CN110190037A - Preparation method of heat sink, heat sink and mobile terminal - Google Patents
Preparation method of heat sink, heat sink and mobile terminal Download PDFInfo
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- CN110190037A CN110190037A CN201910473135.2A CN201910473135A CN110190037A CN 110190037 A CN110190037 A CN 110190037A CN 201910473135 A CN201910473135 A CN 201910473135A CN 110190037 A CN110190037 A CN 110190037A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 230000017525 heat dissipation Effects 0.000 claims abstract description 121
- 238000000576 coating method Methods 0.000 claims abstract description 82
- 239000011248 coating agent Substances 0.000 claims abstract description 77
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 44
- 239000006185 dispersion Substances 0.000 claims abstract description 39
- 239000002131 composite material Substances 0.000 claims abstract description 35
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000011230 binding agent Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 8
- 239000012459 cleaning agent Substances 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000004381 surface treatment Methods 0.000 claims description 5
- 239000012670 alkaline solution Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 14
- 238000013021 overheating Methods 0.000 abstract description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 7
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229960003964 deoxycholic acid Drugs 0.000 description 1
- KXGVEGMKQFWNSR-LLQZFEROSA-N deoxycholic acid Chemical compound C([C@H]1CC2)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(O)=O)C)[C@@]2(C)[C@@H](O)C1 KXGVEGMKQFWNSR-LLQZFEROSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005007 epoxy-phenolic resin Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/367—Cooling facilitated by shape of device
- H01L23/3672—Foil-like cooling fins or heat sinks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3735—Laminates or multilayers, e.g. direct bond copper ceramic substrates
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/2039—Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
- H05K7/20409—Outer radiating structures on heat dissipating housings, e.g. fins integrated with the housing
- H05K7/20427—Outer radiating structures on heat dissipating housings, e.g. fins integrated with the housing having radiation enhancing surface treatment, e.g. black coating
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
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Abstract
Description
技术领域technical field
本发明涉及产品制造技术领域,尤其涉及一种散热件的制备方法、散热件及移动终端。The invention relates to the technical field of product manufacturing, in particular to a method for preparing a heat sink, a heat sink and a mobile terminal.
背景技术Background technique
随着移动终端行业的不断发展,超薄化已经成为移动终端的发展方向之一。移动终端的超薄化就意味着移动终端内部的狭小空间内要容纳更多的元器件,而元器件工作时会产生大量的热,如果热量无法及时散出,就会导致移动终端工作时容易出现损坏。With the continuous development of the mobile terminal industry, ultra-thinning has become one of the development directions of the mobile terminal. The ultra-thinning of the mobile terminal means that more components must be accommodated in the small space inside the mobile terminal, and the components will generate a lot of heat when they work. If the heat cannot be dissipated in time, it will cause the mobile terminal to be easily Corruption occurs.
以移动终端的电路板上集成设置的多个芯片为例,随着移动终端的功能不断升级,这些芯片的功率也在不断增大,所产生的热量越来越高。为了防止芯片因温度过高而出现损坏,以及改善用户握持移动终端时的温感体验,可以在芯片周围增加散热结构,例如可以在电池盖或者主上支架上增加石墨散热膜,该石墨散热膜可以通过粘贴的方式固定到电池盖或者主上支架上。Taking the multiple chips integrated on the circuit board of the mobile terminal as an example, as the functions of the mobile terminal are continuously upgraded, the power of these chips is also increasing, and the heat generated is getting higher and higher. In order to prevent the chip from being damaged due to excessive temperature and improve the user's temperature experience when holding the mobile terminal, a heat dissipation structure can be added around the chip, for example, a graphite heat dissipation film can be added on the battery cover or the main upper bracket, and the graphite heat dissipation The membrane can be fixed to the battery cover or the main upper bracket by sticking.
