JP2012255089A - Ink for inkjet, inkjet recording method, and recording apparatus - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an ink for inkjet, which is excellent in scratch resistance, and capable of forming images having high gloss; and to provide a recording method and a recording apparatus using the same.SOLUTION: The ink for inkjet includes a resin dispersion liquid B in which a dispersoid b containing a self-dispersion pigment and a first resin is dispersed, a dispersion liquid D in which a dispersoid d containing a second resin is dispersed, and water, wherein the dispersoid b in the resin dispersion liquid B has a specific gravity smaller than 1, and the dispersoid b has a larger average particle diameter than that of the self-dispersion pigment; and the dispersoid d in the resin dispersion liquid D has a specific gravity larger than 1, the dispersoid d has a smaller average particle diameter than that of the self-dispersion pigment, and the second resin has a glass transition temperature of ≤23°C.

Description

  The present invention relates to an inkjet ink-jet recording method and a recording apparatus.

2. Description of the Related Art Conventionally, a printing method in which ink droplets are ejected and attached to a recording medium such as paper to perform printing, a so-called inkjet recording method is known.
As the ink used in such a recording method, generally, various water-soluble dyes dissolved in water or water and a water-soluble organic solvent, or inks obtained by dispersing a pigment in an aqueous medium are used. ing. It has been generally pointed out that an image formed with an ink containing a water-soluble dye is inferior in water resistance and light resistance. On the other hand, an ink (pigment ink) obtained by dispersing a pigment in an aqueous medium has an advantage of being excellent in water resistance and light resistance.

  As pigment inks, water-based pigment inks in which carbon black is dispersed with a surfactant or a polymer dispersant have been proposed. In these inks, the ink content of the colorant is increased in order to increase the print density of recorded matter. When it increases, the ink viscosity may increase suddenly. In addition, in order to stably disperse carbon black in the ink, an excessive surfactant or polymer dispersant is required, which may cause deterioration in printing stability due to foaming or defoaming deterioration. there were.

  In order to solve such problems, a certain amount or more of surface active hydrogen or a salt thereof is introduced to the surface of carbon black, and even if there is no dispersant such as a surfactant or a polymer dispersant, carbon black alone is an aqueous system. Self-dispersing carbon black dispersions that can be dispersed in a solvent are disclosed (for example, see Patent Documents 1 and 2). Further, a method for introducing a sulfonic acid group into the surface of carbon black is disclosed (for example, see Patent Document 3). Furthermore, an inkjet ink containing the above-described surface-modified carbon black and glycol ethers has been proposed (see, for example, Patent Document 4).

  A so-called self-dispersing pigment that does not require such a dispersant increases the OD value (optical density) of the image when used in an ink as a colorant, and has an appropriate viscosity in the ink. It has been developed in various ways because it is easy to handle because it is easy to match, and it is not necessary to consider the compatibility between the dispersant and various added solvents. The surface is modified with an anionic surface that is formed by bonding a hydrophilic functional group such as a carbonyl group, carboxyl group, hydroxyl group, sulfone group, or ammonium group directly or indirectly through an alkyl group or aryl group. It is common.

  However, ink jet ink using such a self-dispersing pigment has a high OD value, but the ink fixing property to the recording medium (particularly the fixing property of the pigment in the ink) is insufficient, and the friction resistance. There was a problem of being inferior. Further, in recent years, glossiness (gross) has been required for an image formed on a recording medium such as special paper by inkjet ink. However, conventional inkjet inks have sufficient glossiness (gloss). Couldn't get.

JP-A-8-3498 JP-A-10-120958 Japanese Patent Laid-Open No. 10-110127 Japanese Patent Laid-Open No. 10-95941

  An object of the present invention is to provide an ink jet ink that is excellent in friction resistance and capable of forming an image having a high gloss, and such an ink jet recording method and recording apparatus.

Such an object is achieved by the present invention described below.
The inkjet ink of the present invention comprises a self-dispersing pigment,
A resin dispersion B in which the dispersoid b containing the first resin is dispersed;
A resin dispersion D in which a dispersoid d containing a second resin is dispersed;
Including water,
In the resin dispersion B, the specific gravity of the dispersoid b is less than 1, and the average particle size of the dispersoid b is larger than the average particle size of the self-dispersing pigment,
In the resin dispersion D, the specific gravity of the dispersoid d is greater than 1, the average particle diameter of the dispersoid d is smaller than the average particle diameter of the self-dispersing pigment, and
The glass transition point of the second resin is 23 ° C. or less.
Accordingly, it is possible to provide an ink jet ink that is excellent in friction resistance and capable of forming an image having high gloss.

In the ink-jet ink of the present invention, the first resin is preferably an amorphous polyolefin.
Thereby, the image surface to be formed can be made smoother, and an image having a higher gloss can be formed.
In the ink-jet ink of the present invention, the amorphous polyolefin preferably contains at least a maleic acid-modified polyolefin oligomer and a polyethylene glycol alkyl ether.
Thereby, the image surface to be formed can be made smoother, and an image having a higher gloss can be formed.
In the ink-jet ink of the present invention, the second resin is preferably an acrylic resin.
As a result, the second resin can be more effectively permeated into the recording medium, the anchor effect becomes even more remarkable, and the friction resistance is particularly excellent.

The ink-jet ink of the present invention preferably contains a zwitterionic compound.
Thereby, the image surface to be formed can be made smoother, and an image having a higher gloss can be formed.
In the ink jet ink of the present invention, the zwitterionic compound is preferably a betaine compound having a molecular weight of 100 or more and 250 or less.
Thereby, the image surface to be formed can be made smoother, and an image having a higher gloss can be formed.

The inkjet recording apparatus of the present invention includes a recording unit that performs recording using the inkjet ink of the present invention on the main surface of a recording medium having a main surface and a back surface that is a surface opposite to the main surface. ,
A discharge portion for discharging the recording medium with the main surface facing downward;
A correction guide that presses the back surface of the recording medium being discharged from the discharge unit downward and corrects the recording medium; and
A bend amount acquisition unit for acquiring the bend amount of the recording medium discharged from the discharge unit;
And a pressing control unit that controls the pressing force of the correction guide according to the bending amount acquired by the bending amount acquisition unit.
As a result, it is possible to easily produce an inkjet ink that is excellent in friction resistance and capable of forming an image having high gloss.

1 is a perspective view schematically showing a part of an ink jet recording apparatus according to an embodiment of the present invention. It is a side view of the inkjet recording device shown in FIG. 1 is a schematic view schematically showing an ink jet recording apparatus according to an embodiment of the present invention. It is a figure which expands and shows a part of inkjet recording device shown in FIG.

Hereinafter, preferred embodiments of the present invention will be described in detail.
<Inkjet ink>
In the inkjet ink of the present invention, a self-dispersing pigment, a resin dispersion B in which a dispersoid b containing a first resin as described later is dispersed, and a dispersoid d containing a second resin as described later are dispersed. Resin dispersion D and water are included, resin dispersion B has a specific gravity of dispersoid b smaller than 1, and average particle size of dispersoid b is an average of the self-dispersing pigment. The resin dispersion D is larger than the particle size, and the specific gravity of the dispersoid d is greater than 1, the average particle size of the dispersoid d is smaller than the average particle size of the self-dispersing pigment, and the second resin The glass transition point is 23 ° C. or lower.
By having such characteristics, it is possible to provide an inkjet ink that is excellent in friction resistance and capable of forming an image having high gloss.

Hereinafter, each component will be described in detail. [Self-dispersing pigment]
The self-dispersing pigment has a functional group (dispersibility imparting group) such as one or more selected from the group consisting of —COOH, —CHO, —OH, —SO ₃ H and salts thereof on the surface of the pigment. It is the pigment processed so that it may have.
Such a self-dispersing pigment can be uniformly dispersed in the water-based ink composition without separately adding a dispersant. The term “dispersed” as used herein refers to a state in which the self-dispersing pigment is stably present in water without a dispersant, not only in a dispersed state but also in a dissolved state. Shall also be included.

  Ink-jet inks formulated with self-dispersing pigments have higher dispersion stability and viscosity of the ink than ordinary inks containing non-self-dispersing pigments and dispersants other than self-dispersing pigments. Therefore, it is possible to contain more pigment, and it is possible to form images such as characters and figures with excellent color developability especially on plain paper. Furthermore, ink containing a self-dispersing pigment does not cause a decrease in fluidity even when a penetrating agent (described later) effective in improving print quality is blended. Print quality is also improved.

However, an image formed with an inkjet ink using such a self-dispersing pigment has a problem that it is inferior in abrasion resistance and gloss because the amount of resin contained in the ink is smaller than that of a conventional ink. was there. On the other hand, such a problem can be solved by applying the present invention.
As the pigment capable of forming a self-dispersing pigment, any of known inorganic pigments and organic pigments can be used. Examples of such pigments include pigment yellow, pigment red, pigment violet, pigment blue, and pigment black described in the Color Index, as well as phthalocyanine, azo, anthraquinone, azomethine, and condensed rings. Examples thereof include pigments of the type. Further, organic pigments such as yellow No. 4, No. 5, 205, 401; orange No. 228, 405; blue No. 1, 404, carbon black, titanium oxide, zinc oxide, zirconium oxide, iron oxide, ultramarine , Inorganic pigments such as bitumen and chrome oxide.

