JP5433836B2 - Carbon fiber reinforced composite material of woven fabric wrapped with thermoplastic fiber yarn - Google Patents
Carbon fiber reinforced composite material of woven fabric wrapped with thermoplastic fiber yarn Download PDFInfo
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- JP5433836B2 JP5433836B2 JP2007135349A JP2007135349A JP5433836B2 JP 5433836 B2 JP5433836 B2 JP 5433836B2 JP 2007135349 A JP2007135349 A JP 2007135349A JP 2007135349 A JP2007135349 A JP 2007135349A JP 5433836 B2 JP5433836 B2 JP 5433836B2
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- 229920000049 Carbon (fiber) Polymers 0.000 title claims description 123
- 239000004917 carbon fiber Substances 0.000 title claims description 123
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 116
- 229920001169 thermoplastic Polymers 0.000 title claims description 30
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 30
- 239000002759 woven fabric Substances 0.000 title claims description 25
- 239000000835 fiber Substances 0.000 title claims description 24
- 239000011208 reinforced composite material Substances 0.000 title claims description 16
- 238000009958 sewing Methods 0.000 claims description 29
- 229920002994 synthetic fiber Polymers 0.000 claims description 20
- 239000012209 synthetic fiber Substances 0.000 claims description 20
- 239000004744 fabric Substances 0.000 claims description 19
- 238000004804 winding Methods 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000011295 pitch Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 238000009941 weaving Methods 0.000 description 7
- 230000002787 reinforcement Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000013307 optical fiber Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
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- Reinforced Plastic Materials (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
Description
本発明は、繊維強化分野における、特に熱可塑性繊維糸を巻縫いした織物の炭素繊維強化複合材料に関するものである。 The present invention relates to a carbon fiber reinforced composite material of a woven fabric in which a thermoplastic fiber yarn is wound in particular, in the field of fiber reinforcement.
本出願人は、自動車やモーターボートのボディ等を補強するのに、規格外で廃棄処分される光ファイバーを織物として製織し、有効にリサイクルすることを提案している。 The present applicant has proposed that an optical fiber discarded outside the standard is woven as a woven fabric and effectively recycled to reinforce the body of an automobile or a motor boat.
規格外の廃棄処分される光ファイバーを利用すると、費用は格安となって好ましいが、光ファイバーは滑りやすいので天然や合成の繊維糸と絡ませて織物糸としており、また光ファイバーなので折曲したりすると、途中で切断することがあり、その用途は限定される。 Using non-standard discarded optical fiber is preferable because the cost is low, but the fiber is slippery, so it is entangled with natural or synthetic fiber yarn, and it is woven, and if it is an optical fiber, it will be bent halfway. May be cut at a limited time.
また、使用する光ファイバーは、極細状で軽量であるが、多数本を組み合わせると軽量ではなくなってくる。 Moreover, although the optical fiber to be used is very thin and lightweight, when many fibers are combined, it becomes lighter.
一方、軽量で強度が高いことから、炭素繊維の利用が航空機や自動車、ボート、スポーツ分野で行なわれている。たとえば、特開2003−20542号公報や特開10−102792号公報などのように炭素繊維糸を織物や布帛として航空機や構造物の補強用に利用することが提案されている。
しかし、炭素繊維は、単繊維糸径が4〜20μmといった極細の繊維長30〜500mmといった短繊維と長繊維のものを数十本〜数千本サイジング剤等で付着して炭素繊維糸としているもので、織物とするときに単繊維糸がばらけたり、毛羽だったり、剥がれたりしやすく、また炭素繊維糸を織物としてもその厚さが薄いので何枚も重ね合わせなければならざず、その重ね合わせるのにプリプレグ工程等が必要となったりして相当の手間がかかるものであった。 However, carbon fibers are made of carbon fiber yarns by attaching tens of to thousands of sizing agents or the like with short fibers and long fibers such as ultrafine fibers having a single fiber yarn diameter of 4 to 20 μm and lengths of 30 to 500 mm. In the case of woven fabrics, single fiber yarns are scattered, fluffy, and easy to peel off, and carbon fiber yarns are also thin as woven fabrics, so many sheets must be stacked, In order to superimpose it, a prepreg process or the like is required, which requires considerable labor.
