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JPH06202560A - Moisture reactive label - Google Patents

Moisture reactive label

Info

Publication number
JPH06202560A
JPH06202560A JP136193A JP136193A JPH06202560A JP H06202560 A JPH06202560 A JP H06202560A JP 136193 A JP136193 A JP 136193A JP 136193 A JP136193 A JP 136193A JP H06202560 A JPH06202560 A JP H06202560A
Authority
JP
Japan
Prior art keywords
moisture
dye
water
colored layer
label
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP136193A
Other languages
Japanese (ja)
Inventor
Masanaga Yamagou
眞永 山郷
Yuichi Nishikawa
祐一 西川
Yukio Ito
幸雄 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP136193A priority Critical patent/JPH06202560A/en
Publication of JPH06202560A publication Critical patent/JPH06202560A/en
Pending legal-status Critical Current

Links

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  • Laminated Bodies (AREA)

Abstract

PURPOSE:To make the color of a colored layer change by submerging the product and to discriminate the change even after drying by using a dye being colored with moisture, decolored or discolored and root returning to the original state as a colorant of the colored layer. CONSTITUTION:A moisture reactive label consists of a base material 1 and the colored layer 2. The colored layer 2 uses the dye being colored with moisture, decolored or discolored and also not returning to the original state after drying as the colorant, and the dye is dispersed into an optional binder to prepare an ink and the label is formed by applying the ink on the base surface. In this case, the reaction speed between the dye and moisture and the sensitivity can be controlled by a kind of the using binder and the quantity and also the flowing down, when the dye coming into contact with moisture, can be prevented. Such a moisture reactive label can be used as indicators of an electric product generating troubles such as fault in case of sticking of moisture and submergence or 8 fine instrument, etc., and a bottom part of a case conveying and storing a container.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、戸外で使用する電気製
品等の内部に貼着して、該電気製品等が水没した経歴が
あるか否かを判定するために用いられる水分反応ラベル
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water-reactive label which is attached to the inside of an electric product or the like used outdoors and used to determine whether the electric product or the like has a history of being submerged in water. It is a thing.

【0002】[0002]

【従来の技術】ラジオ、ビデオカメラ、ポケットベル、
携帯用電話機等の戸外で使用する電気製品等は、雨に濡
れたり水が掛かったりするという危険性が比較的高いも
のであるため、ある程度の耐水性が考慮されている。し
かし、誤って水たまりに落としたり、水を入れた容器の
中に落としたりしてその内部の回路等が水に濡れ、電気
製品としての機能が損なわれてしまう場合があり、この
様な場合は、使用者すなわち一般消費者の不注意による
ものとして有料修理の対象としている。ところが、故障
の原因が水没によるものなのか、通常の使用の範囲で生
じたものなのかの判別が難しく、トラブルの原因となる
場合もあった。
2. Description of the Related Art Radios, video cameras, pagers,
Electric appliances and the like used outdoors such as mobile phones have a relatively high risk of getting wet with rain or splashing with water, so that some degree of water resistance is considered. However, if you drop it in a puddle or drop it in a container filled with water, the internal circuits may get wet and the function as an electrical product may be impaired. , Is subject to paid repairs due to the carelessness of the user, that is, the general consumer. However, it is difficult to determine whether the cause of the failure is due to submersion in water or in the range of normal use, which may cause trouble.

【0003】そこで、水性インキを塗布したラベルを予
め製品の内部に貼着しておき、故障が発生した場合には
ラベルの状態を確認して、水性インキが滲んでいるか否
か、あるいは変色しているか否かによって故障の原因を
判別していた。
Therefore, a label coated with a water-based ink is adhered to the inside of the product in advance, and when a failure occurs, the state of the label is checked to see if the water-based ink is bleeding or discolored. The cause of the failure was determined by whether or not

【0004】ところが従来のラベルは、 (1)滲んだインキが機械内部を汚す。 (2)滲ませるために必要な水分量のコントロールが難
しく、結果的には多量の水が作用しないと滲みを生じな
い。 (3)同種のインキが入手できれば、ラベルを改竄する
ことができる。 (4)コバルト系あるいはアミン系等の染料を用いたイ
ンキを用いると、インキの変色によって水没したことが
判別できるが、それが乾いてしまうと元の状態に戻って
しまい判別できなくなる。 という欠点があった。
However, in the conventional label, (1) the bleeding ink stains the inside of the machine. (2) It is difficult to control the amount of water necessary for bleeding, and as a result, bleeding does not occur unless a large amount of water acts. (3) If the same type of ink is available, the label can be tampered with. (4) When an ink using a cobalt-based or amine-based dye is used, it can be determined that the ink is submerged due to the discoloration of the ink, but when it is dried, it returns to its original state and cannot be identified. There was a drawback.