  Examples of the pigment color index include C.I. I. Pigment Yellow 1, 2, 3, 4, 5, 6, 7, 10, 11, 12, 13, 14, 16, 17, 24, 34, 35, 37, 53, 55, 65, 73, 74, 75, 81, 83, 93, 94, 95, 97, 98, 99, 108, 109, 110, 113, 114, 117, 120, 124, 128, 129, 133, 138, 139, 147, 151, 153, 154, 167, 172, 180, etc., C.I. I. Pigment Red 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 14, 15, 16, 17, 18, 19, 21, 22, 23, 30, 31, 32, 37, 38, 40, 41, 42, 48 (Ca), 48 (Mn), 57 (Ca), 57: 1, 88, 112, 114, 122, 123, 144, 146, 149, 150, 166, 168 170, 171, 175, 176, 177, 178, 179, 184, 185, 187, 202, 209, 219, 224, 245, or C.I. I. Pigment violet 19, 23, 32, 33, 36, 38, 43, 50, C.I. I. Pigment Blue 1, 2, 3, 15, 15: 1, 15: 2, 15: 3, 15: 4, 15: 6, 15:34, 16, 18, 22, 25, 60, 65, 66, C.I. I. Bat Blue 4, 60 etc., C.I. I. Pigment green 7, 10, C.I. I. Pigment brown 3, 5, 25, 26, C.I. I. Pigment orange 2, 5, 7, 13, 14, 15, 16, 24, 34, 36, 38, 40, 43, 63, etc., C.I. I. And CI pigment black 1,7.

  In order to prepare such a self-dispersing pigment, a functional group or a molecule containing a functional group is coordinated on the surface of the pigment by chemical treatment such as vacuum plasma or chemical treatment, and chemical bonding such as grafting is performed. Can be obtained. For example, it can be obtained by the method described in JP-A-8-3498. In addition, as the self-dispersing pigment, commercially available products can be used. Preferred examples include “Microjet CW1” and “Microjet CW2” manufactured by Orient Chemical Industries, Ltd., and “CAB” manufactured by Cabot Corporation. -O-JET 200 "," CAB-O-JET 300 "and the like.

The self-dispersing pigment is prepared as follows, for example.
(Example of preparation method of self-dispersing pigment (pigment surface oxidation treatment-sulfonation treatment))
A pigment is added to the solvent, and this is subjected to high-speed shear dispersion with a high-speed mixer or the like, or impact-dispersed with a bead mill or jet mill to obtain a slurry-like pigment dispersion. While slowly stirring the pigment dispersion, a treatment agent containing sulfur (sulfamic acid, fuming sulfuric acid, sulfuric acid, chlorosulfuric acid, fluorosulfuric acid, amidosulfuric acid, etc.) is added, and the pigment dispersion is heated to 60 to 200 ° C. Then, the dispersibility-imparting group is introduced on the pigment surface. After removing the solvent from the pigment dispersion, the treatment agent containing sulfur is removed by repeating washing with water, ultrafiltration, reverse osmosis, centrifugation, filtration and the like to obtain a self-dispersing pigment.

In addition, the self-dispersing pigment preferably has an average particle size of 10 nm to 300 nm, more preferably 40 nm to 150 nm, from the viewpoint of improving the storage stability of the ink and preventing nozzle clogging. preferable.
The content of the self-dispersing pigment is 2% by mass or more and 15% by mass or less in the ink composition of Embodiment A in that a sufficient OD value is obtained and the liquid stability of the ink composition. It is more preferable that it is 4 mass% or more and 10 mass% or less.

[Resin dispersion B]
The resin dispersion B is a dispersion in which the dispersoid b containing the first resin is dispersed.
In the present invention, examples of the dispersion include suspensions (suspensions) and emulsions (emulsions, emulsions, and emulsions). In this specification, the term “suspension” refers to a dispersion (including a suspended colloid) in which a solid (solid) dispersoid (suspended particle) is dispersed in a liquid dispersion medium. The term “emulsified liquid (emulsion, emulsion, milky liquid)” refers to a dispersion in which a liquid dispersoid (dispersed particles) is dispersed in a liquid dispersion medium. In the dispersion liquid, a solid dispersoid and a liquid dispersoid may coexist. In such a case, among the dispersoids in the dispersion, those in which the proportion of the solid dispersoid is larger than the proportion of the liquid dispersoid is called a suspension, and the proportion of the liquid dispersoid is solid. What is larger than the proportion of the dispersoid in the form of a powder is called an emulsion.

  In the resin dispersion B used in the present invention, the specific gravity of the dispersoid b is smaller than 1, and the average particle diameter of the dispersoid b is larger than the average particle diameter of the self-dispersing pigment described above. Thereby, the first resin constituting the dispersoid b can be left in the vicinity of the recording medium surface. Thus, by making 1st resin exist on the surface, the unevenness | corrugation of the image surface can be filled, and the smoothness of the image surface can be made excellent. As a result, the gloss of the formed image can be made particularly excellent.

  In the present invention, the specific gravity of the dispersoid b is less than 1, but specifically, it is preferably 0.9 or more and less than 1. Thereby, the first resin can be effectively left in the vicinity of the surface of the recording medium, and the gloss can be made higher. On the other hand, if the specific gravity of the resin dispersion B is 1 or more, the first resin cannot be sufficiently present on the surface of the recording medium, and the gloss cannot be sufficiently high.

  In the present invention, the average particle size of the dispersoid b is larger than the average particle size of the self-dispersing pigment, and specifically, it is preferably 100 nm or more and 500 nm or less. Thereby, the first resin can be effectively left in the vicinity of the surface of the recording medium, and the gloss can be made higher. On the other hand, when the average particle size of the dispersoid b is equal to or less than the average particle size of the self-dispersing pigment, the first resin cannot be sufficiently present on the surface of the recording medium, and the gloss is sufficiently high. It can not be.

  The first resin used in the present invention is not particularly limited as long as it has the above characteristics, but is preferably an amorphous polyolefin. Thereby, the smoothness of the image surface to be formed can be made higher, and the gloss of the image can be made higher. In particular, by using an amorphous resin, the smoothness of the image surface can be made particularly high.

The number average molecular weight (Mn) of the amorphous polyolefin is usually preferably 600 or more and 10,000 or less. In addition, a number average molecular weight (Mn) can be calculated | required by measuring by gel permeation chromatography (GPC).
Moreover, as an amorphous olefin, it is preferable to use what contains at least a maleic acid-modified polyolefin oligomer and polyethylene glycol alkyl ether. Thereby, the smoothness of the image surface to be formed can be further improved, and an image with particularly excellent gloss can be formed.

The maleic acid-modified polyolefin oligomer is a polymer obtained by graft copolymerizing maleic acid or a derivative thereof with a polyolefin oligomer. Specifically, Mitsui High Wax 1105A, 2203A, NPO555A (manufactured by Mitsui Chemicals) and Umex 1010 (Sanyo Chemical Industries). Etc.).
As a method for producing a maleic acid-modified polyolefin oligomer, for example, a polyolefin oligomer is melted or dissolved in a solvent such as hexane, and a radical initiator such as peroxide and maleic acid or a derivative thereof are gradually added dropwise. can get.

The radical initiator to be used is not particularly limited, and examples thereof include di-tert-butyl peroxide, tert-butylperoxy-2-ethylhexanoate, benzoyl peroxide, dicumyl peroxide, and lauroyl peroxide. Organic peroxides such as oxide, tert-butylperoxybenzoate, cumene hydroperoxide, azobisisobutyronitrile, 4,4′-azobis (4-cyanopentanoic acid), 2,2′-azobis (2- And azo compounds such as methyl-N- (2-hydroxyethyl) propioamide). These can be used alone or in combination of two or more.
Furthermore, the radical generation method in the case of performing the reaction by generating radicals is a known method such as a method of irradiating light in the presence of a photopolymerization initiator or a method of adding an organic peroxide. Can be used.

  Examples of the photopolymerization initiator include benzophenone, diacetyl, benzyl, benzoin, 2-methylbenzoin, ω-bromoacetophenone, chloroacetone, acetophenone, 2,2-diethoxyacetophenone, 2,2-dimethoxy-2-phenylacetophenone. 2-hydroxy-2-methylpropiophenone, 2-chlorobenzophenone, p-dimethylaminopropiophenone, p-dimethylaminoacetophenone, p, p'-bisdiethylaminobenzophenone, 3,3'-4,4'- Tetra-benzophenone, Michler's ketone, benzoin methyl ether, benzoin isopropyl ether, benzoin isobutyl ether, benzoin-n-butyl ether, 2,4,6-trimethylbenzoyldiphenylphosphineoxy Carbonyls such as benzyl dimethyl ketal and methyl benzoyl formate, sulfides such as diphenyl disulfide, dibenzyl disulfide, tetramethyl thiuram monosulfide, quinones such as benzoquinone, anthraquinone, chloroanthraquinone, ethyl anthraquinone, butyl anthraquinone, thioxanthone, Examples thereof include thioxanthones such as 2-methylthioxanthone and 2-chlorothioxanthone, but these may be used alone or in combination of two or more. These photopolymerization initiators include amines such as triethylamine, trimethylamine, triethanolamine, dimethylaminoethanol, pyridine, quinoline, and trimethylbenzylammonium chloride, alkylphosphines such as triphenylphosphine, and β-thiodi. A thiol ether such as glycol may be used in combination.

The amount of the photopolymerization initiator used is preferably 10% by mass or more and 50% by mass or less, and more preferably 20% by mass or more and 40% by mass or less with respect to the added maleic acid.
Moreover, it is preferable to add these reaction initiators and maleic acid or derivatives thereof little by little as much as possible. Although depending on the amount used, in general, when organic peroxides are added all at once, the reaction solution is relatively susceptible to gelation. It is preferable to add little by little.
The maleic acid content in the maleic acid-modified polyolefin oligomer is preferably 0.5 to 5% by mass.

  Polyethylene glycol alkyl ether is a compound having an alkyl group having 12 to 22 carbon atoms and a repeating unit number of oxyethylene group of 4 to 50,000, and copolymerization with an oxyalkylene group such as an oxypropylene group. Things are also included. Examples of such compounds include polyoxyethylene dodecyl ether, polyoxyethylene cetyl ether, polyoxyethylene octyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene lauryl ether, octaethylene glycol mono- Examples thereof include n-dodecyl ether.