そのため、炭素繊維糸にカバリング精紡機でカバリングすることも提案されているが、一本一本の炭素繊維糸にカバリングするもので、装置も大掛かりとなり、手間もかかり、またそのカバリングが伸縮しやすいもので品質が安定しにくいものであった。 For this reason, it is also proposed to cover carbon fiber yarns with a spinning spinning machine, but it is also possible to cover each carbon fiber yarn, which requires a large amount of equipment and labor, and the covering is easy to expand and contract. The quality was difficult to stabilize.
本発明は、上記のような点に鑑みたもので、上記の課題を解決するために、オーバロックミシンやロックミシンのメローミシンでマルチフィラメントを束ねた炭素繊維束の1束ないし複数束に熱可塑性の合成繊維糸の掛合糸をループ状に巻縫い掛合して炭素繊維束糸を形成し、この形成した炭素繊維束糸を経糸および/または緯糸として所定の大きさの織物に作製し、作製した炭素繊維束糸の織物を加熱して熱可塑性の合成繊維糸のループ状にそれぞれ巻縫い掛合した掛合糸を溶融させて炭素繊維強化複合材料を形成したことを特徴とする熱可塑性繊維糸を巻縫いした織物の炭素繊維強化複合材料を提供するにある。 The present invention has been made in view of the above points, and in order to solve the above-described problems, one or more bundles of carbon fiber bundles in which multifilaments are bundled with an overlock sewing machine or a mellow sewing machine of a lock sewing machine are thermoplastic. A carbon fiber bundle yarn was formed by winding and looping the synthetic fiber yarns in a loop shape, and the formed carbon fiber bundle yarns were produced as warps and / or wefts into a woven fabric of a predetermined size. A carbon fiber reinforced composite material is formed by heating a woven fabric of carbon fiber bundle yarns and melting the hook yarns wound in loops of thermoplastic synthetic fiber yarns to form a carbon fiber reinforced composite material. It is in providing a carbon fiber reinforced composite material of a sewn fabric.
なお、マルチフィラメントを束ねた炭素繊維束の複数束を断面が3芯状や7芯状の多芯ロープ状に束ねた状態として、熱可塑性の合成繊維糸の掛合糸を巻縫い掛合して、多芯状の炭素繊維束糸を形成することができる。 In addition, as a state where a plurality of bundles of carbon fiber bundles in which multifilaments are bundled are bundled in a multicore rope shape having a cross section of 3 cores or 7 cores, a loop of a thermoplastic synthetic fiber thread is wound and sewn, A multi-core carbon fiber bundle yarn can be formed .
また、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束にロックミシンのメローミシンで2〜5mmのピッチで熱可塑性の合成繊維糸の掛合糸を巻縫い掛合して炭素繊維束糸を形成することもできる。 Also , a carbon fiber bundle yarn is formed by winding and staking a synthetic yarn yarn of thermoplastic synthetic yarn at a pitch of 2 to 5 mm on one or more bundles of carbon fiber bundles in which multifilaments are bundled with a mellow sewing machine of a lock sewing machine. You can also.
そしてまた、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束にロックミシンのメローミシンで2〜5mmのピッチで熱可塑性の合成繊維糸の掛合糸を巻縫い掛合して炭素繊維束糸を形成し、この熱可塑性の合成繊維糸の掛合糸を巻縫いした炭素繊維束糸による織物を複数層重ね合わせたことを特徴とする熱可塑性繊維糸を巻縫いした織物の炭素繊維強化複合材料を提供するにある。 In addition, one or more carbon fiber bundles in which multifilaments are bundled are wound together with a lock sewing machine mellow sewing machine with 2-5 mm pitches of thermoplastic synthetic yarns to form carbon fiber bundle yarns. And providing a carbon fiber reinforced composite material of a woven fabric wrapped with thermoplastic fiber yarns, characterized in that a plurality of layers of carbon fiber bundle yarns obtained by wrapping these thermoplastic synthetic fiber yarns are overlapped. There is.
