[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

US3620813A - Method of treating workpieces in a treating fluid - Google Patents

Method of treating workpieces in a treating fluid Download PDF

Info

Publication number
US3620813A
US3620813A US774761A US3620813DA US3620813A US 3620813 A US3620813 A US 3620813A US 774761 A US774761 A US 774761A US 3620813D A US3620813D A US 3620813DA US 3620813 A US3620813 A US 3620813A
Authority
US
United States
Prior art keywords
treating fluid
workpiece
stream
treating
conduit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US774761A
Inventor
Louis J Minbiole Jr
John W Neumann
Chester G Clark
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OMI International Corp
Udylite Corp
Original Assignee
Udylite Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Udylite Corp filed Critical Udylite Corp
Application granted granted Critical
Publication of US3620813A publication Critical patent/US3620813A/en
Assigned to OXY METAL INDUSTRIES CORPORATION reassignment OXY METAL INDUSTRIES CORPORATION CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). 4-09-74 Assignors: OXY METAL FINISHING CORPORATION
Assigned to HOOKER CHEMICALS & PLASTICS CORP. reassignment HOOKER CHEMICALS & PLASTICS CORP. MERGER (SEE DOCUMENT FOR DETAILS). Assignors: OXY METAL INDUSTRIES CORPORATION
Assigned to OCCIDENTAL CHEMICAL CORPORATION reassignment OCCIDENTAL CHEMICAL CORPORATION CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). EFFECTIVE MARCH 30, 1982. Assignors: HOOKER CHEMICAS & PLASTICS CORP.
Assigned to OMI INTERNATIONAL CORPORATION reassignment OMI INTERNATIONAL CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: OCCIDENTAL CHEMICAL CORPORATION
Assigned to MANUFACTURERS HANOVER TRUST COMPANY, A CORP OF reassignment MANUFACTURERS HANOVER TRUST COMPANY, A CORP OF SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: INTERNATIONAL CORPORATION, A CORP OF DE
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G49/00Conveying systems characterised by their application for specified purposes not otherwise provided for
    • B65G49/02Conveying systems characterised by their application for specified purposes not otherwise provided for for conveying workpieces through baths of liquid
    • B65G49/04Conveying systems characterised by their application for specified purposes not otherwise provided for for conveying workpieces through baths of liquid the workpieces being immersed and withdrawn by movement in a vertical direction
    • B65G49/0409Conveying systems characterised by their application for specified purposes not otherwise provided for for conveying workpieces through baths of liquid the workpieces being immersed and withdrawn by movement in a vertical direction specially adapted for workpieces of definite length
    • B65G49/0436Conveying systems characterised by their application for specified purposes not otherwise provided for for conveying workpieces through baths of liquid the workpieces being immersed and withdrawn by movement in a vertical direction specially adapted for workpieces of definite length arrangements for conveyance from bath to bath
    • B65G49/0495Conveying systems characterised by their application for specified purposes not otherwise provided for for conveying workpieces through baths of liquid the workpieces being immersed and withdrawn by movement in a vertical direction specially adapted for workpieces of definite length arrangements for conveyance from bath to bath conveying by flows of fluids
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/08Apparatus, e.g. for photomechanical printing surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/16Apparatus for electrolytic coating of small objects in bulk
    • C25D17/28Apparatus for electrolytic coating of small objects in bulk with means for moving the objects individually through the apparatus during treatment