The HLB in the present invention refers to a hydrophilic / lipophilic balance representing the effect of a surfactant. For example, Griffin's formula: HLB = 20 × (the number of hydrophilic groups) or Davis' formula: HLB = 7 + Σ (of hydrophilic groups) Number of radicals) -Σ (the number of hydrophobic groups).
The preferable HLB of the polyoxyethylene alkyl ether is 8 or more, more preferably 12 or more and 18 or less. Specific examples include Emulgen 120P, Emulgen 320P, Emulgen 420, Emulgen 1108, Emulgen 2020G-HA, Emulgen LS110 (Kao Corporation), Neugen XL-80 (Daiichi Kogyo Seiyaku Co., Ltd.), and the like.

The production method of the resin dispersion B includes, for example, a melting step in which the maleic acid-modified polyolefin oligomer and the polyethylene glycol alkyl ether are melt-mixed and an emulsification step in which water-dispersed particles are produced by emulsifying and dispersing.
The melting step is a step in which a mixture of maleic acid-modified polyolefin oligomer and polyethylene glycol alkyl ether is melted at a temperature higher than the melting point of the mixture and uniformly mixed, and more specifically at 80 ° C. or more and 200 ° C. or less. It is preferable to stir for 10 minutes or more. In addition, an organic solvent may be used when performing melt mixing below the melting point of the mixture.

  Specific examples of the organic solvent include aromatic hydrocarbons such as xylene, toluene and ethylbenzene, aliphatic hydrocarbons such as hexane, heptane, octane and decane, alicyclic hydrocarbons such as cyclohexane, cyclohexene and methylcyclohexane, and ethyl acetate. N-butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, ester solvents such as 3-methoxybutyl acetate, and ketone solvents such as methyl ethyl ketone and methyl isobutyl ketone.

  The emulsification step is a method of physically emulsifying and dispersing by mechanical shearing force. Specifically, after dissolving a mixture of maleic acid-modified polyolefin oligomer and polyethylene glycol alkyl ether in a solvent, a high-pressure homogenizer, a high-pressure homogenizer is used. Method of removing solvent after emulsification with a mixer, etc., Method of melting a mixture of maleic acid-modified polyolefin oligomer and polyethylene glycol alkyl ether in a molten state and emulsifying with a high-pressure homogenizer, high-pressure homomixer, extrusion kneader, α-olefin and (meth) Examples include emulsifying acrylic acid copolymers and alkaline substances such as potassium, sodium, and ammonium in an autoclave, other mechanical pulverization methods, high-pressure jet pulverization methods, and spraying methods from pores. .

[Resin dispersion D]
The resin dispersion D is a dispersion in which the dispersoid b containing the second resin is dispersed.
In the resin dispersion D used in the present invention, the specific gravity of the dispersoid d is larger than 1, and the average particle diameter of the dispersoid d is smaller than the average particle diameter of the self-dispersing pigment described above. Thereby, the dispersoid d penetrates deeper than the pigment into the recording medium after the ink has landed. For this reason, the second resin constituting the dispersoid d exists inside the recording medium, and the anchor effect of the second resin can improve the friction resistance of the formed image.

In the present invention, as the second resin constituting the dispersoid d, one having a glass transition point of 23 ° C. or lower is used. By using such a second resin, it becomes easy to penetrate into the inside of the recording medium, and the formed image has particularly high friction resistance.
In the present invention, the specific gravity of the dispersoid d is greater than 1, but specifically, it is preferably greater than 1 and 1.3 or less. Thereby, the dispersoid d (second resin) can be more effectively permeated into the recording medium, and the anchor effect can be made more remarkable. As a result, the friction resistance can be made particularly excellent. On the other hand, if the specific gravity of the dispersoid d is 1 or less, the second resin cannot be made sufficiently close to the inside of the recording medium, and the friction resistance cannot be made sufficiently high.

  In the present invention, the average particle size of the dispersoid d is smaller than the average particle size of the self-dispersing pigment, and specifically, it is preferably 20 nm or more and 120 nm or less. Thereby, the second resin can be more effectively permeated into the recording medium, and the friction resistance can be further increased. On the other hand, if the average particle size of the dispersoid d is equal to or greater than the average particle size of the self-dispersing pigment, the second resin cannot be sufficiently penetrated into the recording medium, and the friction resistance is sufficient. Cannot be expensive.

Moreover, in this invention, although the glass transition point of 2nd resin which comprises the dispersoid d is 23 degrees C or less, it is more preferable that they are -80 degreeC or more and 15 degrees C or less. Thereby, the effect of this invention can be made more remarkable. On the other hand, when the glass transition point of the second resin constituting the dispersoid d is less than the lower limit value, excellent friction resistance cannot be obtained.
In addition, a glass transition point can be measured using thermal analyzers, such as a normal method, for example, a differential scanning calorimeter (DSC). An example of the thermal analyzer is SSC5000 manufactured by Seiko Electronics. Moreover, a glass transition point can be evaluated as a glass transition point calculation value, when resin is a copolymer. The glass transition point of the copolymer and the methodology for its evaluation are as follows. The glass transition point of a copolymer having a specific monomer composition can be determined by calculation using the Fox equation. Here, the Fox formula is for calculating the Tg of the copolymer based on the Tg of the homopolymer of the monomer for each monomer forming the copolymer, The details thereof are described in Bulletin of the American Physical Society, Series 2 (Volume of the American Physical Society, Series 2) Vol. 1, No. 3, p. 123 (1956). The concept of the term “calculated glass transition point” used in the specification of the present invention includes a glass transition point calculated by the Fox equation. For example, the Tg of the homopolymer of various monomers serving as the basis for calculating the Tg of the copolymer according to the Fox formula is, for example, Polymer Data Handbook Fundamentals (Polymer Society), pages 525-546. Or actual values measured by a normal method can be employed.

  The second resin is not particularly limited as long as it has the above characteristics, and examples thereof include acrylic resins, urethane resins, epoxy resins, polyolefin resins, and the like. One type or a combination of two or more types may be used. it can. Among the above-mentioned, it is particularly preferable to use an acrylic resin. As a result, the color developability of the image can be improved, the second resin can be more effectively penetrated into the recording medium, the anchor effect becomes even more remarkable, and the friction resistance is particularly excellent. It becomes.

The resin dispersion D can be obtained by a known emulsion polymerization method. For example, it can be obtained by emulsion polymerization of an unsaturated monomer (such as an unsaturated vinyl monomer) in water containing a polymerization initiator and a surfactant.
Examples of unsaturated monomers include acrylic acid ester monomers, methacrylic acid ester monomers, aromatic vinyl monomers, vinyl ester monomers, vinyl cyanide compounds generally used in emulsion polymerization. Examples include monomers, halogenated monomers, olefin monomers, and diene monomers. Further, specific examples include methyl acrylate, ethyl acrylate, isopropyl acrylate, n-butyl acrylate, isobutyl acrylate, n-amyl acrylate, isoamyl acrylate, n-hexyl acrylate, 2-ethylhexyl acrylate, octyl acrylate, decyl acrylate, dodecyl acrylate. Acrylates such as octadecyl acrylate, cyclohexyl acrylate, phenyl acrylate, benzyl acrylate, glycidyl acrylate, methyl methacrylate, ethyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, n-amyl methacrylate, isoamyl methacrylate, n-hexyl Methacrylate, 2-ethyl Hexyl methacrylate, octyl methacrylate, decyl methacrylate, dodecyl methacrylate, octadecyl methacrylate, cyclohexyl methacrylate, methacrylic acid esters such as phenyl methacrylate, benzyl methacrylate, glycidyl methacrylate, and vinyl esters such as vinyl acetate; vinyl such as acrylonitrile and methacrylonitrile Cyanides; halogenated monomers such as vinylidene chloride and vinyl chloride; simple aromatic vinyl such as styrene, α-methylstyrene, vinyltoluene, 4-t-butylstyrene, chlorostyrene, vinylanisole, vinylnaphthalene Olefins such as ethylene and propylene; dienes such as butadiene and chloroprene; vinyl ethers, vinyl ketones, vinyl pyrroles Vinyl monomers such as Don; unsaturated carboxylic acids such as acrylic acid, methacrylic acid, itaconic acid, fumaric acid and maleic acid; acrylamides such as acrylamide, methacrylamide and N, N′-dimethylacrylamide; 2-hydroxy Examples thereof include hydroxyl group-containing monomers such as ethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, and 2-hydroxypropyl methacrylate, and one or a mixture of two or more of these can be used. .

A crosslinkable monomer having two or more polymerizable double bonds can also be used. Examples of the crosslinkable monomer having two or more polymerizable double bonds include polyethylene glycol diacrylate, triethylene glycol diacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,6-hexanediol diacrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, polypropylene glycol diacrylate, 2,2′-bis (4-acryloxypropyloxyphenyl) propane, 2,2 ′ -Diacrylate compounds such as bis (4-acryloxydiethoxyphenyl) propane, triacrylate compounds such as trimethylolpropane triacrylate, trimethylolethane triacrylate, tetramethylolmethane triacrylate Tetraacrylate compounds such as ditrimethylol tetraacrylate, tetramethylol methane tetraacrylate, pentaerythritol tetraacrylate, hexaacrylate compounds such as dipentaerythritol hexaacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, polyethylene glycol di Methacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,6-hexanediol dimethacrylate, neopentyl glycol dimethacrylate, dipropylene glycol dimethacrylate, polypropylene glycol dimethacrylate, polybutylene glycol dimethacrylate Methacrylate, 2, Examples include dimethacrylate compounds such as 2′-bis (4-methacryloxydiethoxyphenyl) propane, trimethacrylate compounds such as trimethylolpropane trimethacrylate and trimethylolethane trimethacrylate, methylenebisacrylamide, divinylbenzene, and the like. Among them, one kind or a mixture of two or more kinds can be used.
In addition to the polymerization initiator and surfactant used in the emulsion polymerization, a chain transfer agent, further a neutralizing agent, and the like may be used according to a conventional method. In particular, ammonia and inorganic alkali hydroxides such as sodium hydroxide and potassium hydroxide are preferred as the neutralizing agent.

