CN1294163A - Ultraviolet ray solidified anticorrosion decorative paint for metal - Google Patents
Ultraviolet ray solidified anticorrosion decorative paint for metal Download PDFInfo
- Publication number
- CN1294163A CN1294163A CN 99115612 CN99115612A CN1294163A CN 1294163 A CN1294163 A CN 1294163A CN 99115612 CN99115612 CN 99115612 CN 99115612 A CN99115612 A CN 99115612A CN 1294163 A CN1294163 A CN 1294163A
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- CN
- China
- Prior art keywords
- ultraviolet ray
- decorative paint
- metal
- anticorrosion
- ray solidified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
An ultraviolet ray solidified anticorrosion decorative paint for metal is prepared from acrylic epoxy resin, diluent, optical trigger and assitant through proportional mixing. Its advantages include high productivity, low energy consumption, no environmental pollution, high anticorrosion effect and high decorative effect.
Description
The present invention relates to a kind of lacquer in the chemical field, be specifically related to a kind of ultraviolet light polymerization anticorrosion decorative paint.
Domestic anticorrosion decorative paint for metal is antifouling paint or paint for decoration at present, function singleness, and face and the anticorrosion or decoration simple function that is had are also very limited, preservative effect or decorative effect are not good enough, be unsuitable for pipelining, production efficiency is low, and energy consumption is big, environmental pollution is serious.
The present invention's purpose aims to provide a kind ofly can be used for base material corrosion-resistanting decoration glazing, be suitable for streamline production, production efficiency height, energy consumption are low, non-environmental-pollution, erosion resistance are strong, the ultraviolet ray solidified anticorrosion decorative paint for metal of good decorating effect.
Technical solution of the present invention is: this ultraviolet ray solidified anticorrosion decorative paint for metal is made up of matrix resin, thinner, light trigger, auxiliary agent, and by after certain weight percent proportioning, mixing and stirring makes.
Above-mentioned matrix resin adopts acrylic acid epoxy resin, thinner is an esters of acrylic acid, comprise acrylic monoester or diester or polyester, light trigger is selected the material that produces free radical under UV-irradiation for use, and auxiliary agent comprises flow agent, defoamer, pigment, stopping composition, promotor.
The weight percent proportioning of above-mentioned component is: matrix resin 30-70%, thinner: 20-65%, light trigger: 1-5%, auxiliary agent: 1-10%.
Matrix resin of the present invention is photo curable acrylic acid epoxy resin, this resin by Resins, epoxy through acrylic acid modified and make, product as Sartomer company, thinner is an esters of acrylic acid, comprise monoesters, diester or polyester, as Isooctyl acrylate monomer, vinylformic acid cyclohexyl ester, (methyl) Hydroxyethyl acrylate, HEA, butyl acrylate, 1.6-hexanediyl ester, dipropylene glycol two (methyl) acrylate, Viscoat 295, ethoxyquin Viscoat 295.Light trigger adopts the radical photoinitiator of absorbing wavelength at 200-450nm, as st-yrax ethers, thioxanthone derivates and anthraquinone class, thioxanthones etc.Auxiliary agent comprises flow agent, defoamer, pigment, stopping composition, promotor.
Making method of the present invention is: after aforesaid four component matrix resins, thinner, light trigger, auxiliary agent are pressed certain weight percent proportioning, under 35-50 ℃ temperature, fully stir, make it to mix, promptly get ultraviolet ray solidified anticorrosion decorative paint for metal of the present invention.With ultraviolet ray solidified anticorrosion decorative paint for metal of the present invention is that the UV oil polish is coated on the base material according to constructional method, then it is solidified under UV-light, can obtain acid and alkali-resistance, protection against corrosion, ornamental fabulous coating at last.
In sum, the present invention fills a prescription rationally, technology is simple, and technical feature is good, is suitable for streamline production, production efficiency height, and non-environmental-pollution, energy consumption are low, of many uses.
Embodiment 1:
Adopt following component and weight percent proportioning, and it mixed under 35-50 ℃ temperature:
UCB6040:56%, EHA:11%, HEA:10%, HDDA:12%, TMPTA:6%, 1173:4%, flow agent, defoamer: 0.4%, promotor: 0.6%
The physical and chemical performance experimental data is as follows:
Color: water white transparency
Coating method: brush
Viscosity (being coated with 25 ℃ in 4# cup): 24S
Salt fog resistance: 400h no change
20%H
2SO
4: the 100h no change
The 20%NaOH:100h no change
Glossiness: 〉=100 °
Pencil hardness: 〉=2H
Embodiment 2:
Adopt following component and weight percent proportioning, and it mixed under 35 °-50 ℃ temperature:
Modification 828:45%
TMPTA：5％
HDDA：10％
Butyl acrylate: 30%
EHA：4％
1173：4％
Auxiliary agent: 2%
Physical and chemical performance:
Color: water white transparency
Viscosity: 16S
Coating method: spraying
Salt spray resistance: 400h no change
Glossiness: 〉=100 °
Embodiment 3:
Adopt following component and weight percent proportioning, and under 35 °-50 ℃ temperature, mix:
Matrix resin:
Acrylic acid epoxy resin: 40%
Acrylate: 34%
Hydroxyethyl acrylate: 15%
TMPTA：6％
1173：4％
Auxiliary agent: 1%
Physical and chemical performance:
Color: water white transparency
Coating method: brushing
Viscosity: 24S
Salt fog resistance: 400h no change
20%H
2SO
4: the 100h no change
The 20%NaOH:100h no change
Glossiness: 〉=100 °
Pencil hardness: 〉=2H
Claims (3)
1, a kind of ultraviolet ray solidified anticorrosion decorative paint for metal is characterized in that being made up of matrix resin, thinner, light trigger, auxiliary agent, by after certain weight percent proportioning, mixes to stir all making.