なお、熱可塑性の合成繊維糸の掛合糸を巻縫い掛合した炭素繊維束糸を製織した織物の炭素繊維束糸の方向が、交互に45度毎に対応するように積層することもできる。 The direction of the thermoplastic engaging yarns of synthetic fiber yarn winding sewing engagement with carbon fiber Tabaito of fabric woven carbon fiber bundle yarns, may be laminated alternately so as to correspond to each 45 °.
本発明の熱可塑性繊維糸を巻縫いした織物の炭素繊維強化複合材料は、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束に熱可塑性の合成繊維糸の掛合糸をループ状に巻縫い掛合して炭素繊維束糸を形成し、この形成した炭素繊維束糸を経糸および/または緯糸として所定の大きさの織物に作製することによって、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束を掛合糸でループ状に巻縫いでき、単繊維がばらけたり、毛羽立って、剥がれたりせず、かつループ状となった掛合糸でほとんど伸縮性のない炭素繊維束に弾力性を付与でき、経糸切れ、緯糸切れを起こすことなく非常に製織性が向上でき、また撚りがかからずに巻縫いすることができて、非常に細く折れやすい単炭素繊維糸を切断することなく巻縫いできて、炭素繊維糸の強度を低下させることを防止できて織物に製織することができる。
そして、この形成した炭素繊維束糸を経糸および/または緯糸として所定の大きさの織物に作製し、作製した炭素繊維束糸の織物を加熱して熱可塑性の合成繊維糸の掛合糸を溶融させることで、容易に樹脂を溶融させた炭素繊維強化複合材料を形成することができるものであり、成形工程の省力化がはかれる。また、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束であっても、撚りがかからずに簡単に巻縫いできて分厚く製織することができ、被補強物に補強する場合に従来に比して少ない積層で補強でき、補強の手間を低減できて補強できる。
The carbon fiber reinforced composite material of a woven fabric in which the thermoplastic fiber yarn of the present invention is wound is wound by looping a loop of a synthetic synthetic yarn thread into one or a plurality of carbon fiber bundles in which multifilaments are bundled. A carbon fiber bundle yarn is formed by binding, and the formed carbon fiber bundle yarn is produced as a warp and / or weft into a woven fabric of a predetermined size, so that one or a plurality of carbon fiber bundles in which multifilaments are bundled Bundles can be wound in loops with hooking yarns, single fibers can not be scattered, fluffed, peeled off, and looped hooking yarns can give elasticity to carbon fiber bundles that are hardly stretchable , warp breakage, can greatly improved weaving property without causing the weft thread breakage, and can also be wound stitched in less twist, it can wound stitching without cutting a very thin frangible single carbon fibers , Can be woven into fabrics can be prevented from reducing the strength of the carbon fiber yarn.
Then, the formed carbon fiber bundle yarn is produced as a warp and / or weft into a woven fabric of a predetermined size, and the produced carbon fiber bundle yarn fabric is heated to melt the hooking yarn of the thermoplastic synthetic fiber yarn. Thus, it is possible to easily form a carbon fiber reinforced composite material in which a resin is melted, and labor saving in the molding process can be achieved. In addition, even one or a plurality of carbon fiber bundles in which multifilaments are bundled can be easily wound without being twisted, and can be woven thickly. Reinforcement can be achieved with a smaller number of layers, and the labor and time required for reinforcement can be reduced.
なお、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束にロックミシンのメローミシンで2〜5mmのピッチで熱可塑性の合成繊維糸の掛合糸を巻縫い掛合して炭素繊維束糸を形成すると、マルチフィラメントを束ねた炭素繊維束を多芯ロープ状として掛合糸を巻縫い掛合でき、上記したように単繊維がばらけたり、毛羽立って剥がれたりせず、かつ炭素繊維束に弾力性を付与できて織物に製織することができ、掛合糸に熱可塑性繊維糸を使用することで、上記のように作製した炭素繊維糸の織物を加熱して容易に樹脂を溶融させて形成することができる。 A carbon fiber bundle yarn is formed by winding and staking a synthetic yarn yarn of thermoplastic synthetic yarn at a pitch of 2 to 5 mm with a lock sewing machine mellow sewing machine to one or a plurality of bundles of carbon fiber bundles in which multifilaments are bundled. The multi-filament bundled carbon fiber bundle can be wound into a multi-core rope, and the thread can be wound and sewn as described above, so that the single fiber does not scatter or fluff and peel off, and the carbon fiber bundle has elasticity. and can be granted can be woven into a fabric, the use of thermoplastic fibers yarn engaging yarn easily be shape formed by melting the resin by heating the fabric carbon fibers prepared as described above Can do.