The resin dispersion D can be manufactured as follows, for example.
In a reaction vessel equipped with a dropping device, a thermometer, a water-cooled reflux condenser and a stirrer, 100 parts of ion-exchanged water is added, and 0.2 part of a polymerization initiator is added while stirring at a temperature of 70 ° C. in a nitrogen atmosphere. To this, a separately prepared monomer solution is dropped and subjected to a polymerization reaction to prepare a primary substance. Thereafter, at a temperature of 70 ° C., 2 parts of a 10% aqueous solution of a polymerization initiator is added to the primary substance and stirred, and a separately prepared reaction solution is added and stirred to cause a polymerization reaction to obtain a polymerization reaction product. . The polymerization reaction product was neutralized with a neutralizing agent to adjust the pH to 8 to 8.5, and then filtered through a 0.3 μm filter to remove coarse particles, and the dispersoid d was dispersed. Resin dispersion D is obtained.

  As the polymerization initiator, those used for normal radical polymerization are used, for example, potassium persulfate, ammonium persulfate, hydrogen peroxide, azobisisobutyronitrile, benzoyl peroxide, dibutyl peroxide, Examples include peracetic acid, cumene hydroperoxide, t-butyl hydroxy peroxide, paramentane hydroxy peroxide, and the like. In particular, as described above, when the polymerization reaction is performed in water, a water-soluble polymerization initiator is preferable.

Examples of the emulsifier used in the polymerization reaction include those generally used as an anionic surfactant, nonionic surfactant or amphoteric surfactant in addition to sodium lauryl sulfate.
Examples of the chain transfer agent used in the polymerization reaction include t-dodecyl mercaptan, n-dodecyl mercaptan, n-octyl mercaptan, xanthogens such as dimethylxanthogen disulfide, diisobutylxanthogen disulfide, dipentene, indene, 1,4- Examples include cyclohexadiene, dihydrofuran, and xanthene.

[water]
The inkjet ink of the present invention contains water as a dispersion medium for the self-dispersing pigment. In the present invention, water is a main solvent, and it is preferable to use pure water or ultrapure water such as ion exchange water, ultrafiltration water, reverse osmosis water, and distilled water. In particular, it is preferable to use water sterilized by ultraviolet irradiation or addition of hydrogen peroxide in order to prevent the generation of mold and bacteria and enable long-term storage of the pigment ink.
The water content is preferably 10% by mass or more and 60% by mass or less. Thereby, the dispersion stability of the ink-jet ink can be further improved, and an image having excellent friction resistance and gloss can be formed.

[Zwitterionic compounds]
The ink jet ink of the present invention may contain a zwitterionic compound. By including such a compound, the penetration of the dispersoid d into the recording medium can be further improved, and the friction resistance of the image to be formed can be further improved. Furthermore, the film forming property of the first resin on the surface of the recording medium can be improved, and the gloss of the formed image can be further increased.

  The zwitterionic compound is not particularly limited, and examples thereof include betaine compounds, amino acids, and derivatives thereof. More specifically, as betaine compounds, glycine betaine (molecular weight 117, also referred to as “trimethylglycine”), γ-ptyrobetaine (145), homarine (137), trigonelin (137), carnitine (161) Homoserine betaine (161), valine betaine (159), lysine betaine (188), ornithine betaine (176), alanine betaine (117), stachydrin (185), and betaine glutamate (189). N-trialkyl substitution of an amino acid is mentioned. As amino acids, glycine (molecular weight 75), alanine (89), serine (105), threonine (119), valine (117), methionine (149), cysteine (121), proline (same) 115), lysine (same as 146), histidine (same as 155), arginine (same as 174) and derivatives thereof. Among these, betaine compounds are preferable and trimethylglycine is more preferable from the viewpoint of more surely slowing the expansion speed of the recording medium after printing and preventing clogging of the ink discharge nozzles. A zwitterionic compound is used alone or in combination of two or more, and may be synthesized by a conventional method or a commercially available product may be obtained. As a commercially available product, for example, aminocoat (manufactured by Asahi Kasei Chemicals Corporation) can be used as trimethylglycine.

The molecular weight of the zwitterionic compound is preferably 100 or more and 250 or less. Thereby, the film forming property of the first resin on the surface of the recording medium can be made more suitable, the image surface to be formed can be made smoother, and an image having a higher gloss can be formed. . Further, it is possible to further improve the penetration of the dispersoid d into the recording medium, and it is possible to further improve the friction resistance of the formed image.
The ink-jet ink preferably contains 10% by mass or more and 40% by mass or less of the zwitterionic compound, and more preferably contains 10% by mass or more and 25% by mass or less of the zwitterionic compound. Thereby, an image having excellent friction resistance and high gloss can be efficiently formed.

[Acetylene glycol]
The inkjet ink may contain acetylene glycol. Acetylene glycol is a nonionic surfactant having an acetylene group in the center and a symmetrical structure, and is applied to water-based materials in various directions as a wetting agent that does not easily foam. Acetylene glycol is excellent in functions such as wetting, defoaming, and dispersion. Since the glycol has a very stable molecular structure, it has a small molecular weight and has an effect of reducing the surface tension of water, the penetrability and bleeding of the ink on the recording medium can be controlled appropriately.

Specific examples of acetylene glycol include 2,4,7,9-tetramethyl-5-decyne-4,7-diol, 3,6-dimethyl-4-octyne-3,6-diol, and 3,5-dimethyl. Examples include -1-hexyn-3-ol.
Commercially available products of acetylene glycol include, for example, Surfynol 104 (series), 420, 440, 465, 485 (above, Air Products and Chemicals. Inc. trade name), Olphine STG, PD-001, SPC, E1004, E1010 (trade names manufactured by Nissin Chemical Industry Co., Ltd. (hereinafter, Nissin Chemical Industry Co., Ltd.)), acetylenol E00, E40, E100, LH (above, Kawaken Fine Chemicals Co., Ltd.) Ltd.) product name) and the like.
Acetylene glycol may be used individually by 1 type, and may be used in combination of 2 or more type.
The content of acetylene glycol is preferably 0.1% by mass or more and 3.0% by mass or less, and more preferably 0.3% by mass or more and 2.0% by mass or less.

[Wetting agent]
The ink jet ink may contain a wetting agent. Thereby, clogging in the vicinity of the nozzle of the inkjet head can be effectively prevented.
As the wetting agent, for example, glycerin, 1,2,6-hexanetriol, trimethylolpropane, pentamethylene glycol, trimethylene glycol, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, number Polyethylene glycol having an average molecular weight of 2000 or less, dipropylene glycol, tripropylene glycol, isobutylene glycol, 2-butene-1,4-diol, 2-ethyl-1,3-hexanediol, 2-methyl-2,4-pentanediol Polyhydric alcohols such as mesoerythritol and pentaerythritol, as well as glucose, mannose, fructose, ribose, xylose, arabinose, galactose, Sugars such as ludonic acid, glucitol (sorbit), maltose, cellobiose, lactose, sucrose, trehalose, and maltotriose, so-called solid wetting agents such as sugar alcohols, hyaluronic acids, and ureas, and ethanol, methanol, butanol, C1-C4 alkyl alcohols such as propanol and isopropanol, and 2-pyrrolidone, N-methyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone, formamide, acetamide, dimethyl sulfoxide, sorbit, Examples include sorbitan, acetin, diacetin, triacetin, and sulfolane.
A wetting agent may be used individually by 1 type, and may be used in combination of 2 or more type.
The content of the wetting agent is preferably 10% by mass or more and 50% by mass or less.

[Antioxidant]
The inkjet ink may contain an antioxidant.
Examples of antioxidants (ultraviolet absorbers) include L-ascorbic acid and salts thereof, and lanthanide oxides such as allophanates such as allophanate and methyl allophanate, biurets such as biuret, dimethylbiuret and tetramethylbiuret. Etc. As these commercially available products, for example, Tinuvin 328, 900, 1130, 384, 292, 123, 144, 622, 770, 292, Irgacor 252, 153, Irganox 1010, 1076, 1035, MD1024 manufactured by Ciba Geigy are used.
An antioxidant may be used individually by 1 type and may be used in combination of 2 or more type.
The content of the antioxidant is preferably 0.5% by mass or less.

[Preservatives and fungicides]
The inkjet ink may contain a preservative / antifungal agent.
Examples of the antiseptic / antifungal agent include sodium benzoate, sodium pentachlorophenol, sodium 2-pyridinethiol-1-oxide, sodium sorbate, sodium dehydroacetate, 1,2-dibenzisothiazoline-3-one , Dichlorophen, hexachlorophene, p-hydroxybenzoate, ethylenediaminetetraacetic acid (EDTA), sodium dehydroacetate, 3,4-isothiazolin-3-one, and 4,4-dimethyloxazolidine. Examples of these commercially available products include Proxel CRL, Proxel BDN, Proxel GXL, Proxel XL-2 (1,2-benchazolin-3-one), Proxel TN (all trade names manufactured by Avecia), and the like. .
An antiseptic | preservative and an antifungal agent may be used individually by 1 type, and may be used in combination of 2 or more type.
The content of the antiseptic / antifungal agent is preferably 0.5% by mass or less.

[Penetration enhancer]
The ink-jet ink may contain a penetration enhancer.
As such a penetration enhancer, at least one of alkyl ethers of polyhydric alcohols (also referred to as glycol ethers) and 1,2-alkyldiols is preferably used. Examples of the alkyl ether of polyhydric alcohol include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol mono Isopropyl ether, diethylene glycol monoisopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene glycol monobutyl ether, ethylene glycol mono-t-butyl ether, diethylene glycol mono-t-butyl ether, 1-methyl-1-methoxybutanol, Lopylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-t-butyl ether, propylene glycol monopropyl ether, propylene glycol monoisopropyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether , Dipropylene glycol monoisopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, and the like. Examples of the 1,2-alkyldiol include 1,2-pentanediol and 1,2-hexanediol. In addition to these, straight-line such as 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol. There may be mentioned diols of chain hydrocarbons.
A penetration enhancer may be used individually by 1 type, and may be used in combination of 2 or more type.
The content of the penetration enhancer is preferably 3% by mass or more and 20% by mass or less.
As described above, the inkjet ink of the present invention includes, for example, a dispersion in which a self-dispersing pigment is dispersed, a resin dispersion B in which a dispersoid b containing the first resin as described above is dispersed, It can be obtained by mixing the resin dispersion D in which the dispersoid d containing the second resin is dispersed and water.