然而,由于设置石墨散热膜的部分可能存在凹凸不平的结构,在该凹凸不平的结构处,石墨散热膜也会发生变形,导致石墨散热膜的散热效果变差,致使移动终端容易因过热而出现损坏。However, since the part where the graphite heat dissipation film is installed may have an uneven structure, the graphite heat dissipation film will also be deformed at the uneven structure, resulting in the deterioration of the heat dissipation effect of the graphite heat dissipation film, causing the mobile terminal to easily appear due to overheating. damage.
发明内容Contents of the invention
本发明公开一种散热件的制备方法、散热件及移动终端,以解决移动终端容易因过热而出现损坏的问题。The invention discloses a method for preparing a heat sink, a heat sink and a mobile terminal, so as to solve the problem that the mobile terminal is easily damaged due to overheating.
为了解决上述问题,本发明采用下述技术方案:In order to solve the above problems, the present invention adopts the following technical solutions:
一种散热件的制备方法,所述制备方法包括:A method for preparing a heat sink, the method comprising:
在所述散热件的待涂覆面上涂覆石墨烯复合分散液,所述石墨烯复合分散液包括石墨烯粉体、粘结剂和溶剂;Coating graphene composite dispersion liquid on the surface to be coated of described heat sink, described graphene composite dispersion liquid comprises graphene powder, binding agent and solvent;
对所述石墨烯复合分散液实施固化操作,以使所述散热件上形成散热涂层。A curing operation is performed on the graphene composite dispersion liquid, so that a heat dissipation coating is formed on the heat dissipation element.
一种散热件,所述散热件采用上述制备方法制备而成,所述散热件上设有散热涂层,所述散热涂层采用石墨烯粉体、粘结剂和溶剂混合形成的石墨烯复合分散液制成。A heat dissipation piece, the heat dissipation piece is prepared by the above-mentioned preparation method, the heat dissipation coating is provided on the heat dissipation piece, and the heat dissipation coating is a graphene composite formed by mixing graphene powder, a binder and a solvent The dispersion is made.
一种移动终端,所述移动终端包括主板以及上述散热件,所述散热件包括主上支架、电池盖、主板上屏蔽盖、主板下屏蔽盖和显示屏中的至少一者,其中,所述主板位于所述电池盖和所述主上支架之间,所述主板上屏蔽盖和所述主板下屏蔽盖分别设置于所述主板的两侧表面上。A mobile terminal, the mobile terminal includes a main board and the above-mentioned heat sink, the heat sink includes at least one of a main upper bracket, a battery cover, a shield cover on the main board, a shield cover under the main board, and a display screen, wherein the The main board is located between the battery cover and the main upper bracket, and the main board upper shielding cover and the main main board lower shielding cover are respectively arranged on two side surfaces of the main board.
本发明采用的技术方案能够达到以下有益效果:The technical scheme adopted in the present invention can achieve the following beneficial effects:
采用本发明公开的制备方法制成的散热件的表面设有散热涂层,该散热涂层采用石墨烯复合分散液制成,由于所采用的工艺是涂覆工艺,因此即使散热件的表面存在凹凸不平的结构,也可以实现散热涂层与该凹凸不平的结构之间的充分贴合,使得散热涂层不容易发生变形,进而改善散热涂层的散热效果,使得移动终端不容易因过热而出现损坏。The surface of the heat sink made by the preparation method disclosed in the present invention is provided with a heat dissipation coating, which is made of graphene composite dispersion. Since the adopted process is a coating process, even if there is The uneven structure can also achieve a sufficient fit between the heat dissipation coating and the uneven structure, so that the heat dissipation coating is not easy to deform, thereby improving the heat dissipation effect of the heat dissipation coating, making it difficult for the mobile terminal to be damaged due to overheating. Corruption occurs.
附图说明Description of drawings
此处所说明的附图用来提供对本发明的进一步理解,构成本发明的一部分,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings described here are used to provide a further understanding of the present invention, and constitute a part of the present invention. The schematic embodiments of the present invention and their descriptions are used to explain the present invention, and do not constitute improper limitations to the present invention. In the attached picture:
图1为本发明实施例公开的制备方法的流程示意图;Fig. 1 is a schematic flow diagram of the preparation method disclosed in the embodiment of the present invention;
图2为本发明另一实施例公开的制备方法的流程示意图;2 is a schematic flow diagram of a preparation method disclosed in another embodiment of the present invention;
图3为本发明实施例公开的移动终端的部分结构的示意图;FIG. 3 is a schematic diagram of a partial structure of a mobile terminal disclosed in an embodiment of the present invention;
图4为本发明另一实施例公开的移动终端的部分结构的示意图;FIG. 4 is a schematic diagram of a partial structure of a mobile terminal disclosed in another embodiment of the present invention;
图5为本发明又一实施例公开的移动终端的部分结构的示意图;FIG. 5 is a schematic diagram of a partial structure of a mobile terminal disclosed in another embodiment of the present invention;
图6为本发明再一实施例公开的移动终端的部分结构的示意图。Fig. 6 is a schematic diagram of a partial structure of a mobile terminal disclosed in yet another embodiment of the present invention.
附图标记说明:Explanation of reference signs:
110-主板、120-主上支架、130-电池盖、140-主板上屏蔽盖、150-主板下屏蔽盖、160-芯片、170-导热部、200-散热涂层。110-Main board, 120-Main upper bracket, 130-Battery cover, 140-Mainboard upper shielding cover, 150-Mainboard lower shielding cover, 160-Chip, 170-Heat conducting part, 200-Heat dissipation coating.
具体实施方式Detailed ways
为使本发明的目的、技术方案和优点更加清楚,下面将结合本发明具体实施例及相应的附图对本发明技术方案进行清楚、完整地描述。显然,所描述的实施例仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose, technical solution and advantages of the present invention clearer, the technical solution of the present invention will be clearly and completely described below in conjunction with specific embodiments of the present invention and corresponding drawings. Apparently, the described embodiments are only some of the embodiments of the present invention, but not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
以下结合附图,详细说明本发明各个实施例公开的技术方案。The technical solutions disclosed by various embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings.
本发明实施例公开一种散热件的制备方法,该散热件可以是移动终端的一部分。需要说明的是,如图3所示,该散热件可以包括主上支架120、电池盖130、主板上屏蔽盖140、主板下屏蔽盖150和显示屏中的至少一者,移动终端还包括主板110,该主板110位于电池盖130和主上支架120之间,主板上屏蔽盖140和主板下屏蔽盖150分别设置于主板110的两侧表面上。当然,散热件并不限于这里提到的部件,也可以是其他的发热部件或者发热部件周围的部件,例如散热件还可以包括副板上设置的屏蔽盖、扬声器等部件。The embodiment of the present invention discloses a method for preparing a heat sink, and the heat sink may be a part of a mobile terminal. It should be noted that, as shown in FIG. 3 , the heat sink may include at least one of the main upper bracket 120, the battery cover 130, the upper shielding cover 140 of the main board, the lower shielding cover 150 of the main board and the display screen, and the mobile terminal also includes a main board 110 , the main board 110 is located between the battery cover 130 and the main upper bracket 120 , and the main board upper shielding cover 140 and the main board lower shielding cover 150 are respectively arranged on the two side surfaces of the main board 110 . Certainly, the heat sink is not limited to the components mentioned here, and may also be other heat-generating components or components around the heat-generating components. For example, the heat sink may also include shielding covers, speakers and other components arranged on the sub-board.
如图1所示,本发明实施例公开的制备方法具体可以包括:As shown in Figure 1, the preparation method disclosed in the embodiment of the present invention may specifically include:
S100、在散热件的待涂覆面上涂覆石墨烯复合分散液,该石墨烯复合分散液包括石墨烯粉体、粘结剂和溶剂。S100. Coat the graphene composite dispersion liquid on the surface to be coated of the heat sink. The graphene composite dispersion liquid includes graphene powder, a binder and a solvent.
