp and injector may, for example, be similar to those described in the aforementioned patent specifications GB-A-2121762, GB-A- 2122881, EP-A-0179641, EP-A-0247841 and WO-A-9905044.
- a single apparatus has clamps adapted, respectively, for high-pressure and low-pressure beverage preparation.
- the first and second clamp assemblies are in a single housing with a single control system and display associated therewith.
- the apparatus may comprise a control system and display programmed to prompt a user to carry out the following sequential steps:
- the prompt (a) directs the user to select from various beverage options, such as filter coffee, filter tea, espresso coffee, or two-component beverages such as cappuccino coffee.
- the prompt to select a beverage may be by means of one or more menu selection screens accessed by soft keys.
- the apparatus may also be programmed to prompt the user to provide a payment before or after said step (a).
- the payment may be by means of a coin-freed mechanism, or a card swipe, or some other automatic debiting procedure provided in the system.
- the display may show a welcome screen, such as a logo or a picture of a cup of coffee, when not in use.
- the apparatus may also be programmed to prompt the user to place a receptacle in a beverage receiving location ("cup station") of the apparatus before said step (a).
- the apparatus may comprise a cup-detect interlock, for example an infrared detector interlock, to block or interrupt the operation of the apparatus if there is no receptacle in a beverage receiving position in the apparatus.
- the control system may be adapted to provide a prompt to the user to insert a cup if no cup is detected in the cup receiving station at any stage of the procedure.
- the control system and display may comprise for example a liquid crystal display and soft key controls.
- the prompt (b) may include mechanically opening the appropriate clamp to permit insertion of a capsule.
- the prompt (b) may include a visual prompt on the display to select a capsule of the type appropriate for that clamp (i.e. a high-pressure capsule according to the present invention for a high-pressure beverage such as espresso coffee, or a conventional FLAVIA capsule for a low-pressure beverage for preparation in the low-pressure clamp).
- the beverage making apparatus may further provide a prompt after prompt (c), to perform the following step: (d) transfer receptacle from a beverage receiving station below the second clamp assembly to a beverage receiving station below the first clamp assembly.
- This prompt would be appropriate, for example, if a two-component beverage is being prepared for example a cappuccino-type beverage comprising a hot foamed dairy component prepared in the second clamp assembly from a whitener/milk capsule, to which is then added a shot of espresso coffee prepared from a coffee capsule in the first clamp assembly.
- the beverage making apparatus comprises a control system and display programmed to prompt a user to carry out the following sequential steps in response to a command to brew a multicomponent beverage: (a) insert a first capsule containing a first beverage brewing ingredient into one of the clamps;
- the apparatus is capable of preparing both beverage components in a single clamp, for example if the clamp assembly according to the invention has an outlet region that can be adjusted to provide a larger opening resulting in low back-pressure in the ingredient chamber for preparation of filter coffee or foamed milk components, followed by a smaller opening to provide a high back-pressure for preparation of an espresso coffee shot.
- the control system and display are programmed to prompt a user to carry out the following sequential steps in response to a command to brew a multicomponent beverage:
- the beverage making apparatus may further provide a final prompt to perform the following step: remove receptacle containing the beverage from the apparatus.
- the beverage making apparatus suitably further comprises a mechanical ejection means for ejecting capsules from the holder after water injection is complete.
- the apparatus further comprises a mechanism operatively associated with the holder to retract the injection tube or tubes when the holder is opened.
- the beverage making apparatus further comprises a water jet-forming nozzle supplied by one of the pumps for directing a jet of water into a liquid in a receptacle in the cup receiving station of one or both clamps to foam the liquid by high-shear mixing of air and liquid when it hits the surface of a liquid in a receptacle.
- the internal cross sectional area of the jet-forming outlet of the nozzle is generally from about 0.2 to about
- the beverage making apparatus further comprises a capsule recognition device in the clamp assembly operatively associated with the control system and the display of the apparatus.
- this device may be a simple bimodal detector, such as a source of UV light and a light detector, for detecting whether a fluorescent region is present on a capsule. More complex capsule recognition devices such as bar code readers or RFID chip detectors are also contemplated.
- the primary purpose of the capsule recognition device is to determine whether the right type of capsule has been inserted into the clamp, i.e. a high-pressure capsule of the kind described in accordance with the present invention for a high pressure brewing clamp, or a low pressure capsule such as the conventional FLAVIA type capsules for a low pressure configuration clamp.
- Fig. 17 shows a general view, partially cut-away, of a beverage making apparatus according to the invention. Visible are the cavity for receiving the beverage capsule with the pillow pads 203 projecting into the cavity. The elastomeric sheet with the pillow pads 203 is supported on movable piston 142. The front clamp shell is hinged at the bottom 221 so that door 220 can pivot outwardly for insertion of a capsule into the capsule cavity.
