CN1195369A - Concentrated stable fabric softening composition - Google Patents

Abstract

The present invention discloses primary solvents, especially monoalcohol and diol primary solvents having a ClogP value of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, and more preferably from about 0.40 to about 0.60, which can be prepared at relatively high concentrations and at Transparent aqueous fabric softener compositions of fabric softener actives having ester linkages in their long hydrophobic chains. The fabric softener active is either unsaturated or has a medium chain length (~C _12-14 ), and the primary solvent is used in an amount of less than about 40%. Other solvents may be present. Some of said primary solvents are novel compounds and/or novel mixtures. To eliminate/limit the need for heating, a premix of fabric softening active, primary solvent, and optionally other solvents can be used to prepare the complete formulation.

Description

Concentrated and stabilized fabric softening compositions

This application is a continuation-in-part of the following 13 of our pending US patent applications: 08/621019; 08/620627; 08/620767; 08/620513; 08/621285; 08/620625; 08/620772; 08/621281; 08/620514; combination".

technical field

The present invention relates to preferably translucent, or more preferably clear, aqueous concentrated liquid softening compositions for softening laundry. In particular, the present invention relates to fabric softening compositions for use in the rinse cycle of fabric laundering operations to obtain excellent fabric softening/static control benefits, which compositions are characterized by, for example, reduced fabric staining, excellent water dispersibility, Rewettability, and/or storage and viscosity stability at temperatures below normal temperature, ie below normal room temperature, eg, 25°C.

Background of the invention

The prior art reveals problems associated with formulating and producing clear concentrated fabric conditioning formulations. For example, EP 404471, Machin et al., published December 27, 1990, teaches homogeneous liquid softening compositions containing at least 20% by weight softener and at least 5% by weight short chain organic acids.

Fabric softening compositions containing high levels of solvents are known in the art. However, softeners can form clumps and can deposit on garments, which can cause staining and reduce softening performance. The composition may also thicken and/or settle at lower temperatures, ie, at temperatures from about 40°F (about 4°C) to about 65°F (about 18°C). These compositions are also expensive to the consumer due to the high levels of solvents required to prepare concentrated and clear products.

The present invention provides concentrated aqueous liquid fabric treatment compositions having a low organic solvent content (i.e., less than about 40% by weight of the composition) at normal temperatures, i.e. at room temperature and below normal temperatures improved stability (ie, remain clear or translucent, and do not precipitate, gel, thicken, or solidify) under prolonged storage conditions. Said compositions also provide reduced fabric staining, excellent cold water dispersibility, and excellent softness, antistatic and fabric rewet properties, as well as reduced dispersant residue accumulation and excellent freeze-thaw restorative properties.

It is an object of the present invention to provide aqueous and concentrated, translucent or preferably clear rinse-added liquid fabric softening compositions which provide one or more benefits such as reduced staining on fabrics, ease in rinse water Dispersibility, phase stability at low temperature, and/or, preferably acceptable viscosity and viscosity stability at low temperature, and/or freeze recovery properties.

Summary of the invention

The compositions of the present invention comprise: A. from about 2% to about 80% by weight of the composition, preferably from about 13% to about 75%, more preferably from about 17% to about 70%, and even more preferably about 19 % to about 65% biodegradable fabric softener actives:

1. A softener having the following formula:

[(R) _4-m -N ⁽⁺⁾ -[(CH ₂ ) _n -YR ¹ ] _m ]X ^(-) (1)

wherein each R substituent is H or short chain C _1-6 , preferably C _1-3 alkyl or hydroxyalkyl, for example, methyl (most preferred), ethyl, propyl, hydroxyethyl, etc., benzyl , or mixtures thereof; each m is 2 or 3; each n is 1 to about 4, preferably 2; each Y is -O-(O)C-, -(R)N-(O)C- , -C(O)-N(R)-, or -C(O)-O-, preferably -O-(O)C-; the sum of the carbon numbers in each R ¹ , when Y is -O- (O)C- or -(R)N-(O)C-, the sum of the carbon numbers plus 1 (hereinafter, R ¹ and YR ¹ , "the sum of YR ¹ " can be used interchangeably to represent the hydrophobic chain, The chain length of R ¹ is usually counted by even fatty alcohols and amines and odd fatty acids), is C _6-22 , preferably C _14-20 , but only one YR ¹ sums less than about 12 and the other YR ¹ sums at least about 16 , wherein each R ¹ is a long chain C _6-22 (or C _5-21 ) hydrocarbon group, or a substituted hydrocarbon group substituent, preferably a C _10-20 (or C _{9- 19} ) alkyl or alkenyl group ( unsaturated alkyl, including polyunsaturated alkyl, sometimes referred to as "alkylene"), most preferably C _12-18 (or C _11-17 ) alkyl or alkenyl, and wherein, when the carbon When the sum of the numbers is C _16-18 and R ¹ is a linear group, the iodine value (hereinafter referred to as IV) of the parent fatty acid of the R ¹ group is preferably from about 20 to about 140, more preferably from about 50 to about 130; most preferably from about 70 to about 115 (as used herein, the iodine value of the "parent" fatty acid or the "corresponding" fatty acid is used to define the degree of unsaturation of the ^R group, which is the same as that containing The degree of unsaturation present in the fatty acid of the same ^R group is the same); wherein the counter ion X ^- can be any anion that can be compatible with the softener, preferably chloride, bromide, methyl sulfate, ethyl sulfate, Sulfates, and nitrates, more preferably chlorides;

其中Y，R，R¹，和X^(-)各自具有与前述相同的含义(该化合物包括具有下式的化合物：2. A softener having the formula:

Wherein Y, R, R ¹ , and X ^(-) each have the same meaning as described above (the compound includes compounds of the following formula:

[CH ₃ ] ₃ N ⁽⁺⁾ [CH ₂ CH(CH ₂ O(O)CR ¹ )O(O)CR ¹ ]Cl ^(-) where C(O)R ¹ is derived from an unsaturated fatty acid such as oleic acid, Preferably each R is a methyl or ethyl group, preferably each ^R is in the range _C15-19 and is branched, with substituents optionally present in the alkyl chain); and

3. Their mixtures;

[In a preferred biodegradable quaternary ammonium fabric softening compound, -(O)CR ¹ is derived from unsaturated fatty acids, e.g., oleic acid, and/or fatty acids and/or partially hydrogenated fatty acids, from vegetable oils and/or Derived from partially hydrogenated vegetable oils such as canola oil; safflower oil; peanut oil; sunflower oil; soybean oil, corn oil, tall oil; rice bran oil, etc. In another preferred biodegradable quaternary ammonium fabric softening compound, -(O)CR ¹ is saturated (iodine number preferably 10 or less, more preferably less than about 5) C _8-14 , preferably C _{12 - 14} hydrocarbyl, or substituted hydrocarbyl substituents derived from, for example, coconut oil]. [As used hereinafter, these biodegradable fabric softener actives containing ester linkages are referred to as "DEQA" and include diesters, triesters, and monoester compounds. Corresponding amide softener actives and mixed ester-amide softener actives may also contain from 1 to 3, preferably 2, long chain hydrophobic groups. Preferred fabric softener actives are characterized in that they can be processed by conventional mixing methods at room temperature in the presence of at least about 15% of solvent C as disclosed hereinafter]. B. Less than about 40%, preferably from about 10% to about 35%, more preferably from about 12% to about 25%, and even more preferably from about 14% to about 20%, by weight of the composition, of a primary solvent having about 0.15 to about 0.64, preferably about 0.25 to about 0.62, and more preferably 0.40 to about 0.60 ClogP value, the main solvent contains a deficient amount of a solvent selected from the group consisting of 2,2,4-trimethyl-1, 3-pentanediol; ethoxylate, diethoxylate, or triethoxylate derivatives of 2,2,4-trimethyl-1,3-pentanediol; and/or 2-ethanediol -1,3-Hexanediol, and/or mixtures thereof, are used to obtain a clear product, are preferably used in an insufficient amount to obtain a stable product, and are more preferably used in an insufficient amount to obtain discernible physical characteristics In varying compositions, especially completely free of them, the main solvent is preferably selected from: I. Monohydric alcohols comprising:

a. n-propanol; and/or

b. 2-butanol and/or 2-methyl-2-propanol; II. Including the following hexanediol isomers: 2,3-dimethyl-2,3-butanediol; 2,3- Dimethyl-1,2-butanediol; 3,3-dimethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3- pentanediol; 4-methyl-2,3-pentanediol; 2,3-hexanediol; 3,4-hexanediol; 2-ethyl-1,2-butanediol; 2-methyl -1,2-pentanediol; 3-methyl-1,2-pentanediol; 4-methyl-1,2-pentanediol; and/or 1,2-hexanediol; III. includes the following Heptanediol isomers: 2-butyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2-(1-methylpropyl)-1,3-propanediol; 2-(2-Methylpropyl)-1,3-propanediol; 2-methyl-2-propyl-1,3-propanediol; 2,3,3-trimethyl-1,2-butanediol ;2-Ethyl-2-methyl-1,4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-propyl-1,4-butanediol; 2-isopropyl-1,4-butanediol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4- Dimethyl-1,5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl Base-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl- 3,4-pentanediol; 2-ethyl-1,5-pentanediol; 2-methyl-1,6-hexanediol; 3-methyl-1,6-hexanediol; 2-methyl Base-2,3-hexanediol; 3-methyl-2,3-hexanediol; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2 -Methyl-3,4-hexanediol; 3-methyl-3,4-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; and /or 1,6-heptanediol; IV. Including the following isomers of octanediol: 2-(2-methylbutyl)-1,3-propanediol; 2-(1,1-dimethylpropane base)-1,3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(1 -methylbutyl)-1,3-propanediol; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2-(3-methylbutyl)-1,3-propanediol; 2-butyl-2-methyl-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1,3-propanediol; 2 -Methyl-2-(1-methylpropyl)-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl-2 -Methyl-1,3-propanediol; 2,2-diethyl-1,3-butanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-butyl- 1,3-butanediol; 2-ethyl-2,3-dimethyl-1,3-butanediol; 2-(1,1-dimethylethyl)-1,3-butanediol ; 2-(2-methylpropyl)-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 2-methyl-2-propyl-1 , 3-butanediol; 3-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethylene Base-1,4-butanediol; 2-methyl-2-propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2-ethane Base-2,3-dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1-dimethylethyl base)-1,4-butanediol; 2-(2-methylpropyl)-1,4-butanediol; 2-methyl-3-propyl-1,4-butanediol; 3- Methyl-2-isopropyl-1,4-butanediol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol Diol; 2,3,4-Trimethyl-1,3-pentanediol; 2,4,4-Trimethyl-1,3-pentanediol; 3,4,4-Trimethyl-1 , 3-pentanediol; 2,2,3-trimethyl-1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3-tri Methyl-1,4-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 3,3,4-trimethyl-1,4-pentanediol; 2,2 , 3-trimethyl-1,5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-1,5-pentanediol ;2,3,4-Trimethyl-1,5-pentanediol; 2,3,3-Trimethyl-2,4-pentanediol; 2,3,4-Trimethyl-2,4 -Pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 2-ethyl-4-methyl -1,3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl- 3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol; 3 -Ethyl-3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-3-methyl-1,5-pentanediol Diol; 2-ethyl-4-methyl-1,5-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2 , 4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2- Propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 2-isopropyl-1,5-pentanediol; 3-propyl-2,4-pentanediol Alcohol; 2,2-dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol; 4, 5-Dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol; 2,4- Dimethyl-1,4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl Base-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,4-dimethyl-1,3-hexanediol; 4,5-dimethyl- 1,4-hexanediol; 5,5-dimethyl-1,4-hexanediol; 2,2-dimethyl-1,5-hexanediol; 2,3-dimethyl-1, 5-hexanediol; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-1,5- Hexylene glycol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol Alcohol; 2,2-dimethyl-1,6-hexanediol; 2,3-dimethyl-1,6-hexanediol; 2,4-dimethyl-1,6-hexanediol; 2,5-dimethyl-1,6-hexanediol; 3,3-dimethyl-1,6-hexanediol; 3,4-dimethyl-1,6-hexanediol; 2, 3-Dimethyl-2,4-hexanediol; 2,4-dimethyl-2,4-hexanediol; 2,5-dimethyl-2,4-hexanediol; 3,3- Dimethyl-2,4-hexanediol; 3,4-dimethyl-2,4-hexanediol; 3,5-dimethyl-2,4-hexanediol; 4,5-dimethyl Base-2,4-hexanediol; 5,5-dimethyl-2,4-hexanediol; 2,3-dimethyl-2,5-hexanediol; 2,4-dimethyl- 2,5-hexanediol; 2,5-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,5-hexanediol; 3,4-dimethyl-2, 5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol; 4-ethyl-1,3-hexanediol; 2- Ethyl-1,4-hexanediol; 4-ethyl-1,4-hexanediol; 2-ethyl-1,5-hexanediol; 3-ethyl-2,4-hexanediol; 4-Ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-1,3-heptanediol; 3-methyl-1,3-heptanediol Alcohol; 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 2-methyl-1,4- Heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol; 5-methyl-1,4-heptanediol; 6-methyl-1, 4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4-methyl-1,5-heptanediol; 5-methyl- 1,5-heptanediol; 6-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl Base-1,6-heptanediol; 5-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol; 2-methyl-2,4-heptanediol; 3 -Methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol ;2-Methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol Diol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6 -Heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl-3 , 5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; and/or 3,6-octanediol; V. includes the following nonanediol isomers: 2,3,3,4-tetramethyl-2,4-pentanediol; 3-tert-butyl-2,4- Pentylene glycol; 2,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2,4-hexanediol; 3,3,5-trimethyl- 2,4-hexanediol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4- Trimethyl-2,5-hexanediol; and/or 3,3,5-trimethyl-2,5-hexanediol; VI. Including the following glyceryl ethers and/or di(hydroxyalkyl) ethers : 3-(n-pentyloxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3 -(2-methyl-1-butoxy)-1,2-propanediol; 3-(iso-pentyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy) -1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy) -1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1-butane oxy)-1,3-propanediol; 2-(iso-pentyloxy)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-( cyclohexyloxy)-1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; triethoxylated 3-(butoxy)-1,2 - propylene glycol; tetraethoxylated 3-(butoxy)-1,2-propanediol; pentaethoxylated 3-(butoxy)-1,2-propanediol; hexaethoxylated 3-(butoxy)-1,2-propanediol; -(butoxy)-1,2-propanediol; heptaethoxylated 3-(butoxy)-1,2-propanediol; octaethoxylated 3-(butoxy)-1,2 - propylene glycol; nonaethoxylated 3-(butoxy)-1,2-propanediol; monopropoxylated 3-(butoxy)-1,2-propanediol; dibutylideneoxylated 3 -(butoxy)-1,2-propanediol; tributoxylated 3-(butoxy)-1,2-propanediol; 3-phenoxy-1,2-propanediol; 3-benzyloxy -1,2-propanediol; 3-(2-phenylethoxy)-1,2-propanediol; 3-(1-phenyl-2-propoxy)-1,2-propanediol; 2-phenoxy Base-1,3-propanediol; 2-(m-tolyloxy)-1,3-propanediol; 2-(p-tolyloxy)-1,3-propanediol; Benzyloxy-1,3-propanediol ; 2-(2-phenylethoxy)-1,3-propanediol; 2-(1-phenylethoxy)-1,3-propanediol; bis(2-hydroxybutyl) ether; and/or Di(2-hydroxycyclopentyl) ether; VII. Including the following saturated and unsaturated alicyclic diols and their derivatives: (a) saturated diols and their derivatives, including: 1-isopropyl-1 , 2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2 -Cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclo Pentylene glycol; 2,4,5-trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1, 2-cyclopentadiol; 3,5-dimethyl-1,2-cyclopentadiol; 3-ethyl-1,2-cyclopentadiol; 4,4-dimethyl-1,2- Cyclopentanediol; 4-Ethyl-1,2-cyclopentanediol; 1,1-bis(hydroxymethyl)cyclohexane; 1,2-bis(hydroxymethyl)cyclohexane; 1,2 -Dimethyl-1,3-cyclohexanediol; 1,3-bis(hydroxymethyl)cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-bis Methyl-1,3-cyclohexanediol; 1-hydroxy-cyclohexaneethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1 , 2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl- 1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1, 3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3- Hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5- Dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl- 1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl -1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl Base-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl-1,4-cycloheptanediol Diol; 1,3-Cyclooctanediol; 1,4-Cyclooctanediol; 1,5-Cyclooctanediol; 1,2-Cyclohexanediol Diethoxylate; 1,2-Cyclohexanediol Diol triethoxylate; 1,2-cyclohexanediol tetraethoxylate; 1,2-cyclohexanediol pentaethoxylate; 1,2-cyclohexanediol hexaethoxylate; 1,2-Cyclohexanediol Heptaethoxylate; 1,2-Cyclohexanediol Octaethoxylate; 1,2-Cyclohexanediol Nonaethoxylate; 1,2-Cyclohexanediol Monopropoxylate; 1,2-Cyclohexanediol Monobutylidene Oxide; 1,2-Cyclohexanediol Dibutylidene Oxide; and/or 1,2-Cyclohexanediol Tributylidene Oxide and (b) include the following unsaturated cycloaliphatic diols: 1-vinyl-2-ethyl-1,2-cyclobutanediol; 1,2,3,4-tetramethyl-3-cyclo Butene-1,2-diol; 3,4-diethyl-3-cyclobutene-1,2-diol; 3-(1,1-dimethylethyl)-3-cyclobutene -1,2-diol; 3-butyl-3-cyclobutene-1,2-diol; 1,2-dimethyl-4-methylene-1,2-cyclopentanediol; 1 -Ethyl-3-methylene-1,2-cyclopentadiol; 4-(1-propenyl)-1,2-cyclopentadiol; 1-ethyl-3-methyl-3-cyclo Pentene-1,2-diol; 1-vinyl-1,2-cyclohexanediol; 1-methyl-3-methylene-1,2-cyclohexanediol; 1-methyl-4 -Methylene-1,2-cyclohexanediol; 3-vinyl-1,2-cyclohexanediol; 4-vinyl-1,2-cyclohexanediol; 2,6-dimethyl- 3-cyclohexene-1,2-diol; 6,6-dimethyl-3-cyclohexene-1,2-diol; 3,6-dimethyl-4-cyclohexene-1, 2-diol; 4,5-dimethyl-4-cyclohexene-1,2-diol; 3-cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol Alcohols; and/or 5-cyclooctene-1,2-diols; VIII. Alkoxylated derivatives of C _3-8 diols [In the following descriptions, "EO" refers to polyethoxylates, That is -(CH ₂ CH ₂ O) _n H; Me-E _n refers to methyl-terminated polyethoxylate -(CH ₂ CH ₂ O) _n CH ₃ ; "2(Me-E _n )" refers to the required 2Me-E _n group; "PO" refers to polypropoxylate, -(CH(CH ₃ )CH ₂ O) _n H; "BO" refers to polybutylene oxide group, -(CH(CH ₂ CH ₃ ) _CH2O ) _nH ; and "n- _BO " refers to a poly(n-butyleneoxy ₎ or _poly (tetramethylene)oxy group -( _{CH2CH2CH2CH2O} ) _nH . The term "(C _x )" as used herein refers to the number of carbon atoms in the starting material to be alkoxylated]. include;

1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1,2-propanediol (C3)PO ₄ ; 2-methyl-1,2-propanediol (C4) (Me-E _{4- 10} ); 2-methyl-1,2-propanediol (C4) 2 (Me-E ₁ ); 2-methyl-1,2-propanediol (C4)PO ₃ ; 2-methyl-1,2-propanediol (C4)BO ₁ ; 1,3-propanediol (C3)2(Me-E _6-8 ); 1,3-propanediol (C3)PO _5-6 ; 2,2-diethyl-1,3-propanediol (C7) E _1-7 ; 2,2-diethyl-1,3-propanediol (C7)PO ₁ ; 2,2-diethyl-1,3-propanediol (C7)n-BO _1-2 ; 2,2-dimethyl-1,3-propanediol (C5) 2 (MeE _1-2 ); 2,2-dimethyl-1,3-propanediol (C5)PO _3-4 ; 2-(1- Methylpropyl)-1,3-propanediol (C7) E _1-7 ; 2-(1-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methylpropyl )-1,3-propanediol (C7)n-BO _1-2 ; 2-(2-methylpropyl)-1,3-propanediol (C7)E _1-7 ; 2-(2-methylpropyl )-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1,3-propanediol (C7)n-BO _1-2 ; 2-ethyl-1,3-propanediol ( C5)(MeE _6-10 ); 2-Ethyl-1,3-propanediol (C5)2( _MeE1 ); 2-Ethyl-1,3-propanediol (C5)PO3; 2-Ethyl- ₂ -Methyl-1,3-propanediol (C6) (MeE _1-6 ); 2-Ethyl-2-methyl-1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl- 1,3-propanediol (C6)BO ₁ ; 2-isopropyl-1,3-propanediol (C6) (MeE _{1 -6} ); 2-isopropyl-1,3-propanediol (C6)PO ₂ ; 2 -Isopropyl-1,3-propanediol (C6)BO ₁ ; 2-methyl-1,3-propanediol (C4)2(MeE _2-5 ); 2-methyl-1,3-propanediol (C4) PO _4-5 ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)E _2-9 ; 2-methyl- 2-isopropyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)n-BO _1-3 ; 2-methyl-2- Propyl-1,3-propanediol (C7) E _1-7 ; 2-methyl-2-propyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-propyl-1,3 -Propylene glycol (C7)n-BO _1-2 ; 2-Propyl-1,3-propanediol (C6) (MeE _1-4 ); 2-Propyl-1,3-propanediol (C6)PO ₂ ; 2- Propyl-1,3-propanediol (C6) _BO1 ;

2. 1,2-butanediol (C4) (Me-E _2-8 ); 1,2-butanediol (C4)PO _2-3 ; 1,2-butanediol (C4)BO ₁ ; 2 , 3-dimethyl-1,2-butanediol (C6) E _1-6 ; 2,3-dimethyl-1,2-butanediol (C6) n-BO _1-2 ; 2-ethane Base-1,2-butanediol (C6) E _1-3 ; 2-ethyl-1,2-butanediol (C6)n-BO ₁ ; 2-methyl-1,2-butanediol ( C5)(Me-E _1-2 ); 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _{1- 6} ; 3,3-dimethyl-1,2-butanediol (C6)n-BO _{1- 2} ; 3-methyl-1,2-butanediol (C5) (MeE _1-2 ); 3 -Methyl-1,2-butanediol (C5)PO ₁ ; 1,3-butanediol (C4) 2 (MeE _3-6 ); 1,3-butanediol (C4)PO ₅ ; 1, 3-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,3-butanediol (C7) (MeE _1-3 ); 2,2,3-trimethyl-1, 3-Butanediol (C7)PO _1-2 ; 2,2-Dimethyl-1,3-butanediol (C6)(MeE _{3 -8} ); 2,2-Dimethyl-1,3- Butanediol (C6)PO ₃ ; 2,3-dimethyl-1,3-butanediol (C6) (MeE _3-8 ); 2,3-dimethyl-1,3-butanediol ( C6) PO ₃ ; 2-Ethyl-1,3-butanediol (C6) (MeE _1-6 ); 2-Ethyl-1,3-butanediol (C6)PO _2-3 ; 2-Ethyl Base-1,3-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,3-butanediol (C7)(MeE ₁ ); 2-Ethyl-2-methyl- 1,3-butanediol (C7)PO ₁ ; 2-ethyl-2-methyl-1,3-butanediol (C7)n-BO _2-4 ; 2-ethyl-3-methyl- 1,3-butanediol (C7) (MeE ₁ ); 2-ethyl-3-methyl-1,3-butanediol (C7)PO ₁ ; 2-ethyl-3-methyl-1, 3-butanediol (C7) n-BO _2-4 ; 2-isopropyl-1,3-butanediol (C7) (MeE ₁ ); 2-isopropyl-1,3-butanediol ( C7) PO ₁ ; 2-isopropyl-1,3-butanediol (C7)n-BO _2-4 ; 2-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ) ; 2-methyl-1,3-butanediol (C5)PO ₄ ; 2-propyl-1,3-butanediol (C7)E _2-9 ; 2-propyl-1,3-butanediol Alcohol (C7) PO ₁ ; 2-propyl-1,3-butanediol (C7) n-BO _1-3 ; 3-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ); 3-methyl-1,3-butanediol (C5)PO ₄ ; 1,4-butanediol (C4) 2 (MeE _2-4 ); 1,4-butanediol (C4)PO _{4 -5} ; 1,4-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,4-butanediol (C7)E _2-9 ; 2,2,3-trimethyl -1,4-butanediol (C7)PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _1-3 ; 2,2-dimethyl-1 , 4-butanediol (C6) (MeE _1-6 ); 2,2-dimethyl-1,4-butanediol (C6)PO ₂ ; 2,2-dimethyl-1,4-butane Diol (C6) BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _{1- 6} ); 2,3-dimethyl-1,4-butanediol (C6 )PO ₂ ; 2,3-dimethyl-1,4-butanediol (C6)BO ₁ ; 2-ethyl-1,4-butanediol (C6)(MeE _{1 -4} ); 2-ethane Base-1,4-butanediol (C6)PO ₂ ; 2-Ethyl-1,4-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7) E _1-7 ; 2-Ethyl-2-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7 )n-BO _1-2 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)E _1-7 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,4-butanediol (C7)n-BO _1-2 ; 2-isopropyl-1,4-butanediol (C7)E _1-7 ; 2-isopropyl-1,4-butanediol (C7)PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO _1-2 ; 2-methyl -1,4-butanediol (C5) (MeE _6-10 ); 2-methyl-1,4-butanediol (C5) 2 (MeE ₁ ); 2-methyl-1,4-butanediol Alcohol (C5)PO ₃ ; 2-methyl-1,4-butanediol (C5)BO ₁ ; 2-propyl-1,4-butanediol (C7)E _{1 -5} ; 2-propyl- 1,4-butanediol (C7)n-BO _1-2 ; 3-ethyl-1-methyl-1,4-butanediol (C7)E _2-9 ; 3-ethyl-1-methyl Base-1,4-butanediol (C7)PO ₁ ; 3-ethyl-1-methyl-1,4-butanediol (C7)n-BO _1-3 ; 2,3-butanediol ( C4) (MeE _6-10 ); 2,3-butanediol (C4) 2 (MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-dimethyl-2,3-butanediol (C6)E _3-9 ; 2,3-dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3 -Dimethyl-2,3-butanediol (C6)n-BO _1-3 ; 2-methyl-2,3-butanediol (C5)(MeE _1-5 ); 2-Methyl-2 , 3-butanediol (C5) PO ₂ ; 2-methyl-2,3-butanediol (C5) BO ₁ ;

3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol (C5) n-BO _2-3 ; 2-methyl Base-1,2-pentanediol (C6) E _{1- 3} ; 2-methyl-1,2-pentanediol (C6)n-BO ₁ ; 2-methyl-1,2-pentanediol ( C6)BO ₁ ; 3-methyl-1,2-pentanediol (C6)E _1-3 ; 3-methyl-1,2-pentanediol (C6)n-BO ₁ ; 4-methyl- 1,2-pentanediol (C6) E _1-3 ; 4-methyl-1,2-pentanediol (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (MeE _{1- 2} ); 1,3-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,3-pentanediol (C7) (MeE ₁ ); 2,2-dimethyl-1 , 3-pentanediol (C7) PO ₁ ; 2,2-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,3-pentane Diol (C7) (Me-E ₁ ); 2,3-dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,3-pentanediol (C7 )n-BO _2-4 ; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 2,4-dimethyl-1,3-pentanediol (C7 )PO ₁ ; 2,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2-ethyl-1,3-pentanediol (C7)E _2-9 ; 2 -Ethyl-1,3-pentanediol (C7)PO ₁ ; 2-Ethyl-1,3-pentanediol (C7)n-BO _1-3 ; 2-methyl-1,3-pentanediol Alcohol (C6) 2 (MeE _{1- 6} ); 2-methyl-1,3-pentanediol (C6)PO _2-3 ; 2-methyl-1,3-pentanediol (C6)BO ₁ ; 3,4-Dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 3,4-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4- Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 3-methyl-1,3-pentanediol (C6)(Me-E _1-6 ); 3-methyl- 1,3-pentanediol (C6)PO _2-3 ; 3-methyl-1,3-pentanediol (C6)BO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7 )(Me-E ₁ ); 4,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 4-methyl-1,3-pentanediol (C6) (MeE _1-6 ); 4-methyl-1,3-pentanediol (C6)PO _2-3 ; 4-methyl -1,3-pentanediol (C6)BO ₁ ; 1,4-pentanediol (C5) 2 (MeE _{1- 2} ); 1,4-pentanediol (C5)PO _3-4 ; 2,2 - Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,2-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,2-Dimethyl -1,4-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,3-dimethyl -1,4-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2,4-dimethyl-1,4 - Pentanediol (C7) (Me-E ₁ ); 2,4-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2-methyl-1,4-pentanediol (C6) (MeE _1-6 ); 2-methyl-1,4-pentanediol (C6)PO _{2- 3} ; 2-methyl-1,4-pentanediol (C6)BO ₁ ; 3,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,3-di Methyl-1,4-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 3,4-Dimethyl-1 , 4-pentanediol (C7) (Me-E ₁ ); 3,4-dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,4-pentane Diol (C7) n-BO _2-4 ; 3-methyl-1,4-pentanediol (C6) 2 (Me-E _1-6 ); 3-methyl-1,4-pentanediol ( C6)PO _{2 -3} ; 3-methyl-1,4-pentanediol (C6)BO ₁ ; 4-methyl-1,4-pentanediol (C6)2(Me-E _1-6 ); 4-methyl-1,4-pentanediol (C6)PO _2-3 ; 4-methyl-1,4-pentanediol (C6)BO ₁ ; 1,5-pentanediol (C5)(Me -E _4-10 ); 1,5-pentanediol (C5) 2 (MeE ₁ ); 1,5-pentanediol (C5)PO ₃ ; 2,2-dimethyl-1,5-pentanediol Alcohol (C7) E _1-7 ; 2,2-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-Dimethyl-1,5-pentanediol (C7)n- BO _1-2 ; 2,3-dimethyl-1,5-pentanediol (C7) E _1-7 ; 2,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2 , 3-dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2,4-dimethyl-1,5-pentanediol (C7)E _1-7 ; 2,4 -Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2-Ethyl-1, 5-pentanediol (C7) E _1-5 ; 2-ethyl-1,5-pentanediol (C7) n-BO _1-2 ; 2-methyl-1,5-pentanediol (C6) (Me-E _1-4 ); 2-methyl-1,5-pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _1-7 ; 3,3-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 3-methyl -1,5-pentanediol (C6) (Me-E _1-4 ); 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) (Me -E _1-3 ); 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6)E _1-7 ; 2-methyl-2,3-pentane Diol (C6) PO ₁ ; 2-methyl-2,3-pentanediol (C6) n-BO _1-2 ; 3-methyl-2,3-pentanediol (C6) E _1-7 ; 3-methyl-2,3-pentanediol (C6)PO ₁ ; 3-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 4-methyl-2,3-pentane Diol (C6) E _1-7 ; 4-methyl-2,3-pentanediol (C6)PO ₁ ; 4-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 2,4-pentanediol (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol (C7 )(Me-E _1-4 ); 2,3-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-dimethyl-2,4-pentanediol (C7)( Me-E _1-4 ); 2,4-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2-methyl-2,4-pentanediol (C7) (Me-E _{5- 10} ); 2-methyl-2,4-pentanediol (C7)PO ₃ ; 3,3-dimethyl-2,4-pentanediol (C7) (Me-E _1-4 ); 3, 3-Dimethyl-2,4-pentanediol (C7)PO ₂ ; 3-methyl-2,4-pentanediol (C6) (Me-E _5-10 ); 3-methyl-2, 4-pentanediol (C6) _PO3 ;

4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _2-9 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _1-3 ; 2-methyl-1,3-hexanediol (C7)BO ₁ ; 3-methyl-1,3-hexanediol (C7)E _2-9 ; 3-methyl- 1,3-hexanediol (C7)PO ₁ ; 3-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,3-hexanediol (C7) E _2-9 ; 4-methyl-1,3-hexanediol (C7)PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 5-methyl- 1,3-hexanediol (C7)E _2-9 ; 5-methyl-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n- BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7) E _2-9 ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 3-methyl-1,4-hexanediol (C7)E _2-9 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3- Methyl-1,4-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,4-hexanediol (C7)E _2-9 ; 4-methyl-1,4-hexane Diol (C7) PO ₁ ; 4-methyl-1,4-hexanediol (C7) n-BO _1-3 ; 5-methyl-1,4-hexanediol (C7) E _2-9 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6)PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7) E _2-9 ; 2-methyl-1,5-hexanediol (C7)PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 3-methyl- 1,5-hexanediol (C7)E _2-9 ; 3-methyl-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n- BO _1-3 ; 4-methyl-1,5-hexanediol (C7)E _2-9 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1, 5-hexanediol (C7)n-BO _1-3 ; 5-methyl-1,5-hexanediol (C7)E _2-9 ; 5-methyl-1,5-hexanediol (C7) PO ₁ ; 5-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 1,6-hexanediol (C6)(Me-E _1-2 ); 1,6-hexanediol Alcohol (C6) PO _1-2 ; 1,6-Hexanediol (C6) n-BO ₄ ; 2-Methyl-1,6-Hexanediol (C7) E _1-5 ; 2-Methyl-1 , 6-hexanediol (C7) n-BO _1-2 ; 3-methyl-1,6-hexanediol (C7) E _1-5 ; 3-methyl-1,6-hexanediol (C7 )n-BO _1-2 ; 2,3-hexanediol (C6)E _1-5 ; 2,3-hexanediol (C6)n-BO ₁ ; 2,3-hexanediol (C6)BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6)PO ₃ ; 2-methyl-2,4-hexanediol (C7) (Me -E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4-hexanediol (C7)(Me-E _1-2 ) ; 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 4-methyl- 2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _1-2 ); 5-methyl-2,4-hexanediol Alcohol (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-Methyl-2,5- Hexylene glycol (C7) (Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol (C6)EO _1-5 ; 3,4-hexanediol Alcohol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ;

5. 1,3-Heptanediol (C7) E _1-7 ; 1,3-Heptanediol (C7)PO ₁ ; 1,3-Heptanediol (C7)n-BO _1-2 ; 1,4 -Heptanediol (C7) E _1-7 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO _1-2 ; 1,5-Heptanediol ( C7)E _1-7 ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO _1-2 ; 1,6-heptanediol (C7)E _{1- 7} ; 1,6-heptanediol (C7)PO ₁ ; 1,6-heptanediol (C7)n-BO _1-2 ; 1,7-heptanediol (C7)E _1-2 ; 1,7 -Heptanediol (C7)n-BO ₁ ; 2,4-Heptanediol (C7)E _3-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol Alcohol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me- E ₁ ); 2,5-heptanediol (C7)PO ₁ ; 2,5-heptanediol (C7)n-BO ₃ ; 2,6-heptanediol (C7)E _3-10 ; 2,6 - Heptanediol (C7) (Me-E ₁ ); 2,6-Heptanediol (C7)PO ₁ ; 2,6-Heptanediol (C7)n-BO ₃ ; 3,5-Heptanediol ( C7)E _3-10 ; 3,5-heptanediol (C7)(Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ;

6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 -Isopropyl-1,4-butanediol (C8)n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl-2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptane Diol (C8)n- _BO1 ; 3-methyl-2,4-heptanediol (C8)n- _BO1 ; 4-methyl-2,4-heptanediol (C8)n- _BO1 ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl-2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptane Diol (C8)n- _BO1 ; 3-methyl-2,5-heptanediol (C8)n- _BO1 ; 4-methyl-2,5-heptanediol (C8)n- _BO1 ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl-2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptane Diol (C8)n- _BO1 ; 3-methyl-2,6-heptanediol (C8)n- _BO1 ; 4-methyl-2,6-heptanediol (C8)n- _BO1 ; 2-Methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)E _1-3 ; 2-Ethylene Base-2,3-dimethyl-1,3-butanediol (C8) E _1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8) E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8) E _1-3 ; 5-methyl-2,5-heptanediol (C8) E _1-3 ; 6-methyl-2,5-heptanediol (C8) E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; and

7. Their mixtures; IX. Including the following aromatic diols: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 1-phenyl-1,2-propanediol ; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3-propanediol; 2-methyl -1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol ; 2-phenyl-1,4-butanediol; and/or 1-phenyl-2,3-butanediol; X. The main solvent is a homologue or analog of the above structure, wherein one or Multiple _CH2 groups, and for each _CH2 group added, two hydrogen atoms on the carbon atoms adjacent to them in the molecule are removed to form a carbon-carbon double bond, thus maintaining the Constant number of hydrogen atoms, they include the following substances: 2,2-di-2-propenyl-1,3-propanediol; 2-(1-pentenyl)-1,3-propanediol; 2-(2-methanol Base-2-propenyl)-2-(2-propenyl)-1,3-propanediol; 2-(3-methyl-1-butenyl)-1,3-propanediol; 2-(4-pentene alkenyl)-1,3-propanediol; 2-ethyl-2-(2-methyl-2-propenyl)-1,3-propanediol; 2-ethyl-2-(2-propenyl)-1 , 3-propanediol; 2-methyl-2-(3-methyl-3-butenyl)-1,3-propanediol; 2,2-allyl-1,3-butanediol; 2-( 1-Ethyl-1-propenyl)-1,3-butanediol; 2-(2-butenyl)-2-methyl-1,3-butanediol; 2-(3-methyl- 2-butenyl)-1,3-butanediol; 2-ethyl-2-(2-propenyl)-1,3-butanediol; 2-methyl-2-(1-methyl- 2-propenyl)-1,3-butanediol; 2,3-bis(1-methylethylene)-1,4-butanediol; 2-(3-methyl-2-butenyl )-3-methylene-1,4-butanediol; 2-(1,1-dimethylpropyl)-2-butene-1,4-diol; 2-(1-methylpropane Base)-2-butene-1,4-diol; 2-butyl-2-butene-1,4-diol; 2-vinyl-3-ethyl-1,3-pentanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1,4-pentanediol; 2-(1-propenyl )-1,5-pentanediol; 2-(2-propenyl)-1,5-pentanediol; 2-ethylene-3-methyl-1,5-pentanediol; 2-propylene 1,5-pentanediol; 3-ethylene-2,4-dimethyl-2,4-pentanediol; 2-(1,1-dimethylethyl)-4-pentene -1,3-diol; 2-ethyl-2,3-dimethyl-4-pentene-1,3-diol; 4-ethyl-2-methylene-1,4-hexanediol Alcohol; 2,3,5-trimethyl-1,5-hexadiene-3,4-diol; 5-ethyl-3-methyl-1,5-hexadiene-3,4-diol Alcohol; 2-(1-methylvinyl)-1,5-hexanediol; 2-vinyl-1,6-hexanediol; 5,5-dimethyl-1-hexene-3,4 -diol; 5,5-dimethyl-1-hexene-3,4-diol; 4-vinyl-2,5-dimethyl-2-hexene-1,5-diol; 2 -Vinyl-2,5-dimethyl-3-hexene-1,6-diol; 2-ethyl-3-hexene-1,6-diol; 3,4-dimethyl-3 -Hexene-1,6-diol; 2,5-Dimethyl-4-hexene-2,3-diol; 3,4-Dimethyl-4-hexene-2,3-diol ; 3-(2-propenyl)-5-hexene-1,3-diol; 2,3-dimethyl-5-hexene-2,3-diol; 3,4-dimethyl- 5-hexene-2,3-diol; 3,5-dimethyl-5-hexene-2,3-diol; 3-vinyl-2,5-dimethyl-5-hexene- 2,4-diol; 6-methyl-5-methylene-1,4-heptanediol; 2,3-dimethyl-1,5-heptadiene-3,4-diol; 2 , 5-Dimethyl-1,5-heptadiene-3,4-diol; 3,5-dimethyl-1,5-heptadiene-3,4-diol; 2,6-diol (Methylene)-1,7-heptanediol; 4-methylene-1,7-heptanediol; 2,4-dimethyl-1-heptene-3,5-diol; 2, 6-Dimethyl-1-heptene-3,5-diol; 3-vinyl-5-methyl-1-heptene-3,5-diol; 6,6-dimethyl-1- Heptene-3,5-diol; 4,6-Dimethyl-2,4-heptadiene-2,6-diol; 4,4-Dimethyl-2,5-heptadiene-1 ,7-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 5,6-dimethyl-2-heptene-1,4-diol ; 5-ethyl-2-heptene-1,5-diol; 2-methyl-2-heptene-1,7-diol; 4,6-dimethyl-3-heptene-1, 5-diol; 3-methyl-6-methylene-3-heptene-1,7-diol; 2,4-dimethyl-3-heptene-2,5-diol; 2, 5-Dimethyl-3-heptene-2,5-diol; 2,6-dimethyl-3-heptene-2,6-diol; 4,6-dimethyl-3-heptene -2,6-diol; 2,4-dimethyl-5-heptene-1,3-diol; 3,6-dimethyl-5-heptene-1,3-diol; 2, 6-Dimethyl-5-heptene-1,4-diol; 3,6-Dimethyl-5-heptene-1,4-diol; 2,3-Dimethyl-5-heptene -2,4-diol; 2,2-dimethyl-6-heptene-1,3-diol; 4-(2-propenyl)-6-heptene-1,4-diol; 5 , 6-Dimethyl-6-heptene-1,4-diol; 2,4-dimethyl-6-heptene-1,5-diol; 2-ethylene-6-methyl- 6-heptene-1,5-diol; 4-(2-propenyl)-6-heptene-2,4-diol; 5,5-dimethyl-6-heptene-2,4- Diol; 4,6-Dimethyl-6-heptene-2,5-diol; 5-vinyl-4-methyl-6-heptene-2,5-diol; 2-methylene -1,3-octanediol; 2,6-dimethyl-1,6-octadiene-3,5-diol; 3,7-dimethyl-1,6-octadiene-3, 5-Diol; 2,6-Dimethyl-1,7-octadiene-3,6-diol; 2,7-Dimethyl-1,7-octadiene-3,6-diol ;3,6-Dimethyl-1,7-octadiene-3,6-diol; 3-vinyl-1-octene-3,6-diol; 2,7-Dimethyl-2 , 4,6-octatriene-1,8-diol; 3,7-dimethyl-2,4-octadiene-1,7-diol; 2,6-dimethyl-2,5 -octadiene-1,7-diol; 3,7-dimethyl-2,5-octadiene-1,7-diol; 3,7-dimethyl-2,6-octadiene -1,4-diol (Rosiridol); 2-methyl-2,6-octadiene-1,8-diol; 3,7-dimethyl-2,7-octadiene-1,4 -diol; 2,6-dimethyl-2,7-octadiene-1,5-diol; 2,6-dimethyl-2,7-octadiene-1,6-diol ( 8-hydroxylinalool); 2,7-dimethyl-2,7-octadiene-1,6-diol; 2-octene-1,4-diol; 2-octene-1, 7-diol; 2-methyl-6-methylene-2-octene-1,7-diol; 3,7-dimethyl-3,5-octadiene-1,7-diol ; 2,7-dimethyl-3,5-octadiene-2,7-diol; 4-methylene-3,5-octanediol; 2,6-dimethyl-3,7- Octadiene-1,6-diol; 2,7-Dimethyl-3,7-octadiene-2,5-diol; 2,6-Dimethyl-3,7-octadiene- 2,6-diol; 4-methyl-3-octene-1,5-diol; 5-methyl-3-octene-1,5-diol; 2,2-dimethyl-4 , 6-octadiene-1,3-diol; 2,6-dimethyl-4,7-octadiene-2,3-diol; 2,6-dimethyl-4,7-octane Diene-2,6-diol; 7-methyl-4-octene-1,6-diol; 2,7-di(methylene); 2-methylene; 2,7-dimethyl 7-methyl-5,7-octadiene-1,4-diol; 7-methyl-5,7-octadiene-1,4-diol; 5-octene-1,3-diol; 7 -Methyl-6-octene-1,3-diol; 7-methyl-6-octene-1,4-diol; 6-octene-1,5-diol; 7-methyl- 6-octene-1,5-diol; 2-methyl-6-octene-3,5-diol; 4-methyl-6-octene-3,5-diol; 2-methyl -7-octene-1,3-diol; 4-methyl-7-octene-1,3-diol; 7-methyl-7-octene-1,3-diol; 7-octene ene-1,5-diol; 7-octene-1,6-diol; 5-methyl-7-octene-1,6-diol; 2-methyl-6-methylene-7 -octene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene-3,5-diol; 1-nonene- 3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 8-methyl-4,6-nonadiene-1,3-diol ; 4-nonene-2,8-diol; 6,8-nonene-1,5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol Alcohol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol; and/or 1,9-decadiene-4,6-diol; and XI. Their mixture; C. Optional but preferred, an effective amount of low molecular weight water-soluble solvents sufficient to improve transparency, such as ethanol, isopropanol, propylene glycol, 1,3-propylene glycol, propylene carbonate, etc., so The content of said water-soluble solvents is such that they themselves do not form a transparent composition; D. Optional but preferred, an effective amount of water-soluble calcium and/or magnesium salts, preferably chlorides, sufficient to improve clarity; and E . Balance of water.

When the fabric softener active is wherein R is hydrogen, or hydroxyalkyl, and especially when the Y group is amido, the solvent is preferably not a monohydric alcohol, especially not tert-butanol, or 2-methyl-pentanediol .

The compositions of the present invention are preferably aqueous, translucent or transparent, preferably transparent compositions comprising from about 3% to about 95%, preferably from about 5% to about 80%, more preferably from about 15% to about 70%, and even More preferably from about 40% to about 60% water and from about 3% to about 40%, preferably from about 10% to about 35%, more preferably from about 12% to about 25%, and even more preferably from about 14% to about 20% The main alcohol solvent B above. Without the primary solvent B these preferred products (compositions) are not translucent or transparent. The amount of primary solvent B required to render the composition translucent or transparent is preferably in excess of 50%, more preferably in excess of about 60%, even more preferably in excess of about 75% of the total organic solvent present.

Primary solvents need to be kept to a minimum in the compositions of the present invention in order to obtain acceptable stability/clarity. The presence of water plays an important role as the primary solvent to make these compositions transparent. The higher the water content, the higher the amount of main solvent needed to make the product transparent. Conversely, the lower the water content, the less primary solvent (relative to softener) is required. Thus, at low water levels of from about 5% to about 15%, the weight ratio of softener active to primary solvent is preferably from about 55:45 to about 85:15, more preferably from about 60:40 to about 80:20. At water levels of from about 15% to about 75%, the weight ratio of softener active to primary solvent is preferably from about 45:55 to about 70:30, more preferably from about 55:45 to about 70:30. However, at high water contents of about 70% to about 80%, the weight ratio of softener active to primary solvent is preferably from about 30:70 to about 55:45, more preferably from about 35:65 to about 45:55. At higher water contents, the ratio of softener to primary solvent is even higher.

As described hereinafter, some of the above solvents are novel compounds and/or mixtures of compounds.

The pH of the composition should be from about 1 to about 7, preferably from about 1.5 to about 5, more preferably from about 2 to about 3.5.

DETAILED DESCRIPTION OF THE INVENTION I. Fabric Softener Actives

The compositions of the present invention contain as an essential component about 2% to about 80% by weight of the composition, preferably about 13% to about 75%, more preferably about 17% to about 70%, even more preferably about 19% to about 65% fabric softener active selected from the compounds defined hereinafter and mixtures thereof. (A) Diester quaternary ammonium fabric softener active compound (DEQA) (1) The first type of DEQA preferably contains a compound of the following formula as the main active agent:

[(R) _4-m -N ⁽⁺⁾ )-[(CH ₂ ) _n -YR ¹ ] _m ]X ^(-) (1)

Where: each R substituent is H or short chain C _1-6 , preferably C _1-3 alkyl or hydroxyalkyl, for example, methyl (most preferred), ethyl, propyl, hydroxyethyl, etc., benzyl Each m is 2 or 3; Each n is 1 to about 4, preferably 2; Each Y is -O-(O)C-, -(R)N-(O)C -, -C(O)-N(R)-, or -C(O)-O-, preferably -O-(O)C-, but not -OC(O)O-; in ^each R The sum of carbon numbers, when Y is -O-(O)C- or -(R)N-(O)C-, the sum of carbon numbers plus 1 is C _6-22 , preferably C _14-20 , but only one YR ¹ sum is less than about 12 and the other YR ¹ sum is at least about 16, wherein each R ¹ is a long chain C _8-22 (or C _7-21 ) hydrocarbyl, or substituted hydrocarbyl substituent, Preferably C _10-20 (or C _9-19 ) alkyl or alkenyl, most preferably C _12-18 (or C _11-17 ) alkyl or alkenyl, wherein, when the sum of the carbon numbers is C When _16-18 and ^R are linear alkyl or alkenyl groups, the iodine value (hereinafter referred to as IV) of the parent fatty acid of the ^R group is preferably from about 20 to about 140, more preferably from about 50 to about 130 ; most preferably from about 70 to about 115 (as used herein, the iodine value of the "parent" fatty acid or the "corresponding" fatty acid is used to define the degree of unsaturation of the ^R group that contains the same The same degree of unsaturation present in the fatty acid of the ^R1 group).

The above counter ion X ^(-) can be any anion that can be compatible with the softener, preferably an anion of a strong acid, for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate and nitrate, etc., more Chloride is preferred. The anion can also (but is not preferred) be double charged, in which case X ^(-) represents a half group.

Preferred biodegradable quaternary ammonium fabric softening compounds may contain the group -(O)CR ¹ derived from unsaturated and polyunsaturated fatty acids, e.g. oleic acid, and/or partially hydrogenated fatty acids, derived from vegetable oils and/or Derived from partially hydrogenated vegetable oils such as canola oil; safflower oil; peanut oil; sunflower oil; corn oil, soybean oil, tall oil; Non-limiting examples of DEQAs prepared from preferred fatty acids have the following approximate distributions: fatty acyl groups DEQA ¹ DEQA ² DEQA ³ DEQA ⁴ DEQA ⁵ C12 trace trace 0 0 0C14 3 3 0 0 0C16 4 4 5 5 5C18 0 0 5 6 6C14: 1 3 3 0 0 0C16: 1 11 7 0 0 3C18: 1 74 73 71 68 67C18: 2 4 8 8 11 11C18: 3 0 1 1 2 2C20: 1 0 0 2 2 2C20 and above 0 0 2 0 0 Unknown 0 0 6 6 7 Total 99 99 100 100 102IV 86-90 88-95 99 100 95 Cis/Trans 20-30 20-30 4 5 5 (C18:1) TPU 4 9 10 13 13

It is possible and preferred to use fatty acid mixtures and mixtures of DEQAs derived from different fatty acids. Non-limiting examples of DEQA's that may be added to form the DEQA's of the present invention are as follows: fatty acyl group DEQA ¹⁰ DEQA ¹¹ C14 0 1C16 11 25C18 4 20C14:1 0 0C16:1 1 0C18:1 27 45C18:2 50 6C18:3 7 0 unknown 0 3 total 100 100IV 125-138 56 cis/trans (C18: 71 not available) TPU 57 6

DEQA ¹⁰ is made from soybean fatty acid and DEQA ¹¹ is made from lightly hydrogenated tallow fatty acid.

R ¹ may also optionally but preferably contain branching, for example R 1 is derived from isostearic acid, at least part of the R ¹ group does. When branched groups are present, the active agent represented by the branched group will generally total from about 1% to about 90%, preferably from about 10% to about 70%, more preferably from about 20% to about 50%. Fatty acyl group DEQA ¹² DEQA ¹³ DEQA ¹⁴ Isomyristic acid- 1-2-myristic acid 7-11 0.5-1-isopalmitic acid 6-7 6-7 1-3 palmitic acid 4-5 6-7 - Isostearic acid 70-76 80-82 60-66 Stearic acid - 2-3 8-10 Isoleic acid - - 13-17 Oleic acid - - 6-12IV 3 2 7-12

DEQA ¹² -DEQA ¹⁴ were prepared from various commercially available isostearic acids.

More preferred DEQA's are those prepared as a single DEQA from a mixture of all the different fatty acids expressed as (total fatty acid mixture), rather than from a blend of separate finished DEQA's, wherein the finished DEQA's are composed of different proportions A total fatty acid blend was prepared.