Definitions

  • Mueller ABSTRACT An apparatus and method for simultaneously treating and conveying containerlike workpieces in which the workpieces are introduced and entrained in aligned orientation in a confined stream of a selected treating fluid and are subsequently extracted therefrom and whereafter, if desired, the workpieces are successively introduced into separate succeeding confined streams of alternative selected treating fluids to effect a multiple stage treatment thereof.
  • PATENTEDNB 1 1 3. 620. 8 l 3 sum 1 or 4 VENTORS. 6741/? METHOD OF TREATING WORKPIECES IN A TREATING FLUID CROSS-REFERENCE TO RELATED APPLICATIONS
  • the subject matter of this application is related to that described in copending United States application Ser. No. 774,923, filed Nov. I2, 1968, for Method and Apparatus for Processing workpieces.”
  • plastic materials employed in fabricating such containers glass, and more frequently metals and metal alloys, are employed such as, for example, tin-plated steel, plastic-lined steel, aluminum and aluminum alloys, etc., which are formed on high-speed automatic machines capable of forming such containers in any desired preliminary or final form.
  • Such treatments conventionally comprise various chemical treatments such as, for example, a cleaning treatment to effect removal of contaminating substances from the interior and exterior surfaces thereof, the application of various protective coatings and/or linings to the container, the alteration of the surface characteristics of the container to provide a required physical alteration thereof or a desired decorative appearance, as well as various intermediate treatments such as rinsing, drying and the like.
  • the disadvantages associated with mechanical apparatuses and processes heretofore known for supporting and conveying such containers through a prescribed post-treatment are overcome by providing an apparatus and method which is adaptable to high-speed processing of such containers while concurrently providing for a substantial simplification in the apparatus and a substantial increase in the flexibility and versatility of operation, which heretofore was unattainable in apparatuses and techniques of the types heretofore known.
  • an apparatus comprising an elongated conduit including means for introducing a treating fluid into the conduit for flow therethrough and means for introducing a workpiece container into the treating fluid in a manner so as to effect an entrainment thereof in the stream in a manner to achieve a simultaneous conveyance and treatment of the workpiece during the course of its travel through the conduit.
  • a correlation is provided between the length of the conduit and the velocity of the treating fluid so as to provide the desired duration of treatment of the containers which are thereafter extracted from the conduit at a point downstream from their point of introduction.
  • a multiple-stage treatment of the workpieces can be achieved by successively introducing the containers extracted from one conduit into a next conduit having a separate desired treating fluid therein in a manner so as to provide a multiple-step, sequentially phased treatment of the containers.
  • Each conduit of the apparatus can be formed in any one of a desired variety of shapes so as to provide optimum utilization of plant space, as well as for discharging the containers at the desired location for further processing or handling, as the case may be.
  • FIG. 1 is a schematic plan view of an apparatus constructed in accordance with the preferred embodiments of the present invention consisting of a series of interconnected conduit sections for providing a multiple-stage treatment;
  • FIG. 2 is a perspective view of a typical cylindrical container which is applicable for treatment in accordance with the method and apparatus comprising the present invention
  • FIG. 3 is an enlarged plan view of one section of the apparatus shown in FIG. 1;
  • FIG. 4 is an enlarged longitudinal vertical sectional view of an inductor of a type suitable for introducing a container and the treating fluid into the inlet end of a processing conduit;
  • FIG. 5 is a fragmentary side elevational view partly in section illustrating an alternative satisfactory arrangement in which the inductor is submerged in a treating liquid contained in a reservoir to which the workpiece containers are successively transferred;
  • FIG. 6 is a transverse cross sectional view of a processing conduit of a substantially circular cross sectional configuration
  • FIG. 7 is a transverse cross sectional view of a processing conduit having a substantially square cross sectional configuration
  • FIG. 8 is a transverse cross sectional view of a processing conduit having a substantially triangular cross sectional configuration
  • FIG. 9 is a transverse cross sectional view of a processing conduit provided with a plurality of helical grooves in the interior surface thereof for imparting directional guidance to the treating fluid passing therethrough;
  • FIG. 10 is a transverse cross sectional view of a processing conduit provided with a plurality of helically extending lands along the interior surface thereof for imparting a preselected flow pattern to the treating fluid passing therethrough;
  • FIG. 11 is a transverse vertical sectional view of a processing conduit provided with a supply tube for injecting supplemental treating fluid to the interior of the conduit in a substantially tangential direction, thereby imparting a prescribed flow pattern thereto;
  • FIG. 12 is a longitudinal vertical sectional view of an alternative satisfactory inductor for introducing the workpiece containers and treating fluid into the inlet portion of the processing conduit;
  • FIG. 13 is a vertical transverse sectional view through the inductor shown in FIG. 12 and taken substantially along the line l3l3 thereof;
  • FIG. 14 is a fragmentary side elevational view of the outlet end of a processing conduit and a transfer chute for effecting an extraction of a workpiece from the treating fluid;
  • FIG. 15 is a transverse vertical sectional view through the transfer chute shown in FIG. 14 and taken substantially along the line 15-15 thereof;
  • FIG. 16 is a fragmentary enlarged longitudinal sectional view through one of the tubular rails of the transfer chute shown in FIG. 15 and taken substantially along the line 16 16 thereof;
  • FIG. 17 is a fragmentary side elevational view partly in section of a portion of the processing conduit provided with a booster arrangement for extracting a portion of the treating fluid from the conduit and thereafter returning the extracted portion to the conduit under increased pressure and velocity;
  • FIG. 18 is an alternative arrangement of the booster shown in FIG. 17.
  • FIG. 19 is an alternative arrangement of section F of the apparatus shown in FIG. 1.
  • a processing apparatus is schematically illustrated comprised of six individual sections designated as A through F, inclusive.
  • Each section includes a processing conduit 30 and an inductor 32 at the inlet end thereof for introducing a container to be treated and a separate treating fluid into the conduit for simultaneous conveyance and treatment during its travel through the processing conduit.
  • Each of sections A through E, inclusive is provided with a receptacle or tank 34, which serves as a reservoir for each individual treating fluid which is recirculated from the outlet or discharge end of the processing conduit 30 back to the inductor 32 through a pressurized supply line 36.
  • the outlet end of the processing conduit 30 of one section is connected to the inlet end of the processing conduit of the next adjacent section by means of an arcuate transfer chute 38 providing a continuous uninterrupted transfer of the workpiece containers through the processing apparatus.
  • FIG. 1 The arrangement as schematically illustrated in FIG. 1 is typical of one in which a liquid treating fluid is employed in sections A through E, inclusive, and a gaseous treating fluid, such as air, is employed in section F.
  • a gaseous treating fluid such as air
  • the air is introduced into the inductor 32 of section F by means of an axial compressor 40 connected to a supply duct 42 and the air is subsequently discharged from the outlet end of the processing conduit and may be discharged to the atmosphere or a portion of all thereof may be recirculated as may be desired.
  • the apparatus shown in FIG. 1 is typical of a variety of multiple treatments that can be achieved in a continuous in-line operation employing one or a plurality of interconnected individual processing sections through which the workpieces are sequentially conveyed.
  • the multiple-stage treatment provided by the arrangement of FIG. 1 may consist, for example, of a multiple-stage chemical conversion coating treatment of aluminum containers, such as the cylindrical container 44 shown in FIG. 2, which is integrally formed with a continuous circular cylindrical sidewall and bottom typical of containers used for packaging for beverages of various types.
  • the provision of a conversion-type coating on the internal and external surfaces of the container enhances the resistance of the aluminum container to chemical attack, as well as providing for an improved base for the application of supplemental decorative and/or protective coatings thereto.
  • the versatility of the apparatus and method comprising the present invention enables the apparatus as shown in FIG. 1 to be connected directly to the output end of one or a plurality of fabricating machines for making the containers 44 which are suitably transferred in end-to-end relationship in the direction of the arrow into the inductor 32 of section A, which in turn effects a concurrent cleaning and conveyance of the containers from the fabricating plant area to the treating area disposed remotely therefrom.
  • the treating fluid employed in the processing conduit of section A may comprise any suitable aqueous or organic cleaning solution such as, for example, an acid cleaner having a phosphoric acid or sulfuric acid base incorporating a suitable surface active agent or preferably an alkaline cleaner usually comprising a mixture of alkali metal salts such as sodium salts of carbonates, phosphates, polyphosphates and hydroxides, which are employed in amounts of 0.5 to 4 ounces per gallon and usually range in pH from 9 to l l.
  • the cleaning solution effects a removal of contaminating substances and oxides from the surfaces of the containers, as well as performing a mild surface etching thereof.
  • the length of the processing conduit 30 of section A and the velocity of the cleaning liquid are correlated so as to provide a contact or residence time of the containers with the cleaning liquid for a period of time sufficient to effect a substantially complete removal of the contaminating substances. Conventionally, such cleaning cycles may range from about 10 seconds up to about one minute.
  • the cleaning fluid upon discharge from the outletend of the processing conduit of section A is returned to the reservoir 34 from which it is again recirculated to the inductor through the supply line 36.
  • Section B of the apparatus shown in FIG. I may conveniently comprise a water rinse treatment in which the treating fluid comprises water or deionized water to effect removal of any residual cleaning liquid from the container surfaces, as well as any remaining contaminating substances.
  • the rinsing cycle may consist of one or a plurality of sections rather than the single section B illustrated in FIG. I to provide the appropriate rinsing of the containers.
  • the rinse liquid similarly is returned to the reservoir 34 of section B for recycling through supply line 36 to the inlet end of the processing conduit.
  • a suitable chemical conversion coating treating liquid such as a chromate coating of any of the types well known in the art typically including hexavalent chromium ions in concentrations usually ranging from about 0.2 to about l0 grams per liter and wherein the treating liquid is maintained within a controlled temperature range such as, for example, from about 60 to about l30 F. and at a pH usually ranging from about I to about 3.
  • the aluminum container is retained in the chromate conversion coating treating liquid for a period of time sufficient to form an amorphous corrosion protective film of a desired thickness so as to provide the requisite corrosion protection and/or base for subsequent paints or other organic finishes, as well as a final decorative finish.
  • the length of the process conduit and the velocity of the treating liquid are correlated so as to. provide a treating duration conventionally of at least about one second up to about 12 seconds or greater as may be desired.
  • the treating fluid discharged from the outlet end of the processing conduit of section C, as in the preceding sections, is returned to the receptacleor reservoir 34 for recirculation to the inductor 32 by means of the supply line 36.
  • section D After treatment in section C, the containers are transferred to section D which, in this particular instance, provides a water rinse treatment in which the containers are rinsed in tap water and thereafter are transferred to section E in which they are subjected to a final deionized water rinse. Rinsing times of a length usually ranging from I to 3 seconds are generally acceptable for most purposes.
  • section E After emergence from section E, the treated and rinsed containers are transferred to section F at which a drying operation is performed during the concurrent advance of the containers to a desired remote plant location at which further fabrication and/or container filling operations are performed as desired.
  • the air introduced into section F is preferably heated to accelerate a removal and evaporation of any residuary rinse water from the container surfaces and render them in a sufficiently dry state for further processing.
  • processing conduits may be arranged in any one of a variety of configurations in order to achieve optimum utilization of plant space and to effect a discharge of the workpieces from each section at a desired location either remote or adjacent to their point of entry in that processing conduit.
  • the processing conduits of sections B through E, inclusive are of a generally U-shaped configuration corresponding to a so-called retum-type arrangement wherein the point of introduction of the workpieces at the inlet end of the processing conduit is disposed proximate or adjacent to the point of discharge of the workpieces.
  • the arrangement of the processing conduits of sections A and F are such to provide a desired transfer of the workpieces from their point of introduction to a point disposed remotely therefrom coinciding with a desired location at which further processing or handling thereof is to be performed, thereby minimizing material handling problems and enhancing the efficiency of the operation.
  • the individual processing conduits of each section can extend to different vertically spaced levels to provide an optimum material flow pattern and may additionally extend underground, providing unobstructed plant working areas adjacent to the treating fluid reservoirs for accommodating additional equipment as may be desired.
  • suitable treatments in addition to the specific multiple-stage chemical conversion treatment of aluminum containers can be provided in accordance with the apparatus of the present invention.
  • other chemical treatments typical of those feasible include the application of phosphate coatings, acid pickling, acid etching, electroless coatings, the application of coatings or dyes, such as anodized aluminum surfaces, chemical drying employing solvents such as trichloroethylene and the like.
  • the treating fluids correspondingly may consist of homogenous gases or liquids or may comprise liquid emulsions, fluid suspensions containing solid particles entrained within a liquid or gaseous carrier, as well as two-phase mixtures consisting of gas and/or liquid and/or air.
  • containers as herein employed is intended to broadly encompass generally cupshaped articles having open or closed ends and is intended to encompass such other articles within this general category including, for example, ammunition shell cases, beverage and food containers, pressurized aerosol containers and the like, wherein the longitudinal length to the diameter of the workpiece is such as to facilitate its longitudinal directionally oriented guidance within a conduit for travel therethrough including the arcuate convolutions provided therein.
  • the workpieces may be of any one of a variety of cross sectional configurations other than a circular configuration as typified by the container 44 shown in FIG.
  • 2 may include containers of an elliptical, rectangular, square, triangular or other polygonal or irregular configuration wherein the maximum diameter thereof approaches but is disposed in clearance relationship with respect to the inner surfaces of the processing conduit and wherein the length thereof enables unobstructed directionally oriented travel of such containers through the conduit and the arcuate convolutions formed therein.
  • FIG. 3 A more detailed description of a processing section, such as the processing section C, is shown in FIG. 3.
  • This section which contains the conversion coating treating solution as previously described, includes a centrifugal pump 46 driven by a motor 48 and having an inlet line 50 connecting its suction end to the tank 34 containing the treating fluid.
  • the pressurized treating fluid is transferred through a supply line 52 connected to the discharge side of the pump to the inductor 32 disposed at the inlet side of the processing conduit 30.
  • a section 54 of the processing conduit 30 is of a transparent material such as glass or polymethylmethacrylate, for example, in order to permit a visual inspection of the workpieces and treating fluid passing therethrough.
  • the control of the velocity of treating fluid introduced into the processing conduit and the correlation of the speed of travel of the workpieces in section C with the preceding and succeeding sections can conveniently be achieved within preselected limits by means of a suitable flow measuring device 56 schematically shown in FIG. 3.
  • the flow measuring device may be of any one of the various types well known in the art which are operable for alternatively counting or indicating the rate of workpieces passing through the conduit and/or the longitudinal velocity of the treating fluid passing therethrough to assure the maintenance of an appropriate spacing between successive workpiece containers and a desired net flow rate thereof.
  • the flow measuring device 56 is suitably connected to a control box 58 which incorporates appropriate circuitry including presettable limits of the type well known in the art which are operative to effect a periodic energization of a motorized control valve 60 in the supply line 52 for increasing or decreasing the supply of treating fluid to the inductor 32 to maintain the velocity within the preset limits.
  • the control box 56 can regulate the speed of rotation of the motor 48 to effect appropriate correction of the treating fluid output from the pump 46.
  • the arrangement illustrated in FIG. 3 also illustrates ancillary control devices which can be conveniently incorporated in one or more sections of the apparatus to maintain coordination therebetween, as well as to control each particular treating fluid within a preselected temperature and composition range, thereby assuring uniformity in treatment of the workpiece containers.
  • the temperature of the treating liquid can be maintained in prescribed limits by providing suitable temperature sensing device, such as a thermocouple 62, which senses the temperature of the treating liquid in the reservoir 34 and communicates this information to a control box 64 which in turn regulates the heat or coolant input into a heat exchanger 66 immersed in the treating liquid.
  • the treating fluid can also be maintained in a substantially homogenous condition, as well as assuring uniformity in temperatures, by means of providing a propeller-type agitator 68 extending inwardly of one of the walls of the reservoir 34.
