[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

EP0090342A2 - Water-based lubricant for saw chains - Google Patents

Water-based lubricant for saw chains Download PDF

Info

Publication number
EP0090342A2
EP0090342A2 EP83102869A EP83102869A EP0090342A2 EP 0090342 A2 EP0090342 A2 EP 0090342A2 EP 83102869 A EP83102869 A EP 83102869A EP 83102869 A EP83102869 A EP 83102869A EP 0090342 A2 EP0090342 A2 EP 0090342A2
Authority
EP
European Patent Office
Prior art keywords
water
weight
lubricant
lubricant according
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP83102869A
Other languages
German (de)
French (fr)
Other versions
EP0090342B1 (en
EP0090342A3 (en
Inventor
Peter Dr. Geymayer
Erich Leidl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT83102869T priority Critical patent/ATE18068T1/en
Publication of EP0090342A2 publication Critical patent/EP0090342A2/en
Publication of EP0090342A3 publication Critical patent/EP0090342A3/en
Application granted granted Critical
Publication of EP0090342B1 publication Critical patent/EP0090342B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/10—Groups 5 or 15
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/12—Groups 6 or 16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles

Definitions

  • the known synthetic saw chain lubricants consist essentially of water and a water-soluble antifreeze, preferably glycols, glycol ethers and / or trihydric aliphatic alcohols such as glycerol, optionally together with monohydric lower aliphatic alcohols such as isopropanol, as the main constituents.
  • a water-soluble antifreeze preferably glycols, glycol ethers and / or trihydric aliphatic alcohols such as glycerol, optionally together with monohydric lower aliphatic alcohols such as isopropanol, as the main constituents.
  • glycerol glycols, glycol ethers and / or trihydric aliphatic alcohols
  • monohydric lower aliphatic alcohols such as isopropanol
  • the new saw chain lubricant surprisingly has particularly good rheological properties, a high lubricating effect and excellent adhesion. It still functions properly if the component evaporates water during operation.
  • These outstanding properties should in particular be attributable to the special combination of the adhesion promoters and polyethylene oxide-polypropylene oxide adducts present according to the invention. These two components obviously complement each other to an unexpectedly high degree in terms of viscosity, lubrication, adhesion and rheological behavior of the agent, even if more or less large parts of the main component water are no longer present.
  • the new saw chain lubricant contains a special lubricant (component F), namely liquid and water-soluble polyethylene oxide-polypropylene oxide adducts which have a viscosity of at least 300 mPa s, preferably 1,000 to 20,000, in particular 3,000 to 12,000 mPa s (measured at 50 ° C according to DIN 53 018 with a rotary viscometer).
  • component F a special lubricant
  • component F liquid and water-soluble polyethylene oxide-polypropylene oxide adducts which have a viscosity of at least 300 mPa s, preferably 1,000 to 20,000, in particular 3,000 to 12,000 mPa s (measured at 50 ° C according to DIN 53 018 with a rotary viscometer).
  • These polyethylene oxide-polypropylene oxide adducts are known and commercially available. These are statistical ethylene oxide-propylene oxide polyadducts which have the stated viscosity.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Luminescent Compositions (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

This saw chain lubricant is composed essentially of water and a water-soluble antifreeze agent, as main constituents, and of corrosion inhibitors, wear inhibitors and adhesion promoters in a quantity which is effective in each case, the adhesion promoter being a water-soluble polyethylene glycol and/or a water-soluble acrylamide copolymer which contains sulfonic acid groups, the molecular weight of each being at least 500,000. In combination with this adhesion promoter, which is present in an amount of 0.05 to 1% by weight, the lubricant contains 5 to 50% by weight of a water-soluble polyethylene oxide/polypropylene oxide adduct having a viscosity of at least 300 mPa.s at 50 DEG C., as a special lubricant, percentages by weight relating in each case to the weight of the agent.

Description

Die Erfindung betrifft ein Schmiermittel für Sägeketten, das im wesentlichen aus Wasser und einem wasserlöslichen Frostschutzmittel als Hauptbestandteile, Korrosionsinhibitoren, Verschleißinhibitoren und Haftvermittlern besteht und insbesondere einen lang andauernden Betrieb der Sägeketten-Maschine gewährleistet.The invention relates to a lubricant for saw chains, which consists essentially of water and a water-soluble antifreeze as the main components, corrosion inhibitors, wear inhibitors and adhesion promoters and in particular ensures long-term operation of the saw chain machine.

Zum Schmieren von Kettensägen, wie sie beispielsweise in der Forstwirtschaft zum Fällen von Bäumen verwendet werden, sind Schmiermittel auf der Basis von Mineralöl oder synthetische Produkte in Gebrauch. Auch zum Schmieren von stationär betriebenen Sägen wie Gattersägen, werden derartige Schmiermittel eingesetzt.Lubricants based on mineral oil or synthetic products are used to lubricate chainsaws, such as those used in forestry to fell trees. Such lubricants are also used to lubricate stationary saws such as frame saws.

Die auf Mineralöl basierenden Schmiermittel befriedigen zwar bezüglich Verschleißschutz und Korrosionsverhalten, jedoch werden dagegen zunehmend ökologische Bedenken vorgebracht, weil sie aufgrund des Mineralöls nicht biologisch abbaubar sind.The lubricants based on mineral oil are satisfactory in terms of wear protection and corrosion behavior, but ecological concerns are increasingly being raised because they are not biodegradable due to the mineral oil.

Die bekannten synthetischen Sägeketten-Schmiermittel bestehen im wesentlichen aus Wasser und aus einem wasserlöslichen Frostschutzmittel, vorzugsweise Glykolen, Glykolethern und/oder dreiwertigen aliphatischen Alkoholen wie Glycerin, gegebenenfalls gemeinsam mit einwertigen niedrigen aliphatischen Alkoholen wie Isopropanol, als Hauptbestandteile. Neben diesen Hauptbestandteilen enthalten sie in einer jeweils wirksamen Menge Korrosionsinhibitoren, Verschleißinhibitoren und Haftvermittler.The known synthetic saw chain lubricants consist essentially of water and a water-soluble antifreeze, preferably glycols, glycol ethers and / or trihydric aliphatic alcohols such as glycerol, optionally together with monohydric lower aliphatic alcohols such as isopropanol, as the main constituents. In addition to these main components, they each contain an effective amount of corrosion inhibitors, wear inhibitors and adhesion promoters.