散热件的待涂覆面可以是散热件的局部表面,也可以是散热件的全部表面,可以是散热件的单侧表面,也可以是散热件的两侧表面。例如,当散热件包括主上支架120时,如图3所示,该待涂覆面可以包括主上支架120背离主板110的一侧表面以及主上支架120朝向主板110的一侧表面中的至少一者;当散热件包括主板上屏蔽盖140时,如图4所示,该待涂覆面可以是主板上屏蔽盖140背离主板110的一侧表面;当散热件包括主板下屏蔽盖150时,如图4所示,该待涂覆面可以是主板下屏蔽盖150背离主板110的一侧表面;当散热件包括电池盖130时,如图5所示,该待涂覆面可以是电池盖130朝向主板110的一侧表面。具体实施例中,这里所述的各种方式可以自由组合,以达到更好的效果,具体可以参考图6所示结构。The surface to be coated of the heat sink can be a partial surface of the heat sink, or the entire surface of the heat sink, can be a single side surface of the heat sink, or can be both sides of the heat sink. For example, when the heat sink includes the main upper bracket 120, as shown in FIG. One; when the heat sink includes the shield cover 140 on the main board, as shown in Figure 4, the surface to be coated can be the side surface of the shield cover 140 on the main board away from the main board 110; when the heat sink includes the shield cover 150 under the main board, As shown in Figure 4, the surface to be coated can be the side surface of the lower shielding cover 150 of the main board away from the main board 110; One side surface of the motherboard 110 . In a specific embodiment, the various ways described here can be freely combined to achieve better effects, for details, refer to the structure shown in FIG. 6 .
石墨烯粉体可以经过分散改性处理,以便于该石墨烯粉体与粘结剂和溶剂混合后,最终可以形成层状结构。石墨烯复合分散液可以是离子型分散液,也可以是非离子型分散液。当石墨烯复合分散液为离子型分散液时,所采用的分散剂可以是十二烷基苯磺酸钠(sodium dodecyl benzene sulfonate,SDBS)和脱氧胆酸钠,对应的溶剂为碱性溶液,例如氢氧化钾+硝酸钠+高锰酸钾所形成的混合溶液。当石墨烯复合分散液为非离子型分散液时,所采用的分散剂可以是聚乙烯吡咯烷酮(polyvinyl pyrrolidone,PVP),对应的溶剂可以是二甲基甲酰胺溶剂(N,N-Dimethylformamide,DMF)、N-甲基吡咯烷酮溶剂(N-Methylpyrrolidone,NMP)或者乙醇溶剂。这里所提到的溶剂本身可以含有粘接剂,使其具有一定的粘性,如果要提升粘接性能,还可以额外增加粘结剂。粘结剂具体可以是环氧树脂、酚醛树脂等。The graphene powder can be dispersed and modified so that the graphene powder can finally form a layered structure after being mixed with a binder and a solvent. The graphene composite dispersion liquid can be an ionic dispersion liquid or a non-ionic dispersion liquid. When the graphene composite dispersion liquid is an ionic dispersion liquid, the dispersant used can be sodium dodecylbenzene sulfonate (sodium dodecyl benzene sulfonate, SDBS) and sodium deoxycholate, and the corresponding solvent is an alkaline solution, For example, a mixed solution formed of potassium hydroxide + sodium nitrate + potassium permanganate. When the graphene composite dispersion liquid is a non-ionic dispersion liquid, the dispersant used can be polyvinylpyrrolidone (polyvinyl pyrrolidone, PVP), and the corresponding solvent can be a dimethylformamide solvent (N, N-Dimethylformamide, DMF ), N-methylpyrrolidone solvent (N-Methylpyrrolidone, NMP) or ethanol solvent. The solvent mentioned here can itself contain a binder to make it sticky to a certain extent. If the adhesive performance is to be improved, an additional binder can be added. Specifically, the binder may be epoxy resin, phenolic resin or the like.
