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WO2003038934A1 - Fuel cell system - Google Patents

Fuel cell system Download PDF

Info

Publication number
WO2003038934A1
WO2003038934A1 PCT/JP2002/011191 JP0211191W WO03038934A1 WO 2003038934 A1 WO2003038934 A1 WO 2003038934A1 JP 0211191 W JP0211191 W JP 0211191W WO 03038934 A1 WO03038934 A1 WO 03038934A1
Authority
WO
WIPO (PCT)
Prior art keywords
fuel cell
solid oxide
electro
gas
reaction
Prior art date
Application number
PCT/JP2002/011191
Other languages
French (fr)
Japanese (ja)
Inventor
Minoru Suzuki
Akihiro Mabuchi
Takeshi Umehara
Original Assignee
Osaka Gas Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osaka Gas Co., Ltd. filed Critical Osaka Gas Co., Ltd.
Priority to JP2003541085A priority Critical patent/JP4450623B2/en
Publication of WO2003038934A1 publication Critical patent/WO2003038934A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2457Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • H01M8/2425High-temperature cells with solid electrolytes
    • H01M8/2432Grouping of unit cells of planar configuration
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/249Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
    • H01M8/2495Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies of fuel cells of different types
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

A fuel cell system includes a solid oxide fuel cell (22) and a second fuel cell (24) performing electro-generating reaction at not higher than 250 degrees C. In a conventional solid oxide fuel cell system, a raw fuel gas such as natural gas is mixed with recycle gas as a part of reaction fuel gas after the electro-generating reaction in the solid oxide fuel cell (22) and passed through a quality modifying reactor (30) before fed to the solid oxide fuel cell (22). Since the electromotive force at a high fuel use ratio is theoretically low, there are problems that the use ratio of the raw fuel gas remains at 80 to 85% and the electro-generating efficiency also remains at a low level. According to the present invention, the reaction fuel gas not used for recycle in the conventional solid oxide fuel cell system is fed to a carbon monooxide shift reactor (32) and then fed to a fuel side of the second fuel cell (24) for performing electro-generating reaction while the raw fuel gas use ratio in the solid oxide fuel cell is set to 65 to 80%, thereby maximizing the electro-generating efficiency.
PCT/JP2002/011191 2001-11-01 2002-10-29 Fuel cell system WO2003038934A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003541085A JP4450623B2 (en) 2001-11-01 2002-10-29 Fuel cell system

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2001336121 2001-11-01
JP2001-336121 2001-11-01
JP2002-11070 2002-01-21
JP2002011070 2002-01-21

Publications (1)

Publication Number Publication Date
WO2003038934A1 true WO2003038934A1 (en) 2003-05-08

Family

ID=26624275

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/011191 WO2003038934A1 (en) 2001-11-01 2002-10-29 Fuel cell system

Country Status (2)

Country Link
JP (1) JP4450623B2 (en)
WO (1) WO2003038934A1 (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005044571A (en) * 2003-07-25 2005-02-17 Kansai Electric Power Co Inc:The Hybrid type fuel cell system
JP2005056777A (en) * 2003-08-07 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005056775A (en) * 2003-08-07 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005056666A (en) * 2003-08-04 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005056735A (en) * 2003-08-06 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005317232A (en) * 2004-04-27 2005-11-10 Tokyo Gas Co Ltd Power generator
JP2007265732A (en) * 2006-03-28 2007-10-11 Tokyo Gas Co Ltd Supply system of electricity and hydrogen
GB2460715A (en) * 2008-06-10 2009-12-16 Itm Power Mini Fuel Cell
KR101314982B1 (en) * 2006-01-17 2013-10-04 삼성에스디아이 주식회사 fuel cell system using butane
JP6084314B1 (en) * 2016-01-26 2017-02-22 東京瓦斯株式会社 Fuel cell system
JP6084265B1 (en) * 2015-09-30 2017-02-22 東京瓦斯株式会社 Fuel cell system
JP6152436B1 (en) * 2016-01-26 2017-06-21 東京瓦斯株式会社 Fuel cell system