Die Korrosionsschutz- und die Verschleißschutz-Additive sollen insbesondere die Kettenglieder, die Kettenführung und das Antriebsritzel vor Korrosion und Verschleiß schützen. Dazu werden gegebenenfalls auch sogenannte extreme pressure-additives (EP-additives) eingesetzt. Die Haftadditive sollen einerseits viskositätsregulierend wirken und andererseits das Abschleudern des Schmiermittels von der Sägekette während des Betriebs möglichst weitgehend verhindern. Eine wirksame Verhinderung hängt insbesondere damit zusammen, daß das eingesetzte Haftadditiv die Eigenschaft besitzt, das fertige Schmiermittel fadenziehend zu machen.The corrosion protection and wear protection additives are intended in particular to protect the chain links, the chain guide and the drive pinion from corrosion and wear. Extreme pressure additives (EP additives) may also be used for this purpose. On the one hand, the adhesive additives should have a viscosity-regulating effect and, on the other hand, should largely prevent the lubricant from being thrown off the saw chain during operation. An effective prevention is particularly related to the fact that the adhesive used has the property of making the finished lubricant thread-pulling.

Die in den bekannten Sägeketten-Schmiermitteln aus Wasser und Frostschutzmittel als Hauptbestandteile benutzten Haftvermittler vermögen zwar die Viskosität der Grundbestandteile zu erhöhen, sie fallen jedoch während des Betriebes der Sägeketten-Maschine infolge Verdampfung von Wasser aus, wodurch nicht nur ihre viskositätsregulierende, sondern auch ihre fadenziehende Wirkung weitgehend verlorengeht. Durch die während des Betriebes herrschenden Scherkräfte wird das Haftadditiv schließlich vollständig zerstört.The adhesion promoters used as main components in the known saw chain lubricants made of water and antifreeze may increase the viscosity of the basic components, but they fail during the operation of the saw chain machine due to evaporation of water, which means that not only its viscosity-regulating but also its thread-pulling Effect is largely lost. The adhesive additive is finally completely destroyed by the shear forces prevailing during operation.

Diese bekannten Sägeketten-Schmiermittel sind demnach insbesondere hinsichtlich Viskositätsverhalten und Haftwirkung nicht zufriedenstellend. Aufgrund dieser Nachteile ermöglichen sie auch keinen dauerhaften Betrieb.These known saw chain lubricants are therefore unsatisfactory, in particular with regard to viscosity behavior and adhesive effect. Because of these disadvantages, they do not enable permanent operation.

Aufgabe der Erfindung ist es daher, ein Schmiermittel für Sägeketten auf der Basis von Wasser und üblichen Frostschutzmitteln bereitzustellen, das die Nachteile der bekannten derartigen Mittel nicht aufweist. Das neue Sägeketten-Schmiermittel soll nicht nur hinsichtlich Korrosionsschutz und Verschleißschutz, sondern insbesondere auch hinsichtlich Schmierwirkung, Viskosität und Haftung ausgezeichnete Eigenschaften aufweisen. Es soll darüber hinaus auch dann noch voll wirksam sein, wenn während des Betriebes der Sägeketten-Maschine das Wasser teilweise oder ganz verdampft, und somit einen lang andauernden Betrieb gewährleisten.The object of the invention is therefore to provide a lubricant for saw chains based on water and conventional antifreeze agents, which does not have the disadvantages of the known agents of this type. The new saw chain lubricant should not only have excellent properties in terms of corrosion protection and wear protection, but also in particular with regard to lubrication, viscosity and adhesion. It should also still be full be effective if the water evaporates partially or completely during operation of the saw chain machine, thus ensuring long-term operation.

Diese Aufgabe wird erfindungsgemäß gelöst mit einem Schmiermittel für Sägeketten, bestehend im wesentlichen aus Wasser und einem wasserlöslichen Frostschutzmittel als Hauptbestandteile und aus Korrosionsinhibitoren, Verschleißinhibitoren und Haftvermittler in einer jeweils wirksamen Menge, dadurch gekennzeichnet, daß der Haftvermittler ein wasserlösliches Polyethylenglykol und/oder ein Sulfonsäuregruppen enthaltendes und wasserlösliches Acrylamidcopolymer mit einem Molekulargewicht von jeweils mindestens 500 000 ist, in einer Menge von 0,05 bis 1 Gew.-%, bezogen auf das Gewicht des Mittels, und daß es zusätzlich 5 bis 50 Gew.-%, bezogen auf das Gewicht des Mittels, wasserlösliches Polyethylenoxid-Polypropylenoxid-Addukt mit einer Viskosität von mindestens 300 mPa s bei 50 °C enthält.This object is achieved according to the invention with a lubricant for saw chains consisting essentially of water and a water-soluble antifreeze as the main constituents and of corrosion inhibitors, wear inhibitors and adhesion promoters in an effective amount in each case, characterized in that the adhesion promoter contains a water-soluble polyethylene glycol and / or a sulfonic acid group and water-soluble acrylamide copolymer having a molecular weight of at least 500,000 each, in an amount of 0.05 to 1% by weight based on the weight of the agent, and that it is additionally 5 to 50% by weight based on the weight of the agent, contains water-soluble polyethylene oxide-polypropylene oxide adduct with a viscosity of at least 300 mPa s at 50 ° C.

Das neue Sägeketten-Schmiermittel besitzt überraschenderweise besonders gute rheologische Eigenschaften, eine hohe Schmierwirkung und ein hervorragendes Haftvermögen. Es wirkt auch dann noch funktionsgerecht, wenn die Komponente Wasser während des Betriebes verdampft. Diese hervorragenden Eigenschaften dürften insbesondere auf die spezielle Kombination der erfindungsgemäß vorhandenen Haftvermittler und Polyethylenoxid-Polypropylenoxid-Addukte zurückzuführen sein. Diese beiden Komponenten ergänzen sich offensichtlich in einem unerwartet hohen Ausmaß hinsichtlich Viskosität, Schmierung, Haftung und rheologischem Verhalten des Mittels, auch wenn mehr oder weniger große Teile der Hauptkomponente Wasser nicht mehr vorliegen.The new saw chain lubricant surprisingly has particularly good rheological properties, a high lubricating effect and excellent adhesion. It still functions properly if the component evaporates water during operation. These outstanding properties should in particular be attributable to the special combination of the adhesion promoters and polyethylene oxide-polypropylene oxide adducts present according to the invention. These two components obviously complement each other to an unexpectedly high degree in terms of viscosity, lubrication, adhesion and rheological behavior of the agent, even if more or less large parts of the main component water are no longer present.