また、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束にロックミシンのメローミシンで2〜5mmのピッチで熱可塑性の合成繊維糸の掛合糸を巻縫い掛合して炭素繊維束糸を形成することによって、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束をメローミシンで容易にかつ迅速に合成繊維糸の掛合糸を巻縫い掛合して炭素繊維束糸を製造でき、掛合糸に熱可塑性繊維糸を使用することで、上記のように作製した炭素繊維糸の織物を加熱して容易に樹脂を溶融させて形成することができる。 Also, a carbon fiber bundle yarn is formed by winding and staking a synthetic yarn yarn of thermoplastic synthetic yarn at a pitch of 2 to 5 mm on one or more bundles of carbon fiber bundles in which multifilaments are bundled with a mellow sewing machine of a lock sewing machine. As a result, one or more carbon fiber bundles in which multifilaments are bundled can be easily and quickly wrapped with synthetic fiber yarns to produce carbon fiber bundle yarns, which are thermoplastic. the use of fiber yarns, it is possible that form readily melted resin by heating the fabric carbon fibers prepared as above.
また、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束にロックミシンのメローミシンで2〜5mmのピッチで熱可塑性の合成繊維糸の掛合糸を巻縫い掛合して炭素繊維束糸を形成し、この熱可塑性の合成繊維糸の掛合糸を巻縫いした炭素繊維束糸による織物を複数層重ね合わせた巻縫いした炭素繊維糸による織物に成形することによって、上記したように単繊維がばらけたり、毛羽立って剥がれたりせず、かつ炭素繊維束に弾力性を付与できて織物に製織することができ、掛合糸に熱可塑性繊維糸を使用することで、できるだけ少ない積層として、樹脂を溶融させた炭素繊維強化複合材料を形成することができる。 Also, a carbon fiber bundle yarn is formed by winding a synthetic fiber yarn of a synthetic fiber yarn with a mellow sewing machine of a lock sewing machine at a pitch of 2 to 5 mm on one or a plurality of bundles of carbon fiber bundles in which multifilaments are bundled. A single fiber can be separated as described above by forming a woven fabric of carbon fiber bundles obtained by winding a plurality of layers of carbon fiber bundle yarns obtained by winding a loop of this synthetic synthetic fiber yarn. or not peeled off or fluffed and made impart elasticity to the carbon fiber bundle can be woven into a fabric, the use of thermoplastic fibers yarn engaging yarn and the smallest possible lamination, melt the resin A carbon fiber reinforced composite material can be formed.
なお、熱可塑性の合成繊維糸の掛合糸を巻縫い掛合した炭素繊維束糸を製織した織物の炭素繊維束糸の方向が、交互に45度毎に対応するように積層した巻縫いした炭素繊維糸による織物に成形して、積層する織物の強度を所要の均一状に形成することができる。
In addition, the carbon fiber bundled and sewed so that the direction of the carbon fiber bundle yarn of the woven fabric obtained by weaving the carbon fiber bundle yarn obtained by winding and winding the synthetic yarn of the thermoplastic synthetic fiber yarn alternately corresponds to every 45 degrees. It can be formed into a woven fabric made of yarn, and the strength of the woven fabric to be laminated can be formed to a required uniform shape.