- Injector 1 17 is mounted on a suitable drive mechanism for automatic retraction and insertion into the capsule.
- O-ring 116 is mounted on a flange on the injector so that it forms a seal against a countersunk top rim 214 of the nozzle holder of the clamp (i.e. in this embodiment the O-ring seals against the top of the clamp, not against the top of the capsule nozzle itself).
- the present invention provides a beverage preparation system comprising a beverage preparation apparatus according to the present invention, and further comprising one or more beverage preparation capsules according to the invention.
- the system comprises both capsules according to the invention (e.g. for preparing espresso shots) and capsules not according to the invention, for low pressure beverage preparations such as filter coffee, filter tea, or hot foamed milk for subsequent addition to an espresso shot to form a cappuccino.
- the capsules not according to the invention are suitably made in accordance with one of the FLAVIA patents identified above.
- the hot foamed milk capsules suitably contain a solid or liquid milk concentrate for example as described in detail in WO-A-02087400.
- the present invention provides a method of making a beverage comprising inserting a beverage preparation capsule according to the invention into the clamp assembly of a beverage preparation apparatus according to the present invention such that the outlet channel of said capsule is pinched between the clamp members in said outlet region; injecting an aqueous liquid into said capsule in said inlet region to produce a beverage in said capsule; and allowing said beverage to escape through said outlet channel and downstream chamber (where present).
- the bottom of the capsule extends through the exit region of the clamp, whereby the beverage exiting the capsule does not contact the clamp. This substantially eliminates cross-contamination between successive beverages prepared in the same clamp.
- the beverage preparation capsule is inserted into the clamp assembly of the beverage brewing machine, where it is gripped by the clamp members with sufficient force to resist the pressure of fluid injected into the capsule.
- the clamp members are mounted in parallel and moved directly into abutment by suitable mechanical clamping means such as a vice, lever arm or the like (not shown).
- suitable mechanical clamping means such as a vice, lever arm or the like (not shown).
- the sealed edges 31 of the capsule are gripped by the edges of the clamp shells.
- An O-ring may be fitted in the clamp above the nozzle for sealing against the water injection tube of the apparatus. Alternatively, the O-ring may be fitted at a fixed position on the injection tube and held in said position by flanges on the injection tube.
- the pressure pads extending along the inner wall of the chamber enclosing the capsule contact and compress the beverage preparation capsule when the clamp is closed around the capsule.
- the compressed bed of coffee (or other ingredient) inside the capsule is profiled by the buffer pads and this has been found to improve the quality of the final beverage, in particular the total extracted solids. This improvement is thought to be due to a reduction in channelling of liquid through the profiled ingredient bed inside the capsule.
- a further advantage of the pressure pads is that they allow the same clamp to be used for capsules containing different amounts of ingredient. Typically, systems of this type use capsules having identical dimensions but containing different amounts of ground coffee to make products of different volumes or strengths.
- the buffer pads enable the clamp effectively to compress capsules containing a range of different ingredient amounts.
- the capsule may be preheated by a heater within the clamp assembly before and during beverage preparation.
- a hollow needle is inserted through the inlet region in the top of the clamp assembly and into the nozzle bore of the capsule to pierce the membrane seal, and hot water is injected at a pressure of approximately 10 bar gauge to brew coffee inside the capsule.
- the pressure and temperature of the hot coffee in the downstream chamber causes the weakly bonded margin region at the bottom of the capsule to peel apart, releasing the resulting coffee from the outlet of the clamp assembly in a controlled fashion.
- the pinch force is just sufficient to permit the resulting beverage to escape through the outlet channel at the desired rate while maintaining high pressure inside the capsule, without excessive build-up of back pressure in the ingredient chamber.
- the aqueous fluid is injected at a pressure of from about 5 to about 15 bar gauge, for example about 10 bar gauge.
- the aqueous fluid is injected at a temperature of from about 88°C to about 98°C, for example about 90°C.
- the liquid may be injected into the capsule at an average rate suitably from about 25 ml/min to about 500 ml/min and more preferably from about 50 to about 150 ml/min.
- the duration of the water injection is suitably from about 10 to about 30 seconds, for example about 12 to about 15 seconds.
- the aqueous fluid consists essentially of water and the brewing ingredient comprises ground coffee. This enables espresso-type coffee to be produced.
- the liquid may be injected in intermittent or pulsed fashion to optimise the organoleptic properties of the product.
- the method may further comprise the step of injecting air into the capsule after brewing to expel residual beverage from the capsule.
- dewatering of the residue may be achieved by compressing the ingredient bed after brewing by moving one or both movable clamp walls inwardly as described above.
- a similar compression of the ingredient (e.g ground coffee) bed may be performed before water injection to consolidate the ingredient bed.