Die Menge an Wasser (Komponente A) im erfindungsgemäßen Mittel beträgt im allgemeinen 30 bis 60 Gew.-%, vorzugsweise 35 bis 50 Gew.-%, bezogen auf das Gewicht des Mittels (des gesamten Mittels).The amount of water (component A) in the composition according to the invention is generally 30 to 60% by weight, preferably 35 to 50% by weight, based on the weight of the composition (of the entire composition).

Als Frostschutz (Komponente B) können alle jene Verbindungen eingesetzt werden, die auch bei den bekannten synthetischen Sägeketten-Schmiermitteln verwendet werden. Geeignete Frostschutzmittel sind (a) Glykole, nämlich Alkylenglykole mit 2 bis 6, vorzugsweise 2 bis 4 C-Atomen wie Ethylenglykol, Propylenglykol und Butylenglykol, und Oxalkylenglykole, vorzugsweise Oxethylen-und Oxpropylenglykole mit 4 bis 14, vorzugsweise 4 bis 10 C-Atomen wie Diethylenglykol, Dipropylenglykol, Triethylenglykol, Tetraethylenglykol und Tripropylenglykol, (b) aliphatische Monoether der genannten Glykole, vorzugsweise die Monomethyl-, Ethyl-, Propyl- und Butylether, und (c) mehrwertige aliphatische Alkohole, vorzugsweise Glycerin, Erythrit und Pentaerythrit.Frost protection (component B) can be used for all those compounds which are also used in the known synthetic saw chain lubricants. Suitable antifreeze agents are (a) glycols, namely alkylene glycols having 2 to 6, preferably 2 to 4, carbon atoms, such as ethylene glycol, propylene glycol and butylene glycol, and oxalkylene glycols, preferably oxylene and oxypropylene glycols, having 4 to 14, preferably 4 to 10, carbon atoms, such as Diethylene glycol, dipropylene glycol, triethylene glycol, tetraethylene glycol and tripropylene glycol, (b) aliphatic monoethers of the glycols mentioned, preferably the monomethyl, ethyl, propyl and butyl ethers, and (c) polyhydric aliphatic alcohols, preferably glycerol, erythritol and pentaerythritol.

Die Glykole, Glykolether und mehrwertigen Alkohole können jeweils allein oder in Mischung eingesetzt werden. Es können auch noch andere gefrierpunkterniedrigende Verbindungen, zweckmäßigerweise Alkali- und Erdalkalisalze, vorzugsweise Alkalicarbonate, Harnstoff und einwertige aliphatische Alkohole mit 1 bis 6, vorzugsweise 2 bis 4 C-Atomen wie Ethanol und Isopropanol verwendet werden. Unter den genannten Frostschutzmitteln sind Ethylenglykol (Monoethylenglykol), Propylenglykol, Oxethylenglykole mit 4 bis 10 C-Atomen wie Diethylenglykol, Triethylenglykol und Tetraethylenglykol, und deren Monomethyl-, Ethyl-, Propyl- und Butylether oder Mischungen davon, gegebenenfalls gemeinsam mit Harnstoff, in einer Menge von 1 bis 10 Gew.-%, bezogen auf das Gewicht des Frostschutzmittels, bevorzugt.The glycols, glycol ethers and polyhydric alcohols can each be used alone or as a mixture. Other freezing point-lowering compounds, advantageously alkali metal and alkaline earth metal salts, preferably alkali metal carbonates, urea and monohydric aliphatic alcohols having 1 to 6, preferably 2 to 4, carbon atoms, such as ethanol and isopropanol, can also be used. Among the antifreeze agents mentioned are ethylene glycol (monoethylene glycol), propylene glycol, oxyethylene glycols with 4 to 10 carbon atoms such as diethylene glycol, triethylene glycol and tetraethylene glycol, and their monomethyl, ethyl, propyl and butyl ether or mixtures thereof, optionally together with urea, in one Amount of 1 to 10 wt .-%, based on the weight of the antifreeze, preferred.

Die Menge des Frostschutzmittels (Komponente B) beträgt im allgemeinen 15bis bis 60 Gew.-%, vorzugsweise 30 bis 50 Gew.-%, bezogen auf das Gewicht des Mittels.The amount of the antifreeze (component B) is generally 15 to 60% by weight, preferably 30 to 50% by weight, based on the weight of the agent.

Als Inhibitoren gegen Korrosion (Komponente C) und gegen Verschleiß (Komponente D) eignen sich die diesbezüglich bei funktionellen Flüssigkeiten auf der Basis von Wasser und Glykolen allgemein üblichen Verbindungen.Suitable inhibitors against corrosion (component C) and against wear (component D) are the compounds which are generally customary in this regard for functional liquids based on water and glycols.

