JP3502702B2 - Water-in-oil emulsion cosmetics - Google Patents

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a water-in-oil type emulsion cosmetic having a low viscosity, good storage stability, and excellent usability.

[0002]

2. Description of the Related Art Conventionally, water-in-oil type emulsion cosmetics are often used in skin care products and make-up products because they form an oil film on the skin surface, have a high moisturizing effect, are excellent in water repellency, and have little makeup damage. Has been done. On the other hand, it has the drawback of poor storage stability, and the aqueous phase, which is the dispersed phase (inner phase), tends to aggregate at low temperatures, and the oil phase tends to separate at high temperatures.

In order to improve the storage stability of these water-in-oil type emulsion cosmetics, it has been studied in the past to add a large amount of wax to the oil phase to increase the viscosity of the continuous phase (outer phase). , Which is effective for low temperature stability,
The high temperature stability is not improved, and there is a drawback that new problems such as heavy spread occur in usability. Further, in order to obtain a low-viscosity water-in-oil emulsion cosmetic, it is usually necessary to increase the amount of the oil phase (outer phase) compounded, but such a low-viscosity water-in-oil emulsion cosmetic is storage stable. However, it is difficult to obtain a stable low-viscosity water-in-oil type emulsion cosmetic.

[0004]

SUMMARY OF THE INVENTION An object of the present invention is to provide a low-viscosity water-in-oil type emulsion cosmetic having excellent storage stability and a good feeling in use.

[0005]

Means for Solving the Problems As a result of intensive studies to solve these problems, the present inventors have found that a water-in-oil emulsion cosmetic containing a lipophilic nonionic surfactant, an oily component, and sodium alginate. The present invention has completed the present invention by discovering that the material has good storage stability and is excellent in usability.

That is, according to the present invention, (a) a lipophilic nonionic surfactant which is liquid at room temperature is 0.5 to 5% by weight, (b) an oily component is 10 to 30% by weight, and (c) sodium alginate is 0.01. The present invention provides a water-in-oil type emulsified cosmetic characterized by containing 3 to 3% by weight. According to the invention,
Despite its low viscosity, it has good storage stability and spreads well,
It is possible to provide a water-in-oil type emulsified cosmetic composition having a good feeling of use such as no oily feeling and no sticky feeling.

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION The lipophilic nonionic surfactant used in the present invention is not particularly limited as long as it is in a liquid state at room temperature, and known diglyceryl monooleate, diglyceryl dioleate, and monooleate are known. Diglyceryl isostearate, tetraglyceryl monooleate, decaglyceryl pentaoleate, decaglyceryl pentaisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monoisostearate, sorbitan sesquiisostearate, polyoxy Examples include ethylene (3EO) hydrogenated castor oil, polyoxyethylene (5EO) hydrogenated castor oil, polyoxyethylene (10EO) hydrogenated castor oil, and the like.
Among them, diglyceryl monooleate, diglyceryl monoisostearate, sorbitan sesquiisostearate, and polyoxyethylene (5EO) hydrogenated castor oil are particularly preferable.

These lipophilic nonionic surfactants are
One kind or two or more kinds thereof can be optionally used, and the compounding amount thereof is 0.5 to 5% by weight based on the total amount of the cosmetic. If the compounding amount is less than 0.5% by weight, the emulsion stability is poor, and if the compounding amount exceeds 5% by weight, the viscosity of the cosmetic composition becomes high or the usability is impaired.

The oily component used in the present invention is not particularly limited as long as it is an oily component usually used in cosmetics. For example, liquid paraffin, squalane, olefin oligomer, hydrocarbons such as petrolatum, ceresin, paraffin and microcrystalline wax, waxes such as lanolin, beeswax and candelilla wax, fatty acids such as stearic acid and oleic acid, cetanol and stearyl. Higher alcohols such as alcohol, octyldodecyl oleate, oleyl oleate, isostearyl octoate, cetyl octoate, isopropyl myristate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, pentaerythritol tetra-2-ethylhexanoate And fatty acid esters such as, silicone oils such as methyl polysiloxane, methylphenyl polysiloxane, and highly polymerized methyl polysiloxane. Among them, liquid paraffin, squalane, microcrystalline wax, beeswax, cetanol, cetyl octanoate, isopropyl myristate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, tetra-2-ethylhexanoate pentaerythritol, and silicone oil are preferable.

