EP1765697A1 - Dosierventil und vorrichtung zur abgabe einer vorzugsweise kosmetischen flüssigkeit - Google Patents
Dosierventil und vorrichtung zur abgabe einer vorzugsweise kosmetischen flüssigkeitInfo
- Publication number
- EP1765697A1 EP1765697A1 EP05754391A EP05754391A EP1765697A1 EP 1765697 A1 EP1765697 A1 EP 1765697A1 EP 05754391 A EP05754391 A EP 05754391A EP 05754391 A EP05754391 A EP 05754391A EP 1765697 A1 EP1765697 A1 EP 1765697A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- valve
- sealing element
- metering
- housing
- sealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
- B65D83/44—Valves specially adapted for the discharge of contents; Regulating devices
- B65D83/52—Metering valves; Metering devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49405—Valve or choke making
Definitions
- the present invention relates to a metering valve for dispensing a preferably cosmetic liquid according to the preamble of claim 1, a device with such a metering valve, a method for producing such a metering valve and the use of such a metering valve or such a device.
- cosmetic liquid is to be understood in a narrower sense as hair spray, hair lacquer, a deodorant, a foam, a gel, a color spray, a sun or skin care product or the like.
- other personal care products, cleaning products, cosmetics or the like, and also suspensions and fluids, in particular with gas phases are preferably also included.
- other liquids for example air fresheners, and in particular also technical liquids and fluids, such as rust removers or the like, can be used. In the following, however, for reasons of simplification and due to the lack of use, we often only speak of cosmetic liquid.
- a container containing the liquid having a metering valve with a movable valve element in a valve housing. Together with the valve housing, the valve element forms an inlet-side inlet valve and an outlet-side outlet valve.
- the valve element is preferably provided with an attached spray head or the like for dispensing and atomizing the liquid. By depressing the spray head, the valve element is moved axially, which initially closes the inlet valve of the metering valve and only then opens the outlet valve of the metering valve.
- the liquid which preferably contains a propellant, can then escape from the metering space formed in the valve housing and be atomized and dispensed by the connected spray head.
- a cosmetic liquid under pressure is in addition to the so-called "Undercup” process, in which the filling by lifting or before placing a lid with the metering valve on the container, that is, before the final closing of the container bypassing the Dosing valve takes place, so-called “pressure filling” is increasingly used, in which filling takes place through the dosing valve or past the dosing valve between the cover and a sealing element of the dosing valve on the delivery side. Filling pressures are increasingly being used to reduce the filling time.
- the known metering valves are not ideal for pressure filling and or for sealing and / or do not allow an optimal securing of the seal with a simple structure.
- the present invention is based on the object of specifying a metering valve and a device for the metered delivery of a preferably cosmetic liquid, as well as a method for producing such a metering valve and the use of such a metering valve or such a device, the metering valve being easy to manufacture, sealing better and / or more universally applicable.
- a basic idea of the present invention is to design the sealing element to be essentially ring-shaped or sleeve-shaped, at least in sections.
- the sealing element seals at least essentially radially.
- the sealing element is supported - at least in the sealing area - either radially inside or outside. This enables a seal that is better than that of the prior art, in particular since the sealing element, which is preferably made of a soft material, cannot radially deflect.
- the valve seat or the sealing element can also be conical in order to achieve an optimal radial sealing seat in the closed state.
- the sealing element on the valve element or valve housing is secured or fixed by means of a return spring assigned to the valve element.
- a return spring assigned to the valve element.
- the sealing element for sealing between the valve element and the valve housing when the inlet valve is closed preferably consists of a softer or more elastic material than the valve element and the valve housing. This enables the metering valve, in particular the valve housing, to be designed in a stable manner, which accordingly can better withstand higher propellant and filling pressures. Therefore, the proposed metering valve and a device provided with such a metering valve can be used universally.