Geeignet sind demnach (a) Alkalisalze von Fettsäuren mit vorzugsweise 6 bis 18 C-Atomen und von aliphatischen oder aromatischen Sulfonsäuren, wobei der aliphatische Rest vorzugsweise ein Alkylrest mit mehr als 15 bis 20 C-Atomen und der aromatische Rest vorzugsweise der Benzolrest ist, beispielsweise Natrium- oder Kaliumsalz von Capronsäure, Laurinsäure, Stearinsäure, Alkansulfonsäuren mit mehr als 20 C-Atomen (Petroleumsulfonat) und von Benzolsulfonamidocapronsäure; (b) Alkalisalze und Ester der phosphorigen Säure, Phosphorsäure, Kieselsäure und der Mono- oder Dithiophosphorsäure mit aliphatischen Alkoholen mit vorzugsweise 4 bis 12 C-Atomen, beispielsweise Natriuraphosphit, Natriumphosphat, Wasserglas und Mono- und Diisopropylester der Phosphorsäure; (c) Mono- und Dialkylamine, gegebenenfalls ethoxyliert mit 1 bis 5 Ethylenoxid-Einheiten, und deren Salze mit den unter (a) und (b) genannten Säuren, wobei die Alkylgruppe im Amin 1 bis 18, vorzugsweise 4 bis 12 C-Atome hat, beispielsweise Butylamin, Hexylamin, Octylamin, Isononylamin, Oleylamin, Dibutylamin, Dioctylamin, Diisononylamin und die Salze dieser Amine mit Fettsäuren mit 6 bis 18 C-Atomen, Phosphorsäure, phosphoriger Säure und mit Benzolsulfonamidocapronsäure; (d) Alkanolamine, gegebenenfalls ethoxyliert mit 1 bis 5 Ethylenoxid-Einheiten, und deren Salze mit den unter (a) und (b) genannten Säuren, wobei die Alkylgruppe im Alkanol 2 bis 6 C-Atome besitzt, beispielsweise Monoethanolamin, Diethanolamin, Triethanolamin und die Salze dieser Alkanolamine mit Fettsäuren mit 6 bis 18 C-Atomen, Phosphorsäure, phosphoriger Säure und mit Benxolsulfonamidocaprönsäure; (e) Molybden- und Antimonverbindungen in Form von vorzugsweise Dithiocarbamaten; (f) Chlorparaffine und (g) Molybdensulfid- und Graphitdispersionen. Mit den genannten Verbindungen (allein oder in Mischung untereinander) wird Schutz sowohl gegen Korrosion als auch gegen Verschleiß erreicht. Weitere geeignete Verbindungen, die insbesondere als Korrosionsschutz dienen, sind Alkalisalze von Borsäure und Triazole, vorzugsweise Benztriazol.Accordingly, (a) alkali metal salts of fatty acids with preferably 6 to 18 carbon atoms and of aliphatic or aromatic sulfonic acids are suitable, the aliphatic radical preferably being an alkyl radical with more than 15 to 20 carbon atoms and the aromatic radical preferably being the benzene radical, for example Sodium or potassium salt of caproic acid, lauric acid, stearic acid, alkanesulfonic acids with more than 20 C atoms (petroleum sulfonate) and of benzenesulfonamidocaproic acid; (b) alkali metal salts and esters of phosphorous acid, phosphoric acid, silica and mono- or dithiophosphoric acid with aliphatic alcohols preferably having 4 to 12 carbon atoms, for example sodium phosphate, sodium phosphate, water glass and mono- and diisopropyl ester of phosphoric acid; (c) Mono- and dialkylamines, optionally ethoxylated with 1 to 5 ethylene oxide units, and their salts with the acids mentioned under (a) and (b), the alkyl group in the amine having 1 to 18, preferably 4 to 12, carbon atoms has, for example butylamine, hexylamine, octylamine, isononylamine, oleylamine, dibutylamine, dioctylamine, diisononylamine and the salts of these amines with fatty acids having 6 to 18 carbon atoms, phosphoric acid, phosphorous acid and with benzenesulfonamidocaproic acid; (d) Alkanolamines, optionally ethoxylated with 1 to 5 ethylene oxide units, and their salts with the acids mentioned under (a) and (b), the alkyl group in the alkanol having 2 to 6 carbon atoms, for example monoethanolamine, diethanolamine, triethanolamine and the salts of these alkanolamines with fatty acids having 6 to 18 carbon atoms, phosphoric acid, phosphorous acid and with benxolsulfonamidocapronic acid; (e) molybdenum and antimony compounds in the form of preferably dithiocarbamates; (f) chlorinated paraffins and (g) molybdenum sulfide and graphite dispersions. Protection against both corrosion and wear is achieved with the compounds mentioned (alone or as a mixture with one another). Other suitable compounds which serve in particular as corrosion protection are alkali salts of boric acid and triazoles, preferably benzotriazole.

Als Verschleißinhibitoren werden vorzugsweise die Alkalisalze von Fettsäuren mit 6 bis 18 C-Atomen, Alkalisalze von Phosphorsäure, die Salze von Monoalkylaminen mit 4 bis 12 C-Atomen in der Alkylgruppe und von Mono-, Di-und Triethanolamin mit Fettsäuren mit 6 bis 18 C-Atomen und mit Phosphorsäure, und die Molybdenverbindungen eingesetzt.The wear inhibitors are preferably the alkali metal salts of fatty acids with 6 to 18 carbon atoms, alkali metal salts of phosphoric acid, the salts of monoalkylamines with 4 to 12 carbon atoms in the alkyl group and of mono-, di- and triethanolamine with fatty acids with 6 to 18 ° C. -Atoms and with phosphoric acid, and the molybdenum compounds used.

Als Korrosionsinhibitoren werden vorzugsweise die Alkalisalze von Alkansulfonsäuren mit mehr als 20 C-Atomen (Petroleumsulfonat), Alkalisalze von Phosphorsäure, Wasserglas, die Salze von Monoalkylaminen mit 4 bis 12 C-Atomen in der Alkylgruppe und von Mono-, Di- und Triethanolamin mit Phosphorsäure und mit Benzolsulfonamidocapronsäure, und Benztriazol eingesetzt.Corrosion inhibitors are preferably the alkali metal salts of alkanesulfonic acids with more than 20 carbon atoms (petroleum sulfonate), alkali metal salts of phosphoric acid, water glass, the salts of monoalkylamines with 4 to 12 carbon atoms in the alkyl group and of mono-, di- and triethanolamine with phosphoric acid and used with benzenesulfonamidocaproic acid, and benzotriazole.

Die Menge an Korrosionsinhibitor (Komponente C) und Verschleißinhibitor (Komponente D) beträgt im allgemeinen 0,5 bis 5 Gew.-%, vorzugsweise 1 bis 3 Gew.-%, bezogen auf das Gewicht des Mittels.The amount of corrosion inhibitor (component C) and wear inhibitor (component D) is generally 0.5 to 5% by weight, preferably 1 to 3% by weight, based on the weight of the composition.