These oily components may be used alone or in combination of two or more, and the blending amount thereof is 10 to 30% by weight, preferably 10 to 20% by weight based on the total amount of the cosmetic. If the blending amount is less than 10% by weight, it is difficult to emulsify, and if the blending amount exceeds 30% by weight, the emulsion stability is impaired.

The sodium alginate used in the present invention is
Usually obtained from seaweeds such as kelp, and commercially available as duck algin (Kibun Food Chemifa).
The content of sodium alginate is 0.01 to 3% by weight, and preferably 0.05 to 1% by weight, based on the total amount of the cosmetic. If the content is less than 0.01% by weight or more than 3% by weight, the emulsion stability will be impaired.

The inorganic sunscreen agent used in the present invention is not particularly limited, but examples thereof include fine particle titanium oxide, fine particle zinc oxide, kaolin, and talc. As these inorganic sunscreens, those subjected to a hydrophobic treatment such as silicone and metal soap are preferably used, and one or more of them can be blended in an amount of 1 to 30% by weight, particularly 5 to 20% by weight, based on the total amount of the cosmetic. preferable.

The cosmetic of the present invention is a spindle No. B type viscometer (model BL, manufactured by Tokyo Keiki Co., Ltd.). The viscosity measured using 4 is 20,000 to 100,000 at 25 ° C.
The feeling of use is most excellent within the range of 0 cps.

The water-in-oil type emulsified cosmetic composition of the present invention can be produced by a conventional method and is used as a sunscreen cosmetic composition, a body cosmetic composition, a cleansing composition, a foundation, a cosmetic composition for a makeup base, an emulsion and the like. According to the purpose of each, within a range that does not impair the effects of the present invention, for example, octyl paradimethylaminobenzoate, octyl salicylate, homomenthyl salicylate, 2-ethylhexyl paramethoxycinnamate, 2-ethoxycinnamic acid 2-ethoxy. Organic sunscreen ingredients such as ethyl, glyceryl mono-2-ethylhexanoate diparamethoxycinnamate, oxybenzone, tetrahydroxybenzophenone, oxybenzone sulfonate, glycerin, polyglycerin, dipropylene glycol, triethylene glycol, 1, 3-butylene glycol, propylene glycol Polyhydric alcohol such as alcohol,
Sorbitol, sugars such as hyaluronic acid, glutamic acid or salts thereof, amino acids or derivatives thereof such as sodium pyrrolidonecarboxylate, betaines such as trimethylglycine, inorganic salts such as sodium chloride and magnesium sulfate, vitamins, glycyrrhetinic acid ester, glycyrrhizinic acid Well-known components such as a medicinal agent such as a salt, a binder, an antiseptic, an antioxidant, a dye, a pigment, a pH adjusting agent, a chelating agent, an astringent, and a flavoring agent can be appropriately added.

[0015]

EXAMPLES Next, the present invention will be described in more detail with reference to Examples, but it goes without saying that the present invention is not limited to these. In addition, "%" in the examples means "% by weight" unless otherwise specified. Examples 1 to 7 and Comparative Examples 1 to 6 The cosmetic samples of Examples 1 to 7 and Comparative Examples 1 to 6 shown in Table 1 were produced by a conventional method and evaluated by the methods described below.