  • composition of the treating liquid can also be automatically maintained within prescribed concentration limits by the provision of an electrode 70 which is immersed in the treating liquid and is operable to continuously or intermittently sense the electrical conductivity of the treating liquid which in turn is a function of the concentration of dissolved constituents therein.
  • Conductivity electrodes of this type are well known in the art and can be conveniently connected to a suitable control box 72 containing circuitry and presettable means for monitoring the electrical conductivity as sensed by the electrode.
  • control box 72 When the solution conductivity falls below a preset limit, indicating that the concentration of the constituents therein is a preselected minimum level, the control box 72 is operative to energize a suitable metering pump 74, effecting the addition of a makeup solution concentrate from a container 76 through a supply line 78 to the treating receptacle 34. Still further control devices can be incorporated in the apparatus to provide constant or intermittent sensing of the several physical and chemical variables and a corresponding correction or control thereof as may be desired to assure consistent uniformity of treatment of successive workpieces transferred through the apparatus section.
  • FIG. 4 A typical inductor constructed in accordance with one embodiment of the present invention for introducing fluid and workpiece containers into the processing conduit is illustrated in detail in FIG. 4.
  • the inductor comprises a tubular sleeve 80 provided with a lining 82 of a low fiction material, such as a polytetrafluoroethylene plastic, disposed along the interior surface thereof and which is formed with an outwardly tapered or bellmouth configuration 84 at the inlet end thereof to facilitate entry and alignment of workpiece containers such as the container 44 illustrated in phantom.
  • the workpiece containers are adapted to be guidably transported to the inlet portion of the inductor by a suitable transfer chute, such as the transfer chutes 38 shown in FIG.
  • a tubular manifold ring 86 is disposed in concentric relationship adjacent to the tapered inlet portion 84 and is formed with an annular nozzle 88 for directing a curtainous conical stream of the pressurized treating fluid inwardly of the tubular sleeve forming a low friction fluid film upon which the workpiece containers 44 are slidably supported during their inward travel into the inductor.
  • the interior of the manifold ring 86 is connected, as schematically shown in FIG. 4, to a supply line 90, which in turn is connected to a suitable pressurized source of the treating fluid such as the pump 92.
  • the tubular sleeve 80 is rigidly supported by a housing 94 which is formed with an annular flange 96 at its outlet end to which a flange 98 is connected which in turn is afiixed to a processing conduit 30 or a suitable extension thereof through which the workpiece containers and treating fluid are conveyed.
  • the lower portion of the housing 94 is formed with a suitable flange 99 to which the supply line 90 is connected for supplying the pressurized treating fluid to the interior of the housing.
  • the tubular sleeve 80 and the inner end of the conduit 30 are fonned with conforming tapered edges at their adjacent ends, defining therebetween an annular tapered nozzle 100, through which the pressurized treating fluid is discharged from the housing into the interior of the processing conduit.
  • the nozzle 100 is formed with a series of angularly disposed vanes 102 which are offset with respect to the longitudinal axis of the conduit 30 such that the treating fluid discharged is in the form of a helix forming a rapidly rotating wall of liquid, indicated in phantom as 104 in FIG. 4, extending around the inner surface of the pipe and including a central vortex indicated at 106.
  • the treating fluid has a combined rotary and longitudinal component whereby the workpiece containers entrained therein are caused to rapidly rotate and travel longitudinally along the processing conduit, effecting a concurrent conveyance and treatment of the surfaces thereof.
  • the turbulence of the vortex of treating fluid formed assures intimate contact with the surfaces of the work piece container, as well as assuring the maintenance of a substantially homogenous treating fluid.
  • inductors as previously described in connection with the apparatus as illustrated in FIGS. 1 and 3 are shown in their conventional position in which they are disposed above the level of the treating solutions contained in receptacles 34. It is also contemplated in accordance with the practice of the present invention that similar type inductors, such as the inductor 108 shown in FIG. 5, can be immersed in and submerged below the level of a treating liquid 110 in a tank 112 to which pressurized treating liquid is supplied through a supply line 114.
  • the workpieces such as the workpiece containers 44, are suitably supplied to the inlet portion of the inductor 108 by meansof transfer chutes, as previously described, or alternatively, by a vertical magazine I16 terminating at a point adjacent to the inlet of the inductor.
  • the inductor 108 may also be of the type as shown in FIG. 4, wherein the high pressure discharge of the treating fluid from the nozzle 100 imposes a suction at the inlet end of the tubular sleeve, which in turn draws a workpiece container inwardly of the inductor, effecting an entrainment and conveyance thereof in the treating liquid.
  • the process conduits may be composed of any one of a variety of suitable materials and may be of any one of a desired cross sectional configuration which may remain constant along the length thereof or may vary as desired in order to obtain the desired fluid flow velocity or flow pattern.
  • Typical variations of cross sectional configuration of processing conduits are those illustrated in FIGS. 6 through 8.
  • a processing conduit 118 is shown in FIG. 6 which is of a substantially circular tubular cross section in which a workpiece container 44, indicated in phantom, is adapted to be concurrently conveyed and treated.
  • a conduit 120 is shown in FIG. 7 which is of a substantially square or rectangular configuration, while a processing conduit 122 is shown in FIG. 8 having a substantially triangular cross sectional shape.
  • the processing conduit 122 may also be provided with corner fillers 124 for effecting a strengthening of the conduit, as well as providing selected variations in the cross-sectional area and fluid flow pattern.
  • the processing conduits or select portions thereof may be made of any one of a variety of suitable materials which are of adequate strength and which are resistant to and compatible with the treating fluids circulated therethrough.
  • all or portions of the processing conduits can include transparent or translucent sections to enable visual inspection of the treating fluid flow pattern and workpiece travel through the processing conduit.
  • various synthetic plastic materials either of a rigid or flexible structure can be satisfactorily employed including, for example, vinyl polymers and copolymers, acrylics, elastomeric polymers, such as rubber and the like.
  • Processing conduits made of transparent acrylic resin, such as polymethylmethacrylate have been found particularly suitable due to their transparency, enabling a visual inspection of the workpieces during their entire course of travel through their processing conduit.
  • the processing conduits can be provided with suitable means along the inner surfaces thereof for providing guidance and variations in the fluid flow patterns during the course of the travel of the treating fluid and workpieces through the conduits.
  • a supplement to the initial helical flow pattern can be provided such as by means of a series of helical grooves I26 formed along and extending in a spiral pattern along the inner surface of a processing conduit 128 as shown in FIG. 9.
  • a series of lands or vanes I30 projecting substantially radially inwardly of the interior surface of a processing conduit 132, as shown in FIG. 10 can be provided which extend in a spiral or helical pattern to provide directional guidance and selected variations in the flow pattern of treating fluid.
  • a conduit 134 is provided at a point intermediate its length with a supply pipe 136 terminating in a wan nozzle 138 for injecting a supplemental quantity of the same treating fluid or different treating fluid into the interior of the conduit in a substantially tangential forwardly inclined direction.
  • This arrangement can serve to effect a pressure or velocity boost of the treating fluid at one or more points disposed downstream from the inlet end portion of the conduit and can further supplement the helical flow pattern of the treating fluid.
  • the axis of the nozzle 138 is oriented so as to impart an appropriate pitch to the helical flow pattern of the fluid passing thereby.
  • FIG. 12 and 13 An alternative satisfactory construction of an inductor is illustrated in FIG. 12 and 13.
  • the inductor comprises a conduit 140 which may be integrally formed with or removably coupled to the processing conduit disposed downstream therefrom.
  • An annular chamber 142 as defined by an exterior hollow housing 144, surrounds a section of a conduit 140 to which pressurized treating fluid is supplied through a flanged connector 146.
  • the left-hand or inlet end of the inductor, as viewed in FIG. 12, is provided with a tapered tubular sleeve 148 having a manifold ring 150 disposed adjacent to the inlet opening of the same type and for the same purposes as the manifold ring 86 previously described in connection with FIG. 4.
  • the conduit 140 enclosed within the housing 144 is formed with a plurality of angularly oriented nozzles 152, the axes of discharge of which are preferably forwardly and tangentially oriented with respect to the longitudinal axis of the conduit so as to impart a helical flow pattern as defined by a rapidly rotating wall of water indicated in phantom having a centrally extending vortex.
  • the discharge of the treating fluid through the plurality of nozzles 152 similarly effects the imposition of a suction at the inlet end portion of the inductor serving to draw workpiece containers inwardly for entrainment in the helically moving treating liquid.
  • the inductor shown in FIG. 4 and inductor shown in FIGS. 12 and 13 can also be employed at one or more points along the length of the processing conduit to effect a boost in the pressure of the treating fluid, as well as to impart or reestablish the desired flow pattern or turbulence of the treating fluid so as to maintain the desired correlation between fluid flow and treatment time.
  • the treating fluid is injected in accordance with the preferred embodiments in the form of a helical vortex
  • the combined effects of internal fluid friction and friction with the surfaces of the conduit and workpieces effects a progressive reduction in the velocity which is generally manifested in an increase in the pitch of the helical flow pattern, as well as a reduction in the diameter of the centrally extending vortex.
  • boosters such as the inductors illustrated in FIG. 4 and 12, at one or a plurality of locations therealong to reestablish the desired treating fluid flow pattern and velocity-pressure relationship.
  • the transfer chute 38 is composed of a plurality of tubular rails 154, which are disposed at circumferentially spaced intervals, forming an open enclosure for guidably receiving the workpiece containers discharged from the outlet end of a processing conduit 156.
  • the open construction of the transfer chute enables the separation and discharge of the treating liquid to pass downwardly in the direction of the arrows into a suitable catch basin or receptacle from which it can be recovered and recirculated to the inlet end of the processing conduit.
  • the open construction also enables a disengagement of the treating fluid from the workpiece containers at the completion of one treatment and preparatory to the next successive treatment or processing step.
  • the tubular rails 154 are retained in appropriate circumferentially spaced position by means of a series of straps 158 which are securely fastened to the rails at longitudinally spaced intervals therealong.
  • the specific number and spacing of the tubular rails can be varied consistent with the particular configuration and size of the workpieces being processed in order to assure appropriate guidance and conveyance of the containers along the transfer chutes.
  • one or more of the tubular rails with a plurality of angularly oriented jets disposed at spaced intervals therealong through which a pressurized gas, such as air,"-is ejected, effecting a propelling of the workpiece containers along the transfer chute.
  • a pressurized gas such as air
  • the formation of a plurality of jets is also effective to maintain the workpiece containers in at least partially spaced relationship with respect to the surfaces of the rails, counteracting any centrifugal forces and thereby minimizing friction therebetween.
  • the supply of the pressurized gas to one or more of the tubular rails can be conveniently achieved by a supply header 162, such as shown in FIG. 15, which is disposed in communication with a source, such as a compressor of the pressurized gas.
  • FIG. 17 which is processing conduit 164 is illustrated, through which the treating fluid, as shown in phantom, is traveling in a helical pattern including a centrally disposed vortex.
  • a manifold 166 defining an annular chamber 168, is disposed in encircling relationship around an upstream section of the process conduit which is formed with a plurality of angularly oriented nozzles 170, through which a portion of the treating fluid is withdrawn into the annular chamber 168.
  • the interior of the manifold 166 is disposed in communication with the suction side of a booster pump 172 to effect a constant withdrawal of the treating fluid from the annular chamber.
  • the pressurized discharge side of the booster pump is connected to a supply line 174 through which the pressurized treating fluid is conveyed to an annular chamber 176 defined by a manifold I78 encircling the processing conduit at a point spaced downstream from the withdrawal manifold I66.
  • the process conduit is formed with a series of angularly oriented nozzles 180, through which the treating fluid is discharged in the desired helical flow pattern into the interior of the conduit, effecting a reestablishment of the desired vortex and an appropriate boost in the pressure and velocity of the fluid passing therealong.
  • FIG. 17 can be employed for adding supplemental treating fluid at a point intermediate the inlet and outlet ends of a processing conduit such as by providing a secondary supply line 182 connected to the suction side of the booster pump 172.
  • FIG. 18 An alternative satisfactory arrangement of the device shown in FIG. 17 is illustrated in FIG. 18 which similarly enables a partial replenishment or replacement of the treating fluid, effecting a boost in its pressure and/or velocity, as well as a reestablishment of the helical flow pattern at a point intermediate the length of a processing conduit.
  • a manifold 184i encircles a processing conduit 186 defining an annular chamber 138 which is disposed in communication with a suction line 190 connected to the suction side of a centrifugal pump 192.
  • the processing conduit I86 disposed within the manifold 184 is formed with a series of angularly oriented nozzles 194, through which the treating fluid is withdrawn from the interior of the processing conduit through the chamber 188 and into the suction line 190.
  • All or a portion of the treating fluid withdrawn is replaced in the processing conduit by means of a pressure line 196 connected to the output side of the pump 192, which is disposed in communication with a chamber 198 defined by a manifold 200 encircling the process conduit 186 at a point upstream from the withdrawal manifold 184.
  • the process conduit 186 disposed within the encircling manifold 200 is provided with a series of angularly oriented discharge nozzles 202, through which the pressurized treating fluid is discharged from the chamber 198 into the interior of the processing conduit, effecting a boost in the pressure and/or velocity thereof, as well as effecting a reestablishment of the helical or other desired flow pattern.
  • FIG. 19 An alternative satisfactory arrangement of processing section F, as illustrated in FIG. 1, is shown in FIG. 19 in which the inductor is located adjacent to the output end 206 of a processing conduit 208 rather than at the inlet end as shown in FIG. 1.
  • an axial compressor 210 is connected by means of a pressure line 212 to an inductor 214 disposed adj. cent to the output end 206 of the processing conduit, imposing a suction or negative pressure along the upstream portion of the processing onduit 208, which is operative to draw workpiece containers. asindicated in phantom, into the inlet end of the processing conduit which is disposed in alignment with a transfer chute 38.
  • the inductor 214 may be of any one of the types previously described which is operative, by an appropriate nozzle arrangement through which the high pressure fluid, such as air, is discharged, to effect an imposition of a reduced pressure in the upstream portion of the processing conduit, causing supplemental air to be drawn inwardly of the inlet end of the conduit, which in turn effects a conveyance or transfer of the workpiece containers therealong.
  • the workpiece containers upon passage through the inductor 214, are advanced outwardly of the outlet end 206 of the conduit by the high pressure air discharged through the inductor and are conveyed by a suitable transfer chute 216 to the next succeeding work station.
  • the processing apparatus and the method comprising the present invention is readily adaptable to a variety of different treating fluids and treating processes in order to effect an appropriate treatment of the workpiece containers.
  • alternative treatments such as electrolytic treatments, coating treatments, mechanical treatments, as well as electromechanical treatments, can also be accomplished by appropriate adjustments in the treating fluids to provide the desired treating action.
  • the workpiece containers are concurrently transferred and treated in the processing conduit while entrained in a confined stream of the treating fluid.
  • the movement of the workpieces is substantially in response to the travel of the treating fluid therealong, which may, in some instances, be supplemented by gravity when all or sections of the processing conduit are oriented in a downwardly inclined direction.
  • supplemental mechanical loading and air jets for example, can be employed to assist in the rapid transfer of the workpieces from one section to the next adjacent process section.
  • the method of treating elongated containerlike workpieces which comprises the steps of forming a confined stream of a treating fluid having a helical flow pattern and a cross-sectional size greater than the cross-sectional size of the workpiece, introducing a workpiece into said stream in longitudinally oriented relationship with respect to the longitudinal direction of travel of said stream effecting a rotation of the workpiece about its longitudinal axis and a longitudinal conveyance of the workpiece and a simultaneous treatment thereof during its travel while entrained in said stream, maintaining the workpiece in said stream for a period of time sufficient to perform a desired treatment thereof, and thereafter extracting the workpiece from said stream of said treating fluid.
  • said treating fluid comprises a cleaning fluid for performing a cleaning treatment of the surfaces of the workpiece.
  • said treating fluid comprises an aqueous rinse solution for performing a rinse treatment of the surfaces of the workpiece.
  • said treating fluid comprises a coating composition for depositing a coating on the surfaces of the workpiece.
  • said treating fluid comprises a chemical conversion coating solution for forming a conversion coating on the surfaces of the workpiece.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Cleaning In General (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