Als Haftvermittler (Komponente E) werden erfindungsgemäß wasserlösliche Polyethylenglykole mit einem Molekulargewicht von mindestens 500 000, vorzugsweise 1 000 000 bis 10 000 000, insbesondere 5 000 000 bis 7 000 000 eingesetzt. Diese festen Polyethylenglykole sind bekannt und im Handel in der Regel in Pulverform erhältlich. Weitere erfindungsgemäß zu verwendende Haftvermittler sind die wasserlöslichen Acrylamidcopolymerisate mit einem Molekulargewicht von mindestens 500 000, vorzugsweise 1 000 000 bis 10 000 000, insbesondere 5000 000 bis 7 000 000, wobei das Comonomere im Copolymerisat eine Sulfonsäuregruppe (eine SO3H-Gruppe je Comonomereinheit) enthält.According to the invention, water-soluble polyethylene glycols with a molecular weight of at least 500,000, preferably 1,000,000 to 10,000,000, in particular 5,000,000 to 7,000,000, are used as adhesion promoters (component E). These solid polyethylene glycols are known and are generally commercially available in powder form. Further adhesion promoters to be used according to the invention are the water-soluble acrylamide copolymers with a molecular weight of at least 500,000, preferably 1,000,000 to 10,000,000, in particular 5,000,000 to 7,000,000, the comonomer in the copolymer containing a sulfonic acid group (one SO 3 H group per comonomer unit).

Das Comonomere (zum Acrylamid als dem anderen Monomeren) ist vorzugsweise 2-Acrylamido-2-methylpropansulfon- säure. Ein bevorzugtes Acrylamidcopolymer besteht demnach aus Acrylamid und 2-Acrylamido-2-methylpropansulfon- säure. Die Comonomermenge beträgt im allgemeinen 10 bis 80 Gew.-%, vorzugsweise 50 bis 70 Gew.-%, bezogen auf das Copolymerisat.The comonomer (to acrylamide as the other monomer) is preferably 2-acrylamido-2-methylpropanesulfonic acid. A preferred acrylamide copolymer accordingly consists of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid. The amount of comonomer is generally 10 to 80% by weight, preferably 50 to 70% by weight, based on the copolymer.

Die Menge an Haftvermittler beträgt im allgemeinen 0,05 bis 1 Gew.-%, vorzugsweise 0,1 bis 0,5 Gew.-%,bezogen auf das Gewicht des Mittels.The amount of coupling agent is generally 0.05 to 1% by weight, preferably 0.1 to 0.5% by weight, based on the weight of the composition.

Das neue Sägeketten-Schmiermittel enthält erfindungsgemäß einen besonderen Schmierstoff (Komponente F), nämlich flüssige und wasserlösliche Polyethylenoxid-Polypropylenoxid-Addukte, die eine Viskosität von mindestens 300 mPa s, vorzugsweise 1 000 bis 20 000, insbesondere 3 000 bis 12 000 mPa s besitzen (gemessen bei 50 °C nach DIN 53 018 mit einem Rotationsviskosimeter). Diese Polyethylenoxid-Polypropylenoxid-Addukte sind bekannt und im Handel erhältlich. Es sind statistische Ethylenoxid-Propylenoxid-Polyaddukte, welche die angegebene Viskosität besitzen. In den erfindungsgemäß gewählten Ethylenoxid-Propylenoxid-Polymeren (in denen die Ethylenoxid- und Propylenoxid-Einheiten statistisch verteilt sind) beträgt das Verhältnis von Ethylenoxid zu Propylenoxid im allgemeinen 1 : 3 bis 5 : 1, vorzugsweise 1 : 1 bis 4 : 1.According to the invention, the new saw chain lubricant contains a special lubricant (component F), namely liquid and water-soluble polyethylene oxide-polypropylene oxide adducts which have a viscosity of at least 300 mPa s, preferably 1,000 to 20,000, in particular 3,000 to 12,000 mPa s (measured at 50 ° C according to DIN 53 018 with a rotary viscometer). These polyethylene oxide-polypropylene oxide adducts are known and commercially available. These are statistical ethylene oxide-propylene oxide polyadducts which have the stated viscosity. In the ethylene oxide-propylene oxide polymers chosen according to the invention (in which the ethylene oxide and propylene oxide units are randomly distributed), the ratio of ethylene oxide to propylene oxide is generally 1: 3 to 5: 1, preferably 1: 1 to 4: 1.

Die erfindungsgemäß zu verwendenden Polyethylenoxid-Polypropylenoxid-Addukte werden bekanntlich dadurch hergestellt, daß man an Verbindungen, die aktive Wasserstoffatome, vorzugsweise in Form von Hydroxylgruppen oder primären oder sekundären Amingruppen enthalten, Ethylenoxid und Propylenoxid anlagert. Geeignete Ausgangs-verbindungen sind (a) Wasser; (b) einwertige gesättigte aliphatische Alkohole mit vorzugsweise 1 bis 4 C-Atomen wie Methanol, Ethanol, Isopropanol und Butanol;(c) zweiwertige gesättigte aliphatische Alkohole, vorzugsweise Alkylenglykole mit 2 bis 4 C-Atomen und Oxalkylenglykole mit 2 bis 10 C-Atomen wie Ethylenglykol, Propylenglykol Butylenglykol, Diethylenglykol, Dipropylenglykol und Triethylenglykol; (d) drei- und mehrwertige gesättigte aliphatische Alkohole mit vorzugsweise 3 bis 6 C-Atomen wie Glycerin, Erythrit, Pentaerythrit, Trimethylolethan, Trimethylolpropan, Sorbit und Mannit; (e) gesättigte aliphatische Amine mit vorzugsweise 1 bis 6 C-Atomen wie Ethylamin, Isopropylamin, Butylamin, Dibutylamin und Propylendiamin; (f) gesättigte aliphatische Alkanolamine mit vorzugsweise 2 bis 6 C-Atomen wie Monoethanolamin und Diethanolamin; und (g) Ethoxylate oder Propoxylate aus den genannten Verbindungen (a) bis (f). Als Ausgangsverbindungen zur Addition von Ethylenoxid und Propylenoxid bis zur Erreichung eines Adduktes, das flüssig, wasserlöslich und die angegebene Viskosität aufweist, können auch Mischungen der genannten Verbindungen (a) bis (g) eingesetzt werden.The polyethylene oxide-polypropylene oxide adducts to be used according to the invention are known to be prepared by adding ethylene oxide and propylene oxide to compounds which contain active hydrogen atoms, preferably in the form of hydroxyl groups or primary or secondary amine groups. Suitable starting Connections are (a) water; (b) monohydric saturated aliphatic alcohols with preferably 1 to 4 carbon atoms such as methanol, ethanol, isopropanol and butanol; (c) dihydric saturated aliphatic alcohols, preferably alkylene glycols with 2 to 4 carbon atoms and oxalkylene glycols with 2 to 10 carbon atoms such as ethylene glycol, propylene glycol, butylene glycol, diethylene glycol, dipropylene glycol and triethylene glycol; (d) trihydric and polyhydric saturated aliphatic alcohols preferably having 3 to 6 carbon atoms, such as glycerol, erythritol, pentaerythritol, trimethylolethane, trimethylolpropane, sorbitol and mannitol; (e) saturated aliphatic amines with preferably 1 to 6 carbon atoms such as ethylamine, isopropylamine, butylamine, dibutylamine and propylenediamine; (f) saturated aliphatic alkanolamines with preferably 2 to 6 carbon atoms such as monoethanolamine and diethanolamine; and (g) ethoxylates or propoxylates from said compounds (a) to (f). Mixtures of the compounds (a) to (g) mentioned can also be used as starting compounds for the addition of ethylene oxide and propylene oxide until an adduct which is liquid, water-soluble and has the stated viscosity is reached.