Preferably at least a majority of the fatty acyl groups are unsaturated, for example in a proportion of from about 50% to 100%, preferably from about 55% to about 95%, more preferably from about 60% to about 90%, polyunsaturated fatty acyl groups The total active agent content (TPU) is about 3% to about 30%, preferably about 5% to about 25%, more preferably about 10% to about 18%. The cis/trans ratio of the unsaturated fatty acyl groups is generally important, the cis/trans ratio being from 1:1 to about 50:1, with a minimum of 1:1, preferably at least 3:1, more preferably about 4 :1 to about 20:1. (As used herein, the "percentage of softener active" containing a given ^R group is the same as the percentage of the same ^R group in the total ^R used to form all softener actives) .

The unsaturated, including preferred polyunsaturated fatty acyl groups discussed in this context unexpectedly provide effective softening, but also provide better rewetting properties, excellent antistatic properties, and especially in Excellent recovery properties after freezing and thawing.

Highly unsaturated materials are also readily formulated as concentrated premixes which maintain their low viscosity and are therefore easy to process, eg, pump, mix, etc. These highly unsaturated materials carry only a small amount of solvent normally associated with such materials, typically from about 5% to about 20%, preferably from about 8% to about 25%, more preferably from about From 10% to about 20%, these highly unsaturated materials are readily formulated into concentrated, stable compositions of the present invention, even at room temperature. This ability to process active agents at low temperatures is especially important for polyunsaturated groups, since degradation is minimized. Additional protection from degradation can be provided when the compounds and softener compositions contain effective antioxidants, chelating agents, and/or reducing agents as described hereinafter.

The present invention may contain, as a preferred component, a medium chain biodegradable quaternary ammonium fabric softening compound DEQA having formula (1) above and/or formula (2) below, wherein:

Each Y is -0-(0)C-, -(R)N-(O)C-, -C(O)-N(R)-, or -C(O)-O-, preferably -O -(O)C-;

m is 2 or 3; preferably 2;

each n is 1 to 4, preferably 2;

Each R substituent is H or a short chain C _1-6 alkyl, preferably methyl, ethyl, propyl, benzyl, or mixtures thereof, more preferably C _1-3 alkyl; each R ¹ , or YR ¹ hydrophobe is saturated C _8-14 , preferably C _12-14 hydrocarbyl, or substituted hydrocarbyl substituent (IV is preferably about 10 or less, more preferably less than about 5), [the sum of the carbon numbers in the hydrophobe is the ^R1 group, or the sum of the carbon numbers in the ^YR1 group when Y is -0-(O)C- or -(R)N-(0)C-]. The counterion X ^(-) is the same as above. Preferably X ^(-) does not include phosphate.

Saturated _C8-14 fatty acyl groups can be pure derivatives or can be long chain mixtures.

Suitable fatty acid sources of the fatty acyl groups are coconut acid, lauric acid, caprylic acid and capric acid.

For C _12-14 (or C _11-13 ) hydrocarbyl groups, the group is preferably saturated, for example, preferably has an IV value of less than about 10, preferably less than about 5.

It is understood that the substituents R and ^R can be optionally substituted with various groups such as alkoxy or hydroxyl, and can be linear or branched, as long as the ^R group retains its essentially hydrophobic character. A compound that may be considered preferred is a biodegradable diester variant of ditallow dimethyl ammonium chloride (hereinafter "DTDMAC"), which is a widely used fabric softener.

A preferred long chain DEQA is a DEQA prepared from a starting material containing a high content of polyunsaturation, i.e., N,N-bis(acyloxyethyl)-N,N-dimethylammonium chloride, wherein the acyl group consists of Polyunsaturated fatty acids, for example, derived from a mixture of tallow fatty acid and soybean fatty acid. Another preferred long chain DEQA is dioleoyl (nominal) DEQA, ie, a DEQA in which N,N-bis(oleoyloxyethyl)-N,N-dimethylammonium chloride is the major constituent. Preferred fatty acid sources for the DEQAs are vegetable oils, and/or partially hydrogenated vegetable oils, which have a high content of unsaturated groups, eg, oleoyl. A preferred medium chain DEQAs is the cocoacyl DEQA (derived from coconut fatty acids), i.e., N,N-bis(cocoyloxyethyl)-N,N-dimethylammonium chloride, which is exemplified hereinafter is DEQA ⁶ , and N,N-bis(lauroyloxyethyl)-N,N-dimethylammonium chloride.

When a diester is used and described herein, it may include the monoester present. Preferably at least about 80% of DEQA is in diester form, and 0% to about 20% may be DEQA monoester, e.g., one ^YR group is OH, or -C(O)OH, and for Formula 1 Say m is 2. Corresponding diamides and/or mixed ester-amides may also include actives with a long chain hydrophobic group, for example, a YR ¹ group is -N(R)H, or -C(O)OH. In the following description, any statement, for example, of the content of the monoester active also applies to the monoamide active. For softness, the percentage of monoester should be as low as possible, preferably not more than about 5%, under no/low detergent carry-out laundry conditions. However, under conditions of high anionic detergent surfactant or detergent builder carry-over, some monoesters are preferred. The overall ratio of diester to monoester is from about 100:1 to about 2:1, preferably from about 50:1 to about 5:1, more preferably from about 13:1 to about 8:1. Under high detergent carry-over conditions, the di/monoester ratio is preferably about 11:1. The level of monoester present can be controlled during the production of DEQA.

The compounds described above for use in the practice of the present invention as biodegradable quaternized ester-amine softening materials can be prepared using standard chemical reactions. In one _synthesis of DTDMAC diester variants, where R is, for example, alkyl, an amine of formula RN( _CH2CH2OH ) ₂ is esterified at both hydroxyl positions with an acid chloride of formula ^R1C (O)Cl , to form amines, which can be made cationic (one R is H) by acidification, which is a class of softeners, or then quaternized with an alkyl halide, RX, to give the desired reaction product (where R and R ¹ is as defined above). It should be understood, however, that the sequence of reactions allows a wide choice of reagents to be prepared to those skilled in the chemical arts.

Another DEQA softener active suitable for formulating the concentrated clear liquid fabric softener compositions of the present invention has formula (1) above wherein one R group is a C _1-4 hydroxyalkyl group, preferably one of the R groups is hydroxyethyl. An example of such a hydroxyethyl ester active agent is bis(acyloxyethyl)(2-hydroxyethyl)methylammonium methosulfate, where the acyl group is the same as in DEQA ¹ , exemplified hereinafter as DEQA ⁸ .

(2) The second class of DEQA active agents has the general formula: Wherein each of Y, R, R ¹ and X ^(-) has the same meaning as above. Such compounds include those having the formula:

[CH ₃ ] ₃ N ⁽⁺⁾ [CH ₂ CH(CH ₂ O(O)CR ¹ )O(O)CR ¹ ]Cl ^(-)

wherein each R is methyl or ethyl, preferably each ^R is in the range of C _15-19 . Branches and substituents may be present in the alkyl or alkenyl chain. The anion X ^(-) in the molecule is the same as in DEQA (1) above. When a diester is used and described herein, it may include the monoester present. The amount of monoester that can be present is the same as in DEQA (1). A preferred example of a DEQA of formula (2) is a "propyl" esterquat fabric softener active having the formula 1,2-bis(acyloxy)-3-trimethylpropylammonium chloride, wherein the acyl group is associated with Same as in DEQA ⁵ , exemplified as DEQA ⁹ hereinafter.

Reagents of these types and methods for their preparation are disclosed in US Patent 4,137,180, Naik et al., issued January 30, 1979, which is incorporated herein by reference.

In preferred softener actives (1) and (2), each ^R is hydrocarbyl, or substituted hydrocarbyl, preferably alkyl, monounsaturated alkenyl, and polyunsaturated alkenyl, wherein the softener The active contains at least about 3%, preferably at least about 5%, more preferably at least about 10%, and even more preferably at least about 15% by weight of the total softener active present; The agent preferably contains a mixture of ^R groups, especially in a single molecule, likewise, optionally but preferably saturated ^R groups contain branches, for example, they are derived from isostearic acid, at least partially saturated ^R groups Such groups are such that the total amount of active agent represented by branched groups is preferably from about 1% to about 90%, preferably from about 10% to about 70%, more preferably from about 20% to about 50%. The DEQAs of the present invention may contain low levels of fatty acids, which may be derived from unreacted starting materials used to form the DEQA and/or by-products of any partial degradation (hydrolysis) as softener actives in the finished composition. Low levels of free fatty acid are preferred, preferably less than about 10%, more preferably less than about 5%, by weight of the softener active. II. Main solvent system

The compositions of the present invention contain less than about 40%, preferably from about 10% to about 35%, more preferably from about 12% to about 25%, even more preferably from about 14% to about 20%, by weight of the composition, of primary solvent. The primary solvent is chosen to minimize the effect of solvent odor in the composition and to provide low viscosity to the final composition. For example, isopropyl alcohol is not very effective and it has a strong odor. n-propanol is more effective, but also has a noticeable odor. Several butanols are also odorous, but they can be used for effective clarity/stability, especially if they are used as part of the primary solvent system to reduce their odor. Alcohols are also selected for optimum low temperature stability, i.e. they are capable of forming liquid compositions having acceptably low viscosity and being translucent, preferably transparent, down to about 40°F (about 4.4°C), And can be reconstituted after storage as low as about 20°F (about 6.7°C).

The suitability of any primary solvent for formulating a liquid concentrated, preferably clear, fabric softener composition of the present invention with the necessary stability is an accidental choice. Appropriate solvents can be selected according to their octanol/water partition coefficient (P). The octanol/water partition coefficients of major solvents are the ratio between their equilibrium concentrations in octanol and water. The partition coefficients of the principal solvent components of the invention are generally given in terms of their base 10 logarithms, logP.

The logP of many components has been reported; for example, the Pomona92 database, available from Daylight Chemical Information Systems, Inc. (Daylight CIS), Irvine, California, contains many of these data, and also cites the original literature. However, logP values are most conveniently calculated by the "CLOGP" program (also available from Daylight CIS). The program also lists logP values for experiments when logP values are available in the Pomona92 database. The "calculated logP value" (ClogP) was determined by the fragmentation method of Hansch and Leo (cf. A. Leo, in Comprehensive Medicinal Chemistry, Vol. 4, C. Hansch, P.G. Sammens, J.B. Taylor and C.A. Ramsden , Eds., p.295, Pergamon Press, 1990, which is incorporated herein by reference). Fragmentation methods are based on the chemical structure of each component and take into account the number and type of atoms, connectivity of atoms, and chemical bonds. ClogP values are the most reliable and are widely used to predict this physicochemical property, ClogP values are preferably used instead of experimental logP values to select the main solvent components useful in the present invention. Other methods that can be used to calculate ClogP values include, for example, Crippen's fragmentation method disclosed in J.Chem.Inf.Comput.Sci., 27, 21 (1987); in J.Chem.Inf.Comput.Sci. Viswanadhan's fragmentation method disclosed in , 29, 163 (1989); and Broto's method disclosed in "European Journal of Medicinal Chemistry-Theoretical Chemistry), 19, 71 (1984).

The primary solvent of the present invention is selected from those having a ClogP value of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, more preferably from about 0.40 to about 0.60, said primary solvent is preferably asymmetric, and preferably has The melting point or solidification point, that is, it is a liquid at or near room temperature. Solvents with low molecular weight and biodegradable are also desirable for certain purposes. Very asymmetric solvents are highly desirable for the present invention, and highly symmetrical solvents with centers of symmetry, such as 1,7-heptanediol, or 1,4-bis(hydroxymethyl)cyclohexane, do not appear to provide Compositions that are substantially transparent even if their ClogP values fall within the preferred range. A composition containing about 27% bis(oleoyloxyethyl)dimethylammonium chloride, about 16-20% of the primary solvent, and about 4-6% ethanol was tested at about 40°F (about 4.4°C) Whether it remains transparent during storage and whether it recovers after freezing at about 0°F (about -18°C), one can choose the most suitable primary solvent.

The most preferred primary solvent can be determined by the performance of the freeze-dried diluted treatment composition used to treat fabrics. These dilute compositions are shown to have fabric softener dispersing action, exhibiting a more monolayer appearance than conventional fabric softener compositions. The closer the monolayer appearance is, the better the performance of the composition. These compositions provide surprisingly good fabric softening compared to similar compositions prepared in a conventional manner using the same fabric softener active. These compositions also inherently provide improved perfume deposition compared to conventional fabric softening compositions, especially when the perfume is added to the composition at or near room temperature.

Suitable primary solvents are listed in the various lists below, for example, aliphatic and/or cycloaliphatic diols with the given number of carbon atoms; monohydric alcohols; derivatives of glycerol; alkoxylates of diols; and all mixtures of the above. Preferred primary solvents are in italics and most preferred primary solvents are in bold. The reference number is the Chemical Abstracts Registry Number (CAS No.) of the compound with that number. Novel compounds have established methods described hereinafter that can be used to prepare the compounds. For comparison, some unsuitable main solvents are also listed below. However, unsuitable primary solvents may be mixed with suitable primary solvents. Suitable primary solvents can be used to prepare concentrated fabric softener compositions and meet the stability/clarity requirements set forth herein.

Many diol principal solvents having the same chemical formula can exist as many stereoisomers and/or optical isomers. Each isomer is usually registered with a different CAS registry number. For example, the different isomers of 4-methyl-2,3-hexanediol are registered with at least the following CAS registry numbers: 146452-51-9; 146452-50-8; 146452-49-5; 146452-48-4 ; 123807-34-1; 123807-33-0; 123807-32-9; and 123807-31-8.

For simplicity, in the tables below, only one CAS registry number is listed for each chemical formula. This disclosure is for illustration only and is sufficient to practice the invention. This disclosure is not limiting. Therefore, it should be understood that other isomers having other CAS Registry numbers and mixtures thereof are also included in the present invention. Likewise, when a CAS Registry number indicates the presence of certain particular isotopes, eg, deuterium, tritium, carbon-13, etc., it should be understood that materials containing naturally occurring isotopes are also included, and vice versa.

Table I

Monohydric alcohol

CAS registry number n-propanol 71-23-8

CAS Registry Number 2-Butanol     15892-23-62-Methyl-2-propanol 75-65-0 N/A Isomer 2-Methyl-1-propanol 78-83-1

Table II

Applicable isomers of C6 diols CAS registration number 2,3-dimethyl-2,3-butanediol 76-09-52, 3-dimethyl-1,2-butanediol 66553-15-93 ,3-Dimethyl-1,2-butanediol 59562-82-22-Methyl-2,3-pentanediol 7795-80-43-Methyl-2,3-pentanediol 63521-37- 94-1 Methyl-2,3-pentanediol 7795-79-12,3-Hexanediol 617-30-13,4-Hexanediol 922-17-82-Ethyl-1,2-Butanediol Alcohol 66553-16-02-Methyl-1,2-pentanediol   20667-05-43-Methyl-1,2-pentanediol   159623-53-74-Methyl-1,2-pentanediol 72110 -08-81,2-Hexanediol 6920-22-5 Not applicable isomer 2-ethyl-2-methyl-1,3-propanediol 2-isopropyl-1,3-propanediol 2-propyl -1,3-propanediol 2,2-dimethyl-1,3-butanediol 2,3-dimethyl-1,3-butanediol 2-ethyl-1,3-butanediol 2, 2-Dimethyl-1,4-butanediol 2,3-Dimethyl-1,4-butanediol 2-ethyl-1,4-butanediol 2-methyl-1,3-pentane Diol 3-methyl-1,3-pentanediol 4-methyl-1,3-pentanediol 2-methyl-1,4-pentanediol 3-methyl-1,4-pentanediol 4-methyl-1,4-pentanediol 2-methyl-1,5-pentanediol 3-methyl-1,5-pentanediol 2-methyl-2,4-pentanediol 3- Methyl-2,4-pentanediol 1,3-hexanediol 1,4-hexanediol 1,5-hexanediol 1,6-hexanediol 2,4-hexanediol 2,5-hexanediol diol

Table III

Suitable isomers of C7 diols CAS registry number 2-butyl-1,3-propanediol 2612-26-22,2-diethyl-1,3-propanediol 115-76-42-(1-methylpropyl )-1,3-propanediol 33673-01-72-(2-methylpropyl)-1,3-propanediol 26462-20-82-methyl-2-propyl-1,3-propanediol 78-26- 22,3,3-Trimethyl-1,2-butanediol Method B2-Ethyl-2-methyl-1,4-butanediol 76651-98-42-Ethyl-3-methyl-1 ,4-Butanediol 66225-34-12-Propyl-1,4-Butanediol 62946-68-32-Isopropyl-1,4-Butanediol 39497-66-02,2-Dimethyl -1,5-pentanediol 3121-82-22, 3-dimethyl-1,5-pentanediol 81554-20-32, 4-dimethyl-1,5-pentanediol 2121-69- 93,3-Dimethyl-1,5-pentanediol 53120-74-42,3-Dimethyl-2,3-pentanediol 6931-70-02,4-Dimethyl-2,3- Pentylene glycol 66225-53-43, 4-dimethyl-2,3-pentanediol 37164-04-84, 4-dimethyl-2,3-pentanediol 89851-45-62, 3-diol Methyl-3,4-pentanediol Method B2-Ethyl-1,5-pentanediol 14189-13-02-Methyl-1,6-hexanediol 25258-92-83-Methyl-1, 6-Hexanediol 4089-71-82-Methyl-2,3-Hexanediol 59215-55-33-Methyl-2,3-Hexanediol 139093-40-64-Methyl-2,3- Hexylene glycol ***5-Methyl-2,3-hexanediol Method B2-Methyl-3,4-hexanediol Method B3-Methyl-3,4-hexanediol 18938-47-11, 3-Heptanediol 23433-04-71, 4-Heptanediol 40646-07-91, 5-Heptanediol 60096-09-51, 6-Heptanediol Butyl Isomer - 2724-2175 1,3-propanediol 2612-26-22-propyl-1,4-butanediol 62946-68-32-ethyl-1,5-pentanediol 14189-13-02,3-dimethyl -2,3-pentanediol 6931-70-02, 4-dimethyl-2,3-pentanediol 66225-53-43, 4-dimethyl-2,3-pentanediol 37164-04- 84,4-Dimethyl-2,3-pentanediol 89851-45-62,3-Dimethyl-3,4-pentanediol Method B2-methyl-1,6-hexanediol 25258-92 -83-Methyl-1,6-hexanediol 4089-71-81,3-heptanediol 23433-04-71,4-heptanediol 40646-07-91,5-heptanediol 960-096- 51,6-Gengyol 13175-27-4 More preferably more preferably 2,3-two-base-2, 3-pentol 6931-70-02, 4-two-based-2, 3-pentagon Diol 66225-53-43, 4-dimethyl-2,3-pentanediol 37164-04-84, 4-dimethyl-2,3-pentanediol 89851-45-62, 3-dimethyl Ethyl-3,4-pentanediol Isomers not suitable for Method B 2-Methyl-2-isopropyl-1,3-propanediol 2-Ethyl-3-methyl-1,2-butanediol 2,2,3-Trimethyl-1,3-butanediol 2-ethyl-2-methyl-1,3-butanediol 2-ethyl-3-methyl-1,3-butanediol Alcohol 2-isopropyl-1,3-butanediol 2-propyl-1,3-butanediol 2,2,3-trimethyl-1,4-butanediol 3-ethyl-1- Methyl-1,4-butanediol 2,3-dimethyl-1,2-pentanediol 2,4-dimethyl-1,2-pentanediol 3,3-dimethyl-1, 2-pentanediol 3,4-dimethyl-1,2-pentanediol 4,4-dimethyl-1,2-pentanediol 2-ethyl-1,2-pentanediol 2,2 -Dimethyl-1,3-pentanediol 2,3-Dimethyl-1,3-pentanediol 2,4-Dimethyl-1,3-pentanediol 2-ethyl-1,3 -pentanediol 3,4-dimethyl-1,3-pentanediol 4,4-dimethyl-1,3-pentanediol 2,2-dimethyl-1,4-pentanediol 2 , 3-Dimethyl-1,4-pentanediol 2,4-dimethyl-1,4-pentanediol 3,3-dimethyl-1,4-pentanediol 3,4-dimethyl Dimethyl-1,4-pentanediol 2,3-dimethyl-2,4-pentanediol 2,4-dimethyl-2,4-pentanediol 3,3-dimethyl-2,4 -Pentanediol 2-methyl-1,2-hexanediol 3-methyl-1,2-hexanediol 4-methyl-1,2-hexanediol 5-methyl-1,2-hexanediol Diol 2-methyl-1,3-hexanediol 3-methyl-1,3-hexanediol 4-methyl-1,3-hexanediol 5-methyl-1,3-hexanediol 2-methyl-1,4-hexanediol 3-methyl-1,4-hexanediol 4-methyl-1,4-hexanediol 5-methyl-1,4-hexanediol 2- Methyl-1,5-hexanediol 3-methyl-1,5-hexanediol 4-methyl-1,5-hexanediol 5-methyl-1,5-hexanediol 2-methyl -2,4-hexanediol 3-methyl-2,4-hexanediol 4-methyl-2,4-hexanediol 5-methyl-2,4-hexanediol 2-methyl-2 ,5-Hexanediol 3-Methyl-2,5-Hexanediol 1,2-Heptanediol 2,3-Heptanediol 2,4-Heptanediol 2,5-Heptanediol 2,6- Heptanediol 3,4-Heptanediol 1,7-Heptanediol 3,5-Heptanediol***146452-51-9; 146452-50-8; 146452-49-5; 146452-48-4 ; 123807-34-1; 123807-33-0; 123807-32-9; 123807-31-8; and mixtures thereof.

Table IV

Octanediol Isomer Propylene Glycol Derivatives Chemical Name CAS Registry Number Applicable Isomer 2-(2-Methylbutyl)-1,3-Propanediol 87194-40-92-(1,1-Dimethylpropyl )-1,3-propanediol method D2-(1,2-dimethylpropyl)-1,3-propanediol method D2-(1-ethylpropyl)-1,3-propanediol 25462-28-62- (1-Methylbutyl)-1,3-propanediol 22131-29-92-(2,2-Dimethylpropyl)-1,3-propanediol Method D2-(3-Methylbutyl)-1 , 3-propanediol 25462-27-52-butyl-2-methyl-1,3-propanediol 3121-83-32-ethyl-2-isopropyl-1,3-propanediol 24765-55-72-ethyl Base-2-propyl-1,3-propanediol 25450-88-82-methyl-2-(1-methylpropyl)-1,3-propanediol 813-60-52-methyl-2-(2 -Methylpropyl)-1,3-propanediol 25462-42-42-tert-butyl-2-methyl-1,3-propanediol 25462-45-7 More preferred isomers 2-(1,1- Dimethylpropyl)-1,3-propanediol Method D2-(1,2-Dimethylpropyl)-1,3-propanediol Method D2-(1-Ethylpropyl)-1,3-propanediol 25462 -28-6 2-(2,2-Dimethylpropyl)-1,3-propanediol Method D2-Ethyl-2-isopropyl-1,3-propanediol 24765-55-72-Methyl-2- (1-methylpropyl)-1,3-propanediol 813-60-52-methyl-2-(2-methylpropyl)-1,3-propanediol 25462-42-42-tert-butyl-2 -Methyl-1,3-propanediol 25462-45-7 Inapplicable isomer 2-pentyl-1,3-propanediol Butanediol derivative Applicable isomer 2,2-diethyl-1,3- Butanediol 99799-77-62-(1-methylpropyl)-1,3-butanediol Method C2-Butyl-1,3-butanediol 83988-22-12-Ethyl-2,3 -Dimethyl-1,3-butanediol Method D2-(1,1-Dimethylethyl)-1,3-butanediol 67271-58-32-(2-methylpropyl)-1 , 3-butanediol method C2-methyl-2-isopropyl-1,3-butanediol method C2-methyl-2-propyl-1,3-butanediol 99799-79-83-methan Diethyl-2-isopropyl-1,3-butanediol method C3-methyl-2-propyl-1,3-butanediol method D2,2-diethyl-1,4-butanediol method H2-Methyl-2-propyl-1,4-butanediol method H2-(1-methylpropyl)-1,4-butanediol method H2-ethyl-2,3-dimethyl- 1,4-Butanediol Method F2-Ethyl-3,3-Dimethyl-1,4-Butanediol Method F2-(1,1-Dimethylethyl)-1,4-Butanediol 36976-70-22-(2-Methylpropyl)-1,4-butanediol Method F2-Methyl-3-propyl-1,4-butanediol 90951-76-13-Methyl-2 - Isopropyl-1,4-butanediol 99799-24-3 Preferred isomer 2,2-diethyl-1,3-butanediol 99799-77-62-(1-methylpropyl) -1,3-Butanediol Method C2-Butyl-1,3-Butanediol 83988-22-12-Ethyl-2,3-Dimethyl-1,3-Butanediol Method D2-(1 ,1-dimethylethyl)-1,3-butanediol 67271-58-32-(2-methylpropyl)-1,3-butanediol method C2-methyl-2-isopropyl -1,3-Butanediol Method C2-Methyl-2-Propyl-1,3-Butanediol 99799-79-83-Methyl-2-Propyl-1,3-Butanediol Method D2, 2-Diethyl-1,4-butanediol method H2-ethyl-2,3-dimethyl-1,4-butanediol method F2-ethyl-3,3-dimethyl-1, 4-Butanediol Method F2-(1,1-Dimethylethyl)-1,4-butanediol 36976-70-23-Methyl-2-olpropyl-1,4-butanediol 99799 -24-3 More preferred isomer 2-(1-methylpropyl)-1,3-butanediol method C2-(2-methylpropyl)-1,3-butanediol method C2- Butyl-1,3-butanediol 83988-22-12-methyl-2-propyl-1,3-butanediol 99799-79-83-methyl-2-propyl-1,3-butane Diol Method D2,2-Diethyl-1,4-Butanediol Method H2-Ethyl-2,3-Dimethyl-1,4-Butanediol Method F2-Ethyl-3,3-Diol Methyl-1,4-butanediol Method F2-(1,1-Dimethylethyl)-1,4-butanediol 36976-70-2 N/A Isomer 2-Butyl-1,4 -Butanediol 2-ethyl-3,3-dimethyl-1,2-butanediol 2-methyl-2-isopropyl-1,4-butanediol 3-methyl-2-iso Propyl-1,2-butanediol 2,2,3,3-tetramethyl-1,4-butanediol Trimethylpentanediol isomers Applicable isomers 2,2,3-trimethyl Dimethyl-1,3-pentanediol 35512-54-02, 2,4-trimethyl-1,3-pentanediol 144-19-42, 3,4-trimethyl-1,3-pentanediol Alcohol 116614-13-22, 4,4-Trimethyl-1,3-pentanediol 109387-36-23, 4,4-Trimethyl-1,3-pentanediol 81756-50-52, 2 ,3-Trimethyl-1,4-pentanediol Method H2,2,4-Trimethyl-1,4-pentanediol 80864-10-42,3,3-Trimethyl-1,4- Pentylene glycol method H2,3,4-Trimethyl-1,4-pentanediol 92340-74-43, 3,4-Trimethyl-1,4-pentanediol 16466-35-62,2, 3-Trimethyl-1,5-pentanediol Method F2,2,4-Trimethyl-1,5-pentanediol 3465-14-32,3,3-Trimethyl-1,5-pentanediol Diol Method A2,3,4-Trimethyl-1,5-pentanediol 85373-83-72, 3,3-Trimethyl-2,4-pentanediol 24892-51-12,3,4 -Trimethyl-2,4-pentanediol 24892-52-2 Preferred isomer 2,2,3-Trimethyl-1,3-pentanediol 35512-54-02,2,4-Trimethyl Base-1,3-pentanediol 144-19-42, 3,4-trimethyl-1,3-pentanediol 116614-13-22, 4,4-trimethyl-1,3-pentanediol Alcohol 109387-36-23, 4,4-Trimethyl-1,3-pentanediol 81756-50-52, 2,3-Trimethyl-1,4-pentanediol Method H2,2,4- Trimethyl-1,4-pentanediol 80864-10-42,3,3-Trimethyl-1,4-pentanediol Method F2,3,4-Trimethyl-1,4-pentanediol 92340-74-43, 3,4-Trimethyl-1,4-pentanediol 16466-35-62, 2,3-Trimethyl-1,5-pentanediol Method A2, 2,4-tris Methyl-1,5-pentanediol 3465-14-32, 3,3-Trimethyl-1,5-pentanediol Method A2, 3,4-Trimethyl-2,4-pentanediol 24892 -52-2 More preferred isomer 2,3,4-trimethyl-1,3-pentanediol 116614-13-22,3,4-trimethyl-1,4-pentanediol 92340- 74-42,2,3-Trimethyl-1,5-pentanediol Method A2,2,4-Trimethyl-1,5-pentanediol 3465-14-32,3,3-Trimethylpentanediol -1,5-Pentanediol Method A does not apply isomer 2,3,3-Trimethyl-1,2-pentanediol 2,3,4-Trimethyl-1,2-pentanediol 2 , 4,4-Trimethyl-1,2-pentanediol 3,3,4-Trimethyl-1,2-pentanediol 3,4,4-Trimethyl-1,2-pentanediol 2,3,4-Trimethyl-2,3-pentanediol 2,4,4-Trimethyl-2,3-pentanediol 3,4,4-trimethyl-2,3-pentanediol Alcohol Ethyl Methylpentanediol Isomer Applicable Isomer 2-Ethyl-2-methyl-1,3-pentanediol Method C2-Ethyl-3-methyl-1,3-pentanediol Method D2-Ethyl-4-methyl-1,3-pentanediol 148904-97-63-Ethyl-2-methyl-1,3-pentanediol 55661-05-72-Ethyl-2- Methyl-1,4-pentanediol Method H2-Ethyl-3-methyl-1,4-pentanediol Method F2-Ethyl-4-methyl-1,4-pentanediol Method G3-B Ethyl-2-methyl-1,4-pentanediol Method F3-Ethyl-3-methyl-1,4-pentanediol Method F2-Ethyl-2-methyl-1,5-pentanediol Method F2-Ethyl-3-methyl-1,5-pentanediol 54886-83-82-Ethyl-4-methyl-1,5-pentanediol Method F3-Ethyl-3-methyl- 1,5-Pentanediol 57740-12-23-Ethyl-2-methyl-2,4-pentanediol Method G more preferred isomer 2-Ethyl-2-methyl-1,3- Pentanediol Method C2-Ethyl-3-methyl-1,3-pentanediol Method D2-Ethyl-4-methyl-1,3-pentanediol 148904-97-63-Ethyl-2- Methyl-1,3-pentanediol 55661-05-72-Ethyl-2-methyl-1,4-pentanediol Method H2-Ethyl-3-methyl-1,4-pentanediol Method F2-Ethyl-4-methyl-1,4-pentanediol Method G3-Ethyl-3-methyl-1,5-pentanediol 57740-12-23-Ethyl-2-methyl-2 , 4-pentanediol Method G does not apply isomer 2-ethyl-3-methyl-1,2-pentanediol 2-ethyl-4-methyl-1,2-pentanediol 3-ethane Base-2-methyl-1,2-pentanediol 3-ethyl-3-methyl-1,2-pentanediol 3-ethyl-4-methyl-1,2-pentanediol 3- Ethyl-4-methyl-1,3-pentanediol 3-ethyl-4-methyl-1,4-pentanediol 3-ethyl-2-methyl-1,5-pentanediol 3 -Ethyl-2-methyl-2,3-pentanediol 3-ethyl-4-methyl-2,3-pentanediol 3-ethyl-3-methyl-2,4-pentanediol Propylpentanediol Isomer Applicable Isomer 2-Isopropyl-1,3-pentanediol Method D2-Propyl-1,3-pentanediol Method C2-Isopropyl-1,4-pentanediol Diol method H2-propyl-1,4-pentanediol method H3-isopropyl-1,4-pentanediol method H2-isopropyl-1,5-pentanediol 90951-89-63-propane 2-Propyl-1,3-pentanediol Method C More preferred isomers 2-Isopropyl-1,3-pentanediol Method D2-Propyl-1,3-pentanediol Method C2-Isopropyl- 1,4-pentanediol Method H2-Propyl-1,4-pentanediol Method H3-Isopropyl-1,4-pentanediol Method H3-Propyl-2,4-pentanediol Method C No Applicable isomers 2-propyl-1,2-pentanediol 2-isopropyl-1,2-pentanediol 3-propyl-1,4-pentanediol 2-propyl-1,5- Pentylene glycol 3-isopropyl-2,4-pentanediol dimethyl hexanediol isomer applicable isomer 2,2-dimethyl-1,3-hexanediol 22006-96-82, 3-Dimethyl-1,3-hexanediol Method D2, 4-Dimethyl-1,3-hexanediol 78122-99-32, 5-Dimethyl-1,3-hexanediol Method C3 , 4-Dimethyl-1,3-hexanediol Method D3, 5-Dimethyl-1,3-hexanediol Method D4, 4-Dimethyl-1,3-hexanediol Method C4,5 -Dimethyl-1,3-hexanediol Method C2,2-Dimethyl-1,4-hexanediol Method F2,3-Dimethyl-1,4-hexanediol Method F2,4-diol Methyl-1,4-hexanediol Method G2,5-Dimethyl-1,4-hexanediol 22417-60-33,3-Dimethyl-1,4-hexanediol Method F3,4- Dimethyl-1,4-hexanediol Method E3,5-Dimethyl-1,4-hexanediol Method H4,5-Dimethyl-1,4-hexanediol Method E5,5-Dimethyl-1,4-hexanediol Method E5,5-Dimethyl-1,4-hexanediol Method E Dimethyl-1,4-hexanediol 38624-38-32, 2-Dimethyl-1,5-hexanediol Method A2, 3-Dimethyl-1,5-hexanediol 62718-05-22, 4-Dimethyl-1,5-hexanediol 73455-82-02, 5-Dimethyl-1,5-hexanediol 58510-28-43, 3-Dimethyl-1,5-hexanediol Alcohol 41736-99-63, 4-Dimethyl-1,5-hexanediol Method A3, 5-Dimethyl-1,5-hexanediol Method G4, 5-Dimethyl-1,5-hexanediol Diol Method F2, 2-Dimethyl-1,6-hexanediol 13622-91-82, 3-Dimethyl-1,6-hexanediol Method F2,4-Dimethyl-1,6- Hexanediol Method F2, 5-Dimethyl-1,6-Hexanediol 49623-11-23, 3-Dimethyl-1,6-Hexanediol Method F3, 4-Dimethyl-1,6 -Hexanediol 65363-45-32, 3-Dimethyl-2,4-hexanediol 26344-17-22, 4-Dimethyl-2,4-hexanediol 29649-22-72, 5- Dimethyl-2,4-hexanediol 3899-89-63, 3-dimethyl-2,4-hexanediol 42412-51-13, 4-dimethyl-2,4-hexanediol 90951 -83-03,5-Dimethyl-2,4-hexanediol 159300-34-24,5-Dimethyl-2,4-hexanediol Method D5,5-Dimethyl-2,4- Hexanediol 108505-10-82, 3-Dimethyl-2,5-Hexanediol Method G2, 4-Dimethyl-2,5-Hexanediol Method G2,5-Dimethyl-2,5 -Hexanediol 110-03-23,3-Dimethyl-2,5-Hexanediol Method H3,4-Dimethyl-2,5-Hexanediol 99799-30-13,3-Dimethyl -2,6-Hexanediol Method A more preferred isomer 2,2-Dimethyl-1,3-Hexanediol 22006-96-82,3-Dimethyl-1,3-Hexanediol Method D2,4-Dimethyl-1,3-hexanediol 78122-99-32,5-Dimethyl-1,3-hexanediol Method C3,4-Dimethyl-1,3-hexanediol Alcohol Method D3,5-Dimethyl-1,3-Hexanediol Method D4,4-Dimethyl-1,3-Hexanediol Method C4,5-Dimethyl-1,3-Hexanediol Method C2,2-Dimethyl-1,4-hexanediol Method H2,3-Dimethyl-1,4-hexanediol Method F2,4-Dimethyl-1,4-hexanediol Method G2, 5-Dimethyl-1,4-hexanediol 22417-60-33,3-Dimethyl-1,4-hexanediol Method F3, 4-Dimethyl-1,4-hexanediol Method E3 ,5-Dimethyl-1,4-hexanediol Method H4,5-Dimethyl-1,4-hexanediol Method E5,5-Dimethyl-1,4-hexanediol 38624-38- 32,2-Dimethyl-1,5-hexanediol Method A 2,3-Dimethyl-1,5-hexanediol 62718-05-22,4-Dimethyl-1,5-hexanediol 73455-82-02, 5-Dimethyl-1,5-hexanediol 58510-28-43, 3-Dimethyl-1,5-hexanediol 41736-99-63, 4-Dimethyl- 1,5-Hexanediol Method A3, 5-Dimethyl-1,5-Hexanediol Method G4, 5-Dimethyl-1,5-Hexanediol Method F3, 3-Dimethyl-2, 6-Hexanediol Method A does not apply Isomer 2,3-Dimethyl-1,2-Hexanediol 2,4-Dimethyl-1,2-Hexanediol 2,5-Dimethyl- 1,2-Hexanediol 3,3-Dimethyl-1,2-Hexanediol 3,4-Dimethyl-1,2-Hexanediol 3,5-Dimethyl-1,2-Hexanediol Diol 4,4-Dimethyl-1,2-hexanediol 4,5-Dimethyl-1,2-hexanediol 5,5-Dimethyl-1,2-hexanediol 2,3 -Dimethyl-2,3-hexanediol 2,4-dimethyl-2,3-hexanediol 2,5-dimethyl-2,3-hexanediol 3,4-dimethyl- 2,3-Hexanediol 3,5-Dimethyl-2,3-Hexanediol 4,4-Dimethyl-2,3-Hexanediol 4,5-Dimethyl-2,3-Hexanediol Diol 5,5-Dimethyl-2,3-hexanediol 2,2-Dimethyl-3,4-hexanediol 2,3-Dimethyl-3,4-hexanediol 2,4 -Dimethyl-3,4-hexanediol 2,5-Dimethyl-3,4-hexanediol 3,4-Dimethyl-3,4-hexanediol ethyl hexanediol isomers More preferred isomers 2-Ethyl-1,3-hexanediol 94-96-24-Ethyl-1,3-hexanediol Method C2-Ethyl-1,4-hexanediol 148904-97 -64-Ethyl-1,4-hexanediol 1113-00-42-Ethyl-1,5-hexanediol 58374-34-83-Ethyl-2,4-hexanediol Method C4-Ethyl -2,4-Hexanediol 33683-47-5 3-Ethyl-2,5-Hexanediol Method F N/A Isomer 4-Ethyl-1,5-Hexanediol 2-Ethyl-1, 6-hexanediol 3-ethyl-1,4-hexanediol 3-ethyl-1,5-hexanediol 3-ethyl-1,6-hexanediol 2-ethyl-1,2- Hexanediol 3-Ethyl-1,2-Hexanediol 4-Ethyl-1,2-Hexanediol 3-Ethyl-2,3-Hexanediol 4-Ethyl-2,3-Hexanediol Alcohol 3-Ethyl-3,4-Hexanediol 3-Ethyl-1,3-Hexanediol Isomers of Methyl Heptanediol Applicable Isomers 2-Methyl-1,3-Heptanediol 109417 -38-13-Methyl-1,3-heptanediol 165326-88-54-Methyl-1,3-heptanediol method C5-methyl-1,3-heptanediol method D6-methyl- 1,3-Heptanediol Method C2-Methyl-1,4-heptanediol 15966-03-73-Methyl-1,4-heptanediol 7748-38-14-Methyl-1,4-heptanediol Diol 72473-94-05-Methyl-1,4-heptanediol 63003-04-36-Methyl-1,4-heptanediol 99799-25-42-Methyl-1,5-heptanediol 141605-00-73-Methyl-1,5-heptanediol Method A4-Methyl-1,5-heptanediol Method A5-Methyl-1,5-heptanediol 99799-26-56-Methyl -1,5-Heptanediol 57740-00-82-Methyl-1,6-Heptanediol 132148-22-23-Methyl-1,6-Heptanediol Method G4-Methyl-1,6- Heptanediol 156307-84-55-Methyl-1,6-Heptanediol Method A6-Methyl-1,6-Heptanediol 5392-57-42-Methyl-2,4-Heptanediol 38836- 26-93-Methyl-2,4-heptanediol 6964-04-14-Methyl-2,4-heptanediol 165326-87-45-Methyl-2,4-heptanediol Method C6-Me G-2,4-heptanediol 79356-95-92-methyl-2,5-heptanediol 141605-02-93-methyl-2,5-heptanediol method G4-methyl-2,5 -Heptanediol 156407-38-45-Methyl-2,5-Heptanediol 148843-72-56-Methyl-2,5-Heptanediol 51916-46-22-Methyl-2,6-Heptanediol Diol 73304-48-03-Methyl-2,6-heptanediol 29915-96-64-Methyl-2,6-heptanediol 106257-69-63-Methyl-3,4-heptanediol 18938-50-62-Methyl-3,5-heptanediol Method C3-Methyl-3,5-heptanediol 99799-27-64-Methyl-3,5-heptanediol 156407-37-3 More preferred isomers 2-methyl-1,3-heptanediol 109417-38-13-methyl-1,3-heptanediol 165326-88-54-methyl-1,3-heptanediol method C5-Methyl-1,3-Heptanediol Method D6-Methyl-1,3-Heptanediol Method C2-Methyl-1,4-Heptanediol 15966-03-73-Methyl-1,4 -Heptanediol 7748-38-14-Methyl-1,4-heptanediol 72473-94-05-Methyl-1,4-heptanediol 63003-04-36-Methyl-1,4-heptanediol Diol 99799-25-42-Methyl-1,5-heptanediol 141605-00-73-Methyl-1,5-heptanediol Method A4-Methyl-1,5-heptanediol Method A5- Methyl-1,5-heptanediol 99799-26-56-methyl-1,5-heptanediol 57740-00-82-methyl-1,6-heptanediol 132148-22-23-methyl -1,6-Heptanediol Method G4-Methyl-1,6-Heptanediol 156307-84-55-Methyl-1,6-Heptanediol Method A6-Methyl-1,6-Heptanediol 5392-57-42-Methyl-2,4-heptanediol 38836-26-93-Methyl-2,4-heptanediol 6964-04-14-Methyl-2,4-heptanediol 165326- 87-45-Methyl-2,4-heptanediol Method C6-Methyl-2,4-heptanediol 79356-95-92-Methyl-2,5-heptanediol 141605-02-93-methano H4-Methyl-2,5-Heptanediol Method H4-Methyl-2,5-Heptanediol 156407-38-45-Methyl-2,5-Heptanediol 148843-72-56-Methyl-2,5 -Heptanediol 51916-46-22-Methyl-2,6-heptanediol 73304-48-03-Methyl-2,6-heptanediol 29915-96-64-Methyl-2,6-heptanediol Diol 106257-69-63-Methyl-3,4-heptanediol 18938-50-62-Methyl-3,5-heptanediol Method C4-Methyl-3,5-heptanediol 156407-37 -3 N/A isomer 2-methyl-1,7-heptanediol 3-methyl-1,7-heptanediol 4-methyl-1,7-heptanediol 2-methyl-2, 3-Heptanediol 3-methyl-2,3-heptanediol 4-methyl-2,3-heptanediol 5-methyl-2,3-heptanediol 6-methyl-2,3- Heptanediol 2-methyl-3,4-heptanediol 4-methyl-3,4-heptanediol 5-methyl-3,4-heptanediol 6-methyl-3,4-heptanediol Alcohol 2-methyl-1,2-heptanediol 3-methyl-1,2-heptanediol 4-methyl-1,2-heptanediol 5-methyl-1,2-heptanediol 6 -Methyl-1,2-heptanediol octanediol isomers More preferred isomers 2,4-octanediol 90162-24-62, 5-octanediol 4527-78-02,6-octanediol Diol method A2, 7-octanediol 19686-96-53, 5-octanediol 24892-55-53, 6-octanediol 24434-09-1 Not applicable isomer 1,2-octanediol 1117 -86-81, 3-octanediol 23433-05-81, 4-octanediol 51916-47-31, 5-octanediol 2736-67-61, 6-octanediol 4060-76-61, 7 - Octanediol 13175-32-11, 8-octanediol 629-41-42, 3-octanediol eg 98464-24-53, 4-octanediol eg 99799-31-23, 5-octanediol Diol eg, 129025-63-4

Table V

Chemical name of nonanediol isomers CAS registry number Preferred isomer 2,3,3,4-tetramethyl-2,4-pentanediol 19424-43-2 Applicable isomer 3-tert-butyl-2 , 4-Pentanediol 142205-14-92, 5,5-Trimethyl-2,4-Hexanediol 97460-08-73, 3,4-Trimethyl-2,4-Hexanediol Method D3 , 3,5-trimethyl-2,4-hexanediol 27122-58-33,5,5-trimethyl-2,4-hexanediol Method D4,5,5-trimethyl-2, 4-Hexanediol Method D3, 3,4-Trimethyl-2,5-Hexanediol Method H3, 3,5-Trimethyl-2,5-Hexanediol Method G Not applicable 500 non-applicable isomers, including the following isomers: 2,4,5-Trimethyl-2,4-hexanediol 36587-81-2 Erythro-2,3,5-Trimethyl-2 , 4-hexanediol 26344-20-7threo-2,3,5-trimethyl-2,4-hexanediol 26343-49-72-butyl-2-ethyl-1,3-propanediol 115-84-4threo-2,3,5-trimethyl-2,4-hexanediol 26343-49-7

Table VI

Alkyl glyceryl ethers, di(hydroxyalkyl) ethers, and aryl glyceryl ethers Preferred monoglyceryl ethers and derivatives Triethoxylated 3-(butoxy)-1,2-propanediol tetraethoxy More preferred monoglycerol ethers and derivatives of 3-(n-pentoxy)-1,2-propanediol CAS registry number 3-(n-pentoxy)-1,2-propanediol 22636-32-43-( 2-pentyloxy)-1,2-propanediol 3-(3-pentyloxy)-1,2-propanediol 3-(2-methyl-1-butoxyl)-1,2-propanediol 3-( Is-pentyloxy)-1,2-propanediol 3-(3-methyl-2-butoxy)-1,2-propanediol 3-(cyclohexyloxy)-1,2-propanediol 3-(1 -cyclohex-1-enyloxy)-1,2-propanediol 2-(pentyloxy)-1,3-propanediol 2-(2-pentyloxy)-1,3-propanediol 2-(3-pentane Oxy)-1,3-propanediol 2-(2-methyl-1-butoxy)-1,3-propanediol 2-(iso-pentyloxy)-1,3-propanediol 2-(3-methyl Base-2-butoxy)-1,3-propanediol 2-(cyclohexyloxy)-1,3-propanediol 2-(1-cyclohex-1-enyloxy)-1,3-propanediol pentaethyl Oxylated 3-(butoxy)-1,2-propanediol Hexaethoxylated 3-(butoxy)-1,2-propanediol Heptaethoxylated 3-(butoxy)- 1,2-propanediol octaethoxylated 3-(butoxy)-1,2-propanediol nonaethoxylated 3-(butoxy)-1,2-propanediol monopropoxylated 3 -(butoxy)-1,2-propanediol dibutylideneoxylated 3-(butoxy)-1,2-propanediol tributylidene oxide 3-(butoxy)-1,2-propanediol more Preferred bis(hydroxyalkyl) ethers bis(2-hydroxybutyl) ethers bis(2-hydroxycyclopentyl) ethers not suitable monoglyceryl ethers 3-ethoxy-1,2-propanediol 3-propoxy- 1,2-propanediol 3-isopropoxy-1,2-propanediol 3-butoxy-1,2-propanediol 3-isobutoxy-1,2-propanediol 3-tert-butoxy-1,2 -Propanediol 3-octyloxy-1,2-propanediol 3-(2-ethylhexyloxy)-1,2-propanediol 3-(cyclopentyloxy)-1,2-propanediol 3-(1-cyclo Hex-2-enyloxy)-1,2-propanediol 2-(1-cyclohex-2-enyloxy)-1,2-propanediol

Aromatic Glyceryl Ether Suitable Aromatic Glyceryl Ether 3-Phenoxy-1,2-Propanediol 3-Benzyloxy-1,2-Propanediol 3-(2-Phenylethoxy)-1,2-Propanediol 3-(1-phenyl-2-propoxy)-1,2-propanediol 2-phenoxy-1,3-propanediol 2-(m-tolyloxy)-1,3-propanediol 2-(p -methylphenoxy)-1,3-propanediol 2-benzyloxy-1,3-propanediol 2-(2-phenylethoxy)-1,3-propanediol 2-(1-phenylethoxy) -1,3-propanediol Preferred aromatic glyceryl ethers 3-phenoxy-1,2-propanediol 3-benzyloxy-1,2-propanediol 3-(2-phenylethoxy)-1,2 -Propanediol 2-(m-tolyloxy)-1,3-propanediol 2-(p-tolyloxy)-1,3-propanediol 2-benzyloxy-1,3-propanediol 2-(2-phenyl Ethoxy)-1,3-propanediol Preferred aromatic glyceryl ethers 3-phenoxy-1,2-propanediol 3-benzyloxy-1,2-propanediol 3-(2-phenylethoxy) -1,2-propanediol 2-(m-tolyloxy)-1,3-propanediol 2-(p-tolyloxy)-1,3-propanediol 2-(2-phenylethoxy)-1, 3-propanediol

Table VII

Cycloaliphatic Diols and Derivatives Chemical Name CAS Registry Number Preferred Cyclic Diols and Derivatives 1-Isopropyl-1,2-Cyclobutanediol 59895-32-83-Ethyl-4-methyl-1,2 -Cyclobutanediol 3-Propyl-1,2-Cyclobutanediol 3-Isopropyl-1,2-Cyclobutanediol 42113-90-61-Ethyl-1,2-Cyclopentanediol 67396 -17-21, 2-Dimethyl-1, 2-cyclopentanediol 33046-20-71, 4-Dimethyl-1, 2-cyclopentanediol 89794-56-92, 4, 5-tri Methyl-1,3-cyclopentanediol 3,3-Dimethyl-1,2-cyclopentanediol 89794-57-03, 4-Dimethyl-1,2-cyclopentanediol 70051-69 -33,5-Dimethyl-1,2-cyclopentadiol 89794-58-13-Ethyl-1,2-cyclopentadiol 4,4-Dimethyl-1,2-cyclopentadiol 70197-54-54-Ethyl-1,2-cyclopentanediol 1,1-bis(hydroxymethyl)cyclohexane 2658-60-81,2-bis(hydroxymethyl)cyclohexane 76155-27 -61,2-Dimethyl-1,3-cyclohexanediol 53023-07-71,3-bis(hydroxymethyl)cyclohexane 13022-98-51,3-Dimethyl-1,3- Cyclohexanediol 128749-93-91, 6-Dimethyl-1,3-cyclohexanediol 164713-16-01-Hydroxy-cyclohexaneethanol   40894-17-51-Hydroxy-cyclohexanemethanol     15753- 47-61-Ethyl-1,3-cyclohexanediol 10601-18-01-Methyl-1,2-cyclohexanediol 52718-65-72,2-Dimethyl-1,3-cyclohexane Diol 114693-83-32, 3-Dimethyl-1,4-cyclohexanediol 70156-82-02, 4-Dimethyl-1,3-cyclohexanediol 2,5-dimethyl- 1,3-cyclohexanediol 2,6-dimethyl-1,4-cyclohexanediol 34958-42-42-ethyl-1,3-cyclohexanediol 155433-88-82-hydroxycyclohexanediol Alkanol 24682-42-62-Hydroxyethyl-1-cyclohexanol 2-hydroxymethylcyclohexanol 89794-52-53-Hydroxyethyl-1-cyclohexanol 3-hydroxycyclohexanol 86576-87 -63-Hydroxymethylcyclohexanol 3-methyl-1,2-cyclohexanediol 23477-91-04, 4-dimethyl-1,3-cyclohexanediol 14203-50-04, 5- Dimethyl-1,3-cyclohexanediol 4,6-dimethyl-1,3-cyclohexanediol 16066-66-34-Ethyl-1,3-cyclohexanediol 4-hydroxyethyl -1-Cyclohexanol 4-Hydroxymethylcyclohexanol                                                                                                                        Alcohol 51335-83-25-Ethyl-1,3-Cyclohexanediol 1,2-Cycloheptanediol 108268-28-62-Methyl-1,3-Cycloheptanediol 101375-80-82-Methanol 1,4-cycloheptanediol 4-methyl-1,3-cycloheptanediol 5-methyl-1,3-cycloheptanediol 5-methyl-1,4-cycloheptanediol 90201 -00-66-methyl-1, 4-ringgenol 1, 3-ring sibol 101935-36-81, 4-ring Xin diol 73982-04-41, 5-ring Xin dibol 23418- 82-81,2-cyclohexanediol diethoxylate 1,2-cyclohexanediol triethoxylate 1,2-cyclohexanediol tetraethoxylate 1,2-cyclohexanediol pentaethoxylate Ethoxylates 1,2-Cyclohexanediol Hexaethoxylate 1,2-Cyclohexanediol Heptaethoxylate 1,2-Cyclohexanediol Octaethoxylate 1,2-Cyclohexanediol Alcohol Nonaethoxylate 1,2-Cyclohexanediol Monopropoxylate 1,2-Cyclohexanediol Monobutylidene Oxylate 1,2-Cyclohexanediol Dibutylidene Oxylate 1,2- Cyclohexanediol Tributylene Oxide Chemical Name CAS Registry Number More Preferred Cyclodiols and Derivatives 1-Isopropyl-1,2-Cyclobutanediol 59895-32-83-Ethyl-4-methyl -1,2-cyclobutanediol 3-propyl-1,2-cyclobutanediol 3-isopropyl-1,2-cyclobutanediol 42113-90-61-ethyl-1,2-cyclobutanediol Pentylene glycol 67396-17-21, 2-dimethyl-1,2-cyclopentanediol 33046-20-71, 4-dimethyl-1,2-cyclopentanediol 89794-56-93,3 -Dimethyl-1,2-cyclopentanediol 89794-57-03,4-Dimethyl-1,2-cyclopentanediol 70051-69-33,5-Dimethyl-1,2-cyclo Pentylene glycol 89794-58-13-Ethyl-1,2-cyclopentanediol 4,4-Dimethyl-1,2-cyclopentanediol 70197-54-54-Ethyl-1,2-cyclopentadiol Pentylene glycol 1,1-bis(hydroxymethyl)cyclohexane 2658-60-81, 2-bis(hydroxymethyl)cyclohexane 76155-27-61,2-dimethyl-1,3-cyclohexane Ji dibol 53023-07-71, 3-two (hydroxytal) cyclonexane 13022-98-51-hydroxyl-cycloin alcohol 15753-47-61-methyl-1, 2-cycloid diol 52718 -65-73-Hydroxymethylcyclohexanol 3-methyl-1,2-cyclohexanediol 23477-91-04, 4-dimethyl-1,3-cyclohexanediol 14203-50-04, 5-Dimethyl-1,3-cyclohexanediol 4,6-dimethyl-1,3-cyclohexanediol 16066-66-34-Ethyl-1,3-cyclohexanediol 4-hydroxy Ethyl-1-cycloinol 4-hydroxytisyl cycloid alcohol 33893-85-54-methyl-1, 2-cycloid diol 23832-27-11, 2-ring glycol 108268-28-61 , 2-cyclohexanediol pentaethoxylate 1,2-cyclohexanediol hexaethoxylate 1,2-cyclohexanediol heptaethoxylate 1,2-cyclohexanediol octaethoxylate 1,2-Cyclohexanediol Nonaethoxylate 1,2-Cyclohexanediol Monopropoxylate 1,2-Cyclohexanediol Dibutylidene Oxide

Unsaturated cycloaliphatic diols include the following known unsaturated cycloaliphatic diols: Applicable Unsaturated Cycloaliphatic Diol Chemical Name CAS Registry Number 1-Vinyl-2-ethyl-1,2-cyclobutane Diol 58016-14-11, 2,3,4-tetramethyl-3-cyclobutene-1,2-diol 90112-64-43, 4-diethyl-3-cyclobutene-1, 2-diol 142543-60-03-(1,1-dimethylethyl)-3-cyclobutene-1,2-diol 142543-56-43-butyl-3-cyclobutene-1 , 2-diol                                                                                                            Cyclopentanediol 90314-52-64-(1-propenyl)-1,2-cyclopentadiol 128173-45-51-ethyl-3-methyl-3-cyclopentene-1,2-di Alcohol 90314-43-51-Vinyl-1,2-cyclohexanediol 134134-16-01-Methyl-3-methylene-1,2-cyclohexanediol 98204-78-51-Methyl- 4-Methylene-1,2-cyclohexanediol 133358-53-93-Vinyl-1,2-cyclohexanediol 55310-51-54-Vinyl-1,2-cyclohexanediol 85905- 16-42,6-Dimethyl-3-cyclohexene-1,2-diol 81969-75-76,6-Dimethyl-3-cyclohexene-1,2-diol 61875-93- 23,6-Dimethyl-4-cyclohexene-1,2-diol 156808-73-04,5-Dimethyl-4-cyclohexene-1,2-diol 154351-54-93- Cyclooctene-1,2-diol 170211-27-54-Cyclooctene-1,2-diol 124791-61-35-Cyclooctene-1,2-diol 117468-07-2 Not applicable Unsaturated cyclic diol 1-(1-methylvinyl)-1,2-cyclopentanediol 61447-83-41-cyclopentenyl-1,2-propanediol 55383-20-52-(1-methyl Ethylene)-1,3-cyclopentanediol 65651-46-92-(1-cyclopenten-1-yl)-1,3-propanediol 77192-43-92-(2-cyclopentene- 1-yl)-1,3-propanediol 25462-31-11-(1-cyclohexen-1-yl)-1,2-ethanediol 151674-61-21-(3-cyclohexen-1- base)-1,2-ethanediol 64011-53-65,5-dimethyl-2-cyclohexene-1,4-diol 147274-55-33,6-dimethyl-4-cyclohexyl ene-1,3-diol 127716-90-92-methylene-1,3-cycloheptanediol 132292-67-21-methyl-5-cycloheptene-1,3-diol 160813-33 -25-methyl-5-cycloinhne -1, 3-diol 160813-32-12-cyclone-1, 4-diol 37996-40-0

Table VIII

C _3-7 Diol Alkoxylated Derivatives

In the tables below, "EO" refers to polyethoxylate, ie, -(CH ₂ CH ₂ O) _n H; Me-En refers to methyl-terminated polyethoxylate -(CH ₂ CH ₂ O) _n CH ₃ ; "2(Me-En)" means that 2 Me-En groups are required; "PO" means polypropoxylate-(CH(CH ₃ )CH ₂ O) _n H; "BO" means polybutylene oxy(CH(CH ₂ CH ₃ )CH ₂ O) _n H; and "n-BO" refers to poly(n-butyleneoxy) or poly(tetramethylene)oxy-(CH ₂ CH ₂ CH ₂ CH ₂ O) _n H. The alkoxylated derivatives indicated are all suitable, the preferred alkoxylated derivatives are in bold type and listed on the second row. A non-limiting general synthetic procedure for the preparation of the alkoxylated derivatives is given below.