2, ultraviolet ray solidified anticorrosion decorative paint for metal according to claim 1, it is characterized in that described matrix resin adopts acrylic acid epoxy resin, thinner is an esters of acrylic acid, comprise acrylic monoester or diester or polyester, light trigger is selected the material that produces free radical under UV-irradiation for use, and auxiliary agent comprises flow agent, defoamer, pigment, stopping composition, promotor.
3, ultraviolet ray solidified anticorrosion decorative paint for metal according to claim 1 and 2 is characterized in that the weight percent proportioning of described component is: matrix resin: 30-70%, thinner: 20-65%, light trigger: 1-5%, auxiliary agent: 1-10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99115612 CN1294163A (en) | 1999-10-28 | 1999-10-28 | Ultraviolet ray solidified anticorrosion decorative paint for metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99115612 CN1294163A (en) | 1999-10-28 | 1999-10-28 | Ultraviolet ray solidified anticorrosion decorative paint for metal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1294163A true CN1294163A (en) | 2001-05-09 |
Family
ID=5278547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99115612 Pending CN1294163A (en) | 1999-10-28 | 1999-10-28 | Ultraviolet ray solidified anticorrosion decorative paint for metal |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1294163A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100425741C (en) * | 2004-03-08 | 2008-10-15 | 中国印钞造币总公司 | Surface protection process for copper, aluminium alloy, steel-cored nickel coin and medal |
| CN100587014C (en) * | 2007-05-31 | 2010-02-03 | 捷伟实业有限公司 | Production method of active ecological paint |
| CN101245200B (en) * | 2008-03-12 | 2011-01-05 | 北京双燕商标彩印有限公司 | UV gloss oil, preparation method and application thereof |
| CN103122204A (en) * | 2013-02-05 | 2013-05-29 | 江苏宏泰高分子材料有限公司 | Solvent-free metal preservative UV (ultraviolet) paint and preparation method thereof |
| CN103525273A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV (ultraviolet) coating with water drop effect and preparation method thereof |
| CN103540241A (en) * | 2013-10-18 | 2014-01-29 | 安徽蓝柯复合材料有限公司 | Ultraviolet-curing primer wood coating and preparation method thereof |
| CN103540225A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Electrical cabinet anti-corrosive base coat and preparation method thereof |
| CN103540226A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Low-carbon metal cabinet board paint and preparation method thereof |
| CN103555188A (en) * | 2013-10-18 | 2014-02-05 | 安徽蓝柯复合材料有限公司 | UV (ultraviolet) photocuring paint and preparation method thereof |
| CN103555030A (en) * | 2013-10-28 | 2014-02-05 | 安徽明都电气有限公司 | Epoxy resin metallic paint and preparation method thereof |
| CN103555031A (en) * | 2013-10-28 | 2014-02-05 | 安徽明都电气有限公司 | Antiseptic and antirust epoxy resin paint and preparation method thereof |
| CN103709904A (en) * | 2013-11-29 | 2014-04-09 | 广东千叶松化工有限公司 | UV oil solid color paint |
| CN107902962A (en) * | 2017-05-12 | 2018-04-13 | 国网浙江省电力公司湖州供电公司 | A kind of transmission line of electricity down conductor for being suitable for the quick preservative treatment in scene |
-
1999
- 1999-10-28 CN CN 99115612 patent/CN1294163A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100425741C (en) * | 2004-03-08 | 2008-10-15 | 中国印钞造币总公司 | Surface protection process for copper, aluminium alloy, steel-cored nickel coin and medal |
| CN100587014C (en) * | 2007-05-31 | 2010-02-03 | 捷伟实业有限公司 | Production method of active ecological paint |
| CN101245200B (en) * | 2008-03-12 | 2011-01-05 | 北京双燕商标彩印有限公司 | UV gloss oil, preparation method and application thereof |
| CN103122204A (en) * | 2013-02-05 | 2013-05-29 | 江苏宏泰高分子材料有限公司 | Solvent-free metal preservative UV (ultraviolet) paint and preparation method thereof |
| CN103122204B (en) * | 2013-02-05 | 2016-08-17 | 江苏宏泰高分子材料有限公司 | No-solvent type anti-corrosion of metal UV coating and preparation method thereof |
| CN103525273A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV (ultraviolet) coating with water drop effect and preparation method thereof |
| CN103555188A (en) * | 2013-10-18 | 2014-02-05 | 安徽蓝柯复合材料有限公司 | UV (ultraviolet) photocuring paint and preparation method thereof |
| CN103540241A (en) * | 2013-10-18 | 2014-01-29 | 安徽蓝柯复合材料有限公司 | Ultraviolet-curing primer wood coating and preparation method thereof |
| CN103540225A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Electrical cabinet anti-corrosive base coat and preparation method thereof |
| CN103555030A (en) * | 2013-10-28 | 2014-02-05 | 安徽明都电气有限公司 | Epoxy resin metallic paint and preparation method thereof |
| CN103555031A (en) * | 2013-10-28 | 2014-02-05 | 安徽明都电气有限公司 | Antiseptic and antirust epoxy resin paint and preparation method thereof |
| CN103540226A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Low-carbon metal cabinet board paint and preparation method thereof |
| CN103709904A (en) * | 2013-11-29 | 2014-04-09 | 广东千叶松化工有限公司 | UV oil solid color paint |
| CN107902962A (en) * | 2017-05-12 | 2018-04-13 | 国网浙江省电力公司湖州供电公司 | A kind of transmission line of electricity down conductor for being suitable for the quick preservative treatment in scene |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BB1A | Publication of application | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |