EP1274871A1 - Use of a hardenable copper alloy for molds - Google Patents
Use of a hardenable copper alloy for moldsInfo
- Publication number
- EP1274871A1 EP1274871A1 EP01929554A EP01929554A EP1274871A1 EP 1274871 A1 EP1274871 A1 EP 1274871A1 EP 01929554 A EP01929554 A EP 01929554A EP 01929554 A EP01929554 A EP 01929554A EP 1274871 A1 EP1274871 A1 EP 1274871A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- copper alloy
- molds
- side plates
- nickel
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 21
- 238000005266 casting Methods 0.000 claims abstract description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 7
- 229910052790 beryllium Inorganic materials 0.000 claims abstract description 6
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 2
- 238000009749 continuous casting Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910000967 As alloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QZLJNVMRJXHARQ-UHFFFAOYSA-N [Zr].[Cr].[Cu] Chemical compound [Zr].[Cr].[Cu] QZLJNVMRJXHARQ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- YCKOAAUKSGOOJH-UHFFFAOYSA-N copper silver Chemical compound [Cu].[Ag].[Ag] YCKOAAUKSGOOJH-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/06—Alloys based on copper with nickel or cobalt as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/059—Mould materials or platings
Definitions
- the invention relates to the use of a hardenable copper alloy for molds, in particular for the production of broad side plates for thin slab casting molds
- mold wide side plates for thin slab systems and in particular for CSP (compact strip product) systems are produced from copper alloys such as CuCrZr (copper chromium zirconium) or CuAg (copper silver). Because of this, a CuAg alloy for CSP mold plates has been produced comparatively high elongation with increasing temperatures has proven to be advantageous
- mold wide side plates made of CuAg or CuCrZr are not able to absorb the high temperature tensions in the bath level of the cast metal and tend to form cracks in the area in this area, whereby CuCrZr in particular tends to form cracks particularly early. This crack formation is then the failure point for the mold wide side plates and causes high repair and replacement costs for the operator of a continuous caster
- the failure rate of the narrow side plates is not the formation of cracks, but rather the wear or abrasion of the contact surfaces to the steel.
- the most common failure criterion of the wide side plates is crack formation in the area of the mold level
- Document DE 31 20 978 C2 discloses a number of precipitation-hardenable copper alloys and their use for stationary continuous casting molds, inter alia with various CuNiBe alloys, which, as further alloy components, include niobium (Nb), zirconium (Zr), magnesium (Mg) and / or titanium (Ti ) contain
- a copper alloy CuZrNiBe is known from document US Pat. No. 2,137,281 for a strip mold (twin-belt casting) which is characterized by a combination of properties of comparatively great hardness with comparatively high thermal conductivity
- the invention has for its object to provide a suitable for the production of broad side plates for thin slab casting molds with high casting speed in a special way suitable copper alloys, by their use in the casting operation early cracking, especially in the area of the mold level, avoided and Wear of the contact surface with liquid steel is reduced, and which withstands the extremely high thermal and mechanical stresses in the casting operation with long-term availability
- the solution to this problem consists in the use of a hardenable copper alloy with a beryllium content of 0.1% to 0.5% and a nickel content of 0.5% to 2.0% (CuNiBe) for the production of broad side plates for thin slab casting molds
- this copper alloy After hardening, this copper alloy has the great advantage of being able to absorb high temperature stresses in the area of the mold level while avoiding crack formation and to remain available over longer operating times
- the copper alloy CuNiBe used according to the invention is helped by this advantageous operating result due to its advantageous material properties, for example a much higher tensile strength of approx. 770 or approx. 650 N / mm 2 and 0.2 proof strength of approx 500 N / mm 2 both at 20 ° C and at 300 ° C
- the material properties of three selected copper alloys, CuCrZr, CuAg and CuNiBe are shown in the following table Material properties
- Another positive property e.g. resistance to mechanical wear, results from the high hardness of the material used according to the invention of approximately 220 HB, because CuNiBe has approximately the same hardness as a galvanically applied nickel layer with approximately 220-230 HB.
