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WO2008136435A1 - 撥水撥油剤組成物、その製造方法および物品 - Google Patents

撥水撥油剤組成物、その製造方法および物品 Download PDF

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Publication number
WO2008136435A1
WO2008136435A1 PCT/JP2008/058127 JP2008058127W WO2008136435A1 WO 2008136435 A1 WO2008136435 A1 WO 2008136435A1 JP 2008058127 W JP2008058127 W JP 2008058127W WO 2008136435 A1 WO2008136435 A1 WO 2008136435A1
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WO
WIPO (PCT)
Prior art keywords
repellant
oil
water
monomer
composition
Prior art date
Application number
PCT/JP2008/058127
Other languages
English (en)
French (fr)
Inventor
Minako Shimada
Kazunori Sugiyama
Yuichi Ohmori
Original Assignee
Asahi Glass Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Company, Limited filed Critical Asahi Glass Company, Limited
Priority to ES08752161T priority Critical patent/ES2432055T3/es
Priority to CA002681368A priority patent/CA2681368A1/en
Priority to JP2009512996A priority patent/JP5572385B2/ja
Priority to EP08752161.3A priority patent/EP2141212B1/en
Priority to KR20097016372A priority patent/KR101489975B1/ko
Publication of WO2008136435A1 publication Critical patent/WO2008136435A1/ja
Priority to US12/555,377 priority patent/US9115234B2/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/186—Monomers containing fluorine with non-fluorinated comonomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

　物品の表面に、撥水撥油性を付与でき、かつ耐久性（洗濯耐久性および豪雨耐久性）に優れる撥水撥油剤組成物、その製造方法および撥水撥油性を有し、かつ洗濯および豪雨による撥水撥油性の低下が少ない物品を提供する。 　単量体（ａ）に基づく重合単位と単量体（ｂ）に基づく重合単位と単量体（ｃ）に基づく重合単位とを有する共重合体を含む撥水撥油剤組成物。単量体（ａ）：（Ｚ－Ｙ）ｎＸで表される化合物。ただし、Ｚは炭素数が１～６のパーフルオロアルキル基等、Ｙは２価有機基または単結合、ｎは１または２、Ｘは重合性不飽和基である。単量体（ｂ）：ポリフルオロアルキル基を有さず、炭素数が２０～３０のアルキル基を有する（メタ）アクリレート。単量体（ｃ）：塩化ビニリデン。
PCT/JP2008/058127 2007-04-27 2008-04-25 撥水撥油剤組成物、その製造方法および物品 WO2008136435A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ES08752161T ES2432055T3 (es) 2007-04-27 2008-04-25 Composición oleófuga/hidrófuga, método para la producción de la misma, y artículo
CA002681368A CA2681368A1 (en) 2007-04-27 2008-04-25 Water/oil repellent composition, method for production thereof, and article
JP2009512996A JP5572385B2 (ja) 2007-04-27 2008-04-25 撥水撥油剤組成物、その製造方法および物品
EP08752161.3A EP2141212B1 (en) 2007-04-27 2008-04-25 Water-repellant/oil-repellant composition, method for production thereof, and article
KR20097016372A KR101489975B1 (ko) 2007-04-27 2008-04-25 발수 발유제 조성물, 그 제조 방법 및 물품
US12/555,377 US9115234B2 (en) 2007-04-27 2009-09-08 Water/oil repellent composition, method for production thereof, and article

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007120228 2007-04-27
JP2007-120228 2007-04-27

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/555,377 Continuation US9115234B2 (en) 2007-04-27 2009-09-08 Water/oil repellent composition, method for production thereof, and article

Publications (1)

Publication Number Publication Date
WO2008136435A1 true WO2008136435A1 (ja) 2008-11-13

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PCT/JP2008/058127 WO2008136435A1 (ja) 2007-04-27 2008-04-25 撥水撥油剤組成物、その製造方法および物品

Country Status (9)

Country Link
US (1) US9115234B2 (ja)
EP (1) EP2141212B1 (ja)
JP (1) JP5572385B2 (ja)
KR (1) KR101489975B1 (ja)
CN (1) CN101668826A (ja)
CA (1) CA2681368A1 (ja)
ES (1) ES2432055T3 (ja)
TW (1) TWI507514B (ja)
WO (1) WO2008136435A1 (ja)