<Inkjet recording device>
Next, an ink jet recording apparatus to which the ink jet ink of the present invention is suitably applied will be described.
As shown in FIGS. 1 to 4, the ink jet recording apparatus 100 according to the present embodiment is disposed in a casing 102 of the ink jet recording apparatus 100 and records on the main surface of the recording medium 101 using an ink composition. An inkjet head unit 190 as a recording unit for performing recording, a discharge unit 150 for discharging the recording medium 101 from the casing 102 to the outside with the main surface facing downward, and a back surface of the recording medium 101 discharged from the discharge unit 150 Is pressed downward to correct the recording medium 101 and guide the recording medium 101, and the correction guide 301 is perpendicular to the ejection direction of the recording medium 101 and perpendicular to the vertical direction. A width direction moving part 350 that moves in the width direction (hereinafter simply referred to as “width direction”), and the recording medium 101 discharged from the discharge part 150 That the discharge tray 106, a user interface 400, a control unit 111 for performing various controls, and is configured to include a position detecting sensor 109 for detecting the position of the recording medium 101, a fed.

  The ink jet head unit 190 ejects ink droplets (hereinafter also referred to as “ink droplets”) onto a recording medium 101 such as paper and records an image, and a plurality of ink jet heads corresponding to the type of ink. 110 and a carriage (not shown) for mounting them, and each inkjet head 110 is a so-called line head in which a large number of ink discharge nozzles corresponding to the entire width are arranged in the width direction of the recording medium 101. It consists of However, in the present invention, the inkjet head 110 is not limited to a line head, and may be a serial head.

  Below the inkjet head unit 190, a storage cassette 104 that stores the recording medium 101 before recording, a feed roller 105 that feeds the recording medium 101 from the storage cassette 104, and the recording medium 101 are conveyed. A pair of transport rollers (gate rollers) 140 and a transport belt 130 for transporting the recording medium 101 are sequentially arranged. In addition, a decompression suction unit 210 that decompresses and sucks the recording medium 101 through an opening (not shown) of the transport belt 130 is disposed below the transport belt 130.

The feeding roller 105 is a roller for feeding the recording medium 101 inside the storage cassette 104 to the conveying roller 140, and is driven by a motor 118 that is driven and controlled by the control unit 111.
The conveyance roller 140 includes a driving roller 140A as a roller unit that is driven by a motor 116 that is driven and controlled by the control unit 111, and a driven roller 140B that is driven by contacting the driving roller 140A.

The conveyance belt 130 is arranged in an annular shape, and conveys the recording medium 101 to the inkjet head unit 190 (recording area). The conveyor belt 130 is stretched over a driving roller 180 that drives the conveyor belt 130 and a driven roller 170 that is driven while the conveyor belt 130 is opposed to the discharge port of the inkjet head unit 190. Move). The driving roller 180 is driven by a motor 115 that is driven and controlled by the control unit 111. However, in the present invention, the transport belt 130 may not be used for transporting the recording medium 101, and a so-called roller transport system may be used.
The reduced pressure suction unit 210 includes a suction fan 210A and a body 210B surrounding the suction fan 210A. The suction fan 210 </ b> A is driven by a motor 211 that is driven and controlled by the control unit 111, and sucks the recording medium 101 on the conveyor belt 130 under reduced pressure.

  The discharge unit 150 is disposed on the downstream side of the inkjet head unit 190, and includes a pair of discharge rollers 151, 152, and 154 for discharging the recording medium 101, between the discharge rollers 151 and 152, and the discharge rollers 152 and 152. 154 and a conveyance path 156 for conveying the recording medium 101 between them. The discharge roller 151 includes a driving roller 151A driven by a motor 117 that is driven and controlled by the control unit 111, and a driven roller 151B that is driven by contacting the driving roller 151A. The discharge roller 152 includes a driving roller 152A driven by a motor 153 that is driven and controlled by the control unit 111, and a driven roller 152B that is driven by contacting the driving roller 152A. The discharge roller 154 includes a driving roller 154A driven by a motor 155 that is driven and controlled by the control unit 111, and a driven roller 154B that is driven by contacting the driving roller 154A. The discharge roller 154 is disposed at a position that is a boundary between the inside and the outside of the housing 102, and this position is a discharge port of the recording medium 101.

  The correction guides 301 are respectively attached to both sides in the width direction of the outer wall of the housing 102 on the side where the recording medium 101 is discharged and above the drive roller 154A via a width direction moving unit 350 described in detail later. The recording medium 101 is corrected by pressing the back surface of the recording medium 101 discharged from the discharge unit 150 downward, and the path of the recording medium 101 is guided toward the discharge tray 106. . Each of the correction guides 301 is connected to a plate-like support portion 301A that is movably attached to the width-direction moving portion 350, and an angle adjustment mechanism 302 that is disposed at the lower end of the support portion 301A. Inclined portions 301B that are inclined obliquely downward in front of the conveyance direction of the medium 101 are provided.

The angle adjusting mechanism 302 includes a pair of gears (not shown) that mesh with each other, and a motor 305 that is driven and controlled by the control unit 111 and drives one of the pair of gears.
The inclination portion 301B is configured such that the inclination angle α with the support portion 301A is changed according to the meshing position of the pair of gears changed by driving one gear by the motor 305. The inclined portion 301B can adjust a pressing force for pressing the recording medium 101 by an inclination angle α with the support portion 301A.

  A medium pressing unit 303 is disposed between the correction guide 301 and the correction guide 301 disposed on the outer wall of the housing 102 on the side where the recording medium 101 is discharged. The medium pressing portion 303 is a plate-like member that extends forward from the outer wall of the housing 102 in the transport direction, and the shape of the recording medium 101 transported below is viewed from the front end in the transport direction. Tapering as you head. Further, a plate-like portion that hangs down is provided in the vicinity of the tip of the medium pressing portion 303, and the plate-like portion has a triangular shape that spreads downward toward the tip. However, the shape of the medium pressing portion 303 is not particularly limited as long as the shape is suitable for fulfilling the function. That is, the medium pressing portion 303 can sandwich a plurality of stacked recording media 101 together with the discharge tray 106 even if both ends in the width direction of the recording medium 101 are curved upward and slightly lifted. What is necessary is just to arrange the stacked state of the recording medium 101.

  The width direction moving unit 350 is driven and controlled by the control unit 111, the rack 351 long disposed in the width direction of the outer wall of the housing 102, the pinion 352 that meshes with the rack 351 and moves in the width direction, and controls the pinion 352. A motor 353 to be driven. A support portion 301 </ b> A of the correction guide 301 is attached to the pinion 352, and the correction guide 301 moves in the width direction of the housing 102 when the pinion 352 moves in the width direction.

The user interface 400 is connected to the control unit 111 and displays a selection screen for requesting the user to select one of the types and sizes of a plurality of recording media registered in advance. An input unit that allows the user to input a desired condition from the contents that are input, and an output unit that outputs information input to the input unit to the control unit 111 are provided.
The control unit 111 is a CPU (Central Processing Unit) that executes various processes such as a recording process and a correction process of the recording medium 101 by the correction guide 301, a recording data input via an interface from a host computer or the like, and a user interface 400. RAM (Random Access Memory) that stores various data such as data input to the data storage area or temporarily stores various data, PROM (Programmable Read-Only Memory) that stores a control program for controlling each part, EEPROM ( (ElectricallyErasableProgrammableRead-OnlyMemory) and the like.

  Further, the control unit 111 stores the type and size of the recording medium 101 selected by the user through the user interface 400, the ink ejection amount and ejection position calculated from the recording data obtained from the host computer, and the recording stored in advance in the RAM. From the ink data and the temperature detected by a temperature sensor (not shown), the position that is most curved in the width direction of the recording medium 101 is estimated, and a curved position acquisition unit that acquires the position, and the recording medium discharged from the discharge unit 150 101 includes a bending amount acquisition unit that acquires the bending amount of 101, and a pressing control unit that controls the pressing force of the correction guide 301 in accordance with the bending amount acquired by the bending amount acquisition unit. Is stored in PROM or EEPROM. The control unit 111 has map data indicating the relationship between the amount of bending of the recording medium 101 and the pressing force of the correction guide 301 necessary to appropriately correct the bending of the recording medium 101 (paper discharge curl). is doing.

  In the case of the present embodiment, this pressing force is adjusted according to the inclination angle α (see FIG. 4) of the inclined portion 301B of the correction guide 301 with respect to the support portion 301A. That is, when the inclination angle α increases, the lower end of the inclined portion 301B decreases and the pressing force against the recording medium 101 increases, and when the inclination angle α decreases, the lower end of the inclined portion 301B increases and the pressing force against the recording medium 101 increases. Therefore, the inclination angle α is adjusted by acquiring in advance the relationship between the pressing force necessary for correcting the recording medium 101 and the inclination angle α necessary for applying the pressing force. Thus, optimal correction can be performed.

As the position detection sensor 109, for example, a reflection type photosensor in which an infrared light emitting diode as a light emitting element and a phototransistor as a light receiving element are combined is used. The position detection sensor 109 is disposed in a paper conveyance unit between the feeding roller 105 and the conveyance roller 140, detects the tip position of the recording medium 101 being conveyed (presence / absence of the recording medium 101), and a detection signal thereof. Is input to the control unit 111. In the control unit 111, drive control processing of the transport roller 140 is performed based on the detection signal of the leading end position of the recording medium 101.
The ink jet recording apparatus 100 is provided with a temperature sensor (not shown) that detects the internal temperature, and the control unit 111 monitors the temperature detected by the temperature sensor.