- the sealing element is injection molded directly onto the valve element. This can be done, for example, directly in the injection mold for the valve element. If necessary, the sealing element can also be inserted into the injection mold as a prefabricated part and the valve element can be injection molded onto the sealing element. In both cases, a particularly simple and inexpensive manufacture is made possible, the assembly being able to be carried out in the usual way without an additional assembly step for the sealing element.
- the sealing element is attached to the valve element in particular by being plugged on.
- the sealing element is preferably arranged in the region of a free end on the valve element. This is particularly conducive to a corresponding end-side arrangement of the inlet valve and a possible placement of the sealing element on the valve element.
- the sealing element can, for example, also be arranged, in particular molded, in a region of the valve element that is spaced from the end of the valve element.
- the sealing element is injection molded onto the valve housing or the valve housing onto the sealing element. This also enables simple and therefore inexpensive production, and the metering valve can be assembled as before.
- the sealing element can also be inserted into the valve housing. This enables greater degrees of freedom in the manufacture, in particular of the sealing element.
- the sealing element, the valve element and the valve housing are preferably injection molded from plastic in order to enable inexpensive mass production.
- the injection molding is preferably carried out with such precision and such a choice of materials that no post-processing is required to achieve the desired sealing effect.
- the sealing element is designed to be self-locking. This can be achieved, for example, by the sealing element engaging in a preferably undercut recess in the valve element or the valve housing. However, this is particularly preferably achieved by injecting the sealing element directly onto the valve element or the valve housing or injecting it therein, or vice versa, in order to form a non-releasable bond.
- the valve element very particularly preferably forms both the inlet valve and the outlet valve of the metering valve.
- the valve element is preferably at least essentially rigid, in particular in the actuation or axial direction.
- the metering valve is particularly preferably used for the metered delivery of a cosmetic liquid which contains particles, distributed projections in a metering space of the metering valve being used for the temporary deposition of the particles in order to counteract a bottom-side settling of the particles and in particular clogging of the inlet valve, the particles deposited on the protrusions are also carried away by the liquid when dispensing. This enables a better distribution of the particles in the discharged liquid. This is beneficial for particle-containing formulations or suspensions, which are increasingly being used, in order to be able to ensure uniform distributions and thus uniform properties.
- Figure 1 is a schematic sectional view of a proposed device with a proposed metering valve for the metered delivery of a cosmetic liquid according to a first embodiment.
- FIG. 2 shows a schematic sectional illustration of a proposed device with a proposed metering valve for the metered delivery of a cosmetic liquid according to a second embodiment
- Fig. 3 is a schematic sectional view of a proposed device with a proposed metering valve for the metered delivery of a cosmetic liquid according to a third embodiment.
- FIG. 1 shows a schematic sectional view of a proposed device 1 with a metering valve 2 for metered dispensing of a preferably cosmetic liquid 3 or the like.
- the liquid 3 is dispensed via a not shown, connected to the metering valve 2, preferably plugged onto it.
- Spray head for atomizing and dispensing the liquid 3.
- the liquid 3 is under pressure or can be put under pressure.
- the liquid 3 contains a blowing agent, preferably a volatile and / or combustible blowing agent, compressed gas, carbon dioxide or the like.
- the cosmetic liquid 3 is particularly preferably a particle-containing mixture or suspension in the aforementioned sense.
- the device 1 also has a container 4 for the liquid 3 and a cover 5 carrying the metering valve 2.
- the metering valve 2 has a movable valve element 6 and a valve housing 7.
- the valve element 6 is axially movably guided in the valve housing 7 in the illustration example - vertically in the illustration according to FIG. 1 and forms a projecting connecting piece 8 on the delivery side for connecting the spray head (not shown) or the like.
- the metering valve 4 has an inlet-side inlet valve 9, an outlet-side outlet valve 10 and a metering chamber 11 formed between them in the valve housing 7.
- a return spring 12 assigned to the valve element 6 is arranged, which biases the valve element 6 into the unactuated position shown, that is to say upwards here.