An apparatus and method for simultaneously treating and conveying containerlike workpieces in which the workpieces are introduced and entrained in aligned orientation in a confined stream of a selected treating fluid and are subsequently extracted therefrom and whereafter, if desired, the workpieces are successively introduced into separate succeeding confined streams of alternative selected treating fluids to effect a multiple stage treatment thereof.

Description

United States Patent Inventors Louis J. Minbiole, Jr.
Detroit; Chester G. Clark, Grosse Pointe Woods; John W. Neumann, Birmingham, all 01 Mich.
Appl. No. 774,761
Filed Nov. 12, 1968 Patented Nov. 16, 1971 Assignee The Udylite Corporation METHOD OF TREATING WORKPIECES' IN A TREATING FLUID 22 Claims, 19 Drawing Figs.
U.S. Cl 117/94, 117/95, 117/102 R, 118/7, 118/73, 118/423, 118/429,118/602,134/32,134/34,148/6.15,
Int. Cl B05b 3/04, BOSb 3/02 Field of Search 21/56, 57,
[56] References Cited UNlTED STATES PATENTS 1,252,302 11/1918 Riesenecker 134/32 X 2,760,873 8/1956 Munz 99/214 2,808,344 10/1957 Kaulen eta] 117/94 2,876,132 3/1959 Worden et a1. 117/94 X 3,442,708 5/1969 Huddle 134/25 X 3,446,757 9/1969 Dunn 34/22 Primary ExaminerAlfred L. Leavitt Assistant Examiner-Edward G. Whitby Att0rneysPeter F. Casella and Richard P. Mueller ABSTRACT: An apparatus and method for simultaneously treating and conveying containerlike workpieces in which the workpieces are introduced and entrained in aligned orientation in a confined stream of a selected treating fluid and are subsequently extracted therefrom and whereafter, if desired, the workpieces are successively introduced into separate succeeding confined streams of alternative selected treating fluids to effect a multiple stage treatment thereof.
PATENTEDNB 1 1 3. 620. 8 l 3 sum 1 or 4 VENTORS. 6741/? METHOD OF TREATING WORKPIECES IN A TREATING FLUID CROSS-REFERENCE TO RELATED APPLICATIONS The subject matter of this application is related to that described in copending United States application Ser. No. 774,923, filed Nov. I2, 1968, for Method and Apparatus for Processing workpieces."
BACKGROUND OF THE INVENTION Improvements in the technology of product packaging and distribution has occasioned an increased demand for new materials and fabricating techniques for manufacturing containers of high quality and in quantities sufficient to provide an economical means for packaging a variety of products. Typical of such products are foodstuffs including various beverages which are packaged in sealed containers whereby the contents are kept in a wholesome, palatable condition over prolonged periods of time. The advent and increasing widespread use of pressurized containers for storing and dispensing various products, such as paints, deodorants, insecticides, etc., has also contributed to the impetus in seeking improvements in the fabrication of containers which are of economical cost and high quality. In addition to various plastic materials employed in fabricating such containers, glass, and more frequently metals and metal alloys, are employed such as, for example, tin-plated steel, plastic-lined steel, aluminum and aluminum alloys, etc., which are formed on high-speed automatic machines capable of forming such containers in any desired preliminary or final form.
Due to the stringent requirements imposed on such containers in connection with their strength, cleanliness, resistance to corrosion, deterioration during storage and the like, it has been and is conventional to subject such containers to various post-treatments after a preliminary or final fabrication thereof. Such treatments conventionally comprise various chemical treatments such as, for example, a cleaning treatment to effect removal of contaminating substances from the interior and exterior surfaces thereof, the application of various protective coatings and/or linings to the container, the alteration of the surface characteristics of the container to provide a required physical alteration thereof or a desired decorative appearance, as well as various intermediate treatments such as rinsing, drying and the like. The large number of such containers and the increasing complexity of the post-treatments to which they are subjected has created a heretofore unfilled need for an improved method and apparatus for processing such containers at high production rates and which avoids the time-consuming and costly individual handling of the containers while concurrently assuring careful control of the post-treatment to which each container is subjected.
In accordance with the method and apparatus comprising the present invention, the disadvantages associated with mechanical apparatuses and processes heretofore known for supporting and conveying such containers through a prescribed post-treatment are overcome by providing an apparatus and method which is adaptable to high-speed processing of such containers while concurrently providing for a substantial simplification in the apparatus and a substantial increase in the flexibility and versatility of operation, which heretofore was unattainable in apparatuses and techniques of the types heretofore known.
SUMMARY OF THE INVENTION The advantages and benefits of the present invention are achieved by an apparatus comprising an elongated conduit including means for introducing a treating fluid into the conduit for flow therethrough and means for introducing a workpiece container into the treating fluid in a manner so as to effect an entrainment thereof in the stream in a manner to achieve a simultaneous conveyance and treatment of the workpiece during the course of its travel through the conduit. A correlation is provided between the length of the conduit and the velocity of the treating fluid so as to provide the desired duration of treatment of the containers which are thereafter extracted from the conduit at a point downstream from their point of introduction. A multiple-stage treatment of the workpieces can be achieved by successively introducing the containers extracted from one conduit into a next conduit having a separate desired treating fluid therein in a manner so as to provide a multiple-step, sequentially phased treatment of the containers. Each conduit of the apparatus can be formed in any one of a desired variety of shapes so as to provide optimum utilization of plant space, as well as for discharging the containers at the desired location for further processing or handling, as the case may be.
It will be understood that the entire post-treatment of such containers can be achieved by employing one or a plurality of such conduits or, alternatively, a portion of such post-treatment can be achieved by the apparatus and method comprising the present invention and the balance thereof by conven tional processing equipment as may be required or desired in any particular instance to achieve optimum processing flexibility and economy.
Still further advantages and benefits of the present invention will become apparent upon a reading of the description of the preferred embodiments taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic plan view of an apparatus constructed in accordance with the preferred embodiments of the present invention consisting of a series of interconnected conduit sections for providing a multiple-stage treatment;
FIG. 2 is a perspective view of a typical cylindrical container which is applicable for treatment in accordance with the method and apparatus comprising the present invention;
FIG. 3 is an enlarged plan view of one section of the apparatus shown in FIG. 1;
FIG. 4 is an enlarged longitudinal vertical sectional view of an inductor of a type suitable for introducing a container and the treating fluid into the inlet end of a processing conduit;
FIG. 5 is a fragmentary side elevational view partly in section illustrating an alternative satisfactory arrangement in which the inductor is submerged in a treating liquid contained in a reservoir to which the workpiece containers are successively transferred;
FIG. 6 is a transverse cross sectional view of a processing conduit of a substantially circular cross sectional configuration;
FIG. 7 is a transverse cross sectional view of a processing conduit having a substantially square cross sectional configuration;
FIG. 8 is a transverse cross sectional view of a processing conduit having a substantially triangular cross sectional configuration;
FIG. 9 is a transverse cross sectional view of a processing conduit provided with a plurality of helical grooves in the interior surface thereof for imparting directional guidance to the treating fluid passing therethrough;
FIG. 10 is a transverse cross sectional view of a processing conduit provided with a plurality of helically extending lands along the interior surface thereof for imparting a preselected flow pattern to the treating fluid passing therethrough;
FIG. 11 is a transverse vertical sectional view of a processing conduit provided with a supply tube for injecting supplemental treating fluid to the interior of the conduit in a substantially tangential direction, thereby imparting a prescribed flow pattern thereto;
FIG. 12 is a longitudinal vertical sectional view of an alternative satisfactory inductor for introducing the workpiece containers and treating fluid into the inlet portion of the processing conduit;
FIG. 13 is a vertical transverse sectional view through the inductor shown in FIG. 12 and taken substantially along the line l3l3 thereof;
lntntn (IAIN FIG. 14 is a fragmentary side elevational view of the outlet end of a processing conduit and a transfer chute for effecting an extraction of a workpiece from the treating fluid;
FIG. 15 is a transverse vertical sectional view through the transfer chute shown in FIG. 14 and taken substantially along the line 15-15 thereof;
FIG. 16 is a fragmentary enlarged longitudinal sectional view through one of the tubular rails of the transfer chute shown in FIG. 15 and taken substantially along the line 16 16 thereof;
FIG. 17 is a fragmentary side elevational view partly in section of a portion of the processing conduit provided with a booster arrangement for extracting a portion of the treating fluid from the conduit and thereafter returning the extracted portion to the conduit under increased pressure and velocity;
FIG. 18 is an alternative arrangement of the booster shown in FIG. 17; and
FIG. 19 is an alternative arrangement of section F of the apparatus shown in FIG. 1.
DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring now in detail to the drawings, and as may be best seen in FIG. 1, a processing apparatus is schematically illustrated comprised of six individual sections designated as A through F, inclusive. Each section includes a processing conduit 30 and an inductor 32 at the inlet end thereof for introducing a container to be treated and a separate treating fluid into the conduit for simultaneous conveyance and treatment during its travel through the processing conduit. Each of sections A through E, inclusive, is provided with a receptacle or tank 34, which serves as a reservoir for each individual treating fluid which is recirculated from the outlet or discharge end of the processing conduit 30 back to the inductor 32 through a pressurized supply line 36. The outlet end of the processing conduit 30 of one section is connected to the inlet end of the processing conduit of the next adjacent section by means of an arcuate transfer chute 38 providing a continuous uninterrupted transfer of the workpiece containers through the processing apparatus.
The arrangement as schematically illustrated in FIG. 1 is typical of one in which a liquid treating fluid is employed in sections A through E, inclusive, and a gaseous treating fluid, such as air, is employed in section F. The air is introduced into the inductor 32 of section F by means of an axial compressor 40 connected to a supply duct 42 and the air is subsequently discharged from the outlet end of the processing conduit and may be discharged to the atmosphere or a portion of all thereof may be recirculated as may be desired.
The apparatus shown in FIG. 1 is typical of a variety of multiple treatments that can be achieved in a continuous in-line operation employing one or a plurality of interconnected individual processing sections through which the workpieces are sequentially conveyed. The multiple-stage treatment provided by the arrangement of FIG. 1 may consist, for example, of a multiple-stage chemical conversion coating treatment of aluminum containers, such as the cylindrical container 44 shown in FIG. 2, which is integrally formed with a continuous circular cylindrical sidewall and bottom typical of containers used for packaging for beverages of various types. The provision of a conversion-type coating on the internal and external surfaces of the container enhances the resistance of the aluminum container to chemical attack, as well as providing for an improved base for the application of supplemental decorative and/or protective coatings thereto. The versatility of the apparatus and method comprising the present invention enables the apparatus as shown in FIG. 1 to be connected directly to the output end of one or a plurality of fabricating machines for making the containers 44 which are suitably transferred in end-to-end relationship in the direction of the arrow into the inductor 32 of section A, which in turn effects a concurrent cleaning and conveyance of the containers from the fabricating plant area to the treating area disposed remotely therefrom. For this purpose, the treating fluid employed in the processing conduit of section A may comprise any suitable aqueous or organic cleaning solution such as, for example, an acid cleaner having a phosphoric acid or sulfuric acid base incorporating a suitable surface active agent or preferably an alkaline cleaner usually comprising a mixture of alkali metal salts such as sodium salts of carbonates, phosphates, polyphosphates and hydroxides, which are employed in amounts of 0.5 to 4 ounces per gallon and usually range in pH from 9 to l l. The cleaning solution effects a removal of contaminating substances and oxides from the surfaces of the containers, as well as performing a mild surface etching thereof.
The length of the processing conduit 30 of section A and the velocity of the cleaning liquid are correlated so as to provide a contact or residence time of the containers with the cleaning liquid for a period of time sufficient to effect a substantially complete removal of the contaminating substances. Conventionally, such cleaning cycles may range from about 10 seconds up to about one minute. The cleaning fluid upon discharge from the outletend of the processing conduit of section A is returned to the reservoir 34 from which it is again recirculated to the inductor through the supply line 36.
Section B of the apparatus shown in FIG. I may conveniently comprise a water rinse treatment in which the treating fluid comprises water or deionized water to effect removal of any residual cleaning liquid from the container surfaces, as well as any remaining contaminating substances. The rinsing cycle may consist of one or a plurality of sections rather than the single section B illustrated in FIG. I to provide the appropriate rinsing of the containers. The rinse liquid similarly is returned to the reservoir 34 of section B for recycling through supply line 36 to the inlet end of the processing conduit.
The containers, after the rinsing cycle in section B, are transferred to section C in which a suitable chemical conversion coating treating liquid is employed such as a chromate coating of any of the types well known in the art typically including hexavalent chromium ions in concentrations usually ranging from about 0.2 to about l0 grams per liter and wherein the treating liquid is maintained within a controlled temperature range such as, for example, from about 60 to about l30 F. and at a pH usually ranging from about I to about 3. The aluminum container is retained in the chromate conversion coating treating liquid for a period of time sufficient to form an amorphous corrosion protective film of a desired thickness so as to provide the requisite corrosion protection and/or base for subsequent paints or other organic finishes, as well as a final decorative finish. The length of the process conduit and the velocity of the treating liquid are correlated so as to. provide a treating duration conventionally of at least about one second up to about 12 seconds or greater as may be desired. The treating fluid discharged from the outlet end of the processing conduit of section C, as in the preceding sections, is returned to the receptacleor reservoir 34 for recirculation to the inductor 32 by means of the supply line 36.
After treatment in section C, the containers are transferred to section D which, in this particular instance, provides a water rinse treatment in which the containers are rinsed in tap water and thereafter are transferred to section E in which they are subjected to a final deionized water rinse. Rinsing times of a length usually ranging from I to 3 seconds are generally acceptable for most purposes. After emergence from section E, the treated and rinsed containers are transferred to section F at which a drying operation is performed during the concurrent advance of the containers to a desired remote plant location at which further fabrication and/or container filling operations are performed as desired. The air introduced into section F is preferably heated to accelerate a removal and evaporation of any residuary rinse water from the container surfaces and render them in a sufficiently dry state for further processing.