[0016]

[Table 1]

Evaluation method 1. Emulsion stability Immediately after preparing a test sample from the formulation of the example (or comparative example), the sample is left to stand at 40 ° C, room temperature and -5 ° C. After being left for 2 weeks, the sample placed under each condition was visually judged according to the following criteria. <Criteria> ○: Not separated △: Slightly separated ×: Completely separated

2. Feeling of use Each cosmetic sample was actually used by 5 panelists,
From the viewpoint of oily feeling and sticky feeling, the evaluation was made according to the following criteria. <Judgment Criteria> ○: 4-5 people answered that it was good △: 2-3 people answered that it was good ×: 0-1 people answered that it was good

3. Comprehensive Evaluation <Judgment Criteria> ○: All of the above 2 evaluation items are ○ Δ: Among the above 2 evaluation items, the feeling of use is Δ and the emulsion stability is ○ or higher ×: Any of the above 2 evaluation items One is X, or the emulsion stability is Δ. The evaluation results are summarized in Table 1.

As shown in Table 1, the cosmetic samples of Examples, which are the water-in-oil type emulsion cosmetics of the present invention, are superior in emulsion stability and have a good feeling in use as compared with the cosmetic samples of Comparative Examples. Was accepted.

Example 8 A milky lotion was produced according to the following formulation by a conventional method.         Component blending amount (%)         Squalane 10.0         Decamethylcyclopentasiloxane 10.0         Diglyceryl isostearate 2.0         Concentrated glycerin 3.0         1,3-butylene glycol 5.0         Sodium alginate 0.1         Preservative A small amount         Fragrance amount         Purified water residue         Total 100.0           (Viscosity: 32,700 cps)

Example 9 A liquid foundation was manufactured according to the following formulation by a conventional method. Ingredient content (%) Liquid paraffin 10.0 Neopentyl glycol dioctanoate 5.0 Decamethylcyclopentasiloxane 7.0 Beeswax 1.5 Polyoxyethylene (5EO) hydrogenated castor oil 2.5 Diglyceryl isostearate 0.0 5 Talc 5.0 Titanium oxide 3.0 Zinc oxide 2.0 Iron oxide 1.5 Trimethylglycine 3.0 1,3-Butylene glycol 5.0 Sodium alginate 0.3 Preservatives Fragrance Fragrance Purified water Residue Total 100.0 (viscosity: 46,000 cps)

Example 10 A sunscreen was manufactured according to the following formulation by a conventional method. Ingredient content (%) Squalane 7.0 Microcrystalline 0.5 Decamethylcyclopentasiloxane 10.0 Highly polymerized methyl polysiloxane 0.3 Dibenzoylmethane 3.0 Sorbitan sesquiisostearate 3.5 Fine particle zinc oxide 5.0 0 Fine Titanium Oxide 5.0 Talc 3.0 Sorbitol 5.0 Propylene Glycol 3.0 Sodium Alginate 1.0 Preservatives Slight amount Fragrances Slight amount Purified water Residual total amount 100.0 (viscosity: 61,500 cps) Example It was also recognized that Nos. 8 to 10 were water-in-oil type emulsion cosmetics each having excellent emulsion stability and a good feeling in use.

[0024]

According to the present invention, the emulsion stability and the feeling of use, which are the problems of the conventional water-in-oil type emulsion cosmetics, are improved.
It is possible to provide a water-in-oil type emulsion cosmetic having excellent stability and a refreshing feel.

Claims (2)

(57) [Claims] 1. A lipophilic nonionic surfactant which is liquid at room temperature (a) is 0.5 to 5% by weight, (b) an oily component is 10 to 30% by weight, and (c) sodium alginate is 0.01 to 3% by weight.
Water-in-oil emulsification, characterized in that the viscosity is 20,000 to 100,000 cps, which is measured by using a B-type viscometer (model BL, manufactured by Tokyo Keiki Co., Ltd.) spindle No. 4 at 25 ° C. Cosmetics. 2. Further, 1 to (d) an inorganic sunscreen agent
The water-in-oil type emulsified cosmetic composition according to claim 1, containing 30% by weight.