Die Menge an Polyethylenoxid-Polypropylenoxid-Addukt (Komponente F) beträgt im allgemeinen 5 bis 50 Gew.-%, vorzugsweise 10 bis 30 Gew.-%, bezogen auf das Gewicht des Mittels.The amount of polyethylene oxide-polypropylene oxide adduct (component F) is generally 5 to 50% by weight, preferably 10 to 30% by weight, based on the weight of the composition.

Die Herstellung des erfindungsgemäßen flüssigen Sägeketten-Schmiermittels erfolgt durch Zusammenmischen der einzelnen Komponenten. Dies wird zweckmäßigerweise in einem mit einem Rührer ausgestatteten Behälter durchgeführt, wobei die Komponenten zweckmäßigerweise bei Raumtemperatur nacheinander eingebracht und unter Rühren gemischt werden.The liquid saw chain lubricant according to the invention is produced by mixing the individual components together. This is expediently carried out in a container equipped with a stirrer, the components advantageously being introduced in succession at room temperature and mixed with stirring.

Die Erfindung wird nun an Beispielen noch näher erläutert.The invention will now be explained in more detail using examples.

Beispiel 1example 1

Die in der nachstehenden Tabelle I in Kolonne 1 angegebenen Mengen der einzelnen Komponenten eines erfindungsgemäßen Schmiermittels werden bei Raumtemperatur vermischt. Dabei wird in das vorgelegte Diethylenglykol zunächst das Polyethylenglykol, Molekulargewicht 5 000 000, und anschließend das Wasser eingerührt, worauf die vorliegende Suspension bis zum vollständigen Quellen stehengelassen wird. Nun werden die übrigen Komponenten wiederum unter Rühren zugesetzt.The amounts of the individual components of a lubricant according to the invention given in column 1 in Table I below are mixed at room temperature. The polyethylene glycol, molecular weight 5,000,000, and then the water are first stirred into the diethylene glycol provided, whereupon the present suspension is left to swell completely. Now the remaining components are again added with stirring.

Das erhaltene Schmiermittel weist die in der nachstehenden Tabelle II in Kolonne 1 angeführten Eigenschafswerte auf.The lubricant obtained has the property values listed in column II below in column 1.

Beispiele 2 bis 8Examples 2 to 8

In diesen Beispielen wird analog Beispiel 1 vorgegangen, wobei die in der Tabelle I in den Kolonnen 2 bis 9 angegebenen erfindungsgemäßen Schmiermittel erhalten werden. Sie weisen die in den Kolonnen 2 bis 9 der Tabelle II angeführten Eigenschaftwerte auf.In these examples, the procedure is analogous to Example 1, the lubricants according to the invention given in columns I to columns 2 to 9 being obtained. They have the property values listed in columns 2 to 9 of Table II.

VergleichsbeispielComparative example

In der Tabelle II sind die Eigenschaftswerte eines dem Stand der Technik entsprechenden synthetischen Schmiermittels für Sägeketten angegeben.Table II shows the property values of a state-of-the-art synthetic lubricant for saw chains.

Wie aus der Tabelle II hervorgeht, besitzt das erfindungsgemäße Schmiermittel, verglichen mit dem bekannten, eine viel vorteilhaftere Viskosität. Es zeigt auch noch bei hohen Schergeschwindigkeiten ein günstiges Viskositätsverhalten, was für den bestimmungsgemäßen Einsatz besonders wichtig ist. Der erfindungsgemäß eingesetzte Haftvermittler bleibt auch nach dem Abdampfen des Wassers voll wirksam, während der im Vergleichsbeispiel anwesende seine fadenziehende Wirkung relativ schnell verliert. Das erfindungsgemäße Schmiermittel weist im Gegensatz zum bekannten auch eine hervorragende Verschleißschutzwirkung auf.

Figure imgb0001
Figure imgb0002
 As can be seen from Table II, the lubricant according to the invention has a much more advantageous viscosity compared to the known one. It shows a favorable viscosity behavior even at high shear rates, which is particularly important for the intended use. The adhesion promoter used according to the invention remains fully effective even after the water has evaporated, while that present in the comparative example loses its stringy effect relatively quickly. In contrast to the known lubricant, the lubricant according to the invention also has an excellent wear protection effect.
Figure imgb0001
Figure imgb0002

Claims (10)