- the broad side plates therefore need can no longer be nickel-plated
- the lower thermal conductivity of the copper alloy CuNiBe of approx. 300 W / mK compared to CuAg with a thermal conductivity of approx. 370 W / mK, can be compensated for by a reduced copper wall thickness of approx. 25% before water. This also results in a saving in material costs for the production
- the invention enables the casting of thin slabs at high casting speeds of at least 2 to 6 m / min and more.
- the significant improvement in the operating behavior as a result of longer availability, in particular the minimized one Cracking in the area of the bathroom mirror, the cost-effective expenditure for material and production are the result of the special selection of the alloy components
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Continuous Casting (AREA)
Abstract
The invention relates to the use of a hardenable copper alloy containing 0.1 % to 0.5 % beryllium and 0.5 % to 2.0 % nickel for the production of broad side plates for thin slab continuous casting molds at casting speeds of at least 2 to 6 m/min and higher.
Description
Verwendung einer aushärtbaren Kupferlegierung für KokillenUse of a hardenable copper alloy for molds
Die Erfindung betrifft die Verwendung einer aushartbaren Kupferlegierung für Kokillen, insbesondere zur Herstellung von Breitseitenplatten für Dunnbrammen- StranggießkokillenThe invention relates to the use of a hardenable copper alloy for molds, in particular for the production of broad side plates for thin slab casting molds
Beim Stand der Technik werden Kokillenbreitseitenplatten für Dunnbrammenanla- gen und insbesondere für CSP (Compact Strip Productιoπ)-Anlagen aus Kupferlegierungen wie CuCrZr (Kupfer Chrom Zirkon) oder CuAg (Kupfer Silber) hergestellt Dabei hat sich eine CuAg-Legierung für CSP-Kokillenplatten aufgrund seiner vergleichsweise hohen Dehnung bei steigenden Temperaturen als vorteilhaft erwiesenIn the prior art, mold wide side plates for thin slab systems and in particular for CSP (compact strip product) systems are produced from copper alloys such as CuCrZr (copper chromium zirconium) or CuAg (copper silver). Because of this, a CuAg alloy for CSP mold plates has been produced comparatively high elongation with increasing temperatures has proven to be advantageous
Kokillenbreitseitenplatten aus CuAg bzw CuCrZr sind jedoch nicht in der Lage, die im Badspiegeibereich des Gießmetalles herrschenden hohen Temperaturspannungen aufzunehmen und neigen dazu, in diesem Bereich Risse in den Platten zu bilden, wobei insbesondere CuCrZr zu besonders früher Rißbildung tendiert Diese Rißbildung ist dann das Ausfallkπteπum für die Kokillenbreitseitenplatten und verursacht hohe Reparatur- und Ersatzkosten für den Betreiber einer StranggießanlageHowever, mold wide side plates made of CuAg or CuCrZr are not able to absorb the high temperature tensions in the bath level of the cast metal and tend to form cracks in the area in this area, whereby CuCrZr in particular tends to form cracks particularly early. This crack formation is then the failure point for the mold wide side plates and causes high repair and replacement costs for the operator of a continuous caster
Es wurde beobachtet, daß CuAg trotz geringerer Zugfestigkeit nur deshalb eine verminderte Rißbildung aufweist, weil es infolge erhöhter Dehnfahigkeit bei hohen Temperaturen in der Kokillenplatte in der Lage ist, Spannungen abzubauen, und weil die vergleichsweise hohe Wärmeleitfähigkeit deren mittlere Betriebstemperatur niedriger halt
Für die Schmalseitenplatten von Dunnbrammen-Kokillen ist es beim Stand der Technik üblich, CuCrZr mit ca 125 HB-Harte einzusetzen, wobei deren seitliche Kontaktflachen zur Erhöhung der Harte vernickelt sindIt has been observed that CuAg, despite its lower tensile strength, only shows reduced crack formation because it is able to relieve stress in the mold plate as a result of increased extensibility at high temperatures, and because the comparatively high thermal conductivity keeps its mean operating temperature lower For the narrow side plates of thin slab molds it is customary in the prior art to use CuCrZr with approximately 125 HB hardness, the lateral contact surfaces of which are nickel-plated to increase the hardness