S110、对石墨烯复合分散液实施固化操作,以使散热件上形成散热涂层200。S110 , performing a solidification operation on the graphene composite dispersion, so that a heat dissipation coating 200 is formed on the heat dissipation element.
也就是说,涂覆在散热件上的石墨烯复合分散液固化后即成为散热涂层200,该散热涂层200具有优异的导热率,因此其散热性能更优。具体地,该散热涂层200在水平方向上的导热系数可达1400~2000W/m·K,垂直方向的导热系数可达15~20W/m·K,优于现有的石墨散热膜。That is to say, the graphene composite dispersion coated on the heat dissipation element becomes the heat dissipation coating 200 after solidification, and the heat dissipation coating 200 has excellent thermal conductivity, so its heat dissipation performance is better. Specifically, the thermal conductivity of the heat dissipation coating 200 in the horizontal direction can reach 1400-2000 W/m·K, and the thermal conductivity in the vertical direction can reach 15-20 W/m·K, which is superior to the existing graphite heat dissipation film.
采用本发明公开的制备方法时,散热件的表面形成散热涂层200,该散热涂层200采用石墨烯复合分散液制成,由于所采用的工艺是涂覆工艺,因此即使散热件的表面存在凹凸不平的结构,也可以实现散热涂层200与该凹凸不平的结构之间的充分贴合,使得散热涂层200不容易发生变形,进而改善散热涂层200的散热效果,使得移动终端不容易因过热而出现损坏。When the preparation method disclosed in the present invention is adopted, a heat dissipation coating 200 is formed on the surface of the heat sink, and the heat dissipation coating 200 is made of a graphene composite dispersion. The uneven structure can also achieve sufficient bonding between the heat dissipation coating 200 and the uneven structure, so that the heat dissipation coating 200 is not easily deformed, thereby improving the heat dissipation effect of the heat dissipation coating 200, making it difficult for the mobile terminal Damage due to overheating.
同时,本发明实施例中所形成的散热涂层200的厚度更薄,该散热涂层200所占用的空间更小,因此更有利于实现移动终端向更薄的方向发展。具体地,该散热涂层200的厚度约0.01mm,小于现有的石墨散热膜。另外,散热涂层200通过涂覆工艺形成于散热件的表面,因此该散热涂层200与散热件之间所形成的结合力较大,散热涂层200不容易与散热件分离,以此防止散热涂层200脱离散热件后造成线路短路问题;同样,由于散热涂层200通过涂覆工艺形成于散热件的表面,因此该散热涂层200对于散热件的形状、平整度等基本没有要求,因此该散热涂层200可以适用于多种散热件,其适用范围更广。此外,此种散热涂层200的成本较低。At the same time, the thickness of the heat dissipation coating 200 formed in the embodiment of the present invention is thinner, and the space occupied by the heat dissipation coating 200 is smaller, so it is more conducive to the development of a thinner mobile terminal. Specifically, the heat dissipation coating 200 has a thickness of about 0.01mm, which is smaller than the existing graphite heat dissipation film. In addition, the heat dissipation coating 200 is formed on the surface of the heat dissipation element through a coating process, so the bonding force formed between the heat dissipation coating 200 and the heat dissipation element is relatively large, and the heat dissipation coating 200 is not easy to separate from the heat dissipation element, thereby preventing After the heat dissipation coating 200 is separated from the heat sink, the problem of circuit short circuit is caused; similarly, since the heat dissipation coating 200 is formed on the surface of the heat sink through the coating process, the heat dissipation coating 200 has basically no requirements for the shape and flatness of the heat sink. Therefore, the heat dissipation coating 200 can be applied to various heat dissipation elements, and its application range is wider. In addition, the cost of this heat dissipation coating 200 is relatively low.