- the outlet valve 10 In the unactuated position, the outlet valve 10 is closed and the inlet valve 9 is open. In this state, the dosing chamber 11 is filled with the liquid 3 (this is not shown in the figures for reasons of simplification) provides), the liquid 3 can flow from the container 4 via an inlet riser 13 through the open inlet valve 9 into the metering chamber 11 or after.
- the inlet valve 9 is first closed and only then is the outlet valve 10 opened.
- the liquid 3 located in the metering chamber 11 can then be dispensed via the opened outlet valve 10, in particular it can flow out independently due to the propellant mentioned and can be sprayed or atomized, for example, by the spray head (not shown) connected to the connector 8. Accordingly, the metering valve 2 dispenses only a certain or metered amount of liquid 3 with each actuation.
- valve element 6 and the valve housing 7 are preferably each formed in one piece and injection molded from plastic, in particular from a relatively hard or rigid plastic, such as polyamide or polyoxymethylene (POM).
- plastic in particular from a relatively hard or rigid plastic, such as polyamide or polyoxymethylene (POM).
- POM polyoxymethylene
- a sealing element 14 made of a softer or more elastic material than the valve element 6 and the valve housing 7 is additionally provided between the valve element 6 and the valve housing 7.
- the sealing element 14 is injection molded onto the valve element 7, preferably directly in the injection mold used to manufacture the valve element 6 or in a separate injection molding mold.
- the sealing element 14 can, for example, also be inserted into the injection mold as a prefabricated part and the valve element 6 can be molded on, or the sealing element 14 can be plugged onto the prefabricated valve element 6.
- the sealing element 14 preferably surrounds the valve element 6 in an annular manner and, in the example shown, has a frusto-conical or rounded insertion area 15 in order to facilitate insertion into a corresponding sealing section of the valve housing 7 for preferably radial sealing against the sealing element 14 when the inlet valve 9 is closed.
- the sealing element 14 has a lateral projection, in particular an annular flange 16 or the like, for attachment to the valve element 6, the projection or annular flange 16 between an abutment for the return spring 12 on the valve element 6 and the associated one End of the return spring 12 is arranged and thereby fixed.
- This enables the sealing element 14 to be fixed very securely on the valve element 6, in particular even when the sealing element 14 is injection molded onto the valve element 6, since in the case of different materials, the sealing element 14 can not always be detached from the valve element 6.
- sealing element 14 can alternatively be arranged and fixed in a corresponding manner on the valve housing 7.
- the sealing element 14 is preferably also injection molded, in particular from a suitable elastomer, preferably from a thermoplastic elastomer (TPE), a thermoplastic polyurethane (TPU) or low-density polyethylene (LDPE) produced under high pressure.
- a suitable elastomer preferably from a thermoplastic elastomer (TPE), a thermoplastic polyurethane (TPU) or low-density polyethylene (LDPE) produced under high pressure.
- the injection molding enables inexpensive mass production, in particular in which a reworking of the sealing surfaces - on the one hand on the sealing element 14 and on the other hand on the valve element 6 or valve housing 7 - is not necessary.
- Valve housing 7 has the advantage that the sealing element 14 does not form a separate part and therefore does not require a separate assembly step, and moreover has the further advantage that a very good seal between the Sealing element 14 and the associated valve element 6 or valve housing 7 can be reached without additional measures.
- the sealing element 14 is arranged at a free end of the valve element 6 in such a way that an axial inlet channel 17 in the valve housing 7 to the metering chamber 11 is not blocked in the unactuated state.
- the valve element 14 In the actuated state - that is to say when the valve element 6 is depressed - the valve element 14 is at least partially inserted with a front end of the valve element 6 into the feed channel 17 for radial sealing at a sealing section of the valve housing 7.
- other valve constructions are also possible, for example a plate-like design and / or an axial seal.
- the outlet valve 10 has a separate sealing element 18, which is in particular ring-shaped and is held in a sealing manner by the valve housing 7 against a ring section of the cover 5.
- the separate sealing element 18 seals radially to a shaft section of the valve element 6 or connector 8.
- the outlet valve 10 is closed and, accordingly, no liquid 3 can escape from the metering chamber 11 on the dispensing side.