1. Schmiermittel für Sägeketten, bestehend im wesentlichen aus Wasser und einem wasserlöslichen Frostschutzmittel als Hauptbestandteile und aus Korrosionsinhibitoren, Verschleißinhibitoren und Haftvermittler in einer jeweils wirksamen Menge, dadurch gekennzeichnet, daß der Haftvermittler ein wasserlösliches Polyethylenglykol und/oder ein Sulfonsäuregruppen enthaltendes und wasserlösliches Acrylamidcopolymer mit einem Molekulargewicht von jeweils mindestens 500 000 ist, in einer Menge von 0,05 bis 1 Gew.-%, bezogen auf das Gewicht des Mittels, und daß es zusätzlich 5 bis 50 Gew.-%, bezogen auf das Gewicht des Mittels, wasserlösliches Polyethylenoxid-Polypropylenoxid-Addukt mit einer Viskosität von mindestens 300 mPa s bei 50 °C enthält.1. Lubricant for saw chains, consisting essentially of water and a water-soluble antifreeze as the main constituents and of corrosion inhibitors, wear inhibitors and adhesion promoters in a respectively effective amount, characterized in that the adhesion promoter contains a water-soluble polyethylene glycol and / or a water-soluble acrylamide copolymer containing and sulfonic acid groups Molecular weight of at least 500,000 each, in an amount of 0.05 to 1 wt .-%, based on the weight of the agent, and that it is additionally 5 to 50 wt .-%, based on the weight of the agent, water-soluble polyethylene oxide -Polypropylene oxide adduct with a viscosity of at least 300 mPa s at 50 ° C. 2. Schmiermittel nach Anspruch 1, dadurch gekennzeichnet, daß das Molekulargewicht des Haftvermittlers 1 Million bis 10 Millionen beträgt.2. Lubricant according to claim 1, characterized in that the molecular weight of the coupling agent is 1 million to 10 million. 3. Schmiermittel nach Anspruch 1, dadurch gekennzeichnet, daß das Molekulargewicht des Haftvermittlers 5 bis 7 Millionen beträgt.3. Lubricant according to claim 1, characterized in that the molecular weight of the coupling agent is 5 to 7 million. 4. Schmiermittel nach Anspruch 1, dadurch gekennzeichnet, daß die Menge an Haftvermittler 0,1 bis 0,5 Gew.-% beträgt.4. Lubricant according to claim 1, characterized in that the amount of coupling agent is 0.1 to 0.5 wt .-%. 5. Schmiermittel nach Anspruch 1, dadurch gekennzeichnet, daß die Viskosität des Adduktes 1 000 bis 20 000 mPa s beträgt.5. Lubricant according to claim 1, characterized in that the viscosity of the adduct is 1,000 to 20,000 mPa s. 6. Schmiermittel nach Anspruch 1, dadurch gekennzeichnet, daß die Viskosität des Adduktes 3 000 bis 12 000 mPa s beträgt.6. Lubricant according to claim 1, characterized in that the viscosity of the adduct is 3,000 to 12,000 mPa s. 7. Schmiermittel nach Anspruch 1, dadurch gekennzeichnet, daß die Menge an Addukt 10 bis 30 Gew.-% beträgt.7. Lubricant according to claim 1, characterized in that the amount of adduct is 10 to 30 wt .-%. 8. Schmiermittel nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, daß das Acrylamidcopolymer aus Acrylamid und 2-Acrylamido-2-methylpropansulfon- säure besteht.8. Lubricant according to one of claims 1 to 7, characterized in that the acrylamide copolymer consists of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid. 9. Schmiermittel nach einem der Ansprüche 1 bis 8, bestehend im wesentlichen aus
Figure imgb0003
 9. Lubricant according to one of claims 1 to 8, consisting essentially of
Figure imgb0003
 10. Schmiermittel nach Anspruch 9, dadurch gekennzeichnet, daß es die Komponenten A) bis F) in den nachstehenden Gewichtsprozentmengen enthält:
Figure imgb0004
 10. Lubricant according to claim 9, characterized in that it contains components A) to F) in the following weight percentages:
Figure imgb0004
EP83102869A 1982-03-27 1983-03-23 Water-based lubricant for saw chains Expired EP0090342B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83102869T ATE18068T1 (en) 1982-03-27 1983-03-23 WATER-BASED LUBRICANT FOR SAW CHAIN.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3211352 1982-03-27
DE19823211352 DE3211352A1 (en) 1982-03-27 1982-03-27 WATER-BASED LUBRICANT FOR SAW CHAINS

Publications (3)

Publication Number Publication Date
EP0090342A2 true EP0090342A2 (en) 1983-10-05
EP0090342A3 EP0090342A3 (en) 1984-03-07
EP0090342B1 EP0090342B1 (en) 1986-02-19

Family

ID=6159489

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83102869A Expired EP0090342B1 (en) 1982-03-27 1983-03-23 Water-based lubricant for saw chains

Country Status (8)

Country Link
US (1) US4563294A (en)
EP (1) EP0090342B1 (en)
JP (1) JPS58176297A (en)
AT (1) ATE18068T1 (en)
BR (1) BR8301550A (en)
CA (1) CA1206141A (en)
DE (2) DE3211352A1 (en)
FI (1) FI72739C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501422A2 (en) * 1991-02-26 1992-09-02 The Dow Chemical Company Deicing fluids
WO2007068915A1 (en) * 2005-12-12 2007-06-21 Scota Industries Limited Motive force producer apparatus

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4749503A (en) * 1986-03-07 1988-06-07 Chemical Exchange Industries, Inc. Method and composition to control microbial growth in metalworking fluids
US4781847A (en) * 1986-05-08 1988-11-01 American Polywater Corporation Aqueous lubricant
WO1990001057A1 (en) * 1988-07-25 1990-02-08 Kharkovsky Avtomobilno-Dorozhny Institut Imeni Komsomola Ukrainy Non-flammable lubricating liquid
US5641734A (en) * 1991-10-31 1997-06-24 The Lubrizol Corporation Biodegradable chain bar lubricant composition for chain saws
CA2204717C (en) * 1996-05-13 2005-01-04 Sanjay Kalhan Sulfonate containing copolymers as mist suppressants in soluble oil (water based) metal working fluids
US6020291A (en) * 1997-11-21 2000-02-01 The Lubrizol Corporation Branched sulfonate containing copolymers as mist suppressants in soluble oil (water-based) metal working fluids
DE19931220B4 (en) * 1999-07-06 2005-03-10 Clariant Gmbh Use of polymers as anti-fog additive in water-based cooling lubricants
US6475408B1 (en) 2000-09-28 2002-11-05 The Lubrizol Corporation Shear-stable mist-suppressing compositions
DE10313280A1 (en) * 2003-03-25 2004-10-07 Basf Ag Antifreeze concentrates and coolant compositions based on polyglycols and amides for the protection of magnesium and its alloys
ATE520763T1 (en) * 2008-10-23 2011-09-15 Klinger Wolfgang CHAINSAW FLUID COMPOSITION
AT12470U1 (en) * 2011-02-03 2012-06-15 Klinger Wolfgang CHAIN FLUID COMPOSITION
FR2971515B1 (en) * 2011-02-14 2013-02-22 Michel Martin OIL FOR MECHANICAL SAW CHAIN.
DE102012014395B3 (en) * 2012-07-13 2013-08-22 Oxea Gmbh Isononylamines starting from 2-ethylhexanol, process for their preparation and their use
AT514523A1 (en) * 2013-06-20 2015-01-15 Eurollubricants Tribologie Gmbh Sägekettenschmiermittel
FR3111639B1 (en) * 2020-06-22 2022-08-19 Total Marketing Services Aqueous composition for the lubrication of mechanical systems

