GB610137A - Process for incorporating pigments or delustrants with highly polymeric linear esters - Google Patents
Process for incorporating pigments or delustrants with highly polymeric linear estersInfo
- Publication number
- GB610137A GB610137A GB9640/46A GB964046A GB610137A GB 610137 A GB610137 A GB 610137A GB 9640/46 A GB9640/46 A GB 9640/46A GB 964046 A GB964046 A GB 964046A GB 610137 A GB610137 A GB 610137A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glycol
- substances
- titanate
- microns
- dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002148 esters Chemical class 0.000 title abstract 2
- 239000000049 pigment Substances 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 6
- 239000000126 substance Substances 0.000 abstract 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 239000006185 dispersion Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000004408 titanium dioxide Substances 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 239000001175 calcium sulphate Substances 0.000 abstract 2
- 235000011132 calcium sulphate Nutrition 0.000 abstract 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000005083 Zinc sulfide Substances 0.000 abstract 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 abstract 1
- 238000000498 ball milling Methods 0.000 abstract 1
- 229910002113 barium titanate Inorganic materials 0.000 abstract 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 abstract 1
- BTVWZWFKMIUSGS-UHFFFAOYSA-N dimethylethyleneglycol Natural products CC(C)(O)CO BTVWZWFKMIUSGS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000013980 iron oxide Nutrition 0.000 abstract 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- -1 lithopone Chemical compound 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000000454 talc Substances 0.000 abstract 1
- 229910052623 talc Inorganic materials 0.000 abstract 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 abstract 1
- 229910003452 thorium oxide Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G85/00—General processes for preparing compounds provided for in this subclass
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
A finely-divided, inert, inorganic or organic substance or mixture of substances is incorporated with highly polymeric linear esters obtainable by heating glycols of the series HO(CH2)nOH, where n is greater than 1 and not greater than 10, with terephthalic acid or an ester-forming derivative of the acid by adding the substance or mixture of substances in the form of a dispersion in a glycol of the series HO(CH2)nOH, where n is an integer greater than 1 but not exceeding 10, preferably the glycol used in the polyester formation, to the mixture of polyester-forming reactants or to a low molecular weight product thereof and continuing the reaction to yield a highly polymerized product. The substances added may be titanium dioxide, zinc sulphide, barium titanate, barium sulphate, calcium sulphate extended with titanium dioxide, zinc titanate, magnesium titanate, calcium titanate, lithopone, zirconium dioxide, calcium sulphate, aluminium oxide, thorium oxide, talc, mica, kaolin, carbon black, phthalocyanine pigments, lead chromates, iron oxides, chromium oxides and ultramarine, and the particle size is not larger than 25 microns and preferably less than 5 microns. The substances are added in the form of a suspension formed by ball milling the inert filler in the glycol. Ten parts titanium dioxide are ball milled for three days with 115 parts of ethylene glycol, thus obtaining a dispersion of particle size 0.3-1.3 microns. The dispersion is mixed with dimethyl terephthalate, ethylene glycol and magnesium oxide in a closed flask heated to 197 DEG C. while circulating nitrogen therethrough and taking of methanol. The temperature is increased to 277 DEG C. under pressure of 0.3 mm. glycol, being distilled off and a melt obtained which can be extruded into fibres.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9640/46A GB610137A (en) | 1946-03-28 | 1946-03-28 | Process for incorporating pigments or delustrants with highly polymeric linear esters |
| FR943361D FR943361A (en) | 1946-03-28 | 1947-03-17 | Incorporation of pigments or delustrants with linear superpolymer esters |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9640/46A GB610137A (en) | 1946-03-28 | 1946-03-28 | Process for incorporating pigments or delustrants with highly polymeric linear esters |
| GB943361X | 1946-03-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB610137A true GB610137A (en) | 1948-10-12 |
Family
ID=29217355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9640/46A Expired GB610137A (en) | 1946-03-28 | 1946-03-28 | Process for incorporating pigments or delustrants with highly polymeric linear esters |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR943361A (en) |
| GB (1) | GB610137A (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2665263A (en) * | 1949-08-31 | 1954-01-05 | Allied Chem & Dye Corp | Preparation of improved polymerizable unsaturated polyester compositions and polymerized material therefrom |
| US3007892A (en) * | 1957-12-27 | 1961-11-07 | Hoechst Ag | Pigmented polyethylene terephthalates and process for preparing them |
| DE1119511B (en) * | 1954-11-04 | 1961-12-14 | Ici Ltd | Process for the production of high molecular weight polymethylene terephthalates containing finely divided inert substances |