It will be apparent from the foregoing description in connection with the multiple-section apparatus illustrated in FIG. 1, a continuous in-line high-speed processing of the workpiece containers is achieved without any intervening handling or IOIOIO 0406 manual manipulation of the workpiece containers. In such multiple-section apparatus, it is conventional to control the longitudinal flow velocity of the treating fluid in each section so that the velocity of the workpieces transferred therethrough is at least equal to and preferably slightly greater than the velocity of the workpieces in the preceding section to assure unobstructed continuity of workpiece flow. By correlating the several factors to provide the requisite minimum treatment time, production rates of from 100 to over 1,000 containers per minute can be satisfactorily achieved in accordance with the apparatus and method comprising the present invention.
It will also be apparent in the arrangement shown in FIG. 1
that the processing conduits may be arranged in any one of a variety of configurations in order to achieve optimum utilization of plant space and to effect a discharge of the workpieces from each section at a desired location either remote or adjacent to their point of entry in that processing conduit. In this regard, it will be noted that the processing conduits of sections B through E, inclusive, are of a generally U-shaped configuration corresponding to a so-called retum-type arrangement wherein the point of introduction of the workpieces at the inlet end of the processing conduit is disposed proximate or adjacent to the point of discharge of the workpieces. On the other hand, the arrangement of the processing conduits of sections A and F are such to provide a desired transfer of the workpieces from their point of introduction to a point disposed remotely therefrom coinciding with a desired location at which further processing or handling thereof is to be performed, thereby minimizing material handling problems and enhancing the efficiency of the operation. It will also be understood that the individual processing conduits of each section can extend to different vertically spaced levels to provide an optimum material flow pattern and may additionally extend underground, providing unobstructed plant working areas adjacent to the treating fluid reservoirs for accommodating additional equipment as may be desired.
It will be appreciated that alternative suitable treatments in addition to the specific multiple-stage chemical conversion treatment of aluminum containers can be provided in accordance with the apparatus of the present invention. For example, other chemical treatments typical of those feasible include the application of phosphate coatings, acid pickling, acid etching, electroless coatings, the application of coatings or dyes, such as anodized aluminum surfaces, chemical drying employing solvents such as trichloroethylene and the like. The treating fluids correspondingly may consist of homogenous gases or liquids or may comprise liquid emulsions, fluid suspensions containing solid particles entrained within a liquid or gaseous carrier, as well as two-phase mixtures consisting of gas and/or liquid and/or air.
The variations provided in the nature of the treating fluids and in the number and configuration of the individual treating section provides for almost limitless flexibility and versatility in the apparatus and method comprising the present invention for effecting any one of a variety of treatments of workpiece containers consistent with their intended end use. It will also be understood that in addition to the circular cylindrical container having one end closed as shown in FIG. 2, workpiece containers of alternative configurations and lengths including ones having both ends opened or partially opened such as by protruding flanges can be satisfactorily processed in the practice of the present invention. The term containers as herein employed, is intended to broadly encompass generally cupshaped articles having open or closed ends and is intended to encompass such other articles within this general category including, for example, ammunition shell cases, beverage and food containers, pressurized aerosol containers and the like, wherein the longitudinal length to the diameter of the workpiece is such as to facilitate its longitudinal directionally oriented guidance within a conduit for travel therethrough including the arcuate convolutions provided therein. The workpieces, moreover, may be of any one of a variety of cross sectional configurations other than a circular configuration as typified by the container 44 shown in FIG. 2 and may include containers of an elliptical, rectangular, square, triangular or other polygonal or irregular configuration wherein the maximum diameter thereof approaches but is disposed in clearance relationship with respect to the inner surfaces of the processing conduit and wherein the length thereof enables unobstructed directionally oriented travel of such containers through the conduit and the arcuate convolutions formed therein.
A more detailed description of a processing section, such as the processing section C, is shown in FIG. 3. This section, which contains the conversion coating treating solution as previously described, includes a centrifugal pump 46 driven by a motor 48 and having an inlet line 50 connecting its suction end to the tank 34 containing the treating fluid. The pressurized treating fluid is transferred through a supply line 52 connected to the discharge side of the pump to the inductor 32 disposed at the inlet side of the processing conduit 30. In accordance with a preferred embodiment, a section 54 of the processing conduit 30 is of a transparent material such as glass or polymethylmethacrylate, for example, in order to permit a visual inspection of the workpieces and treating fluid passing therethrough.
The control of the velocity of treating fluid introduced into the processing conduit and the correlation of the speed of travel of the workpieces in section C with the preceding and succeeding sections can conveniently be achieved within preselected limits by means of a suitable flow measuring device 56 schematically shown in FIG. 3. The flow measuring device may be of any one of the various types well known in the art which are operable for alternatively counting or indicating the rate of workpieces passing through the conduit and/or the longitudinal velocity of the treating fluid passing therethrough to assure the maintenance of an appropriate spacing between successive workpiece containers and a desired net flow rate thereof. The flow measuring device 56 is suitably connected to a control box 58 which incorporates appropriate circuitry including presettable limits of the type well known in the art which are operative to effect a periodic energization of a motorized control valve 60 in the supply line 52 for increasing or decreasing the supply of treating fluid to the inductor 32 to maintain the velocity within the preset limits. Alternatively, the control box 56 can regulate the speed of rotation of the motor 48 to effect appropriate correction of the treating fluid output from the pump 46.
In addition to the flow control device, the arrangement illustrated in FIG. 3 also illustrates ancillary control devices which can be conveniently incorporated in one or more sections of the apparatus to maintain coordination therebetween, as well as to control each particular treating fluid within a preselected temperature and composition range, thereby assuring uniformity in treatment of the workpiece containers. As an example, the temperature of the treating liquid can be maintained in prescribed limits by providing suitable temperature sensing device, such as a thermocouple 62, which senses the temperature of the treating liquid in the reservoir 34 and communicates this information to a control box 64 which in turn regulates the heat or coolant input into a heat exchanger 66 immersed in the treating liquid.
The treating fluid can also be maintained in a substantially homogenous condition, as well as assuring uniformity in temperatures, by means of providing a propeller-type agitator 68 extending inwardly of one of the walls of the reservoir 34.
The composition of the treating liquid can also be automatically maintained within prescribed concentration limits by the provision of an electrode 70 which is immersed in the treating liquid and is operable to continuously or intermittently sense the electrical conductivity of the treating liquid which in turn is a function of the concentration of dissolved constituents therein. Conductivity electrodes of this type are well known in the art and can be conveniently connected to a suitable control box 72 containing circuitry and presettable means for monitoring the electrical conductivity as sensed by the electrode. When the solution conductivity falls below a preset limit, indicating that the concentration of the constituents therein is a preselected minimum level, the control box 72 is operative to energize a suitable metering pump 74, effecting the addition of a makeup solution concentrate from a container 76 through a supply line 78 to the treating receptacle 34. Still further control devices can be incorporated in the apparatus to provide constant or intermittent sensing of the several physical and chemical variables and a corresponding correction or control thereof as may be desired to assure consistent uniformity of treatment of successive workpieces transferred through the apparatus section.
A typical inductor constructed in accordance with one embodiment of the present invention for introducing fluid and workpiece containers into the processing conduit is illustrated in detail in FIG. 4. As shown, the inductor comprises a tubular sleeve 80 provided with a lining 82 of a low fiction material, such as a polytetrafluoroethylene plastic, disposed along the interior surface thereof and which is formed with an outwardly tapered or bellmouth configuration 84 at the inlet end thereof to facilitate entry and alignment of workpiece containers such as the container 44 illustrated in phantom. As previously described in connection with FIG. 1, the workpiece containers are adapted to be guidably transported to the inlet portion of the inductor by a suitable transfer chute, such as the transfer chutes 38 shown in FIG. 1 and fragmentarily indicated in FIG. 4. A tubular manifold ring 86 is disposed in concentric relationship adjacent to the tapered inlet portion 84 and is formed with an annular nozzle 88 for directing a curtainous conical stream of the pressurized treating fluid inwardly of the tubular sleeve forming a low friction fluid film upon which the workpiece containers 44 are slidably supported during their inward travel into the inductor. The interior of the manifold ring 86 is connected, as schematically shown in FIG. 4, to a supply line 90, which in turn is connected to a suitable pressurized source of the treating fluid such as the pump 92.
The tubular sleeve 80 is rigidly supported by a housing 94 which is formed with an annular flange 96 at its outlet end to which a flange 98 is connected which in turn is afiixed to a processing conduit 30 or a suitable extension thereof through which the workpiece containers and treating fluid are conveyed. The lower portion of the housing 94 is formed with a suitable flange 99 to which the supply line 90 is connected for supplying the pressurized treating fluid to the interior of the housing. In accordance with a preferred construction, the tubular sleeve 80 and the inner end of the conduit 30 are fonned with conforming tapered edges at their adjacent ends, defining therebetween an annular tapered nozzle 100, through which the pressurized treating fluid is discharged from the housing into the interior of the processing conduit. The nozzle 100 is formed with a series of angularly disposed vanes 102 which are offset with respect to the longitudinal axis of the conduit 30 such that the treating fluid discharged is in the form of a helix forming a rapidly rotating wall of liquid, indicated in phantom as 104 in FIG. 4, extending around the inner surface of the pipe and including a central vortex indicated at 106.
In accordance with this arrangement, the treating fluid has a combined rotary and longitudinal component whereby the workpiece containers entrained therein are caused to rapidly rotate and travel longitudinally along the processing conduit, effecting a concurrent conveyance and treatment of the surfaces thereof. The turbulence of the vortex of treating fluid formed assures intimate contact with the surfaces of the work piece container, as well as assuring the maintenance of a substantially homogenous treating fluid.
The inductors as previously described in connection with the apparatus as illustrated in FIGS. 1 and 3 are shown in their conventional position in which they are disposed above the level of the treating solutions contained in receptacles 34. It is also contemplated in accordance with the practice of the present invention that similar type inductors, such as the inductor 108 shown in FIG. 5, can be immersed in and submerged below the level of a treating liquid 110 in a tank 112 to which pressurized treating liquid is supplied through a supply line 114. The workpieces, such as the workpiece containers 44, are suitably supplied to the inlet portion of the inductor 108 by meansof transfer chutes, as previously described, or alternatively, by a vertical magazine I16 terminating at a point adjacent to the inlet of the inductor. The inductor 108 may also be of the type as shown in FIG. 4, wherein the high pressure discharge of the treating fluid from the nozzle 100 imposes a suction at the inlet end of the tubular sleeve, which in turn draws a workpiece container inwardly of the inductor, effecting an entrainment and conveyance thereof in the treating liquid.
The process conduits may be composed of any one of a variety of suitable materials and may be of any one of a desired cross sectional configuration which may remain constant along the length thereof or may vary as desired in order to obtain the desired fluid flow velocity or flow pattern. Typical variations of cross sectional configuration of processing conduits are those illustrated in FIGS. 6 through 8. A processing conduit 118 is shown in FIG. 6 which is of a substantially circular tubular cross section in which a workpiece container 44, indicated in phantom, is adapted to be concurrently conveyed and treated. A conduit 120 is shown in FIG. 7 which is of a substantially square or rectangular configuration, while a processing conduit 122 is shown in FIG. 8 having a substantially triangular cross sectional shape. The processing conduit 122 may also be provided with corner fillers 124 for effecting a strengthening of the conduit, as well as providing selected variations in the cross-sectional area and fluid flow pattern.
The processing conduits or select portions thereof may be made of any one of a variety of suitable materials which are of adequate strength and which are resistant to and compatible with the treating fluids circulated therethrough. In addition, all or portions of the processing conduits can include transparent or translucent sections to enable visual inspection of the treating fluid flow pattern and workpiece travel through the processing conduit. In addition to various metals and metal alloys, such as steel and aluminum, for example, which may further be provided with suitable protective linings or coatings, various synthetic plastic materials either of a rigid or flexible structure can be satisfactorily employed including, for example, vinyl polymers and copolymers, acrylics, elastomeric polymers, such as rubber and the like. Processing conduits made of transparent acrylic resin, such as polymethylmethacrylate, have been found particularly suitable due to their transparency, enabling a visual inspection of the workpieces during their entire course of travel through their processing conduit.
It is also contemplated in accordance with the methods of the present invention that the processing conduits can be provided with suitable means along the inner surfaces thereof for providing guidance and variations in the fluid flow patterns during the course of the travel of the treating fluid and workpieces through the conduits. In accordance with the preferred practice of the present invention in which the treating fluid is initially introduced in the form of a vortex, a supplement to the initial helical flow pattern can be provided such as by means of a series of helical grooves I26 formed along and extending in a spiral pattern along the inner surface of a processing conduit 128 as shown in FIG. 9. Similarly, a series of lands or vanes I30 projecting substantially radially inwardly of the interior surface of a processing conduit 132, as shown in FIG. 10, can be provided which extend in a spiral or helical pattern to provide directional guidance and selected variations in the flow pattern of treating fluid.
Selected variations in the flow pattern of a treating fluid passing through a processing conduit can also be achieved in accordance with the construction illustrated in FIG. 11. In the arrangement illustrated, a conduit 134 is provided at a point intermediate its length with a supply pipe 136 terminating in a wan nozzle 138 for injecting a supplemental quantity of the same treating fluid or different treating fluid into the interior of the conduit in a substantially tangential forwardly inclined direction. This arrangement can serve to effect a pressure or velocity boost of the treating fluid at one or more points disposed downstream from the inlet end portion of the conduit and can further supplement the helical flow pattern of the treating fluid. Conventionally, the axis of the nozzle 138 is oriented so as to impart an appropriate pitch to the helical flow pattern of the fluid passing thereby.
An alternative satisfactory construction of an inductor is illustrated in FIG. 12 and 13. As shown, the inductor comprises a conduit 140 which may be integrally formed with or removably coupled to the processing conduit disposed downstream therefrom. An annular chamber 142, as defined by an exterior hollow housing 144, surrounds a section of a conduit 140 to which pressurized treating fluid is supplied through a flanged connector 146. The left-hand or inlet end of the inductor, as viewed in FIG. 12, is provided with a tapered tubular sleeve 148 having a manifold ring 150 disposed adjacent to the inlet opening of the same type and for the same purposes as the manifold ring 86 previously described in connection with FIG. 4.
The conduit 140 enclosed within the housing 144 is formed with a plurality of angularly oriented nozzles 152, the axes of discharge of which are preferably forwardly and tangentially oriented with respect to the longitudinal axis of the conduit so as to impart a helical flow pattern as defined by a rapidly rotating wall of water indicated in phantom having a centrally extending vortex. The discharge of the treating fluid through the plurality of nozzles 152 similarly effects the imposition of a suction at the inlet end portion of the inductor serving to draw workpiece containers inwardly for entrainment in the helically moving treating liquid.
It will be appreciated that the inductor shown in FIG. 4 and inductor shown in FIGS. 12 and 13 can also be employed at one or more points along the length of the processing conduit to effect a boost in the pressure of the treating fluid, as well as to impart or reestablish the desired flow pattern or turbulence of the treating fluid so as to maintain the desired correlation between fluid flow and treatment time. When the treating fluid is injected in accordance with the preferred embodiments in the form of a helical vortex, the combined effects of internal fluid friction and friction with the surfaces of the conduit and workpieces effects a progressive reduction in the velocity which is generally manifested in an increase in the pitch of the helical flow pattern, as well as a reduction in the diameter of the centrally extending vortex. When processing conduits of substantial length are required in order to achieve the requisite treatment time, it is generally desirable to employ boosters, such as the inductors illustrated in FIG. 4 and 12, at one or a plurality of locations therealong to reestablish the desired treating fluid flow pattern and velocity-pressure relationship.
Referring now to FIGS. 1446, a satisfactory construction is illustrated of the transfer chutes 38, as previously discussed in connection with FIG. 1, for transferring the workpiece containers from the outlet end to the inlet end of adjacent process sections. As shown, the transfer chute 38 is composed of a plurality of tubular rails 154, which are disposed at circumferentially spaced intervals, forming an open enclosure for guidably receiving the workpiece containers discharged from the outlet end of a processing conduit 156. The open construction of the transfer chute enables the separation and discharge of the treating liquid to pass downwardly in the direction of the arrows into a suitable catch basin or receptacle from which it can be recovered and recirculated to the inlet end of the processing conduit. The open construction also enables a disengagement of the treating fluid from the workpiece containers at the completion of one treatment and preparatory to the next successive treatment or processing step. The tubular rails 154 are retained in appropriate circumferentially spaced position by means of a series of straps 158 which are securely fastened to the rails at longitudinally spaced intervals therealong. The specific number and spacing of the tubular rails can be varied consistent with the particular configuration and size of the workpieces being processed in order to assure appropriate guidance and conveyance of the containers along the transfer chutes.
In order to facilitate disengagement of the treating fluid with the workpiece containers and to further overcome any tendency of the containers to slow down during the course of their travel along the transfer chute, it is conventionally preferred to provide one or more of the tubular rails with a plurality of angularly oriented jets disposed at spaced intervals therealong through which a pressurized gas, such as air,"-is ejected, effecting a propelling of the workpiece containers along the transfer chute. The formation of a plurality of jets is also effective to maintain the workpiece containers in at least partially spaced relationship with respect to the surfaces of the rails, counteracting any centrifugal forces and thereby minimizing friction therebetween. The supply of the pressurized gas to one or more of the tubular rails can be conveniently achieved by a supply header 162, such as shown in FIG. 15, which is disposed in communication with a source, such as a compressor of the pressurized gas.
It is also contemplated in accordance with the present invention that the treating fluid passing through a processing conduit can be completely or partially removed to enable a replacement or replenishment thereof with the same or a different treating fluid as may be desired in certain treating processes. An arrangement for achieving the foregoing is illustrated in FIG. 17 which is processing conduit 164 is illustrated, through which the treating fluid, as shown in phantom, is traveling in a helical pattern including a centrally disposed vortex. A manifold 166, defining an annular chamber 168, is disposed in encircling relationship around an upstream section of the process conduit which is formed with a plurality of angularly oriented nozzles 170, through which a portion of the treating fluid is withdrawn into the annular chamber 168. The interior of the manifold 166 is disposed in communication with the suction side of a booster pump 172 to effect a constant withdrawal of the treating fluid from the annular chamber.
The pressurized discharge side of the booster pump is connected to a supply line 174 through which the pressurized treating fluid is conveyed to an annular chamber 176 defined by a manifold I78 encircling the processing conduit at a point spaced downstream from the withdrawal manifold I66. The process conduit is formed with a series of angularly oriented nozzles 180, through which the treating fluid is discharged in the desired helical flow pattern into the interior of the conduit, effecting a reestablishment of the desired vortex and an appropriate boost in the pressure and velocity of the fluid passing therealong. It will also be appreciated that the arrangement as illustrated in FIG. 17 can be employed for adding supplemental treating fluid at a point intermediate the inlet and outlet ends of a processing conduit such as by providing a secondary supply line 182 connected to the suction side of the booster pump 172.
An alternative satisfactory arrangement of the device shown in FIG. 17 is illustrated in FIG. 18 which similarly enables a partial replenishment or replacement of the treating fluid, effecting a boost in its pressure and/or velocity, as well as a reestablishment of the helical flow pattern at a point intermediate the length of a processing conduit. As shown in FIG. 18, a manifold 184i encircles a processing conduit 186 defining an annular chamber 138 which is disposed in communication with a suction line 190 connected to the suction side of a centrifugal pump 192. The processing conduit I86 disposed within the manifold 184 is formed with a series of angularly oriented nozzles 194, through which the treating fluid is withdrawn from the interior of the processing conduit through the chamber 188 and into the suction line 190.
All or a portion of the treating fluid withdrawn is replaced in the processing conduit by means of a pressure line 196 connected to the output side of the pump 192, which is disposed in communication with a chamber 198 defined by a manifold 200 encircling the process conduit 186 at a point upstream from the withdrawal manifold 184. The process conduit 186 disposed within the encircling manifold 200 is provided with a series of angularly oriented discharge nozzles 202, through which the pressurized treating fluid is discharged from the chamber 198 into the interior of the processing conduit, effecting a boost in the pressure and/or velocity thereof, as well as effecting a reestablishment of the helical or other desired flow pattern.
In normal operation in accordance with the arrangement shown in FIG. 18, all of the treating fluid withdrawn through the withdrawal manifold 184 is immediately returned at a point immediately upstream through the input manifold 200, providing thedesired velocity and pressure boost, thereby assuring continuity of flow of the treating fluid and workpieces entrained therein. It is also contemplated, as in the arrangement illustrated in FIG. 17, that a partial replenishment or addition of the same or an alternative treating fluid can be accomplished through a supply line 204 connected to the suction line 190.
An alternative satisfactory arrangement of processing section F, as illustrated in FIG. 1, is shown in FIG. 19 in which the inductor is located adjacent to the output end 206 of a processing conduit 208 rather than at the inlet end as shown in FIG. 1. In the embodiment illustrated in FIG. 19, an axial compressor 210 is connected by means of a pressure line 212 to an inductor 214 disposed adj. cent to the output end 206 of the processing conduit, imposing a suction or negative pressure along the upstream portion of the processing onduit 208, which is operative to draw workpiece containers. asindicated in phantom, into the inlet end of the processing conduit which is disposed in alignment with a transfer chute 38. The inductor 214 may be of any one of the types previously described which is operative, by an appropriate nozzle arrangement through which the high pressure fluid, such as air, is discharged, to effect an imposition of a reduced pressure in the upstream portion of the processing conduit, causing supplemental air to be drawn inwardly of the inlet end of the conduit, which in turn effects a conveyance or transfer of the workpiece containers therealong. The workpiece containers, upon passage through the inductor 214, are advanced outwardly of the outlet end 206 of the conduit by the high pressure air discharged through the inductor and are conveyed by a suitable transfer chute 216 to the next succeeding work station.
It will be apparent from the foregoing description that the processing apparatus and the method comprising the present invention is readily adaptable to a variety of different treating fluids and treating processes in order to effect an appropriate treatment of the workpiece containers. In addition to enabling rapid continuous in-line chemical treatments of such workpieces, alternative treatments, such as electrolytic treatments, coating treatments, mechanical treatments, as well as electromechanical treatments, can also be accomplished by appropriate adjustments in the treating fluids to provide the desired treating action. In each instance, the workpiece containers are concurrently transferred and treated in the processing conduit while entrained in a confined stream of the treating fluid. The movement of the workpieces is substantially in response to the travel of the treating fluid therealong, which may, in some instances, be supplemented by gravity when all or sections of the processing conduit are oriented in a downwardly inclined direction. In addition to inducing the workpieces into the processing conduit by employing an inductor of the type illustrated in FIGS. 4 and 12 of the drawings, supplemental mechanical loading and air jets, for example, can be employed to assist in the rapid transfer of the workpieces from one section to the next adjacent process section.
Still further variations in the apparatus and method as hereinbefore described can be made without departing from the spirit of the invention.
What is claimed is:
1. The method of treating elongated containerlike workpieces which comprises the steps of forming a confined stream of a treating fluid having a helical flow pattern and a cross-sectional size greater than the cross-sectional size of the workpiece, introducing a workpiece into said stream in longitudinally oriented relationship with respect to the longitudinal direction of travel of said stream effecting a rotation of the workpiece about its longitudinal axis and a longitudinal conveyance of the workpiece and a simultaneous treatment thereof during its travel while entrained in said stream, maintaining the workpiece in said stream for a period of time sufficient to perform a desired treatment thereof, and thereafter extracting the workpiece from said stream of said treating fluid.
2. The method as defined in claim 1, including the further step of recirculating of at least a portion of said treating fluid to said stream.
3. The method as defined in claim 1, including the further steps of forming a plurality of separate confined streams each composed of a separate treating fluid and successively introducing a workpiece into and extracting a workpiece from each of said separate streams in a preselected sequence for performing a plural treatment on the workpiece.
4. The method as defined in claim 1, including the further step of guiding the path of travel of said stream in order that the point at which a workpiece is introduced into said stream is located remotely from the point at which a workpiece is extracted from said stream.
5. The method as defined in claim 1, including the further step of guiding the path of travel of said stream in order that the point at which a workpiece is introducedinto said stream is located adjacent to the point at which a workpiece is extracted from the stream.
6. The method as defined in claim 1, including the further step of introducing at least a portion of said treating fluid into said stream at a point downstream from the point at which a workpiece is introduced into said stream.
7. The method as defined in claim 1, including the further step of replenishing said treating fluid to maintain the composition thereof within a preselected range.
8. The method as defined in claim-1, including the further step of controlling the temperature of said treating fluid within a preselected range.
9. The method as defined in claim 1, in which said treatin fluid is a liquid.
10. The method as defined in claim 1, in which said treating fluid is a gas.
11. The method as defined in claim I, in which said treating fluid is an aqueous solution.
12. The method as defined in claim 1, in which said treating fluid is an organic solution.
13. The method as defined in claim I, in which said treating fluid is a liquid emulsion.
14. The method as defined in claim 1, in which said treating fluid is a two-phase mixture of liquid and gas.
15. The method as defined in claim 1, in which said treating fluid includes solid particles suspended therein.
16. The method as defined in claim 1, in which said treating fluid comprises a cleaning fluid for performing a cleaning treatment of the surfaces of the workpiece.
17. The method as defined in claim 1, in which said treating fluid comprises an aqueous rinse solution for performing a rinse treatment of the surfaces of the workpiece.
18. The method as defined in claim 1, in which said treating fluid comprises a coating composition for depositing a coating on the surfaces of the workpiece.
19. The method as defined in claim 1, in which said treating fluid comprises a chemical conversion coating solution for forming a conversion coating on the surfaces of the workpiece.
20. The method as defined in claim I, in which said treating fluid comprises a liquid for effecting a chemical drying of the workpiece.
22. The method as defined in claim 1, in which the step of forming said confined stream having said helical flow pattern is performed in a manner to form a centrally oriented vortex along at least a portion of the length of said stream.