如图2所示,一种可选的实施例中,前文所述的步骤S100之前还可以包括:As shown in FIG. 2, in an optional embodiment, before step S100 described above, it may also include:
S101、对散热件的待涂覆面进行表面处理。S101 , performing surface treatment on the surface to be coated of the heat sink.
这里进行表面处理的目的是,为石墨烯复合分散液与散热件的结合提供更优良的条件,例如该表面处理可以实现待涂覆面的清洁、打磨等等处理内容。可选地,考虑到待涂覆面的清洁度对石墨烯复合分散液与散热件的结合具有至关重要的影响,因此该步骤具体包括:采用清洗剂对散热件的待涂覆面进行浸泡和清洗,该清洗剂包括乙醇、丙酮、碱性溶液中的至少一种,当然,也可以包括其他具有清洗功能的物质。经过清洗后,散热件的待涂覆面上的杂质、油污等物质可以被清理掉,从而使得散热件与石墨烯复合分散液之间的结合更充分。The purpose of the surface treatment here is to provide better conditions for the combination of the graphene composite dispersion and the heat sink, for example, the surface treatment can realize the cleaning, grinding and other treatment content of the surface to be coated. Optionally, considering that the cleanliness of the surface to be coated has a crucial impact on the combination of the graphene composite dispersion and the heat sink, this step specifically includes: using a cleaning agent to soak and clean the surface to be coated of the heat sink , the cleaning agent includes at least one of ethanol, acetone, and alkaline solution, and of course, other substances with cleaning functions may also be included. After cleaning, impurities, oil stains and other substances on the surface to be coated of the heat sink can be removed, so that the combination between the heat sink and the graphene composite dispersion is more sufficient.
进一步的实施例中,如图2所示,步骤S110之后还可以包括:In a further embodiment, as shown in FIG. 2, after step S110, it may also include:
S120、对散热涂层200进行净化处理。S120 , performing purification treatment on the heat dissipation coating 200 .
经过固化的散热涂层200表面可能也会吸附有杂质、油污等物质,并且该散热涂层200通常存在异味,所以对该散热涂层200进行净化处理,不仅可以实现散热涂层200的表面清洁,还可以去除散热涂层200的异味,使得用户使用移动终端时的体验更好。The surface of the cured heat dissipation coating 200 may also be adsorbed with impurities, oil and other substances, and the heat dissipation coating 200 usually has peculiar smell, so purifying the heat dissipation coating 200 can not only clean the surface of the heat dissipation coating 200 , can also remove the peculiar smell of the heat dissipation coating 200, so that the user experience when using the mobile terminal is better.
可选地,为了优化对散热涂层200进行清洗的效果,上述步骤S120具体可以包括:采用清洗剂对散热涂层200进行浸泡和清洗,该清洗剂包括乙醇、丙酮、碱性溶液中的至少一种,当然,也可以包括其他具有清洗功能的物质。需要说明的是,对散热涂层200进行清洗时,由于散热件已经与散热涂层200结合为一体,因此这时实际上是将散热件和散热涂层200同时进行浸泡和清洗。Optionally, in order to optimize the effect of cleaning the heat dissipation coating 200, the above step S120 may specifically include: soaking and cleaning the heat dissipation coating 200 with a cleaning agent, the cleaning agent includes at least One, of course, can also include other substances that have a cleaning function. It should be noted that when cleaning the heat dissipation coating 200 , since the heat dissipation element has been integrated with the heat dissipation coating 200 , the heat dissipation element and the heat dissipation coating 200 are actually soaked and cleaned at the same time.