Table VIIIA raw material ^(a) Raw material CAS registration number EO's 1 (Me-En) 2 (Me-En) PO's n-BO's BO's (b) (c) (d) (e) (f) (g) 1,2-Propanediol (C3) 57-55-6 1-43-4 4 2-Methyl-1,2-propanediol (C4) 558-43-0 4-108-10 1 3 1 1,3-Propanediol (C3) 504-63-2 6-88 5-66 2,2-Diethyl-1,3-propanediol (C7) 115-76-4 1-74-7 1 1-22 2,2-Dimethyl-1,3-propanediol (C5) 126-30-7 1-2 3-44 2-(1-methylpropyl)-1,3-propanediol (C7) 33673-01-7 1-74-7 1 1-22 2-(2-Methylpropyl)-1,3-propanediol (C7) 26462-20-8 1-74-7 1 1-22 2-Ethyl-1,3-propanediol (C5) 2612-29-5 6-109-10 1 3 2-Ethyl-2-methyl-1,3-propanediol (C6) 77-84-9 1-63-6 2 1 2-Isopropyl-1,3-propanediol (C6) 2612-27-3 1-63-6 2 1 2-Methyl-1,3-propanediol (C4) 2163-42-0 2-54-5 4-55 2 2-Methyl-2-isopropyl-1,3-propanediol (C7) 2109-23-1 2-96-9 1 1-32-3 2-Methyl-2-propyl-1,3-propanediol (C7) 78-26-2 1-74-7 1 1-22 2-Propyl-1,3-propanediol (C6) 2612-28-4 1-4 2 1 (a) The numbers of alkoxylated groups indicated in this table and in Table VIII below are applicable, the general limitations of which are listed on the first line, and the preferred numbers are indicated in bold type and listed on the second line . (b) The number in this column is the average number of ( _CH2CH2O ) groups in _the polyethoxylated derivative. (c) The number in this column is the average number of ( _CH2CH2O ) groups in one methyl-terminated polyethoxylate substituent _per derivative. (d) The number in this column is the average number of ( _CH2CH2O ) groups per two methyl-terminated polyethoxylate substituents in _each derivative. (e) The number in this column is the average number of (CH(CH ₃ )CH ₂ O) groups in the polypropoxylated derivative. (f) The number in this column is the average number _of ( _{CH2CH2CH2CH2O} ) groups in the _{polytetramethyleneoxylated derivative} . (g) The number in this column is the average _number of (CH( _CH2CH3 ) _CH2O ) groups in the polybutoxylated derivative.

Table VIIIB raw material ^(a) Raw material CAS registration number EO's 1 (Me-En) 2 (Me-En) PO's n-BO's BO's (b) (c) (d) (e) (f) (g) 1,2-Butanediol (C4) 584-03-2 2-86-8 2-3 1 2,3-Dimethyl-1,2-butanediol (C6) 66553-15-9 1-62-5 1-21 2-Ethyl-1,2-butanediol (C6) 66553-16-0 1-3 1 2-Methyl-1,2-butanediol (C5) 41051-72-3 1-2 1 3,3-Dimethyl-1,2-butanediol (C6) 59562-82-2 1-62-5 1-21 3-Methyl-1,2-butanediol (C5) 50468-22-9 1-2 1 1,3-Butanediol (C4) 107-88-0 3-65-6 5 2 2,2,3-Trimethyl-1,3-butanediol (C7) 16343-75-2 1-3 1-22 2,2-Dimethyl-1,3-butanediol (C6) 76-35-7 3-86-8 3 2,3-Dimethyl-1,3-butanediol (C6) 24893-35-4 3-86-8 3 2-Ethyl-1,3-butanediol (C6) 66553-17-1 1-64-6 2-3 1 2-Ethyl-2-methyl-1,3-butanediol (C7) Method C 1 1 2-43 2-Ethyl-3-methyl-1,3-butanediol (C7) 68799-03-1 1 1 2-43 2-Isopropyl-1,3-butanediol (C7) 66567-04-2 1 1 2-43 2-Methyl-1,3-butanediol (C5) 684-84-4 1-32-3 4 2-Propyl-1,3-butanedi 66567-03-1 2-9 1-3 Alcohol (C7) 6-8 1 2-3 3-Methyl-1,3-butanediol (C5) 2568-33-4 1-32-3 4 1,4-Butanediol (C4) 110-63-4 2-43-4 4-54-5 2 2,2,3-Trimethyl-1,4-butanediol (C7) 162108-60-3 2-96-9 1 1-32-3 2,2-Dimethyl-1,4-butanediol (C6) 32812-23-0 1-63-6 2 1 2,3-Dimethyl-1,4-butanediol (C6) 57716-80-0 1-63-6 2 1 2-Ethyl-1,4-butanediol (C6) 57716-79-7 1-4 2 1 2-Ethyl-2-methyl-1,4-butanediol (C7) 76651-98-4 1-74-7 1 1-22 2-Ethyl-3-methyl-1,4-butanediol (C7) 66225-34-1 1-74-7 1 1-22 2-Isopropyl-1,4-butanediol (C7) 39497-66-0 1-74-7 1 1-22 2-Methyl-1,4-butanediol (C5) 2938-98-9 6-109-10 1 3 1 2-Propyl-1,4-butanediol (C7) 62946-68-3 1-52-5 1-21 3-Ethyl-1-methyl-1,4-butanediol (C7) Method F 2-96-8 1 1-32-3 2,3-Butanediol (C4) 513-85-9 6-109-10 1 3-4 1 2,3-Dimethyl-2,3-butanediol (C6) 76-09-5 3-97-9 1 1-32-3 2-Methyl-2,3-butanediol (C5) 5396-58-7 1-52-5 2 1 (a) The number of alkoxylated groups indicated in this table is applicable, with general limitations listed on the first line and preferred numbers indicated in bold and listed on the second line. (b) The number in this column is the average number of ( _CH2CH2O ) groups in _the polyethoxylated derivative. (c) The number in this column is the average number of ( _CH2CH2O ) groups in one methyl-terminated polyethoxylate substituent _per derivative. (d) The number in this column is the average number of ( _CH2CH2O ) groups per two methyl-terminated polyethoxylate substituents in _each derivative. (e) The number in this column is the average number of (CH(CH ₃ )CH ₂ O) groups in the polypropoxylated derivative. (f) The number in this column is the average number _of ( _{CH2CH2CH2CH2O} ) groups in the _{polytetramethyleneoxylated derivative} . (g) The number in this column is the average _number of (CH( _CH2CH3 ) _CH2O ) groups in the polybutoxylated derivative.

Table VIIIC raw material ^(a) Raw material CAS registration number EO's 1 (Me-En) 2 (Me-En) PO's n-BO's BO's (b) (c) (d) (e) (f) (g) 1,2-pentanediol (C5) 5343-92-0 3-107-10 1 2-33 2-Methyl-1,2-pentanediol (C6) 20667-05-4 1-3 1 3-Methyl-1,2-pentanediol (C6) 159623-53-7 1-3 1 4-Methyl-1,2-pentanediol (C6) 72110-08-8 1-3 1 1,3-Pentanediol (C5) 3174-67-2 1-2 3-4 2,2-Dimethyl-1,3-pentanediol (C7) 2157-31-5 1 1 2-43 2,3-Dimethyl-1,3-pentanediol (C7) 66225-52-3 1 1 2-43 2,4-Dimethyl-1,3-pentanediol (C7) 60712-38-1 1 1 2-43 2-Ethyl-1,3-pentanediol (C7) 29887-11-4 2-96-8 1 1-32-3 2-Methyl-1,3-pentanediol (C6) 149-31-5 1-64-6 2-3 1 3,4-Dimethyl-1,3-pentanediol (C7) 129851-50-9 1 1 2-43 3-Methyl-1,3-pentanediol (C6) 33879-72-0 1-64-6 2-3 1 4,4-Dimethyl-1,3-pentanediol (C7) 30458-16-3 1 1 2-43 4-Methyl-1,3-pentanediol (C6) 54876-99-2 1-64-6 2-3 1 1,4-pentanediol (C5) 626-95-9 1-2 3-4 2,2-Dimethyl-1,4-pentanediol (C7) Method F 1 1 2-43 2,3-Dimethyl-1,4-pentanediol (C7) Method F 1 1 2-43 2,4-Dimethyl-1,4-pentanediol (C7) Method F 1 1 2-43 2-Methyl-1,4-pentanediol (C6) 6287-17-8 1-64-6 2-3 1 3,3-Dimethyl-1,4-pentanediol (C7) 81887-62-9 1 1 2-43 3,4-Dimethyl-1,4-pentanediol (C7) 63521-36-8 1 1 2-43 3-methyl-1,4-pentanedi 26787-63-3 1-6 1 Alcohol (C6) 4-6 2-3 4-Methyl-1,4-pentanediol (C6) 1462-10-8 1-64-6 2-3 1 1,5-Pentanediol (C5) 111-29-5 4-108-10 1 3 2,2-Dimethyl-1,5-pentanediol (C7) 3121-82-2 1-74-7 1 1-22 2,3-Dimethyl-1,5-pentanediol (C7) 81554-20-3 1-74-7 1 1-22 2,4-Dimethyl-1,5-pentanediol (C7) 2121-69-9 1-74-7 1 1-22 2-Ethyl-1,5-pentanediol (C7) 14189-13-0 1-52-5 1-22 2-Methyl-1,5-pentanediol (C6) 42856-62-2 1-4 2 3,3-Dimethyl-1,5-pentanediol (C7) 53120-74-4 1-74-7 1 1-22 3-Methyl-1,5-pentanediol (C6) 4457-71-0 1-4 2 2,3-Pentanediol (C5) 42027-23-6 1-3 2 2-Methyl-2,3-pentanediol (C6) 7795-80-4 1-74-7 1 1-22 3-Methyl-2,3-pentanediol (C6) 63521-37-9 1-74-7 1 1-22 4-Methyl-2,3-pentanediol (C6) 7795-79-1 1-74-7 1 1-22 2,4-Pentanediol (C5) 625-69-4 1-42-4 4 2,3-Dimethyl-2,4-pentanediol (C7) 24893-39-8 1-42-4 2 2,4-Dimethyl-2,4-pentanediol (C7) 24892-49-7 1-42-4 2 2-Methyl-2,4-pentanediol (C6) 107-41-5 5-108-10 3 3,3-Dimethyl-2,4-pentanediol (C7) 24892-50-0 1-42-4 2 3-Methyl-2,4-pentanediol (C6) Method H 5-108-10 3 (a) The number of alkoxylated groups indicated in this table is applicable, with general limitations listed on the first line and preferred numbers indicated in bold and listed on the second line. (b) The number in this column is the average number of ( _CH2CH2O ) groups in _the polyethoxylated derivative. (c) The number in this column is the average number of ( _CH2CH2O ) groups in one methyl-terminated polyethoxylate substituent _per derivative. (d) The number in this column is the average number of ( _CH2CH2O ) groups per two methyl-terminated polyethoxylate substituents in _each derivative. (e) The number in this column is the average number of (CH(CH ₃ )CH ₂ O) groups in the polypropoxylated derivative. (f) The number in this column is the average number _of ( _{CH2CH2CH2CH2O} ) groups in the _{polytetramethyleneoxylated derivative} . (g) The number in this column is the average _number of (CH( _CH2CH3 ) _CH2O ) groups in the polybutoxylated derivative.

Table VIIID raw material ^(a) Raw material CAS registration number EO's 1 (Me-En) PO's n-BO's BO's (b) (c) (e) (f) (g) 1,3-Hexanediol (C6) 21531-91-9 1-52-5 2 1 2-Methyl-1,3-hexanediol (C7) 66072-21-7 2-96-8 1 1-32-3 1 3-Methyl-1,3-hexanediol (C7) Method D 2-96-8 1 1-32-3 4-Methyl-1,3-hexanediol (C7) Method C 2-96-8 1 1-32-3 5-Methyl-1,3-hexanediol (C7) 109863-14-1 2-96-8 1 1-32-3 1,4-Hexanediol (C6) 16432-53-4 1-52-5 2 1 2-Methyl-1,4-hexanediol (C7) Method F 2-96-8 1 1-32-3 3-Methyl-1,4-hexanediol (C7) 66225-36-3 2-96-8 1 1-32-3 4-Methyl-1,4-hexanediol (C7) 40646-08-0 2-96-8 1 1-32-3 5-Methyl-1,4-hexanediol (C7) 38624-36-1 2-96-8 1 1-32-3 1,5-Hexanediol (C6) 928-40-5 1-52-5 2 1 2-Methyl-1,5-hexanediol (C7) Method F 2-96-8 1 1-32-3 3-Methyl-1,5-hexanediol (C7) Method F 2-96-8 1 1-32-3 4-Methyl-1,5-hexanediol (C7) 66225-37-4 2-96-8 1 1-32-3 5-methyl-1,5-hexanediol (C7) 1462-11-9 2-96-8 1 1-32-3 1,6-Hexanediol (C6) 629-11-8 1-2 1-2 4 2-Methyl-1,6-hexanediol (C7) 25258-92-8 1-52-5 1-21 3-Methyl-1,6-hexanediol 4089-71-8 1-5 1-2 (C7) 2-5 1 2,3-Hexanediol (C6) 617-30-1 1-52-5 1-21 2,4-Hexanediol (C6) 19780-90-6 3-85-8 3 2-Methyl-2,4-hexanediol (C7) 66225-35-2 1-2 1-2 3-Methyl-2,4-hexanediol (C7) 116530-79-1 1-2 1-2 4-Methyl-2,4-hexanediol (C7) 38836-25-8 1-2 1-2 5-methyl-2,4-hexanediol (C7) 54877-00-8 1-2 1-2 2,5-Hexanediol (C6) 2935-44-6 3-85-8 3 2-Methyl-2,5-hexanediol (C7) 29044-06-2 1-2 1-2 3-Methyl-2,5-hexanediol (C7) Method H 1-2 1-2 3,4-Hexanediol (C6) 922-17-8 1-52-5 1 (a) The number of alkoxylated groups indicated in this table is applicable, with general limitations listed on the first line and preferred numbers indicated in bold and listed on the second line. (b) The number in this column is the average number of ( _CH2CH2O ) groups in _the polyethoxylated derivative. (c) The number in this column is the average number of ( _CH2CH2O ) groups in one methyl-terminated polyethoxylate substituent _per derivative. (e) The number in this column is the average number of (CH(CH ₃ )CH ₂ O) groups in the polypropoxylated derivative. (f) The number in this column is the average number _of ( _{CH2CH2CH2CH2O} ) groups in the _{polytetramethyleneoxylated derivative} . (g) The number in this column is the average _number of (CH( _CH2CH3 ) _CH2O ) groups in the polybutoxylated derivative.

Table VIIIE raw material ^(a) Raw material CAS registration number EO's 1 (Me-En) PO's n-BO's (b) (c) (e) (f) 1,3-Heptanediol (C7) 23433-04-7 1-73-6 1 1-22 1,4-Heptanediol (C7) 40646-07-9 1-73-6 1 1-22 1,5-Heptanediol (C7) 60096-09-5 1-73-6 1 1-22 1,6-Heptanediol (C7) 13175-27-4 1-73-6 1 1-22 1,7-Heptanediol (C7) 629-30-1 1-2 1 2,4-Heptanediol (C7) 20748-86-1 3-107-10 1 1 3 2,5-Heptanediol (C7) 70444-25-6 3-107-10 1 1 3 2,6-Heptanediol (C7) 5969-12-0 3-107-10 1 1 3 3,5-Heptanediol (C7) 86632-40-8 3-107-10 1 1 3 (a) The number of alkoxylated groups indicated in this table is applicable, with general limitations listed on the first line and preferred numbers indicated in bold and listed on the second line. (b) The number in this column is the average number of ( _CH2CH2O ) groups in _the polyethoxylated derivative. (c) The number in this column is the average number of ( _CH2CH2O ) groups in one methyl-terminated polyethoxylate substituent _per derivative. (e) The number in this column is the average number of (CH(CH ₃ )CH ₂ O) groups in the polypropoxylated derivative. (f) The number in this column is the average number _of ( _{CH2CH2CH2CH2O} ) groups in the _{polytetramethyleneoxylated derivative} .

Table IX

Aromatic diols

Suitable aromatic diols include: Chemical Name CAS Registry No. Applicable Aromatic Diol 1-Phenyl-1,2-ethanediol 93-56-11-Phenyl-1,2-propanediol 1855-09-02- Phenyl-1,2-propanediol 87760-50-73-Phenyl-1,2-propanediol 17131-14-51-(3-methylphenyl)-1,3-propanediol 51699-43-51-(4-toluene base)-1,3-propanediol 159266-06-52-methyl-1-phenyl-1,3-propanediol 139068-60-31-phenyl-1,3-butanediol 118100-60-03-benzene 1,3-butanediol 68330-54-11-phenyl-1,4-butanediol 136173-88-12-phenyl-1,4-butanediol 95840-73-61-phenyl- 2,3-Butanediol 169437-68-7 Preferred aromatic diol 1-phenyl-1,2-ethanediol 93-56-11-phenyl-1,2-propanediol 1855-09-02- Phenyl-1,2-propanediol 87760-50-73-Phenyl-1,2-propanediol 17131-14-51-(3-methylphenyl)-1,3-propanediol 51699-43-51-(4-toluene base)-1,3-propanediol 159266-06-52-methyl-1-phenyl-1,3-propanediol 139068-60-31-phenyl-1,3-butanediol 118100-60-03-benzene Diol-1,3-butanediol 68330-54-11-phenyl-1,4-butanediol 136173-88-1 More preferred aromatic diol 1-phenyl-1,2-propanediol 1855-09 -02-Phenyl-1,2-propanediol 87760-50-73-Phenyl-1,2-propanediol 17131-14-51-(3-methylphenyl)-1,3-propanediol 51699-43-51-( 4-methylphenyl)-1,3-propanediol 159266-06-52-methyl-1-phenyl-1,3-propanediol 139068-60-33-phenyl-1,3-butanediol 68330-54- 11-Phenyl-1,4-butanediol 136173-88-1 Unsuitable aromatic diol 1-phenyl-1,3-propanediol 2-phenyl-1,3-propanediol 1-phenyl-1 ,2-Butanediol 154902-08-62-Phenyl-1,2-butanediol 157008-55-43-Phenyl-1,2-butanediol 141505-72-84-Phenyl-1,2 -Butanediol 143615-31-02-Phenyl-1,3-butanediol 103941-94-24-Phenyl-1,3-butanediol 81096-91-52-Phenyl-2,3-butanediol Diol 138432-94-7X. The main solvent of homologs or analogs of the above structures is also suitable, wherein the total number of hydrogen atoms of the homologues or analogs is increased by adding one or more additional _CH2 groups, or The total number of hydrogen atoms is kept constant by the introduction of double bonds, examples of which include the following known compounds:

Table X

Examples of unsaturated compounds Suitable unsaturated diols 2,2-bis-2-propenyl-1,3-propanediol 55038-13-62-(1-pentenyl)-1,3-propanediol 138436-18- 72-(2-methyl-2-propenyl)-2-(2-propane 121887-76-1enyl)-1,3-propanediol 2-(3-methyl-1-butenyl)-1 , 3-propanediol 138436-17-6 alcohol 2-(4-pentenyl)-1,3-propanediol 73012-46-12-ethyl-2-(2-methyl-2-propenyl)-1 , 91367-61-23-propanediol 2-ethyl-2-(2-propenyl)-1,3-propanediol 2-methyl-2-(3-methyl-3-butane) 27606-26-4 Alkenyl)-1, 132130-95-13-propanediol 2,2-diallyl-1,3-butanediol 103985-49-52-(1-ethyl-1-propenyl)-1,3 -Butanediol 116103-35-6 2-(2-butenyl)-2-methyl-1,3-butanediol 92207-83-5 2-(3-methyl-2-butenyl)ol -1,3-Butanedi 98955-19-2 Alcohol 2-Ethyl-2-(2-propenyl)-1,3-Butanedi 122761-93-7 Alcohol 2-Methyl-2-(1-Methanol Base-2-propenyl)-1, 141585-58-23-butanediol 2,3-bis(1-methylethylene)-1,4-butanediol 52127-63-6 alcohol 2-(3 -Methyl-2-butenyl)-3-methylene- 115895-78-81, 4-butanediol 2-(1,1-dimethylpropyl)-2-butene-1, 91154 -01-74-diol 2-(1-methylpropyl)-2-butene-1,4-diol 91154-00-6-diol 2-butyl-2-butene-1,4-diol 153943-66-92-Vinyl-3-ethyl-1,3-pentanediol 104683-37-62-Vinyl-4,4-dimethyl-1,3-pentanediol 143447-08-93 -Methyl-2-(2-propenyl)-1,4-pentanediol 139301-86-3 Alcohol 2-(1-propenyl)-1,5-pentanediol 84143-44-22-(2- Propyl)-1,5-pentanediol           134757-01-02-Ethylene-3-methyl-1,5-pentanediol    42178-93-82-Propylene-1,5-pentanediol 58203-50-23-Ethylene-2,4-dimethyl-2,4-pentanediol 88610-19-92-(1,1-dimethylethyl)-4-pentene-1, 109788-04-73-diol 2-ethyl-2,3-dimethyl-4-pentene-1,3 90676-97-4-diol 4-ethyl-2-methylene-1, 4-hexanediol 66950-87-62, 3,5-trimethyl-1,5-hexadiene-3,4 18984-03-7-diol 5-ethyl-3-methyl-1, 5-Hexadiene-3,4 18927-12-3-diol 2-(1-methylvinyl)-1,5-hexanediol 98602-18-52-vinyl-1,6-hexanediol Alcohol 66747-31-75, 5-Dimethyl-1-hexene-3,4-diol 169736-29-25, 5-Dimethyl-1-hexene-3,4-diol 120191-04 -04-vinyl-2,5-dimethyl-2-hexene-1, 70101-76-75-diol 2-vinyl-2,5-dimethyl-3-hexene-1, 112763 -52-76-diol 2-ethyl-3-hexene-1,6-diol 84143-45-33, 4-dimethyl-3-hexene-1,6-diol 125032-66- 82,5-Dimethyl-4-hexene-2,3-diol 13295-61-93,4-Dimethyl-4-hexene-2,3-diol 135367-17-83-(2 -propenyl)-5-hexene-1,3-diol 74693-24-62,3-dimethyl-5-hexene-2,3-diol 154386-00-23,4-dimethyl -5-hexene-2,3-diol 135096-13-83,5-dimethyl-5-hexene-2,3-diol 134626-63-43-vinyl-2,5-dimethyl Diol-5-hexene-2, 155751-24-94-diol 6-methyl-5-methylene-1,4-heptanediol 100590-29-22,3-dimethyl-1,5 -Heptadiene-3,4-di-18927-06-5-ol 2,5-dimethyl-1,5-heptadiene-3,4-di-22607-16-5-ol 3,5-dimethyl -1,5-heptadiene-3,4-di 18938-51-7 alcohol 2,6-di(methylene)-1,7-heptanediol 139618-24-94-methylene-1, 7-Heptanediol 71370-08-62, 4-Dimethyl-1-heptene-3,5-diol 155932-77-72, 6-Dimethyl-1-heptene-3,5-diol Alcohol 132157-35-83-vinyl-5-methyl-1-heptene-3,5-diol 6184110-9 alcohol 6,6-dimethyl-1-heptene-3,5-diol 109788- 01-44,6-Dimethyl-2,4-heptadiene-2,6-di 162816-19-5-alcohol 2,5,5-trimethyl-2,6-heptadiene-1,4 115346-30-0-diol 5,6-dimethyl-2-heptene-1, 4-diol 103867-76-15-ethyl-2-heptene-1,5-diol 104683-39-82-methyl-2-heptene-1,7-diol 74868-68-14, 6-Dimethyl-3-heptene-1,5-diol 147028-45-33-methyl-6-methylene-3-heptene-1,7-diol 109750-55-2-ol 2, 4-Dimethyl-3-heptene-2,5-diol 98955-40-92, 5-Dimethyl-3-heptene-2,5-diol 24459-23-22,6-dimethyl Dimethyl-3-heptene-2,6-diol 160524-66-34, 6-dimethyl-3-heptene-2,6-diol 59502-66-82, 4-dimethyl-5- Heptene-1,3-diol 123363-69-93, 6-Dimethyl-5-heptene-1,3-diol 96924-52-62, 6-Dimethyl-5-heptene-1 , 4-Diol 106777-98-43, 6-Dimethyl-5-heptene-1,4-diol 106777-99-52, 3-Dimethyl-5-heptene-2,4-diol Alcohol 104651-56-12, 2-Dimethyl-6-heptene-1,3-diol 140192-39-84-(2-propenyl)-6-heptene-1,4-diol 1727- 87-35,6-Dimethyl-6-heptene-1,4-diol 152344-16-62,4-Dimethyl-6-heptene-1,5-diol 74231-27-92- Ethylene-6-methyl-6-heptene-1,5-diol 4-(2-propenyl)-6-heptene-2,4-diol 101536-75-85 , 5-Dimethyl-6-heptene-2,4-diol 98753-77-64, 6-Dimethyl-6-heptene-2,5-diol 134876-94-15-ethylene -4-methyl-6-heptene-2,5-di 65757-31-5 alcohol 2-methylene-1,3-octanediol 108086-78-82,6-dimethyl-1,6 -Octadiene-3,5-di91140-06-6-ol 3,7-dimethyl-1,6-octadiene-3,5-di75654-19-2-ol 2,6-dimethyl -1,7-octadiene-3,6-di-51276-33-6-ol 2,7-dimethyl-1,7-octadiene-3,6-di-26947-10-4-ol 3,6 -Dimethyl-1,7-octadiene-3,6-diol 31354-73-1-ol 3-ethylene-1-octene-3,6-diol 65757-34-82,7-diol Methyl-2,4,6-octatriene-1,8 162648-63-7-diol 3,7-dimethyl-2,4-octadiene-1,7-di 136054-24-5 Alcohol 2,6-dimethyl-2,5-octadiene-1,7-di 91140-07-7 Alcohol 3,7-dimethyl-2,5-octadiene-1,7-di 117935 -59-8 alcohol 3,7-dimethyl-2,6-octadiene-1,4-di 101391-01-9 alcohol (Rosiridol) 2-methyl-2,6-octadiene-1, 8-Diol 149112-02-73,7-Dimethyl-2,7-octadiene-1,4-diol 2,6-Dimethyl-2,7-octadiene 91140-08-8 -1,5-di 91140-09-9 alcohol 2,6-dimethyl-2,7-octadiene-1,6-di 103619-06-3 alcohol (8-hydroxylinalool) 2,7 -Dimethyl-2,7-octadiene-1,6-diol 60250-14-8-ol 2-octene-1,4-diol 40735-15-72-octene-1,7-diol 73842-95-22-Methyl-6-methylene-2-octene-1,7-di -Di 62875-09-6-ol 2,7-dimethyl-3,5-octadiene-2,7-di 7177-18-6-ol 4-methylene-3,5-octanediol   143233- 15-22,6-Dimethyl-3,7-octadiene-1,6-di 127446-29-1 alcohol 2,7-dimethyl-3,7-octadiene-2,5-di 171436-39-8 alcohol 2,6-dimethyl-3,7-octadiene-2,6-diol 150283-67-3 alcohol 4-methyl-3-octene-1,5-diol 147028 -43-15-Methyl-3-octene-1,5-diol 19764-77-32,2-Dimethyl-4,6-octadiene-1,3-diol 39824-01-6 2,6-Dimethyl-4,7-octadiene-2,3-di-51117-38-5-ol 2,6-Dimethyl-4,7-octadiene-2,6-di-59076- 71-0 alcohol 7-methyl-4-octene-1,6-diol 84538-24-92,7-bis(methylene-4-octene-1,8-diol 109750-56-3 alcohol 2-Methylene-4-octene-1,8-diol 109750-58-52, 7-Dimethyl-5,7-octadiene-1,4-diol 105676-78-6-ol 7- Methyl-5,7-octadiene-1,4-diol 105676-80-05-octene-1,3-diol 130272-38-77-Methyl-6-octene-1,3- Diol 110971-19-27-Methyl-6-octene-1,4-diol 152715-87-26-Octene-1,5-diol 145623-79-67-Methyl-6-octene -1,5-diol 116214-61-02-Methyl-6-octene-3,5-diol 65534-66-94-Methyl-6-octene-3,5-diol 156414-25 -42-Methyl-7-octene-1,3-diol   155295-38-84-Methyl-7-octene-1,3-diol   142459-25-47-Methyl-7-octene -1,3-diol 132130-96-27-octene-1,5-diol 7310-51-27-octene-1,6-diol 159099-43-15-methyl-7-octene -1,6-diol 144880-56-82-methyl-6-methylene-7-octene-2,4-di 72446-81-2-ol 7-methyl-7-octene-2, 5-diol 152344-12-22-methyl-7-octene-3,5-diol 98753-85-61-nonene-3,5-diol 119554-56-21-nonene-3, 7-diol 23866-97-93-Nonene-2,5-diol 165746-84-98-Methyl-4,6-nonadiene-1,3-diol 124099-52-14-None -2,8-diol 154600-80-36,8-nonadiene-1,5-diol 108586-03-47-nonene-2,4-diol 30625-41-38-nonene-2 , 4-diol                                                                                                                                                                4,6-diol 138835-67-3 Preferred unsaturated diol 2,2-diallyl-1,3-butanediol 103985-49-52-(1-ethyl-1-propenyl) -1,3-Butanediol 116103-35-6-2-(2-butenyl)-2-methyl-1,3-butanediol 92207-83-5-2-(3-methyl-2-alcohol) Butenyl)-1,3-butanedi 98955-19-2 alcohol 2-ethyl-2-(2-propenyl)-1,3-butanedi (1-methyl-2-propenyl)-1, 141585-58-23-butanediol 2,3-di(1-methylethylene)-1,4-butanediol 52127-63-6 alcohol 2-vinyl-3-ethyl-1,3-pentanediol 104683-37-62-vinyl-4,4-dimethyl-1,3-pentanediol 143447-08-93-methyl- 2-(2-propenyl)-1,4-pentanediol 139301-86-3-ol 2-(1,1-dimethylethyl)-4-pentene-1, 109788-04-73-diol 2-Ethyl-2,3-dimethyl-4-pentene-1,3 90676-97-4-diol 4-ethyl-2-methylene-1,4-hexanediol 66950-87 -62,3,5-Trimethyl-1,5-hexadiene-3,4 18984-03-7-diol 2-(1-methylvinyl)-1,5-hexanediol 96802- 18-54-Vinyl-2,5-dimethyl-2-hexene-1, 70101-76-75-diol 6-methyl-5-methylene-1,4-heptanediol 100590- 29-24,6-Dimethyl-2,4-heptadiene-2,6-di 102605-95-8 alcohol 2,5,5-trimethyl-2,6-heptadiene-1,4 115346-30-0-diol 5,6-dimethyl-2-heptene-1,4-diol 103867-76-14,6-dimethyl-3-heptene-1,5-diol 147028-45-32, 4-Dimethyl-5-heptene-1,3-diol 123363-69-93, 6-Dimethyl-5-heptene-1,3-diol 96924-52- 62,6-Dimethyl-5-heptene-1,4-diol 106777-98-43,6-Dimethyl-5-heptene-1,4-diol 106777-99-52,2- Dimethyl-6-heptene-1,3-diol 140192-39-85, 6-Dimethyl-6-heptene-1,4-diol 152344-16-62,4-Dimethyl- 6-Heptene-1,5-diol 74231-27-92-Ethylene-6-methyl-6-heptene-1,5-diol 91139-73-0alcohol 4-(2-propenyl) -6-Heptene-2,4-diol 101536-75-83-Ethylene-1-octene-3,6-diol 65757-34-82,7-Dimethyl-2,4,6 -octatriene-1,8 162648-63-7-diol 2,6-dimethyl-2,5-octadiene-1,7-diol 3,7-diol 3,7-diol -2,5-octadiene-1,7-di-117935-59-8 alcohol 3,7-dimethyl-2,6-octadiene-1,4-di-101391-01-9 alcohol (Rosiridol) 2-Methyl-2,6-octadiene-1,8-diol 149112-02-73, 7-Dimethyl-2,7-octadiene-1,4-diol 91140-08-8 2,6-Dimethyl-2,7-octadiene-1,5-diene 91140-09-9 Alcohol 2,6-Dimethyl-2,7-octadiene-1,6-diene 103619- 06-3 alcohol (8-hydroxylinalool) 2,7-dimethyl-2,7-octadiene-1,6-di 60250-14-8 alcohol 2-methyl-6-methylene- 2-Octene-1,7-di91140-16-8-ol 2,7-dimethyl-3,5-octadiene-2,7-di7177-18-6-ol 4-methylene-3 , 5-octanediol 143233-15-22, 6-dimethyl-3,7-octadiene-1,6-di 127446-29-1 alcohol 2-methylene-4-octene-1, 8-Diol 109750-58-52-Methyl-6-octene-3,5-diol 65534-66-94-Methyl-6-octene-3,5-diol 156414-25-42- Methyl-6-methylene-7-octene-2,4-diol 72446-81-2-ol 7-methyl-7-octene-2,5-diol 152344-12-22-methyl- 7-octene-3,5-diol 98753-85-61-nonene-3,5-diol 119554-56-21-nonene-3,7-diol 23866-97-93-nonene- 2,5-diol 165746-84-94-nonene-2,8-diol 154600-80-36,8-nonadiene-1,5-diol 108586-03-47-nonene-2, 4-Diol 30625-41-38-Nonene-2,4-diol 119785-59-08-Nonene-2,5-diol 132381-58-91,9-Decadiene-3,8- Diol 103984-04-91, 9-Decadiene-4,6-diol 138835-67-3; and XI. Mixtures thereof.

There are no _C1-2 monoalcohols that can provide the clear, concentrated fabric softener compositions of the present invention. Only one _C3 monoalcohol, n-propanol, provided acceptable performance (formed clear product, remained clear at about 4°C, or recovered after rewarming to room temperature), although its boiling point (BP) was undesirable low. For _C4 monoalcohols, only 2-butanol and 2-methyl-2-propanol give very good performance, but 2-methyl-2-propanol has an undesirably low boiling point. Apart from the unsaturated monoalcohols described in this context, there are no _C5-6 monoalcohols that can give clear products.

Certain primary solvents having two hydroxyl groups in their formula have been found to be suitable for use in formulating the liquid concentrated clear fabric softener compositions of the present invention. The suitability of each major solvent was found to have very unexpected selectivity depending on the number of carbon atoms, isomeric configurations of molecules with the same number of carbon atoms, degree of unsaturation, etc. A primary solvent having similar solubility characteristics to the above primary solvents and having at least some degree of asymmetry would provide the same benefits. Suitable primary solvents have been found to have ClogP values of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, more preferably from about 0.40 to about 0.60.

For example, for the main solvent series of 1,2-alkanediols having the general formula HO- _CH2- CHOH-( _CH2 ) _n -H, where n is 1-8, only 1,2-Hexanediol (n=4) in the range of effective ClogP values of about 0.15 to about 0.64 is an excellent primary solvent and is within the scope of the claimed invention, while other alcohols such as, 1,2-propanediol, 1,2-butanediol, 1,2-pentanediol, 1,2-octanediol, 1,2-decanediol, which have ClogP effective values outside 0.15-0.64 ClogP value, not excellent primary solvent. Moreover, isomers of hexanediol, such as 1,2-hexanediol are excellent primary solvents, while many other isomers such as 1,3-hexanediol, 1,4-hexanediol, 1 , 5-hexanediol, 1,6-hexanediol, 2,4-hexanediol, and 2,5-hexanediol, which have ClogP values outside the effective range of 0.15-0.64, which are not excellent main solvent. These are illustrated by Examples and Comparative Examples IA and IB (see below).

There are no _C3-5 diols that can provide the clear, concentrated compositions of the present invention.

Although many _C6 diols are possible isomers, only those listed above are suitable for making clear products, and only: 2,3-dimethyl-1,2-butanediol; 3,3-di Methyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3-pentanediol; 4-methyl-2,3-pentanediol; 3,4-hexanediol; 2-ethyl-1,2-butanediol; 2-methyl-1,2-pentanediol; 3-methyl-1,2-pentanediol; 4-methyl -1,2-pentanediol; and 1,2-hexanediol are preferred, of which the most preferred are: 2-ethyl-1,2-butanediol; 2-methyl-1,2- pentanediol; 3-methyl-1,2-pentanediol; 4-methyl-1,2-pentanediol; and 1,2-hexanediol.

Although there are many more possible _C7 diol isomers, only the ones listed above make clear products and are preferred: 2-Butyl-1,3-butanediol; 2-Propyl-1 , 4-butanediol; 2-ethyl-1,5-pentanediol; 2,3,-dimethyl-2,3-pentanediol; 2,4,-dimethyl-2,3- Pentylene glycol; 4,4-dimethyl-2,3-pentanediol; 2,3,-dimethyl-3,4-pentanediol; 2-methyl-1,6-hexanediol; 3-methyl-1,6-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; 1,6-heptanediol; : 2,3,-Dimethyl-2,3-pentanediol; 2,4,-Dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol ; 4,4-dimethyl-2,3-pentanediol; and 2,3,-dimethyl-3,4-pentanediol.

Similarly, although there are even more _C8 diol isomers, only the ones listed above make clear products, and the preferred ones are: 2-(1,1-Dimethylpropyl)-1, 3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(2,2-dimethyl propyl)-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-methyl-2-(1-methylpropyl)-1,3-propanediol; 2-Methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl-2-methyl-1,3-propanediol; 2,2-diethyl-1,3 -Butanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-butyl-1,3-butanediol; 2-ethyl-2,3-dimethyl- 1,3-butanediol; 2-(1,1-dimethylethyl)-1,3-butanediol; 2-(2-methylpropyl)-1,3-butanediol; 2 -Methyl-2-propyl-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3- Butanediol; 2,2-diethyl-1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl-3,3- Dimethyl-1,4-butanediol; 2-(1,1-dimethylethyl)-1,4-butanediol; 3-methyl-2-isopropyl-1,4-butane Diol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol; 2,3,4-trimethyl-1 , 3-pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3,4,4-trimethyl-1,3-pentanediol; 2,2,3-tri Methyl-1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2,3 ,4-Trimethyl-1,4-pentanediol; 3,3,4-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol ;2,2,4-Trimethyl-1,5-pentanediol; 2,3,3-Trimethyl-1,5-pentanediol; 2,3,4-Trimethyl-2,4 -Pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 2-ethyl-4-methyl -1,3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl- 3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3 -Ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl- 1,4-pentanediol; 2-propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 3-propyl-2,4-pentanediol; 2, 2-Dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5- Dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol; 4,4-dimethyl Base-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl- 1,4-hexanediol; 2,4-dimethyl-1,4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl-1, 4-hexanediol; 3,4-dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,5-dimethyl-1,4- Hexylene glycol; 5,5-dimethyl-1,4-hexanediol; 2,2-dimethyl-1,5-hexanediol; 2,3-dimethyl-1,5-hexanediol Alcohol; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 3, 3-Dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol; 4-ethyl-1,3-hexanediol; 2-ethyl-1,4-hexanediol Diol; 4-ethyl-1,4-hexanediol; 2-ethyl-1,5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4 -Hexanediol; 3-Ethyl-2,5-Hexanediol; 2-Methyl-1,3-Heptanediol; 3-Methyl-1,3-Heptanediol; 4-Methyl-1 , 3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 2-methyl-1,4-heptanediol; 3-methyl -1,4-heptanediol; 4-methyl-1,4-heptanediol; 5-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol; 2- Methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4-methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 6-Methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1,6-heptanediol Alcohol; 5-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol; 2-methyl-2,4-heptanediol; 3-methyl-2,4- Heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2, 5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl- 2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl Base-3,4-heptanediol; 2-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; and/or 3,6-octanediol; wherein the following are most preferred: 2-(1,1 -Dimethylpropyl)-1,3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol ; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-methyl-2-(1-methyl Propyl)-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl-2-methyl-1,3-propanediol; 2 -(1-methylpropyl)-1,3-butanediol; 2-(2-methylpropyl)-1,3-butanediol; 2-butyl-1,3-butanediol; 2-Methyl-2-propyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1,4-butanediol Alcohol; 2-ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1 -Dimethylethyl)-1,4-butanediol; 2,3,4-trimethyl-1,3-pentanediol; 2,2,3-trimethyl-1,5-pentanediol Alcohol; 2,2,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-1,5-pentanediol; 2-ethyl-2-methyl-1, 3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 2-ethyl-4-methyl-1,3-pentanediol; 3-ethyl-2-methanol Base-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4-pentanediol; 2-ethyl -4-methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1,4- pentanediol; 3-isopropyl-1,4-pentanediol; 3-propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol; 2,3 -Dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-di Methyl-1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol; 4,4-dimethyl-1,3-hexanediol; 4,5-dimethyl -1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol; 2,4-dimethyl-1 , 4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4 -hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,5-dimethyl-1,4-hexanediol; 5,5-dimethyl-1,4-hexanediol Diol; 2,2-Dimethyl-1,5-hexanediol; 2,3-Dimethyl-1,5-hexanediol; 2,4-Dimethyl-1,5-hexanediol ;2,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol;3 , 5-dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 2-ethane Base-1,3-hexanediol; 4-ethyl-1,3-hexanediol; 2-ethyl-1,4-hexanediol; 4-ethyl-1,4-hexanediol; 2 -Ethyl-1,5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol ;2-methyl-1,3-heptanediol; 3-methyl-1,3-heptanediol; 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol Diol; 6-methyl-1,3-heptanediol; 2-methyl-1,4-heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4 -Heptanediol; 5-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1 , 5-heptanediol; 4-methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 6-methyl-1,5-heptanediol; 2-methyl -1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 6- Methyl-1,6-heptanediol; 2-methyl-2,4-heptanediol; 3-methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol Alcohol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6- Heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3, 5-heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol ; 3,5-octanediol; and/or 3,6-octanediol.

Preferred C ₈ -1,3-diol mixtures can be formed by condensation of mixtures of butyraldehyde, isobutyraldehyde and/or methyl ethyl ketone (2-butanone), as long as there are at least two of these reactants in the reaction mixture , in the presence of a strongly basic catalyst, followed by conversion by hydrogenation to form a C ₈ -1,3-diol mixture, that is, a C ₈ -1,3-diol mixture consisting mainly of the following diols: 2,2,4- Trimethyl-1,3-pentanediol; 2-ethyl-1,3-hexanediol; 2,2-dimethyl-1,3-hexanediol; 2-ethyl-4-methyl -1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 3,5-octanediol; 2,2-dimethyl-2,4-hexanediol ; 2-methyl-3,5-heptanediol; and/or 3-methyl-3,5-heptanediol. 2,2,4-Trimethyl-1,3-pentanediol is present in less than half of any mixture, and when it is present, it is probably derived from the methylene group in 2-butanone as is the other minor isomer Condensation on the methyl group rather than on the methyl group.