Das Ausfallkπteπum der Schmalseitenplatten ist im Unterschied zu den Breitsei- tenplatten nicht die Rißbildung, sondern der Verschleiß bzw Abrieb der Kontaktflachen zum Stahl Im Gegensatz dazu ist das häufigste Ausfallkriteπum der Breit- seitenplatten eine Rißbildung im GießspiegelbereichIn contrast to the broad side plates, the failure rate of the narrow side plates is not the formation of cracks, but rather the wear or abrasion of the contact surfaces to the steel. In contrast, the most common failure criterion of the wide side plates is crack formation in the area of the mold level
Das Dokument DE 31 20 978 C2 offenbart eine Anzahl ausscheiduπgshartbarer Kupferlegierungen und deren Verwendung für stationäre Stranggießkokillen, u a mit verschiedenen CuNiBe-Legierungen, welche als weitere Legierungsanteile Niob (Nb), Zirkonium (Zr), Magnesium (Mg) und/oder Titan (Ti) enthaltenDocument DE 31 20 978 C2 discloses a number of precipitation-hardenable copper alloys and their use for stationary continuous casting molds, inter alia with various CuNiBe alloys, which, as further alloy components, include niobium (Nb), zirconium (Zr), magnesium (Mg) and / or titanium (Ti ) contain
Aus dem Dokument US-PS 2 137 281 ist eine Kupferlegierung CuZrNiBe bekannt, für eine Bandkokille (Twin-belt casting), die sich durch eine Eigenschaftskombina- tion von vergleichsweise großer Harte bei vergleichsweise hoher Wärmeleitfähigkeit auszeichnetA copper alloy CuZrNiBe is known from document US Pat. No. 2,137,281 for a strip mold (twin-belt casting) which is characterized by a combination of properties of comparatively great hardness with comparatively high thermal conductivity
Aus dem Dokument GB-PS 95 47 96 ist für Kokillen eine Kupferlegierung Cu- BeZrTi bekannt, die bei vergleichsweise guter Wärmeleitfähigkeit vergleichsweise hohe Festigkeitswerte aufweistFrom the document GB-PS 95 47 96 a copper alloy Cu-BeZrTi is known for molds, which has comparatively high strength values with a comparatively good thermal conductivity
Für einen störungsfreien Gießbetrieb insbesondere von Dunnbrammen mit hohen Gießgeschwindigkeiten, bspw 6 m/min und mehr, reichen die vorhandenen mechanischen Eigenschaften der Kokillenwerkstoffe nicht aus, um die hierbei auftretenden hohen Temperaturen, insbesondere im Bereich des Gießspiegeis, zu beherrschen
Ausgehend vom vorgenannten Stand der Technik liegt der Erfindung die Aufgabe zugrunde, eine zur Herstellung von Breitseitenplatten für Dunnbrammen- Stranggießkokillen mit hoher Gießgeschwindigkeit in besonderer Weise geeignete Kupferlegierungen anzugeben, durch deren Verwendung beim Gießbetrieb eine frühzeitige Rißbildung, insbesondere im Bereich des Gießspiegels, vermieden und der Verschleiß der Kontaktflache mit flussigem Stahl reduziert wird, und welche den extrem hohen thermischen und mechanischen Beanspruchungen im Gießbetrieb bei langdauernder Verfügbarkeit widerstehtFor trouble-free casting operations, especially of thin slabs with high casting speeds, e.g. 6 m / min and more, the existing mechanical properties of the mold materials are not sufficient to control the high temperatures that occur, particularly in the area of the casting mirror Starting from the aforementioned prior art, the invention has for its object to provide a suitable for the production of broad side plates for thin slab casting molds with high casting speed in a special way suitable copper alloys, by their use in the casting operation early cracking, especially in the area of the mold level, avoided and Wear of the contact surface with liquid steel is reduced, and which withstands the extremely high thermal and mechanical stresses in the casting operation with long-term availability