【0005】[0005]

【発明が解決しようとする課題】本発明は以上の様な従
来の状況に鑑みて成されたものであり、製品の水没によ
って着色層が変化し、乾燥後もその変化したことが明確
に判別でき、しかも機械の内部を汚すという様な問題の
ないラベルを提供するものである。
SUMMARY OF THE INVENTION The present invention has been made in view of the above conventional circumstances, and it is clearly discriminated that the colored layer changes due to the submersion of the product, and the change occurs even after drying. It is possible to provide a label which can be produced and which does not have a problem of soiling the inside of the machine.

【0006】[0006]

【課題を解決するための手段】すなわち本発明は、基材
と着色層とから成るラベルであって、該着色層が、水分
によって発色、変色、または失色し、かつ乾燥後に元の
状態に復帰しない染料を着色剤として用いていることを
特徴とする水分反応ラベルである。
That is, the present invention is a label comprising a base material and a colored layer, the colored layer being colored, discolored or discolored by moisture and returning to its original state after drying. It is a moisture-reactive label characterized by using a dye not used as a colorant.

【0007】以下、図面を参照しながら本発明の水分反
応ラベルを詳細に説明する。すなわち本発明の水分反応
ラベルは、図1に示す様に基材(1)と着色層(2)と
から成っている。基材(1)は、紙、合成樹脂フィルム
等従来からラベル基材として用いられているものであれ
ば任意に使用できる。ただし、これらの基材の表面に吸
水性層を形成したもの、多孔質構造体、不織布等を用い
れば、着色層中の染料が該吸水性層や基材に浸透し、水
と接触した際にも流れ落ちを防止できるので好ましい。
また、この染料が水分と反応する際にも、吸水性層や基
材に水が徐々に浸透して反応するので、吸水性層や基材
の染料や水に対する浸透の度合いを調節することによっ
て、染料と水の反応速度や感度をコントロールすること
ができる。
Hereinafter, the moisture responsive label of the present invention will be described in detail with reference to the drawings. That is, the moisture-reactive label of the present invention comprises a substrate (1) and a colored layer (2) as shown in FIG. The substrate (1) can be arbitrarily used as long as it has been conventionally used as a label substrate such as paper and synthetic resin film. However, when a material having a water absorbing layer formed on the surface of these base materials, a porous structure, a non-woven fabric, or the like is used, when the dye in the coloring layer penetrates into the water absorbing layer or the base material and comes into contact with water. Also, it is preferable because it can prevent runoff.
Further, even when this dye reacts with water, water gradually penetrates into the water-absorbent layer or the base material and reacts, so that by adjusting the degree of penetration of the water-absorbent layer or base material into the dye or water. , The reaction speed and sensitivity of dye and water can be controlled.

【0008】着色層(2)は水分によって発色、変色、
または失色し、かつ乾燥後に元の状態に復帰しない染料
を着色剤として用いており、この染料を任意のバインダ
ーに分散させてインキ化し、基材表面に塗布することで
形成できる。この場合、使用するバインダーの種類や量
によって染料と水の反応速度や感度をコントロールする
ことができ、かつ、染料が水と接触した際に流れ落ちる
のを防止することができる。また、バインダーと共に吸
水性粉体を添加することで多孔質構造の着色層を形成し
て、水分と染料の反応速度及び感度をコントロールする
とともに、染料の流れ落ちを防ぐ効果を付加することも
可能である。吸水性粉体は親水性を有することが望まし
く、デンプン、カオリン、タルク、微粉末セルロース、
ケイ酸アルミニウム、酸化ケイ素、炭酸カルシウム等が
用いられる。バインダーは染料と吸水性粉体を基材に固
着するために用いられ、有機溶剤に可溶な樹脂であれば
いずれも使用できる。例えば、ポリエステル系樹脂、ア
クリル系樹脂、ポリアミド系樹脂、ポリアセタール系樹
脂、ポリウレタン系樹脂、エポキシ系樹脂、石油系樹
脂、セルロース系樹脂等が使用できるが、バインダーが
なくても、水分によって発色、変色、または失色する能
力を失うことはない。
The colored layer (2) is colored or discolored by moisture.
Alternatively, a dye that loses its color and does not return to its original state after drying is used as a colorant. The dye can be formed by dispersing the dye in an arbitrary binder to form an ink and applying the ink to the surface of the substrate. In this case, the reaction rate and sensitivity of the dye and water can be controlled by the kind and amount of the binder used, and the dye can be prevented from flowing down when it comes into contact with water. In addition, it is possible to form a colored layer having a porous structure by adding a water-absorbing powder together with a binder to control the reaction rate and sensitivity of water with the dye and to add the effect of preventing the dye from flowing off. is there. It is desirable that the water-absorbing powder has hydrophilicity, such as starch, kaolin, talc, fine powder cellulose,
Aluminum silicate, silicon oxide, calcium carbonate, etc. are used. The binder is used to fix the dye and the water-absorbing powder to the substrate, and any resin soluble in an organic solvent can be used. For example, polyester-based resin, acrylic resin, polyamide-based resin, polyacetal-based resin, polyurethane-based resin, epoxy-based resin, petroleum-based resin, cellulose-based resin, etc. can be used, but even if there is no binder, coloring or discoloration due to moisture , Or lose the ability to bleach.

【0009】染料と水の反応速度や感度をコントロール
したり染料が水と接触した際に流れ落ちるのを防止する
手段としては、着色層(2)の上に水分が通過可能な樹
脂層を形成する方法もある。すなわち、着色層(2)の
上に、ポリアクリル酸、イソブチレン無水マレイン酸、
ポリエチレンオキサイド等の樹脂組成物を塗布して樹脂
層を形成したり、それらの樹脂から成るフィルムを張り
合わせて樹脂層とすることによって、水分の通過量を調
節したり染料の流れ落ちを防止することができる。
As a means for controlling the reaction rate and sensitivity of the dye and water and for preventing the dye from flowing down when it comes into contact with water, a resin layer through which water can pass is formed on the colored layer (2). There is also a method. That is, on the colored layer (2), polyacrylic acid, isobutylene maleic anhydride,
By coating a resin composition such as polyethylene oxide to form a resin layer, or by laminating films made of these resins to form a resin layer, it is possible to control the amount of water passing through and prevent the dye from flowing off. it can.

【0010】以上の様な構成から成る本発明の水分反応
ラベルは、水分の付着や水没によって故障等の不具合を
生じる電気製品や精密機器に使用する他、容器を運搬ま
たは保管するケースの底部分に用いたり、水道やボイラ
ーの管あるいはウオーターポンプ等の水漏れを検出する
インジケーターとして、種々の機器や設備の水漏れの経
路を調べる手段として、等に利用することができる。
The water-reactive label of the present invention having the above-mentioned structure is used for electric appliances and precision instruments which cause troubles such as failure due to adhesion of water or submersion in water, and the bottom portion of a case for transporting or storing a container. It can be used as an indicator for detecting water leaks in water pipes, boiler pipes, water pumps, and the like, as a means for checking water leak paths of various devices and equipment, and the like.

【0011】[0011]

【発明の効果】本発明の水分反応ラベルは以上の様な構
成であるので、 水没等によって水に濡れ、その後時間が経過してラベ
ルが乾いた後でも、水に濡れたことが明確に判別でき
る。 水に濡れても染料がラベルから流れ落ちることがな
く、機器の内部を汚すことがない。 使用する染料やバインダーや吸水性粉体あるいは基材
の選択、あるいは表面処理をすることによって、染料と
水の反応速度や感度をコントロールすることができ、か
つ、染料が水と接触した際に流れ落ちるのを防止するこ
とができる。 という効果を有する。
Since the water-reactive label of the present invention has the above-mentioned constitution, it can be clearly discriminated that the water-reactive label has been wetted with water even after being immersed in water due to submersion or the like and then the label has dried after a lapse of time. it can. The dye will not run off the label when it gets wet and will not contaminate the inside of the device. The reaction speed and sensitivity of the dye and water can be controlled by selecting the dye, binder, water-absorbing powder or base material to be used, or by surface treatment, and the dye runs off when it comes into contact with water. Can be prevented. Has the effect.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の水分反応ラベルの実施例を示す断面図
である。
FIG. 1 is a cross-sectional view showing an example of a moisture reaction label of the present invention.