As mentioned above, although this invention was demonstrated based on suitable embodiment, this invention is not limited to these.
For example, the inkjet ink of the present invention may include a resin dispersion in which a resin other than the above-described resins is dispersed.

Next, specific examples of the present invention will be described.
[1] Preparation of self-dispersing pigment (1) Black self-dispersing pigment dispersion (B1)
100 g of commercially available carbon black Color Black S170 (trade name: manufactured by Degussa Huls) was mixed with 1 kg of water and pulverized with a ball mill using zirconia beads. 1400 g of sodium hypochlorite (effective chlorine concentration 12%) was added dropwise to this pulverized stock solution, reacted for 5 hours while pulverizing with a ball mill, and further boiled for 4 hours with stirring to perform wet oxidation. The obtained dispersion stock solution was filtered with glass fiber filter paper GA-100 (trade name: manufactured by Advantech Toyo Co., Ltd.) and further washed with water. The obtained wet cake is re-dispersed in 5 kg of water, desalted and purified with a reverse osmosis membrane until the conductivity becomes 2 mS / cm, and further concentrated until the pigment concentration becomes 20% by mass to be self-dispersing black. A pigment dispersion B1 was prepared. The volume average particle size of the pigment in this dispersion was measured by measuring the particle size distribution of Microtrac UPA 150 (manufactured by Microtrac), and found to be 120 nm.

(2) Cyan self-dispersing pigment dispersion (C1)
A 4 liter stainless steel beaker was attached to a rotor-stator type high shear mixer (Silverson L4RT-A) and immersed in an ice bath. In this beaker, C.I. I. Pigment Blue 15: 4 About 75 g and 1000 g of water were added and homogenized at 7200 rpm for 15 minutes. To this was added 20 ml of an isopropanol solution in which 2.07 g (0.01 mol) of o-acetaniside was dissolved, and the mixture was further stirred for 15 minutes.

In a separate container, 4.35 g (0.025 mol) of sulfanilic acid, 30 mL of 1N HCl, and 1.73 g (0.025 mol) of sodium nitrite were mixed at 5-10 ° C. to form a diazonium salt. . Then, this was changed to the above C.I. I. Pigment Blue 15: 4 and o-acetaniside were added with stirring to maintain the temperature at about 10 ° C. This mixture was adjusted to pH 5-6 by dropwise addition of 5M sodium hydroxide solution, and further stirred for 2 hours while confirming the progress of the reaction based on the presence or absence of a diazonium salt. When a diazonium salt is present, when the reaction mixture and a 1M Na ₂ CO ₃ solution in which 0.1% aminosalicylic acid is dissolved are dropped on a filter paper one by one, when the spread of these two drops touches, Become.

  The mixture was transferred to a Telsonic flow sonicator and sonicated for 2 hours, and the resulting pigment dispersion was purified using a 50 nm diafiltration membrane column and then concentrated to a solids content of 20% Thus, a self-dispersing pigment dispersion (C1) was obtained. The volume average particle size of the pigment in this dispersion was measured by measuring the particle size distribution of Microtrac UPA 150 (manufactured by Microtrac), and found to be 120 nm.

(3) Cyan self-dispersing pigment dispersion (C2)
A cyan self-dispersing pigment dispersion C2 was prepared in the same manner as the cyan self-dispersing pigment dispersion C1 except that the production conditions were changed so that the volume average particle diameter was 105 nm.
(4) Cyan self-dispersing pigment dispersion (C3)
A cyan self-dispersing pigment dispersion C3 was prepared in the same manner as the cyan self-dispersing pigment dispersion C1 except that the production conditions were changed so that the volume average particle diameter was 85 nm.

(5) Yellow self-dispersing pigment dispersion (Y1)
As a pigment, C.I. I. Pigment Blue 15: 4 instead of C.I. I. A yellow self-dispersing pigment dispersion (Y1) having a solid content of 20% by mass was prepared in the same manner as the cyan self-dispersing pigment dispersion (C1) except that CI Pigment Yellow 74 was used. The volume average particle size of the pigment in this dispersion was measured by measuring the particle size distribution of Microtrac UPA 150 (manufactured by Microtrac), and found to be 110 nm.

(6) Magenta self-dispersing pigment dispersion (M1)
As a pigment, C.I. I. Pigment Blue 15: 4 instead of C.I. I. Except for using Pigment Red 122, a magenta self-dispersing pigment dispersion (M1) having a solid content concentration of 20% by mass was prepared in the same manner as the Cicyan self-dispersing pigment dispersion (C1). The volume average particle size of the pigment in this dispersion was measured by measuring the particle size distribution of Microtrac UPA 150 (manufactured by Microtrac) and found to be 100 nm.

[2] Preparation of resin dispersion (resin emulsion) B (1) Resin emulsion B1
On the melting drum, 40 parts of polyethylene wax (Mitsui High Wax 210P, Mitsui Chemicals) as the polyolefin oligomer and 60 parts of maleic acid-modified polyethylene wax (Mitsui High Wax 1105A, Mitsui Chemicals) as the maleic acid-modified polyolefin oligomer and polyoxyethylene 10 parts of polyoxyethylene alkyl (C = 11) ether (Emulgen 1108, manufactured by Kao Corporation) having an HLB of 13.5 as an alkyl ether is heated at 160 ° C. and stirred and mixed for 2 hours. Then, while stirring at 8000 rpm in a pressure-resistant homomixer (Homomixer MARKII: manufactured by Tokushu Kika Co., Ltd.), 1800 g / hr of a potassium hydroxide solution in which 9880 mL of water and 120 g of 85% potassium hydroxide were previously dissolved and the above-described polyolefin oligomer, Maleic acid-modified polyolefin oligomer and polyoxyethylene alkyl ether are fed to the mixer by a gear pump while being melted at 140 ° C. at a rate of 1200 g / hr. The density is 0.92 g / cm ³ and the average particle size of the dispersoid is A 160 nm resin emulsion B1 was obtained.

(2) Resin emulsion B2
70 parts of polyethylene wax (Mitsui High Wax 210P, manufactured by Mitsui Chemicals) as a polyolefin oligomer and 30 parts of maleic acid-modified polyethylene wax (Mitsui High Wax 1105A, manufactured by Mitsui Chemicals) as a maleic acid-modified polyolefin oligomer and polyoxyethylene 10 parts of polyoxyethylene alkyl (C = 11) ether (Emulgen 1108, manufactured by Kao Corporation) having an HLB of 13.5 as an alkyl ether is heated at 160 ° C. and stirred and mixed for 2 hours. Then, while stirring at 8000 rpm in a pressure-resistant homomixer (Homomixer MARKII: manufactured by Tokushu Kika Co., Ltd.), 1800 g / hr of a potassium hydroxide solution in which 9880 mL of water and 120 g of 85% potassium hydroxide were previously dissolved and the above-described polyolefin oligomer, Maleic acid-modified polyolefin oligomer and polyoxyethylene alkyl ether are fed to the mixer by a gear pump while being melted at 140 ° C. at a rate of 1200 g / hr. The density is 0.92 g / cm ³ and the average particle size of the dispersoid is A 220 nm resin emulsion B2 was obtained.

(3) Resin emulsion B3
70 parts of polyethylene wax (Mitsui High Wax 210P, manufactured by Mitsui Chemicals) as a polyolefin oligomer and 30 parts of maleic acid-modified polyethylene wax (Mitsui High Wax 1105A, manufactured by Mitsui Chemicals) as a maleic acid-modified polyolefin oligomer and polyoxyethylene 10 parts of polyoxyethylene alkyl decyl ether (Neugen XL-80, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) having an HLB of 13.8 as an alkyl ether is heated at 160 ° C. and mixed with stirring for 2 hours. Thereafter, 1800 g / hr of a potassium hydroxide solution in which 9880 mL of water and 120 g of 85% potassium hydroxide were previously dissolved in a pressure-resistant homomixer (Homomixer MARKII: manufactured by Tokushu Kika Co., Ltd.) and the above-mentioned polyolefin oligomer were previously dissolved. , Maleic acid-modified polyolefin oligomer and polyoxyethylene alkyl ether are fed to the mixer by a gear pump while being melted at 140 ° C. at a rate of 1200 g / hr, and the density is 0.92 g / cm ³ and the average particle size of the dispersoid Gave a resin emulsion B3 of 310 nm.

(4) Resin emulsion B4
On the melting drum, 100 parts of maleic acid-modified polyethylene wax (Mitsui High Wax 2203A, manufactured by Mitsui Chemicals) as maleic acid-modified polyolefin oligomer and polyoxyethylene lauryl ether (Emulgen 120, HLB of 15.3 as polyoxyethylene alkyl ether) 10 parts) are heated at 160 ° C. and stirred and mixed for 2 hours. Then, 1800 g / hr of a potassium hydroxide solution in which 9760 mL of water and 240 g of 85% potassium hydroxide were previously dissolved in a pressure-resistant homomixer (Homomixer MARK II: manufactured by Tokushu Kika Co., Ltd.) and the maleic acid described above. The modified polyolefin oligomer and polyoxyethylene alkyl ether are supplied to the mixer by a gear pump while being melted at 140 ° C. at a rate of 1200 g / hr, the density is 0.92 g / cm ³ , and the average particle size of the dispersoid is 400 nm. Resin emulsion B4 was obtained.

(5) Resin emulsion B5
70 parts of polyethylene wax (Mitsui High Wax 210P, manufactured by Mitsui Chemicals) as a polyolefin oligomer and 30 parts of maleic acid-modified polyethylene wax (Mitsui High Wax 1105A, manufactured by Mitsui Chemicals) as a maleic acid-modified polyolefin oligomer and polyoxyethylene 10 parts of polyoxyethylene oleyl ether (Emulgen 420, manufactured by Kao Corporation) having an HLB of 13.6 as an alkyl ether is heated at 160 ° C. and stirred for 2 hours. Thereafter, 1800 g / hr of a potassium hydroxide solution in which 9880 mL of water and 120 g of 85% potassium hydroxide were previously dissolved in a pressure-resistant homomixer (Homomixer MARKII: manufactured by Tokushu Kika Co., Ltd.) and the above-mentioned polyolefin oligomer were previously dissolved. , Maleic acid-modified polyolefin oligomer and polyoxyethylene alkyl ether are fed to the mixer by a gear pump while being melted at 140 ° C. at a rate of 1200 g / hr, and the density is 0.92 g / cm ³ and the average particle size of the dispersoid Gave a resin emulsion B5 of 150 nm.