对石墨烯复合分散液实施固化操作的具体方式有很多种,为了提升固化效果,可选地,对石墨烯复合分散液实施固化操作具体包括:采用烘烤工艺对石墨烯复合分散液实施固化操作。一种具体的实施例中,对散热件和石墨烯复合分散液进行烘烤时,烘烤温度可以设置为90℃左右,烘烤过程中需要惰性气体保护,烘烤时间设置为约24小时。如此设置后,石墨烯复合分散液中的水分将充分挥发,使得石墨烯复合分散液更牢固地固化在散热件的表面上。There are many specific ways to implement the curing operation on the graphene composite dispersion. In order to improve the curing effect, optionally, the implementation of the curing operation on the graphene composite dispersion specifically includes: implementing a curing operation on the graphene composite dispersion using a baking process . In a specific embodiment, when the heat sink and the graphene composite dispersion are baked, the baking temperature can be set at about 90° C., an inert gas protection is required during the baking process, and the baking time is set at about 24 hours. After setting in this way, the water in the graphene composite dispersion will be fully volatilized, so that the graphene composite dispersion will be more firmly solidified on the surface of the heat sink.
基于上述任一实施例所述的制备方法,本发明实施例还公开一种散热件,该散热件采用上述任一实施例所述的制备方法制备而成。如图3-图6所示,该散热件上设有散热涂层200,该散热涂层200采用石墨烯粉体、粘结剂和溶剂混合形成的石墨烯复合分散液制成。参考前文所述的内容,该散热涂层200的散热效果更好,且其占用的空间更小、使用范围更广,因此采用该散热涂层200后,移动终端中大部分的部件上均可以成型该散热涂层200,使其不容易因过热而损坏,用户握持该移动终端时的体验更佳,并且该移动终端的厚度可以设置得更小。Based on the preparation method described in any of the above embodiments, the embodiment of the present invention also discloses a heat sink, which is prepared by using the preparation method described in any of the above embodiments. As shown in FIGS. 3-6 , the heat dissipation element is provided with a heat dissipation coating 200 , and the heat dissipation coating 200 is made of a graphene composite dispersion formed by mixing graphene powder, a binder and a solvent. With reference to the foregoing, the heat dissipation coating 200 has a better heat dissipation effect, occupies a smaller space, and has a wider application range. Therefore, after using the heat dissipation coating 200, most of the components in the mobile terminal can be used. The heat dissipation coating 200 is shaped so that it is not easily damaged due to overheating, the user's experience when holding the mobile terminal is better, and the thickness of the mobile terminal can be set smaller.
如前文所述,散热件的待涂覆面可以是散热件的局部表面,也可以是散热件的全部表面,采用这两种设置方式时,散热涂层200覆盖散热件的面积不同,进而所产生的散热效果也存在差异。为了进一步提升散热涂层200的散热效果,散热涂层200的边缘可以与散热件的边缘相平齐。换言之,散热涂层200尽量覆盖散热件可以设置散热涂层200的表面的全部,使得散热涂层200的设置面积更大,进而达到更好的散热效果。As mentioned above, the surface to be coated of the heat sink can be a partial surface of the heat sink or the entire surface of the heat sink. When these two arrangements are adopted, the area covered by the heat sink coating 200 is different, and the resulting There are also differences in the cooling effect. In order to further improve the heat dissipation effect of the heat dissipation coating 200, the edge of the heat dissipation coating 200 may be flush with the edge of the heat dissipation element. In other words, the heat dissipation coating 200 covers as much as possible the entire surface of the heat dissipation element where the heat dissipation coating 200 can be disposed, so that the disposition area of the heat dissipation coating 200 is larger, thereby achieving a better heat dissipation effect.