本発明の熱可塑性繊維糸を巻縫いした織物の炭素繊維強化複合材料は、マルチフィラメントを束ねた炭素繊維束の1束ないし複数束に熱可塑性の合成繊維糸の掛合糸をループ状に巻縫い掛合して炭素繊維束糸を形成し、この形成した炭素繊維束糸を経糸および/または緯糸として所定の大きさの織物に作製し、作製した炭素繊維束糸の織物を加熱して熱可塑性の合成繊維糸の掛合糸を溶融させて炭素繊維強化複合材料を形成したことを特徴としている。 The carbon fiber reinforced composite material of a woven fabric in which the thermoplastic fiber yarn of the present invention is wound is wound by looping a loop of a synthetic synthetic yarn thread into one or a plurality of carbon fiber bundles in which multifilaments are bundled. A carbon fiber bundle yarn is formed by hooking, and the formed carbon fiber bundle yarn is produced as a warp and / or weft into a woven fabric of a predetermined size, and the produced carbon fiber bundle yarn is heated to produce a thermoplastic fiber. It is characterized in that a carbon fiber reinforced composite material is formed by melting an engaging yarn of a synthetic fiber yarn.
巻縫いした炭素繊維糸1は、図1のようにオーバーロックやロックミシンのメローミシン2を利用してマルチフィラメントを束ねた炭素繊維束3の1束ないし複数束をメローミシン2に供給し、この炭素繊維束3に熱可塑性の合成繊維糸の掛合糸4をループ状に巻縫い掛合して炭素繊維束糸として形成するようにしている。 As shown in FIG. 1, the wound carbon fiber yarn 1 supplies one or more bundles of carbon fiber bundles 3 in which multifilaments are bundled using an overlock or lock sewing machine mellow sewing machine 2 as shown in FIG. The fiber bundle 3 is hooked and looped with a synthetic synthetic yarn yarn 4 in a loop shape to form a carbon fiber bundle yarn.
マルチフィラメントを束ねた炭素繊維束3は、ポリアクリロニトリルのPAN系の炭素繊維や石油ピッチのピッチ系の炭素繊維などのものが利用でき、PAN系は樹脂をマトリックスとする複合材料として優れた特性を有するので、特に軽量構造用に適する。 The carbon fiber bundle 3 in which multifilaments are bundled can use PAN-based carbon fibers of polyacrylonitrile or pitch-based carbon fibers of petroleum pitch, and the PAN system has excellent characteristics as a composite material using a resin as a matrix. It is particularly suitable for lightweight structures.
炭素繊維束3のフィラメントは、直径が約7〜10μmといった極細であり、これらのフィラメントを上記したように1000〜12000本を束ねて0.数mm〜1mm位の太さとし、その際毛羽の発生を防止するのに少量の樹脂をコーティングするサイジング処理をしている。 The filaments of the carbon fiber bundle 3 are extremely thin with a diameter of about 7 to 10 μm, and these filaments are bundled in a range of 1000 to 12000 as described above. The thickness is about several mm to 1 mm, and a sizing process is performed to coat a small amount of resin in order to prevent the occurrence of fluff.
炭素繊維束3は、1束毎に掛合糸4を巻縫い掛合できるが、3〜5束の複数束、好ましくは5〜20束毎に掛合糸4を巻縫い掛合するのが、炭素繊維糸1を太状ないし嵩高にできるものである。炭素繊維束3は、図2(a)のように1束であれば太状のものを、複数束の場合は図2(b)、(c)のように3束の3芯状や7束の7芯状、さらにこれらの外周部に軸対称に二重、三重状に配設してさらに太状ないし嵩高にすることもできる。 The carbon fiber bundle 3 can be wound with the hook yarn 4 for each bundle, but the carbon fiber yarn is formed by winding the hook yarn 4 every 3 to 5 bundles, preferably every 5 to 20 bundles. 1 can be thick or bulky. The carbon fiber bundle 3 is thick if it is one bundle as shown in FIG. 2 (a), and in the case of a plurality of bundles, it is a three-core or 7-core shape as shown in FIGS. 2 (b) and (c). It can be made thicker or more bulky by arranging it in the form of a seven-core bundle, and in the outer periphery of these bundles in an axisymmetric double or triple shape.
また、図3(a)、(b)のように炭素繊維束3の空隙に小径の炭素繊維束3を介添して軸対称状に型崩れしないように安定した密な状態にすることもできる。 Further, as shown in FIGS. 3A and 3B, a small diameter carbon fiber bundle 3 is interposed in the gap of the carbon fiber bundle 3 so as to be in a stable and dense state so as not to lose its shape in an axial symmetry. .
掛合糸4は、ポリエチレンやポリプロピレン、アラミド等の丈夫な熱可塑性の合成繊維糸が使用でき、0.1〜10デニールの極細のものが炭素繊維束3に嵩高とならずに掛合できて蜜な炭素繊維糸1の織物に形成できて好ましいが、上記した太状や嵩高状の炭素繊維束3のものでは必要により100〜240デニールの適宜の太さの糸を使用することができる。また、掛合糸4は、メローミシン2に供給して2〜5mmピッチで炭素繊維束3に係合していくのが好ましく、かつ炭素繊維束3がばらけたり、毛羽だったり、剥がれたりするのを有効に防止できて好ましい。 As the hooking yarn 4, a strong thermoplastic synthetic fiber yarn such as polyethylene, polypropylene, or aramid can be used, and an extra fine material of 0.1 to 10 denier can be hooked on the carbon fiber bundle 3 without being bulky and is nectar. Although it can form in the textile fabric of the carbon fiber thread | yarn 1, it is preferable in the above-mentioned thick and bulky carbon fiber bundle 3 to use the thread | yarn of the appropriate thickness of 100-240 denier as needed. Further, the hook yarn 4 is preferably supplied to the mellow sewing machine 2 and engaged with the carbon fiber bundle 3 at a pitch of 2 to 5 mm, and the carbon fiber bundle 3 is scattered, fluffy or peeled off. Can be effectively prevented.
このように形成した巻縫いした炭素繊維糸1は、図4のように織物5とするのに経糸6および/または緯糸7に使用して平織、綾織等の所定の大きさの織物5を製織し、ばらけたり、毛羽だったり、剥がれたりするのを防止でき、かつほとんど伸縮性のない炭素繊維束に弾力性を付与でき、また経糸切れ、緯糸切れなくて製織性を向上できる。 The wound and sewn carbon fiber yarn 1 formed in this way is used as a warp 6 and / or weft 7 to form a fabric 5 as shown in FIG. In addition, the carbon fiber bundle can be prevented from being loosened, fluffed or peeled off, and elasticity can be imparted to the carbon fiber bundle having almost no elasticity, and the weaving property can be improved without breaking warp and weft.
この炭素繊維束3は、1束以上でよいが、上記したように複数束とすることにより、所定の嵩高のものが迅速かつ容易にできて強度を高められて好ましい。特に、図3(a)、(b)のように炭素繊維束3の空隙に小径の炭素繊維束3を介添して密な状態のものが強度を高められて好ましい。なお、本発明の趣旨の範囲で適宜の太さのもので適宜の束数とすることができる。 The carbon fiber bundle 3 may be one or more bundles, but a plurality of bundles as described above are preferable because a predetermined bulky one can be quickly and easily increased in strength. In particular, as shown in FIGS. 3A and 3B, a dense state in which the carbon fiber bundle 3 with a small diameter is interposed in the gap of the carbon fiber bundle 3 is preferable because the strength is increased. It should be noted that, within the scope of the present invention, an appropriate thickness can be obtained with an appropriate thickness.
上記した掛合糸4は、図1のようにロックミシンのメローミシン2に上記した炭素繊維束4を同時に供給して、搖動昇降するミシン針8の針糸9に掛合糸4と同一の糸の上糸10、下糸11をかがり縫いして巻縫いすることによって容易かつ迅速に得ることができる。 As shown in FIG. 1, the above-described hooking yarn 4 supplies the above-mentioned carbon fiber bundle 4 to the lock sewing machine mellow sewing machine 2 at the same time, and the needle yarn 9 of the sewing needle 8 that moves up and down is placed on the same yarn as the hooking yarn 4. The thread 10 and the lower thread 11 can be obtained easily and quickly by over-stitching and winding.