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WO2009113589A1 (ja) * 2008-03-12 2009-09-17 旭硝子株式会社 共重合体およびその製造方法
WO2010123042A1 (ja) 2009-04-23 2010-10-28 旭硝子株式会社 撥水撥油剤組成物、その製造方法および物品の処理方法
WO2010140668A1 (ja) 2009-06-05 2010-12-09 旭硝子株式会社 撥水撥油剤組成物、その製造方法および物品の処理方法
WO2011078135A1 (ja) 2009-12-25 2011-06-30 旭硝子株式会社 撥水撥油剤組成物、その製造方法および物品の処理方法
EP2351807A1 (en) * 2008-10-24 2011-08-03 Asahi Glass Company, Limited Water-repellent, oil-repellent agent compositions and manufacturing method therefor
WO2012020806A1 (ja) 2010-08-11 2012-02-16 旭硝子株式会社 撥水撥油剤組成物および物品
JPWO2011099534A1 (ja) * 2010-02-15 2013-06-13 旭硝子株式会社 剥離剤組成物
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JP2015085232A (ja) * 2013-10-29 2015-05-07 東洋紡株式会社 耐油性エレクトレットろ材
JP2016500727A (ja) * 2012-10-18 2016-01-14 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ 脂肪酸及びエステルを含有する部分的にフッ素化されたコポリマーエマルジョン
WO2018164140A1 (ja) 2017-03-07 2018-09-13 Ａｇｃ株式会社 撥水撥油性物品、その製造方法及び撥水撥油剤組成物
JP2019167440A (ja) * 2018-03-23 2019-10-03 藤倉化成株式会社 アクリル共重合体、剥離剤組成物及び剥離シート

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WO2009041648A1 (ja) * 2007-09-28 2009-04-02 Asahi Glass Company, Limited 撥水撥油剤組成物および物品
KR101578243B1 (ko) * 2008-06-04 2015-12-16 아사히 가라스 가부시키가이샤 공중합체, 그 제조 방법 및 발수 발유제 조성물
TWI394506B (zh) * 2008-10-13 2013-04-21 Unimicron Technology Corp 多層立體線路的結構及其製作方法
US9290596B2 (en) * 2010-05-27 2016-03-22 The Chemours Company Fc, Llc Solvent-based fluoropolymer additives and their use in coating compositions
US9029452B2 (en) * 2010-05-27 2015-05-12 E I Du Pont De Nemours And Company Fluoropolymer additive for coatings
WO2012020735A1 (ja) * 2010-08-11 2012-02-16 旭硝子株式会社 撥水剤組成物、その製造方法、疎水性基材処理剤組成物および物品
JP6094585B2 (ja) 2012-08-01 2017-03-15 旭硝子株式会社 撥水撥油剤組成物および物品
CN103160177A (zh) * 2013-03-13 2013-06-19 上海大学 具有超疏水性的丙烯酸树脂涂层材料及其制备方法
CN107001917B (zh) 2014-12-17 2019-03-29 Ａｇｃ株式会社 憎水憎油剂组合物、其制造方法及物品

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JPS62138579A (ja) * 1985-12-13 1987-06-22 Nippon Mektron Ltd 撥水撥油剤
JPS62179517A (ja) * 1986-01-23 1987-08-06 イ−・アイ・デユポン・ドウ・ヌム−ル・アンド・カンパニ− はつ油性およびはつ水性共重合体
JP2001098033A (ja) * 1999-09-30 2001-04-10 Asahi Glass Co Ltd 共重合体、撥水撥油剤、および水分散型撥水撥油剤組成物
JP2003520871A (ja) * 2000-01-18 2003-07-08 ナノテックス， エルエルシー コポリマーならびにこれらを含む撥油性および撥水性組成物
WO2002083809A1 (fr) * 2001-04-13 2002-10-24 Asahi Glass Company, Limited Composition hydrofuge et oleofuge
JP2003013364A (ja) * 2001-06-27 2003-01-15 Asahi Glass Co Ltd 撥水撥油剤組成物
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JP5572385B2 (ja) 2014-08-13
KR101489975B1 (ko) 2015-02-04
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JPWO2008136435A1 (ja) 2010-07-29
TW200907039A (en) 2009-02-16
CA2681368A1 (en) 2008-11-13
US9115234B2 (en) 2015-08-25
EP2141212A8 (en) 2010-08-04
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