- valve element 6 When the valve element 6 is actuated, the valve element 6 or the connecting piece 8 is axially displaced such that a radial passage channel 19 moves past the separate sealing element 18 into the interior of the valve housing 7, that is to say is released towards the metering chamber 11 (this position is not shown) ).
- the outlet valve 10 is opened, and liquid 3 can flow out of the metering chamber 11 through the passage channel 19 into an axial recess 20 and through this out of the connector 8 into the spray head or the like, not shown.
- the sealing element 14 is attached to the valve housing 7, in particular molded on.
- the ring or sleeve-like sealing element 14 engages in at least one preferably undercut recess 23 of the valve housing 7 - or in the case of an arrangement on the valve element 6 - of the valve element 6.
- two substantially annular recesses 23 and a shoulder-like widening for receiving and holding the sealing element 14 are formed.
- the preferably separately formed, ring-like or sleeve-like sealing element 14 is inserted or injected into the valve housing 7 and preferably engages again in a recess 23.
- a radial seal is formed between the sealing element 14 and the end section of the valve element 6 which is introduced when the inlet valve 9 is closed.
- the sealing element 14 thus seals at least essentially radially.
- valves can be combined with one another or interchanged with one another.
- other valve designs are also possible.
- the molded or possibly also injected sealing element 14 can also be used for other valves - that is to say independently of the metering valve 2 present - for such or similar devices 1 for dispensing and in particular atomizing cosmetic liquids 3.
- the proposed device 1 and the proposed metering valve 2 can be used for any type of cosmetic liquids 3, as already explained above.
- the use of such or a similar metering valve 2 is particularly suitable for the metered delivery of a cosmetic liquid 3 which contains particles, projections distributed in the metering chamber 11 of the metering valve 2 being used for the temporary deposition of the particles in order to prevent the particles from settling on the bottom and in particular counteract special clogging of the inlet valve 9 of the metering valve 2, and the particles are discharged from the liquid 3 again when dispensing.
- the projections are preferably distributed in the vertical direction or spaced apart and particularly preferably by the windings of the return spring 12 and / or other recesses, indentations, edges or the like from the valve element 6 and or Valve housing 7 formed in the metering chamber 11.
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004029146 | 2004-06-17 | ||
DE102004034626A DE102004034626A1 (de) | 2004-06-17 | 2004-07-16 | Dosierventil und Vorrichtung zur Abgabe einer vorzugsweise kosmetischen Flüssigkeit |
PCT/EP2005/006532 WO2005123543A1 (de) | 2004-06-17 | 2005-06-17 | Dosierventil und vorrichtung zur abgabe einer vorzugsweise kosmetischen flüssigkeit |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1765697A1 true EP1765697A1 (de) | 2007-03-28 |
EP1765697B1 EP1765697B1 (de) | 2008-10-22 |
Family
ID=34970891
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05754391A Expired - Lifetime EP1765697B1 (de) | 2004-06-17 | 2005-06-17 | Dosierventil und vorrichtung zur abgabe einer vorzugsweise kosmetischen flüssigkeit |