The formulatability of certain _C6-8 diols not listed in Tables II-IV above as preferred, and other properties such as odor, flow, melting point depression, etc., can be improved by polyalkoxylation. Certain alkoxylated _C3-5 diols are also preferred. Preferred alkoxylated derivatives of the above C _3-8 diols [In the following disclosure, "EO" refers to polyethoxylate, "En" refers to -(CH ₂ CH ₂ O) _n H; Me-E _n refers to methyl-terminated polyethoxylate -(CH ₂ CH ₂ O) _n CH ₃ ; "2(Me-E _n )" refers to the desired 2Me-E _n group; "PO" refers to polypropylene Oxylate, -(CH(CH ₃ )CH ₂ O) _n H; "BO" refers to polybutylene oxide, -(CH(CH ₂ CH ₃ )CH ₂ O) _n H; and "n-BO" refers to Poly(n-butyleneoxy)-(CH ₂ CH ₂ CH ₂ CH ₂ O) _n H], including: 1. 1,2-propylene glycol (C3) 2 (Me-E _3-4 ); 1,2- Propylene glycol (C3)PO ₄ ; 2-methyl-1,2-propanediol (C4) (Me-E _8-10 ); 2-methyl-1,2-propanediol (C4)2 (Me-E ₁ ); 2-methyl-1,2-propanediol (C4)PO ₃ ; 1,3-propanediol (C3)2(Me-E ₈ ); 1,3-propanediol (C3)PO ₆ ; 2,2-diethyl -1,3-propanediol (C7) E _4-7 ; 2,2-diethyl-1,3-propanediol (C7)PO ₁ ; 2,2-diethyl-1,3-propanediol (C7)n -BO ₂ ; 2,2-dimethyl-1,3-propanediol (C5)2 (MeE _1-2 ); 2,2-dimethyl-1,3-propanediol (C5)PO ₄ ; 2-( 1-methylpropyl)-1,3-propanediol (C7) E _4-7 ; 2-(1-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methyl Propyl)-1,3-propanediol (C7)n-BO ₂ ; 2-(2-methylpropyl)-1,3-propanediol (C7)E _4-7 ; 2-(2-methylpropyl )-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1,3-propanediol (C7)n-BO ₂ ; 2-ethyl-1,3-propanediol (C5) (MeE _9-10 ); 2-Ethyl-1,3-propanediol (C5) 2 (MeE ₁ ); 2-Ethyl-1,3-propanediol (C5)PO ₃ ; 2-Ethyl-2-methyl Base-1,3-propanediol (C6) (MeE _{3 -6} ); 2-Ethyl-2-methyl-1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl-1, 3-propanediol (C6)BO ₁ ; 2-isopropyl-1,3-propanediol (C6) (MeE _3-6 ); 2-isopropyl-1,3-propanediol (C6)PO 2 ; 2-isopropyl-1,3-propanediol (C6)PO ₂ ; Propyl-1,3-propanediol (C6)BO ₁ ; 2-methyl-1,3-propanediol (C4)2(MeE _4-5 ); 2-methyl-1,3-propanediol (C4)PO ₅ ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)E _6-9 ; 2-methyl-2-isopropyl Base-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)n-BO _2-3 ; 2-methyl-2-propyl-1 , 3-propanediol (C7) E _4-7 ; 2-methyl-2-propyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-propyl-1,3-propanediol (C7 )n-BO ₂ ; 2-propyl-1,3-propanediol (C6) (MeE _1-4 ); 2-propyl-1,3-propanediol (C6)PO ₂ ; 2.1,2-butanediol Alcohol (C4) (Me-E _6-8 ); 1,2-Butanediol (C4)PO _2-3 ; 1,2-Butanediol (C4)BO ₁ ; 2,3-Dimethyl-1 , 2-butanediol (C6) E _2-5 ; 2,3-dimethyl-1,2-butanediol (C6) n-BO ₁ ; 2-ethyl-1,2-butanediol ( C6)E _1-3 ; 2-ethyl-1,2-butanediol (C6)n-BO ₁ ; 2-methyl-1,2-butanediol (C5)(Me-E _1-2 ) ; 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _2-5 ; 3,3-dimethyl- 1,2-butanediol (C6) n-BO ₁ ; 3-methyl-1,2-butanediol (C5) (MeE _1-2 ); 3-methyl-1,2-butanediol ( C5)PO ₁ ; 1,3-butanediol (C4) 2 (MeE _5-6 ); 1,3-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,3- Butanediol (C7) (MeE _{1 -3} ); 2,2,3-trimethyl-1,3-butanediol (C7)PO ₂ ; 2,2-dimethyl-1,3-butanediol Alcohol (C6) (MeE _6-8 ); 2,2-Dimethyl-1,3-butanediol (C6)PO ₃ ; 2,3-Dimethyl-1,3-butanediol (C6) (MeE _{6 -8} ); 2,3-Dimethyl-1,3-butanediol (C6)PO ₃ ; 2-Ethyl-1,3-butanediol (C6) (MeE _4-6 ); 2-Ethyl-1,3-butanediol (C6)PO _{2 -3} ; 2-Ethyl-1,3-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1, 3-Butanediol (C7) (MeE ₁ ); 2-Ethyl-2-methyl-1,3-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,3- Butanediol (C7)n-BO ₃ ; 2-Ethyl-3-methyl-1,3-butanediol (C7)(MeE ₁ ); 2-Ethyl-3-methyl-1,3- Butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,3-butanediol (C7)n-BO ₃ ; 2-isopropyl-1,3-butanediol (C7) (MeE ₁ ); 2-isopropyl-1,3-butanediol (C7)PO ₁ ; 2-isopropyl-1,3-butanediol (C7)n-BO ₃ ; 2-methyl- 1,3-butanediol (C5) 2 (MeE _2-3 ); 2-methyl-1,3-butanediol (C5)PO ₄ ; 2-propyl-1,3-butanediol (C7 )E _6-8 ; 2-propyl-1,3-butanediol (C7)PO ₁ ; 2-propyl-1,3-butanediol (C7)n-BO _2-3 ; 3-methyl -1,3-butanediol (C5) 2 (MeE _2-3 ); 3-methyl-1,3-butanediol (C5)PO ₄ ; 1,4-butanediol (C4) 2 (MeE _3-4 ); 1,4-butanediol (C4)PO _4-5 ; 2,2,3-trimethyl-1,4-butanediol (C7)E _6-9 ; 2,2,3 -Trimethyl-1,4-butanediol (C7)PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _2-3 ; 2,2-di Methyl-1,4-butanediol (C6) (MeE _3-6 ); 2,2-Dimethyl-1,4-butanediol (C6)PO ₂ ; 2,2-Dimethyl-1 , 4-butanediol (C6) BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _{3- 6} ); 2,3-dimethyl-1,4-butane Diol (C6)PO ₂ ; 2,3-dimethyl-1,4-butanediol (C6)BO ₁ ; 2-ethyl-1,4-butanediol (C6)(MeE _{1 -4} ) ; 2-Ethyl-1,4-butanediol (C6)PO ₂ ; 2-Ethyl-2-methyl-1,4-butanediol (C7)E _4-7 ; 2-Ethyl-2 -Methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7)n-BO ₂ ; 2-Ethyl-3-methano Base-1,4-butanediol (C7)E _4-7 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl- 1,4-butanediol (C7) n-BO ₂ ; 2-isopropyl-1,4-butanediol (C7)E _4-7 ; 2-isopropyl-1,4-butanediol ( C7) PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO ₂ ; 2-methyl-1,4-butanediol (C5) (MeE _9-10 ); 2- Methyl-1,4-butanediol (C5) 2 (MeE ₁ ); 2-methyl-1,4-butanediol (C5)PO ₃ ; 2-propyl-1,4-butanediol ( C7) E _2-5 ; 2-propyl-1,4-butanediol (C7)n-BO ₁ ; 3-ethyl-1-methyl-1,4-butanediol (C6)E _{6- 8} ; 3-ethyl-1-methyl-1,4-butanediol (C7)PO ₁ ; 3-ethyl-1-methyl-1,4-butanediol (C7)n-BO _{2- 3} ; 2,3-butanediol (C4) (MeE _9-10 ); 2,3-butanediol (C4) 2 (MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-Dimethyl-2,3-butanediol (C6)E _{7 -9} ; 2,3-Dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3-dimethyl Base-2,3-butanediol (C6)BO _2-3 ; 2-methyl-2,3-butanediol (C5)(MeE _{2 -5} ); 2-methyl-2,3-butanediol Alcohol (C5) PO ₂ ; 2-methyl-2,3-butanediol (C5) BO ₁ ; 3.1,2-pentanediol (C5) E _7-10 ; 1,2-pentanediol ( C5) PO ₁ ; 1,2-pentanediol (C5)n-BO ₃ ; 2-methyl-1,2-pentanediol (C6)E _1-3 ; 2-methyl-1,2-pentane Diol (C6) n-BO ₁ ; 3-methyl-1,2-pentanediol (C6) E _1-3 ; 3-methyl-1,2-pentanediol (C6) n-BO ₁ ; 4-methyl-1,2-pentanediol (C6) E _1-3 ; 4-methyl-1,2-pentanediol (C6)n-BO ₁ ; 1,3-pentanediol (C5) 2(Me-E _1-2 ); 1,3-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,3-pentanediol (C7)(Me-E ₁ ); 2,2-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,2-Dimethyl-1,3-pentanediol (C7)n-BO ₃ ; 2,3-dimethyl Base-1,3-pentanediol (C7) (Me-E ₁ ); 2,3-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,3-Dimethyl-1, 3-pentanediol (C7) n-BO ₃ ; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 2,4-dimethyl-1,3- pentanediol (C7)PO ₁ ; 2,4-dimethyl-1,3-pentanediol (C7)n-BO ₃ ; 2-ethyl-1,3-pentanediol (C7)E _{6- 8} ; 2-ethyl-1,3-pentanediol (C7)PO ₁ ; 2-ethyl-1,3-pentanediol (C7)n-BO _2-3 ; 2-methyl-1,3 -Pentanediol (C6) 2 (Me-E _4-6 ); 2-Methyl-1,3-pentanediol (C6)PO _2-3 ; 3,4-Dimethyl-1,3-pentane Diol (C7) (Me-E ₁ ); 3,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,3-pentanediol (C7 )n-BO ₃ ; 3-methyl-1,3-pentanediol (C6) 2 (Me-E _4-6 ); 3-methyl-1,3-pentanediol (C6)PO _2-3 ; 4,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 4,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 4,4 -Dimethyl-1,3-pentanediol (C7)n-BO ₃ ; 4-methyl-1,3-pentanediol (C6)2(MeE _4-6 ); 4-Methyl-1, 3-pentanediol (C6)PO _2-3 ; 1,4-pentanediol (C5) 2 (Me-E _1-2 ); 1,4-pentanediol (C5)PO _3-4 ; 2, 2-Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,2-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,2-dimethyl Base-1,4-pentanediol (C7)n-BO ₃ ; 2,3-Dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,3-Dimethyl- 1,4-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,4-pentanediol (C7)n-BO ₃ ; 2,4-dimethyl-1,4-pentanediol Alcohol (C7) (Me-E ₁ ); 2,4-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,4-pentanediol (C7) n-BO ₃ ; 2-methyl-1,4-pentanediol (C6) (Me-E _4-6 ); 2-methyl-1,4-pentanediol (C6)PO _2-3 ; 3 , 3-dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 3,3-dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,3-di Methyl-1,4-pentanediol (C7)n-BO ₃ ; 3,4-Dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,4-Dimethyl -1,4-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,4-pentanediol (C7)n-BO ₃ ; 3-methyl-1,4-pentanediol ( C6) 2(Me-E _4-6 ); 3-methyl-1,4-pentanediol (C6)PO _2-3 ; 4-methyl-1,4-pentanediol (C6) 2(Me -E _4-6 ); 4-methyl-1,4-pentanediol (C6)PO _2-3 ; 1,5-pentanediol (C5) (Me-E _4-10 ); 1,5- pentanediol (C5)2(Me- _E1 ); 1,5-pentanediol (C5) _PO3 ; 2,2-dimethyl-1,5-pentanediol (C7) _E4-7 ; 2,2-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-Dimethyl-1,5-pentanediol (C7)n-BO ₂ ; 2,3-dimethyl Base-1,5-pentanediol (C7) E _4-7 ; 2,3-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,3-Dimethyl-1,5- Pentanediol (C7) n-BO ₂ ; 2,4-dimethyl-1,5-pentanediol (C7)E _4-7 ; 2,4-dimethyl-1,5-pentanediol ( C7) PO ₁ ; 2,4-dimethyl-1,5-pentanediol (C7)n-BO ₂ ; 2-ethyl-1,5-pentanediol (C7)E _2-5 ; 2- Ethyl-1,5-pentanediol (C7)n-BO ₁ ; 2-methyl-1,5-pentanediol (C6)(Me-E _1-4 ); 2-methyl-1,5 -pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _4-7 ; 3,3-dimethyl-1,5-pentanediol (C7 )PO ₁ ; 3,3-dimethyl-1,5-pentanediol (C7)n-BO ₂ ; 3-methyl-1,5-pentanediol (C6)(Me-E _1-4 ) ; 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) (Me-E _1-3 ); 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6) E _4-7 ; 2-methyl-2,3-pentanediol (C6)PO ₁ ; 2-methyl-2,3-pentanediol Alcohol (C6)n-BO ₂ ; 3-methyl-2,3-pentanediol (C6)E _4-7 ; 3-methyl-2,3-pentanediol (C6)PO ₁ ; 3-methyl Base-2,3-pentanediol (C6)n-BO ₂ ; 4-methyl-2,3-pentanediol (C6)E _4-7 ; 4-methyl-2,3-pentanediol ( C6)PO ₁ ; 4-methyl-2,3-pentanediol (C6)n-BO ₂ ; 2,4-pentanediol (C5)2(Me-E _2-4 ); 2,4-pentanediol Diol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol (C7) (Me-E _2-4 ); 2,3-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-dimethyl-2,4-pentanediol (C7) (Me-E _2-4 ); 2,4-dimethyl-2,4-pentanediol (C7 )PO ₂ ; 2-methyl-2,4-pentanediol (C7) (Me-E _8-10 ); 2-methyl-2,4-pentanediol (C7)PO ₃ ; 3,3- Dimethyl-2,4-pentanediol (C7) (Me-E _2-4 ); 3,3-Dimethyl-2,4-pentanediol (C7)PO ₂ ; 3-methyl-2 , 4-pentanediol (C6) (Me-E _8-10 ); 3-methyl-2,4-pentanediol (C6)PO ₃ ;

4. 1,3-hexanediol (C6) (Me-E _2-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _6-8 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _2-3 ; 3-methyl-1,3-hexanediol (C7)E _6-8 ; 3-methyl-1,3-hexanediol (C7)PO ₁ ; 3-methyl- 1,3-hexanediol (C7) n-BO _2-3 ; 4-methyl-1,3-hexanediol (C7) E _6-8 ; 4-methyl-1,3-hexanediol ( C7) PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _2-3 ; 5-methyl-1,3-hexanediol (C7)E _6-8 ; 5-methyl Base-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n-BO _2-3 ; 1,4-hexanediol (C6)(Me- E _2-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7)E _{6- 8} ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _2-3 ; 3-methyl-1,4 -Hexanediol (C7) E _6-8 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3-methyl-1,4-hexanediol (C7)n-BO _{2- 3} ; 4-methyl-1,4-hexanediol (C7) E _6-8 ; 4-methyl-1,4-hexanediol (C7)PO ₁ ; 4-methyl-1,4-hexane Diol (C7) n-BO _2-3 ; 5-methyl-1,4-hexanediol (C7)E _6-8 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _2-3 ; 1,5-hexanediol (C6) (Me-E _2-5 ); 1,5-hexanediol (C6 )PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7)E _6-8 ; 2-methyl-1,5-hexanediol ( C7) PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _2-3 ; 3-methyl-1,5-hexanediol (C7)E _6-8 ; 3-methanol Base-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n-BO _2-3 ; 4-methyl-1,5-hexanediol ( C7) E _6-8 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1,5-hexanediol (C7)n-BO _2-3 ; 5-methyl Base-1,5-hexanediol (C7) E _6-8 ; 5-methyl-1,5-hexanediol (C7)PO ₁ ; 5-methyl-1,5-hexanediol (C7) n-BO _2-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6)PO _1-2 ; 1,6-hexanediol (C6 )n-BO ₄ ; 2-methyl-1,6-hexanediol (C7)E _2-5 ; 2-methyl-1,6-hexanediol (C7)n-BO ₁ ; 3-methyl -1,6-hexanediol (C7) E _2-5 ; 3-methyl-1,6-hexanediol (C7) n-BO ₁ ; 2,3-hexanediol (C6) E _2-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,4-hexanediol (C6) (Me-E _5-8 ); 2,4-hexanediol (C6)PO ₃ ; 2- Methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4 -hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7 )(Me-E _1-2 ); 4-methyl-2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _{1 -2} ); 5-methyl-2,4-hexanediol (C7)PO _1-2 ; 2,5-hexanediol (C6) (Me-E _5-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-methyl-2,5-hexanediol (C7)(Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol Alcohol (C6) EO _2-5 ; 3,4-Hexanediol (C6) n-BO ₁ ;

5. 1,3-heptanediol (C7)E _3-6 ; 1,3-heptanediol (C7)PO ₁ ; 1,3-heptanediol (C7)n-BO ₂ ; 1,4-heptanediol Diol (C7) E _3-6 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO ₂ ; 1,5-Heptanediol (C7)E _{3 -6} ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO ₂ ; 1,6-heptanediol (C7)E _3-6 ; 1,6- Heptanediol(C7)PO ₁ ; 1,6-Heptanediol(C7)n-BO ₂ ; 1,7-Heptanediol(C7)E _1-2 ; 1,7-Heptanediol(C7)n -BO ₁ ; 2,4-Heptanediol (C7)E _7-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol (C7)PO ₁ ; 2 , 4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _7-10 ; 2,5-heptanediol (C7) (Me-E ₁ ); 2,5- Heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-BO ₃ ; 2,6-heptanediol (C7) E _7-10 ; 2,6-heptanediol (C7) ( Me-E ₁ ); 2,6-heptanediol (C7)PO ₁ ; 2,6-heptanediol (C7)n-BO ₃ ; 3,5-heptanediol (C7)E _7-10 ; 3 , 5-heptanediol (C7) (Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ;

6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 - Isopropyl-1,3-butanediol (C8) n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8) n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl-2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptane Diol (C8)n- _BO1 ; 3-methyl-2,4-heptanediol (C8)n- _BO1 ; 4-methyl-2,4-heptanediol (C8)n- _BO1 ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl-2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptane Diol (C8)n- _BO1 ; 3-methyl-2,5-heptanediol (C8)n- _BO1 ; 4-methyl-2,5-heptanediol (C8)n- _BO1 ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl-2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptane Diol (C8)n- _BO1 ; 3-methyl-2,6-heptanediol (C8)n- _BO1 ; 4-methyl-2,6-heptanediol (C8)n- _BO1 ; 2-Methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)E _1-3 ; 2-Ethylene Base-2,3-dimethyl-1,3-butanediol (C8) E _1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8) E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8) E _1-3 ; 5-methyl-2,5-heptanediol (C8) E _1-3 ; 6-methyl-2,5-heptanediol (C8) E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; and

7. Mixtures thereof.

Of the nonane isomers, only 2,3,3,4-tetramethyl-2,4-pentanediol is highly preferred.

In addition to the aliphatic glycol primary solvents discussed in this context, and certain of their alkoxylated derivatives, certain specific glycol ethers have also been found to be suitable for formulating the liquid concentrated clear fabric softener compositions of the present invention. main solvent. Similar to the aliphatic glycol primary solvents, it has been found that the suitability of each primary solvent is very selective, depending, for example, on the number of carbon atoms in the particular glycol ether molecule. For example, as given in Table _VI , for the series of glyceryl ethers _having the formula _HOCH2 -CHOH- _CH2 -OR, where R is a C2 to C8 alkyl group, only Monoamyl ether of OC ₅ H ₁₁ (3-pentyloxy-1,2-propanediol), wherein the C ₅ H ₁₁ group contains different pentyl isomers, having a preferred ClogP value between about 0.25 and about 0.62 range of ClogP values and is suitable for formulating the liquid concentrated clear fabric softeners of the present invention. These are illustrated by Examples and Comparative Examples XXXIIA-7 to XXXIIA-7F. It was also found that cyclohexyl derivatives are suitable rather than cyclopentyl derivatives. A similar selectivity is reflected in the selectivity of aryl glyceryl ethers. Of the many possible aromatic groups, only a few phenol derivatives are suitable.

The same narrow range selectivity was also found for di(hydroxyalkyl)ethers. It was also found that bis(2-hydroxybutyl) ether was suitable rather than bis(2-hydroxypentyl) ether. For the bis(cyclic hydroxyalkyl) analog, bis(2-hydroxycyclopentyl)ether is suitable instead of bis(2-hydroxycyclohexyl)ether. Non-limiting examples of synthetic methods for the preparation of certain preferred bis(hydroxyalkyl)ethers are given below.

Butyl monoglyceryl ether (also known as 3-butoxy-1,2-propanediol) is less suitable for formulating the liquid concentrated clear fabric softeners of the present invention. However, polyethoxylated derivatives thereof, preferably from about triethoxylated to about nonaethoxylated derivatives, more preferably pentaethoxylated to about octaethoxylated derivatives, are suitable primary solvents , as given in Table VI.

All preferred alkyl glyceryl ethers and/or di(hydroxyalkyl)ethers that have been identified are given in Table VI, the most preferred being: 3-(n-pentyloxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3-(2-methyl-1-butoxy)-1,2 -Propanediol; 3-(iso-pentyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy)-1,2-propanediol; 3-(cyclohexyloxy)-1 , 2-propanediol; 3-(1-cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy)-1,3-propanediol; 2-(2-pentyloxy)- 1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1-butoxy)-1,3-propanediol; 2-(iso-pentyloxy base)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-(cyclohexyloxy)-1,3-propanediol; 2-(1- cyclohex-1-enyloxy)-1,3-propanediol; pentaethoxylated 3-(butoxy)-1,2-propanediol; hexaethoxylated 3-(butoxy)- 1,2-propanediol; heptaethoxylated 3-(butoxy)-1,2-propanediol; octaethoxylated 3-(butoxy)-1,2-propanediol; nonaethoxylated Monopropoxylated 3-(butoxy)-1,2-propanediol; Monopropoxylated 3-(butoxy)-1,2-propanediol; Dibutylideneoxylated 3-(butoxy)- 1,2-propanediol; and/or tributoxylated 3-(butoxy)-1,2-propanediol. Preferred aromatic glyceryl ethers include: 3-phenoxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3-(2-phenylethoxy)-1,2-propanediol ; 2-(m-tolyloxy)-1,2-propanediol; 2-(m-tolyloxy)-1,3-propanediol; 2-(p-tolyloxy)-1,3-propanediol; 2-benzyloxy 2-(2-phenylethoxy)-1,3-propanediol; and mixtures thereof. More preferred aromatic glyceryl ethers include: 3-phenoxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3-(2-phenylethoxy)-1,2- Propylene glycol; 2-(m-tolyloxy)-1,2-propanediol; 2-(m-tolyloxy)-1,3-propanediol; 2-(p-tolyloxy)-1,3-propanediol; 2-( 2-phenylethoxy)-1,3-propanediol; and mixtures thereof. Most preferred bis(hydroxyalkyl) ethers include: bis(2-hydroxybutyl) ether; and bis(2-hydroxycyclopentyl) ether;

Illustrative and non-limiting examples of synthetic methods for the preparation of preferred alkyl and aryl monoglyceryl ethers are given below.

Preferred cycloaliphatic diols and their derivatives include: (1) saturated diols and their derivatives, including: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl -1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentadiol Diol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 2,4,5-trimethyl-1,3 - Cyclopentanediol; 3,3-Dimethyl-1,2-cyclopentadiol; 3,4-Dimethyl-1,2-cyclopentadiol; 3,5-Dimethyl-1, 2-cyclopentadiol; 3-ethyl-1,2-cyclopentadiol; 4,4-dimethyl-1,2-cyclopentadiol; 4-ethyl-1,2-cyclopentadiol Alcohol; 1,1-bis(hydroxymethyl)cyclohexane; 1,2-bis(hydroxymethyl)cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3 - bis(hydroxymethyl)cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxy-cyclohexane Hexane ethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1 , 3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl- 1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2- Hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; 3- Methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6- Dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4- Methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol Alcohol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1 , 3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl-1,4-cycloheptanediol; 1,3-cyclooctanediol; 1,4-cyclo Octanediol; 1,5-cyclooctanediol; 1,2-cyclohexanediol diethoxylate; 1,2-cyclohexanediol triethoxylate; 1,2-cyclohexanediol tetraethoxylate Ethoxylate; 1,2-cyclohexanediol pentaethoxylate; 1,2-cyclohexanediol hexaethoxylate; 1,2-cyclohexanediol heptaethoxylate; 1,2 -Cyclohexanediol octaethoxylate; 1,2-cyclohexanediol nonaethoxylate; 1,2-cyclohexanediol monopropoxylate; 1,2-cyclohexanediol monobutylidene oxide 1,2-cyclohexanediol dibutylidene oxide; and/or 1,2-cyclohexanediol tributylidene oxide. The most preferred saturated alicyclic diols and their derivatives are: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3- Propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentadiol; 1,2-dimethyl-1 , 2-cyclopentanediol; 1,4-dimethyl-1,2-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl- 1,2-cyclopentadiol; 3,5-dimethyl-1,2-cyclopentadiol; 3-ethyl-1,2-cyclopentadiol; 4,4-dimethyl-1, 2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis(hydroxymethyl)cyclohexane; 1,2-bis(hydroxymethyl)cyclohexane; 1 , 2-Dimethyl-1,3-cyclohexanediol; 1,3-bis(hydroxymethyl)cyclohexane; 1-hydroxy-cyclohexanemethanol; 1-methyl-1,2-cyclohexane Diol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl -1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanediol Hexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 1,2-cycloheptanediol; 1,2-cyclohexanediol pentaethoxylate; 1 , 2-cyclohexanediol hexaethoxylate; 1,2-cyclohexanediol heptaethoxylate; 1,2-cyclohexanediol octaethoxylate; 1,2-cyclohexanediol nine ethoxylates; 1,2-cyclohexanediol monopropoxylate; and/or 1,2-cyclohexanediol dibutylideneoxylate.

Preferred aromatic diols include: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1, 2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; and/or 1-phenyl-1,4-butanediol, most preferred of which are: 1- Phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4 -tolyl)-1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; and/or 1-phenyl-1,4-butanediol.

As discussed above, all unsaturated materials that are related to the other preferred principal solvents of the present invention due to the same relationship, i.e., have one more _CH2 group than the corresponding saturated principal solvent and have ClogP values that remain within the effective range Unsaturated materials within are preferred. However, specifically preferred primary solvents for unsaturated diols are: 2,2-diallyl-1,3-butanediol; 2-(1-ethyl-1-propenyl)-1,3-butanediol Alcohol; 2-(2-butenyl)-2-methyl-1,3-butanediol; 2-(3-methyl-2-butenyl)-1,3-butanediol; 2- Ethyl-2-(2-propenyl)-1,3-butanediol; 2-methyl-2-(1-methyl-2-propenyl)-1,3-butanediol; 2,3 - Di(1-methylethylene)-1,4-butanediol; 2-vinyl-3-ethyl-1,3-pentanediol; 2-vinyl-4,4-dimethyl -1,3-pentanediol 3-methyl-2-(2-propenyl)-1,4-pentanediol; 2-(1,1-dimethylethyl)-4-pentene-1 ,3-diol; 2-ethyl-2,3-dimethyl-4-pentene-1,3-diol; 4-ethyl-2-methylene-1,4-hexanediol; 2,3,5-Trimethyl-1,5-hexadiene-3,4-diol; 2-(1-methylvinyl)-1,5-hexanediol; 4-vinyl-2 , 5-dimethyl-2-hexene-1,5-diol; 6-methyl-5-methylene-1,4-heptanediol; 4,6-dimethyl-2,4- Heptadiene-2,6-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 5,6-dimethyl-2-heptene-1 ,4-diol; 4,6-dimethyl-3-heptene-1,5-diol; 2,4-dimethyl-5-heptene-1,3-diol; 3,6- Dimethyl-5-heptene-1,3-diol; 2,6-dimethyl-5-heptene-1,4-diol; 3,6-dimethyl-5-heptene-1 ,4-diol; 2,2-dimethyl-6-heptene-1,3-diol; 5,6-dimethyl-6-heptene-1,4-diol; 2,4- Dimethyl-6-heptene-1,5-diol; 2-Ethylene-6-methyl-6-heptene-1,5-diol; 4-(2-propenyl)-6- Heptene-2,4-diol; 3-Ethylene-1-octene-3,6-diol; 2,7-Dimethyl-2,4,6-octatriene-1,8- Diol; 2,6-Dimethyl-2,5-octadiene-1,7-diol; 3,7-Dimethyl-2,5-octadiene-1,7-diol; 3 , 7-Dimethyl-2,6-octadiene-1,4-diol (Rosiridol); 2-methyl-2,6-octadiene-1,8-diol; 3,7-diol Methyl-2,7-octadiene-1,4-diol; 2,6-dimethyl-2,7-octadiene-1,5-diol; 2,6-dimethyl-2 , 7-octadiene-1,6-diol (8-hydroxylinalool); 2,7-dimethyl-2,7-octadiene-1,6-diol; 2-methyl- 6-methylene-2-octene-1,7-diol; 2,7-dimethyl-3,5-octadiene-2,7-diol; 4-methylene-3,5 -octanediol; 2,6-dimethyl-3,7-octadiene-1,6-diol; 2-methylene-4-octene-1,8-diol; 2-methyl -6-octene-3,5-diol; 4-methyl-6-octene-3,5-diol; 2-methyl-6-methylene-7-octene-2,4- Diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene-3,5-diol; 1-nonene-3,5-diol; 1 -nonene-3,7-diol; 3-nonene-2,5-diol; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-Nonene-2,4-diol; 8-Nonene-2,4-diol; 8-Nonene-2,5-diol; 1,9-Decadiene-3,8-diol ; and/or 1,9-decadiene-4,6-diol.

The main alcohol solvent can also be preferably selected from: 2,5-dimethyl-2,5-hexanediol; 2-ethyl-1,3-hexanediol; 2-methyl-2-propane 1,3-propanediol; 1,2-hexanediol; and mixtures thereof. More preferably said alcohol solvent is selected from 2-ethyl-1,3-hexanediol; 2-methyl-2-propyl-1,3-propanediol; 1,2-hexanediol; and mixtures thereof . More preferably, the primary alcohol solvent is selected from 2-ethyl-1,3-hexanediol; 1,2-hexanediol; and mixtures thereof.

When several derivatives of the same diol with different alkyleneoxy groups can be used, for example, 2-methoxyl with 3 to 5 ethyleneoxy, or 2 propyleneoxy, or 1 butyleneoxy In the case of 2,3-butanediol, it is preferred to use the derivative with the smallest number of groups, ie, in this case, a derivative with 1 butyleneoxy group is preferred. However, such derivatives are also preferred when only about 1 to about 4 ethyleneoxy groups are required to provide good formulatability.

Unsaturated diols

It has been surprisingly found that there are significant similarities in acceptability (formulatability) between saturated diols and their higher molecular weight unsaturated homologues or analogs. Unsaturated homologues/analogues have the same formulatability as the parent saturated primary solvent, provided that the unsaturated primary solvent has an added methylene group in the formula corresponding to each double bond (i.e., CH ₂ ) . In other words, there is a distinct "additional rule" that for every excellent saturated primary solvent of the present invention suitable for formulating clear concentrated fabric softener compositions, there is an appropriate unsaturated primary solvent, where one or more _CH2 groups are added, and for each added _CH2 group, two hydrogen atoms are removed from its adjacent carbon atoms in the molecule to form a carbon-carbon double bond, thus corresponding to " The chemical formula of the main solvent saturated with "parent" and the number of hydrogen atoms in the molecule remains unchanged. This is due to the surprising fact that adding a _-CH2- group to a solvent chemical formula has the effect of increasing its ClogP value by about 0.53, whereas removing two adjacent hydrogen atoms to form a double bond has the effect of decreasing its ClogP value The effect of about the same value, ie about 0.48, thus approximately compensates for the addition of the _-CH2- group. Thus from the preferred saturated principal solvents it can be deduced that the preferred higher molecular weight unsaturated analogues/homologues contain at least one carbon atom by intercalation of a double bond for each added _CH2 group, thus The total number of hydrogen atoms remains the same as that of the parent saturated primary solvent so long as the ClogP value of the new solvent remains in the effective range of 0.15-0.64, preferably in the range of about 0.25 to about 0.62, more preferably in the range of about 0.40 to about 0.60. The following are some illustrative examples:

2,2-Dimethyl-6-heptene-1,3-diol (CAS registry number: 140192-39-8) is the preferred C9 diol primary solvent, which can be considered as one of the following Preferred main solvents of C8 diols derived by appropriate addition of _CH2 groups and double bonds: 2-methyl-1,3-heptanediol or 2,2-dimethyl-1,3-hexanediol .

2,4-Dimethyl-5-heptene-1,3-diol (CAS registry number: 123363-69-9) is the preferred C9 diol primary solvent, which can be considered as one of the following Preferred main solvents of C8 diols derived by appropriate addition of _CH2 groups and double bonds: 2-methyl-1,3-heptanediol or 2,4-dimethyl-1,3-hexanediol .

2-(1-Ethyl-1-propenyl)-1,3-butanediol (CAS Registry No.: 116103-35-6) is the preferred C9 diol primary solvent, which can be considered by adding One of the preferred C8 diol main solvents is derived by appropriately adding _CH2 groups and double bonds: 2-(1-ethylpropyl)-1,3-propanediol or 2-(1-methylpropyl )-1,3-butanediol.

2-vinyl-3-ethyl-1,3-pentanediol (CAS Registry No.: 104683-37-6) is the preferred C9 diol primary solvent which can be considered as preferred by going to one of the following The C8 diol main solvent is derived by appropriately adding _CH2 groups and double bonds: 3-ethyl-2-methyl-1,3-pentanediol or 2-ethyl-3-methyl-1, 3-pentanediol.

3,6-Dimethyl-5-heptene-1,4-diol (e.g., CAS registry number: 106777-99-5) is the preferred C9 diol primary solvent, which can be considered as A preferred C8 diol main solvent is derived by appropriately adding _CH2 groups and double bonds: 3-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol; Or 3,5-dimethyl-1,4-hexanediol.

5,6-Dimethyl-6-heptene-1,4-diol (e.g., CAS registry number: 152344-16-6) is the preferred C9 diol primary solvent, which can be considered as A preferred C8 diol main solvent is derived by appropriately adding _CH2 groups and double bonds: 5-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol; Or 4,5-dimethyl-1,3-hexanediol.

4-Methyl-6-octene-3,5-diol (CAS registry number: 156414-25-4) is the preferred C9 diol primary solvent, which can be considered as the preferred C8 Derivatized by appropriate addition of _CH2 groups and double bonds to diol main solvents: 3,5-octanediol, 3-methyl-2,4-heptanediol or 4-methyl-3,5-heptanediol diol.

Rosiridol (CAS registry number: 101391-01-9) and isorosiridol (CAS registry number: 149252-15-3) are two compounds of 3,7-dimethyl-2,6-octadiene-1,4-diol isomers and is the preferred primary solvent for C10-diols. They can be considered to be derived by the appropriate addition of two CH2 groups and two double bonds to any of the following preferred C8 diol principal solvents: 2-methyl-1,3-heptanediol; 6-methanol Base-1,3-heptanediol; 3-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol; 2,5-dimethyl-1,3-hexanediol alcohol; or 3,5-dimethyl-1,4-hexanediol.

8-Hydroxylinalool (CAS registry number: 103619-06-3, 2,6-dimethyl-2,7-octadiene-1,6-diol) is the preferred C10-diol main solvent, It can be considered to be derived by the appropriate addition of two _CH2 groups and two double bonds to any of the following preferred C8 diol principal solvents: 2-methyl-1,5-heptanediol; 5- Methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol; or 2,4-dimethyl-1,4- Hexylene glycol.

2,7-Dimethyl-3,7-octadiene-2,5-diol (CAS registry number: 171436-39-8) is the preferred C10-diol main solvent, which can be considered as a Any of the following preferred C8 diols derived from the appropriate addition of _two CH groups and two double bonds: 2,5-octanediol; 6-methyl-1,4-heptanediol; 2 -Methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol ; and 2,5-dimethyl-2,4-hexanediol.

4-Butyl-2-butene-1,4-diol (CAS Registry No.: 153943-66-9) is the preferred C8-diol primary solvent, which can be considered to be derived from any of the following preferred C7 diols Derivatized by appropriately adding _CH2 groups and double bonds to alcohol main solvents: 2-propyl-1,4-butanediol; or 2-butyl-1,3-propanediol.

For the same reason, there are cases where higher molecular weight unsaturated homologues derived from poorly unsuitable saturated solvents are themselves poor solvents. For example, 3,5-dimethyl-5-hexene-2,4-diol (e.g., CAS registry number: 160429-40-3) is a poorly unsaturated C8 solvent, which can be considered by the following difference Derived from saturated C7 solvent: 3-methyl-2,4-hexanediol; 5-methyl-2,4-hexanediol; or 2,4-dimethyl-1,3-pentanediol and 2,6-dimethyl-5-heptene-1,2-diol (for example, CAS registry number: 141505-71-7) is a poorly unsaturated C9 solvent, which can be considered by the following difference Derivatized from a saturated C8 solvent: 2-methyl-1,2-heptanediol; 6-methyl-1,2-heptanediol; or 2,5-dimethyl-1,2-hexanediol .

It has also been surprisingly found that there are exceptions to the above rule of addition where saturated primary solvents always have unsaturated analogs/congeners with the same degree of acceptability. This exception concerns saturated diol principal solvents having two hydroxyl groups on two adjacent carbon atoms. In some cases, but not always, insertion of one or more _CH2 groups between two adjacent hydroxyl groups of a poor solvent yields higher molecular weight unsaturated homologues, which are more suitable for transparent concentrated fabrics Preparation of softener. For example, the preferred unsaturated 6,6-dimethyl-1-heptene-3,5-diol (CAS registry number: 109788-01-4) has no adjacent hydroxyl groups, which can be considered as derived from Derivatized from the unsuitable 2,2-dimethyl-3,4-hexanediol adjacent to the hydroxyl group. In this case, it is more convincing to think that 6,6-dimethyl-1-heptene-3,5-diol is the preferred primary solvent and neither 2-methyl- 3,5-heptanediol or 5,5-dimethyl-2,4-hexanediol derived. Conversely, insertion of _CH2 groups between adjacent hydroxyl groups of preferred primary solvents can yield unsuitable higher molecular weight unsaturated diol solvents. For example, the unsuitable unsaturated 2,4-dimethyl-5-hexene-2,4-diol (CAS Registry No.: 87604-24-8) with no adjacent hydroxyl groups can be considered from the preferred It is derived from 2,3-dimethyl-2,3-pentanediol adjacent to the hydroxyl group. In this case, it is more convincing to think that the unsuitable unsaturated 2,4-dimethyl-5-heptene-2,4-diol is derived from both unsuitable solvents and 2 without adjacent hydroxyl groups. -Methyl-2,4-hexanediol or 4-methyl-2,4-hexanediol derived. There are also cases where unsuitable unsaturated solvents without adjacent hydroxyl groups can be considered to be derived from unsuitable solvents with adjacent hydroxyl groups, such as 4,5-dimethyl-6-hexene-1 , 3-diol and 3,4-dimethyl-1,2-pentanediol pair. Therefore, to infer the formulatability of unsaturated solvents without adjacent hydroxyl groups, one should start with the low molecular weight saturated homologues without adjacent hydroxyl groups. That is, in general mutual association is more reliable when two hydroxyl groups maintain a distance/connection. That is, it is reliable to start from saturated solvents with adjacent hydroxyl groups to extrapolate the formulatability of higher molecular weight unsaturated homologues that also have adjacent hydroxyl groups.

It has now been found that the use of these specific primary alcoholic solvents can produce clear, low viscosity, stable fabric softener compositions at surprisingly low levels of primary solvent, ie, less than about 40% by weight of the composition. It has also been found that the use of a predominantly alcoholic solvent can produce a highly concentrated fabric softener composition which is stable and which can be diluted, for example from about 2:1 to about 10:1, to obtain a fabric softener having a lower dosage. composition, the composition is still stable.

As previously discussed, the primary solvent is desirably kept at the minimum level allowed by the compositions of the present invention to maintain translucency or transparency. The presence of water plays an important role as the primary solvent to make these compositions transparent. The higher the water content, the higher the level of main solvent (relative to the softener content) needed to make the product clear. Conversely, the lower the water content, the less primary solvent (relative to softener) is required. Thus, at low water levels of from about 5% to about 15%, the weight ratio of softener active to primary solvent is preferably from about 55:45 to about 85:15, more preferably from about 60:40 to about 80:20. At water levels of from about 15% to about 70%, the weight ratio of softener active to primary solvent is preferably from about 45:55 to about 70:30, more preferably from about 55:45 to about 70:30. However, at high water contents of about 70% to about 80%, the weight ratio of softener active to primary solvent is preferably from about 30:70 to about 55:45, more preferably from about 35:65 to about 45:55. At higher water contents, the ratio of softener to primary solvent is even higher.

A mixture of the above-mentioned main solvents is particularly preferred because one of the problems associated with large amounts of solvents is safety. Mixtures reduce the amount of any one material present. Using a mixture also minimizes odor and flammability, especially if one of the primary solvents, more likely a low molecular weight material, is volatile and/or has an odor. Suitable solvents that may be used at levels not sufficient to produce clear products are 2,2,4-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol ethoxylate, diethoxylate, or triethoxylate derivatives; and/or 2-ethyl-1,3-hexanediol. For the purposes of the present invention, these solvents are used only in amounts which do not give a stable or clear product. Preferred mixtures are those in which the major part of the solvent is one or more of those solvents which have been identified above as the most preferred solvents. The use of mixtures of solvents is also preferred, especially when one or more of the preferred primary solvents is a solid at room temperature. In this case, the mixture is fluid, or has a lower melting point, thus improving the processability of the softener composition.

It has also been found that as long as an effective amount of the applicable primary solvent of the present invention is still present in the liquid concentrated clear softener composition, a portion of the secondary solvent, or a mixture of secondary solvents, which is not itself a suitable primary solvent for the present invention can be substituted. The principal solvent or mixture of principal solvents of the present invention. When at least about 15% softener active is also present, an effective amount of the primary solvent of the present invention is at least greater than about 5%, preferably greater than about 7%, more preferably greater than about 10%, by weight of the composition. Alternative solvents may be used in any amount, but are preferably about equal to, or less than, the amount of suitable primary solvent as defined above present in the fabric softener composition.

For example, while 1,2-pentanediol, 1,3-octanediol, and hydroxypivaloyl hydroxypivalate (hereinafter HPHP) have the formula:

HO-CH ₂ -C(CH ₃ ) ₂ -CH ₂ -O-CO-C(CH ₃ ) ₂ -CH ₂ -OH (CAS registry number: 1115-20-4) is an unsuitable solvent for the present invention, but Mixtures of these solvents with principal solvents, for example, with the preferred 1,2-hexanediol principal solvent, wherein the 1,2-hexanediol principal solvent is present in an effective amount, also provide liquid concentrated clear fabric softener compositions .

Some of the lesser solvents that may be used are those solvents listed in context as unsuitable solvents, as well as some of the parent non-alkoxylated solvents disclosed in Tables VIIIA-VIIIE.

The primary solvent can be used to prepare a translucent or transparent composition, or can be used to lower the temperature at which the composition is translucent or transparent. The present invention therefore also includes the method of adding a principal solvent to a composition which is not itself translucent or transparent, or which itself has too high a temperature at which instability occurs, in the amount indicated above, so that the composition translucent or transparent, or, when the composition is transparent, for example, at room temperature, or down to a specific temperature, the main solvent is added thereto in the amount indicated above to reduce the temperature at which the instability of the composition occurs , preferably at least about 5°C, more preferably at least about 10°C. The main advantage of the primary solvent is that it provides the greatest benefit for a given weight of solvent. It should be understood that "solvent" as used herein refers to the effect of the primary solvent at a given temperature, rather than its physical form, since some primary solvents are solid at room temperature. Alkyl Lactate

Certain alkyl lactates such as ethyl lactate and isopropyl lactate have ClogP values in the useful range of about 0.15 to about 0.64 and can form liquid concentrated clear fabric softener compositions with the fabric softener actives of the present invention, But they need to be used at slightly higher levels than more effective diol solvents such as 1,2-hexanediol. They can also be used to replace part of the other primary solvents of the present invention to form liquid concentrated clear fabric softener compositions. This is illustrated in Examples I-C.

new compound

Some of the above primary solvents are novel compounds, including: 2,3,3-trimethyl-1,2-butanediol; 2,3-dimethyl-3,4-pentanediol; 4-methyl Base-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl-3,4-hexanediol; 2,3-dimethyl-3,4-pentanediol Alcohol; 2-(1,1-dimethylpropyl)-1,3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(2,2-di Methylpropyl)-1,3-propanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-ethyl-2,3-dimethyl-1,3-butanediol Alcohol; 2-(2-methylpropyl)-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-isopropyl -1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1,4-butanediol; 2-methyl-2- Propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4-butanediol ; 2-Ethyl-3,3-dimethyl-1,4-butanediol; 2-(2-methylpropyl)-1,4-butanediol; 2,2,3-trimethyl -1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2,3,3 -Trimethyl-1,5-pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2 -Ethyl-3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol Diol; 3-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-4-methyl-1 , 5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol Alcohol; 2-isopropyl-1,4-pentanediol;; 2-propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 3-propyl-2 , 4-pentanediol; 2,3-dimethyl-1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3 -hexanediol; 3,5-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol Diol; 2,3-Dimethyl-1,4-hexanediol; 2,4-Dimethyl-1,4-hexanediol; 3,3-Dimethyl-1,4-hexanediol ;3,4-Dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,4-dimethyl-1,3-hexanediol;4 , 5-dimethyl-1,4-hexanediol; 2,2-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5 -Dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 2,3-dimethyl-1,6-hexanediol; 2,4-di Methyl-1,6-hexanediol; 3,3-dimethyl-1,6-hexanediol; 4,5-dimethyl-2,4-hexanediol; 2,3-dimethyl -2,5-hexanediol; 2,4-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,5-hexanediol; 3,3-dimethyl-2 , 6-hexanediol; 4-ethyl-1,3-hexanediol; 3-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 4-methyl -1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 3-methyl-1,5-heptanediol; 4- Methyl-1,5-heptanediol; 3-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 5-methyl-2,4-heptanediol; 3-Methyl-2,5-heptanediol; 2-methyl-3,5-heptanediol; 2,6-octanediol; 3,3,4-trimethyl-2,4-hexanediol Alcohol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2, 5-hexanediol; 3,3,5-trimethyl-2,5-hexanediol; triethoxylated 3-(butoxy)-1,2-propanediol; tetraethoxylated 3-(butoxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3-(2 -Methyl-1-butoxy)-1,2-propanediol; 3-(isoamyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy)-1,2 -Propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy)-1,3-propanediol ; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1-butoxy)-1, 3-propanediol; 2-(isoamyloxy)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-(cyclohexyloxy)-1 , 3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; pentaethoxylated 3-(butoxy)-1,2-propanediol; hexaethoxy Oxylated 3-(butoxy)-1,2-propanediol; Heptaethoxylated 3-(butoxy)-1,2-propanediol; Octaethoxylated 3-(butoxy)- 1,2-propanediol; nonaethoxylated 3-(butoxy)-1,2-propanediol; bis(2-hydroxybutyl) ether; and bis(2-hydroxycyclopentyl) ether.

Likewise, unsaturated analogues of these suitable primary solvents are novel, especially unsaturated _C7-12 diols, more preferably unsaturated _C8-10 diols, with the exception of the specific ones listed in Table IX above. mentioned unsaturated diols. These primary solvents all offer the non-obvious benefits described above. III. Optional Ingredients

(A) Low molecular weight water-soluble solvents may also be used at levels of 0% to about 12%, preferably about 1% to about 10%, more preferably about 2% to about 8%. The water soluble solvent does not provide a clear product at the same low levels as the main solvent described above, but the solvent can provide a clear product when the main solvent is insufficient to give a completely clear product. The presence of these water-soluble solvents is therefore highly desirable. These solvents include: ethanol; isopropanol; 1,2-propanediol; 1,3-propanediol; propylene carbonate, etc.; but does not include any main solvent (B). These water-soluble solvents have a greater affinity for water than the primary solvent in the presence of hydrophobic materials such as softener actives. (B) Whitening agent

The compositions herein may also optionally contain from about 0.005% to about 5% by weight of certain types of hydrophilic optical brighteners which also provide dye transfer inhibition. If used, the compositions of the present invention preferably contain from about 0.001% to 1% by weight of such optical brighteners.

The hydrophilic fluorescent whitening agent that can be used in the present invention has following formula structure:

Wherein R ₁ is selected from anilino, N-2-bis-hydroxyethyl and NH-2-hydroxyethyl; R ₂ is selected from N-2-bis-hydroxyethyl, N-2-hydroxyethyl-N- methylamino, morpholino, chloro and amino; and M is a salt-forming cation such as sodium or potassium.

When in the above formula, R ₁ is anilino, R ₂ is N-2-bis-hydroxyethyl and M is a cation such as sodium, the brightener is 4,4'-bis[(4-anilino-6 -(N-2-Bis-hydroxyethyl)-s-triazin-2-yl)amino]-2,2'-stilbene disulphonic acid and disodium salt. This particular brightener is commercially available from Ciba-Geigy under the tradename Tinopal-UNPA- ^GX® . Tinopal-UNPA-GX is the preferred hydrophilic optical brightener useful in the rinse-in compositions of the present invention.

When in the above formula, R ₁ is anilino, R ₂ is N-2-hydroxyethyl-N-2-methylamino and M is a cation such as sodium, the whitening agent is 4,4'-bis[(4 -anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazin-2-yl)amino]-2,2'-stilbene disulphonic acid disodium salt. This particular brightener is commercially available from Ciba-Geigy under the tradename Tinopal 5BM- ^GX® .

When in the above formula, _R1 is anilino, _R2 is morpholino and M is a cation such as sodium, the brightener is 4,4'-bis[(4-anilino-6-morpholino-s -Triazin-2-yl)amino]2,2'-stilbene disulfonic acid sodium salt. This particular brightener is commercially available from Ciba-Geigy under the tradename Tinopal AMS- ^GX® .

(C) Dispersion Auxiliary

(J) Optional viscosity/dispersibility modifiers

Relatively concentrated compositions containing saturated and unsaturated diesterquats can be prepared wherein they are already stable without the addition of concentration aids. However, the compositions of the present invention also require organic and/or inorganic concentration aids in order to obtain even higher concentrations and/or to meet higher stability standards depending on the other ingredients. These concentration aids, which may typically be viscosity modifiers, may be required, or preferably required, when particular softener active levels are used to ensure stability under extreme conditions. Surfactant concentration aids are generally selected from: (1) mono-long chain alkyl cationic surfactants; (2) nonionic surfactants; (3) amine oxides; (4) fatty acids; and (5) their mixture. These adjuvants are described in co-pending application serial number 08/461207 filed June 5, 1995 by Wahl et al., P&G Corporation, on page 14, line 12 to page 20, line 12, which The application is incorporated herein by reference.

When said dispersing aid is present, its total content is about 2% to about 25%, preferably about 3% to about 17%, more preferably about 4% to about 15%, even more preferably about 2% by weight of the composition. 5% to about 13%. These materials may be added as part of the active softener raw material (I) such as mono-long chain alkyl cationic surfactants and/or fatty acids as reactants for forming biodegradable fabric softener actives as discussed above, or as Individual components are added. The total level of dispersibility aid includes any amount that may be present as part of component (I).

(1) Monoalkyl cationic quaternary ammonium compound

When present, the monoalkyl cationic quaternary ammonium compound generally comprises from about 2% to about 25%, preferably from about 3% to about 17%, more preferably from about 4% to about 15%, and even more preferably from about 5% by weight of the composition. % to about 13%, the total monoalkyl cationic quaternary ammonium compound is present in at least an effective amount.

Such mono-alkyl cationic quaternary ammonium compounds useful in the present invention are preferably quaternary ammonium salts of the general formula:

[R ⁴ N ⁺ (R ⁵ ) ₃ ]X ^- where:

R ⁴ is C _8-22 alkyl or alkenyl, preferably C _10-18 alkyl or alkenyl; more preferably C _10-14 or C _16-18 alkyl or alkenyl;

^Each R is C _1-6 alkyl or substituted alkyl (for example, hydroxyalkyl), preferably C _1-3 alkyl, for example, methyl (most preferred), ethyl, propyl, etc., benzyl, Hydrogen, polyethoxylated chains having from about 2 to about 20 ethylene oxide units, preferably from about 2.5 to about 13 ethylene oxide units, more preferably from about 3 to about 10 ethylene oxide units, and mixtures thereof; and

X ^- as defined above (formula (I)).

Particularly preferred dispersing aids are monolauryltrimethylammonium chloride and monotallowtrimethylammonium chloride available from Witco under the tradename ^Varisoft_471 and available from Witco under the tradename ^Varisoft_417 . Monooleyl Trimethylammonium Chloride.

The ^R group can also be connected to the cationic nitrogen atom by containing one or more linking groups such as ester, amide, ether, amine, etc., which is beneficial for increasing the condensability of the component (I). Such linking groups are preferably separated from the nitrogen atom by about 1 to about 3 carbon atoms.

Monoalkyl cationic quaternary ammonium compounds also include C _8-22 alkyl choline esters. Preferred dispersing aids of this type have the formula:

R ¹ C(O)-O-CH ₂ CH ₂ N ⁺ (R) ₃ X ^-

wherein R ¹ , R and X ^- are as defined above.

Highly preferred dispersancy aids include C _12-14 coconut choline ester and C _16-18 tallow choline ester.

Suitable biodegradable mono long chain alkyl dispersancy aids containing ester linkages in the long chain are described in US Patent 4,840,738, Hardy and Walley, issued June 20, 1989, which is incorporated herein by reference.

When the dispersibility aid comprises an alkylcholine ester, it is preferred that the composition also contain a small amount, preferably from about 2% to about 5%, by weight of the composition, of an organic acid. Organic acids are described in European Patent EP404471, Machin et al., published December 27, 1990, which is incorporated herein by reference. Preferably the organic acid is selected from glycolic acid, acetic acid, citric acid, and mixtures thereof.

Ethoxylated quaternary ammonium compounds that can be used as dispersing aids include ethyl bis(polyethoxyethanol)alkylethylene oxide with 17 moles of ethylene oxide available under the tradename ^Variquat_66 from Sherex Chemical Company. Polyethylene glycol (15) oleoyl ammonium chloride available from Akzo under the trade name Ethoquad_0 ^/ 25; and Polyethylene glycol (15) available under the trade name ^Ethoquad_C /25 from Akzo ) cocoammonium chloride.

Although the primary function of the dispersibility aid is to increase the dispersibility of the ester softener, it is preferred that the dispersibility aid of the present invention also have some softening properties to enhance the softening performance of the composition. Accordingly, the compositions of the present invention are preferably substantially free of non-nitrogen ethoxylated nonionic dispersancy aids since such materials can reduce the overall softening properties of the composition.

Also, quaternary ammonium compounds having only a single long chain alkyl group can avoid cationic softener interactions with anionic surfactants and/or detergent builders carried over to the rinse cycle from the aqueous wash solution.

