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KR870003972A - 측쇄액정중합체를 형성할수 있는 비닐단량체 및 그의 중합체 - Google Patents

측쇄액정중합체를 형성할수 있는 비닐단량체 및 그의 중합체 Download PDF

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Publication number
KR870003972A
KR870003972A KR1019860008651A KR860008651A KR870003972A KR 870003972 A KR870003972 A KR 870003972A KR 1019860008651 A KR1019860008651 A KR 1019860008651A KR 860008651 A KR860008651 A KR 860008651A KR 870003972 A KR870003972 A KR 870003972A
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South Korea
Prior art keywords
polymer
compound
liquid crystal
vinyl monomer
general formula
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KR1019860008651A
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English (en)
Inventor
메티아스 론제이.
이. 헤름즈 로버트
Original Assignee
카렌엠. 야르부로우
유니버시티 오브서던 미시시피
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Application filed by 카렌엠. 야르부로우, 유니버시티 오브서던 미시시피 filed Critical 카렌엠. 야르부로우
Publication of KR870003972A publication Critical patent/KR870003972A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/45—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups
    • C07C233/46—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/47—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C09K19/3833—Polymers with mesogenic groups in the side chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/10—Dispersions; Emulsions
    • A61K9/107—Emulsions ; Emulsion preconcentrates; Micelles
    • A61K9/1075—Microemulsions or submicron emulsions; Preconcentrates or solids thereof; Micelles, e.g. made of phospholipids or block copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/10—Dispersions; Emulsions
    • A61K9/127—Liposomes
    • A61K9/1271—Non-conventional liposomes, e.g. PEGylated liposomes, liposomes coated with polymers
    • A61K9/1273—Polymersomes; Liposomes with polymerisable or polymerised bilayer-forming substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Dispersion Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Molecular Biology (AREA)
  • Biophysics (AREA)
  • Polyamides (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

내용 없음

Description

측쇄액정중합체를 형성할수 있는 비닐단량체 및 그의 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 중합된 단량체에 의해 생성된 기포의 S.E.M. 사진이며, 다음의 실시예4에서 설명한다.
제2도는 제1도의 깨어진 기포의 사진이다.
제3도는 공기/물 경계면에서 N-스테아로일디 히드로알라닌 메틸 에스테르로 이루어진 단층의 압력 대면적 곡선이며, 다음의 실시예 22에서 설명한다.

Claims (19)

  1. 일반식
    인 것을 특징으로 하는 화합물.
    여기에서 R1은 장쇄알킬기, 아릴기, 치환장쇄 알킬기 및 치환 아릴기에서 선택되며, R2는 수소원자, 알킬, 아릴로 구성되는 기에서 선택된다.
  2. 제1항에 있어서, R1은 C5내지 C20알킬인 것을 특징으로 하는 화합물.
  3. 제1항에 있어서, R1은 C9H19이며 R2는 CH3인 것을 특징으로 하는 화합물.
  4. 제1항에 있어서, R1은 C5H11이며 R2는 CH3인 것을 특징으로 하는 화합물.
  5. 제1항에 있어서, R1은 C13H27이며 R2는 CH3인 것을 특징으로 하는 화합물.
  6. 제1항에 있어서, R1은 C17H3이며 R2는 CH3인 것을 특징으로 하는 화합물.
  7. 일반식
    인 반복단위를 함유하는 것을 특징으로 하는 중합체.
    여기에서 R1및 R2는 제1항에서 정의한 바와 같다.
  8. 제7항에 있어서, 약 10,000 내지 약 14,000,000 범위의 분자량을 같는 것을 특징으로 하는 중합체.
  9. 제7항에 있어서, R1은 C9H19이며 R2는 CH3인 것을 특징으로 하는 중합체.
  10. 제7항에 있어서, R1은 C5H11이며 R2는 CH3인 것을 특징으로 하는 중합체.
  11. 제7항에 있어서, R1은 C13H27이며 R2는 CH3인 것을 특징으로 하는 중합체.
  12. 제7항에 있어서, R1은 C17H35이며 R2는 CH3인 것을 특징으로 하는 중합체.
  13. 제7항에 있어서, 유리기 중합법에 의해 생성되는 것을 특징으로 하는 중합체.
  14. 제7항에 있어서, 안정적인 기포, 미셀 또는 단층의 형태인 것을 특징으로 하는 중합체.
  15. 일반식
    반복단위를 함유하는 젓을 특징으로 하는 중합체.
    여기에서 R1및 R2는 제1항에 정의한 바와 같다.
  16. 제15항에 있어서, 약 10,000 내지 약 1,500,000 범위의 분자량을 갖는 것을 특징으로 하는 중합체.
  17. 제15항에 있어서, R1은 C9H19이며 R2는 CH3인 것을 특징으로 하는 중합체.
  18. 제15항에 있어서, R1은 C17H35이며 R2는 CH3인 것을 특징으로 하는 중합체.
  19. 제15항에 있어서, 음이온 중합법에 의해 생성되는 것을 특징으로 하는 중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860008651A 1985-10-15 1986-10-15 측쇄액정중합체를 형성할수 있는 비닐단량체 및 그의 중합체 KR870003972A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/787,051 US4613658A (en) 1985-10-15 1985-10-15 Vinyl monomers capable of forming side-chain liquid crystalline polymers and the resulting polymers
US787,051 1985-10-15

Publications (1)

Publication Number Publication Date
KR870003972A true KR870003972A (ko) 1987-05-06

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ID=25140282

Family Applications (1)

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KR1019860008651A KR870003972A (ko) 1985-10-15 1986-10-15 측쇄액정중합체를 형성할수 있는 비닐단량체 및 그의 중합체

Country Status (7)

Country Link
US (1) US4613658A (ko)
EP (1) EP0219344B1 (ko)
JP (1) JPS6293264A (ko)
KR (1) KR870003972A (ko)
CA (1) CA1298310C (ko)
DE (1) DE3678784D1 (ko)
DK (1) DK490586A (ko)

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US6486344B1 (en) * 2001-07-26 2002-11-26 Jaques Penelle Polymer coatings with improved adhesion properties on metallic surfaces
US9279022B1 (en) 2014-09-08 2016-03-08 Sirrus, Inc. Solution polymers including one or more 1,1-disubstituted alkene compounds, solution polymerization methods, and polymer compositions
US10414839B2 (en) 2010-10-20 2019-09-17 Sirrus, Inc. Polymers including a methylene beta-ketoester and products formed therefrom
US9249265B1 (en) 2014-09-08 2016-02-02 Sirrus, Inc. Emulsion polymers including one or more 1,1-disubstituted alkene compounds, emulsion methods, and polymer compositions
US9828324B2 (en) 2010-10-20 2017-11-28 Sirrus, Inc. Methylene beta-diketone monomers, methods for making methylene beta-diketone monomers, polymerizable compositions and products formed therefrom
CA2853073A1 (en) 2011-10-19 2013-04-25 Bioformix Inc. Methylene beta-diketone monomers, methods for making methylene beta-diketone monomers, polymerizable compositions and products formed therefrom
US9234107B2 (en) 2012-03-30 2016-01-12 Sirrus, Inc. Ink coating formulations and polymerizable systems for producing the same
EP2831124B1 (en) 2012-03-30 2016-10-05 Sirrus, Inc. Composite and laminate articles and polymerizable systems for producing the same
US10047192B2 (en) 2012-06-01 2018-08-14 Sirrus, Inc. Optical material and articles formed therefrom
WO2014078689A1 (en) 2012-11-16 2014-05-22 Bioformix Inc. Plastics bonding systems and methods
US10607910B2 (en) 2012-11-30 2020-03-31 Sirrus, Inc. Composite compositions for electronics applications
CN105008321A (zh) 2013-01-11 2015-10-28 瑟拉斯公司 经过双(羟甲基)丙二酸酯的途径获得亚甲基丙二酸酯的方法
US9416091B1 (en) 2015-02-04 2016-08-16 Sirrus, Inc. Catalytic transesterification of ester compounds with groups reactive under transesterification conditions
US9315597B2 (en) 2014-09-08 2016-04-19 Sirrus, Inc. Compositions containing 1,1-disubstituted alkene compounds for preparing polymers having enhanced glass transition temperatures
US10501400B2 (en) 2015-02-04 2019-12-10 Sirrus, Inc. Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions
US9334430B1 (en) 2015-05-29 2016-05-10 Sirrus, Inc. Encapsulated polymerization initiators, polymerization systems and methods using the same
US9217098B1 (en) 2015-06-01 2015-12-22 Sirrus, Inc. Electroinitiated polymerization of compositions having a 1,1-disubstituted alkene compound
US9518001B1 (en) 2016-05-13 2016-12-13 Sirrus, Inc. High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation
US10196481B2 (en) 2016-06-03 2019-02-05 Sirrus, Inc. Polymer and other compounds functionalized with terminal 1,1-disubstituted alkene monomer(s) and methods thereof
US9567475B1 (en) 2016-06-03 2017-02-14 Sirrus, Inc. Coatings containing polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
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DE3237309A1 (de) * 1982-10-08 1984-04-12 Hoechst Ag, 6230 Frankfurt N-vinylcarbonsaeureamide
FR2538385B1 (fr) * 1982-12-27 1985-09-13 Solvay Composes enamides acyles, compositions pharmaceutiques les contenant, utilisation de ces composes et procede de preparation de ces composes

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US4613658A (en) 1986-09-23
EP0219344A1 (en) 1987-04-22
JPS6293264A (ja) 1987-04-28
CA1298310C (en) 1992-03-31
DK490586D0 (da) 1986-10-14
DE3678784D1 (de) 1991-05-23
DK490586A (da) 1987-04-16
EP0219344B1 (en) 1991-04-17

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