EP05787283A Expired - Lifetime EP1765698B1 (de) | 2004-06-17 | 2005-06-17 | Dosierventil und vorrichtung zur abgabe einer vorzugsweise kosmetischen flüssigkeit |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05787283A Expired - Lifetime EP1765698B1 (de) | 2004-06-17 | 2005-06-17 | Dosierventil und vorrichtung zur abgabe einer vorzugsweise kosmetischen flüssigkeit |
Country Status (6)
Country | Link |
---|---|
US (2) | US7762436B2 (de) |
EP (2) | EP1765697B1 (de) |
AT (2) | ATE411954T1 (de) |
DE (3) | DE102004034626A1 (de) |
ES (2) | ES2329920T3 (de) |
WO (2) | WO2005123542A1 (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004034626A1 (de) * | 2004-06-17 | 2006-01-12 | Seaquist Perfect Dispensing Gmbh | Dosierventil und Vorrichtung zur Abgabe einer vorzugsweise kosmetischen Flüssigkeit |
DE102006012302A1 (de) | 2006-03-15 | 2007-09-27 | Seaquist Perfect Dispensing Gmbh | Abgabevorrichtung |
DE102007049614B4 (de) | 2007-03-15 | 2015-03-05 | Aptar Dortmund Gmbh | Abgabevorrichtung |
DE102009022215B4 (de) * | 2009-05-20 | 2011-06-22 | LINDAL Dispenser GmbH, 23923 | Ventil zur dosierten Abgabe von Flüssigkeiten |
CN102235527B (zh) * | 2010-04-30 | 2014-06-04 | 麦格纳姆制造有限公司 | 一种定量阀门 |
CN105980066B (zh) * | 2014-01-20 | 2018-10-12 | 固瑞克明尼苏达有限公司 | 具有集成阀座的喷涂机 |
DE102016204953A1 (de) * | 2016-03-24 | 2017-09-28 | F. Holzer Gmbh | Dosierpumpe für eine Dosiervorrichtung sowie Dosiervorrichtung |
WO2018162027A1 (en) * | 2017-03-06 | 2018-09-13 | Arcelik Anonim Sirketi | Improved valve assembly for use in a water dispenser of a refrigerator |
US11253111B2 (en) | 2019-08-22 | 2022-02-22 | Gpcp Ip Holdings Llc | Skin care product dispensers and associated self-foaming compositions |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA598388A (en) | 1954-09-20 | 1960-05-24 | Meshberg Philip | Aerosol containers and valves therefor |
US2837249A (en) * | 1957-05-10 | 1958-06-03 | Meshberg Philip | Aerosol valve |
US3018928A (en) | 1958-11-24 | 1962-01-30 | Meshberg Philip | Metering valve |
US3055560A (en) * | 1959-05-18 | 1962-09-25 | Meshberg Philip | Metering valve assembly |
US3073489A (en) * | 1960-06-06 | 1963-01-15 | Jack N Friedman | Aerosol metering valve assembly |
US3272442A (en) * | 1964-01-16 | 1966-09-13 | Union Carbide Corp | Aerosol valve |
US3447551A (en) * | 1967-06-14 | 1969-06-03 | Arthur R Braun | Upside-downside aerosol dispensing valve |
US3583608A (en) * | 1969-05-15 | 1971-06-08 | Scovill Manufacturing Co | Aerosol valve with metering passage |
US3589571A (en) * | 1969-07-18 | 1971-06-29 | Scovill Manufacturing Co | Aerosol valves |
US3666148A (en) * | 1969-10-13 | 1972-05-30 | Gillette Co | Aerosol valve with safety relief device |
US3722759A (en) * | 1971-11-17 | 1973-03-27 | J Rodden | Explosion proof aerosol can |
US4362257A (en) * | 1980-05-05 | 1982-12-07 | Ethyl Products Company | Pressure fillable dispensing device |
FR2502732B1 (fr) * | 1981-03-30 | 1985-08-30 | Valois Sa | Valve doseuse a position inversee pour recipient d'aerosol |
GB2124587B (en) * | 1982-08-06 | 1986-01-08 | Kenneth Wilmot | Aerosol valves |
JPS6346387U (de) * | 1986-09-12 | 1988-03-29 | ||
GB8628472D0 (en) * | 1986-11-28 | 1987-01-07 | Glaxo Group Ltd | Valve assembly |
US5027985A (en) * | 1986-12-03 | 1991-07-02 | Abplanalp Robert H | Aerosol valve |