Die Losung dieser Aufgabe besteht in der Verwendung einer aushartbaren Kupferlegierung mit einem Gehalt an Beryllium von 0,1 % bis 0,5%, und einem Gehalt an Nickel von 0,5% bis 2,0%, (CuNiBe) zur Herstellung von Breitseitenplatten für Dunnbrammen-StranggießkokillenThe solution to this problem consists in the use of a hardenable copper alloy with a beryllium content of 0.1% to 0.5% and a nickel content of 0.5% to 2.0% (CuNiBe) for the production of broad side plates for thin slab casting molds
Mit großem Vorteil ist diese Kupferlegierung nach ihrer Aushärtung in der Lage, hohe Temperaturspannungen im Gießspiegelbereich unter Vermeidung von Rißbildung aufzunehmen und über längere Betriebszeiten verfugbar zu bleibenAfter hardening, this copper alloy has the great advantage of being able to absorb high temperature stresses in the area of the mold level while avoiding crack formation and to remain available over longer operating times
Zu diesem erfolgreichen Betriebsergebnis - im Gegensatz zu den vorbekannten Kupferlegierungen wie CuCrZr oder CuAg - verhelfen der erfindungsgemaß verwendeten Kupferlegierung CuNiBe ihre vorteilhaften Material-Eigenschaften einer z B wesentlich höheren Zugfestigkeit von ca 770 bzw ca 650 N/mm2 und 0,2 Dehngrenze von ca 500 N/mm2 sowohl bei 20 °C als auch bei 300 °C Die Mate- πaleigenschaften von drei beispielhaft ausgewählten Kupfer-Legierungen, CuCrZr, CuAg sowie CuNiBe sind der folgenden Tabelle zu entnehmen
Material EigenschaftenIn contrast to the previously known copper alloys such as CuCrZr or CuAg, the copper alloy CuNiBe used according to the invention is helped by this advantageous operating result due to its advantageous material properties, for example a much higher tensile strength of approx. 770 or approx. 650 N / mm 2 and 0.2 proof strength of approx 500 N / mm 2 both at 20 ° C and at 300 ° C The material properties of three selected copper alloys, CuCrZr, CuAg and CuNiBe are shown in the following table Material properties
TABELLETABLE
Chemische ZusammensetzungChemical composition
Mechanische EigenschaftenMechanical properties
Eine weitere positive Eigenschaft, bspw die Resistenz gegen mechanischen Verschleiß, ergibt sich aus der hohen Harte des erfindungsgemaß verwendeten Materials von ca 220 HB, weil CuNiBe annähernd die gleiche Harte besitzt, wie eine galvanisch aufgebrachte Nickelschicht mit ca 220-230 HB Die Breitseitenplatten brauchen also nicht mehr vernickelt werden Another positive property, e.g. resistance to mechanical wear, results from the high hardness of the material used according to the invention of approximately 220 HB, because CuNiBe has approximately the same hardness as a galvanically applied nickel layer with approximately 220-230 HB. The broad side plates therefore need can no longer be nickel-plated
Die im Vergleich zu CuAg mit einer Wärmeleitfähigkeit von ca 370 W/mK geringere Wärmeleitfähigkeit der Kupferlegierung CuNiBe, von ca 300 W/mK, kann durch eine reduzierte Kupferwandstarke um ca 25% vor Wasser ausgeglichen werden Damit ergibt sich auch eine Ersparnis an Materialkosten für die FertigungThe lower thermal conductivity of the copper alloy CuNiBe, of approx. 300 W / mK compared to CuAg with a thermal conductivity of approx. 370 W / mK, can be compensated for by a reduced copper wall thickness of approx. 25% before water. This also results in a saving in material costs for the production
Die erfindungsgemaß verwendete Kupferlegierung CuNiBe zur Herstellung von Breitseitenplatten für Dunnbrammen-Stranggießkokillen mit hohen Gießgeschwindigkeiten bspw von 2 bis 6 m/min und mehr enthalt als Legierungsbestandteile 0,1 % bis 0,5% Beryllium, 0,5 % bis 2,0 % Nickel und Kupfer bis zu 99,5 % Gesamtgewicht Sie soll nicht mehr als 0,5 % Verunreinigungen enthalten, worunter z B Spuren anderer Metalle wie Fe, Zr, Ag, Cr, Mg etc verstanden werdenThe copper alloy CuNiBe used according to the invention for the production of broad side plates for thin slab continuous casting molds with high casting speeds, for example from 2 to 6 m / min and more, contains 0.1% to 0.5% beryllium, 0.5% to 2.0% nickel as alloy components and copper up to 99.5% total weight. It should not contain more than 0.5% impurities, which means, for example, traces of other metals such as Fe, Zr, Ag, Cr, Mg etc.