(2) Hydrogenated amine

Suitable amine oxides include those having from about 8 to about 22 carbon atoms, preferably from about 10 to about 18 carbon atoms, more preferably from about 8 to about 14 carbon atoms, an alkyl or hydroxyalkyl moiety, and two Amine oxides selected from the alkyl moieties of alkyl and hydroxyalkyl groups having from about 1 to about 3 carbon atoms.

Examples include dimethyloctylamine oxide, diethyldecylamine oxide, di-(2-hydroxyethyl)dodecylamine oxide, dimethyldodecylamine oxide, dipropyl Myristylamine Oxide, Methylethylhexadecylamine Oxide, Dimethyl-2-Hydroxystearylamine Oxide, and Coco Fatty Alkyldimethylamine Oxide.

(D) stabilizer

Stabilizers may be present in the compositions of the invention. The term "stabilizer" as used herein includes antioxidants and reducing agents. These agents are present at levels from about 0% to about 2%, preferably from about 0.01% to about 0.2%, more preferably from about 0.035% to about 0.1% for antioxidants, and more preferably from about 0.01% to about 0.2% for reducing agents. They guarantee excellent odor stability under long-term storage conditions. Antioxidant and reducing agent stabilizers are particularly critical for odorless or low odor products (no or low levels of fragrance).

Examples of antioxidants that may be added to the compositions of the present invention include mixtures of ascorbic acid, ascorbyl palmitate, propyl gallate, which are available from Eastman Chemical Company under the trade names ^Tenox_PG and ^Tenox_S -1; BHT ( butylated hydroxytoluene), BHA (butylated hydroxyanisole), propyl gallate, and a mixture of citric acid, which can be obtained from Eastman Chemical Company under the trade name Tenox ^- 6; butylated hydroxy Toluene, available under the tradename ^Sustane_BHT from UOP Process Division; tert-butylhydroquinone, available under the tradename ^Teno_TBHQ from Eastman Chemical Company; natural tocopherol, available under the tradename ^Tenox_GT -1/GT- 2 available from Eastman Chemical Company; and butylated hydroxyanisole, available under the tradename BHA from Eastman Chemical Company; long chain esters (C _8-22 ) of gallic acid, e.g., dodecane gallate Irganox_1010; Irganox_1035; Irganox_B1171; Irganox_1425; Irganox_3114; Irganox_3125; and mixtures thereof; preferably Irganox_3125, Irganox_1425, Irganox_3114, and mixtures thereof; A mixture of propyl esters, Dequest_2010, which is available from Monsanto under the chemical name 1-hydroxyethylidene-1,1-diphosphonic acid (hydroxydiphosphonic acid), and Tiron_, available under the chemical name 4,5-dihydroxy - m-Benzenesulfonic acid/sodium salt from Kodak, and DTPA_, available under the chemical name diethylenetriaminepentaacetic acid from Aldrich.

The chemical names and US Chemical Abstracts Registry Numbers of some of the above stabilizers which may be used in the compositions of the present invention are listed in Table I below.

(E) Stain remover

In the present invention, an optional soil release agent may be added. The detergent can be added in admixture with the premix, can be added in admixture with the acid/water, can be added before or after the addition of the electrolyte, or after the final composition is prepared. Softening compositions prepared by the process of the present invention may contain from 0% to about 10%, preferably from 0.2% to about 5%, of soil release agent. Preferably the soil release agent is a polymer. Polymeric soil release agents which may be used in the present invention include copolymeric blocks of terephthalate and polyethylene oxide or polypropylene oxide, and the like. A preferred soil release agent is a copolymer having blocks of terephthalate and polyethylene oxide. More specifically, these polymers consist of ethylene terephthalate and polyethylene oxide terephthalate units, where the ethylene terephthalate unit is combined with polyethylene oxide terephthalate The molar ratio of alkyl ester units is 25:75 to about 35:65, and the polyethylene oxide terephthalate contains polyethylene oxide blocks having a molecular weight of about 300 to about 2000. The polymeric soil release agent has a molecular weight in the range of about 5,000 to about 55,000.

Another preferred polymeric soil release agent is a crystallizable polyester having from about 10% to about 15% by weight of ethylene terephthalate repeat units and from about 10% to about 50% by weight Polyoxyethylene terephthalate repeating units derived from polyoxyethylene glycols having an average molecular weight of from about 300 to about 6000, the ethylene terephthalate units being combined with polyoxyethylene in the crystallizable polymer The molar ratio of the terephthalate units is from 2:1 to 6:1. Examples of such polymers include the commercially available materials Zelcon 4780 ^® (from DuPont) and MileaseT ^® (from ICI).

Highly preferred soil release agents are polymers having the general formula:

wherein each X may be a suitable capping group, wherein each X is generally selected from H, and an alkyl or acyl group containing from about 1 to about 4 carbon atoms. p is selected based on water solubility, and is generally about 6 to about 113, preferably about 20 to about 50. u is critical to the formulation of liquid compositions with higher ionic strength. There are few materials where u is greater than 10. Also, there should be at least 20%, preferably at least 40%, of materials having a u value of from about 3 to about 5.

The ^R14 moiety is essentially a 1,4-phenylene moiety. As used herein, the term "the R moiety is essentially a ^1,4 -phenylene moiety" means that the R moiety consists entirely of a ^1,4 -phenylene moiety, or is replaced by other arylene or alkylarylene groups. Moieties, alkenyl moieties, alkenylene moieties or mixtures thereof partially substituted compounds. Arylene and alkylarylene moieties that may partially substitute for 1,4-phenylene include 1,3-phenylene, 1,2-phenylene, 1,8-naphthylene, 1,4- Naphthylene, 2,2-biphenylene, 4,4-biphenylene, and mixtures thereof. Alkylene and alkenylene moieties which may be partially substituted include 1,2-propylene, 1,4-butylene, 1,5-pentylene, 1,6-hexylene, 1,7-propylene Heptyl, 1,8-octylene, 1,4-cyclohexylene, and mixtures thereof.

For the ^R14 moieties, the degree of partial substitution with groups other than 1,4-phenylene should be such that the soil release properties of the compound are not adversely affected to any extent. The degree of partial substitution that can be tolerated generally depends on the backbone length of the compound, ie, for 1,4-phenylene moieties, longer backbones can have greater partial substitution. Typically, compounds wherein ^R14 contains from about 50% to about 100% 1,4-phenylene moieties (0% to about 50% non-1,4-phenylene moieties) have sufficient soil release activity. For example, a polyester prepared in accordance with the present invention with a molar ratio of isophthalic acid (1,3-phenylene) to terephthalic acid (1,4-phenylene) of 40:60 has sufficient soil release activity . However, since most polyesters used to make fibers contain ethylene terephthalate units, it is generally desirable to reduce the degree of partial substitution with moieties other than 1,4-phenylene in order to obtain the best soil release activity. The ^R14 moieties preferably consist entirely of 1,4-phenylene moieties (ie, contain 100% phenylene), ie, each ^R14 moiety is 1,4-phenylene.

For the R ^moiety , suitable ethylene or substituted ethylene moieties include ethylene, 1,2-propylene, 1,2-butylene, 1,2-hexylene, 3-methoxy- 1,2-Propylene, and mixtures thereof. Preferably the ^R15 moiety is essentially an ethylene moiety, a 1,2-propylene moiety, or a mixture thereof. Inclusion of a greater percentage of ethylene moieties tends to improve the soil release activity of the compound. Unexpectedly, inclusion of a greater percentage of 1,2-propylene moieties tended to improve the water solubility of the compound.

Accordingly, it is desirable to incorporate 1,2-propylene moieties or similar branched equivalents thereof into any substantial portion of the soil release components of liquid fabric softener compositions. Preferably from about 75% to about 100% are 1,2-propylene moieties.

Each p-value is at least about 6, preferably at least about 10. A typical range for each value of n is about 12 to about 113. Each p-value generally ranges from about 12 to about 43.

A more complete description of detergents includes Decker, Konig, Straathof, and Gosselink US Patent No. 4,661,267 issued April 28, 1987; U.S. Patent US4749596 of Evans, Huntington, Stewart, Wolf and Zimmerer granted on April 7; U.S. Patent No. 4818569 of Trinh, Gosselink and Rattinger granted on April 4, 1989; Maldonado, Trinh and Gosselink granted on October 31, 1989 US Patent No. 4,877,896 issued September 11, 1990 to Gosselink et al.; and US Patent No. 4,976,879 issued December 11, 1990 to Maldonado, Trinh and Gosselink, all of which are incorporated herein by reference.

These soil removers can also be used as scum dispersants.

(F) Scum dispersant

In the present invention, the premix may be combined with an optional non-detergent scum dispersant and heated to a temperature at or above the melting point of the component.

Preferred scum dispersants of the present invention are formed by highly ethoxylated hydrophobic materials. The hydrophobic material can be a fatty alcohol, a fatty acid, a fatty amine, a fatty amide, an amine oxide, a quaternary ammonium compound, or the hydrophobic moiety used to form the soil release polymer. Preferred scum dispersants are highly ethoxylated, for example having an average of more than about 17, preferably more than about 25, more preferably more than about 40 moles of ethylene oxide per molecule, wherein the polyethylene oxide moiety is a percent of the total molecular weight From about 76% to about 97%, preferably from about 81% to about 94%.

The level of scum dispersant is sufficient to maintain scum at an acceptable, preferably consumer-invisible level under conditions of use, but not so high as to adversely affect softening performance. For some uses, it is desirable that no scum be present. Depending on the amount of anionic or nonionic detergent etc. used in the wash cycle of a typical laundry method, the effect of the rinse step prior to adding the composition of the present invention, and the hardness of the water, the anionic or nonionic residues in the fabric (clothes) The amount of detersive surfactants and detergency builders (especially phosphates and zeolites) will vary. Generally the lowest amount of scum dispersant is used to avoid adversely affecting softening performance. Scum dispersants generally require at least about 2%, preferably at least about 4%, based on softener active level (maximum scum avoidance value is at least 6%, preferably at least 10%). However, at levels of about 10% (relative to the softener substance) or higher, there is a risk of losing product softening benefits, especially when fabrics contain a high proportion of nonionic surfactants that have been adsorbed during the washing process This is the case with the dose.

Preferred scum dispersants are: Brij 700 ^_ ; Varonic U-250 ^_ ; Genapol T-500 ^_ ; Genapol T-800 ^_ ; Plurafac A- ^{79 _} ;

(G) Bactericide

Examples of fungicides useful in the compositions of the present invention include glutaraldehyde, formaldehyde, 2-bromo-2-nitro-propane-1,3-diol sold under the trade name ^Bronopol® by Inolex Chemicals located in Philadelphia, Pennsylvania , and about a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one sold under the tradename Kathon by Rohm and Hass 1 to about 1000 ppm (by weight) of reagent.

(H) Spices

The present invention may contain any perfume compatible with the softener. Suitable fragrances are disclosed in US Patent No. 5,500,138, Bacon et al., issued March 19, 1996, which is incorporated herein by reference.

Perfume as used herein includes aromatic substances or mixtures thereof, including natural fragrance substances (i.e., substances obtained by extraction from flowers, grasses, leaves, roots, barks, woods, flowers or plants), artificial fragrance substances (i.e. , various natural oils or mixtures of oil components) and synthetic fragrance substances (that is, synthetically obtained). These substances are usually accompanied by auxiliary materials such as fixatives, extenders, stabilizers and solvents. These auxiliary materials are also included in the scope of "perfume" used in the present invention. Fragrances are generally complex mixtures of many organic compounds.

Examples of fragrance ingredients useful in fragrances in the compositions of the present invention include, but are not limited to, hexyl cinnamaldehyde; amyl cinnamaldehyde; amyl salicylate, hexyl salicylate; terpineol; Methyl-cis-2,6-octadien-1-ol; 2,6-dimethyl-2-octanol; 2,6-dimethyl-7-octen-2-ol; 3, 7-Dimethyl-3-octanol; 3,7-Dimethyl-trans-2,6-octadien-1-ol; 3,7-Dimethyl-6-octen-1-ol; 3,7-Dimethyl-1-octanol; 2-methyl-3-(p-tert-butylphenyl)-propanal; 4-(4-hydroxy-4-methylpentyl)-3- Cyclohexene-1-carbaldehyde; Tricyclodecenyl propionate; Tricyclodecenyl acetate; Anisaldehyde; 2-Methyl-2-(p-isopropylphenyl)-propionaldehyde; 1-(2,6,6-trimethyl-2-cyclohexen-1-yl )-2-buten-1-one; p-methoxyacetophenone; p-methoxy-α-phenylpropene; 2-n-hexyl-3-oxo-cyclopentanecarboxylic acid methyl ester; Carbolides.

Other examples of aroma substances include, but are not limited to, orange oil, lemon oil, grapefruit oil, bergamot oil, clove oil; gamma-laudecanolide; 2-(2-pentyl-3-oxo -cyclopentyl) methyl acetate; β-naphthol methyl ether; methyl-β-naphthyl ketone; coumarin; decanal; benzaldehyde; 4-tert-butyl-cyclohexyl acetate; -Dimethylphenethyl ester; methylphenylmethyl acetate; Schiff of 4-(4-hydroxy-4-methylphenyl)-3-cyclohexene-1-carbaldehyde and methyl anthranilate Base; cyclic tridecanedioic acid ethylene glycol diester; 3,7-dimethyl-2,6-octadiene-1-carbonitrile; γ-methyl-ionone; α-ionone ; β-ionone; Orange leaf oil; Methyl cedryl ketone; 7-Acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetra Methylnaphthalene; Methylionone; Methyl-1,6,10-trimethyl-2,5,9-cyclododecatrien-1-ylketone; 7-Acetyl-1,1, 3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene; 4-acetyl-6-tert-butyl-1,1-dimethylindene; benzophenone; 6- Acetyl-1,1,2,3,3,5-hexamethylindene; 5-acetyl-3-isopropyl-1,1,2,6-tetramethylindene; 1-dodecanal ; 7-hydroxy-3,7-dimethyloctanal; 10-undecene-1-al; isohexenylcyclohexylcarbaldehyde; formyltricyclodecane; cyclopentadecanolide; 16-Hydroxy-9-hexadecenolactone; 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopentadieno- γ-2-benzopyran; ambroxane; dodecahydro-3a,6,6,9a-tetramethylnaphtho-[2,1b]furan; cedrol; 5-(2,2,3-tetramethyl Cyclopent-3-enyl)-3-methylpent-2-ol; 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2 -Butene-1-ol; Caryophyllenol; Cedaryl acetate; p-tert-Butylcyclohexyl acetate; Patchouli; Frankincense; Cistus; Vetiver; Cuban butter; Canada butter; and condensation products of: Methylal and anthranilic acid methyl ester; hydroxycitronellal and indole; phenylacetaldehyde and indole; 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carbaldehyde and ammonia methyl anisate.

Further examples of perfume ingredients are geraniol; geraniyl acetate; linalool; linalyl acetate; tetrahydrolinalool; citronellol; citronellol acetate; dihydromyrcenol; Dihydromyrcenyl acetate; Tetrahydromyrcenyl alcohol; Terpinyl acetate; Nopol; Nopol acetate; 2-Phenylethanol; 2-Phenylethyl acetate; Benzyl alcohol; Benzyl acetate Esters; benzyl salicylate; benzyl benzoate; styrallyl acetate; dimethylbenzyl carbinol; trichloromethylphenylmethyl methylphenylmethylacetate; Lanyl ester; Velanol; 2-methyl-3-(p-tert-butylphenyl)-propionaldehyde; 2-methyl-3-(p-isopropylphenyl)-propionaldehyde; 3-(p- tert-butylphenyl)-propionaldehyde; 4-(4-methyl-3-pentenyl)-3-cyclohexenecarbaldehyde; 4-acetoxy-3-pentyltetrahydropyran; dihydrojasmine Methyl ketoate; 2-n-heptylcyclopentanone; 3-methyl-2-pentyl-cyclopentanone; n-decyl aldehyde; n-dodecanal; 9-decen-1-ol; isobutyric acid Phenoxyethyl ester; phenylacetaldehyde dimethyl acetal; phenylacetaldehyde diethyl acetal; geranyl nitrile; citronella nitrile; cedar wood acetal; luteolone; anisaldehyde nitrile; anisaldehyde; heliotrope; eugenol; vanillin; diphenyl ether; citronellal ionone; methyl ionone; isomethyl ionone; methyl fennel Ketones; cis-3-hexenol and its esters; 1,2-indane musk fragrance; 1,2,3,4-tetrahydroindane musk fragrance; isochroman musk fragrance; macroketones ; Macrolide Musk Fragrance; Ethylene Glycol Brasilate.

Perfumes useful in the compositions of the present invention are substantially free of halogenated materials and nitromusks.

Suitable solvents, diluents or carriers for the above fragrance ingredients are, for example, ethanol, isopropanol, diethylene glycol, monoethyl ether, dipropylene glycol ether, diethyl phthalate; triethyl citrate; base esters etc. The amount of these solvents, diluents or carriers incorporated into the perfume is preferably kept to the minimum necessary to provide a homogeneous perfume solution.

Perfume may be present at a level of from 0% to about 10%, preferably from about 0.1% to about 5%, more preferably from about 0.2% to about 3%, by weight of the finished composition. The fabric softener compositions of the present invention provide improved fabric perfume deposition.

(I) Chelating agent

The compositions and methods of the present invention may optionally employ one or more copper and/or nickel chelating agents ("chelating agents"). Such water-soluble chelating agents may be selected from amino carboxylates, amino phosphonates, polyfunctionally substituted aromatic chelating agents and mixtures thereof, all of which are defined hereinafter. The whiteness and/or brightness of the fabric is substantially improved or restored by the chelating agent, and the stability of the materials in the composition is improved.

Amino carboxylates used as chelating agents in the present invention include ethylenediaminetetraacetate (EDTA), N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate (NTA ), ethylenediamine tetrapropionate, ethylenediamine-N,N'-diglutamate, 2-hydroxypropylenediamine-N,N'-disuccinate, triethylenediamine diethylenetriaminepentaacetate (DETPA), and diglycine, including their water-soluble salts such as alkali metal, ammonium, and substituted ammonium salts, and mixtures thereof.

Amino phosphonates are also suitable for use as chelating agents in the compositions of the invention when at least low levels of total phosphorus are tolerated in detergent compositions, and they include ethylene diamine tetrakis (methylene phosphonates) , diethylenetriamine-N,N,N',N",N"-penta(methylphosphonate) (DETMP) and 1-hydroxyethyl-1,1-diphosphonate (HEDP) . Preferably, these amino phosphonates do not contain alkyl or alkenyl groups having more than about 6 carbon atoms.

Chelating agents are typically used in the rinse process of the present invention at levels of from about 2 ppm to about 25 ppm, and over a 1 minute to several hour soak.

A preferred EDDS chelating agent (also known as ethylenediamine-N,N'-disuccinate) for use in the present invention is the material described in U.S. Patent No. 4,704,233 cited above, which has the following formula (with Expressed in free acid form):

As disclosed in this patent, EDDS can be prepared using maleic anhydride and ethylenediamine. The preferred biodegradable [S,S] isomer of EDDS can be prepared by reacting L-aspartic acid with 1,2-dibromoethane. The advantage of EDDS over other chelating agents is that it efficiently chelates both copper and nickel cations and is available in biodegradable form without phosphorus. EDDS used as a chelating agent in the present invention is usually in the form of its salt, that is, one or more of the four acidic hydrogen atoms are replaced by water-soluble cations M, such as sodium, potassium, ammonium, triethanolammonium, etc. . As noted previously, EDDS chelating agents are also typically used in the rinse process of the present invention at levels of from about 2 ppm to about 25 ppm, and over a 1 minute to several hour soak. EDDS is preferably used in combination with zinc cations at a certain pH.

A variety of chelating agents can be used in the present invention. Indeed, simple polycarboxylates such as citrates, oxydisuccinates, etc. can also be used herein, although these chelating agents are not as effective on a weight basis as aminocarboxylates and phosphonates. Therefore, the amount of chelating agent used can be adjusted to account for varying degrees of chelating effectiveness. The chelating agents of the present invention preferably have a stability constant for copper ions of at least about 5, preferably at least about 7 (fully ionizing chelating agents). Chelating agents, in addition to those materials which are stabilizers, typically comprise from about 0.5% to about 10%, more preferably from about 0.75% to about 5%, by weight of the compositions herein. Preferred chelating agents include DETMP, DETPA, NTA, EDDS and mixtures thereof.

(J) Other optional ingredients

The present invention may include optional components commonly used in fabric treatment compositions such as: colorants; preservatives; surfactants; antishrinkage agents; fabric wrinkling agents; spotting agents; Oxidizing agents such as butylated hydroxytoluene, corrosion inhibitors, etc.

Particularly preferred ingredients include water-soluble calcium and/or magnesium compounds which provide additional stability. Chloride salts are preferred, but acetates, nitrates, etc. may be used. The content of said calcium and/or magnesium salt is 0% to about 2%, preferably about 0.05% to about 0.5%, more preferably about 0.1% to about 0.25%.

Compositions of the present invention may also include other compatible ingredients, including those disclosed in pending application Ser. No. 08/372068, Rusche et al., filed January 12, 1995; Shaw et al., filed January 12, 1995; Ser. No. 08/372,490; and components of Hartman et al., Ser. No. 08/277,558, filed July 19, 1994; incorporated herein by reference.

Preparation of the main solvent

                                

A number of synthetic methods can be used to prepare the diol primary solvents of this invention. Select the appropriate method according to the specific structural needs of each major solvent. And most primary solvents can also be prepared by more than one method. Therefore, the method cited in the present invention for each specific primary solvent is for illustrative purposes only and should not be considered as a limitation. Method A Preparation of 1,5-, 1,6- and 1,7-diols 1

This synthesis is a general method for the preparation of α,ω-type diols derived from substituted cycloalkenes. Examples of cycloalkenes are cyclopentene, cyclohexene and the alkylated isomers of cycloheptene. The general formula for a useful alkylated cycloalkene is

wherein each R is H, or C _1-4 alkyl, and wherein x is 3, 4 or 5.

Cycloalkenes can be converted into final diols through a three-step reaction.

Step 1 is the reaction of cyclic olefins with ozone (O ₃ ) in a solvent such as anhydrous ethyl acetate to form an ozonide intermediate. The ozonide is reduced in step 2, e.g., by palladium catalyst/ _H to the dialdehyde, and this product is then converted to the target diol by borohydride reduction in step 3.

1,2-diols are usually prepared by direct hydroxylation of appropriately substituted alkenes. For example:

wherein each R is H, alkyl, etc.

In a typical reaction, an olefin is reacted with hydrogen peroxide (30%) and a catalytic amount of osmium tetroxide in tert-butanol or other suitable solvent. The reaction was cooled to about 0°C and left overnight. Unreacted compounds and solvents are removed by distillation, and the desired 1,2-diol is isolated by distillation or crystallization. Method 2 Another method is the conversion of olefins to epoxides by m-chloroperbenzoic acid, or peracetic acid in a solvent such as dichloromethane at temperatures as low as about 25°C. The epoxides obtained according to this chemistry are then ring-opened by, for example, hydrolysis with dilute sulfuric acid to give diols.

Step 3 is to obtain the target diol by borohydride reduction. Method 3

Another method of preparing these compounds is by the direct hydroxylation of cycloalkenes with hydrogen peroxide and a catalytic amount of osmium tetroxide. The reaction yields cyclic diols, which are then converted to open-chain dialdehydes by periodate or lead tetraacetate. The dialdehyde is then reduced with borohydride as in Method 1 to give the desired 1,5- or 1,6-diol, etc. Method B Preparation of 1,2-diol Method 1 Method C 1,3-diol Preparation of Enamine Acylation

This preparation is suitable for all types of 1,3-diols and accommodates various structural features. Enamines are formed from ketones and aldehydes, which react with acid chlorides to form acylated products. The acylated amine derivative is hydrolyzed to its acylated carbonyl compound, which is the 1,3-dicarbonyl precursor of the desired 1,3-diol. Diols are obtained by borohydride reduction of 1,3-dicarbonyl compounds.

Thus, acetaldehyde (aldehydes) can be reacted with secondary amines, preferably cyclic amines such as pyrrolidine or morpholine, by refluxing in a solvent such as toluene and using a catalytic amount of p-toluenesulfonic acid. When the amine reacts (condenses) with the carbonyl compound, water is produced and is removed, for example, by refluxing using a water trap. After removal of the theoretical amount of water, the reaction mixture is freed of solvent under vacuum, if desired (acylation can be carried out in the same solvent system in most cases).

Acylated enamines are obtained by reacting anhydrous crude enamines containing some excess of amine with appropriate acid chlorides at about 20°C. The reaction usually requires stirring overnight at room temperature. The total reaction mixture was then poured into crushed ice, stirred, and the mixture was made acidic with 20% hydrochloric acid. This treatment hydrolyzes the enamine to the acylated dicarbonyl compound. This intermediate is then isolated by extraction and distillation to remove low boiling impurities, followed by reduction with sodium borohydride to the desired 1,3-diol. Method D Preparation of 1,4-Diols by Aldol Condensation and Reduction

Typical reactions involve one or more aldehydes, one or more ketones, and mixtures thereof, which have at least one alpha-hydrogen atom on a carbon atom adjacent to the carbonyl group. Typical examples of some reactants and some possible end products are as follows:

2R-CH ₂ -CHO→HO-CH ₂ -CH(R)-CHOH-CH ₂ -RR-CH ₂ -CHO+R′-CH ₂ -CHO→HO-CH ₂ -CH(R)-CHOH-CH ₂ -R+

HO-CH ₂ -CH(R′)-CHOH-CH ₂ -R′+

HO-CH ₂ -CH(R′)-CHOH-CH ₂ -R+

HO-CH ₂ -CH(R)-CHOH-CH ₂ -R′R-CH ₂ -CHO+R′-CO-CH ₃ →HO-CH ₂ -CH(R)-CHOH-CH ₂ -R+

R-CH ₂ -CHOHCH ₂ -CHOH-R'

The aldehyde, ketone or mixture thereof to be condensed is placed in an autoclave under an inert atmosphere with a solvent such as butanol or with a phase transfer medium such as polyethylene glycol. When the purpose of the reaction is a mixed condensation such as the condensation of a ketone and an aldehyde, the two reactants are generally used in a molar ratio of about 1:1. A catalytic amount of a strong base catalyst, such as sodium methoxide, is typically added at about 0.5-10 mole percent of the reactants. The autoclave is sealed and the mixture is heated at about 35-100° C. until most of the starting reactants have been converted, which usually takes about 5 minutes to about 3 hours. The crude mixture was neutralized and the carbonyl functions present were reduced by hydrogenation with Raney nickel at about 100°C and about 50 atmospheres for about 1 hour. The volatile components were removed by distillation, and the desired diol main solvent was obtained by vacuum distillation.

More information about this preparation method is disclosed in "Synthesis", (3), 164-5 (1975), A. Pochini and R. Ungaro; PCT International Application WO9507254, Kulmala et al., March 16, 1995; Japanese Patent Application 40333, Sato et al., Feb. 9, 1990; Japanese patent application 299240, Sato et al., Dec. 4, 1989; European patent application EP367743, Ankner et al., May 9, 1990; all articles and patents cited above are incorporated This article is for reference. Illustrative example: Condensation of butyraldehyde and/or isobutyraldehyde and conversion to octa-1,3-diol

A portion of n-butanol (about 148 g, about 2 moles, Aldrich) in a 500 ml three-necked round-bottomed flask equipped with a stir bar, built-in thermometer, condenser, and nitrogen-protected connection was treated with metallic sodium (about 2.3 g, about 0.1 mol, Aldrich) was treated until all the sodium was dissolved. A mixture of butyraldehyde (about 72 grams, about 1 mole, Aldrich) and isobutyraldehyde (about 72 grams, about 1 mole, Aldrich) was then added and the system maintained at about 40°C until most of the starting aldehyde had reacted. Sulfuric acid is carefully added to neutralize the base catalyst, any salts are removed by filtration, and the solution is hydrogenated with Raney nickel at about 100°C and about 50 atmospheres for about 1 hour to give an octacarbon-1,3-diol mixture. Distillation of the butanol solvent and any isobutanol formed in the hydrogenation yields the following mixture of octa-1,3-diols: 2,2,4-trimethyl-1,3-pentanediol; 2-ethane 2,2-dimethyl-1,3-hexanediol; and 2-ethyl-4-methyl-1,3-pentanediol. The mixture is optionally further purified by vacuum distillation, or by decolorization with activated charcoal. The recovered solvent is used for the preparation of the next batch of diol.

When only butyraldehyde is used in the reaction, the major product obtained is 2-ethyl-1,3-hexanediol.

When only isobutyraldehyde is used in the reaction, the major product obtained is 2,2,4-trimethyl-1,3-pentanediol.

Mixed Condensation of Butyraldehyde and Methyl Ethyl Ketone and Conversion Condition A to Form Eight-Carbon-1,3-Diol Mixtures

A portion of n-butanol (about 148 g, about 2 moles, Aldrich) in a 500 ml three-necked round-bottomed flask equipped with a stir bar, built-in thermometer, condenser, and nitrogen-protected connection was treated with metallic sodium (about 2.3 g, about 0.1 mol, Aldrich) was treated until all the sodium was dissolved. A mixture of butyraldehyde (about 72 grams, about 1 mole, Aldrich) and 2-butanone (about 72 grams, about 1 mole, Aldrich) was then added and the system maintained at about 40°C until most of the starting butyraldehyde had reacted. Sulfuric acid is carefully added to neutralize the base catalyst and any salts are removed by filtration. Unreacted starting material and reaction solvent are optionally removed by distillation. The mixture containing the condensation product is hydrogenated with Raney nickel at about 100°C and about 50 atmospheres for about 1 hour to obtain a mixture of eight carbon-1,3-diols, which include: 2-ethyl-1,3-hexanediol; 2 - Ethyl-3-methyl-1,3-pentanediol; 3,5-octanediol; 3-methyl-3,5-heptanediol; and very small amounts of other 1,3-diols Isomers, for example, 3-methyl-2,4-heptanediol and 3,4-dimethyl-2,4-hexanediol. The crude diol mixture can be further purified by fractional distillation. Condition B

The above reaction was repeated except that about 2 moles of butyraldehyde were used to correspond to 1 mole of 2-butanone. This results in a higher proportion of the diol reaction product resulting from the condensation of the aldehyde itself (i.e., 2-ethyl-1,3-hexanediol), and the diol reaction product resulting from the mixed condensation of the aldehyde and 2-butanone products (e.g., 2-ethyl-3-methyl-1,3-pentanediol and 3,5-octanediol), and to a lesser extent diols produced by self-condensation of 2-butanone (e.g., 3- methyl-3,5-heptanediol and 3,4-dimethyl-2,4-hexanediol). Condition C

The above condensation was repeated except that about 1 mole of 2-butanone was placed in the reaction vessel with solvent and catalyst and about 1 mole of butyraldehyde was gradually added. The reaction conditions are adjusted so that the rate of self-condensation of 2-butanone is slow and the more reactive aldehyde carbonyl reacts rapidly upon addition. This results in a higher proportion of diols resulting from the condensation of 2-butanone and butyraldehyde and diols resulting from the self-condensation of 2-butanone and a small proportion of diols resulting from the self-condensation of butyraldehyde in the reaction product. Condition D.

Repeat Condensation C above at low temperature. About 1.0 mole of 2-butanone was dissolved in about 5 volumes of anhydrous tetrahydrofuran. The solution was cooled to about -78°C, and about 0.95 moles of potassium hydride was added in portions. After hydrogen evolution had ceased, the solution was allowed to equilibrate for about 1 hour to obtain the more stable enolate, then 1 mole of n-butyraldehyde was added slowly with excellent stirring and maintaining the temperature at about -78°C. After the addition was complete, the solution was gradually warmed to room temperature, and sulfuric acid was carefully added for neutralization. Filter to remove salt. Unreacted starting material and reaction solvent are optionally removed by distillation. The mixture containing the condensation products is hydrogenated with Raney nickel at about 100°C and about 50 atmospheres for about 1 hour to give primarily the diol, 3,5-octanediol, which is produced by condensation of the enolate of 2-butanone with butyraldehyde. Purification is optionally performed by distillation.

Mixed condensation of isobutyraldehyde and methyl ethyl ketone and transformation to form eight-carbon-1,3-diol mixtures

The reaction of Condition A above was repeated except that isobutyraldehyde was used instead of butyraldehyde. Condensation and reduction are carried out similarly, and the final diol product is mainly 2,2,4-trimethyl-1,3-pentanediol; 2,2,3-trimethyl-1,3-pentanediol; 2-methyl-3,5-heptanediol; and 3-methyl-3,5-heptanediol.

Mixed condensation of butyraldehyde, isobutyraldehyde and methyl ethyl ketone and transformation to form octacarbon-1,3-diol mixtures

The reaction of Condition A above was repeated except that about 1 mole of each of butyraldehyde, isobutyraldehyde, and 2-butanone was used. Condensation and reduction were carried out similarly to give an octa-1,3-diol mixture mainly consisting of: 2,2,4-trimethyl-1,3-pentanediol; 2-ethyl-1 , 3-hexanediol; 2,2-dimethyl-1,3-hexanediol; 2-ethyl-4-methyl-1,3-pentanediol; 2-ethyl-3-methyl -1,3-pentanediol; 3,5-octanediol; 2,2,3-trimethyl-1,3-pentanediol; 2-methyl-3,5-heptanediol; and 3 -Methyl-3,5-heptanediol, and other minor isomers obtained from condensation of the methylene group of 2-butanone instead of its methyl group.

The mixture prepared by condensation of butyraldehyde, isobutyraldehyde, and/or methyl ethyl ketone preferably has no more than about 90%, preferably no more than about 80%, more preferably no more than about 70%, even more preferably no more than about 60%, and most preferably Preferably no more than about 50% by weight of any one particular compound is present. Likewise, the reaction mixture should contain no more than about 95%, preferably no more than about 90%, more preferably no more than about 85%, and most preferably no more than about 80% by weight of butyraldehyde or isobutyraldehyde. Method E Preparation of 1,4-diols by addition of acetylides to carbonyl compounds

Reaction of dimetallic acetylides Na ^+-: C≡C ^: -Na ⁺ with aldehydes or ketones to form unsaturated alcohols, e.g.,

The resulting acetylenic diols are then reduced to alkenes or completely reduced to saturated diols. The reaction can also be carried out using about 18% slurry of monosodium acetylide with the carbonyl compound to form the acetylenic alcohol, which can be converted to the sodium salt and reacted with another mole of the carbonyl compound to give the unsaturated 1,4-di alcohol. When mixed carbonyls are used to react with dieacetylides, diol mixtures are obtained. Compounds of specific structures can be obtained in higher yields when monoacetylides are used. Illustrative Example: Preparation of 6-Methyl-2,5-Heptanediol

Reaction of sodium acetylide (about 18,% in xylene) slurry with isobutyraldehyde to form acetylenic alcohol:

The acetylenic (acetylene) alcohol is converted to sodium acetylide R-CHOH-C≡CNa with base, which is then reacted with 1 mole of acetaldehyde to give the acetylenyl diol R-CHOH-C≡C-CHOHR'. This compound, (CH ₃ ) ₂ CH-CHOH-C≡C-CHOH-CH ₃ , can be isolated as an unsaturated diol and, if desired, reduced by catalytic hydrogenation to the corresponding material containing a double bond at the acetylenic position, or Further reduction by catalytic hydrogenation affords the saturated 1,4-diol. Method F Derivatization of Saturated Diols from Cyclic Anhydrides, Lactones and Dicarboxylates

This preparation is the synthesis of diols, especially certain 1,4-diols, derived from dicarboxylic anhydrides, diesters and lactones, but not limited to 1,4-diols or tetracarbonic diacids .

These types of diols are usually synthesized by reducing the parent anhydride, lactone or diester with bis(2-methoxyethoxy)sodium aluminum hydride (Red-Al) as a reducing agent. The reducing agent is commercially available as a 3.1 molar solution in toluene, providing 1 mole of hydrogen per mole of reagent. About 3 moles of Red-Al are required per mole of substrate. The method is illustrated below with alkyl-substituted succinic anhydrides, and the general reduction proceeds as follows:

The acid anhydride was first dissolved in anhydrous toluene and placed in a reaction vessel equipped with a dropping funnel, a mechanical stirrer, a thermometer and a reflux condenser connected to calcium chloride and soda lime tubes for removal of water and carbon dioxide. The reducing agent in toluene was placed in the dropping funnel and slowly added to the stirring anhydride solution. The reaction was exothermic, allowing the temperature to reach about 80°C. The temperature was maintained at about 80°C during the addition and continued for 2 hours after the addition was complete.

The reaction mixture was then cooled to room temperature. The mixture was then added to a stirred HCl solution (about 20% strength) cooled in an ice bath, maintaining the temperature at about 20-30°C. After acidification, the mixture was separated in a separatory funnel and the organic layer was washed with dilute saline solution until pH paper was neutral. The neutral diol solution was dried over anhydrous magnesium sulfate, filtered, and stripped under vacuum to give the desired 1,4-diol. Method G Preparation of Diols Having One or Both Secondary or Tertiary Alcohol Functions

This method is a general procedure for the preparation of substituted diols from lactones and/or diesters by carbonyl alkylation using methylmagnesium bromide (Grignard reagent) or alkyllithium compounds, usually methyllithium compounds, for example:

This type of alkylation can be extended to diesters. An excess of methylating reagent will produce a diol in which both alcohol groups are tertiary. Method H Preparation of substituted 1,3-, 1,4- and 1,5-diols

其中，每个R是H或C_1-4烷基，和其中X是1，2或3。This method is a general method for the preparation of certain 1,3-, 1,4- and 1,5-diols utilizing the chemistry outlined in Method A-1 and Method A-2. The change here is to use a cyclic diene instead of the cycloalkene described in Method A. The general formula of the raw material is:

wherein each R is H or C _1-4 alkyl, and wherein X is 1, 2 or 3.

This reaction is that of method A, with the change corresponding to each mole of the required diol principal solvent formed, yielding 1 mole of ethylene glycol, for example, the following from 1-ethyl-5,5-dimethyl -1,3-Cyclohexanediol (CAS registry number: 79419-18-4) to prepare 2,2-dimethyl-1,4-hexanediol:

Preparation of polyethoxylated derivatives

Polyethoxylated derivatives of diol principal solvents are usually prepared in high pressure reactors under nitrogen atmosphere. An appropriate amount of ethylene oxide is added to the mixture of diol solvent and potassium hydroxide at elevated temperature (about 80°C to about 170°C). The amount of ethylene oxide is calculated relative to the amount of diol solvent in order to add the correct number of ethylene oxide groups per mole of diol. When the reaction is complete, eg, after about 1 hour, residual unreacted ethylene oxide is removed under vacuum. Illustrative Example: Preparation of tetraethoxylated 3,3-dimethyl-1,2-butanediol

Into a 2 liter Parr reactor equipped with a temperature controller were charged about 354 grams (about 3.0 moles) of 3,3-dimethyl-1,2-butanediol and about 0.54 grams of potassium hydroxide. The reactor was sparged with nitrogen and evacuated three times to a pressure of about 30 mmHg. The reactor was then refilled to atmospheric pressure with nitrogen and heated to about 130°C. The reactor pressure was then adjusted to slightly below atmospheric pressure by applying a slight vacuum. Ethylene oxide (about 528 grams, about 12.0 moles) was added over 1 hour while controlling the temperature at about 130°C. After about 1 additional hour of reaction, the reaction was cooled to about 90°C and any residual ethylene oxide was removed under vacuum.

Preparation of methyl-terminated polyethoxylated derivatives

Methyl-terminated polyethoxylated derivatives of diols are generally prepared by adding methoxypoly(ethoxy)ethyl chloride (i.e., CH ₃ O-(CH ₂ CH ₂ O) _n -CH ₂ -CH ₂ -Cl) with the diol of choice, or by adding methyl-terminated polyethylene glycol of the desired chain length (i.e., CH ₃ O-(CH ₂ CH ₂ O) _n -CH ₂ -CH ₂ -OH) with epoxidized precursors of diols, or a combination of these methods. Illustrative example: (CH ₃ ) ₂ C(OH)CH(CH ₃ )(OCH ₂ CH ₂ ) ₄ -OCH ₃ , methyl-terminated tetraethoxylate of 2-methyl-2,3-butanediol Synthesis of ylated derivatives.

To a 1-liter three-neck round bottom flask equipped with a magnetic stir bar, condenser, thermometer and temperature controller (Thermowatch ^I R) was added tetraethylene glycol methyl ether (about 208 g, about 1.0 mol) and sodium metal ( about 2.3 g, about 0.1 mole, Aldrich), and the mixture was heated to about 100°C under argon. After the sodium had dissolved, 2-methyl-2,3-epoxybutane (about 86 g, about 1.0 mole) was added and the solution was stirred overnight at about 120°C under argon. ¹³ C-NMR (dmso-d ₆ ) showed that the epoxide peak disappeared, indicating that the reaction was complete. The reaction mixture was cooled, poured into an equal volume of water, neutralized with 6N hydrochloric acid, saturated with sodium chloride, and extracted twice with dichloromethane. The combined dichloromethane layers were dried over sodium sulfate and the solvent was stripped to give the desired polyether alcohol in crude form. Purification can optionally be performed by vacuum fractional distillation. Synthesis of Methoxytriethoxyethyl Chloride

To a 1 L three necked round bottom flask equipped with a magnetic stir bar, condenser and temperature controller (Thermowatch, ^I2R ) was added tetraethylene glycol methyl ether (ca. 208 g, ca. 1.0 mol) under argon. Thionyl chloride (ca. 256.0 g, ca. 2.15 moles) was added dropwise with excellent stirring over about 3 hours while maintaining the temperature at 50-60°C. The reaction mixture was then heated at about 55°C overnight. ¹³ C-NMR (D ₂ O) spectrum showed only a small peak at ~60ppm corresponding to unreacted alcohol, and an obvious peak at ~43.5ppm corresponding to the chlorinated product ( _-CH2Cl ). Slowly add saturated sodium chloride solution to the material until the thionyl chloride is destroyed. The material was dissolved in about 300 ml of saturated sodium chloride solution and extracted with about 500 ml of dichloromethane. The organic layer was dried, and the solvent was stripped on a rotary evaporator to obtain crude methoxyethoxyethyl chloride. Purification can optionally be performed by vacuum fractional distillation. C ₂ H ₅ CH(OH)CH(CH ₃ )CH ₂ (OCH ₂ CH ₂ ) ₄ -OCH ₃ , the methyl-terminated tetraethoxylated derivative of 2-methyl-1,3-pentanediol Synthesis.

To a 1 L three necked round bottom flask equipped with a magnetic stir bar, condenser and _temperature controller ( ^{Thermowatch_I2R} ) was charged the alcohol, _C2H5CH (OH)CH( _CH3 ) _CH2OH (about 116 g , about 1.0 mol) and about 100 ml of tetrahydrofuran as a solvent. Sodium hydride (about 32 g, about 1.24 mol) was added portionwise to the solution, and the system was kept under reflux until no gas evolved. Methoxytriethoxyethyl chloride (about 242 grams, about 1.2 moles, prepared as above) was added and the system maintained at reflux for about 48 hours. The reaction mixture was cooled to room temperature and water was carefully added dropwise with stirring to decompose excess hydride. The tetrahydrofuran was stripped off on a rotary evaporator. The crude product was dissolved in about 400 mL of water, and enough sodium chloride was dissolved in the water to bring it close to the saturation level. The mixture was then extracted twice with about 300 ml of dichloromethane. The combined dichloromethane layers were dried over sodium sulfate and stripped of solvent on a rotary evaporator to yield the crude product. Purification may optionally be carried out by further stripping off unreacted starting material and low molecular weight by-products under vacuum using a kugelrohr apparatus at about 150°C. Further purification can optionally be carried out by vacuum distillation to give the title polyether.

   Preparation of Polypropoxylated Derivatives

A three-neck round bottom flask was equipped with a magnetic stirring bar, dry ice cooled condenser, dropping funnel, thermometer and temperature controller (Therm-O-Watch, ^I2R ). The air in the system was blown out with a nitrogen stream, and then a protective tube for protecting the reaction mixture with nitrogen was installed. Add the propoxylated absolute alcohol or dioxin to the reaction flask. About 0.1-5 mole percent sodium metal is carefully added in portions to the reaction vessel, heating if necessary to react all of the sodium. The reaction mixture was then heated to about 80-130°C and propylene oxide (Aldrich) was added dropwise from the dropping funnel at such a rate as to maintain a small reflux from the dry ice cooled condenser. Addition of propylene oxide is continued until the amount of propylene oxide required for the target degree of propoxylation has been added. Heating was continued until all propylene oxide reflux ceased, and the temperature was maintained for about 1 hour to ensure completion of the reaction. The reaction mixture is then cooled to room temperature and neutralized by careful addition of a conventional acid such as methanesulfonic acid. Any salt was removed by filtration to give the desired propoxylated product. The average degree of propoxylation is usually confirmed by quadrature of ¹ H-NMR spectra.

  Preparation of polybutoxylated derivatives

A three necked round bottom flask was equipped with a magnetic stir bar, dry ice cooled condenser, dropping funnel, thermometer and temperature controller (Therm-O- ^WatchI2R ). The air in the system was blown out with a nitrogen stream, and then a protective tube for protecting the reaction mixture with nitrogen was installed. Add the butoxylated absolute alcohol or diol to the reaction flask. About 0.1-5 mole percent sodium metal is carefully added in portions to the reaction vessel, heating if necessary to react all of the sodium. The reaction mixture was then heated to about 80-130°C and alpha-butene oxide (Aldrich) was added dropwise from the dropping funnel at such a rate to maintain a small reflux from the dry ice cooled condenser. Addition of butylene oxide is continued until the amount of butylene oxide required for the target degree of butoxylation has been added. Heating was continued until all butene oxide reflux ceased, and the temperature was maintained for about 1-2 hours to ensure completion of the reaction. The reaction mixture is then cooled to room temperature and neutralized by careful addition of a conventional acid such as methanesulfonic acid. Any salts were removed by filtration to give the desired butoxylated product. The average degree of butoxylation is usually confirmed by quadrature of ¹ H-NMR spectra.

  Preparation of Polybutylidene Oxylated Derivatives

About 0.1 mole of anhydrous desired alcohol or diol starting material was placed in a three-neck round bottom flask equipped with a magnetic stirrer, condenser, built-in thermometer and argon protection system. If the average degree of "butoxylation" desired per hydroxyl group is about 1, about 0.11 moles of 2-(4-chlorobutoxy)tetrahydropyran (ICI) are added per mole of alcohol functionality. A solvent such as anhydrous tetrahydrofuran, dioxane or dimethylformamide can be added if necessary. Sodium hydride (approximately 5 mole % excess relative to the chlorinated compound) was then added in small portions with excellent stirring while maintaining the temperature at about 30-120°C. After all hydride reactions, the temperature is maintained until all the alcohol has been alkylated, which typically takes about 4-24 hours. After the reaction was complete, the reaction mixture was cooled and the excess hydride was decomposed by carefully adding methanol in small portions. Then about an equal volume of water was added and the pH was adjusted to about 2 with sulfuric acid. Warm to about 40°C for about 15 minutes to hydrolyze the tetrahydropyranyl protecting group, neutralize the reaction mixture with sodium hydroxide, and strip the solvent on a rotary evaporator. The residue was dissolved in ether or dichloromethane and filtered to remove salts. Stripping yields crude butoxylated alcohols or diols. Further purification can be performed by vacuum distillation. If a final average degree of butoxylation of less than 1 is desired, correspondingly lower amounts of chlorinated compounds and hydrides are used. If the average degree of butoxylation is desired to be greater than 1, the entire process is repeated until the accumulation reaches the desired target value.

Preparation of Alkyl and Aryl Monoglyceryl Ethers

A conventional method for preparing alkyl and/or aryl monoglyceryl ethers involves first preparing the corresponding alkyl glyceryl ether precursors. It is then converted to a ketal, which is then hydrolyzed to a monoglyceryl ether (diol). The following is an illustrative example for the preparation _of the preferred n-pentyl monoglyceride, (ie, 3-(pentyloxy)-1,2-propanediol) _nC5H11 -O-CHOH- _CH2OH . Preparation of 3-(pentyloxy)-1,2-propanediol

Add about 546 grams of sodium hydroxide aqueous solution (about 50% concentration) and about 38.5 grams of tetrabutyl hydrogen sulfate in a 2-liter three-necked round-bottomed reaction flask (equipped with an upper stirrer, a cold water condenser, a mercury thermometer and a dropping funnel). Ammonium (PTC, phase transfer catalyst). The contents of the flask were stirred to dissolve, then about 200 grams of 1-pentanol and about 400 mL of hexane (mixture of isomers, about 85% of which was n-hexane) were added. About 418 grams of epichlorohydrin was added to the dropping funnel and added slowly (dropped) to the stirred reaction mixture. The temperature gradually rose to about 68°C due to the exotherm of the reaction. The reaction was continued for about 1 hour after the addition of epichlorohydrin (without heating).

The crude reaction mixture was diluted with about 500 mL of warm water, stirred slowly, then the aqueous layer was allowed to clarify and removed. The hexane layer was mixed and diluted with about 1 liter of warm water, and the pH was adjusted to about 6.5 by adding aqueous dilute sulfuric acid. The aqueous layer was re-separated and removed, then the hexane layer was washed 3 times with fresh water. Then the hexane layer was separated and evaporated to dryness with a rotary evaporator to obtain crude n-pentylglyceryl ether. Acetonylation (conversion into ketal)

Add about 1 liter of acetone to a 2 liter three-neck round bottom flask (equipped with an upper stirrer, cold water condenser, mercury thermometer and dropping funnel). About 1 mL of _SnCl4 was added to the acetone with stirring. Into the dropping funnel fitted to the reaction flask was added about 200 grams of the n-pentylglyceryl ether just prepared. The glyceryl ether was added very slowly to the stirred acetone solution (the rate of addition was adjusted to control the exotherm). The reaction was allowed to continue for about 1 hour after the addition of the glyceryl ether was complete (maximum temperature about 52°C). hydrolysis

The apparatus was changed to a distillation apparatus, and a heating mantle and temperature controller were added. The crude reaction mixture was concentrated by distillation of about 600 mL of acetone. To the cooled concentrated solution was added about 1 liter of aqueous sulfuric acid (about 20% strength) and about 500 ml of hexane. The contents of the flask were then heated to about 50° C. while stirring (apparatus adjusted to collect and separate liberated acetone). The hydrolysis reaction was continued until completion as confirmed by TLC (thin layer chromatography) analysis.

The crude reaction mixture was cooled, separated and the aqueous layer was removed. The organic layer was then diluted with about 1 L of warm water, and the pH was adjusted to about 7 by the addition of dilute aqueous sodium hydroxide (1N). The aqueous layer was separated again, and the organic phase was washed 3 times with fresh water. The organic phase was then separated and evaporated on a rotary evaporator. The residue was then diluted with fresh hexanes and the desired product was extracted into methanol/water solution (approximately 70/30 weight ratio). The methanol/water solution was evaporated to dryness on a rotary evaporator (additional methanol was added to aid evaporation of water). The residue was then hot filtered through glass microfiber filter paper to obtain n-pentyl monoglyceride.

  Preparation of bis(hydroxyalkyl) ether Synthesis of bis(2-hydroxybutyl) ether

A 500-mL three-necked round-bottom flask equipped with a magnetic stirrer, built-in thermometer, dropping funnel, condenser, argon gas supply, and heating mantle was flushed with argon. Then 1,2-butanediol (about 270 grams, about 3 moles, Aldrich) and sodium metal (about 1.2 grams, about 0.05 moles, Aldrich) were added and the sodium was allowed to dissolve. The reaction mixture was then heated to about 100°C and butylene oxide (about 71 grams, about 1 mole, Aldrich) was added dropwise with stirring. Heating was continued until the reflux of the butylene oxide ceased, and heating was continued for an additional hour to complete conversion. The reaction mixture was neutralized with sulfuric acid, the salts were removed by filtration, and the excess butanediol was recovered by fractional distillation of the liquid under vacuum. The desired ether was obtained as a residue. It can optionally be purified by further vacuum distillation. Synthesis of Bis(2-Hydroxycyclopentyl) Ether

A 1-liter three-necked round-bottom flask equipped with a magnetic stirrer, built-in thermometer, dropping funnel, condenser, argon gas supply, and heating mantle was flushed with argon. Then 1,2-cyclopentanediol (about 306 grams, about 3 moles, Aldrich) was added and boron trifluoride diethyl etherate (about 0.14 grams, about 0.01 moles, cis-trans isomer mixture, Aldrich ). The reaction mixture was then maintained at about 10-40°C while cyclopentene oxide (about 84 grams, about 1 mole, Aldrich) was added dropwise with stirring until all the cyclopentene oxide had reacted. The reaction mixture was neutralized with sodium hydroxide, and excess cyclopentanediol was recovered by fractional distillation of the liquid under vacuum. The desired ether was obtained as a residue. It can optionally be purified by further vacuum distillation.