GB8825632D0 (en) * | 1988-11-02 | 1988-12-07 | Bespak Plc | Dispensing apparatus for pressurised dispensing containers |
FR2670139B1 (fr) * | 1992-01-15 | 1993-12-24 | Valois | Valve doseuse utilisable en position inversee. |
JP2992609B2 (ja) | 1994-03-14 | 1999-12-20 | 誠一 北林 | 圧力充填可能な多量定量バルブ |
DE69425065T2 (de) * | 1994-08-29 | 2001-03-08 | Osaka Shipbuilding Co., Ltd. | Aerosolbehälter mit einer konstanten abgabe |
GB2324121A (en) * | 1997-04-07 | 1998-10-14 | Bespak Plc | Seal arrangements for pressurised dispensing containers |
US5906046A (en) * | 1997-07-31 | 1999-05-25 | Precision Valve Corporation | Aerosol tilt valve and method of forming same |
GB2360272B (en) * | 2000-03-07 | 2002-02-13 | Bespak Plc | Improvements in or relating to valves for dispensers |
FR2829475B1 (fr) * | 2001-09-10 | 2003-12-26 | Oreal | Valve a debit variable et recipient equipe d'une telle valve |
US6832704B2 (en) * | 2002-06-17 | 2004-12-21 | Summit Packaging Systems, Inc. | Metering valve for aerosol container |
GB0315791D0 (en) * | 2003-07-07 | 2003-08-13 | 3M Innovative Properties Co | Two component molded valve stems |
JP4598527B2 (ja) * | 2002-09-06 | 2010-12-15 | スリーエム イノベイティブ プロパティズ カンパニー | 一貫した供給を提供する定量吸入器のための計量弁 |
AU2003263077B2 (en) * | 2002-09-06 | 2010-04-29 | 3M Innovative Properties Company | Metering valve for a metered dose inhaler providing consistent delivery |
DE102004034626A1 (de) * | 2004-06-17 | 2006-01-12 | Seaquist Perfect Dispensing Gmbh | Dosierventil und Vorrichtung zur Abgabe einer vorzugsweise kosmetischen Flüssigkeit |
-
2004
- 2004-07-16 DE DE102004034626A patent/DE102004034626A1/de not_active Withdrawn
-
2005
- 2005-06-17 EP EP05754391A patent/EP1765697B1/de not_active Expired - Lifetime
- 2005-06-17 DE DE502005007898T patent/DE502005007898D1/de not_active Expired - Lifetime
- 2005-06-17 US US11/570,867 patent/US7762436B2/en active Active
- 2005-06-17 AT AT05754391T patent/ATE411954T1/de not_active IP Right Cessation
- 2005-06-17 DE DE502005005758T patent/DE502005005758D1/de not_active Expired - Lifetime
- 2005-06-17 WO PCT/EP2005/006531 patent/WO2005123542A1/de active Application Filing
- 2005-06-17 ES ES05787283T patent/ES2329920T3/es not_active Expired - Lifetime
- 2005-06-17 ES ES05754391T patent/ES2314670T3/es not_active Expired - Lifetime
- 2005-06-17 AT AT05787283T patent/ATE439314T1/de not_active IP Right Cessation
- 2005-06-17 EP EP05787283A patent/EP1765698B1/de not_active Expired - Lifetime
- 2005-06-17 WO PCT/EP2005/006532 patent/WO2005123543A1/de active Application Filing
- 2005-06-17 US US11/570,866 patent/US7651014B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO2005123543A1 * |
Also Published As
Publication number | Publication date |
---|---|
ATE439314T1 (de) | 2009-08-15 |
DE502005005758D1 (de) | 2008-12-04 |
US20080272155A1 (en) | 2008-11-06 |
ES2314670T3 (es) | 2009-03-16 |
US20070228081A1 (en) | 2007-10-04 |
DE102004034626A1 (de) | 2006-01-12 |
ATE411954T1 (de) | 2008-11-15 |
DE502005007898D1 (de) | 2009-09-24 |
EP1765697B1 (de) | 2008-10-22 |
US7651014B2 (en) | 2010-01-26 |
WO2005123542A1 (de) | 2005-12-29 |
US7762436B2 (en) | 2010-07-27 |
EP1765698A1 (de) | 2007-03-28 |
WO2005123543A1 (de) | 2005-12-29 |
ES2329920T3 (es) | 2009-12-02 |
EP1765698B1 (de) | 2009-08-12 |
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