可选的实施例中,散热件的同一侧表面所形成的散热涂层200的层数可以是一层、两层、三层甚至更多层,当散热涂层200的层数增加时,各散热涂层200所带来的散热效果更好,因此,为了改善散热效果,可以在散热件的同一侧表面设置至少两层散热涂层200。但是,散热涂层200的层数增加时,各散热涂层200的厚度也会随之叠加,故散热件的同一侧表面所形成的散热涂层200的层数可以设置为两层或者三层,使得散热涂层200的散热效果得到改善,同时不会占用过大的空间。In an optional embodiment, the number of layers of the heat dissipation coating 200 formed on the same side surface of the heat dissipation element can be one, two, three or even more layers. When the number of layers of the heat dissipation coating 200 increases, each The heat dissipation effect brought by the heat dissipation coating 200 is better. Therefore, in order to improve the heat dissipation effect, at least two layers of heat dissipation coating 200 can be arranged on the same side surface of the heat dissipation element. However, when the number of layers of the heat dissipation coating 200 increases, the thicknesses of the heat dissipation coatings 200 will also superimpose thereupon, so the number of layers of the heat dissipation coating 200 formed on the surface of the same side of the heat dissipation element can be set to two or three layers. , so that the heat dissipation effect of the heat dissipation coating 200 is improved without occupying too much space.
基于上述任一实施例所述的散热件,本发明实施例还公开一种移动终端,该移动终端包括主板110以及上述任一实施例所述的散热件。Based on the heat dissipation element described in any one of the above embodiments, an embodiment of the present invention further discloses a mobile terminal, which includes a main board 110 and the heat dissipation element described in any one of the above embodiments.
可选地,移动终端的主板110上设置有多个芯片160,为了更大程度地散去芯片160工作时所产生的热量,可以在芯片160上粘贴导热部170,该导热部170具体可以包括导热凝胶或者硅胶等结构,该导热部170具有散热能力,进而实现芯片160散热。此时,主板上屏蔽盖140与一部分芯片160和导热部170接触,主板下屏蔽盖150与另一部分芯片160和导热部170接触,因此在主板上屏蔽盖140和主板下屏蔽盖150上增加散热涂层200时,散热涂层200可以辅助导热部170散热,使得芯片160的温度可以保持在较低的范围内。Optionally, the motherboard 110 of the mobile terminal is provided with a plurality of chips 160. In order to dissipate the heat generated by the chips 160 during operation to a greater extent, a heat conduction part 170 can be pasted on the chip 160. The heat conduction part 170 can specifically include Structures such as thermally conductive gel or silica gel, the thermally conductive part 170 has a heat dissipation capability, thereby realizing heat dissipation of the chip 160 . At this time, the shielding cover 140 on the motherboard is in contact with a part of the chips 160 and the heat conduction part 170, and the shielding cover 150 under the motherboard is in contact with another part of the chips 160 and the heat conduction part 170, so the heat dissipation is increased on the shielding cover 140 on the motherboard and the shielding cover 150 under the motherboard. When the coating 200 is used, the heat dissipation coating 200 can assist the heat conduction part 170 to dissipate heat, so that the temperature of the chip 160 can be kept in a lower range.
本发明实施例所公开的移动终端可以为智能手机、平板电脑、电子书阅读器或可穿戴设备。当然,该移动终端也可以是其他设备,本发明实施例对此不做限制。The mobile terminal disclosed in the embodiment of the present invention may be a smart phone, a tablet computer, an e-book reader or a wearable device. Certainly, the mobile terminal may also be other devices, which is not limited in this embodiment of the present invention.
本发明上文实施例中重点描述的是各个实施例之间的不同,各个实施例之间不同的优化特征只要不矛盾,均可以组合形成更优的实施例,考虑到行文简洁,在此则不再赘述。The above-mentioned embodiments of the present invention focus on the differences between the various embodiments. As long as the different optimization features of the various embodiments do not contradict each other, they can be combined to form a better embodiment. Considering the brevity of the text, here No longer.
以上所述仅为本发明的实施例而已,并不用于限制本发明。对于本领域技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原理之内所作的任何修改、等同替换、改进等,均应包含在本发明的权利要求范围之内。The above descriptions are only examples of the present invention, and are not intended to limit the present invention. Various modifications and variations of the present invention will occur to those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the scope of the claims of the present invention.
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CN111549338A (en) * | 2020-05-19 | 2020-08-18 | 江苏江南烯元石墨烯科技有限公司 | Graphene heat dissipation film and preparation method thereof |
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Application publication date: 20190830 |