Die Erfindung ermöglicht mit der aus dem Stand der Technik nicht nahegelegten Verwendung der speziellen Kupferlegierung CuNiBe für Breitseitenplatten von Stranggießkokillen das Gießen von Dunnbrammen mit hohen Gießgeschwindigkeiten von mindestens 2 bis 6 m/min und mehr Die signifikante Verbesserung des Betriebsverhaltens infolge längerer Verfügbarkeit, insbesondere die minimierte Rißbildung im Badspiegeibereich, der kostengünstige Aufwand für Material und Fertigung sind das Ergebnis der speziellen Auswahl der Legierungsbestandteile
With the use of the special copper alloy CuNiBe for broad side plates of continuous casting molds, which is not suggested in the prior art, the invention enables the casting of thin slabs at high casting speeds of at least 2 to 6 m / min and more. The significant improvement in the operating behavior as a result of longer availability, in particular the minimized one Cracking in the area of the bathroom mirror, the cost-effective expenditure for material and production are the result of the special selection of the alloy components
Claims
Patentansprücheclaims
1 Verwendung einer aushartbaren Kupferlegierung mit einem Gehalt an Beryllium von 0,1 % bis 0,5 % und einem Gehalt an Nickel von 0,5 % bis 2,0% für Kokillen insbesondere zur Herstellung von Breitseitenplatten für Dunnbrammen-Stranggießkokillen1 Use of a hardenable copper alloy with a beryllium content of 0.1% to 0.5% and a nickel content of 0.5% to 2.0% for molds, in particular for the production of broad side plates for thin slab casting molds
Verwendung einer aushartbaren Kupferlegierung nach Anspruch 1 zur Herstellung von Breitseitenplatten für Dunnbrammen-Stranggießkokillen mit Gießgeschwindigkeiten von wenigstens 2 bis 6 m/minUse of a hardenable copper alloy according to claim 1 for the production of broad side plates for thin slab casting molds with casting speeds of at least 2 to 6 m / min
Verwendung einer aushartbaren Kupferlegierung nach Anspruch 1 oder 2 mit Legierungsbestandteilen von 0,1 % bis 0,5 % Beryllium und 0,5 bis 2,0% Nickel, die mit einem Bestandteil an Kupfer wenigstens 99,5 % betragenUse of a hardenable copper alloy according to claim 1 or 2 with alloy components of 0.1% to 0.5% beryllium and 0.5 to 2.0% nickel, which are at least 99.5% with a component of copper
Verwendung einer aushartbaren Kupferlegierung nach einem oder mehreren der Ansprüche 1 bis 3, die außer den Legierungsbestandteilen Beryllium, Nickel und Kupfer maximal 0,5 % Verunreinigungen enthalt
Use of a hardenable copper alloy according to one or more of claims 1 to 3, which contains a maximum of 0.5% impurities in addition to the alloy components beryllium, nickel and copper
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10018504 | 2000-04-14 | ||
| DE10018504A DE10018504A1 (en) | 2000-04-14 | 2000-04-14 | Use of a hardenable copper alloy containing beryllium and nickel for molds for producing plates for thin slab continuous casting molds |
| PCT/EP2001/004235 WO2001079574A1 (en) | 2000-04-14 | 2001-04-12 | Use of a hardenable copper alloy for molds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1274871A1 true EP1274871A1 (en) | 2003-01-15 |
Family
ID=7638729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01929554A Ceased EP1274871A1 (en) | 2000-04-14 | 2001-04-12 | Use of a hardenable copper alloy for molds |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20030165396A1 (en) |
| EP (1) | EP1274871A1 (en) |
| JP (1) | JP2003531290A (en) |
| KR (1) | KR20020091154A (en) |
| CN (1) | CN1423707A (en) |
| DE (1) | DE10018504A1 (en) |
| EG (1) | EG22980A (en) |