The above-disclosed methods are only for illustration, in order to help those skilled in the art to implement the present invention, but not for limitation.

Unless otherwise specified, all percentages, ratios and proportions herein are by weight and all numbers are approximations. All documents are incorporated herein by reference in relevant part.

The following non-limiting examples illustrate clear or translucent products with acceptable viscosities.

The compositions in the following examples were prepared by first preparing DEQA softener active oil at room temperature. If the softener active is not fluid at room temperature, the softener active can be heated to melt, for example, at about 130-150°F (about 55-66°C). The softener active was mixed using an IKA RW25_ mixer at about 150 rpm for about 2 to about 5 minutes. The acid/water was prepared separately by mixing HCl and deionized (DI) water at room temperature. If the softener active and/or primary solvent is not fluid at room temperature and heating is required, the acid/water should also be heated to a suitable temperature, e.g., about 100°F (about 38°C), and maintained in a water bath. the stated temperature. The primary solvents (melting at the appropriate temperature if their melting point is above room temperature) are added to the softener active premix and the premix is mixed for about 5 minutes. The acid/water is then added to the emulsifier premix and mixed for about 20 to about 30 minutes or until the composition is clear and uniform. Allow the composition to cool in air to room temperature.

The following are suitable N,N-bis(fatty acyloxyethyl)-N,N-dimethylammonium chloride fabric softener actives (DEQA) hereinafter used in the preparation of the following compositions, which have given Approximate distribution of defined fatty acyl groups. Fatty acyl DEQA ¹ DEQA ² DEQA ³ DEQA ⁴ DEQA ⁵ C12 Trace trace 0 0 0C14 3 3 0 0 0C16 4 4 5 5 5C18 0 0 5 6 6C14: 1 3 3 0 0C16: 1 7 7 0 0 3C18: 1 74 73 71 68 67C18: 2 4 8 8 11 11C18: 3 0 1 1 2 2C20: 1 0 0 2 2 2C20 and above C20 0 0 2 0 0 unknown 0 0 6 6 7 total 99 99 100 100 102IV 86-90 88- 95 99 100 95 cis/trans 20-30 20-30 4 5 5 TPU 4 9 10 13 13 TPU = total polyunsaturated fatty acyl groups (weight).

Component of Example I 1 2 2 3 4 5 6 7 8

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 43.2 - 26.6 - 26.6 26.6 26.6 DEQA ⁶ - - 27.5 - 27.5 - - - Ethanol 6 10 5.1 6 3.1 6 4 62-Ethyl-8 - - 8 9 8 9 -1,3-hexanediol 1,2-hexane8 20 16 8 9 8 9 16 diol HCl (pH2- 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.0053. 5) Fragrance - - - - - 1.0 - -Kathon - - 3ppm 3ppm - - - - Deionized water balance balance balance balance balance balance DEQA ⁶ chloride N,N-di(coconut Oleoyloxyethyl)-N,N-dimethylammonium.

The ClogP values of 2-ethyl-1,3-hexanediol and 1,2-hexanediol were 0.60 and 0.53, respectively, both within the preferred ClogP range.

The above examples illustrate clear or translucent products with acceptable viscosities.

Example IA

Contrast Contrast Contrast Contrast Contrast Components 8 8A 8B 8C 8D 8D F 8E

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.6 26.61,2-Hexanediol-16------1,2-Propanediol-16 - - - - -1,2-Butanediol - - 16 - - - -1,2-Pentanediol - - - 16 - - -1,2-Heptanediol - - - - 16 - -1,2 -Octanediol- - - - - 16 -1,2-Decanediol - - - - - - 16Ethanol6 6 6 6 6 6 6HCl(pH2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005Deionized water balance margin margin margin margin margin margin

With the exception of 1,2-hexanediol, all of the 1,2-alkanediols in Example IA had ClogP values outside the effective range of 0.15 to 0.64. Only the composition of Example 1-8 containing 1,2-hexanediol was a clear composition and had an acceptable viscosity at room temperature and at about 40°F (about 4°C); Comparative Example 1-8A Compositions through I-8F were opaque and/or had no acceptable viscosity.

Example IB

Contrast Contrast Contrast Contrast Contrast 8G 8H 8I 8J 8K L

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.6 26.61,2-Hexanediol 16 - - - - - -1,3-Hexanediol - 16 - - - - -1,4-hexanediol- - 16 - - - -1,5-hexanediol - - - 16 - - -1,6-hexanediol - - - - 16 - -2 ,4-Hexanediol- - - - - 16 -2,5-Hexanediol- - - - - - 16 Ethanol 6 6 6 6 6 6 6HCl (pH2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 Deionized water margin margin margin margin margin margin

With the exception of 1,2-hexanediol, all of the hexanediol isomers in Example IB had ClogP values outside the effective range of 0.15 to 0.64. Only the compositions of Examples 1-8 containing 1,2-hexanediol were clear compositions and had acceptable viscosities at room temperature and at about 40°F (about 4°C); Compositions 8G to 1-8L were opaque and/or had no acceptable viscosity.

Example IC

                                                                             

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.61,2-Hexanediol 16 9.2 13 9 9 -1,2-Pentanediol-6.8 2 - - 6.81,2-octanediol--1--9.2 ethyl lactate---9--isopropyl lactate----9-ethanol6 6 6 6 6 6HCl(pH2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 Deionized water balance balance balance balance balance

Compositions of Examples 1-8, 1-8M and 1-8N containing effective levels of the preferred primary solvent of 1,2-hexanediol were clear at room temperature and at about 40°F (about 4°C) composition and has an acceptable viscosity. The compositions of Examples 1-80 and 1-8P containing effective levels of the preferred 1,2-hexanediol primary solvent were clear compositions at room temperature and had acceptable viscosities at about 40°F (approx. 4°C) was clear but a small layer separated on top, but returned to clear when warmed to room temperature. The compositions of Comparative Examples I-8Q, which did not contain an effective amount of the preferred 1,2-hexanediol, were opaque and/or had no acceptable viscosity.

Components of Example II 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ - 26.6 - 20.0 20.0 26.6 -DEQA ⁶ 27.5 - 27.5 6.8 6.8 - 27.5 Ethanol 5.1 6 5.1 3.8 - 4 5.1 Isopropanol - - - - - 2 -2-Ethyl-1,3- - - - 16 18 - -Hexanediol 1,2-Hexanediol 16 - - - - 16 -2,5-Dimethyl- - - - - - - 162,5-hexanediol 2-methyl-2-propane-16 16 - - - -yl-1,3-propanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) to Ionized water balance balance balance balance balance balance

Components of Example III 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ - 26.6 - 26.6 26.6 26.6 -DEQA ² 26 - 26 - - - 26 Ethanol 5.1 6 5.1 3.8 - 4 5.1 Isopropanol - - - - - 2-n-propanol 18 - - - - - -2-butanol-16 - - - - -2-methyl-1-propanol- - 18 - - 2-ol 2-methyl-2 -Propane- - - 20 - - - Alcohol 2,3-Dimethyl- - - - - 18 - - 2,3-Butanediol 2,3-Dimethyl- - - - - - 16 -1,2 - Butanediol 3,3-Dimethyl- - - - - - - 181,2-Butanediol CaCl ₂ - 0.25 - - - - -HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance balance balance balance

Component of Example IV 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2,3- 18 - - - - - -pentanediol 3-methyl-2,3- - 18 - - - - -pentanediol 4-methyl- 2,3--18-----pentanediol 2,3-hexanediol---17---3,4-hexanediol----18--2-ethyl-1,2 - - - - - - 17-Butanediol 2-methyl-1,2- - - - - - - 18 Pentanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) deionized water margin margin margin margin margin margin

Component of Example V 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - 26 26 - -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-1,2- 18 - - - - - -pentanediol 4-methyl-1,2- - 18 - - - - -pentanediol 1,2-hexane Diol- - 18 - - - -2-Butyl-1,3- - - - 17 - - -Propanediol 2,2-diethyl- - - - - 18 - -1,3-Propanediol 2-(1 -Methylpropane-----17-yl)-1,3-propanediol 2-(2-methylpropane------18-yl)-1,3-propanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.005 3.5) Deionized water balance balance balance balance balance balance

Component of Example VI 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3,3-trimethyl-18- - - - - -yl-1,2-butanediol 2-ethyl-2-methyl-18 - - - - -yl-1,4 -Butanediol 2-ethyl-3-meth--18----yl-1,4-butanediol 2-propyl-1,4----17---butanediol 2-iso Propyl- - - - - 18 - -1,4-Butanediol 2,2-Dimethyl- - - - - - 17 -1,5-Pentanediol 2,3-Dimethyl- - - - - - - 181, 5-pentanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) deionized water balance balance balance balance balance balance

                                                                                 

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ - 26.6 - 20.0 20.0 26.6 DEQA ² 27.5 - 27.5 6.8 6.8 - Ethanol 5.1 6 5.1 3.8 - 4 Isopropanol - - - - - 22 ,4-Dimethyl-1,5-pentan-18-----diol 3,3-dimethyl-1,5-pentan-18----diol 2,3-dimethyl-2 ,3-penta--18---diol 2,4-dimethyl-2,3-penta---16--diol 3,4-dimethyl-2,3-penta---- 18-diol 4,4-dimethyl-2,3-pentane- - - - - 16-diol HCl (pH about 2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 Deionized water balance balance balance balance margin margin

Components of Example VIII 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-Dimethyl-18 - - - - - -3,4-pentanediol 2-ethyl-1,5- 18 - - - - - -pentanediol 2- Methyl-1, 6- - - 18 - - - -Hexanediol 3-methyl-1, 6- - - - 17 - - - Hexanediol 2-methyl-2, 3- - - - - 18 - -Hexanediol 3-methyl-2,3- - - - - - 17 -Hexanediol 4-methyl-2,3- - - - - - - 18Hexanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.005 3.5) Deionized water balance balance balance balance balance balance

Components of Example IX 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -5-Methyl-2,3- 18 - - - - - -Hexanediol 2-methyl-3,4- - 18 - - - - -Hexanediol 3-methyl- 3,4- - - 18 - - - -Hexanediol 1,3-Heptanediol- - - 17 - - -1,4-Heptanediol- - - - 18 - -1,5-Heptanediol- - - - - 17 -1,6-heptanediol - - - - - - 18HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance balance balance margin

Example X component 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-2-(2-Methylbutane-18- - - - - -yl) -1,3-propanediol 2-(1-methylpropane-18 - - - - -yl) -1, 3-Propanediol 2-(1,1-dimethyl--18----ylpropyl)-1,3-propanediol 2-(1,2-dimethyl---17---ylpropyl)- 1,3-propanediol 2-(1-ethylpropane----18-yl)-1,3-propanediol 2-(1-methylbutan-----17-yl)-1,3- Propylene Glycol 2-(2,2-Dimethyl-------18-Propyl)-1,3-Propanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized Water Balance margin margin margin margin margin

Components of Example XI 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-(3-Methylbut18- - - - - -yl) -1,3-propanediol 2-butyl-2-methyl-18 - - - - -yl-1,3 - Propanediol 2-ethyl-2-iso- - 18 - - - -Propyl-1,3-propanediol 2-ethyl-2-propane- - - 17 - - -yl-1,3-propanediol 2-meth Base-2-(1------18--methylpropyl)-1, 3-propanediol 2-methyl-2-(2------17-methylpropyl)-1, 3-propanediol 2-tert-butyl-2- - - - - - - 18methyl-1,3-propanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) deionized water balance balance balance balance balance balance balance

Components of Example XII 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2-Diethyl-18 - - - - - -1,3-Butanediol 2,2-Diethyl- - 18 - - - - -1,3-Butanediol Alcohol 2-(1-methylpropan--18----yl)-1,3-butanediol 2-butyl-1,3----17--butanediol 2-ethyl- 2,3------18--Dimethyl-1,3-butanediol 2-(1,1-Dimethyl-----17-ylethyl)-1,3-butanediol 2-(2-Methyl propane-------18 base)-1,3-butanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance margin margin margin margin

                                                                                             

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2-iso-18 - - - - - -propyl-1,3-butanediol 2-methyl-2-propan-18 - - - - -yl-1 ,3-Butanediol 3-methyl-2-iso--18----propyl-1,3-butanediol 3-methyl-2-propane---17---yl-1, 3-butanediol 2,2-diethyl- - - - - 18 - -1,4-butanediol 2-methyl-2-propane- - - - - 17-yl-1,4-butanediol Alcohol 2-(1-methyl propane-------18 base)-1,4-butanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance balance balance balance balance

Components of Example XIV 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Ethyl-2,3- 18 - - - - - -Dimethyl-1,4-butanediol 2-ethyl-3,3- - 18 - - - - - Dimethyl-1,4-butanediol 2-(1,1-dimethyl--18- - - -ylethyl)-1,4-butanediol 2-(2-methylpropane- - - 17- - -yl)-1,4-butanediol 2-methyl-3-propane- - - - 18- -yl-1,4-butanediol 3-methyl-2-iso- - - - - 17-propyl-1,4-butanediol 3-methyl-2-iso- - - - - - 18-propyl-1,4-butanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) deionized water balance balance balance balance balance balance

Example XV Components 1 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2---6 2-2,2,3-Trimethyl-18-------1,3-Pentanediol 2,2,4-Trimethyl-18------1, 3-pentanediol 2,3,4-trimethyl- - 18 - - - --1,3-pentanediol 2,4,4-trimethyl- - - 17 - - --1,3- pentanediol 3,4,4-trimethyl- - - - 18 - --1,3-pentanediol 2,2,3-trimethyl- - - - - 17 --1,4-pentanediol Alcohol 2,2,4-trimethyl- - - - - - 18-1,4-pentanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance margin margin margin margin

Components of Example XVI 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2---6 2-2,3,3-Trimethyl-18-------1,4-Pentanediol 2,3,4-Trimethyl-18------1, 4-pentanediol 3,3,4-trimethyl- - 18 - - - --1,4-pentanediol 2,2,3-trimethyl- - - 17 - - --1,5- pentanediol 2,2,4-trimethyl- - - - 18 - --1,5-pentanediol 2,3,3-trimethyl- - - - - 17 --1,5-pentanediol Alcohol 2,3,4-trimethyl- - - - - - 18-1,5-pentanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance margin margin margin margin

Components of Example XVII 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3,4-Trimethyl-18 - - - - - --2,4-Pentanediol 2,3,3-Trimethyl-18 - - - - --2, 4-pentanediol 2,3,4-trimethyl- - 18 - - - --2,4-pentanediol 2,3,3-trimethyl- - - 17 - - --2,4- Pentanediol 2,3,3-trimethyl- - - - 18 - --2,4-pentanediol 2,3,4-trimethyl- - - - - 17 --2,4-pentanediol Alcohol 2-ethyl-2-methyl- - - - - - 18-yl-1,3-pentanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

Components of Example XVIII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-2-Ethyl-3-methyl-18- - - - - -yl-1, 3-pentanediol 2-ethyl-4-methyl-18 - - - - -yl-1, 3-Pentanediol 3-ethyl-2-metha--18----yl-1,3-pentanediol 2-ethyl-2-metha---17---yl-1,4- Pentanediol 2-ethyl-3-meth-- - - 18-yl-1,4-pentanediol 2-ethyl-4-meth- - - - - 17-yl-1,4-pentanediol Alcohol 3-Ethyl-2-Methyl-- - - - - 18-yl-1,4-pentanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance margin margin margin margin

Components of Example XIX 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-3-Ethyl-3-methyl-18- - - - - -yl-1, 4-pentanediol 2-ethyl-2-methyl-18 - - - - -yl-1, 5-Pentanediol 2-ethyl-3-metha--18----yl-1,5-pentanediol 2-ethyl-4-metha---17---yl-1,5- pentanediol 3-ethyl-3-metha- - - - 18-yl-1,5-pentanediol 2-ethyl-4-metha- - - - - 17-yl-1,5-pentanediol Alcohol 3-ethyl-3-methyl------18-yl-1,5-pentanediol HCl (pH about 2- 0.005 0.005 0.005 0.005 0.005 0.005 0.0053.5) Deionized water balance balance balance margin margin margin margin

Example XX component 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Ethyl-2-methyl-18- - - - - -yl-2, 4-pentanediol 3-ethyl-2-methyl-18 - - - - -yl-2, 4-pentanediol 2-isopropyl- - - 18 - - - -1,3-pentanediol 2-propyl-1,3- - - - 17 - - -pentanediol 2-isopropyl- - - - - 18 - -1,4-pentanediol 2-propyl-1,4- - - - - - 17-pentanediol 3-isopropyl- - - - - - - 181,4-pentanediol Glycol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Components of Example XXI 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-isopropyl-18 - - - - - -1,5-pentanediol 3-propyl-2,4- - 18 - - - - -pentanediol 2,2- Dimethyl- - - 18 - - - -1,3-Hexanediol 2,3-Dimethyl- - - - 17 - - -1,3-Hexanediol 2,4-Dimethyl- - - - - 18 - -1,3-Hexanediol 2,5-Dimethyl- - - - - - 17 -1,3-Hexanediol 3,4-Dimethyl- - - - - - - 181, 3-Hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Component of Example XXII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,5-Dimethyl-18 - - - - - -1,3-Hexanediol 4,5-Dimethyl- - 18 - - - - -1,3-Hexanediol Alcohol 2,2-Dimethyl---18----1,4-Hexanediol 2,3-Dimethyl----17---1,4-Hexanediol 2,4-Di Methyl- - - - - 18 - -1,4-Hexanediol 2,5-Dimethyl- - - - - - 17-1,4-Hexanediol 3,3-Dimethyl- - - - - - - 181,4-hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Component of Example XXIII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ - 26.6 - 20.0 20.0 26.6 -DEQA ⁶ 27.5 - 27.5 6.8 6.8 - 27.5 Ethanol 5.1 6 5.1 3.8 - 4 5.1 Isopropanol - - - - - 2 -3,4-Dimethyl-18 - - - - - -1,4-Hexanediol 3,5-Dimethyl- - 18 - - - - -1,4-Hexanediol Alcohol 4,4-Dimethyl---18----1,3-Hexanediol 4,5-Dimethyl----17---1,4-Hexanediol 5,5-Di Methyl- - - - - 18 - -1,4-Hexanediol 2,2-Dimethyl- - - - - - 16 -1,5-Hexanediol 2,3-Dimethyl- - - - - - - 181,5-hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Components of Example XXIV 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,4-Dimethyl-18 - - - - - -1,5-Hexanediol 2,5-Dimethyl- - 18 - - - - -1,5-Hexanediol Alcohol 3,3-Dimethyl---18----1,5-Hexanediol 3,4-Dimethyl----17---1,5-Hexanediol 3,5-Di Methyl- - - - - 18 - -1,5-Hexanediol 4,5-Dimethyl- - - - - - 17-1,5-Hexanediol 2,2-Dimethyl- - - - - - - 181,6-hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Components of Example XXV 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-Dimethyl-18 - - - - - -1,6-Hexanediol 2,4-Dimethyl- - 18 - - - - -1,6-Hexanediol Alcohol 2,5-Dimethyl---18----1,6-Hexanediol 3,3-Dimethyl----17---1,6-Hexanediol 3,4-Di Methyl- - - - - 18 - -1,6-Hexanediol 2,3-Dimethyl- - - - - - 17-2,4-Hexanediol 2,4-Dimethyl- - - - - - - 182, 4-hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Components of Example XXVI 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,5-Dimethyl-18 - - - - - -2,4-Hexanediol 3,3-Dimethyl- - 18 - - - - -2,4-Hexanediol Alcohol 3,4-Dimethyl---18---2,4-Hexanediol 3,5-Dimethyl----17---2,4-Hexanediol 4,5-Di Methyl- - - - - 18 - -2,4-Hexanediol 5,5-Dimethyl- - - - - - 17-2,4-Hexanediol 2,3-Dimethyl- - - - - - - 182, 5-hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Components of Example XXVII 1 2 3 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,4-Dimethyl-18 - - - - - -2,5-Hexanediol 2,5-Dimethyl- - 18 - - - - -2,5-Hexanediol Alcohol 3,3-Dimethyl---18---2,5-Hexanediol 3,4-Dimethyl----17---2,5-Hexanediol 3,3-Di Methyl- - - - - 18 - -2,6-hexanediol 2-ethyl-1,3- - - - - - 17-hexanediol 4-ethyl-1,3- - - - - - - 18 hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Components of Example XXVIII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Ethyl-1,3- 18 - - - - - -hexanediol 4-ethyl-1,3- - 18 - - - - -hexanediol 2-ethyl- 1, 4- - - 18- - - - Hexanediol 4-ethyl-1, 4- - - - 17 - - - Hexanediol 2-ethyl-1, 5- - - - - 18 - - Hexa Diol 4-ethyl-1,4- - - - - - 17-hexanediol 2-ethyl-1,5- - - - - - - 18-hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH About 2-3.5) deionized water balance balance balance balance balance balance

                                                                                               

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Ethyl-2,4- 18 - - - - - -hexanediol 4-ethyl-2,4- - 18 - - - - -hexanediol 3-ethyl- 2, 5- - - 18 - - - - hexanediol 3-ethyl-2, 5- - - - 17 - - - hexanediol 2-methyl-1, 3- - - - - 18 - - heptan Diol 3-methyl-1,3- - - - - - 17-heptanediol 4-methyl-1,3- - - - - - - 18heptanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH About 2-3.5) deionized water balance balance balance balance balance balance

Example XXX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -5-Methyl-1,3- 18 - - - - - -Heptanediol 6-methyl-1,3- - 18 - - - - -Heptanediol 2-methyl- 1, 4- - - 18 - - - - Heptanediol 3-methyl-1, 4- - - - 17 - - - Heptanediol 4-methyl-1, 4- - - - - 18 - - Heptane Diol 5-methyl-1,4- - - - - - 17-heptanediol 6-methyl-1,4- - - - - - - 18heptanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005(pH About 2-3.5) deionized water balance balance balance balance balance balance

Components of Example XXXI 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-1,5- 18 - - - - - -Heptanediol 3-methyl-1,5- - 18 - - - - -Heptanediol 4-methyl- 1,5- - - 18- - - - Heptanediol 5-methyl-1, 5- - - - 17 - - - Heptanediol 6-methyl-1, 5- - - - - 18 - - Heptane Diol 2-methyl-1,6- - - - - - 17-heptanediol 3-methyl-1,6- - - - - - - 18heptanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH About 2-3.5) deionized water balance balance balance balance balance balance

Components of Example XXXIA 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -4-Methyl-1,6- 18 - - - - - -Heptanediol 5-methyl-1,6- - 18 - - - - -Heptanediol 6-methyl- 1, 6- - - 18 - - - - Heptanediol 2-methyl-2, 4- - - - 17 - - - Heptanediol 3-methyl-2, 4- - - - - 18 - - Heptane Diol 4-methyl-2,4- - - - - - 17-heptanediol 5-methyl-2,4- - - - - - - - 18heptanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH About 2-3.5) deionized water balance balance balance balance balance balance

Example XXXIB Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -6-Methyl-2,4- 18 - - - - - -Heptanediol 2-methyl-2,5- - 18 - - - - -Heptanediol 3-methyl- 2, 5- - - 18 - - - - Heptanediol 4-methyl-2, 5- - - - 17 - - - Heptanediol 5-methyl-2, 5- - - - - 18 - - Heptane Diol 6-methyl-2,5- - - - - - 17-heptanediol 2-methyl-2,6- - - - - - - 18heptanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH About 2-3.5) deionized water balance balance balance balance balance balance

Example XXXIC Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-2,6- 18 - - - - - -Heptanediol 4-methyl-2,6- - 18 - - - - -Heptanediol 3-methyl- 3, 4- - - 18 - - - - Heptanediol 2-methyl-3, 5- - - - 17 - - - Heptanediol 3-methyl-3, 5- - - - - 18 - - Heptane Diol 4-methyl-3,5- - - - - - 17-Heptanediol 2,4-octanediol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) to Ionized water balance balance balance balance balance balance

Example XXXID Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,5-octanediol-18 - - - - - -2,7-octanediol-18 - - - - -3,5-octanediol- - 18 - - - -3 ,6-octanediol- - - 17 - - -2,3,3,4-tetramethyl- - - - 18 - -yl-2,4-pentanediol 3-tert-butyl - - - - - - 17-2,4-pentanediol 2,5,5-trimethyl- - - - - - 18-2,4-hexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance

Components of Example XXXII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,3,4-Trimethyl-18 - - - - - --2,4-Hexanediol 3,3,5-Trimethyl-18 - - - - --2, 4-Hexanediol 3,5,5-trimethyl- - 18 - - - --2,4-Hexanediol 4,5,5-trimethyl- - - 17 - - --2,4- Hexanediol 3,3,4-trimethyl- - - - 18 - --2,5-Hexanediol 3,3,5-trimethyl- - - - - 17 --2,5-hexanediol Alcohol 3-(n-pentyloxy-------18 base)-1,2-propanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

Example XXXIIA

Contrast Contrast Contrast Contrast Contrast Components 7 7A 7B 7C 7D 7E F 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 26.6 26.6 26.6 26.6 26.6 3-(n-Pentyloxy)-16 - - - - - -1,2-Propanediol 3-Ethoxy-1,2--16-----propanediol 3-butoxy-1,2---16----propanediol 3-octyloxy-1,2----16 - - -Propanediol 3-(2-Ethylhexyloxy- - - - 16 - -yl) -1,2-Propanediol monoolein - - - - - 16 -Glycerol monostearate - - - - - - 16 Ethanol 6 6 6 6 6 6 6CaCl ₂ 0.5 0.5 0.5 0.5 0.5 0.5 0.5HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH2-3.5) deionized water balance balance balance balance balance balance

3-(n-pentyloxy)-1,2-propanediol has a ClogP value of 0.54, which is within the preferred range of 0.40 to 0.60, and all other 1,2-propanediol derivatives in Example XXXIIA have a ClogP value of 0.15 to 0.60. ClogP values outside the valid range of 0.64. Only the composition of Example XXXII-7 containing 3-(n-pentyloxy)-1,2-propanediol was a clear composition at room temperature and at about 40°F (about 4°C) and had acceptable Viscosity; the compositions of Comparative Examples XXXII-7A to XXXII-7F were opaque and/or did not have acceptable viscosity.

Components of Example XXXIII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-(2-pentyloxy)-18 - - - - - -1,2-propanediol 3-(3-pentyloxy)- - 18 - - - - -1,2- Propylene glycol 3-(2-methyl-1-butan--18----oxyl)-1,2-propanediol 3-(isoamyloxy)----17---1,2-propanediol 3 -(3-Methyl-2-butan----18--oxyl)-1,2-propanediol 2-propyl-1,3-penta-----17-diol 2,6-octyl Diol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Components of Example XXXIV 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 26 DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 21-isopropyl-1,2- 18 - - - - - -cyclobutanediol 3-ethyl-4-methyl- - 18 - - - - -1,2-cyclobutanediol Alcohol 3-propyl-1,2-cyclo--18---butanediol 3-isopropyl-1,2----17---cyclobutanediol 1-ethyl-1,2 -cyclo- - - - 18 - -pentanediol 1,2-dimethyl- - - - - - 17 -1,2-cyclopentanediol 2,3,4-trimethyl- - - - - - - 182,4-pentanediol n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Components of Example XXXV 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,4-Dimethyl-18 - - - - - -1,2-Cyclopentanediol 2,4,5-Trimethyl- -18 - - - - -1,3 -Cyclopentanediol 3,3-Dimethyl- - - 18 - - - -1,2-Cyclopentanediol 3,4-Dimethyl- - - - 17 - - -1,2-Cyclopentanediol Alcohol 3,5-Dimethyl-----18--1,2-Cyclopentanediol 3-Ethyl-1,2-cyclo-----17-Pentanediol 1-Phenyl-1 , 2-B- - - - - - 18 diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example XXXVA

                                                                                                                                      

Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 26.6 26.6 cis-1,2-bis(hydroxymethyl)cyclohexane 16 - - -1,4-bis(hydroxymethyl)cyclohexane - 16 - -1,2-cyclohexanediol- - 16 -4,5-dimethyl-1,2-cyclohexanediol- - - 16Ethanol6 6 6 6HCl 0.005 0.005 0.005 0.005 (pH2-3.5) Deionized water balance balance balance balance

Cis-1,2-bis(hydroxymethyl)cyclohexane has a ClogP value of 0.47, which is within the preferred range of 0.40 to 0.60. 1,4-bis(hydroxymethyl)cyclohexane also has a ClogP value of 0.47, which is within the preferred range of 0.40 to 0.60, but it has a center of symmetry and does not form an acceptable composition (composition XXXVA- 5A). 1,2-cyclohexanediol and 4,5-dimethyl-1,2-cyclohexanediol have ClogP values outside the effective range of 0.15 to 0.64. Only the composition of Example XXXVA-5 was a clear composition at room temperature and at about 40°F (about 4°C); the compositions of Comparative Examples XXXVA-5A to XXXVA-5C were opaque and/or had no acceptable viscosity .

Components of Example XXXVI 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-1,2-propanediol 18 - - - - - -2(Me-E ₃ )1,2-propanediol PO ₄ - 18 - - - - -2-methyl-1,2-propane Di--18----alcohol (Me-E ₈ ) 2-methyl-1,2-propanedi- - -17- - -alcohol 2 (Me-E ₁ ) 2-methyl-1,2- Propanedi- - - - 18 - -alcohol-PO ₃ 1,3-propanediol - - - - - 17 -2(Me-E ₈ )1,3-propanediol PO ₆ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Component of Example XXXVII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2-diethyl-1,3- 18 - - - - - -propanediol-E ₅ 2,2-diethyl-1,3- - 18 - - - - -propanediol -PO ₁ 2,2-dimethyl-1,3- - - 18 - - - -propanediol-2(MeE ₂ )2,2-dimethyl-1,3- - - - 17 - - -propanediol- PO ₄ 2-(1-methylpropyl)- - - - - 18 - -1,3-propanediol-E ₅ 2-(1-methylpropyl)- - - - - - 17 -1,3- Propylene glycol-PO ₁ 2-(2-methylpropyl)- - - - - - - 181,3-Propanediol-E ₅ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

Example XXXVIII Components 1 2 3 4 5 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-(2-methylpropyl)-18 - - - - - -1,3-propanediol-PO ₁ 2-ethyl-1,3-propanedi-18 - - - - -Alcohol-(MeE ₉ ) 2-Ethyl-1,3-propanedi- - - 18 - - - -alcohol 2(MeE ₁ ) 2-ethyl-1, 3-propanedi- - - 17 - - -alcohol -PO ₃ 2-ethyl-2-methyl- - - - - 18 - -1,3-propanediol-(MeE ₄ ) 2-ethyl-2-methyl- - - - - - 17 -1,3 -Propanediol-PO ₂ 2-Ethyl-2-Methyl- - - - - - - 181,3-Propanediol-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

                                                                                                           

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-isopropyl-1,3-propane18 - - - - - -diol-(MeE ₄ )2-isopropyl-1,3-propane-18 - - - - - Diol-PO ₂ 2-isopropyl-1,3-propane - - 18 - - - -diol-BO ₁ 2-methyl-1,3-propanedi- - - 17 - - -alcohol-2( MeE ₄ ) 2-methyl-1,3-propanedi- - - - 18 - -alcohol-PO ₅ 2-methyl-1,3-propanedi- - - - - 17 -alcohol-BO ₂ 2-methanol Base-2-isopropyl- - - - - - 18-1,3-Propanediol-E ₆ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

                                                                                                               

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2-isopropyl18 - - - - - --1,3-Propanediol-PO ₁ 2-Methyl-2-propyl- - 18 - - - - - l,3-propanediol-E ₄ 2-methyl-2-propyl- - - 18 - - - -1,3-propanediol-PO ₁ 2-propyl-1,3-propanedi- - - 17 - - -alcohol-(MeE ₃ )2-propyl-1,3-propanedi- - - - 18 - -alcohol-PO ₂ 2-ethyl-1,2-butanedi- - - - - 17 -alcohol-E ₂ 2-Ethyl-1,2-butanedi - - - - - - 18 alcohol-n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

                                                                                                                 

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-1,2-butanedi18 - - - - - -alcohol-(MeE ₂ ) 2-methyl-1,2-butane-di-18 - - - - - Alcohol-PO ₁ 3,3-Dimethyl-1,2- - - 18 - - - -Butanediol-E ₄ 3,3-Dimethyl-1,2- - - - 17 - - -Butanediol Alcohol n-BO ₁ 3-methyl-1,2-butanedi- - - - 18 - -alcohol-(MeE ₂ ) 3-methyl-1,2-butanedi- - - - - 17 -alcohol-PO ₁ 1,3-Butanediol- - - - - - - 182(MeE ₅ )HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance margin

                                                                                                 

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,3-Butanediol PO ₅ 18 - - - - - -1,3-Butanediol BO ₂ - 18 - - - - -2,2,3-Trimethyl- - - 18 - - - -1,3-butanediol-(MeE ₂ )2,2,3-trimethyl- - - - 17 - - -1,3-butanediol-PO ₂ 2,2-di Methyl-1,3- - - - - 18 - -Butanediol-(MeE ₆ )2,2-Dimethyl-1,3- - - - - - 17 -Butanediol PO ₃ 2,3- Dimethyl-1,3- - - - - - - 18 Butanediol (MeE ₆ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

                                                                            

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEOA ⁴ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-Dimethyl-1,3-18 - - - - - -butanediol PO ₃ 2-ethyl-1,3-butanedi-18 - - - - -alcohol (MeE ₄ ) 2-Ethyl-1,3-butanedi- - 18 - - - -alcohol PO ₂ 2-ethyl-1,3-butanedi- - - 17 - - -alcohol BO ₁ 2-ethyl -2-methyl- - - - - 18 - -1,3-butanediol (MeE ₁ ) 2-ethyl-2-methyl- - - - - - 17 -1,3-butanediol PO ₁ 2-ethyl-3-methyl- - - - - - - 181, 3-butanediol (MeE ₁ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance balance

Example XXXXIV Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQAU ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Ethyl-3-methyl-18 - - - - - -1,3-Butanediol PO ₁ 2-Isopropyl-1,3-Butane-18 - - - - -diol (MeE ₁ ) 2-isopropyl-1,3-butane--18----diol PO ₁ 2-methyl-1,3-butanedi---17---alcohol 2( MeE ₂ ) 2-methyl-1,3-butanedi- - - - 18 - -alcohol PO ₄ 2-propyl-1,3-butanedi- - - - - 17-alcohol E ₆ 2-propyl- 1,3-Butanedi- - - - - - 18 alcohol PO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance balance

                          Components                                                                                                                                                      

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-1,3-butanedi-18- - - - - -alcohol 2(MeE ₂ ) 3-methyl-1,3-butanedi-18 - - - - -alcohol PO ₄ 1,4-butanediol - - 18 - - - -2(MeE ₃ )1,4-butanediol PO ₄ - - - 17 - - -1,4-butanediol BO ₂ - - - - 18 - -2,2,3-Trimethyl- - - - - - 17 -1,4-Butanediol E ₆ 2,2,3-Trimethyl- - - - - - - 181,4-Butane Diol PO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example XXXXVI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2-Dimethyl-1,4-18 - - - - - - Butanediol (MeE ₄ ) 2,2-Dimethyl-1,4- - 18 - - - - -Butanediol PO ₂ 2,2-Dimethyl-1,4- - - 18 - - - -Butanediol BO ₁ 2,3-Dimethyl-1,4- - - - 17 - - - Butanediol (MeE ₅ ) 2,3-Dimethyl-1,4- - - - - 18 - -Butanediol PO ₂ 2,3-Dimethyl-1,4- - - - - - 17 - Butanediol BO ₁ 2-ethyl-1,4-butanedi- - - - - - 18 alcohol (MeE ₃ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

                                                                                                                                           

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Ethyl-1,4-butanedi-18- - - - - -alcohol BO ₁ 2-ethyl-1,4-butanedi-18 - - - - -alcohol (C ₆ )PO ₂ 2-ethyl-2-methyl - - 18 - - - -1,4-butanediol-E ₄ 2-ethyl-2-methyl - - - - 17 - - -1,4- Butanediol PO ₁ 2-Ethyl-3-methyl- - - - - 18 - -1,4-Butanediol E ₄ 2-Ethyl-3-methyl- - - - - - 17 -1, 4-butanediol PO ₁ 2-isopropyl-1,4-butane - - - - - - 18diol E ₄ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

                                                                                                                   

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-isopropyl-1,4-butane 18 - - - - - -diol PO ₁ 2-methyl-1,4-butanedi-18 - - - - -alcohol (MeE ₈ ) 2-methyl-1,4-butane---18----alcohol 2(MeE ₁ )2-methyl-1,4-butanedi---17---alcohol PO ₃ 2-iso Propyl-1,4-butane- - - - 18 - -diol E ₅ 3-ethyl-1-methyl- - - - - - 17 -1,4-butanediol E ₆ 3-ethyl- 1-Methyl- - - - - - - 181,4-Butanediol PO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance margin

Example IL Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-butanediol 18 - - - - - -(MeE ₉ )2,3-butanediol - 18 - - - - -2(MeE ₁ )2,3-butanediol Alcohol PO ₄ - - 18 - - - -2,3-Dimethyl-2,3- - - - 17 - - - Butanediol E ₇ 2,3-Dimethyl-2,3- - - - - 18 - -butanediol PO ₁ 2,3-dimethyl 2,3- - - - - - 17 -butanediol n-BO ₂ -2-methyl-2,3-butanedi- - - - - - 18 alcohol (MeE ₄ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example L component 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-methyl-2,3-butanedi18 - - - - - -alcohol PO ₂ 2-methyl-2,3-butanedi- 17 - - - - -alcohol BO ₁ 1 ,2-pentanediol E ₇ - - 18 - - - -1,2-pentanediol PO ₁ - - - 17 - - -1,2-pentanediol n-BO ₃ - - - - 18 - -2 -methyl-1,2-pentanedi- - - - - 17 -alcohol E ₂ 2-methyl-1,2-pentanedi- - - - - - 18-alcohol n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LI Components 1 1 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-1,2-pentanedi18 - - - - - -alcohol E ₂ 3-methyl-1,2-pentanedi-18 - - - - -alcohol n-BO ₁ 4-methyl-1,2-pentanedi- - - 18 - - - -alcohol E ₂ 4-methyl-1,2-pentanedi- - - - 17 - - -alcohol n-BO ₁ 1,3-pentane Diol- - - - 18 - -2(MeE ₂ )1,3-Pentanediol PO ₄ - - - - - 17 -2,2-Dimethyl-1,3- - - - - - - 18pentane Diol (Me-E ₁ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example LII Components 1 1 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-Dimethyl-1,3-18 - - - - - -pentanediol (Me-E ₁ ) 2,3-dimethyl-1,3- - 18 - - - - -pentanediol PO ₁ 2,4-dimethyl-1,3- - - 18 - - - -pentanediol (Me-E ₁ ) 2,4-dimethyl-1,3- - - - 17 - - -Pentanediol PO ₁ 2-Ethyl-1,3-pentanedi- - - - - 18 - -Alcohol E ₆ 2-Ethyl-1,3-pentanedi- - - - - 17 - Alcohol PO ₁ 2-methyl-1,3-pentanedi- - - - - - 18 Alcohol 2(Me-E ₄ )HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

Example LIII Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁴ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-1,3-pentanedi18 - - - - - -alcohol PO ₂ 2-methyl-1,3-pentanedi-18 - - - - -alcohol-BO ₁ 3,4-Dimethyl-1,3- - - 18 - - - -pentanediol (Me-E ₁ )3,4-Dimethyl-1,3- - - - 17 - - -pentanediol PO ₁ 3-Methyl-1,3-pentanedi- - - - 18 - -ol 2(Me-E ₄ ) 3-methyl-1,3-pentanedi- - - - - 17-ol PO ₃ 3 -Methyl-1,3-pentanedi- - - - - - 18 alcohol BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance margin

Example LIV Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -4,4-Dimethyl-1,3-18 - - - - - -pentanediol (Me-E ₁ ) 4,4-dimethyl-1,3- - 18 - - - - -pentanediol PO ₁ 4-methyl-1,3-pentanediol - - 18 - - - -alcohol PO ₃ 4-methyl-1,3-pentanediol - - - 17 - - -alcohol BO ₁ 1,4-pentanediol - - - - 18 - -2(Me-E ₂ )1,4-pentanediol PO ₃ - - - - - 17 -2,2-Dimethyl-1,4- - - - - - - 18 pentanediol (Me-E ₁ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example LV Components 1 2 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2-Dimethyl-1,4- 18 - - - - - -Pentanediol PO ₁ 2,3-Dimethyl-1,4- - 18 - - - - - Pentylene glycol (Me-E ₁ ) 2,3-dimethyl-1,4- - - 18 - - - -pentanediol PO ₁ 2,4-dimethyl-1,4- - - - 17 - - -pentanediol (Me-E ₁ )2,4-dimethyl-1,4- - - - - 18 - -pentanediol PO ₁ 2-methyl-1,4-pentanedi- - - - - 17-alcohol 2(Me-E ₄ )2-methyl-1,4-pentanedi- - - - - - 18-alcohol PO ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water margin margin margin margin margin margin

Example LVI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-1,4-pentanediol 18 - - - - - -alcohol BO ₁ 3,3-Dimethyl-1,4- - 18 - - - - -pentanediol (Me-E ₁ )3,3-Dimethyl-1,4- - - 18 - - - -pentanediol PO ₁ 3,4-dimethyl-1,4- - - - 17 - - -pentanediol Diol (Me-E ₁ ) 3,4-dimethyl-1,4- - - - - 18 - -pentanediol PO ₁ 3-methyl-1,4-pentanedi- - - - - 17 - Alcohol 2 (Me-E ₄ ) 3-methyl-1,4-pentanedi- - - - - - 18 alcohol PO ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

Example LVII Components 1 2 3 4 5 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-1,4-pentanedi-18- - - - - -alcohol BO ₁ 4-methyl-1,4-pentanedi-18 - - - - -alcohol 2(Me -E ₄ ) 4-methyl-1,4-pentanedi- - 18 - - - -alcohol PO ₃ 4-methyl-1,4-pentanedi- - - 17 - - -alcohol BO ₁ 1,5- Pentylene glycol (Me- - - - - 18 - -E ₆ ) 1,5-pentanediol - - - - - 17 -2(Me-E ₁ ) 1,5-pentanediol PO ₃ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LVIII Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2-Dimethyl-1,5-18 - - - - - -Pentanediol E ₅ 2,2-Dimethyl-1,5- - 18 - - - - - Pentanediol PO ₁ 2,3-Dimethyl-1,5- - - 18 - - - - Pentanediol E ₄ 2,3-Dimethyl-1, 5- - - - 17 - - - Pentanediol Alcohol PO ₁ 2,4-Dimethyl-1,5- - - - - 18 - -pentanediol E ₅ 2,4-Dimethyl-1,5- - - - - - 17 -pentanediol PO ₁ 2-Ethyl-1,5-pentanedi- - - - - - 18 alcohol E ₄ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

Example LIX Components 1 1 2 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-1,5-pentanedi18 - - - - - -alcohol (Me-E ₂ ) 2-methyl-1,5-pentane-18 - - - - -di Alcohol PO ₂ 3,3-Dimethyl-1,5- - - 18 - - - -Pentanediol E ₄ 3,3-Dimethyl-1,5- - - - 17 - - -Pentanediol PO ₁ 3-methyl-1,5-pentanedi- - - - 18 - -alcohol (Me-E ₂ ) 3-methyl-1,5-pentanedi- - - - - 17-alcohol PO ₂ 2,3 -pentanediol (Me- - - - - - - 18E ₂ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example LX Components 1 1 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-pentanediol PO ₂ 18 - - - - - -2-methyl-2,3-pentanediol - 18 - - - - -alcohol E ₄ 2-methyl-2 ,3-pentanedi--18----alcohol PO ₁ 2-methyl-2,3-pentanedi- - - 17 - - -alcohol n-BO ₂ 2,2-dimethyl-1,3- - - - - 18 - -pentanediol PO ₁ 3-methyl-2,3-pentanediol - - - - - 17 -alcohol E ₄ 3-methyl-2,3-pentanediol- - - - - - 18 alcohol PO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example LXI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Ethyl-1-methyl-18 - - - - - -1,4-butanediol n-BO ₂ 3-methyl-2,3-pentanedi-18 - - - - - Alcohol n-BO ₂ 4-methyl-2,3-pentanedi - - 18 - - - - Alcohol E ₄ 4-methyl-2,3-pentanedi - - - 17 - - - Alcohol PO ₁ 4-Methyl-2,3-pentanedi- - - - 18 - -alcohol n-BO ₂ 2,2-Dimethyl-1,3- - - - - - 17 -pentanediol n-BO ₃ 2 , 4-pentanediol- - - - - - 182 (Me-E ₃ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance quantity

Example LXII Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,4-pentanediol PO ₄ 18 - - - - - -2,3-dimethyl-2,4- - 18 - - - - -pentanediol (Me-E ₃ )2,3-dimethyl-2,4- - - 18 - - - -pentanediol PO ₂ 2,4-dimethyl-2,4- - - - 17 - - -pentanediol (Me- E ₃ ) 2,4-dimethyl-2,4- - - - - 18 - -pentanediol PO ₂ 2-methyl-2,4-pentanedi- - - - - 17 -alcohol (Me-E ₈ ) 2-methyl-2,4-pentanedi- - - - - - 18 alcohol PO ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

Example LXIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,3-Dimethyl-2,4- 18 - - - - - -pentanediol (Me-E ₂ ) 3,3-dimethyl-2,4- - 18 - - - - -pentanediol PO ₂ 3-methyl-2,4-pentanediol - - 18 - - - -alcohol (Me-E ₈ ) 3-methyl-2,4-pentanediol- - - 17 - - -Alcohol PO ₃ 1,3-Hexanediol (Me- - - - - 18 - -E ₃ ) 1,3-Hexanediol PO ₂ - - - - - 17 -1,3-Hexanediol BO ₁ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance

Example LXIV Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-1,3-hexanedi18 - - - - - -alcohol E ₆ 2-methyl-1,3-hexanedi-18 - - - - -alcohol PO ₁ 3 -Methyl-1,3-hexanedi- - 18 - - - - Alcohol E ₆ 3-Methyl-1,3-hexanedi - - - 17 - - - Alcohol PO ₁ 4-Methyl-1,3- Hexamethylenedi- - - - 18 - -alcohol E ₅ 4-methyl-1,3-hexanedi- - - - - - 17-alcohol PO _{1 5} -methyl-1,3-hexanedi- - - - - - 18 alcohol E ₅ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example LXV Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26. 6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 ISO Propanol 2 - - - 6 2 -5-methyl-1,3-hexanediol 18 - - - - - - alcohol PO ₁ 1,4-hexanediol (Me- 18 - - - - - -E ₃ ) 1,4-hexanediol BO ₁ - - 18 - - - -1,4-hexanediol PO ₂ - - - 17 - - -2-methyl-1,4-hexanediol - - - - 18 - - Alcohol-E ₆ 2-methyl-1,4-hexanedi- - - - - 17-alcohol PO ₁ 3-methyl-1,4-hexanedi- - - - - - - 18-alcohol E ₆ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXVI Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-1,4-hexanedi18 - - - - - -alcohol PO ₁ 4-methyl-1,4-hexanedi-18 - - - - -alcohol E ₆ 4 -Methyl-1,4-hexanedi- - 18 - - - -Alcohol PO ₁ 5-Methyl-1,4-hexanedi- - - 17 - - -Alcohol E ₆ 5-Methyl-1,4- Hexamethylenediol - - - - 18 - - Alcohol PO ₁ 1,5-Hexanediol (Me- - - - - - - 17 -E ₃ ) 1,5-Hexanediol PO ₂ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXVII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,5-hexanediol BO ₁ 18 - - - - - -2-methyl-1,5-hexanediol - 18 - - - - -alcohol E ₆ 2-methyl-1 , 5-Hexanedi- - 18 - - - - Alcohol PO ₁ 3-Methyl-1,5-Hexanedi- - - 17 - - - Alcohol E ₆ 3-Methyl-1,5-Hexanedi- - - - 18 - -alcohol PO ₁ 4-methyl-1,5-hexanedi- - - - - 17-alcohol E ₅ 4-methyl-1,5-hexanedi- - - - - - - 18-alcohol PO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Components of Example LXVIII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁴ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -5-methyl-1,5-hexanedi18 - - - - - -alcohol E ₅ 5-methyl-1,5-hexanedi-18 - - - - -alcohol PO ₁ 1 ,6-Hexanediol (Me- - - 18 - - - -E ₂ )1,6-Hexanediol PO ₂ - - - 17 - - -2-Methyl-1,6-Hexanedi- - - - 18 - -alcohol E ₃ 3-methyl-1,6-hexanediol - - - - - 17 -alcohol E ₃ 2,3-hexanediol E ₃ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXIX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-hexanediol n-BO ₁ 18 - - - - - -2,4-hexanediol (Me- - 18 - - - - -E ₅ )2,4-hexane Diol PO ₃ - - 18 - - - -2-methyl-2,4-hexanedi- - - 17 - - -alcohol (Me-E ₂ ) 2-methyl-2,4-hexanedi- - - - 18 - - Alcohol PO ₂ 3-methyl-2,4-hexanedi- - - - - 17 - Alcohol-(Me-E ₂ ) 3-methyl-2,4-hexanedi- - - - - - 18 alcohol-PO ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example LXX Components 1 1 2 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -4-methyl-2,4-hexane 18 - - - - - -diol (Me-E ₂ ) 4-methyl-2,4-hexane-18 - - - - -diol Alcohol PO ₂ 5-methyl-2,4-hexane- - 18 - - - -diol (Me-E ₂ ) 5-methyl-2,4-hexanedi- - - 17 - - -alcohol PO ₂ 2 ,5-Hexanediol (Me- - - - - 18 - -E ₅ ) 2,5-Hexanediol PO ₃ - - - - - 17 -2-Methyl-2,5-Hexanedi- - - - - - 18 alcohol (Me-E ₂ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

                                                                                                           

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ - 26.6 - 20.0 20.0 20.0 20.0DEQA ² 26 - 27 6.8 6.8 6.8 6.8 Ethanol 5 4 5.1 4 - - - Isopropanol - - - 2 - - -2-methyl-2,5-hexane 18 - - - - - -diol PO ₂ 3-methyl-2,5-hexane- 18 - - - - -diol (Me- E ₂ ) 3-methyl-2,5-hexane--18----diol PO ₁ 3,4-hexanediol E ₃ ---17---3,4-hexanediol n-- - - - 18 - -BO ₁ 4-Ethyl-1,2-cyclo- - - - - 18-pentanediol bis(2-hydroxy-cyclopentyl- - - - - - 18-yl) ether HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

                                                                      

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -4,4-Dimethyl-1,2- 18 - - - - - -Cyclopentanediol 1,3-Heptanediol E ₄ - 18 - - - - -1,3- Heptanediol PO ₁ - - 18 - - - -1,3-Heptanediol n-BO ₂ - - - 17 - - -1,4-Heptanediol E ₄ - - - - 18 - -1,4- Heptanediol PO ₁ - - - - - 17 -1,4-Heptanediol n-BO ₂ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

                                                                          

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,5-heptanediol E ₄ 18 - - - - - -1,5-heptanediol PO ₁ - 18 - - - - -1,5-heptanediol n-BO ₂ - - 18 - - - -1,6-heptanediol E ₄ - - - 17 - - -1,6-heptanediol PO ₁ - - - - 18 - -1,6-heptanediol n-BO ₂ - - - - - 17 -1,7-heptanediol E ₁ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

                                                                                                               

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,7-heptanediol n-BO ₁ 18 - - - - - -2,4-heptanediol E ₇ - 18 - - - - -2,4-heptanediol (Me - - - 18 - - - -E ₁ )2,4-heptanediol PO ₁ - - - 17 - - -2,4-heptanediol n-BO ₃ - - - - 18 - -2,5-heptanediol Diol E ₇ - - - - - 17 -2,5-heptanediol (Me- - - - - - - - 18E ₁ ) HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance margin margin margin margin margin margin

                                                                            