このようにして平織り等の所定の大きさの織物5を製織していくことができ、掛合糸4に熱可塑性繊維糸を使用することで、作製した炭素繊維糸1の織物5を加熱して容易に樹脂を溶融させた炭素繊維強化複合材料(CFRP)を成形することができ、成形工程の省力化ができる。織物5の成形材料は、用途によってその幅を適宜に決定できて装着して、従来のFRPやCFRPと同様に航空機や自動車、ボート、スポーツ分野や、土木、建築分野、通信装置、携帯電話、TV、医療機器、レーザー装置、その他の用途に対応して機械、装置、物品、構造物等の軽量、補強、電磁雑音防止などに有効に対処することができる。 In this way, a woven fabric 5 having a predetermined size such as a plain weave can be woven, and by using a thermoplastic fiber yarn as the hooking yarn 4, the produced woven fabric 5 of the carbon fiber yarn 1 is heated. A carbon fiber reinforced composite material (CFRP) in which a resin is easily melted can be molded, and the labor of the molding process can be saved. The molding material of the woven fabric 5 can be appropriately determined in width depending on the application, and is installed in the same manner as conventional FRP and CFRP. Aircraft, automobile, boat, sports field, civil engineering, architecture field, communication device, mobile phone, In response to TV, medical equipment, laser devices, and other applications, it is possible to effectively cope with lightness, reinforcement, electromagnetic noise prevention, etc. of machines, devices, articles and structures.
図1以下は、本発明の実施例を示すもので、図1のようにマルチフィラメントを束ねた0.5mm径位の炭素繊維束3を図2(a)や(b)、(c)のように一束ないし複数束をメローミシン2に供給し、メローミシンを駆動してミシン針8を搖動、昇降して140デニールのポリプロピレンの熱可塑性の合成繊維糸の針糸9を上糸10、下糸11を介して同様の合成繊維糸の掛合糸4に3mmピッチでループ状に掛合して炭素繊維束3に撚りがかからずに、したがって単炭素繊維糸が折れなくて炭素繊維糸1を形成し、図4のように製織機に経糸6および緯糸7として供給し、たとえば平編みとして所定の大きさに製織していくものである。 FIG. 1 and the following figures show an embodiment of the present invention. As shown in FIG. 1, a 0.5 mm diameter carbon fiber bundle 3 in which multifilaments are bundled is shown in FIGS. 2 (a), 2 (b) and 2 (c). In this way, one or a plurality of bundles are supplied to the mellow sewing machine 2, and the mellow sewing machine is driven to swing the sewing needle 8, and the needle thread 9 of 140 denier polypropylene thermoplastic synthetic fiber yarn is moved to the upper thread 10 and the lower thread. 11 is looped on a similar synthetic fiber yarn 4 via a loop at a pitch of 3 mm, so that the carbon fiber bundle 3 is not twisted, and therefore the single carbon fiber yarn is not broken and the carbon fiber yarn 1 is formed. Then, as shown in FIG. 4, it is supplied to the weaving machine as warps 6 and wefts 7, and is woven to a predetermined size, for example, as flat knitting.
炭素繊維束3は、1ないし所定の複数を供給することによって、図2(a)〜(c)のように1束ないし複数の軸対称状の束となった所要の太さの炭素繊維束糸として、図4のように製織機に経糸6および緯糸7として供給して平織等の織物5を形成し、プリプレグ処理等を行なってできるだけ少なく所要数を積層して手間を少なく補強用に形成できるものである。 The carbon fiber bundle 3 is a bundle of carbon fibers having a required thickness which is formed into one bundle or a plurality of axisymmetric bundles as shown in FIGS. 2 (a) to 2 (c) by supplying one or a predetermined plurality. As a yarn, as shown in FIG. 4, it is supplied to a weaving machine as warp yarn 6 and weft yarn 7 to form a plain weave fabric 5 and the like, and a prepreg treatment or the like is performed to laminate as few as possible to reduce labor and form for reinforcement. It can be done.