(6) Resin emulsion B6
70 parts of polyethylene wax (Mitsui High Wax 210P, manufactured by Mitsui Chemicals) as a polyolefin oligomer and 30 parts of maleic acid-modified polyethylene wax (Mitsui High Wax 1105A, manufactured by Mitsui Chemicals) as a maleic acid-modified polyolefin oligomer and polyoxyethylene 10 parts of polyoxyethylene lauryl ether (Emulgen 120, manufactured by Kao Corporation) having an HLB of 15.3 as alkyl ether is heated at 160 ° C. and stirred for 2 hours. Thereafter, 1800 g / hr of a potassium hydroxide solution in which 9880 mL of water and 120 g of 85% potassium hydroxide were previously dissolved in a pressure-resistant homomixer (Homomixer MARKII: manufactured by Tokushu Kika Co., Ltd.) and the above-mentioned polyolefin oligomer were previously dissolved. , Maleic acid-modified polyolefin oligomer and polyoxyethylene alkyl ether are fed to the mixer by a gear pump while being melted at 140 ° C. at a rate of 1200 g / hr, and the density is 0.92 g / cm ³ and the average particle size of the dispersoid Of 240 nm was obtained.

(7) Resin emulsion B7
70 parts of polyethylene wax (Mitsui High Wax 210P, manufactured by Mitsui Chemicals) as a polyolefin oligomer and 30 parts of maleic acid-modified polyethylene wax (Mitsui High Wax 1105A, manufactured by Mitsui Chemicals) as a maleic acid-modified polyolefin oligomer and polyoxyethylene 10 parts of polyoxyethylene octyldodecyl ether (Emulgen 2020G-HA, manufactured by Kao Corporation) having an HLB of 13.0 as an alkyl ether is heated at 160 ° C. and mixed with stirring for 2 hours. Thereafter, 1800 g / hr of a potassium hydroxide solution in which 9880 mL of water and 120 g of 85% potassium hydroxide were previously dissolved in a pressure-resistant homomixer (Homomixer MARKII: manufactured by Tokushu Kika Co., Ltd.) and the above-mentioned polyolefin oligomer were previously dissolved. , Maleic acid-modified polyolefin oligomer and polyoxyethylene alkyl ether are fed to the mixer by a gear pump while being melted at 140 ° C. at a rate of 1200 g / hr, and the density is 0.92 g / cm ³ and the average particle size of the dispersoid Of 330 nm was obtained.

[3] Preparation of resin dispersion (resin emulsion) D (1) Resin emulsion D1
A reaction vessel equipped with a stirrer, a reflux condenser, a dropping device, and a thermometer was charged with 1000 g of ion exchange water and 2.5 g of sodium lauryl sulfate, and the temperature was raised to 70 ° C. while purging with nitrogen under stirring. Maintaining the internal temperature at 70 ° C., adding 4 g of potassium persulfate as a polymerization initiator, dissolving, and previously stirring 450 g of ion exchange water, 3 g of sodium lauryl sulfate, 20 g of acrylamide, 300 g of styrene, 640 g of butyl acrylate, and 30 g of methacrylic acid The emulsion prepared by adding below was continuously dropped into the reaction solution over 4 hours. After completion of the dropwise addition, aging was performed for 3 hours. The obtained aqueous emulsion was cooled to room temperature, and then ion-exchanged water and 5% aqueous sodium hydroxide solution were added to adjust the solid content to 40% by mass and pH 8. In the obtained resin emulsion D1, the glass transition temperature of the resin was −15 ° C., the density of the resin emulsion D1 was 1.12 g / cm ³ , and the average particle size of the dispersoid was 80 nm.

(2) Resin emulsion D2
A reaction vessel equipped with a stirrer, a reflux condenser, a dropping device, and a thermometer was charged with 1000 g of ion-exchanged water and 7.5 g of sodium lauryl sulfate, and the temperature was raised to 70 ° C. while purging with nitrogen under stirring. The internal temperature was kept at 70 ° C., 4 g of potassium persulfate was added as a polymerization initiator, and after dissolution, 450 g of ion exchange water, 3 g of sodium lauryl sulfate, 20 g of acrylamide, 130 g of styrene, 780 g of 2-ethylhexyl acrylate, 30 g of methacrylic acid, Then, an emulsion prepared by adding 2 g of ethylene glycol dimethacrylate under stirring was continuously dropped into the reaction solution over 4 hours. After completion of the dropwise addition, aging was performed for 3 hours. After cooling the obtained aqueous emulsion to room temperature, ion exchange water and 5% aqueous ammonia solution were added to adjust the solid content to 40% by mass and pH 8. In the obtained resin emulsion D2, the glass transition temperature of the resin was −50 ° C., the density of the resin emulsion D2 was 1.12 g / cm ³ , and the average particle size of the dispersoid was 60 nm.

(3) Resin emulsion D3
A reaction vessel equipped with a stirrer, a reflux condenser, a dropping device, and a thermometer was charged with 1000 g of ion-exchanged water and 7.5 g of sodium lauryl sulfate, and the temperature was raised to 70 ° C. while purging with nitrogen under stirring. Maintaining the internal temperature at 70 ° C., adding 4 g of potassium persulfate as a polymerization initiator, dissolving, and previously stirring 450 g of ion exchange water, 3 g of sodium lauryl sulfate, 20 g of acrylamide, 300 g of styrene, 640 g of butyl acrylate, and 30 g of methacrylic acid The emulsion prepared by adding below was continuously dropped into the reaction solution over 4 hours. After completion of the dropwise addition, aging was performed for 3 hours. The obtained aqueous emulsion was cooled to room temperature, and then ion-exchanged water and 5% aqueous sodium hydroxide solution were added to adjust the solid content to 40% by mass and pH 8. In the obtained resin emulsion D3, the glass transition temperature of the resin was −15 ° C., the density of the resin emulsion D3 was 1.12 g / cm ³ , and the average particle size of the dispersoid was 60 nm.

(4) Resin emulsion D4
A reaction vessel equipped with a stirrer, a reflux condenser, a dropping device, and a thermometer was charged with 1000 g of ion-exchanged water and 7.5 g of sodium lauryl sulfate, and the temperature was raised to 70 ° C. while purging with nitrogen under stirring. The internal temperature was kept at 70 ° C., 4 g of potassium persulfate was added as a polymerization initiator, and after dissolution, 450 g of ion-exchanged water, 3 g of sodium lauryl sulfate, 20 g of acrylamide, 356 g of styrene, 545 g of butyl acrylate, and 30 g of methacrylic acid were previously stirred. The emulsion prepared by adding below was continuously dropped into the reaction solution over 4 hours. After completion of the dropwise addition, aging was performed for 3 hours. The obtained aqueous emulsion was cooled to room temperature, and then ion-exchanged water and 5% aqueous sodium hydroxide solution were added to adjust the solid content to 40% by mass and pH 8. In the obtained resin emulsion D4, the glass transition temperature of the resin was −6 ° C., the density of the resin emulsion D4 was 1.12 g / cm ³ , and the average particle size of the dispersoid was 60 nm.

(5) Resin emulsion D5
A reaction vessel equipped with a stirrer, a reflux condenser, a dropping device, and a thermometer was charged with 1000 g of ion-exchanged water and 7.5 g of sodium lauryl sulfate, and the temperature was raised to 70 ° C. while purging with nitrogen under stirring. The internal temperature is kept at 70 ° C., 4 g of potassium persulfate is added as a polymerization initiator, and after dissolution, 450 g of ion exchange water, 3 g of sodium lauryl sulfate, 20 g of acrylamide, 500 g of styrene, 410 g of butyl acrylate, 30 g of methacrylic acid, and ethylene An emulsion prepared by adding 2 g of glycol dimethacrylate under stirring was continuously dropped into the reaction solution over 4 hours. After completion of the dropwise addition, aging was performed for 3 hours. The obtained aqueous emulsion was cooled to room temperature, and then ion-exchanged water and 5% aqueous sodium hydroxide solution were added to adjust the solid content to 40% by mass and pH 8. In the obtained resin emulsion D5, the glass transition temperature of the resin was 15 ° C., the density of the resin emulsion D5 was 1.12 g / cm ³ , and the average particle size of the dispersoid was 60 nm.

(6) Resin emulsion D6
A reaction vessel equipped with a stirrer, a reflux condenser, a dropping device, and a thermometer was charged with 1000 g of ion exchange water and 2.5 g of sodium lauryl sulfate, and the temperature was raised to 70 ° C. while purging with nitrogen under stirring. The internal temperature was kept at 70 ° C., 4 g of potassium persulfate was added as a polymerization initiator, and after dissolution, 450 g of ion exchange water, 3 g of sodium lauryl sulfate, 20 g of acrylamide, 130 g of styrene, 780 g of 2-ethylhexyl acrylate, 30 g of methacrylic acid, Then, an emulsion prepared by adding 2 g of ethylene glycol dimethacrylate under stirring was continuously dropped into the reaction solution over 4 hours. After completion of the dropwise addition, aging was performed for 3 hours. After cooling the obtained aqueous emulsion to room temperature, ion exchange water and 5% aqueous ammonia solution were added to adjust the solid content to 40% by mass and pH 8. In the obtained resin emulsion D6, the glass transition temperature of the resin was −50 ° C., the density of the resin emulsion D6 was 1.12 g / cm ³ , and the average particle size of the dispersoid was 80 nm.