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-3-Cyclooctene-1,2-bis-18- - - - - -ol 4-cyclooctene-1,2-bis-18 - - - - -ol 5-cyclooctene -1,2-di--18----alcohol 3,6-dimethyl-4-cyclo---17--hexene-1,2-diol 4,5-dimethyl-4 -cyclo- - - - 18 - -hexene-1,2-diol 1-vinyl-2-ethyl- - - - - 17 --1,2-cyclobutanediol 1,2,3,4 -Tetramethyl- - - - - - 183-Cyclobutene-1,2-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

Components of Embodiment LXXVI 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,4-diethyl-3-cyclo18 - - - - - -butene-1,2-diol 3-(1,1-dimethylethyl-18 - - - - -yl)-3-cyclobutene-1,2-diol 3-butyl-3-cyclobutene--18----1,2-diol 1,2-dimethyl-4 -methylene----17---methyl-1,2-cyclopentanediol 1-ethyl-3-methylene----18--1,2-cyclopentanediol 4-(1 -propenyl)- - - - - - 17 -1,2-Cyclopentanediol 1-ethyl-3-methyl- - - - - - - 183-Cyclopentene-1,2-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Component of Embodiment LXXVII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1-vinyl-1,2-cyclo18 - - - - - -hexanediol 1-methyl-3-methylene-18 - - - - --1,2-cyclo Hexanediol 1-methyl-4-methylene--18----1,2-cyclohexanediol 3-vinyl-1,2-cyclo---17---hexanediol 4 -vinyl-1,2-cyclo- - - - 18 - -hexanediol 2,6-dimethyl-3-cyclo- - - - - 17-hexene-1,2-diol 6,6- Dimethyl-3-cyclo- - - - - - 18-hexene-1,2-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance margin margin

Components of Embodiment LXXVIII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁶ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2-di-2-propenyl18 - - - - - --1,3-propanediol 2-(1-pentenyl)- - 18 - - - - -1,3 -Propanediol 2-(2-methyl-2-prop--18----enyl)-2-(2-propenyl)-1,3-propanediol 2-(3-methyl-1-but- - - 17- - -enyl)-1,3-propanediol 2-(4-pentenyl)- - - - - 18 - -1,3-propanediol 2-ethyl-2-(2-methyl- - - - - 17-yl-2-propenyl)-1,3-propanediol 2-ethyl-2-(2-prop- - - - - - 18-enyl)-1,3-propanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXXIX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2-(3-methyl-18- - - - - -yl-3-butenyl)-1,3-propanediol 2,2-diallyl- - 18 - - - - -1,3-butanediol 2-(1-ethyl-1-propane--18- - - -enyl)-1,3-butanediol 2-(2-butenyl) - - - - 17 - - -2-Methyl-1,3-butanediol 2-(3-methyl-2-butane- - - - 18 - -enyl)-1,3-butanediol 2 -Ethyl-2-(2-propane- - - - - 17-enyl)-1,3-butanediol 2-methyl-2-(1-methyl- - - - - - 18-yl-2- Propyl)-1,3-butanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Example LXXX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-bis(1-methylidene 18 - - - - - -ethyl)-1,4-butanediol 2-(3-methyl-2-butane- 18 - - - - -enyl)-3-methylene-1,4-butanediol 2-(1,1-dimethylprop--18- - - -yl)-2-butene-1,4 -diol 2-(1-methylpropyl)- - - - 17 - - -2-butene-1,4-diol 2-butyl-2-butene- - - - - 18 - -1 , 4-diol 2-vinyl-3-ethyl- - - - - 17 -- 1, 3-pentanediol 2-vinyl-4, 4-di- - - - - - 18 methyl-1 , 3-pentanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-2-(2-propane18 - - - - - -enyl)-1,4-pentanediol 2-(1-propenyl) - - 18 - - - - -1,5-pentanediol 2-(2-propenyl)- - - 18 - - - -1,5-pentanediol 2-ethylene-3-methyl- - - 17 - - -- 1,5-Pentanediol 2-Propylene-1,5-Pentane----18--Diol 3-Ethylene-2,4------17-Dimethyl-2, 4-pentanediol 2-(1,1-dimethylethyl- - - - - - 18 base) -4-pentene-1,3-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2- 3.5) Deionized water balance

Example LXXXII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁴ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Ethyl-2,3-dimethyl-18 - - - - - -yl-4-pentene-1,3-diol 4-ethyl-2-methylene-18 - - - - - 1,4-Hexanediol 2,3,5-trimethyl- - - 18 - - - -1,5-Hexadiene-3,4-diol 5-Ethyl-3 -Methyl-----17---1,5-Hexadiene-3,4-diol 2-(1-Methylethylene----18--yl)-1,5-Hexanediol 2-vinyl-1,6-hex-- - - - 17-diol 5,5-dimethyl-1-hex- - - - - - 18-ene-3,4-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXIII Components 1 1 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -5,5-Dimethyl-1-hexane 18 - - - - - -ene-3, 4-diol 4-vinyl-2, 5- - 18 - - - - -di Methyl-2-hexene-1,5-diol 2-vinyl-2,5- - - 18 - - - -Dimethyl-3-hexene-1,6-diol 2-ethyl- 3-Hexene----17---1,6-diol 3,4-dimethyl-3-hex----18--ene-1,6-diol 2,5-dimethyl yl-4-hex------17-ene-2,3-diol 3.4-dimethyl-4-hex------18-ene-2,3-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Components of Example LXXXIV 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁶ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-(2-propenyl)-5- 18 - - - - - -hexene-1,3-diol 2,3-dimethyl-5-hexyl- 18 - - - - -ene-2,3-diol 3,4-dimethyl-5-hex- - 18 - - - -ene-2,3-diol 3,5-dimethyl-5-hex- - - 17 - - -ene-2,3-diol 3-vinyl-2,5-di- - - - 18 - -methyl-5-hexene-2,4-diol 6-methyl-5- Methylene- - - - - 17--1,4-heptanediol 2,3-dimethyl-1,5- - - - - - - 18-heptadiene-3,4-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXV Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,5-Dimethyl-1,5-18 - - - - - -Heptadiene-3,4-diol 3,5-Dimethyl-1,5- -18 - - - - -Heptadiene-3,4-diol 2,6-di(methylene)- - - 18 - - - -1,7-Heptanediol 4-methylene-1,7- Hept---17---diol 2,4-dimethyl-1-hept----18--ene-3,5-diol 2,6-dimethyl-1-hept--- - - 17-ene-3,5-diol 3-vinyl-5-methyl- - - - - - 18-1-heptene-3,5-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005(pH About 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXVI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -6,6-Dimethyl-1-hept18 - - - - - -ene-3,5-diol 4,6-Dimethyl-2,4- - 18 - - - - -heptadiene-2,6-diol 4,4-dimethyl-2,5- - - 18 - - - -heptadiene-1,7-diol 2,5,5-trimethyl - - - - 17 - - -2,6-Heptadiene-1,4-diol 5,6-dimethyl-2-hept- - - - 18 - -ene-1,4-diol 5- Ethyl-2-heptene- - - - - - 17-1,5-diol 2-methyl-2-heptene- - - - - - - 181,7-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Components of Example LXXXVII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -4,6-Dimethyl-3-heptane-18 - - - - - -ene-1,5-diol 3-methyl-6-methylene-18 - - - - - -3-heptene-1,7-diol 2,4-dimethyl-3-hept--18----ene-2,5-diol 2,5-dimethyl-3-hept- - - 17 - - -ene-2,5-diol 2,6-dimethyl-3-hept- - - - 18 - -ene-2,6-diol 4,6-dimethyl-3- Hept-----17-ene-2,6-diol 2,4-dimethyl-5-hept-----18-ene-1,3-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXVIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,6-Dimethyl-5-hept-18 - - - - - -ene-1,3-diol 2,6-dimethyl-5-hept-18 - - - - -ene-1,4-diol 3,6-dimethyl-5-hept-- 18 - - - -ene-1,4-diol 2,3-dimethyl-5-hept- - - 17 - - -ene-2,4-diol 2,2-dimethyl-6-hept- - - - 18 - -ene-1,3-diol 4-(2-propenyl)-6- - - - - - 17-heptene-1,4-diol 5,6-dimethyl-6-hept- - - - - - 18-ene-1,4-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005(pH About 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXIX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,4-Dimethyl-6-hept18 - - - - - -ene-1,5-diol 2-ethylene-6-methyl-18 - - - - - -6-heptene-1,5-diol 4-(2-propenyl)-6- - - 18 - - - -heptene-2,4-diol 5,5-dimethyl-6-heptene - - - 17- - -ene-2,4-diol 4,6-dimethyl-6-hept- - - - 18 - -ene-2,5-diol 5-vinyl-4-methyl - - - - - 17 --6-heptene-2,5-diol 2-methylene-1,3-octane- - - - - - 18-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH approx. 2-3.5) Deionized water balance balance balance balance balance balance

Example LXXXX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,6-dimethyl-1,6-18 - - - - - -octadiene-3,5-diol 3,7-dimethyl-1,6- - 18 - - - - -octadiene-3,5-diol 2,6-dimethyl-1,7- - - 18 - - - -octadiene-3,6-diol 2,7-dimethyl Base-1,7- - - - 17 - - -octadiene-3,6-diol 3,6-dimethyl-1,7- - - - - 18 - -octadiene-3,6- Diol 3-vinyl-1-octene- - - - - 17 --3,6-diol 2,7-dimethyl- - - - - - - 182,4,6-octatriene-1 , 8-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

                                                                          

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁴ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,7-dimethyl-2,4-18 - - - - - -octadiene-1,7-diol 2,6-dimethyl-2,5- - 18 - - - - -octadiene-1,7-diol 3,7-dimethyl-2,5- - - 18 - - - -octadiene-1,7-diol 3,7-dimethyl Base-2,6- - - - 17 - - -octadiene-1,4-diol (Rosiridol) 2-methyl-2,6-octadi- - - - 18 - -ene-1,8- Diol 3,7-dimethyl-2,7- - - - - - 17-octadiene-1,4-diol 2,6-dimethyl-2,7- - - - - - - 18 Octadiene-1,5-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Example LXXXXII Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,6-Dimethyl-2,4-18 - - - - - -octadiene-1,6-diol (8-hydroxylinalool) 2,7-dimethyl yl-2,7--18-----octadiene-1,6-diol 2-octene-1,4-diol--18----2-octene-1,7- Diol - - - 17 - - -2-Methyl-6-methylene - - - - 18 - --2-octene-1,7-diol 2,2,4-trimethyl- - - - - - 17-1,4-pentanediol n-BO ₁ 3,7-dimethyl-3,5- - - - - - - 18-octadiene-1,7-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXXIII Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt. Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-2,7-Dimethyl-3,5-18 - - - - - -octadiene-2,7-diol 4-methylene-3,5-octyl-18 - - - - -diol 2,6-dimethyl-3,7- - - 8 - - - -octadiene-1,6-diol 2,7-dimethyl-3,7- - - - 7 - - -octadiene-2,5-diol 2,6-dimethyl-3,7- - - - - 18 - -octadiene-2,6-diol 4-methyl-3-octyl ene- - - - - - 17-1,5-diol 5-methyl-3-octene- - - - - - - 181,5-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2- 3.5) Deionized water balance

Example LXXXXIV Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2-Dimethyl-4,6-18 - - - - - -octadiene-1,3-diol 2,6-dimethyl-4,7- - 18 - - - - -octadiene-2,3-diol 2,6-dimethyl-4,7- - - 18 - - - -octadiene-2,6-diol 7-methyl-4 -octene- - - - 17 - - -1,6-diol 2,3,3-trimethyl- - - - - 18 - -1,4-pentanediol n-BO ₁ 2,7-di (Methylene)- - - - - - 17-4-octene-1,8-diol 2-methylene-4-octene- - - - - - 18-1,8-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example LXXXXV Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,7-Dimethyl-5,7-18 - - - - - -octadiene-1,4-diol 7-methyl-5,7-octadiene-18 - - - - -ene-1,4-diol 5-octene-1,3-diol - - 18 - - - -7-methyl-6-octene - - - - 17 - - -1,3 -diol 7-methyl-6-octene- - - - - 18 - -1,4-diol 6-octene-1,5-diol- - - - - 17 -7-methyl-6 -octene- - - - - - - 181,5-diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance

Example LXXXXVI Components 1 2 3 4 5 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-6-octene-18 - - - - - -3,5-diol 4-methyl-6-octene- - 18 - - - - -3,5 -diol 2-methyl-7-octene- - - 18 - - - -1,3-diol 4-methyl-7-octene - - - - 17 - - -1,3-diol 7 -Methyl-7-octene- - - - - 18 - -1,3-diol 7-octene-1,5-diol - - - - - 17 -7-octene-1,6-diol Alcohol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

                                                                                                           

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -5-methyl-7-octene-18 - - - - - -1,6-diol 2-methyl-6-methylene-18 - - - - --7- Octene-2,4-diol 7-methyl-7-octene- - - 18 - - - -2,5-diol 2-methyl-7-octene- - - - 17 - - -3 ,5-diol 1-nonene-3,5-diol- - - - 18 - -1-nonene-3,7-diol- - - - - 17-1-nonene-3,7- Diol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Example LXXXXVIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEOA ⁵ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-3-Nonene-2,5-diol 18 - - - - - -3-Nonene-2, 5-diol-18 - - - - -8-Methyl-4, 6-nonanediol--18----ene-1,3-diol 4-nonene-2,8-diol---17---6,8-nonadiene-1,5-- - - - 18 - -diol 7-nonene-2,4-diol- - - - - 17-8-nonene-2,4-diol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example IC Components 1 1 2 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -8-Nonene-2,5-diol 18 - - - - - -1,9-Decadiene-3,8- - 18 - - - - -diol 1,9- Decadiene-4,6---18----diol bis(2-hydroxycyclopent---17---yl)ether dibutylideneoxylated----18--3-butane Oxy-1,2-propanediol tributylideneoxylated - - - - - 17 -3-Butoxy-1,2-propanediol 1-(3-methylphenyl) - - - - - - - 181 , 3-propanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Component of Example C 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1-(4-methylphenyl)-18 - - - - - -1,3-propanediol 2-methyl-1-phenyl- - 18 - - - - -1,3 -Propanediol 3-(cyclohexyloxy)- - - 18 - - - -1,2-propanediol 3-(1-cyclohex-1-ene- - - 17 - - -oxyl)-1,2-propanediol 2-(pentyloxy)-1,3- - - - - 18 - -propanediol 2-(2-pentyloxy)- - - - - - 17 -1,3-propanediol 2-(3-pentyloxy )- - - - - - - 181,3-propanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Example CI Components 1 2 3 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-(2-Methyl-1-butane18 - - - - - -oxyl)-1,3-propanediol 2-(isoamyloxy) - - 18 - - - - - 1,3-propanediol 2-(3-methyl-2-butan--18----oxyl)-1,3-propanediol 2-(cyclohexyloxy)----17---1, 3-Propanediol 2-(1-Cyclohex-1-ene----18--oxyl)-1,3-propanediol triethoxylated 3-------17-(butoxy) - 1,2-propanediol tetraethoxylated 3- - - - - - - 18(butoxy)-1,2-propanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water margin margin margin margin margin margin

Example CII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁶ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-Pentaethoxylated 3- 18 - - - - - -(butoxy)-1,2-propanediol hexaethoxylated 3- - 18 - - - - -(butan Oxy)-1,2-propanediol heptaethoxylated 3- - - 18 - - - -(butoxy)-1,2-propanediol octaethoxylated 3- - - - 17 - - - (Butoxy)-1,2-propanediol nonaethoxylated 3- - - - - 18 - - (butoxy)-1,2-propanediol 2,6-octanediol - - - - - 17 -3,5-octanediol- - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2-4,4-Dimethyl-1,2-18 - - - - - -cyclopentanediol 4-ethyl-1,2-cyclopentyl-18 - - - - -diol 1,1-bis(hydroxymethyl)--18----cyclohexane 1,2-bis(hydroxymethyl)---17---cyclohexane 1,2-dimethyl-1, 3- - - - - 18 - -cyclohexanediol 1,3-bis(hydroxymethyl) - - - - - 17 -cyclohexane 1,3-dimethyl-1,3- - - - - - - 18 cyclohexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CIV Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,6-Dimethyl-1,3- 18 - - - - - -Cyclohexanediol 1-hydroxy-cyclohexane B- 18 - - - - -Alcohol 1-hydroxy- Cyclohexanemetha- - 18 - - - -alcohol 1-ethyl-1,3-cyclohexyl- - - 17 - - -diol 1-methyl-1,2-cyclohexyl- - - - 18 - - Diol 2,2-Dimethyl-1,3- - - - - - 17-Cyclohexanediol 2,3-Dimethyl-1,4- - - - - - - 18-Cyclohexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CV Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,4-Dimethyl-1,3-18 - - - - - -Cyclohexanediol 2,5-Dimethyl-1,3- - 18 - - - - -Cyclohexanediol Hexanediol 2,6-Dimethyl-1,4---18----Cyclohexanediol 2-Ethyl-1,3-cyclohexyl---17---Diol 2-Hydroxycyclo Hexane B- - - - 18 - -alcohol 2-hydroxyethyl-1-cyclohexyl- - - - - 17-alcohol 2-hydroxymethylcyclohexanol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CVI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Hydroxyethyl-1-cyclohexane 18 - - - - - -alcohol 3-hydroxycyclohexane- 18 - - - - -alcohol 3-hydroxymethylcyclohexanol- - 18 - - - -3-methyl-1,2-cyclohexyl- - - 17 - - -diol 4,4-dimethyl-1,3- - - - - 18 - -cyclohexanediol 4,5 -Dimethyl-1,3- - - - - - 17 -Cyclohexanediol 4,6-Dimethyl-1,3- - - - - - - 18cyclohexanediol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CVII Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -4-Ethyl-1,3-cyclohexane 18 - - - - - -diol 4-hydroxyethyl-1-cyclohexyl-18 - - - - -alcohol 4-hydroxymethyl -1-cyclohexyl- - 18 - - - -alcohol 4-methyl-1,2-cyclohexyl- - - 17 - - -diol 5,5-dimethyl-1,3- - - - - 18 - -cyclohexanediol 5-ethyl-1,3-cyclohexane- - - - - 17-diol 1,2-cycloheptanediol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005(pH About 2-3.5) deionized water balance balance balance balance balance balance

Example CVIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁶ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-1,3-cycloheptane 18 - - - - - -Diol 2-methyl-1, 4-cycloheptane-18 - - - - -Diol 4-methano Diol-1,3-cycloheptyl--18----Diol 5-methyl-1,3-cycloheptyl---17---Diol 5-methyl-1,4-cycloheptyl-- - - 18 - -diol 6-methyl-1,4-cycloheptane- - - - - 17 -diol 1,3-cyclooctanediol - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005( pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CIX Components 1 1 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,4-Cyclooctanediol 18 - - - - - -1, 5-Cyclooctanediol - 18 - - - - -1, 2-Cyclohexanediol di- - 18 - - - - Ethoxylate 1,2-Cyclohexanediol Tri- - - 17 - - - Ethoxylate 1,2-Cyclohexanediol Tetra- - - - 18 - - Ethoxylate 1,2 -cyclohexanediol penta- - - - - 17 -ethoxylate 1,2-cyclohexanediol hexa - - - - - - 18 ethoxylate HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2- 3.5) Deionized water balance

Example CX Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -1,2-cyclohexanediol seven 18 - - - - - - ethoxylate 1, 2-cyclohexanediol octa - 18 - - - - - ethoxylate 1,2 -cyclohexanediol nine- - 18 - - - -ethoxylate 1,2-cyclohexanediol mono- - - 17 - - -propoxylate 1,2-cyclohexanediol mono- - - - 18 - -Butylene oxide 1,2-cyclohexanediol di- - - - - 17 -Butylene oxide 1,2-cyclohexanediol tri - - - - - - 18 Butylene oxide HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CXI Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁴ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 2.3 6 6 6 - 4 6 Isopropanol - - - - 6 2 -1,2-hexanediol 16 - - 8 - - -1-phenyl-1,2-propanedi-18 - - - - -alcohol 2-phenyl-1,2-propane Di--188---alcohol 3-phenyl-1,2-propanedi----18--alcohol 1-(3-methylphenyl)------18-1,3- Propylene glycol 1-(4-methylphenyl)- - - - - - - 181, 3-propanediol MgCl ₂ 0.125 - - - - - -HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water margin margin margin margin margin margin

Example CXII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 6 6 6 6 - 4 6 Isopropanol - - - - 6 2 -2-Methyl-1-phenyl-18 - - - - - -1,3-propanediol 1-phenyl-1,3-butanedi-18 - - - - -alcohol 3- Phenyl-1,3-butanedi- - 18 - - - -alcohol 1-phenyl-1,4-butanedi- - - 18 - - -alcohol 2-phenyl-1,4-butanedi- - - - 18 - -alcohol 1-phenyl-2,3-butanedi- - - - - 18 -alcohol 3-phenoxy-1,2-propane- - - - - - 18-diol MgCl ₂ 0.125 - - - - - -HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CXIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26.6 26.6 -DEQA ² - - 26.6 26.6 - - 26.6 Ethanol 4 6 4 6 - 4 6 Isopropanol - - - - 6 2-propylene carbonate 2 - 2 - - - -3-benzyloxy-1,2-propane 18 - - - - - -diol 3-(2-phenylethoxy- 18 - - - - -yl)-1,2-propanediol 3-(1-phenyl-2-propane--18- - - -oxyl)-1,2-propanediol 2-phenoxy-1,3-propanediol - - - 18 - - -diol 2-(m-tolyloxy)- - - - - 18 - -1,3-propanediol 2-(p-tolyloxy)- - - - - - 18 -1,3- Propylene glycol 2-benzyloxy-1,3-propane- - - - - - 18 diol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance margin

Example CXIV Components 1 1 2 3 4 5 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-(2-Phenylethoxy-18- - - - - -yl)-1,3-propanediol 2-(1-phenylethoxy-18 - - - - -yl)- 1,3-Propanediol 3-methyl-2-isopropyl- - 18 - - - --1,3-Butanediol PO ₁ 2,3,3-Trimethyl- - - - 17 - - -2 ,4-pentanediol PO ₁ 2,2-diethyl-1,3- - - - - 18 - -butanediol n-BO ₂ 2,2-diethyl-1,3- - - - - - 17-butanediol E ₄ 2-ethyl-2,3-dimethyl - - - - - - 18-yl-1,3-butanediol n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH approx. 2-3.5) Deionized water balance balance balance balance balance balance

Example CXV Components 1 1 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2-isopropyl18 - - - - - --1,3-Butanediol n-BO ₁ 2,2,3-Trimethyl- - 18 - - - - -1,3-pentanediol n-BO ₁ 2,2,4-trimethyl- - - 18 - - - -1,3-pentanediol n-BO ₁ 2,3-dimethyl- 2,4- - - - 17 - - -Hexanediol n-BO ₂ 2,3-Dimethyl-2,4- - - - - 18 - -Hexanediol E ₄ 2,4-Dimethyl- 2,4- - - - - - 17-Hexanediol n-BO ₁ 2,4-Dimethyl-2,4- - - - - - - 18-Hexanediol E ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Example CXVI Components 1 1 2 2 3 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEOA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,5-Dimethyl-2,4-18 - - - - - -Hexanediol n-BO ₂ 2,5-Dimethyl-2,4- - 18 - - - - -Hexanediol E ₄ 3,3-Dimethyl-2,4- - - 18 - - - -Hexanediol n-BO ₂ 3,3-Dimethyl-2,4- - - - 17 - - -Hexanediol E ₃ 3,4-Dimethyl-2,4- - - - - 18 - -Hexanediol n-BO ₂ 3,4-Dimethyl-2,4- - - - - - 17-Hexanediol E ₄ 3,5-Dimethyl-2,4- - - - - - - 18-Hexanediol n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance

Components of Example CXVII 1 2 2 3 4 4 5 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,5-Dimethyl-2,4- 18 - - - - - -Hexanediol E ₃ 4,5-Dimethyl-2,4- - 18 - - - - - Hexanediol n-BO ₂ 4,5-Dimethyl-2,4- - - 18 - - - -Hexanediol E ₄ 5,5-Dimethyl-2,4- - - - 17 - - - Hexanediol n-BO ₂ 5,5-Dimethyl-2,4- - - - - 18 - - Hexanediol E ₃ 2,3-Dimethyl-2,5- - - - - - 17 - Hexylene glycol n-BO ₁ 2,3-dimethyl-2,5- - - - - - - 18 Hexylene glycol E ₄ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water margin margin margin margin margin margin

Components of Example CXVIII 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,4-Dimethyl-2,5- 17 - - - - - -Hexanediol n-BO ₁ 2,4-Dimethyl-2,5- - 18 - - - - -Hexanediol E ₄ 2,5-Dimethyl-2,5- - - 18 - - - -Hexanediol n-BO ₂ 2,5-Dimethyl-2,5- - - - 18 - - -Hexanediol E ₄ 3,3-Dimethyl-2,5- - - - - 17 - -Hexanediol n-BO ₁ 3,3-Dimethyl-2,5-hexane- - - - - 18-diol E ₄ 3,4-dimethyl-2,5-hexane - - - - - - 18-diol n-BO ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance

Example CXIX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,4-Dimethyl-2,5-hexane 18 - - - - - -diol E ₄ 3-methyl-3,5-heptanedi-18 - - - - -ol n-BO ₁ 3-methyl-3,5-heptanedi- - 18 - - - -alcohol E ₃ 2-(1,2-dimethylpropane- - - 17 - - -yl)-1,3- Propylene glycol E ₃ 2-ethyl-2,3-dimethyl- - - - 18 - -yl-1,3-butanediol E ₃ 2-methyl-2-isopropyl- - - - - - 17 - 1,3-Butanediol E ₃ 3-Methyl-2-isopropyl- - - - - - - 181,4-Butanediol E ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Example CXX Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,2,3-Trimethyl-18 - - - - - -1,3-Pentanediol E ₃ 2,2,4-Trimethyl- - 18 - - - - - 1,3-pentanediol E ₃ 2,4,4-trimethyl- - - 18 - - - -1,3-pentanediol E ₃ 3,4,4-trimethyl- - - - 17 - - -1,3-pentanediol E ₃ 2,2,3-trimethyl- - - - - 18 - -1,4-pentanediol E ₃ 2,2,4-trimethyl- - - - - - 17 -1,4-pentanediol E ₃ 2,3,3-trimethyl- - - - - - - 181,4-pentanediol E ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2 -3.5) Deionized water balance margin margin margin margin margin margin

Example CXXI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ² - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3,3,4-Trimethyl-18 - - - - - -1,4-Pentanediol E ₃ 2,4,4-Trimethyl- - 18 - - - - - 1,3-Pentanediol n-BO ₁ 2,3,4-Trimethyl- - - 18 - - - -2,4-Pentanediol E ₃ 3,4,4-Trimethyl- - - - 17 - -1,3-pentanediol n-BO ₁ 2-(1,2-dimethylpropane- - - - 18 - -yl)-1,3-propanediol n-BO ₁ 4-ethyl-2 , 4-Hexanedi- - - - - 17 - Alcohol E ₂ 4-Ethyl-2,4-Hexanedi - - - - - - 18 Alcohol E ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5 ) deionized water balance balance balance balance balance balance

Example CXXII Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2,4-heptanedi18 - - - - - -alcohol E ₂ 3-methyl-2,4-heptanedi-18 - - - - -alcohol E ₂ 4 -Methyl-2,4-heptanedi- - 18 - - - -Alcohol E ₂ 5-Methyl-2,4-heptanedi- - - 17 - - -Alcohol E ₂ 6-Methyl-2,4- Heptanedi- - - - 18 - -alcohol E ₂ 2-methyl-2,5-heptanedi- - - - - - 17-alcohol E ₂ 3-methyl-2,5-heptanedi- - - - - - 18 alcohol E ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example CXXIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -4-Methyl-2,5-heptanedi18 - - - - - -alcohol E ₂ 5-methyl-2,5-heptanedi-18 - - - - -alcohol E ₂ 6 -Methyl-2,5-heptanedi- - 18 - - - -Alcohol E ₂ 2-Methyl-2,6-heptanedi- - - 17 - - -Alcohol E ₂ 3-methyl-2,6- Heptanedi- - - - 18 - -alcohol E ₂ 4-methyl-2,6-heptanedi- - - - - - 17-alcohol E _{2 2} -methyl-3,5-heptanedi- - - - - - 18 alcohol E ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Components of Example CXXIV 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-2-isopropyl 18 - - - - - --1,4-Butanediol n-BO ₁ 2,2,3-Trimethyl- - 18 - - - - -1,4-pentanediol n-BO ₁ 4-ethyl-2,4-hexanedi- - - 18 - - - -alcohol n-BO ₁ 4-ethyl-2,4-hexanedi- - 17 - - -alcohol n-BO ₁ 2-methyl-2,4-heptanedi- - - - 18 - -alcohol n-BO ₁ 3-methyl-2,4-heptanedi- - - - - 17 -alcohol n-BO ₁ 4-methyl-2,4-heptanedi- - - - - - 18 alcohol n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance margin margin margin margin margin

Example CXXV Component 1 2 3 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -5-Methyl-2,4-heptanedi-18 - - - - - -alcohol n-BO ₁ 6-methyl-2,4-heptanedi-18 - - - - -alcohol n -BO ₁ 2-Methyl-2,5-heptanedi- - - 18 - - - -alcohol n-BO ₁ 3-methyl-2,5-heptanedi- - - - 17 - - -alcohol n-BO ₁ 4 -Methyl-2,5-heptanedi- - - - 18 - -alcohol n-BO ₁ 5-methyl-2,5-heptanedi- - - - - - 17 -alcohol n-BO ₁ 6-methyl- 2,5-heptanedi- - - - - - 18 alcohol n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water Balance Balance Balance Balance Balance Balance Balance

Example CXXVI component 1 2 3 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2,6-heptanedi-18 - - - - - -alcohol n-BO ₁ 3-methyl-2,6-heptanedi-18 - - - - -alcohol n -BO ₁ 4-methyl-2,6-heptanedi- - 18 - - - -alcohol n-BO ₁ 2-methyl-3,5-heptanedi- - - 17 - - -alcohol (C8)n- BO ₁ 1,2-hexanediol- - - - 8 8 82,2,4-trimethyl- - - - - 8 - -1,3-pentanediol 2-ethyl-1,3-hexanediol - - - - - 8 8 Alcohol fragrance 1.2 1.35 1.2 1.35 1.2 1.35 1.3HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Embodiment CXXVII component 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26.6 26.6 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 2.3 6 4 - 4 2 Isopropanol - - - - 4 - 21,2-Hexanediol 10 10 10 10 12 9 92-Ethyl-1,3-propanediol 7 - - - - - -alcohol 2-methyl-2-propyl - - 8 - - - - -1,3-propanediol 2,3-dimethyl-1,3- - - 6 - - - -butanediol 2-methyl-1,3-pentanediol - - - 7 - - - Alcohol 2-methyl-2,4-pentanediol- - - - 6 - - Alcohol 2,4-hexanediol- - - - - 8 -5-Methyl-2,4-hexanediol- - - - - - 8 alcohol fragrance 1 1 1 1.35 1.35 1.35 1.2HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance

Components of Example CXXVIII 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁴ 26.6 26.6 - - 26 26 -DEQA ⁵ - - 26 26 - - 26 Ethanol 4 4 4 4 - 4 6 Isopropanol - - 2 - - 2 -2,2,4-Trimethyl-10 - 9 - 10 10 -1,3-Pentanediol 2,2,4-Trimethyl- - 10 - 9 - - 101,3 -Pentanediol E ₂ 2-Ethyl-1,3-propanediol 8 8 - - - - -alcohol 2,3-dimethyl-1,3- - - 9 - - - -butanediol 2-methanol Base-1,3-pentanediol---9---alcohol 2-methyl-2,4-pentanediol----9--alcohol 2,4-hexanediol-----7-5 -Methyl-2,4-hexanedi- - - - - - 8 alcohol HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance balance

Example CXXIX Components 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁸ (Hydroxyethyl Ester 29.8 29.8 29.8 - 29.8 29.8 -Quat) DEQA ⁹ (Propyl Ester - - - 29.6 - - 29.6 Quat) Ethanol 2 2 2 - - 3 2 Isopropanol - - - 2 2 - - 1,2-Hexanediol 16 - - 17 8 8 8 2-Ethyl-1, 3-Hexanedi- 16 - - 8 - 8-alcohol 2,2,4-trimethyl- - - 16 - - 8 -1,3-pentanediol CaCl ₂ - 0.125 - - - - -MgCl ₂ - - 0.125 - - - -HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance DEQA ⁸ bis(acyloxyethyl)(2-hydroxyethyl)methylammonium methylsulfate , where the acyl group is the same as that of DEQA ¹ , about 89.4% active in ethanol. DEQA ⁹ 1,2-Bis(oleoyloxy)-3-trimethylpropylammonium chloride, wherein the acyl group is the same as that of DEQA ⁵ , about 88% active in ethanol.

Example CXXX component 1 2 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 4 - 41, 2 - Hexylene glycol 9 8 10 8 - 10 92,2,4-Trimethyl- - - - - 9 - -1,3-Propanediol 3-(n-pentyloxy)-8 - - - - - -1,2 - Propylene glycol 3-cyclohexyloxy-1,2- - 8 - - - - - Propylene glycol bis(2-hydroxybutyl) ether - - 6 - - - -3-Benzyloxy-1,2-propane- - - 8 - - -diol 1,2-bis(hydroxymethyl) - - - - 8 - -cyclohexane 2-phenyl-1,2-propanedi- - - - - - -alcohol 3,7- Dimethyl-2,6- - - - - - - 8-octadiene-1,4-diol CaCl ₂ - - - - - 0.25 -HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) to Ionized water balance balance balance balance balance balance

Example CXXXI Components 1 2 3 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,5-heptanediol PO ₁ 18 - - - - - -2,5-heptanediol n- - 18 - - - - -BO ₃ 2,6-heptanediol E ₇ - - 18 - - - -2,6-heptanediol (Me- - - - 17 - - -E ₁ )2,6-heptanediol PO ₁ - - - - 18 - -2,6-heptanediol n- - - - - - 17 -BO ₃ 2,6-heptanediol E ₇ - - - - - - 18HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance margin margin margin margin

Example CXXXII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁶ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,7-heptanediol (Me- 18 - - - - - -E ₁ )2,7-heptanediol PO ₁ - 18 - - - - -2,7-heptanediol n- - - 18 - - - -BO ₃ 2,2-Dimethyl-1,3- - - - 17 - - -Propanediol n-BO ₂ 2-(1-methylpropyl)- - - - - 18 - -1,3-propanediol n-BO ₂ 2-(2-methylpropyl)- - - - - - 17 -1,3-propanediol n-BO ₂ 2-ethyl-2-methyl- - - - - - - 181, 3-butanediol n-BO ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example CXXXIII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Methyl-2-isopropyl18 - - - - - --1,3-Butanediol n-BO ₂ 2-Methyl-2-propyl- - 18 - - - - -1,3-propanediol n-BO ₂ 1,2-butanediol (Me- - - 18 - - - -E ₆ )1,2-butanediol PO ₂ - - - 17 - - -1, 2-Butanediol BO ₁ - - - - 18 - -2,3-Dimethyl-1,2- - - - - - - 17-Butanediol E ₄ 2,3-Dimethyl-1,2- - - - - - - 18 Butanediol n-BO ₁ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example CXXXIV Components 1 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ³ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Ethyl-3-methyl-18 - - - - - -1,3-Butanediol n-BO ₃ 2-Isopropyl-1,3-Butane-18 - - - - -diol n-BO ₃ 2-propyl-1,3-butanedi- - - 18 - - - -alcohol n-BO ₃ 2,2,3-trimethyl- - - - 17 - - -1 , 4-butanediol n-BO ₂ 2-ethyl-2-methyl- - - - - 18 - -1,4-butanediol n-BO ₂ 2-ethyl-3-methyl- - - - - - 17 -1,4-butanediol n-BO ₂ 2-isopropyl-1,4-butane - - - - - - 18diol n-BO ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH About 2-3.5) deionized water balance balance balance balance balance balance

Components of Example CXXXV 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ⁵ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Propyl-1,4-butanedi18 - - - - - -alcohol n-BO ₁ 2,4-dimethyl-1,3- - 18 - - - - -pentane Diol n-BO ₃ 2-ethyl-1,3-pentanediol - - 18 - - - -alcohol n-BO ₂ 3,4-dimethyl-1,3- - - - 17 - - -pentanediol Alcohol n-BO ₃ 4,4-Dimethyl-1,3- - - - - 18 - -pentanediol n-BO ₃ 4-methyl-1,3-pentanedi- - - - - 17 -alcohol (Me-E ₅ )2,2-Dimethyl-1,4- - - - - - - 18 Pentanediol n-BO ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water margin margin margin margin margin margin

Example CXXXVI Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2,3-Dimethyl-1,4- 18 - - - - - -Pentanediol n-BO ₃ 2,4-Dimethyl-1,4- - 18 - - - - -pentanediol n-BO ₃ 3,3-dimethyl-1,4- - - 18 - - - -pentanediol n-BO ₃ 3,4-dimethyl-1,4- - - - 17 - - -pentanediol n-BO ₃ 2,2-dimethyl-1,5- - - - - 18 - -pentanediol n-BO ₂ 2,3-dimethyl-1,5- - - - - - 17-pentanediol n-BO ₂ 2,4-dimethyl-1,5- - - - - - - 18-pentanediol n-BO ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH approx. 2-3.5) Deionized water balance balance balance balance balance balance

Example CXXXVII Components 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ³ 26.6 26.6 - - 26 26 -DEQA ¹ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -2-Ethyl-1,5-pentanedi18 - - - - - -alcohol n-BO ₁ 3,3-dimethyl-1,5- - 18 - - - - -pentane Diol n-BO ₂ 2-methyl-1,3-hexanedi- - - 18 - - - -alcohol n-BO ₂ 3-methyl-1,3-hexanedi- - - 17 - - -alcohol n- BO ₂ 4-methyl-1,3-hexanedi- - - - 18 - -alcohol n-BO ₂ 5-methyl-1,3-hexanedi- - - - - 17 -alcohol n-BO ₂ 2- Methyl-1,4-hexanedi- - - - - - 18 alcohol n-BO ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance balance margin

Example CXXXVIII Component 1 2 3 4 5 6 7

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ 26.6 26.6 - - 26 26 -DEQA ⁴ - - 26 26 - - 26 Ethanol 4 6 6 6 - 4 6 Isopropanol 2 - - - 6 2 -3-Methyl-1,4-hexanedi-18 - - - - - -alcohol n-BO ₂ 4-methyl-1,4-hexanedi-18 - - - - -alcohol n -BO ₂ 5-methyl-1,4-hexanedi- - 18 - - - -alcohol n-BO ₂ 2-methyl-1,5-hexanedi- - - 17 - - - -alcohol n-BO ₂ 3 -Methyl-1,5-hexanedi- - - - 18 - -alcohol n-BO ₂ 4-methyl-1,5-hexanedi- - - - - - 17 -alcohol n-BO ₂ 5-methyl- 1,5-Hexanedi- - - - - - 18 alcohol n-BO ₂ HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) deionized water balance balance balance balance balance balance balance

Example CXXXIX Components 1 2 3 4 5 6

Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ² 26.6 26.6 - 26.6 26.6 -DEQA ⁵ - - 26 - - 26 Ethanol 4 6 6 4 6 6 Isopropanol 2 - - 2 - - 1,6-hexanediol n-BO ₄ 18 - - - - -2-methyl-1,6-hexanedi- 18 - - - -alcohol n-BO ₁ 3-methyl-1,6-hexanedi - - 18 - - - Alcohol n-BO ₁ 2,3,4-Dimethyl- - - - 18 - - 1,4-Pentanediol 2,3,4-Dimethyl- - - - - 18 - 1,4-pentanediol n-BO ₁ 2,3,4-Dimethyl- - - - - - 181,4-pentanediol E ₃ HCl 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) to Ionized water balance balance balance balance balance balance

Example CXXXX Components 1 2 2 3 4 5 6 7

% Wt.% Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ - 9.1 - 9.1 - - -DEQA ⁵ - - 9.1 9.1 - - -DEQA ¹⁰ 17.7 - - - - - -DEQA ¹¹ 8.3 - - - - - -DEQA ¹² - 16.9 16.9 - - - -DEQA ¹³ - - - 16.9 - - -DEQA ¹⁴ - - - - 16.9 - -DEQA ¹⁵ - - - - - 26 -DEQA ¹⁶ - - - - - - 26 Ethanol 6.6 6.6 6.6 6.6 6.6 6.6 6.6 1,2-Hexanediol 17 17 17 17 17 17 17HCl 0.005 0.005 0.005 0.005 0.005 0.005 0.005 (pH about 2-3.5) Deionized water balance balance balance balance Balance Balance DEQA ¹⁵ : N,N-bis(acyloxyethyl)-N,N-dimethylammonium chloride, wherein the acyl group consists of partially hydrogenated soybean fatty acid (DEQA ^{DEQA 10} fatty acid) and a mixture of lightly hydrogenated tallow fatty acid (DEQA ¹¹ fatty acid). DEQA ¹⁶ : N,N-bis(acyloxyethyl)-N,N-dimethylammonium chloride, wherein the acyl group consists of DEQA ¹ fatty acid and DEQA ¹² isostearic acid in a weight ratio of about 65:35 The mixture is derived.

In mixed branched and unsaturated chain DEQAs, wherein R ¹ is long chain C _5-21 (or C _6-22 ), preferably C _10-20 (or C _9-19 ) branched chain alkyl or unsaturated alkyl group, most preferably C _12-18 (or C _11-17 ) branched alkyl and unsaturated alkyl, the ratio of branched alkyl to unsaturated alkyl is preferably about 95:5 to about 5:95, more preferably is from about 75:25 to about 25:75, even more preferably from about 50:50 to about 30:70, and for unsaturated alkyl groups, the iodine number of the parent fatty acid of the ^R group is preferably from about 20 to about 140, More preferably from about 50 to about 130, most preferably from about 70 to about 115.

  Processing

As disclosed above, primary solvent B, some mixtures of primary solvent B, and secondary solvents provide for the preparation of a premix containing: Softener Active A (about 55% to about 85% by weight of the premix , preferably about 60% to about 80%, more preferably about 65% to about 75%); main solvent B (about 10% to about 30% by weight of the premixture, preferably about 13% to about 25%, more preferably about 15% to about 20%); and optionally contain a water-soluble solvent C (about 5% to about 20%, preferably about 5% to about 17%, more preferably about 5% to about 15% by weight of the premix) . As disclosed above, principal solvent B may optionally be replaced with an effective amount of a mixture of principal solvent B and some unsuitable solvent. These premixes contain the desired level of fabric softening active A and sufficient principal solvent B, and optionally solvent C, to give a premix having the desired viscosity over the desired temperature range. Typical viscosities suitable for processing are below about 1000 cps, preferably below about 500 cps, more preferably below about 300 cps. Use at low temperatures improves safety by minimizing volatilization of solvents, minimizes degradation and/or loss of materials such as biodegradable fabric softener actives, fragrances, etc., and reduces the need for heating, thus saving processing costs. Protection of the softener active may additionally be obtained by adding, for example, a chelating agent such as ethylenediaminepentaacetic acid when preparing the active. The result is improved environmental impact and safety in production operations.

Examples of premixes and processes using these materials include Fabric Softener Active A generally comprising from about 55% to about 85%, preferably from about 60% to about 80%, more preferably from about 65% to about 75%, as hereinafter As exemplified by DEQA ¹ and DEQA ⁸ in the examples, with about 10% to about 30%, preferably about 13% to about 25%, more preferably about 15% to about 20% of the main solvent such as 1,2- Hexylene glycol, and about 5% to about 20%, preferably about 5% to about 15% of a water-soluble solvent C such as ethanol and/or isopropanol mixed pre-mixture.

As disclosed hereinafter, when DEQA ¹ containing about 13% ethanol is used as the fabric softener active, and 1,2-hexanediol is used as the main solvent, the temperature at which the premix becomes clear and/or various levels The liquid of the main solvent is as follows: about 25% 1,2-hexanediol = clear below about -5°C, liquid below about -10°C. About 17% 1,2-hexanediol = clear down to about 0°C, liquid down to about -10°C. About 0% 1,2-hexanediol = clear down to about 17°C, liquid down to about 0°C.

These premixes can be used to formulate finished compositions during processing comprising the following steps:

1. Prepare a premix of fabric softening active such as about 72% DEQA ¹ , about 11% ethanol, and about 17% primary solvent such as 1,2-hexanediol and cool to room temperature.

2. Mix the spices in the premix. 3. Supplement water and HCl aqueous at room temperature. A chelating agent is optionally added. 4. Add the premix to the water with good agitation. 5. Adjust to desired viscosity with CaCl ₂ solution. 6. Add the dye solution to get the desired color.

The fabric softening actives (DEQAs); primary solvent B; and optionally, a water-miscible solvent, can be formulated into a premix which can be used to prepare the following compositions.

Example CXXXXI Components 1 2 3 4 5

Wt.% Wt.% Wt.% Wt.% Wt.% DEQA ¹ (100% active 2 5 10.5 10.5 - matter) DEQA ⁸ (100% active - - - - 10.5 matter) ethanol 0.35 0.88 1.85 1.85 - isopropanol - - - - 1.161, 2-Hexanediol 0.48 1.2 2.53 2.53 2.39 Fragrance 0.7 0.16 1.75 1.75 1.75 Chelating Agent - - - 250pp 250ppm

mHCl(100%) 0.02 0.02 0.02 0.02 0.02CaCl ₂ - - 630ppm 675pp 495ppm

                                                      , 

For commercial purposes, the above composition is placed in a container, especially a bottle, more specifically a transparent bottle made of polypropylene (although glass, oriented polyethylene, etc. transparent bottles), the bottles have a bright blue tint to compensate for any yellow color present, otherwise they will develop color during storage (although for a short time, for a very clear product, no tint or other tint can be used transparent container) and have a UV absorber in the bottle to minimize the effect of UV light on the contents of the bottle, especially highly unsaturated actives (the absorber can also be on the surface). The clarity and overall effect of the container speaks to the clarity of the composition, thus reassuring the consumer of the quality of the product.