Claims (21)

  1. 2. The method as defined in claim 1, including the further step of recirculating of at least a portion of said treating fluid to said stream.
  2. 3. The method as defined in claim 1, including the further steps of forming a plurality of separate confined streams each composed of a separate treating fluid and successively introducing a workpiece into and extracting a workpiece from each of said separate streams in a preselected sequence for performing a plural treatment on the workpiece.
  3. 4. The method as defined in claim 1, including the further step of guiding the path of travel of said stream in order that the point at which a workpiece is introduced into said stream is located remotely from the point at which a workpiece is extracted from said stream.
  4. 5. The method as defined in claim 1, including the further step of guiding the path of travel of said stream in order that the point at which a workpiece is introduced into said stream is located adjacent to the point at which a workpiece is extracted from the stream.
  5. 6. The method as defined in claim 1, including the further step of introducing at least a portion of said treating fluid into said stream at a point downstream from the point at which a workpiece is introduced into said stream.
  6. 7. The method as defined in claim 1, including the further step of replenishing said treating fluid to maintain the composition thereof within a preselected range.
  7. 8. The method as defined in claim 1, including the further step of controlling the temperature of said treating fluid within a preselected range.
  8. 9. The method as defined in claim 1, in which said treating fluid is a liquid.
  9. 10. The method as defined in claim 1, in which said treating fluid is a gas.
  10. 11. The method as defined in claim 1, in which said treating fluid is an aqueous solution.
  11. 12. The method as defined in claim 1, in which said treating fluid is an organic solution.
  12. 13. The method as defined in claim 1, in which said treating fluid is a liquid emulsion.
  13. 14. The method as defined in claim 1, in which said treating fluid is a two-phase mixture of liquid and gas.
  14. 15. The method as defined in claim 1, in which said treating fluid includes solid particles suspended therein.
  15. 16. The method as defined in claim 1, in which said treating fluid comprises a cleaning fluid for performing a cleaning treatment of the surfaces of the workpiece.
  16. 17. The method as defined in claim 1, in which said treating fluid comprises an aqueous rinse solution for performing a rinse treatment of the surfaces of the workpiece.
  17. 18. The method as defined in claim 1, in which said treating fluid comprises a coating composition for depositing a coating on the surfaces of the workpiece.
  18. 19. The method as defined in claim 1, in which said treating fluid comprises a chemical conversion coating solution for forming a conversion coating on the surfaces of the workpiece.
  19. 20. The method as defined in claim 1, in which said treating fluid comprises a liquid for effEcting a chemical drying of the workpiece.
  20. 21. The method as defined in claim 3, including the further step of controlling the longitudinal velocity of said streams such that the velocity of any one separate stream is equal to or greater than the velocity of a preceding stream.
  21. 22. The method as defined in claim 1, in which the step of forming said confined stream having said helical flow pattern is performed in a manner to form a centrally extending vortex along at least a portion of the length of said stream.
US774761A 1968-11-12 1968-11-12 Method of treating workpieces in a treating fluid Expired - Lifetime US3620813A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US77476168A 1968-11-12 1968-11-12
US77492368A 1968-11-12 1968-11-12
US23211672A 1972-03-06 1972-03-06
US00232167A US3823083A (en) 1968-11-12 1972-03-06 Apparatus for electroplating workpieces
US00231951A US3823074A (en) 1968-11-12 1972-03-06 Method for electroplating workpieces

Publications (1)

Publication Number Publication Date
US3620813A true US3620813A (en) 1971-11-16

Family

ID=27539987

Family Applications (5)

Application Number Title Priority Date Filing Date
US774923A Expired - Lifetime US3664354A (en) 1968-11-12 1968-11-12 Apparatus for processing workpieces
US774761A Expired - Lifetime US3620813A (en) 1968-11-12 1968-11-12 Method of treating workpieces in a treating fluid
US00232167A Expired - Lifetime US3823083A (en) 1968-11-12 1972-03-06 Apparatus for electroplating workpieces
US00231951A Expired - Lifetime US3823074A (en) 1968-11-12 1972-03-06 Method for electroplating workpieces
US00232116A Expired - Lifetime US3751297A (en) 1968-11-12 1972-03-06 Method for simultaneous fluid processing and conveying

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US774923A Expired - Lifetime US3664354A (en) 1968-11-12 1968-11-12 Apparatus for processing workpieces

Family Applications After (3)

Application Number Title Priority Date Filing Date
US00232167A Expired - Lifetime US3823083A (en) 1968-11-12 1972-03-06 Apparatus for electroplating workpieces
US00231951A Expired - Lifetime US3823074A (en) 1968-11-12 1972-03-06 Method for electroplating workpieces
US00232116A Expired - Lifetime US3751297A (en) 1968-11-12 1972-03-06 Method for simultaneous fluid processing and conveying

Country Status (6)

Country Link
US (5) US3664354A (en)
AT (1) AT303483B (en)
BE (1) BE741527A (en)
DE (1) DE1966780C3 (en)
GB (1) GB1301678A (en)
NL (1) NL171544C (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3751297A (en) * 1968-11-12 1973-08-07 Oxy Metal Finishing Corp Method for simultaneous fluid processing and conveying
US4051805A (en) * 1975-11-11 1977-10-04 Amchem Products, Inc. Can washing and coating system
US4233108A (en) * 1974-10-05 1980-11-11 Kobe Steel, Limited Process for use in etching the outer surface of a metal member
US4262044A (en) * 1980-05-16 1981-04-14 Kuczma Jr John J Method for the electroless nickel plating of long bodies
US5486272A (en) * 1993-05-28 1996-01-23 Enthone-Omi Inc. Electroplating method and apparatus
US20050084615A1 (en) * 2003-10-15 2005-04-21 Applied Materials, Inc. Measurement techniques for controlling aspects of a electroless deposition process
US20050205112A1 (en) * 2004-03-17 2005-09-22 Green Bobby R Selective removal or application of a coating on a portion of a container
US20100068404A1 (en) * 2008-09-18 2010-03-18 Guardian Industries Corp. Draw-off coating apparatus for making coating articles, and/or methods of making coated articles using the same
CN108799210A (en) * 2018-07-06 2018-11-13 江苏大学 A kind of two-way air extractor
CN112708920A (en) * 2019-10-24 2021-04-27 亚洲电镀器材有限公司 Fluid delivery system and method of plating a workpiece