【符号の説明】[Explanation of symbols]

1 基材 2 着色層 1 base material 2 colored layer

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】基材と着色層とから成るラベルであって、
該着色層が、水分によって発色、変色、または失色し、
かつ乾燥後に元の状態に復帰しない染料を着色剤として
用いていることを特徴とする水分反応ラベル。
1. A label comprising a substrate and a colored layer, comprising:
The colored layer develops, discolors, or loses color due to moisture,
A water-reactive label characterized by using a dye that does not return to its original state after drying as a coloring agent.
【請求項2】染料がその内部に浸透し易い基材を用いた
ことを特徴とする、請求項1に記載の水分反応ラベル。
2. The moisture-reactive label according to claim 1, wherein a base material into which the dye easily penetrates is used.
【請求項3】着色層の上に水分が通過可能な樹脂層を形
成したことを特徴とする、請求項1〜2のいずれかひと
つに記載の水分反応ラベル。
3. The moisture reaction label according to claim 1, wherein a resin layer through which moisture can pass is formed on the colored layer.
JP136193A 1993-01-07 1993-01-07 Moisture reactive label Pending JPH06202560A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP136193A JPH06202560A (en) 1993-01-07 1993-01-07 Moisture reactive label

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP136193A JPH06202560A (en) 1993-01-07 1993-01-07 Moisture reactive label

Publications (1)

Publication Number Publication Date
JPH06202560A true JPH06202560A (en) 1994-07-22

Family

ID=11499359

Family Applications (1)

Application Number Title Priority Date Filing Date
JP136193A Pending JPH06202560A (en) 1993-01-07 1993-01-07 Moisture reactive label

Country Status (1)

Country Link
JP (1) JPH06202560A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997013235A1 (en) * 1995-10-04 1997-04-10 Sumitomo Chemical Company, Limited Indicator
JP2003179366A (en) * 1997-01-09 2003-06-27 Hitachi Kokusai Electric Inc Portable electronic apparatus
US7105225B2 (en) 2001-10-05 2006-09-12 3M Innovative Properties Company Water contract indicator
JP2008090010A (en) * 2006-10-02 2008-04-17 Tokujiro Okui Sheet for sensing wetting
US7732046B2 (en) 2003-11-14 2010-06-08 3M Innovative Properties Company Water contact indicator
JP2012113120A (en) * 2010-11-24 2012-06-14 Dainippon Printing Co Ltd Wetting-detectable hologram label
JP2018187905A (en) * 2017-05-12 2018-11-29 パイロットインキ株式会社 Water-allochroic indicator

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997013235A1 (en) * 1995-10-04 1997-04-10 Sumitomo Chemical Company, Limited Indicator
JP2003179366A (en) * 1997-01-09 2003-06-27 Hitachi Kokusai Electric Inc Portable electronic apparatus
US7105225B2 (en) 2001-10-05 2006-09-12 3M Innovative Properties Company Water contract indicator
US7744997B2 (en) 2001-10-05 2010-06-29 3M Innovative Properties Company Water contact indicator
US7732046B2 (en) 2003-11-14 2010-06-08 3M Innovative Properties Company Water contact indicator
US8182914B2 (en) 2003-11-14 2012-05-22 3M Innovative Properties Company Water contact indicator
JP2008090010A (en) * 2006-10-02 2008-04-17 Tokujiro Okui Sheet for sensing wetting
JP2012113120A (en) * 2010-11-24 2012-06-14 Dainippon Printing Co Ltd Wetting-detectable hologram label
JP2018187905A (en) * 2017-05-12 2018-11-29 パイロットインキ株式会社 Water-allochroic indicator

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