- substantially all steps of the method other than the selection of beverage type and insertion of the capsule into the clamp are performed automatically by the apparatus. It will be appreciated that, for economy of the description, the preferred and alternative features have in some cases been described in relation to only one aspect of the invention even though they are applicable to all of the other aspects. Accordingly, any feature that has been described above in relation to any one aspect of the invention may also be applied to any other aspect of the invention.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Apparatus For Making Beverages (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/128,096 US9687107B2 (en) | 2011-06-24 | 2012-06-22 | Capsules, apparatus and methods for preparing a beverage |
CA2840141A CA2840141C (en) | 2011-06-24 | 2012-06-22 | Capsules, apparatus and methods for preparing a beverage |
EP12731635.4A EP2723222B1 (en) | 2011-06-24 | 2012-06-22 | Capsule and method for preparing a beverage |
BR112013033270A BR112013033270A2 (en) | 2011-06-24 | 2012-06-22 | capsules, apparatus and methods for preparing a drink |
CN201280040791.XA CN104039205B (en) | 2011-06-24 | 2012-06-22 | Capsules, apparatus and methods for preparing a beverage |
JP2014516444A JP2014516749A (en) | 2011-06-24 | 2012-06-22 | Capsule, apparatus and method for preparing a beverage |
RU2014102163/12A RU2592769C2 (en) | 2011-06-24 | 2012-06-22 | Capsule, device and methods for beverage preparation |
US15/633,135 US10543979B2 (en) | 2011-06-24 | 2017-06-26 | Capsules, apparatus and methods for preparing a beverage |
US16/734,054 US11667464B2 (en) | 2011-06-24 | 2020-01-03 | Capsules, apparatus, and methods for preparing a beverage |
US18/205,688 US20230312230A1 (en) | 2011-06-24 | 2023-06-05 | Apparatus for preparing a beverage |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1110848.7 | 2011-06-24 | ||
GBGB1110848.7A GB201110848D0 (en) | 2011-06-24 | 2011-06-24 | Beverage preparation apparatus and method and beverage capsules for use therein |
GB1118571.7 | 2011-10-27 | ||
GBGB1118571.7A GB201118571D0 (en) | 2011-06-24 | 2011-10-27 | Clamp assembly, apparatus and methods for preparing a beverage |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
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US14/128,096 A-371-Of-International US9687107B2 (en) | 2011-06-24 | 2012-06-22 | Capsules, apparatus and methods for preparing a beverage |
US14128096 A-371-Of-International | 2014-06-02 | ||
US15/633,135 Division US10543979B2 (en) | 2011-06-24 | 2017-06-26 | Capsules, apparatus and methods for preparing a beverage |
Publications (1)
Publication Number | Publication Date |
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WO2012175985A1 true WO2012175985A1 (en) | 2012-12-27 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/GB2012/051460 WO2012175985A1 (en) | 2011-06-24 | 2012-06-22 | Capsules, apparatus and methods for preparing a beverage |
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US (4) | US9687107B2 (en) |
EP (2) | EP2723222B1 (en) |
JP (2) | JP2014516749A (en) |
CN (1) | CN104039205B (en) |
BR (1) | BR112013033270A2 (en) |
CA (2) | CA2840141C (en) |
GB (2) | GB201110848D0 (en) |
RU (1) | RU2592769C2 (en) |
WO (1) | WO2012175985A1 (en) |
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CA2840141C (en) | 2020-07-07 |
EP2818085B1 (en) | 2016-07-20 |
RU2592769C2 (en) | 2016-07-27 |
EP2723222A1 (en) | 2014-04-30 |
US20200140189A1 (en) | 2020-05-07 |
CA3078502C (en) | 2022-11-01 |
CA2840141A1 (en) | 2012-12-27 |
EP2723222B1 (en) | 2016-02-10 |
EP2818085A1 (en) | 2014-12-31 |
US10543979B2 (en) | 2020-01-28 |
GB201110848D0 (en) | 2011-08-10 |
US20140287104A1 (en) | 2014-09-25 |
JP6279055B2 (en) | 2018-02-14 |
US11667464B2 (en) | 2023-06-06 |
US20230312230A1 (en) | 2023-10-05 |
GB201118571D0 (en) | 2011-12-07 |
JP2017080417A (en) | 2017-05-18 |
JP2014516749A (en) | 2014-07-17 |
RU2014102163A (en) | 2015-07-27 |
US20170291759A1 (en) | 2017-10-12 |
CA3078502A1 (en) | 2012-12-27 |
CN104039205A (en) | 2014-09-10 |
BR112013033270A2 (en) | 2017-03-01 |
CN104039205B (en) | 2017-02-15 |
US9687107B2 (en) | 2017-06-27 |
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