GB1176696A - Process for the Preparation of Copolymers of Ethylene and Acrylic Acid. - Google Patents
Process for the Preparation of Copolymers of Ethylene and Acrylic Acid.Info
- Publication number
- GB1176696A GB1176696A GB4708067A GB4708067A GB1176696A GB 1176696 A GB1176696 A GB 1176696A GB 4708067 A GB4708067 A GB 4708067A GB 4708067 A GB4708067 A GB 4708067A GB 1176696 A GB1176696 A GB 1176696A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrylic acid
- ethylene
- peroxide
- copolymers
- atmospheres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005977 Ethylene Substances 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- -1 di-t.-butyl peroxide Chemical compound 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 abstract 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 abstract 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000012986 chain transfer agent Substances 0.000 abstract 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 abstract 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,176,696. Ethylene-acrylic acid copolymers. STAMICARBON N.V. 16 Oct., 1967 [18 Oct., 1966], No. 47080/67. Heading C3P. Ethylene/acrylic acid copolymers having a melt index greater than 5, a modulus of elasticity at least 1500, preferably more than 2000 kg./ cm.<SP>2</SP> and an elongation at tensile break of above 350%, may be prepared by a process wherein ethylene, acrylic acid and a free-radical initiator are continuously fed at pressures above 800 atmospheres into an autoclave in which they are mixed with reaction mixture already present, and heated to the polymerization temperature, polymerization being effected at pressure p between 1500 and 10,000 atmospheres and at temperature T between 150‹ and 290‹ C. so that the mole per cent of acrylic acid incorporated in the copolymer is 0À1 to 10 and wherein p, T and M satisfy the relation 0À05 p-T-11M+ 166#O. The initiator may be oxygen, lauroyl peroxide, di-t.-butyl peroxide, capryloyl peroxide, t.-butyl perbenzoate or an azo compound. The acrylic acid may be diluted with iso-octane and propane may be used as chain transfer agent.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6614676A NL6614676A (en) | 1966-10-18 | 1966-10-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1176696A true GB1176696A (en) | 1970-01-07 |
Family
ID=19797957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4708067A Expired GB1176696A (en) | 1966-10-18 | 1967-10-16 | Process for the Preparation of Copolymers of Ethylene and Acrylic Acid. |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE705246A (en) |
| DE (1) | DE1745486A1 (en) |
| ES (1) | ES346172A1 (en) |
| FR (1) | FR1549413A (en) |
| GB (1) | GB1176696A (en) |
| NL (1) | NL6614676A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4195121A (en) * | 1978-03-28 | 1980-03-25 | Union Carbide Corporation | Thin flexible electrodes and the method for producing them |
| WO2014105110A2 (en) | 2012-12-28 | 2014-07-03 | Dow Global Technologies Llc | Method to reduce the crystallization temperature of carboxylic acid comonomer at elevated pressures, and to improve the copolymerization of the same |
-
1966
- 1966-10-18 NL NL6614676A patent/NL6614676A/xx unknown
-
1967
- 1967-10-16 FR FR1549413D patent/FR1549413A/fr not_active Expired
- 1967-10-16 GB GB4708067A patent/GB1176696A/en not_active Expired
- 1967-10-17 BE BE705246D patent/BE705246A/xx unknown
- 1967-10-18 ES ES346172A patent/ES346172A1/en not_active Expired
- 1967-10-18 DE DE19671745486 patent/DE1745486A1/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4195121A (en) * | 1978-03-28 | 1980-03-25 | Union Carbide Corporation | Thin flexible electrodes and the method for producing them |
| WO2014105110A2 (en) | 2012-12-28 | 2014-07-03 | Dow Global Technologies Llc | Method to reduce the crystallization temperature of carboxylic acid comonomer at elevated pressures, and to improve the copolymerization of the same |
| US9416209B2 (en) | 2012-12-28 | 2016-08-16 | Dow Global Technologies Llc | Method to improve the feeding of a carboxylic acid comonomer into a high pressure reactor |
Also Published As
| Publication number | Publication date |
|---|---|
| ES346172A1 (en) | 1968-12-01 |
| DE1745486A1 (en) | 1971-09-16 |
| BE705246A (en) | 1968-04-17 |
| NL6614676A (en) | 1968-04-19 |
| FR1549413A (en) | 1968-12-13 |
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