図5のように掛合糸4は、炭素繊維束3のばらけ防止と、毛羽立ち、剥がれを防ぐだけでなく、ほとんど伸縮性のない炭素繊維糸にループ状となった掛合糸4で弾力性を付与することができる。その結果、経糸切れ、緯糸切れを起こすことなく非常に製織性が向上できる。また、掛合糸4を巻縫い掛合するとき、炭素繊維束3に撚りがかからずに巻縫いをすることができるため、非常に細く折れやすい単炭素繊維糸を切断することなく巻縫いできて、炭素繊維糸1の強度を低下させることを防止できるものである。 As shown in FIG. 5, the hook yarn 4 not only prevents the carbon fiber bundle 3 from flaking and prevents fluffing and peeling, but also provides elasticity with the loop yarn of the carbon fiber yarn having almost no elasticity. Can be granted. As a result, weaving properties can be greatly improved without causing warp breakage and weft breakage. In addition, when winding the hook yarn 4, the carbon fiber bundle 3 can be wound without being twisted, so that the single carbon fiber yarn that is very thin and easy to break can be wound without being cut. It is possible to prevent the strength of the carbon fiber yarn 1 from being lowered.
また、掛合糸4に熱可塑性繊維糸を使用することで、作製した炭素繊維糸1の織物5を加熱して容易に樹脂を溶融させた炭素繊維強化複合材料(CFRP)を成形することができるものであり、成形工程の省力化ができる。 Further, by using a thermoplastic fiber yarn as the hook yarn 4, a carbon fiber reinforced composite material (CFRP) in which the fabric 5 of the produced carbon fiber yarn 1 is heated and the resin is easily melted can be formed. It can save labor in the molding process.
なお、このようなCFRPの織物は、上記したように航空機や自動車、ボート、スポーツ分野や、土木、建築分野、通信装置、携帯電話、TV、医療機器、レーザー装置、その他の用途に対応してこれらの機械、装置、物品、構造物等に内装、外装して軽量、補強、電磁雑音防止などに有効に対処することができる。特に、炭素繊維糸の織物を上記した器具や装置に装着することによって補強の他に電磁雑音防止をはかることができて好ましい。 Such CFRP fabrics correspond to aircraft, automobiles, boats, sports fields, civil engineering, architectural fields, communication devices, mobile phones, TVs, medical equipment, laser devices, and other applications as described above. These machines, devices, articles, structures, etc. can be internally and externally mounted to effectively deal with light weight, reinforcement, electromagnetic noise prevention, and the like. In particular, it is preferable to attach a carbon fiber yarn woven fabric to the above-described appliance or apparatus, in addition to reinforcing electromagnetic noise prevention.
またさらに、積層する炭素繊維糸1を製織した織物5の炭素繊維糸1の方向が、図6のように交互に45度等毎に対応するように積層して、積層する織物5の強度を所要の均一状に形成して利用することができるものである。 Furthermore, the strength of the woven fabric 5 to be laminated is increased by laminating so that the directions of the carbon fiber yarns 1 of the woven fabric 5 obtained by weaving the carbon fiber yarn 1 to be laminated alternately correspond to every 45 degrees as shown in FIG. It can be formed and used in the required uniform form.
なお、図3(a)、(b)のように太径の炭素繊維束3の間に小径の炭素繊維束3を介添して型崩れしないように安定した密な状態にすることができるものである。 As shown in FIGS. 3 (a) and 3 (b), a small-diameter carbon fiber bundle 3 is interposed between the large-diameter carbon fiber bundles 3 so that the mold can be kept in a stable and dense state so as not to lose its shape. It is.
1…炭素繊維糸 2…メローミシン 3…炭素繊維束
4…掛合糸 5…織物
DESCRIPTION OF SYMBOLS 1 ... Carbon fiber thread 2 ... Mellow sewing machine 3 ... Carbon fiber bundle 4 ... Hanging thread 5 ... Textile
Claims (2)
作製した炭素繊維束糸の織物を加熱して熱可塑性の合成繊維糸の掛合糸を溶融させて炭素繊維強化複合材料を形成したことを特徴とする熱可塑性繊維糸を巻縫いした織物の炭素繊維強化複合材料。 One or more carbon fiber bundles bundled with multifilaments are looped with thermoplastic synthetic fiber yarns in a loop shape to form carbon fiber bundle yarns, and the formed carbon fiber bundle yarns are warps. And / or produced as a weft in a predetermined size fabric,
A carbon fiber of a woven fabric in which a thermoplastic fiber yarn is wound and formed by heating the produced carbon fiber bundle yarn fabric to melt a hooking yarn of a thermoplastic synthetic fiber yarn to form a carbon fiber reinforced composite material Reinforced composite material.
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