| RU (1) | RU2260493C2 (en) |
| TW (1) | TW524864B (en) |
| WO (1) | WO2001079574A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW590822B (en) * | 2001-11-21 | 2004-06-11 | Km Europa Metal Ag | Casting-roller for a two-roller-casting equipment and its manufacturing method |
| DE10156925A1 (en) * | 2001-11-21 | 2003-05-28 | Km Europa Metal Ag | Hardenable copper alloy as a material for the production of casting molds |
| CA2436855A1 (en) * | 2002-08-02 | 2004-02-02 | Hildreth Manufacturing, Llc | A precipitation-hardenable alloy core rod, plunger tip having a uniform side wall thickness, and method of forming same |
| DE102009037283A1 (en) * | 2009-08-14 | 2011-02-17 | Kme Germany Ag & Co. Kg | mold |
| CN110218903B (en) * | 2019-07-02 | 2020-07-14 | 西峡龙成特种材料有限公司 | ESP continuous casting crystallizer narrow-surface copper plate base metal and machining method thereof, and ESP continuous casting crystallizer narrow-surface copper plate |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4377424A (en) * | 1980-05-26 | 1983-03-22 | Chuetsu Metal Works Co., Ltd. | Mold of precipitation hardenable copper alloy for continuous casting mold |
| DE3109438A1 (en) * | 1981-03-12 | 1982-09-30 | Kabel- und Metallwerke Gutehoffnungshütte AG, 3000 Hannover | "METHOD FOR THE PRODUCTION OF TUBULAR, STRAIGHT OR CURVED CONTINUOUS CASTING CHILLS WITH PARALLELS OR CONICAL INTERIOR CONTOURS FROM CURABLE copper ALLOYS" |
| US4421570A (en) * | 1982-03-12 | 1983-12-20 | Kabel Und Metallwerke Gutehoffnungshutte Ag | Making molds for continuous casting |
| JPH02111835A (en) * | 1988-10-20 | 1990-04-24 | Chuetsu Gokin Chuko Kk | Mold material for electromagnetic stirring |
| JP2869076B2 (en) * | 1988-12-19 | 1999-03-10 | 中越合金鋳工株式会社 | Precipitation hardening mold material for continuous casting |
| DE4142941A1 (en) * | 1991-12-24 | 1993-07-01 | Kabelmetal Ag | USE OF A CURABLE copper alloy |
| DE69520268T2 (en) * | 1995-02-01 | 2001-08-09 | Brush Wellman Inc., Cleveland | Treatment of alloys and articles made thereafter |
| DE19681298B4 (en) * | 1995-03-07 | 2006-12-28 | Asahi Kasei Chemicals Corporation | A flame retardant resin composition and process for producing an organic phosphorus compound |
-
2000
- 2000-04-14 DE DE10018504A patent/DE10018504A1/en not_active Withdrawn
-
2001
- 2001-04-06 TW TW090108247A patent/TW524864B/en not_active IP Right Cessation
- 2001-04-11 EG EG20010361A patent/EG22980A/en active
- 2001-04-12 EP EP01929554A patent/EP1274871A1/en not_active Ceased
- 2001-04-12 US US10/257,512 patent/US20030165396A1/en not_active Abandoned
- 2001-04-12 WO PCT/EP2001/004235 patent/WO2001079574A1/en not_active Application Discontinuation
- 2001-04-12 CN CN01808026A patent/CN1423707A/en active Pending
- 2001-04-12 RU RU2002130502/02A patent/RU2260493C2/en not_active IP Right Cessation
- 2001-04-12 JP JP2001576957A patent/JP2003531290A/en not_active Withdrawn
- 2001-04-12 KR KR1020027012659A patent/KR20020091154A/en not_active Application Discontinuation
-
2005
- 2005-03-11 US US11/078,006 patent/US20050158204A1/en not_active Abandoned
Non-Patent Citations (2)
| Title |
|---|
| None * |
| See also references of WO0179574A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1423707A (en) | 2003-06-11 |
| TW524864B (en) | 2003-03-21 |
| RU2260493C2 (en) | 2005-09-20 |
| US20050158204A1 (en) | 2005-07-21 |
| WO2001079574A1 (en) | 2001-10-25 |
| JP2003531290A (en) | 2003-10-21 |
| US20030165396A1 (en) | 2003-09-04 |
| EG22980A (en) | 2003-12-31 |
| DE10018504A1 (en) | 2001-10-18 |
| KR20020091154A (en) | 2002-12-05 |
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