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7818969B1 (en) 2009-12-18 2010-10-26 Energyield, Llc Enhanced efficiency turbine
KR101634816B1 (en) * 2010-07-23 2016-06-29 현대중공업 주식회사 Fuel Cell System
JP6228752B2 (en) 2013-04-26 2017-11-08 三菱日立パワーシステムズ株式会社 Power generation system and method for starting power generation system

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0468698A1 (en) * 1990-07-25 1992-01-29 Westinghouse Electric Corporation Electrochemical cell apparatus having an exterior fuel mixer nozzle
JPH0497262A (en) * 1990-08-10 1992-03-30 Sharp Corp Electrophotographic device
JPH08306369A (en) * 1995-04-28 1996-11-22 Matsushita Electric Ind Co Ltd Hybrid fuel cell generating apparatus
JP2001052727A (en) * 1999-08-04 2001-02-23 Mitsubishi Heavy Ind Ltd Power generating system by fuel cell
JP2001106513A (en) * 1999-10-12 2001-04-17 Daikin Ind Ltd Fuel reforming device
JP2001266924A (en) * 2000-03-24 2001-09-28 Tokyo Gas Co Ltd Solid electrolyte fuel cell system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0468698A1 (en) * 1990-07-25 1992-01-29 Westinghouse Electric Corporation Electrochemical cell apparatus having an exterior fuel mixer nozzle
JPH0497262A (en) * 1990-08-10 1992-03-30 Sharp Corp Electrophotographic device
JPH08306369A (en) * 1995-04-28 1996-11-22 Matsushita Electric Ind Co Ltd Hybrid fuel cell generating apparatus
JP2001052727A (en) * 1999-08-04 2001-02-23 Mitsubishi Heavy Ind Ltd Power generating system by fuel cell
JP2001106513A (en) * 1999-10-12 2001-04-17 Daikin Ind Ltd Fuel reforming device
JP2001266924A (en) * 2000-03-24 2001-09-28 Tokyo Gas Co Ltd Solid electrolyte fuel cell system

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4578787B2 (en) * 2003-07-25 2010-11-10 関西電力株式会社 Hybrid fuel cell system
JP2005044571A (en) * 2003-07-25 2005-02-17 Kansai Electric Power Co Inc:The Hybrid type fuel cell system
JP2005056666A (en) * 2003-08-04 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005056735A (en) * 2003-08-06 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005056777A (en) * 2003-08-07 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005056775A (en) * 2003-08-07 2005-03-03 Nippon Telegr & Teleph Corp <Ntt> Fuel cell power generation system
JP2005317232A (en) * 2004-04-27 2005-11-10 Tokyo Gas Co Ltd Power generator
KR101314982B1 (en) * 2006-01-17 2013-10-04 삼성에스디아이 주식회사 fuel cell system using butane
JP2007265732A (en) * 2006-03-28 2007-10-11 Tokyo Gas Co Ltd Supply system of electricity and hydrogen
GB2460715A (en) * 2008-06-10 2009-12-16 Itm Power Mini Fuel Cell
JP6084265B1 (en) * 2015-09-30 2017-02-22 東京瓦斯株式会社 Fuel cell system
JP2017069101A (en) * 2015-09-30 2017-04-06 東京瓦斯株式会社 Fuel cell system
JP6084314B1 (en) * 2016-01-26 2017-02-22 東京瓦斯株式会社 Fuel cell system
JP6152436B1 (en) * 2016-01-26 2017-06-21 東京瓦斯株式会社 Fuel cell system
JP2017134947A (en) * 2016-01-26 2017-08-03 東京瓦斯株式会社 Fuel cell system

Also Published As

Publication number Publication date
JP4450623B2 (en) 2010-04-14
JPWO2003038934A1 (en) 2005-02-24

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