GB1352347A - Stabilized film-forming polyolefin composition - Google Patents
Stabilized film-forming polyolefin compositionInfo
- Publication number
- GB1352347A GB1352347A GB2072371A GB2072371A GB1352347A GB 1352347 A GB1352347 A GB 1352347A GB 2072371 A GB2072371 A GB 2072371A GB 2072371 A GB2072371 A GB 2072371A GB 1352347 A GB1352347 A GB 1352347A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- preferred proportion
- volatilize
- decompose
- polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 229920000098 polyolefin Polymers 0.000 title abstract 4
- -1 polypropylene Polymers 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- FUVVCZPEOKAHJS-UHFFFAOYSA-N 1-dodecoxy-3-(2-hydroxyethylamino)propan-2-ol Chemical compound CCCCCCCCCCCCOCC(O)CNCCO FUVVCZPEOKAHJS-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 229910010413 TiO 2 Inorganic materials 0.000 abstract 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 abstract 1
- 230000004308 accommodation Effects 0.000 abstract 1
- 150000003973 alkyl amines Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- 239000013522 chelant Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 229920001903 high density polyethylene Polymers 0.000 abstract 1
- 239000004700 high-density polyethylene Substances 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000003017 thermal stabilizer Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
1352347 Polyolefin compositions and paperlike films thereof UNION CARBIDE CORP 19 April 1971 [30 Jan 1970] 20723/71 Heading C3P Polyolefin compositions comprise components A, B, C and D below optionally with one or more of components E, F and G. (A) A polyolefin, e.g. high density polyethylene and/or polypropylene; preferred proportion: 45-85 wt. per cent of the composition; (B) A U.V. stabilizer comprising at least one organic compound capable of forming a sixmembered chelate ring through hydrogen bonding, and which is a solid or liquid which does not decompose or volatilize below 200‹ C., e.g. of formula wherein the various A's and B's, which may be the same or different are H or substituents (e.g. OH, Cl, But, n-octoxy); a is 1-9; and b is 1-8; preferred proportion: 0À2-2À0 wt. per cent; (C) An antistatic agent comprising at least one alkoxylated amine or amide which contains at least one saturated or unsaturated C 7 -C 22 hydrocarbon group optionally bearing one or more substituents (e.g. OH), and which does not volatilize or decompose below 200‹ C., e.g. N,N - bis - (2 - hydroxyethyl)- or N,N- bis - 3 - hydroxypropyl) - C 8 -C 22 alkylamines or -C 8 -C 22 fatty acid amides; and N-(3- dodecyloxy - 2 - hydroxypropyl) - ethanolamine; preferred proportion: 0À1-2À0 wt. per cent; (D) A thermal stabilizer comprising at least one sterically hindered phenol which does not volatilize or decompose below 200‹ C., e.g. octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate or tetrakis-[3-(3,5-di-tert-butyl-4- hydroxyphenyl) propionyloxymethyl] methane; preferred proportion: 0À02-1À0 wt. per cent; (E) A filler preferably having an average particle diameter of 0À1-15 microns, e.g. CaO, ZnO, MgCO 3 , CaSO 4 , MgSO 4 , PbSO 4 , TiO 2 , MgO, CaCO 3 , various silicas, silicates, silica-alumina or asbestos; preferred proportion: 5-45 wt. per cent; (F) A polymeric accommodation resin, e.g. a low density vinyl addition polymer or copolymer e.g. polyethylene or ethylene/vinyl acetate copolymer (many others are listed); preferred proportion 3-15 wt. per cent; (G) Unspecified flame retardants and colorants. The compositions may be formed into sheets or into paper-like films of 0À25-20 mils thickness which may be surface-treated by electrostatic discharge, flame treatment or oxidative chemical treatment.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US721370A | 1970-01-30 | 1970-01-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1352347A true GB1352347A (en) | 1974-05-08 |
Family
ID=21724866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2072371A Expired GB1352347A (en) | 1970-01-30 | 1971-04-19 | Stabilized film-forming polyolefin composition |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR2077182A5 (en) |
| GB (1) | GB1352347A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2156837A (en) * | 1984-03-29 | 1985-10-16 | British Telecomm | Optical fibre transmission lines |
| WO2004009690A3 (en) * | 2002-07-18 | 2004-08-12 | Exxonmobil Chem Patents Inc | Ultraviolet radiation stabilized polyolefins |
| WO2004024810A3 (en) * | 2002-09-11 | 2004-08-12 | Ciba Sc Holding Ag | Stabillization of organic materials |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4049751A (en) * | 1976-04-26 | 1977-09-20 | Dart Industries Inc. | Extraction resistant polyolefin stabilizers |
-
1971
- 1971-01-29 FR FR7103163A patent/FR2077182A5/fr not_active Expired
- 1971-04-19 GB GB2072371A patent/GB1352347A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2156837A (en) * | 1984-03-29 | 1985-10-16 | British Telecomm | Optical fibre transmission lines |
| WO2004009690A3 (en) * | 2002-07-18 | 2004-08-12 | Exxonmobil Chem Patents Inc | Ultraviolet radiation stabilized polyolefins |
| US7259198B2 (en) | 2002-07-18 | 2007-08-21 | Exxonmobil Chemical Patents Inc. | Ultraviolet radiation stabilized polyolefins |
| WO2004024810A3 (en) * | 2002-09-11 | 2004-08-12 | Ciba Sc Holding Ag | Stabillization of organic materials |
| US7375149B2 (en) | 2002-09-11 | 2008-05-20 | Ciba Specialty Chemicals Corp. | Stabilization of organic materials |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2103935B2 (en) | 1977-06-08 |
| DE2103935A1 (en) | 1971-08-05 |
| FR2077182A5 (en) | 1971-10-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
| PCNP | Patent ceased through non-payment of renewal fee |