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2105236A1 (en) * 1970-06-18 1972-04-28 Mollco Patentverwertung
FR2111863A1 (en) * 1970-10-27 1972-06-09 Lubrizol Corp
US3699057A (en) * 1970-01-30 1972-10-17 Freeland Chem Co Lubrication
EP0029892A1 (en) * 1979-12-01 1981-06-10 Chemische Werke Hüls Ag Use of alcali or amino salts of a mixture of 2- and 3-alkyl-adipinic acids as corrosion inhibitor

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2825693A (en) * 1955-02-03 1958-03-04 Shell Dev Metal working lubricant
US3424682A (en) * 1966-08-08 1969-01-28 Albert M Sacerdote Materials-working composition containing a high molecular weight polymer
US3833502A (en) * 1973-04-30 1974-09-03 Nalco Chemical Co Method for improving the adherence of metalworking coolants to metal surfaces
JPS5144264B2 (en) * 1973-12-07 1976-11-27
US4177155A (en) * 1975-01-23 1979-12-04 Ciba-Geigy Corporation Additives for water-based functional fluids
US4250046A (en) * 1979-03-05 1981-02-10 Pennwalt Corporation Diethanol disulfide as an extreme pressure and anti-wear additive in water soluble metalworking fluids
DE3123726C2 (en) * 1981-06-15 1985-07-25 Ludwig Müller GmbH u. Co KG, 7100 Heilbronn Adhesive oils

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3699057A (en) * 1970-01-30 1972-10-17 Freeland Chem Co Lubrication
FR2105236A1 (en) * 1970-06-18 1972-04-28 Mollco Patentverwertung
FR2111863A1 (en) * 1970-10-27 1972-06-09 Lubrizol Corp
EP0029892A1 (en) * 1979-12-01 1981-06-10 Chemische Werke Hüls Ag Use of alcali or amino salts of a mixture of 2- and 3-alkyl-adipinic acids as corrosion inhibitor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501422A2 (en) * 1991-02-26 1992-09-02 The Dow Chemical Company Deicing fluids
EP0501422A3 (en) * 1991-02-26 1993-03-10 The Dow Chemical Company Deicing fluids
WO2007068915A1 (en) * 2005-12-12 2007-06-21 Scota Industries Limited Motive force producer apparatus

Also Published As

Publication number Publication date
BR8301550A (en) 1983-12-06
CA1206141A (en) 1986-06-17
FI831007L (en) 1983-09-28
US4563294A (en) 1986-01-07
EP0090342B1 (en) 1986-02-19
FI72739B (en) 1987-03-31
FI831007A0 (en) 1983-03-24
DE3211352A1 (en) 1983-09-29
FI72739C (en) 1987-07-10
JPS58176297A (en) 1983-10-15
DE3362146D1 (en) 1986-03-27
EP0090342A3 (en) 1984-03-07
ATE18068T1 (en) 1986-03-15

Similar Documents

Publication Publication Date Title
EP0090342B1 (en) Water-based lubricant for saw chains
DE602005002649T2 (en) ALKYLENOXIDCOPOLYMERS CONTAINING FUNCTIONAL LIQUIDS WITH LOW PULMONARY TOXICITY
DE2759233C2 (en)
DE68912454T2 (en) Polyether lubricant.
DE1768933C3 (en) Hydraulic fluids that are insensitive to water
EP2379687B1 (en) Water-based hydraulic fluids comprising dithio-di(aryl carbolic acids)
DE1001794B (en) Lubricant concentrate for metalworking
DE19833894A1 (en) Water-miscible coolant concentrate
DE2421477A1 (en) BOILER STONE AND CORROSION INHIBITION FOR COOLING WATER SYSTEMS
DE112015000678T5 (en) Water-dilutable high-performance grease kit for multi-metal metalworking applications
EP0713514B1 (en) Aircraft de-icing and anti-icing agents
EP0835291B1 (en) Production of thickening agents in liquid state
DE69317643T2 (en) Flame retardant hydraulic oil
DE3706038A1 (en) Synthetic polymer thickeners and thickened aqueous systems
DE1594393B2 (en)
DE69402069T2 (en) BASIC LIQUID
DE1594530C3 (en) Hydraulic fluids
EP2427536B1 (en) Use of lubricating additives
DE19600467A1 (en) Liquid packaging of thickeners (II)
EP2446003A1 (en) Polyalkylene glycol-based ether pyrrolidone carboxylic acids, and concentrates for the production of synthetic cooling lubricants containing the same
DE102007004292A1 (en) Cooling lubricant for the aqueous machining of light metals with high dispersibility
EP0011730B2 (en) Brake fluids having a conserving activity and an amount of oleic acid
AT328601B (en) LUBRICANT COMPOSITION
DE19854151A1 (en) Lubricant for the mechanical processing of materials
EP2031093A2 (en) Corrosion inhibitors containing non-ionic tensides

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL SE

17P Request for examination filed

Effective date: 19840509

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 18068

Country of ref document: AT

Date of ref document: 19860315

Kind code of ref document: T

ITF It: translation for a ep patent filed
REF Corresponds to:

Ref document number: 3362146

Country of ref document: DE

Date of ref document: 19860327

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19900215

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19900219

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19900223

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19900228

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19900312

Year of fee payment: 8

ITTA It: last paid annual fee
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19900331

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19900511

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19900822

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19910323

Ref country code: AT

Effective date: 19910323

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19910324

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19910331

Ref country code: CH

Effective date: 19910331

Ref country code: BE

Effective date: 19910331

BERE Be: lapsed

Owner name: HOECHST A.G.

Effective date: 19910331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19911001

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
GBPC Gb: european patent ceased through non-payment of renewal fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19911129

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19920101

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

EUG Se: european patent has lapsed

Ref document number: 83102869.1

Effective date: 19911009