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2154296B1 (en) * 1971-09-27 1975-02-07 Mouzon Nouvelle Ventilateurs
US3776182A (en) * 1972-07-31 1973-12-04 Stolle Corp Can treating apparatus
US3958585A (en) * 1974-01-14 1976-05-25 E. I. Du Pont De Nemours And Company Apparatus for stripping residual solvent from polymer pellets
US3916937A (en) * 1974-07-08 1975-11-04 Bror Erik Nystrom Apparatus for surface processing
US4036478A (en) * 1974-07-15 1977-07-19 Sunbeam Equipment Corporation Liquid quenching system
US4264239A (en) * 1975-10-14 1981-04-28 King-Seeley Thermos Co. Ice transport and dispensing system
DE2915248C3 (en) * 1979-04-14 1982-01-14 Gise, Frhr. von, Hardo, Dr.med., 7400 Tübingen Device for automatic selective and exact treatment of specimens
JPS6039605B2 (en) * 1979-05-10 1985-09-06 ソニー株式会社 Goods transfer device
GB2116637B (en) * 1982-03-11 1985-10-23 Harben Systems Ltd Improvements in and relating to conveying systems
JPS609129A (en) * 1983-06-29 1985-01-18 Fujitsu Ltd Wet processing device
DE3339262A1 (en) * 1983-10-28 1985-05-09 Günther Dipl.-Ing. 7778 Markdorf Boos DEVICE FOR TRANSPORTING BODIES BY MEANS OF A LIQUID FLOWING IN A PIPELINE
GB2150518A (en) * 1983-11-30 1985-07-03 James Arthur Noon Pneumatic tube conveyor system
US4710068A (en) * 1986-09-15 1987-12-01 Reynolds Metals Company Air conveyor
US4992145A (en) * 1989-12-27 1991-02-12 Ford Motor Company Electroplating of precision parts
US5231747A (en) * 1990-12-21 1993-08-03 The Boeing Company Drill/rivet device
US5231754A (en) * 1990-12-21 1993-08-03 The Boeing Company Rivet brake and staging tube
US5210935A (en) * 1990-12-21 1993-05-18 The Boeing Company Curved rivet feed chute
US5174316A (en) * 1991-03-06 1992-12-29 Food Technology International Inc. Method and apparatus for cleaning material recovered from soiled plastic containers, packaging and the like
US5275690A (en) * 1992-06-17 1994-01-04 Santa Barbara Research Center Method and apparatus for wet chemical processing of semiconductor wafers and other objects
GB2313410B (en) * 1996-05-25 2000-03-29 Ian Stephenson Improvements in or relating to pumps
US5862821A (en) * 1996-09-23 1999-01-26 Rodriguez; Jeffrey J. Apparatus for washing leafy plant products
US6071179A (en) * 1997-06-02 2000-06-06 Mitsui High-Tec Inc. Apparatus and method for grinding and polishing spherical bodies
US6554911B1 (en) 1999-10-15 2003-04-29 Corning Incorporated En masse process for cleaning thin polarizing glass devices
US6575722B1 (en) 2000-06-02 2003-06-10 Beringer Llc Apparatus for producing and cooling polymer pellets
US7648584B2 (en) * 2003-06-27 2010-01-19 Lam Research Corporation Method and apparatus for removing contamination from substrate
FR2883889B1 (en) * 2005-04-04 2007-06-08 Commissariat Energie Atomique REDUCTION ELECTRODE FOR METAL DEPOSITION BY OXIDOREDUCTION.
US7708504B2 (en) * 2005-08-29 2010-05-04 Savannah River Nuclear Solutions, Llc Pneumatic conveyance apparatus and process
US7234898B2 (en) * 2005-11-18 2007-06-26 E.F. Bavis & Associates, Inc. Pneumatic transmission system
US20070166114A1 (en) * 2005-12-23 2007-07-19 Whitten James R Orienting means for condom transport equipment
US7401695B2 (en) 2006-06-07 2008-07-22 The Gillette Company Component control device, systems, and methods
FR3008429A1 (en) 2013-07-12 2015-01-16 Commissariat Energie Atomique PROCESS FOR THE SYNTHESIS OF A METALLIC FOAM, METALLIC FOAM, USES THEREOF AND DEVICE COMPRISING SUCH A METAL FOAM
CN103990576B (en) * 2014-04-09 2017-01-04 浙江三箭工贸有限公司 Chopsticks draw paint equipment automatically
DE102016107125A1 (en) * 2016-04-18 2017-10-19 Hauni Maschinenbau Gmbh Delivery nozzle and conveying device with at least one delivery nozzle
US10646977B2 (en) * 2016-06-17 2020-05-12 United Technologies Corporation Abrasive flow machining method
US10099868B1 (en) * 2017-04-20 2018-10-16 Otto Kierulff Da Costa Set of water pipes with capsules for heavy cargo and irrigation transportation system
US11261797B2 (en) 2018-11-05 2022-03-01 General Electric Company System and method for cleaning, restoring, and protecting gas turbine engine components
EP3753885A1 (en) * 2019-06-19 2020-12-23 Heberlein AG Suction device for a textile machine, textile machine with a suction device, use of two cyclone elements and method for suctioning yarns
US11555413B2 (en) 2020-09-22 2023-01-17 General Electric Company System and method for treating an installed and assembled gas turbine engine
US11952224B2 (en) * 2021-10-03 2024-04-09 Louis Handfield Pneumatic conveying venturi for flake ice

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1252302A (en) * 1917-03-13 1918-01-01 Peter Riesenecker Means for and method of operating on canned goods.
US2760873A (en) * 1951-05-05 1956-08-28 Munz Emil Process of transporting cans through a continuous sterilizer
US2808344A (en) * 1953-06-01 1957-10-01 Kaulen Method for seamless coating of printing forms
US2876132A (en) * 1952-07-19 1959-03-03 Gen Motors Corp Process of coating steel tubing
US3442708A (en) * 1965-01-07 1969-05-06 Cincinnati Cleaning & Finishin Handling and cleaning fragile containers
US3446757A (en) * 1966-09-26 1969-05-27 Hercules Inc High molecular weight hydroxyl-containing polyethers

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US914475A (en) * 1907-05-06 1909-03-09 Franz Beduwe Apparatus for elevating and cleaning material of a granular nature.
US1294455A (en) * 1918-12-28 1919-02-18 Charles S Hardy Method and apparatus for cleaning tripe.
US1528995A (en) * 1922-08-28 1925-03-10 Philip A Singer Method and means for treating material
US1837159A (en) * 1929-06-28 1931-12-15 Stanley Works Method of and apparatus for processing strip metal
US2078235A (en) * 1935-08-05 1937-04-27 Frank D Chapman Hydraulic apparatus
US2144334A (en) * 1936-08-17 1939-01-17 Indiana Condensed Milk Company Apparatus for processing canned foods
US2085842A (en) * 1937-02-15 1937-07-06 Herbert B Wentworth Method and means for drying lightweight materials
US2261560A (en) * 1940-02-06 1941-11-04 Pellas Method and apparatus for removing coffee beans from the berry
US2542237A (en) * 1944-11-13 1951-02-20 Ohio Seamless Tube Company Quenching apparatus for heattreated workpieces
US2543993A (en) * 1945-05-03 1951-03-06 Mullins Mfg Corp Dishwashing machine
US2680084A (en) * 1948-07-19 1954-06-01 Redding Mfg Company Inc Hydraulic conveying
US3108012A (en) * 1960-07-20 1963-10-22 Pipelife Corp Method of conditioning transmission lines in situ
US3105720A (en) * 1960-10-03 1963-10-01 Barker Company Pneumatic conveying system
US3118459A (en) * 1962-08-20 1964-01-21 Us Mineral Wool Company Apparatus for wetting dry materials
US3241520A (en) * 1964-10-19 1966-03-22 Wisconsin Alumni Res Found Particle coating apparatus
US3363638A (en) * 1965-07-23 1968-01-16 Ralph Zebarth Inc Heat exchanger for poultry and the like
US3664354A (en) * 1968-11-12 1972-05-23 Udylite Corp Apparatus for processing workpieces

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1252302A (en) * 1917-03-13 1918-01-01 Peter Riesenecker Means for and method of operating on canned goods.
US2760873A (en) * 1951-05-05 1956-08-28 Munz Emil Process of transporting cans through a continuous sterilizer
US2876132A (en) * 1952-07-19 1959-03-03 Gen Motors Corp Process of coating steel tubing
US2808344A (en) * 1953-06-01 1957-10-01 Kaulen Method for seamless coating of printing forms
US3442708A (en) * 1965-01-07 1969-05-06 Cincinnati Cleaning & Finishin Handling and cleaning fragile containers
US3446757A (en) * 1966-09-26 1969-05-27 Hercules Inc High molecular weight hydroxyl-containing polyethers

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3751297A (en) * 1968-11-12 1973-08-07 Oxy Metal Finishing Corp Method for simultaneous fluid processing and conveying
US4233108A (en) * 1974-10-05 1980-11-11 Kobe Steel, Limited Process for use in etching the outer surface of a metal member
US4051805A (en) * 1975-11-11 1977-10-04 Amchem Products, Inc. Can washing and coating system
US4262044A (en) * 1980-05-16 1981-04-14 Kuczma Jr John J Method for the electroless nickel plating of long bodies
US5486272A (en) * 1993-05-28 1996-01-23 Enthone-Omi Inc. Electroplating method and apparatus
US20050084615A1 (en) * 2003-10-15 2005-04-21 Applied Materials, Inc. Measurement techniques for controlling aspects of a electroless deposition process
US20050205112A1 (en) * 2004-03-17 2005-09-22 Green Bobby R Selective removal or application of a coating on a portion of a container
US7412979B2 (en) 2004-03-17 2008-08-19 Ball Corporation Selective removal or application of a coating on a portion of a container
US20100068404A1 (en) * 2008-09-18 2010-03-18 Guardian Industries Corp. Draw-off coating apparatus for making coating articles, and/or methods of making coated articles using the same
CN108799210A (en) * 2018-07-06 2018-11-13 江苏大学 A kind of two-way air extractor
CN108799210B (en) * 2018-07-06 2024-05-14 江苏大学 Two-way air extractor
CN112708920A (en) * 2019-10-24 2021-04-27 亚洲电镀器材有限公司 Fluid delivery system and method of plating a workpiece

Also Published As

Publication number Publication date
US3823074A (en) 1974-07-09
NL171544B (en) 1982-11-16
DE1966780A1 (en) 1975-04-03
US3751297A (en) 1973-08-07
DE1966780C3 (en) 1979-12-06
US3664354A (en) 1972-05-23
NL171544C (en) 1983-04-18
NL6917010A (en) 1970-05-14
AT303483B (en) 1972-11-27
DE1956567A1 (en) 1970-06-18
DE1956567B2 (en) 1975-05-22
DE1966780B2 (en) 1979-04-12
US3823083A (en) 1974-07-09
BE741527A (en) 1970-04-16
GB1301678A (en) 1973-01-04

Similar Documents

Publication Publication Date Title
US3620813A (en) Method of treating workpieces in a treating fluid
US3731647A (en) Apparatus for processing containers
US4051805A (en) Can washing and coating system
US3311085A (en) Apparatus for coating objects
US2279686A (en) Method and apparatus for cleaning and painting
CN106111633B (en) A kind of Full-automatic metal pipe Surface of profile processing method and device structure
JPH05154419A (en) Method and device for surface treatment of di can
JP2010536567A5 (en)
CN104538503A (en) Showering-type wet-process velvet making equipment with solar silicon chips and method
US3519817A (en) Apparatus and method for irradiating continuously flowing liquids
KR100867237B1 (en) Method and apparatus, with redundancies, for treating substrate plastic parts to accept paint without using adhesion promoters
EP0046867A1 (en) Process for phosphating of objects
JPS5827342B2 (en) Inquiry
CN207259591U (en) A kind of new phosphide groove
US4004349A (en) Method for fluid conveyance of articles
KR101686419B1 (en) System and method for surface treatment for rust proof
JP5245089B2 (en) Steel bar coating equipment
CN109482452A (en) Aluminum profile vertical powder workmanship of spraying plastics
US4063564A (en) Vibratory cleaning and coating system
JP2010005536A (en) Coating apparatus for steel bar
KR101681557B1 (en) Shot blast apparatus, and system and method for surface treatment system using shot blast
US2089648A (en) Method of and apparatus for treating metal surfaces
DE1956567C3 (en) Device for conveying and treating workpieces in pipelines
CN221360510U (en) Conveying mechanism for spraying liquid
CN213507150U (en) Quick cooling device is used in hot-galvanize production

Legal Events

Date Code Title Description
AS Assignment

Owner name: OXY METAL INDUSTRIES CORPORATION

Free format text: CHANGE OF NAME;ASSIGNOR:OXY METAL FINISHING CORPORATION;REEL/FRAME:003967/0084

Effective date: 19741220

AS Assignment

Owner name: HOOKER CHEMICALS & PLASTICS CORP.

Free format text: MERGER;ASSIGNOR:OXY METAL INDUSTRIES CORPORATION;REEL/FRAME:004075/0885

Effective date: 19801222

AS Assignment

Owner name: OCCIDENTAL CHEMICAL CORPORATION

Free format text: CHANGE OF NAME;ASSIGNOR:HOOKER CHEMICAS & PLASTICS CORP.;REEL/FRAME:004126/0054

Effective date: 19820330

AS Assignment

Owner name: OMI INTERNATIONAL CORPORATION, 21441 HOOVER ROAD,

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:OCCIDENTAL CHEMICAL CORPORATION;REEL/FRAME:004190/0827

Effective date: 19830915

AS Assignment

Owner name: MANUFACTURERS HANOVER TRUST COMPANY, A CORP OF NY

Free format text: SECURITY INTEREST;ASSIGNOR:INTERNATIONAL CORPORATION, A CORP OF DE;REEL/FRAME:004201/0733

Effective date: 19830930