| DE1128138B (en) * | 1957-12-27 | 1962-04-19 | Hoechst Ag | Process for the production of spinnable linear polyesters containing finely divided pigments |
| US3050548A (en) * | 1955-06-29 | 1962-08-21 | Ici Ltd | Improvements in the esterification of terephthalic acid with ethylene glycol |
| US3095403A (en) * | 1958-06-13 | 1963-06-25 | Glanzstoff Ag | Process for the production of polyethylene terephthalate |
| DE1155240B (en) * | 1959-03-06 | 1963-10-03 | Hoechst Ag | Process for the production of pigmented, aromatic polyesters |
| US3110693A (en) * | 1959-10-06 | 1963-11-12 | Ici Ltd | Manufacture of terephthalate polyesters using a manganese glycoloxide catalyst |
| US3154461A (en) * | 1960-03-07 | 1964-10-27 | Minnesota Mining & Mfg | Matte-finish polymeric film and method of forming the same |
| DE1264061B (en) * | 1962-11-03 | 1968-03-21 | Basf Ag | Process for making linear polyesters pigmented with titanium dioxide |
| DE1264060B (en) * | 1962-11-03 | 1968-03-21 | Basf Ag | Process for making linear polyesters pigmented with titanium dioxide |
| DE1264062B (en) * | 1962-11-03 | 1968-03-21 | Basf Ag | Process for making linear polyesters pigmented with titanium dioxide |
| US3523105A (en) * | 1968-04-01 | 1970-08-04 | Firestone Tire & Rubber Co | Process of condensing polyalkylene terephthalates using zinc sulphide as a condensation catalyst |
| US3547882A (en) * | 1966-06-16 | 1970-12-15 | Ici Ltd | Light-stable polyesters |
| FR2064432A1 (en) * | 1969-10-20 | 1971-07-23 | Eastman Kodak Co | |
| US3607335A (en) * | 1967-11-08 | 1971-09-21 | Basf Ag | Pigment formulations |
| US3669931A (en) * | 1970-07-07 | 1972-06-13 | Celanese Corp | Polyethylene terephthalate films containing hydrated aluminum silicate for less shrinkage and abrasion |
| JPS5023446A (en) * | 1973-06-30 | 1975-03-13 | ||
| DE2647713A1 (en) * | 1975-10-23 | 1977-04-28 | Ici Ltd | LIGHT SENSITIVE IMAGE MATERIALS |
| EP1047723A1 (en) * | 1998-01-21 | 2000-11-02 | Eastman Chemical Company | Modified polyester with improved processability and adhesion in extrusion coating applications |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE562086A (en) * | 1956-11-02 |
-
1946
- 1946-03-28 GB GB9640/46A patent/GB610137A/en not_active Expired
-
1947
- 1947-03-17 FR FR943361D patent/FR943361A/en not_active Expired
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2665263A (en) * | 1949-08-31 | 1954-01-05 | Allied Chem & Dye Corp | Preparation of improved polymerizable unsaturated polyester compositions and polymerized material therefrom |
| DE1119511B (en) * | 1954-11-04 | 1961-12-14 | Ici Ltd | Process for the production of high molecular weight polymethylene terephthalates containing finely divided inert substances |
| US3050548A (en) * | 1955-06-29 | 1962-08-21 | Ici Ltd | Improvements in the esterification of terephthalic acid with ethylene glycol |
| US3007892A (en) * | 1957-12-27 | 1961-11-07 | Hoechst Ag | Pigmented polyethylene terephthalates and process for preparing them |
| US3007891A (en) * | 1957-12-27 | 1961-11-07 | Hoechst Ag | Pigmented polyethylene terephthalates and process for preparing them |
| DE1128138B (en) * | 1957-12-27 | 1962-04-19 | Hoechst Ag | Process for the production of spinnable linear polyesters containing finely divided pigments |
| US3095403A (en) * | 1958-06-13 | 1963-06-25 | Glanzstoff Ag | Process for the production of polyethylene terephthalate |
| DE1155240B (en) * | 1959-03-06 | 1963-10-03 | Hoechst Ag | Process for the production of pigmented, aromatic polyesters |
| US3110693A (en) * | 1959-10-06 | 1963-11-12 | Ici Ltd | Manufacture of terephthalate polyesters using a manganese glycoloxide catalyst |
| US3154461A (en) * | 1960-03-07 | 1964-10-27 | Minnesota Mining & Mfg | Matte-finish polymeric film and method of forming the same |
| DE1264061B (en) * | 1962-11-03 | 1968-03-21 | Basf Ag | Process for making linear polyesters pigmented with titanium dioxide |
| DE1264060B (en) * | 1962-11-03 | 1968-03-21 | Basf Ag | Process for making linear polyesters pigmented with titanium dioxide |
| DE1264062B (en) * | 1962-11-03 | 1968-03-21 | Basf Ag | Process for making linear polyesters pigmented with titanium dioxide |
| US3547882A (en) * | 1966-06-16 | 1970-12-15 | Ici Ltd | Light-stable polyesters |
| US3607335A (en) * | 1967-11-08 | 1971-09-21 | Basf Ag | Pigment formulations |
| US3523105A (en) * | 1968-04-01 | 1970-08-04 | Firestone Tire & Rubber Co | Process of condensing polyalkylene terephthalates using zinc sulphide as a condensation catalyst |
| FR2064432A1 (en) * | 1969-10-20 | 1971-07-23 | Eastman Kodak Co | |
| US3669931A (en) * | 1970-07-07 | 1972-06-13 | Celanese Corp | Polyethylene terephthalate films containing hydrated aluminum silicate for less shrinkage and abrasion |
| JPS5430011B1 (en) * | 1970-07-07 | 1979-09-27 | ||
| JPS5023446A (en) * | 1973-06-30 | 1975-03-13 | ||
| DE2647713A1 (en) * | 1975-10-23 | 1977-04-28 | Ici Ltd | LIGHT SENSITIVE IMAGE MATERIALS |
| EP1047723A1 (en) * | 1998-01-21 | 2000-11-02 | Eastman Chemical Company | Modified polyester with improved processability and adhesion in extrusion coating applications |
Also Published As
| Publication number | Publication date |
|---|---|
| FR943361A (en) | 1949-03-07 |
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