(7) Resin emulsion D7
A reaction vessel equipped with a stirrer, a reflux condenser, a dropping device, and a thermometer was charged with 1000 g of ion exchange water and 2.5 g of sodium lauryl sulfate, and the temperature was raised to 70 ° C. while purging with nitrogen under stirring. The internal temperature was kept at 70 ° C., 4 g of potassium persulfate was added as a polymerization initiator, and after dissolution, 450 g of ion-exchanged water, 3 g of sodium lauryl sulfate, 20 g of acrylamide, 356 g of styrene, 545 g of butyl acrylate, and 30 g of methacrylic acid were previously stirred. The emulsion prepared by adding below was continuously dropped into the reaction solution over 4 hours. After completion of the dropwise addition, aging was performed for 3 hours. The obtained aqueous emulsion was cooled to room temperature, and then ion-exchanged water and 5% aqueous sodium hydroxide solution were added to adjust the solid content to 40% by mass and pH 8. In the obtained resin emulsion D7, the glass transition temperature of the resin was −6 ° C., the density of the resin emulsion D7 was 1.12 g / cm ³ , and the average particle size of the dispersoid was 80 nm.

[4] Preparation of inkjet ink Each component was mixed in the ratios shown in Tables 1 and 2, and after worshiping at room temperature for 2 hours, filtered through a membrane filter having a pore size of 5 μm, Examples 1 to 24, comparison Each inkjet ink of Examples 1-6 was prepared. However, the addition amounts shown in Tables 1 and 2 are all expressed as a concentration of mass%, and the numbers in () of the pigment dispersion indicate the solid content concentration (mass%) of the pigment and () of the resin emulsion. The number indicates the resin concentration (% by mass). The “remaining amount” of ion-exchanged water means that ion-exchanged water is added so that the total amount of ink for ink jet becomes 100% by mass.

[5] Evaluation [Evaluation of fabric rubbing test]
Each adjusted ink was filled in an ink jet printer PX-A550 (manufactured by Seiko Epson), and a 100% duty patch pattern was printed. As a recording medium, printing was performed using photographic paper <glossy> (manufactured by Seiko Epson) and photo glossy paper (manufactured by Seiko Epson), and the obtained sample was allowed to stand in a room temperature and humidity environment for 1 hour. After leaving, the printed part was swept at a speed of 1 cm / sec while being pressed with a weight of 10 mm in diameter and a load of 200 g so that the surface of Bencott M-3 (manufactured by Asahi Kasei) was rubbed. Each patch portion after rubbing and the rubbing surface of Bencott were visually observed and judged based on the following evaluation criteria.
A: No rubbing marks due to cloth rubbing are observed.
B: Although rubbing marks are observed, no stain is observed on the cloth surface.
C: Scratch marks are observed, and a slight stain is recognized on the cloth surface (acceptable).
D: Scratch marks are observed, and a large amount of dirt is observed on the cloth surface (unacceptable).

[Line marker test]
Each adjusted ink was filled in an ink jet printer PX-A550 (manufactured by Seiko Epson Corporation), and a 24 point character pattern was printed. Printing was performed using Xerox 4200 and Xerox P paper as the recording medium, and the obtained sample was allowed to stand for 24 hours in a normal temperature and humidity environment. After standing, the printed characters were rubbed at a writing pressure of 300 g / 15 mm using a yellow aqueous fluorescent pen ZEBRA PEN2 (registered trademark) manufactured by Zebra. The printed characters after rubbing were visually observed and judged based on the following evaluation criteria.
A: When the same part is rubbed twice, no stain is observed.
B: Dirt is not recognized by the first rubbing, but dirt is recognized by the second rubbing.
C: Slight dirt is recognized by the first rubbing (acceptable).
D: A large amount of dirt is recognized by the first rubbing (unacceptable).

[Evaluation of gross]
Each adjusted ink was filled in an ink jet printer PX-A550 (manufactured by Seiko Epson), and a 100% duty patch pattern was printed. As a recording medium, printing was performed using photographic paper <glossy> (manufactured by Seiko Epson) and photo glossy paper (manufactured by Seiko Epson), and the obtained sample was allowed to stand in a room temperature and humidity environment for 1 hour. After leaving, each patch part was measured for gloss at 20 ° using a gloss meter GM-268 (manufactured by Konica Minolta) using a Gretag densitometer (manufactured by Gretag Macbeth), and the average gloss value was based on the following criteria: Judgment based on.
A: 150% or more of the recording medium gloss at a regular reflection angle of 20 °.
B: 100% or more and less than 150% of the recording medium gloss at a regular reflection angle of 20 °.
C: 50% or more and less than 100% of the recording medium gloss at a regular reflection angle of 20 °.
D: Less than 50% of recording medium gloss at regular reflection angle of 20 ° (unacceptable).

[OD value]
Each adjusted ink was filled in an ink jet printer PX-A550 (manufactured by Seiko Epson), and a 100% duty patch pattern was printed. Printing was performed using Xerox 4200 or Xerox P paper as a recording medium, and the obtained sample was left in a room temperature and humidity environment for 1 hour. After leaving, each patch part was measured for OD of each patch part using a Gretag densitometer (manufactured by Gretag Macbeth), and the average OD value was determined based on the following criteria.
A: The optical reflection density (OD value) is 1.3 or more.
B: Optical reflection density (OD value) is 1.2 or more and less than 1.3.
C: The optical reflection density (OD value) is 1.1 or more and less than 1.2.
D: Optical reflection density (OD value) is less than 1.1 (unacceptable).

[Rubbing marks on the recording surface]
Each adjusted ink was filled in a recording apparatus shown in the drawing having a face-down paper discharge mechanism, and a 100% duty patch pattern was printed. As a recording medium, 100 sheets of 100% duty patch pattern were continuously printed using XeroxP paper, and stacked on a dedicated paper discharge tray. The printed surface of the recording medium after continuous stacking was visually observed by face-down in a normal temperature and humidity environment, and the determination was made based on the following evaluation criteria.
A: When 100 solid images are stacked continuously, no rubbing marks are observed on the recording surface.
B: Same as above, a slight rubbing mark is recognized (acceptable).
C: Same as above, a large amount of rubbing marks are recognized (unacceptable).

[Backside dirt]
Each adjusted ink was filled in a recording apparatus shown in the drawing having a face-down paper discharge mechanism, and a 100% duty patch pattern was printed. As a recording medium, 100 sheets of 100% duty patch pattern were continuously printed using XeroxP paper, and stacked on a dedicated paper discharge tray. The back side of the printed surface of the recording medium after continuous stacking was visually observed by face down in a normal temperature and humidity environment, and the determination was made based on the following evaluation criteria.
A: When 100 solid images are stacked continuously, no stain is observed on the back surface.
B: Same as above, slight contamination is recognized (acceptable).
C: Same as above, a large amount of dirt is recognized (unacceptable).
These results are shown in Table 3.

  As is apparent from Table 3, the ink-jet ink of the present invention was excellent in friction resistance and was capable of recording a high gloss image. On the other hand, in each comparative example, satisfactory results were not obtained.

  DESCRIPTION OF SYMBOLS 100 ... Inkjet recording apparatus 101 ... Recording medium 102 ... Housing | casing 104 ... Storage cassette 105 ... Feeding roller 106 ... Discharge tray 109 ... Position detection sensor 110 ... Inkjet head 111 ... Control part 115 ... Motor 116 ... Motor 117 ... Motor 118 ... Motor 130 ... Conveying belt 140 ... Conveying roller 140A ... Driving roller 140B ... Driving roller 150 ... Discharging unit 151 ... Discharging roller 151A ... Driving roller 151B ... Driving roller 152 ... Discharging roller 152A ... Driving roller 152B ... Driving roller 153 ... Motor 154 ... discharge roller 154A ... drive roller 154B ... driven roller 155 ... motor 156 ... transport path 170 ... driven roller 180 ... drive roller 190 ... inkjet head unit 210 ... Pressure suction part 210A ... Suction fan 210B ... Stationary body 211 ... Motor 301 ... Correction guide 301A ... Supporting part 301B ... Inclination part 302 ... Angle adjustment mechanism 303 ... Medium pressing part 305 ... Motor 350 ... Width direction moving part 351 ... Rack 352 ... Pinion 353 ... Motor 400 ... User interface

Claims (7)

A self-dispersing pigment,
A resin dispersion B in which the dispersoid b containing the first resin is dispersed;
A resin dispersion D in which a dispersoid d containing a second resin is dispersed;
Including water,
In the resin dispersion B, the specific gravity of the dispersoid b is less than 1, and the average particle size of the dispersoid b is larger than the average particle size of the self-dispersing pigment,
In the resin dispersion D, the specific gravity of the dispersoid d is greater than 1, the average particle diameter of the dispersoid d is smaller than the average particle diameter of the self-dispersing pigment, and
An inkjet ink, wherein the glass transition point of the second resin is 23 ° C or lower.   The inkjet ink according to claim 1, wherein the first resin is an amorphous polyolefin.   The inkjet ink according to claim 2, wherein the amorphous polyolefin includes at least a maleic acid-modified polyolefin oligomer and a polyethylene glycol alkyl ether.   The inkjet ink according to claim 1, wherein the second resin is an acrylic resin.   The inkjet ink according to any one of claims 1 to 4, comprising a zwitterionic compound.   The inkjet ink according to claim 5, wherein the zwitterionic compound is a betaine compound having a molecular weight of 100 to 250. The recording which records using the inkjet ink of any one of Claim 1 thru | or 6 on the said main surface of the recording medium which has a back surface which is a surface on the opposite side to the main surface and the said main surface. And
A discharge portion for discharging the recording medium with the main surface facing downward;
A correction guide that presses the back surface of the recording medium being discharged from the discharge unit downward and corrects the recording medium; and
A bend amount acquisition unit for acquiring the bend amount of the recording medium discharged from the discharge unit;
An ink jet recording apparatus comprising: a pressing control unit that controls a pressing force of the correction guide according to the bending amount acquired by the bending amount acquisition unit.

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