Claims (57)

1. A material capable of forming a clear concentrated biodegradable fabric softener composition selected from the group consisting of: A. A compound selected from the group consisting of 2,3,3-trimethyl-1,2-butanediol; 2,3-Dimethyl-3,4-pentanediol; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl-3,4 -Hexanediol; 2,3,3-trimethyl-1,2-butanediol; 2,3-dimethyl-3,4-pentanediol; 2-(1,1-dimethylpropane base)-1,3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2 -(1-methylpropyl)-1,3-butanediol; 2-ethyl-2,3-dimethyl-1,3-butanediol; 2-(2-methylpropyl)- 1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-isopropyl-1,3-butanediol; 3-methyl -2-propyl-1,3-butanediol; 2,2-diethyl-1,4-butanediol; 2-methyl-2-propyl-1,4-butanediol; 2- (1-methylpropyl)-1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl -1,4-butanediol; 2-(2-methylpropyl)-1,4-butanediol; 2,2,3-trimethyl-1,4-pentanediol; 2,3, 3-Trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-1,5-pentanediol; 2-Ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4- Pentylene glycol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol; 3-ethyl-3-methyl- 1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-4-methyl-1,5-pentanediol; 3-ethyl-2 -Methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol Diol; 2-propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 3-propyl-2,4-pentanediol; 2,3-dimethyl -1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol; 3,5-dimethyl-1 , 3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4 -hexanediol; 2,4-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol Diol; 3,5-Dimethyl-1,4-hexanediol; 4,4-Dimethyl-1,3-hexanediol; 4,5-Dimethyl-1,4-hexanediol ; 2,2-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol; 4 , 5-dimethyl-1,5-hexanediol; 2,3-dimethyl-1,6-hexanediol; 2,4-dimethyl-1,6-hexanediol; 3,3 -Dimethyl-1,6-hexanediol; 4,5-dimethyl-2,4-hexanediol; 2,3-dimethyl-2,5-hexanediol; 2,4-di Methyl-2,5-hexanediol; 3,3-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 4-ethyl-1, 3-hexanediol; 3-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 4-methyl-1,3-heptanediol; 5-methyl- 1,3-heptanediol; 6-methyl-1,3-heptanediol; 3-methyl-1,5-heptanediol; 4-methyl-1,5-heptanediol; 3-methyl Base-1,6-heptanediol; 5-methyl-1,6-heptanediol; 5-methyl-2,4-heptanediol; 3-methyl-2,5-heptanediol; 2 -Methyl-3,5-heptanediol; 2,6-octanediol; 3,3,4-trimethyl-2,4-hexanediol; 3,5,5-trimethyl-2, 4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2,5-hexanediol; 3,3,5-trimethyl Base-2,5-hexanediol; B. Ether solvent selected from the following: 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol ; 3-(2-methyl-1-butoxy)-1,2-propanediol; 3-(isoamyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy )-1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy )-1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1- butoxy)-1,3-propanediol; 2-(isoamyloxy)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-( cyclohexyloxy)-1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; triethoxylated 3-(butoxy)-1,2 - propylene glycol; tetraethoxylated 3-(butoxy)-1,2-propanediol; pentaethoxylated 3-(butoxy)-1,2-propanediol; hexaethoxylated 3-(butoxy)-1,2-propanediol; -(butoxy)-1,2-propanediol; heptaethoxylated 3-(butoxy)-1,2-propanediol; octaethoxylated 3-(butoxy)-1,2 - propylene glycol; nonaethoxylated 3-(butoxy)-1,2-propanediol; monopropoxylated 3-(butoxy)-1,2-propanediol; dibutylideneoxylated 3 -(butoxy)-1,2-propanediol; and tributoxylated 3-(butoxy)-1,2-propanediol; bis(2-hydroxybutyl)ether; and bis(2-hydroxy C. Compounds which are homologues or analogues of the following compounds, wherein each homologue or analogue contains at least one additional _CH2 group, for each additional _CH2 group, by inserting One double bond, the total number of hydrogen atoms remains the same: I. n-propanol; II. 2-butanol and/or 2-methyl-2-propanol; III. 2,3-dimethyl-2,3-butanol Diol; 2,3-dimethyl-1,2-butanediol; 3,3-dimethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3- Methyl-2,3-pentanediol; 4-methyl-2,3-pentanediol; 2,3-hexanediol; 3,4-hexanediol; 2-ethyl-1,2-butane Diol; 2-methyl-1,2-pentanediol; 3-methyl-1,2-pentanediol; 4-methyl-1,2-pentanediol; and/or 1,2-hexane Diol; IV.2-butyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2-(1-methylpropyl)-1,3-propanediol; 2-( 2-methylpropyl)-1,3-propanediol; 2-methyl-2-propyl-1,3-propanediol; 2,3,3-trimethyl-1,2-butanediol; 2- Ethyl-2-methyl-1,4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-propyl-1,4-butanediol; 2-iso Propyl-1,4-butanediol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4-dimethyl -1,5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2 , 3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4 -pentanediol; 2-ethyl-1,5-pentanediol; 2-methyl-1,6-hexanediol; 3-methyl-1,6-hexanediol; 2-methyl-2 , 3-hexanediol; 3-methyl-2,3-hexanediol; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl -3,4-hexanediol; 3-methyl-3,4-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; and/or 1 , 6-heptanediol; V.2-(2-methylbutyl)-1,3-propanediol; 2-(1,1-dimethylpropyl)-1,3-propanediol; 2-(1 , 2-dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(1-methylbutyl)-1,3-propanediol; 2-(2,2-Dimethylpropyl)-1,3-propanediol; 2-(3-methylbutyl)-1,3-propanediol; 2-butyl-2-methyl-1,3 -Propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1,3-propanediol; 2-methyl-2-(1-methylpropyl )-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl-2-methyl-1,3-propanediol; 2,2 -Diethyl-1,3-butanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-butyl-1,3-butanediol; 2-ethyl- 2,3-Dimethyl-1,3-butanediol; 2-(1,1-dimethylethyl)-1,3-butanediol; 2-(2-methylpropyl)-1 , 3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 2-methyl-2-propyl-1,3-butanediol; 3-methyl-2 -Isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1,4-butanediol; 2-methyl 2-propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4 -Butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1-dimethylethyl)-1,4-butanediol; 2- (2-Methylpropyl)-1,4-butanediol; 2-methyl-3-propyl-1,4-butanediol; 3-methyl-2-isopropyl-1,4- Butanediol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol; 2,3,4-trimethyl- 1,3-pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3,4,4-trimethyl-1,3-pentanediol; 2,2,3- Trimethyl-1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 3, 3,4-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol Alcohol; 2,3,3-trimethyl-1,5-pentanediol; 2,3,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-2, 4-pentanediol; 2,3,4-trimethyl-2,4-pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methanol Base-1,3-pentanediol; 2-ethyl-4-methyl-1,3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl -2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5- Pentylene glycol; 2-ethyl-3-methyl-1,5-pentanediol; 2-ethyl-4-methyl-1,5-pentanediol; 3-ethyl-3-methyl- 1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol Diol; 2-isopropyl-1,4-pentanediol; 2-propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 2-isopropyl- 1,5-pentanediol; 3-propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexane Diol; 2,4-Dimethyl-1,3-hexanediol; 2,5-Dimethyl-1,3-hexanediol; 3,4-Dimethyl-1,3-hexanediol ; 3,5-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2 , 3-dimethyl-1,4-hexanediol; 2,4-dimethyl-1,4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3 -Dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,4-di Methyl-1,3-hexanediol; 4,5-dimethyl-1,4-hexanediol; 5,5-dimethyl-1,4-hexanediol; 2,2-dimethyl -1,5-hexanediol; 2,3-dimethyl-1,5-hexanediol; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1 ,5-hexanediol; 3,3-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5 -hexanediol; 4,5-dimethyl-1,5-hexanediol; 2,2-dimethyl-1,6-hexanediol; 2,3-dimethyl-1,6-hexanediol Diol; 2,4-Dimethyl-1,6-hexanediol; 2,5-Dimethyl-1,6-hexanediol; 3,3-Dimethyl-1,6-hexanediol ; 3,4-dimethyl-1,6-hexanediol; 2,3-dimethyl-2,4-hexanediol; 2,4-dimethyl-2,4-hexanediol; 2 , 5-dimethyl-2,4-hexanediol; 3,3-dimethyl-2,4-hexanediol; 3,4-dimethyl-2,4-hexanediol; 3,5 -Dimethyl-2,4-hexanediol; 4,5-dimethyl-2,4-hexanediol; 5,5-dimethyl-2,4-hexanediol; 2,3-di Methyl-2,5-hexanediol; 2,4-dimethyl-2,5-hexanediol; 2,5-dimethyl-2,5-hexanediol; 3,3-dimethyl -2,5-hexanediol; 3,4-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 2-ethyl-1,3- Hexylene glycol; 4-ethyl-1,3-hexanediol; 2-ethyl-1,4-hexanediol; 4-ethyl-1,4-hexanediol; 2-ethyl-1, 5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl- 1,3-heptanediol; 3-methyl-1,3-heptanediol; 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl Base-1,3-heptanediol; 2-methyl-1,4-heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol; 5 -Methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol ; 4-methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 6-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol Diol; 3-methyl-1,6-heptanediol; 4-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 6-methyl-1,6 -Heptanediol; 2-methyl-2,4-heptanediol; 3-methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2 , 4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl -2,5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3- Methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; and/or 3,6-octanediol; VI. 2,3,3,4-tetramethyl-2,4-pentanediol; 3 - tert-butyl-2,4-pentanediol; 2,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2,4-hexanediol; 3 , 3,5-trimethyl-2,4-hexanediol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexane Diol; 3,3,4-Trimethyl-2,5-Hexanediol; and/or 3,3,5-Trimethyl-2,5-Hexanediol; VII.C _3-8 Diol Alkoxylated derivatives, including: 1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1,2-propanediol (C3)PO ₄ ; 2-methyl-1,2-propanediol (C4) (Me-E _{4- 10} ); 2-methyl-1,2-propanediol (C4) 2 (Me-E ₁ ); 2-methyl-1,2-propanediol (C4)PO ₃ ; 2-methyl-1,2-propanediol (C4)BO ₁ ; 1,3-propanediol (C3)2(Me-E _6-8 ); 1,3-propanediol (C3)PO _5-6 ; 2,2-diethyl-1,3-propanediol (C7) E _1-7 ; 2,2-diethyl-1,3-propanediol (C7)PO ₁ ; 2,2-diethyl-1,3-propanediol (C7)n-BO _1-2 ; 2,2-dimethyl-1,3-propanediol (C5) 2 (MeE _1-2 ); 2,2-dimethyl-1,3-propanediol (C5)PO _3-4 ; 2-(1- Methylpropyl)-1,3-propanediol (C7) E _1-7 ; 2-(1-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methylpropyl )-1,3-propanediol (C7)n-BO _1-2 ; 2-(2-methylpropyl)-1,3-propanediol (C7)E _1-7 ; 2-(2-methylpropyl )-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1,3-propanediol (C7)n-BO _1-2 ; 2-ethyl-1,3-propanediol ( C5)(MeE _6-10 ); 2-Ethyl-1,3-propanediol (C5)2( _MeE1 ); 2-Ethyl-1,3-propanediol (C5)PO3; 2-Ethyl- ₂ -Methyl-1,3-propanediol (C6) (MeE _1-6 ); 2-Ethyl-2-methyl-1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl- 1,3-propanediol (C6)BO ₁ ; 2-isopropyl-1,3-propanediol (C6) (MeE _1-6 ); 2-isopropyl-1,3-propanediol (C6)PO ₂ ; 2 -Isopropyl-1,3-propanediol (C6)BO ₁ ; 2-methyl-1,3-propanediol (C4)2(MeE _2-5 ); 2-methyl-1,3-propanediol (C4) PO _4-5 ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)E _2-9 ; 2-methyl- 2-isopropyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)n-BO _1-3 ; 2-methyl-2- Propyl-1,3-propanediol (C7) E _1-7 ; 2-methyl-2-propyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-propyl-1,3 -Propylene glycol (C7)n-BO _1-2 ; 2-Propyl-1,3-propanediol (C6) (MeE _1-4 ); 2-Propyl-1,3-propanediol (C6)PO ₂ ; 2- Propyl-1,3-propanediol (C6) _BO1 ; 2. 1,2-butanediol (C4) 2 (Me-E _2-8 ); 1,2-butanediol (C4)PO _2-3 ; 1,2-butanediol (C4)BO ₁ ; 2,3-Dimethyl-1,2-butanediol (C6)E _1-6 ; 2,3-Dimethyl-1,2-butanediol (C6)n-BO _1-2 ; 2- Ethyl-1,2-butanediol (C6) E _1-3 ; 2-ethyl-1,2-butanediol (C6)n-BO ₁ ; 2-methyl-1,2-butanediol (C5)(Me-E _1-2 ); 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _{1 -6} ; 3,3-dimethyl-1,2-butanediol (C6)n-BO _{1- 2} ; 3-methyl-1,2-butanediol (C5) (MeE _1-2 ); 3-Methyl-1,2-butanediol (C5)PO ₁ ; 1,3-butanediol (C4) 2 (MeE _3-6 ); 1,3-butanediol (C4)PO ₅ ; 1 , 3-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,3-butanediol (C7) (MeE _1-3 ); 2,2,3-trimethyl-1 , 3-butanediol (C7)PO _1-2 ; 2,2-dimethyl-1,3-butanediol (C6) (MeE _3-8 ); 2,2-dimethyl-1,3 -Butanediol (C6)PO ₃ ; 2,3-Dimethyl-1,3-butanediol (C6) (MeE _3-8 ); 2,3-Dimethyl-1,3-butanediol (C6)PO ₃ ; 2-ethyl-1,3-butanediol (C6) (MeE _1-6 ); 2-ethyl-1,3-butanediol (C6)PO _2-3 ; 2- Ethyl-1,3-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,3-butanediol (C7) (MeE ₁ ); 2-Ethyl-2-methyl -1,3-butanediol (C7)PO ₁ ; 2-ethyl-2-methyl-1,3-butanediol (C7)n-BO _2-4 ; 2-ethyl-3-methyl -1,3-butanediol (C7)(MeE ₁ ); 2-ethyl-3-methyl-1,3-butanediol (C7)PO ₁ ; 2-ethyl-3-methyl-1 , 3-butanediol (C7) n-BO _2-4 ; 2-isopropyl-1,3-butanediol (C7) (MeE ₁ ); 2-isopropyl-1,3-butanediol (C7)PO ₁ ; 2-isopropyl-1,3-butanediol (C7)n-BO _2-4 ; 2-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ); 2-methyl-1,3-butanediol (C5)PO ₄ ; 2-propyl-1,3-butanediol (C7)E _2-9 ; 2-propyl-1,3-butane Diol (C7) PO ₁ ; 2-propyl-1,3-butanediol (C7)n-BO _1-3 ; 3-methyl-1,3-butanediol (C5) 2 (MeE _{1- 3} ); 3-methyl-1,3-butanediol (C5)PO ₄ ; 1,4-butanediol (C4) 2 (MeE _2-4 ); 1,4-butanediol (C4)PO _4-5 ; 1,4-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,4-butanediol (C7)E _2-9 ; 2,2,3-trimethyl Base-1,4-butanediol (C7)PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _1-3 ; 2,2-dimethyl- 1,4-butanediol (C6) (MeE _1-6 ); 2,2-dimethyl-1,4-butanediol (C6)PO ₂ ; 2,2-dimethyl-1,4- Butanediol (C6) BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _{1- 6} ); 2,3-dimethyl-1,4-butanediol ( C6) PO ₂ ; 2,3-dimethyl-1,4-butanediol (C6)BO ₁ ; 2-ethyl-1,4-butanediol (C6) (MeE _{1 -4} ); 2- Ethyl-1,4-butanediol (C6)PO ₂ ; 2-Ethyl-1,4-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol Alcohol (C7) E _1-7 ; 2-Ethyl-2-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol ( C7) n-BO _1-2 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)E _1-7 ; 2-Ethyl-3-methyl-1,4-butanediol Alcohol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,4-butanediol (C7)n-BO _1-2 ; 2-isopropyl-1,4-butanediol (C7) E _1-7 ; 2-isopropyl-1,4-butanediol (C7)PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO _1-2 ; 2-form Base-1,4-butanediol (C5)(MeE _6-10 ); 2-Methyl-1,4-butanediol (C5)2(MeE ₁ ); 2-Methyl-1,4-butane Diol (C5)PO ₃ ; 2-methyl-1,4-butanediol (C5)BO ₁ ; 2-propyl-1,4-butanediol (C7)E _{1 -5} ; 2-propyl -1,4-butanediol (C7) n-BO _1-2 ; 3-ethyl-1-methyl-1,4-butanol (C7) E _2-9 ; 3-ethyl-1-methyl Base-1,4-butanediol (C7)PO ₁ ; 3-ethyl-1-methyl-1,4-butanediol (C7)n-BO _1-3 ; 2,3-butanediol ( C4) (MeE _6-10 ); 2,3-butanediol (C4) 2 (MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-dimethyl-2,3-butanediol (C6)E _3-9 ; 2,3-dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3 -Dimethyl-2,3-butanediol (C6)n-BO _1-3 ; 2-methyl-2,3-butanediol (C5)(MeE _1-5 ); 2-Methyl-2 , 3-butanediol (C5) PO ₂ ; 2-methyl-2,3-butanediol (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol (C5) n-BO _2-3 ; 2-methyl Base-1,2-pentanediol (C6) E _{1- 3} ; 2-methyl-1,2-pentanediol (C6)n-BO ₁ ; 2-methyl-1,2-pentanediol ( C6)BO ₁ ; 3-methyl-1,2-pentanediol (C6)E _1-3 ; 3-methyl-1,2-pentanediol (C6)n-BO ₁ ; 4-methyl- 1,2-pentanediol (C6) E _1-3 ; 4-methyl-1,2-pentanediol (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (MeE _{1- 2} ); 1,3-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,3-pentanediol (C7) (MeE ₁ ); 2,2-dimethyl-1 , 3-pentanediol (C7) PO ₁ ; 2,2-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,3-pentane Diol (C7) (Me-E ₁ ); 2,3-dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,3-pentanediol (C7 )n-BO _2-4 ; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 2,4-dimethyl-1,3-pentanediol (C7 )PO ₁ ; 2,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2-ethyl-1,3-pentanediol (C7)E _2-9 ; 2 -Ethyl-1,3-pentanediol (C7)PO ₁ ; 2-Ethyl-1,3-pentanediol (C7)n-BO _1-3 ; 2-methyl-1,3-pentanediol Alcohol (C6) 2 (MeE _1-6 ); 2-methyl-1,3-pentanediol (C6)PO _2-3 ; 2-methyl-1,3-pentanediol (C6)BO ₁ ; 3,4-Dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 3,4-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4- Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 3-methyl-1,3-pentanediol (C6)(Me-E _1-6 ); 3-methyl- 1,3-pentanediol (C6)PO _2-3 ; 3-methyl-1,3-pentanediol (C6)BO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7 )(Me-E ₁ ); 4,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 4-methyl-1,3-pentanediol (C6) (MeE _1-6 ); 4-methyl-1,3-pentanediol (C6)PO _2-3 ; 4-methyl -1,3-pentanediol (C6)BO ₁ ; 1,4-pentanediol (C5) 2 (MeE _{1- 2} ); 1,4-pentanediol (C5)PO _3-4 ; 2,2 - Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,2-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,2-Dimethyl -1,4-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,3-dimethyl -1,4-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2,4-dimethyl-1,4 - Pentanediol (C7) (Me-E ₁ ); 2,4-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2-methyl-1,4-pentanediol (C6) (MeE _1-6 ); 2-methyl-1,4-pentanediol (C6)PO _{2- 3} ; 2-methyl-1,4-pentanediol (C6)BO ₁ ; 3,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,3-di Methyl-1,4-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 3,4-Dimethyl-1 , 4-pentanediol (C7) (Me-E ₁ ); 3,4-dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,4-pentane Diol (C7) n-BO _2-4 ; 3-methyl-1,4-pentanediol (C6) 2 (Me-E _1-6 ); 3-methyl-1,4-pentanediol ( C6)PO _{2 -3} ; 3-methyl-1,4-pentanediol (C6)BO ₁ ; 4-methyl-1,4-pentanediol (C6)2(Me-E _1-6 ); 4-methyl-1,4-pentanediol (C6)PO _2-3 ; 4-methyl-1,4-pentanediol (C6)BO ₁ ; 1,5-pentanediol (C5)(Me -E _4-10 ); 1,5-pentanediol (C5) 2 (MeE ₁ ); 1,5-pentanediol (C5)PO ₃ ; 2,2-dimethyl-1,5-pentanediol Alcohol (C7) E _1-7 ; 2,2-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-Dimethyl-1,5-pentanediol (C7)n- BO _1-2 ; 2,3-dimethyl-1,5-pentanediol (C7) E _1-7 ; 2,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2 , 3-dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2,4-dimethyl-1,5-pentanediol (C7)E _1-7 ; 2,4 -Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2-Ethyl-1, 5-pentanediol (C7) E _1-5 ; 2-ethyl-1,5-pentanediol (C7) n-BO _1-2 ; 2-methyl-1,5-pentanediol (C6) (Me-E _1-4 ); 2-methyl-1,5-pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _1-7 ; 3,3-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 3-methyl -1,5-pentanediol (C6) (Me-E _1-4 ); 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) (Me -E _1-3 ); 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6)E _1-7 ; 2-methyl-2,3-pentane Diol (C6) PO ₁ ; 2-methyl-2,3-pentanediol (C6) n-BO _1-2 ; 3-methyl-2,3-pentanediol (C6) E _1-7 ; 3-methyl-2,3-pentanediol (C6)PO ₁ ; 3-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 4-methyl-2,3-pentane Diol (C6) E _1-7 ; 4-methyl-2,3-pentanediol (C6)PO ₁ ; 4-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 2,4-pentanediol (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol (C7 )(Me-E _1-4 ); 2,3-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-dimethyl-2,4-pentanediol (C7)( Me-E _1-4 ); 2,4-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2-methyl-2,4-pentanediol (C7) (Me-E _{5- 10} ); 2-methyl-2,4-pentanediol (C7)PO ₃ ; 3,3-dimethyl-2,4-pentanediol (C7) (Me-E _1-4 ); 3, 3-Dimethyl-2,4-pentanediol (C7)PO ₂ ; 3-methyl-2,4-pentanediol (C6) (Me-E _5-10 ); 3-methyl-2, 4-pentanediol (C6) _PO3 ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _2-9 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _1-3 ; 2-methyl-1,3-hexanediol (C7)BO ₁ ; 3-methyl-1,3-hexanediol (C7)E _2-9 ; 3-methyl- 1,3-hexanediol (C7)PO ₁ ; 3-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,3-hexanediol (C7) E _2-9 ; 4-methyl-1,3-hexanediol (C7)PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 5-methyl- 1,3-hexanediol (C7)E _2-9 ; 5-methyl-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n- BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7) E _2-9 ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 3-methyl-1,4-hexanediol (C7)E _2-9 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3- Methyl-1,4-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,4-hexanediol (C7)E _2-9 ; 4-methyl-1,4-hexane Diol (C7) PO ₁ ; 4-methyl-1,4-hexanediol (C7) n-BO _1-3 ; 5-methyl-1,4-hexanediol (C7) E _2-9 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _1-1 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6)PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7) E _2-9 ; 2-methyl-1,5-hexanediol (C7)PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _1-5 ; 3-methyl- 1,5-hexanediol (C7)E _2-9 ; 3-methyl-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n- BO _1-3 ; 4-methyl-1,5-hexanediol (C7)E _2-9 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1, 5-hexanediol (C7)n-BO _1-3 ; 5-methyl-1,5-hexanediol (C7)E _2-9 ; 5-methyl-1,5-hexanediol (C7) PO ₁ ; 5-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 1,6-hexanediol (C6)(Me-E _1-2 ); 1,6-hexanediol Alcohol (C6) PO _1-2 ; 1,6-Hexanediol (C6) n-BO ₄ ; 2-Methyl-1,6-Hexanediol (C7) E _1-5 ; 2-Methyl-1 , 6-hexanediol (C7) n-BO _1-2 ; 3-methyl-1,6-hexanediol (C7) E _1-5 ; 3-methyl-1,6-hexanediol (C7 )n-BO _1-2 ; 2,3-hexanediol (C6)E _1-5 ; 2,3-hexanediol (C6)n-BO ₁ ; 2,3-hexanediol (C6)BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6)PO ₃ ; 2-methyl-2,4-hexanediol (C7) (Me -E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4-hexanediol (C7)(Me-E _1-2 ) ; 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 4-methyl- 2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _1-2 ); 5-methyl-2,4-hexanediol Alcohol (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-Methyl-2,5- Hexylene glycol (C7) (Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol (C6)EO _1-5 ; 3,4-hexanediol Alcohol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-Heptanediol (C7) E _1-7 ; 1,3-Heptanediol (C7)PO ₁ ; 1,3-Heptanediol (C7)n-BO _1-2 ; 1,4 -Heptanediol (C7) E _1-7 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO _1-2 ; 1,5-Heptanediol ( C7)E _1-7 ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO _1-2 ; 1,6-heptanediol (C7)E _{1- 7} ; 1,6-heptanediol (C7)PO ₁ ; 1,6-heptanediol (C7)n-BO _1-2 ; 1,7-heptanediol (C7)E _1-2 ; 1,7 -Heptanediol (C7)n-BO ₁ ; 2,4-Heptanediol (C7)E _3-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol Alcohol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me- E ₁ ); 2,5-heptanediol (C7)PO ₁ ; 2,5-heptanediol (C7)n-BO ₃ ; 2,6-heptanediol (C7)E _3-10 ; 2,6 - Heptanediol (C7) (Me-E ₁ ); 2,6-Heptanediol (C7)PO ₁ ; 2,6-Heptanediol (C7)n-BO ₃ ; 3,5-Heptanediol ( C7)E _3-10 ; 3,5-heptanediol (C7)(Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ; 6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 - Isopropyl-1,3-butanediol (C8) n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8) n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl-2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptane Diol (C8)n- _BO1 ; 3-methyl-2,4-heptanediol (C8)n- _BO1 ; 4-methyl-2,4-heptanediol (C8)n- _BO1 ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl-2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptane Diol (C8)n- _BO1 ; 3-methyl-2,5-heptanediol (C8)n- _BO1 ; 4-methyl-2,5-heptanediol (C8)n- _BO1 ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl-2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptane Diol (C8)n- _BO1 ; 3-methyl-2,6-heptanediol (C8)n- _BO1 ; 4-methyl-2,6-heptanediol (C8)n- _BO1 ; 2-Methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)E _1-3 ; 2-Ethylene Base-2,3-dimethyl-1,3-butanediol (C8) E _1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8) E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8) E _1-3 ; 5-methyl-2,5-heptanediol (C8) E _1-3 ; 6-methyl-2,5-heptanediol (C8) E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; 7. Their mixtures; and VIII. Aromatic diols including the following: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2- Propylene glycol; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3-propanediol; 2-methylphenyl Base-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol Alcohols; 2-phenyl-1,4-butanediol; and/or 1-phenyl-2,3-butanediol; and mixtures thereof; and IX. mixtures thereof; The following specific compounds are exceptions: 2,7-dimethyl-3,7-octadiene-2,5-diol; 3,5-dimethyl-4,6-octadiene-1,2 -diol; 3,5-dimethyl-4,6-octadiene-1,2-diol; 3,5-dimethyl-4,6-octadiene-1,2-diol; 3,5-Dimethyl-4,6-octadiene-1,2-diol; 3,5-dimethyl-4,6-octadiene-1,2-diol; 5,5- Dimethyl-1-hexene-3,4-diol; 4-methyl-6-heptene-1,4-diol; 4-octene-3,6-diol; 4-octene- 3,6-diol; 3-octene-1,2-diol; 3-nonene-2,5-diol; 7-nonene-4,5-diol; 7-nonene-4, 5-diol; 6-nonene-2,3-diol; 5-methyl-6-heptene-2,4-diol; 7-methyl-3-methylene-6-octene- 1,2-diol; 2,6-dimethyl-2,7-octadiene-1,6-diol; 2-(2-methylenepentyl)-1,3-propanediol; 2, 6-Dimethyl-3-heptene-2,6-diol; 2,6-dimethyl-3-heptene-2,6-diol; 3,5-dimethyl-5-hexene -2,4-diol; 2,5-dimethyl-4-hexene-1,2-diol; 2,5-dimethyl-4-hexene-1,2-diol; 7- Octene-1,6-diol; 2,5-Dimethyl-2-hexene-1,4-diol; 2,5-Dimethyl-2-hexene-1,4-diol; 5-methyl-2-methylene-1,4-hexanediol; 4-octene-2,3-diol; nonene-1,4-diol; 4-methyl-6-heptene -1,4-diol; 4-methyl-6-octene-3,5-diol; 2,6-dimethyl-2,6-octadiene-1,8-diol; (8 -hydroxygeraniol); 2,4-dimethyl-1-heptene-3,5-diol; 5-methyl-3-methylene-2,4-hexanediol; 5-methyl -3-methylene-2,4-hexanediol; 3-vinyl-2,5-dimethyl-5-hexene-2,4-diol; 3-vinyl-2,5-diol Methyl-5-hexene-2,4-diol; 5-methyl-6-heptene-2,4-diol; 4,9-decadiene-1,8-diol; 2,4 -Dimethyl-5-hexene-1,3-diol; 2-methyl-7-octene-1,3-diol; 2,6-dimethyl-5-heptene-3-d -1,2-diol; 2,6-dimethyl-5-heptene-3-d-1,2-diol; 4-nonene-2,8-diol; 4-nonene-2 ,8-diol; 2,3-dimethyl-5-hexene-2,3-diol; 2-butyl-2-butene-1,4-diol; 3-(1,1- Dimethylethyl)-2,4-hexadiene-1,6-diol; 7-methyl-6-octene-1,4-diol; 5,6-dimethyl-6-heptene ene-1,4-diol; 5,6-dimethyl-6-heptene-1,4-diol; 7-methyl-7-octene-2,5-diol; 7-methyl -7-octene-2,5-diol; 2,4-dimethyl-4-hexene-1,3-diol; 4-octene-2,7-diol; 4-octene- 2,7-diol; 5-methyl-3-heptene-1,2-diol; 5-methyl-3-heptene-1,2-diol; 2,6-dimethyl-3 , 7-octadiene-2,6-diol; 8-nonene-1,7-diol; 3,7-dimethyl-2,6-octadiene-1,4-diol (Isorosiridol ); 2,4-dimethyl-5-hexene-1,4-diol; 6-methyl-1-heptene-3,4-diol; 4,6-dimethyl-3-heptene ene-1,5-diol; 4-methyl-3-octene-1,5-diol; 3,9-decadiene-1,2-diol; 2-methyl-7-octene -2,3-diol; 2-methyl-7-octene-2,3-diol; 6-nonene-2,3-diol; 3-methyl-4-methylene-2, 5-hexanediol; 2-methyl-6-heptene-1,4-diol; 6-octene-1,5-diol; 1-octene-3,4-diol; Base-7-octene-1,6-diol; 5-methyl-7-octene-1,6-diol; 2-methyl-2-(1-methylvinyl)-1,3 -Butanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 4-methylene-3,5-octanediol; 4-methylene-3,5- Octanediol; 2-methyl-6-heptene-2,3-diol; 2,6-dimethyl-6-heptene-2,3-diol; 2-methyl-6-heptene -2,3-diol; 4-methyl-7-octene-1,3-diol; 2-methyl-2-(1-methyl-2-propenyl)-1,3-butanediol Alcohol; 2,6-Dimethyl-5-heptene-1,2-diol; 1-nonene-3,4-diol; 3-methyl-5-heptene-1,2-diol ; 2,6-Dimethyl-3,7-octadiene-2,6-diol; 2,2-Dimethyl-6-heptene-1,3-diol; 4-nonene-1 , 3-diol; 3-methyl-2-(2-propenyl)-1,4-pentanediol; 1-nonene-3,4-diol; 8-nonene-1,2-diol Alcohol; 3-octene-1,2-diol; 1,9-decadiene-4,6-diol; 1,9-decadiene-4,6-diol; 2,2-dimethyl 2-(1-pentenyl)-1,3-propanediol; 2-(3-methyl-1-butenyl)-1,3-propanediol ; 2-(3-methyl-1-butenyl)-1,3-propanediol; 8-nonene-1,3-diol; 2,7-dimethyl-2,4-octadiene- 1,8-diol; 6-methyl-5-heptene-1,2-diol; 3,9-decadiene-1,2-diol; 3-nonene-1,2-diol ; 6-nonene-1,2-diol; 2,4-dimethyl-4-hexene-1,3-diol; 3,7-dimethyl-2,4-octadiene-1 ,7-diol; 3,4-dimethyl-4-hexene-2,3-diol; 3,4-dimethyl-4-hexene-2,3-diol; 3,4- Dimethyl-4-hexene-2,3-diol; 3,4-dimethyl-4-hexene-2,3-diol; 3,4-dimethyl-5-hexene-2 ,3-diol; 3,4-dimethyl-5-hexene-2,3-diol; 3,4-dimethyl-5-hexene-2,3-diol; 2-methyl -2-(2-propenyl)-1,3-butanediol; 4,6-dimethyl-6-heptene-2,5-diol; 6-methyl-6-heptene-1, 5-diol; 4,6-dimethyl-6-heptene-2,5-diol; 2-(2-propenyl)-1,5-pentanediol; 3,5-dimethyl- 5-Hexene-2,3-diol; 3,5-Dimethyl-5-hexene-2,3-diol; Nonanediol; Octanediol; 3,5-Dimethyl-5- Hexene-1,3-diol; 4-nonene-1,8-diol; 4-nonene-1,7-diol; 4-nonene-1,6-diol; 6-nonene -1,4-diol; 2-nonene-1,4-diol; 8-nonene-2,5-diol; 2-vinyl-6-methyl-5-heptene-1,2 -diol; 2,5-dimethyl-4-hexene-2,3-diol; 2,6-dimethyl-5-heptene-2,3-diol; 2,6-dimethyl Dimethyl-1-heptene-3,5-diol; 2,6-dimethyl-1-heptene-3,5-diol; 7-methyl-7-octene-1,3-diol ; 2-methyl-2-(3-methyl-3-butenyl)-1,3-propanediol; 2,6-dimethyl-5-heptene-1,2-diol; 2,6 -Dimethyl-5,7-octadiene-2,3-diol; 2,6-dimethyl-5,7-octadiene-2,3-diol; 2-ethyl-5- Hexene-1,2-diol; 6-methyl-2,4-nonadiene-4-d-1,7-diol; 6-methyl-2,4-nonadiene-1,6 , 7-d3-1,7-diol; 6-methyl-2,4-nonadiene-1,7-diol; 2-methyl-6-methylene-7-octene-2, 3-diol; 3-methyl-2-(4-pentenylene)-1,3-butanediol; 3-methyl-2-(4-pentenylene)-1,3-butane Diol; 5,5-dimethyl-2-hexene-1,4-diol; 5,5-dimethyl-2-hexene-1,4-diol; 2-nonene-1, 4-diol; 2-nonene-1,4-diol; 2-methyl-6-methylene-7-octene-2,3-diol; 5-octene-1,3-diol Alcohol; 2-methyl-7-octene-1,3-diol; 2-methyl-4-heptene-1,3-diol; 4-octene-2,3-d2-1,2 -diol; 4-octene-2,3-d2-1,2-diol; 3-methyl-5-heptene-1,2-diol; 5-octene-1,2-diol ;2,6-Dimethyl-3,7-octadiene-1,6-diol; 2,6-Dimethyl-5-heptene-1,2-diol; 4,5-dimethyl Base-1,7-octadiene-4,5-diol; 4,5-dimethyl-1,7-octadiene-4,5-diol; 2-methyl-5-heptene- 1,3-diol; 2-methyl-5-heptene-1,3-diol; 3,4-dimethyl-3-hexene-1,6-diol; 3,4-dimethyl Base-3-hexene-1,6-diol; 2,6-dimethyl-2,6-octadiene-1-t-1,8-diol; 2,6-dimethyl-2 , 6-octadiene-1-t-1,8-diol; 2,6-dimethyl-2,6-octadiene-1-d-1,8-diol; 2,6-diol Methyl-2,6-octadiene-1-d-1-t-1,8-diol; 2,6-dimethyl-2,6-octadiene-1-d-1-t- 1,8-diol; 2,6-dimethyl-2,6-octadiene-1-d-1,8-diol; 6-methyl-2-heptene-1,5-diol ; 6-methyl-2-heptene-1,5-diol; 8,9-decadiene-3,5-diol; 8,9-decadiene-3,5-diol; 8- Methyl-4,6-nonadiene-1,3-diol; 8-methyl-3,5-nonadiene-1,7-diol; 2,4-dimethyl-5-heptene -1,3-diol; 2-nonene-1,9-diol; 2-nonene-1,9-diol; 2-ethyl-2-(2-propenyl)-1,3- Butanediol; 6-methyl-3-heptene-1,5-diol; 2-vinyl-4-methyl-1,3-pentanediol; 2-vinyl-4-methyl-1 , 3-pentanediol; 3,4-dimethyl-5-hexene-2,3-diol; 2,3,4-trimethyl-5-hexene-2,3-diol; 2 , 3,3-trimethyl-4-pentene-1,2-diol; 2-(2-methyl-2-propenyl)-2-(2-propenyl)-1,3-propanediol; 2-(2-butenyl)-2-(2-propenyl)-1,3-propanediol; 2-ethyl-5-hexene-1,2-diol; 2-(4-methyl- 3-pentenylene)-1,4-butanediol; (β-Acaridiol); 2-methyl-6-heptene-1,3-diol; 2,6-dimethyl-2,6 -octadiene-1,8-diol-2-13C; 5,5-dimethyl-1-hexene-3,4-diol; 5,5-dimethyl-1-hexene-3 ,4-diol; 1-nonene-3,4-diol; 8-nonene-2,4-diol; 8-nonene-2,4-diol; 2-methyl-7-octane ene-1,2-diol; 1-nonene-3,5-diol; 2,6-dimethyl-2,7-octadiene-1,6-diol; 7-octene-1 , 2-diol; 7-octene-1,2-diol; 3,7-dimethyl-2,5-octadiene-1,7-diol; 2-(2,2-dimethyl propylene)-1,3-propanediol; 7-methyl-3-methylene-6-octene-1,2-diol; 2,8-decadiene-1,10-diol; 7-methyl-6-octene-1,5-diol; 2-(1-ethyl-1-propenyl)-1,3-butanediol; 4-ethyl-3-methyl-4 -Hexene-1,2-diol; 8-nonene-1,3-diol; 2-(3-methyl-2-butenyl)-3-methylene-1,4-butanediol Alcohol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol Alcohol; 8-nonene-2,4-diol; 4-methylene-2,6-heptanediol; 2,5-dimethyl-3-hexene-3,4-diol; 4- Octene-4,5-diol; 2,3-dimethyl-5-hexene-1,2-diol; 2-vinyl-2,5-dimethyl-3-hexene-1, 6-diol; 2,4-dimethyl-3-hexene-1,5-diol; 2,4-dimethyl-3-hexene-1,5-diol; 2,6-diol Methyl-3,7-octadiene-2,6-diol; 3,7-dimethyl-3,6-octadiene-1,2-diol; 6-methyl-7-octene -2,3-diol; 6-methyl-7-octene-2,3-diol; 6-methyl-7-octene-2,3-diol; 3,7-dimethyl- 2,5-octadiene-1,7-diol; 7-methyl-6-octene-1,3-diol; decadiene-diol; 2,3-dimethyl-6-heptene -1,2-diol; 3,5-dimethyl-4-hexene-1,3-diol; 2-(1,1-dimethylethyl)-4-pentene-1,3 -diol; 2-(1,1-dimethylethyl)-4-pentene-1,3-diol; 6,6-dimethyl-1-heptene-3,5-diol; 6,6-Dimethyl-1-heptene-3,5-diol; 5-methyl-4-methylene-1,3-hexanediol; 4-octene-1,2-diol ; 3-vinyl-2,3-heptanediol; 3-vinyl-2,3-heptanediol; 2,4-dimethyl-5-heptene-1,3-diol; 2,4 -Dimethyl-5-hexene-1,3-diol; 2,4-dimethyl-5-hexene-1,3-diol; 3,7-dimethyl-2,6-octane Diene-1-t-1,8-diol; 8-nonene-2,4-diol; 8-nonene-2,4-diol; 2-methylene-1,3-octanediol Alcohol; 8-nonene-1,3-diol; 3,6-dimethyl-5-heptene-1,4-diol; 2,6-dimethyl-5-heptene-1,4 -diol; 4-octene-2,3-diol; 4-octene-2,3-diol; 2,7-dimethyl-5,7-octadiene-1,4-diol ; 7-methyl-7-octene-1,3-diol; 5-ethyl-2-heptene-1,5-diol; 5-ethyl-2-heptene-1,5-diol Alcohol; 2-vinyl-3-ethyl-1,3-pentanediol; 2,3-dimethyl-5-heptene-2,4-diol; 2,3-dimethyl-5- Heptene-2,4-diol; 8-nonene-3,4-diol; 8-nonene-3,4-diol; 4,5-dimethyl-5-hexene-1,3 -diol; 4,5-dimethyl-5-hexene-1,3-diol; 3,7-dimethyl-4,6-octadiene-2,3-diol; 2,2 -Diallyl-1,3-butanediol; 1,9-decadiene-3,8-diol; 5,6-dimethyl-2-heptene-1,4-diol; 5 -Methyl-2-heptene-1,4-diol; 5,6-dimethyl-2-heptene-1,4-diol; 5-methyl-2-heptene-1,4- Diol; 2,8-decadiene-5,6-diol; 2,6-dimethyl-2,7-octadiene-1,6-diol (8-hydroxylinalool); 2 -Methyl-6-heptene-1,2-diol; 2,3-dimethyl-5-hexene-1,3-diol; 6-methyl-2-(methyl-13C)- 2,6-octadiene-1,8-diol; 2-(5-hexenyl)-1,3-propanediol; 8-nonene-3,4-diol; 3-ethyl-5- Hexene-1,3-diol; 7-octene-3,4-diol; 2-methyl-6-heptene-1,2-diol; 4-(2-propenyl)-6- Heptene-2,4-diol; 3,7-dimethyl-2,6-octadiene-1,4-diol (Rosiridol); 8-nonene-3,4-diol; 6- Methyl-6-heptene-2,3-diol; 2,6-dimethyl-6-heptene-2,3-diol; 2,5-dimethyl-4-hexene-2, 3-diol; 2,6-dimethyl-4,6-octadiene-2,3-diol; 2-methyl-6-methylene-7-octene-2,3-diol ;6-methyl-7-octene-2,3-diol; 2,6-dimethyl-4,6-octadiene-2,3-diol; 6-methyl-5-methylene Base-1,4-heptanediol; 2-(4-methyl-3-pentenyl)-2-butene-1,4-diol (α-Acaridiol); 4-octene-1,2 -diol; 4-octene-1,2-diol; 7-octene-2,4-diol; 3-methyl-6-heptene-2,4-diol; 3-methyl- 6-heptene-2,4-diol; 2,4-dimethyl-3-heptene-2,5-diol; 2-(3-methyl-2-butenyl)-1,3 -Butanediol; 2-methyl-7-octene-3,5-diol; 2-methyl-7-octene-3,5-diol; 5,5-dimethyl-6-heptene ene-2,4-diol; 5,5-dimethyl-6-heptene-2,4-diol; 2-methyl-2-(2-methylallyl)-1,3- Propylene glycol; 6-methyl-2-heptene-1,6-diol; 2-allyl-3-methyl-1,3-butanediol; 2-nonene-1,4-diol; 4-vinyl-2,5-dimethyl-5-hexene-2,3-diol; 4-vinyl-2,5-dimethyl-5-hexene-2,3-diol; 2-nonene-1,4-diol; 3,6-dimethyl-5-heptene-1,3-diol; 2-(1-methylvinyl)-1,5-hexanediol and 2-(1-pentenyl)-1,3-propanediol; and D. Mixtures of the above compounds; and E. A mixture of eight-carbon-diol isomers consisting essentially of the following compounds: 2,2,4-trimethyl-1,3-pentanediol; 2-ethyl-1,3-hexanediol ; 2,2-dimethyl-1,3-hexanediol; 2-ethyl-4-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol Diol; 3,5-octanediol; 2,2-dimethyl-2,4-hexanediol; 2-methyl-3,5-heptanediol; and/or 3-methyl-3, 5-Heptanediol, any single 1,3-diol is present in less than about 90% of any mixture. 2. The substance of claim 1, which is a compound selected from the group consisting of 2,3,3-trimethyl-1,2-butanediol; 2,3-dimethyl-3,4-pentanediol ; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl-3,4-hexanediol; 2,3-dimethyl-3, 4-pentanediol; 2-(1,1-dimethylpropyl)-1,3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(2 , 2-dimethylpropyl)-1,3-propanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-ethyl-2,3-dimethyl-1, 3-butanediol; 2-(2-methylpropyl)-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2 -Isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1,4-butanediol; 2-methyl 2-propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4 -Butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(2-methylpropyl)-1,4-butanediol; 2,2,3 - Trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2 , 3,3-trimethyl-1,5-pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol Diol; 2-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1 , 4-pentanediol; 3-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-4- Methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1, 3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 3-propane Base-2,4-pentanediol; 2,3-dimethyl-1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl- 1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1, 4-hexanediol; 2,3-dimethyl-1,4-hexanediol; 2,4-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4- Hexylene glycol; 3,4-dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,4-dimethyl-1,3-hexanediol Alcohol; 4,5-dimethyl-1,4-hexanediol; 2,2-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 2,3-dimethyl-1,6-hexanediol; 2, 4-Dimethyl-1,6-hexanediol; 3,3-dimethyl-1,6-hexanediol; 4,5-dimethyl-2,4-hexanediol; 2,3- Dimethyl-2,5-hexanediol; 2,4-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,5-hexanediol; 3,3-dimethyl Base-2,6-hexanediol; 4-ethyl-1,3-hexanediol; 3-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 4 -Methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 3-methyl-1,5-heptanediol ; 4-methyl-1,5-heptanediol; 3-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 5-methyl-2,4-heptanediol Diol; 3-methyl-2,5-heptanediol; 2-methyl-3,5-heptanediol; 2,6-octanediol; 3,3,4-trimethyl-2,4 -Hexanediol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl -2,5-hexanediol; 3,3,5-trimethyl-2,5-hexanediol; triethoxylated 3-(butoxy)-1,2-propanediol; tetraethoxy 3-(butoxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3 -(2-methyl-1-butoxy)-1,2-propanediol; 3-(isoamyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy)- 1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy)- 1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1-butoxy base)-1,3-propanediol; 2-(isoamyloxy)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-(cyclohexyl oxy)-1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; pentaethoxylated 3-(butoxy)-1,2-propanediol ; Hexaethoxylated 3-(butoxy)-1,2-propanediol; Heptaethoxylated 3-(butoxy)-1,2-propanediol; Octaethoxylated 3-( butoxy)-1,2-propanediol; nonaethoxylated 3-(butoxy)-1,2-propanediol; monopropoxylated 3-(butoxy)-1,2-propanediol ; Dibutylideneoxylated 3-(butoxy)-1,2-propanediol; and Tributylideneoxylated 3-(butoxy)-1,2-propanediol. 3. The substance of claim 1, which is an ether solvent selected from the group consisting of: 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3 -(2-methyl-1-butoxy)-1,2-propanediol; 3-(isoamyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy)- 1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy)- 1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1-butoxy base)-1,3-propanediol; 2-(isoamyloxy)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-(cyclohexyl oxy)-1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; triethoxylated 3-(butoxy)-1,2-propanediol ; Tetraethoxylated 3-(butoxy)-1,2-propanediol; Pentaethoxylated 3-(butoxy)-1,2-propanediol; Hexaethoxylated 3-( butoxy)-1,2-propanediol; heptaethoxylated 3-(butoxy)-1,2-propanediol; octaethoxylated 3-(butoxy)-1,2-propanediol ; nonaethoxylated 3-(butoxyl)-1,2-propanediol; monopropoxylated 3-(butoxyl)-1,2-propanediol; dibutylideneoxylated 3-( butoxy)-1,2-propanediol; and tributoxylated 3-(butoxy)-1,2-propanediol; bis(2-hydroxybutyl)ether; and bis(2-hydroxycyclopentyl) base) ether. 4. The substance of claim 1, which is a homologue or analog of the following compounds, wherein each homologue or analog contains at least one additional _CH2 group, for each additional _CH2 group, by inserting a double bond, the total number of hydrogen atoms of the compound remains the same: I. n-propanol; II. 2-butanol and/or 2-methyl-2-propanol; III. 2,3-dimethyl-2,3-butanediol; 2,3-dimethyl-1,2-butanediol; 3,3-dimethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3-pentanediol; 4-methyl-2,3-pentanediol; 2,3-hexanediol; 3,4 -Hexanediol; 2-ethyl-1,2-butanediol; 2-methyl-1,2-pentanediol; 3-methyl-1,2-pentanediol; 4-methyl-1 , 2-pentanediol; and/or 1,2-hexanediol; IV.2-butyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2-(1-methylpropyl)-1,3-propanediol; 2-(2-methyl propyl)-1,3-propanediol; 2-methyl-2-propyl-1,3-propanediol; 2,3,3-trimethyl-1,2-butanediol; 2-ethyl- 2-methyl-1,4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-propyl-1,4-butanediol; 2-isopropyl- 1,4-butanediol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4-dimethyl-1, 5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3- pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol Alcohol; 2-ethyl-1,5-pentanediol; 2-methyl-1,6-hexanediol; 3-methyl-1,6-hexanediol; 2-methyl-2,3- Hexylene glycol; 3-methyl-2,3-hexanediol; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl-3, 4-hexanediol; 3-methyl-3,4-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; and/or 1,6- Heptanediol; V.2-(2-methylbutyl)-1,3-propanediol; 2-(1,1-dimethylpropyl)-1,3-propanediol; 2-(1,2- Dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(1-methylbutyl)-1,3-propanediol; 2-( 2,2-Dimethylpropyl)-1,3-propanediol; 2-(3-methylbutyl)-1,3-propanediol; 2-butyl-2-methyl-1,3-propanediol; 2-Ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1,3-propanediol; 2-methyl-2-(1-methylpropyl)-1 , 3-propanediol; 2-methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl-2-methyl-1,3-propanediol; 2,2-diethylene Base-1,3-butanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-butyl-1,3-butanediol; 2-ethyl-2,3 -Dimethyl-1,3-butanediol; 2-(1,1-dimethylethyl)-1,3-butanediol; 2-(2-methylpropyl)-1,3- Butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 2-methyl-2-propyl-1,3-butanediol; 3-methyl-2-isopropyl Base-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1,4-butanediol; 2-methyl-2 -Propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4-butanediol Alcohol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1-dimethylethyl)-1,4-butanediol; 2-(2- Methylpropyl)-1,4-butanediol; 2-methyl-3-propyl-1,4-butanediol; 3-methyl-2-isopropyl-1,4-butanediol ;2,2,3-Trimethyl-1,3-pentanediol; 2,2,4-Trimethyl-1,3-pentanediol; 2,3,4-Trimethyl-1,3 -pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3,4,4-trimethyl-1,3-pentanediol; 2,2,3-trimethyl -1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 3,3,4 - Trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol; 2 , 3,3-trimethyl-1,5-pentanediol; 2,3,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-2,4-pentanediol Diol; 2,3,4-trimethyl-2,4-pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1 , 3-pentanediol; 2-ethyl-4-methyl-1,3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2- Methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethane 2-methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol ; 2-ethyl-3-methyl-1,5-pentanediol; 2-ethyl-4-methyl-1,5-pentanediol; 3-ethyl-3-methyl-1,5 - pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 2-isopropyl-1,5 -pentanediol; 3-propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol; 3, 5-Dimethyl-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3- Dimethyl-1,4-hexanediol; 2,4-dimethyl-1,4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl Base-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,4-dimethyl- 1,3-hexanediol; 4,5-dimethyl-1,4-hexanediol; 5,5-dimethyl-1,4-hexanediol; 2,2-dimethyl-1, 5-hexanediol; 2,3-dimethyl-1,5-hexanediol; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1,5- Hexylene glycol; 3,3-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol Alcohol; 4,5-dimethyl-1,5-hexanediol; 2,2-dimethyl-1,6-hexanediol; 2,3-dimethyl-1,6-hexanediol; 2,4-dimethyl-1,6-hexanediol; 2,5-dimethyl-1,6-hexanediol; 3,3-dimethyl-1,6-hexanediol; 3, 4-Dimethyl-1,6-hexanediol; 2,3-dimethyl-2,4-hexanediol; 2,4-dimethyl-2,4-hexanediol; 2,5- Dimethyl-2,4-hexanediol; 3,3-dimethyl-2,4-hexanediol; 3,4-dimethyl-2,4-hexanediol; 3,5-dimethyl Base-2,4-hexanediol; 4,5-dimethyl-2,4-hexanediol; 5,5-dimethyl-2,4-hexanediol; 2,3-dimethyl- 2,5-hexanediol; 2,4-dimethyl-2,5-hexanediol; 2,5-dimethyl-2,5-hexanediol; 3,3-dimethyl-2, 5-hexanediol; 3,4-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol ;4-Ethyl-1,3-Hexanediol; 2-Ethyl-1,4-Hexanediol; 4-Ethyl-1,4-Hexanediol; 2-Ethyl-1,5-Hexane Diol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-1,3 -Heptanediol; 3-methyl-1,3-heptanediol; 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1 , 3-heptanediol; 2-methyl-1,4-heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol; 5-methyl -1,4-heptanediol; 6-methyl-1,4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4- Methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 6-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol Alcohol; 2-methyl-2,4-heptanediol; 3-methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4- Heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl-2, 5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl- 2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl Base-3,5-heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7 -octanediol; 3,5-octanediol; and/or 3,6-octanediol; VI. 2,3,3,4-tetramethyl-2,4-pentanediol; 3-tert-butyl Base-2,4-pentanediol; 2,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2,4-hexanediol; 3,3, 5-Trimethyl-2,4-hexanediol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4-Trimethyl-2,5-hexanediol; and/or 3,3,5-trimethyl-2,5-hexanediol; VIII.C _3-8 diol alkoxy chemical derivatives, including: 1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1,2-propanediol (C3)PO ₄ ; 2-methyl-1,2-propanediol (C4) (Me-E _{4- 10} ); 2-methyl-1,2-propanediol (C4) 2 (Me-E ₁ ); 2-methyl-1,2-propanediol (C4)PO ₃ ; 2-methyl-1,2-propanediol (C4)BO ₁ ; 1,3-propanediol (C3)2(Me-E _6-8 ); 1,3-propanediol (C3)PO _5-6 ; 2,2-diethyl-1,3-propanediol (C7) E _1-7 ; 2,2-diethyl-1,3-propanediol (C7)PO ₁ ; 2,2-diethyl-1,3-propanediol (C7)n-BO _1-2 ; 2,2-dimethyl-1,3-propanediol (C5) 2 (MeE _1-2 ); 2,2-dimethyl-1,3-propanediol (C5)PO _3-4 ; 2-(1- Methylpropyl)-1,3-propanediol (C7) E _1-7 ; 2-(1-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methylpropyl )-1,3-propanediol (C7)n-BO _1-2 ; 2-(2-methylpropyl)-1,3-propanediol (C7)E _1-7 ; 2-(2-methylpropyl )-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1,3-propanediol (C7)n-BO _1-2 ; 2-ethyl-1,3-propanediol ( C5)(MeE _6-10 ); 2-Ethyl-1,3-propanediol (C5)2( _MeE1 ); 2-Ethyl-1,3-propanediol (C5)PO3; 2-Ethyl- ₂ -Methyl-1,3-propanediol (C6) (MeE _1-6 ); 2-Ethyl-2-methyl-1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl- 1,3-propanediol (C6)BO ₁ ; 2-isopropyl-1,3-propanediol (C6) (MeE _{1 -6} ); 2-isopropyl-1,3-propanediol (C6)PO ₂ ; 2 -Isopropyl-1,3-propanediol (C6)BO ₁ ; 2-methyl-1,3-propanediol (C4)2(MeE _2-5 ); 2-methyl-1,3-propanediol (C4) PO _4-5 ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)E _2-9 ; 2-methyl- 2-isopropyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)n-BO _1-3 ; 2-methyl-2- Propyl-1,3-propanediol (C7) E _1-7 ; 2-methyl-2-propyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-propyl-1,3 -Propylene glycol (C7)n-BO _1-2 ; 2-Propyl-1,3-propanediol (C6) (MeE _1-4 ); 2-Propyl-1,3-propanediol (C6)PO ₂ ; 2- Propyl-1,3-propanediol (C6) _BO1 ; 2. 1,2-butanediol (C4) (Me-E _2-8 ); 1,2-butanediol (C4)PO _2-3 ; 1,2-butanediol (C4)BO ₁ ; 2 , 3-dimethyl-1,2-butanediol (C6) E _1-6 ; 2,3-dimethyl-1,2-butanediol (C6) n-BO _1-2 ; 2-ethane Base-1,2-butanediol (C6) E _1-3 ; 2-ethyl-1,2-butanediol (C6)n-BO ₁ ; 2-methyl-1,2-butanediol ( C5)(Me-E _1-2 ); 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _{1- 6} ; 3,3-dimethyl-1,2-butanediol (C6)n-BO _{1- 2} ; 3-methyl-1,2-butanediol (C5) (MeE _1-2 ); 3 -Methyl-1,2-butanediol (C5)PO ₁ ; 1,3-butanediol (C4) 2 (MeE _3-6 ); 1,3-butanediol (C4)PO ₅ ; 1, 3-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,3-butanediol (C7) (MeE _1-3 ); 2,2,3-trimethyl-1, 3-Butanediol (C7)PO _1-2 ; 2,2-Dimethyl-1,3-butanediol (C6)(MeE _{3 -8} ); 2,2-Dimethyl-1,3- Butanediol (C6)PO ₃ ; 2,3-dimethyl-1,3-butanediol (C6) (MeE _3-8 ); 2,3-dimethyl-1,3-butanediol ( C6) PO ₃ ; 2-Ethyl-1,3-butanediol (C6) (MeE _1-6 ); 2-Ethyl-1,3-butanediol (C6)PO _2-3 ; 2-Ethyl Base-1,3-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,3-butanediol (C7)(MeE ₁ ); 2-Ethyl-2-methyl- 1,3-butanediol (C7)PO ₁ ; 2-ethyl-2-methyl-1,3-butanediol (C7)n-BO _2-4 ; 2-ethyl-3-methyl- 1,3-butanediol (C7) (MeE ₁ ); 2-ethyl-3-methyl-1,3-butanediol (C7)PO ₁ ; 2-ethyl-3-methyl-1, 3-butanediol (C7) n-BO _2-4 ; 2-isopropyl-1,3-butanediol (C7) (MeE ₁ ); 2-isopropyl-1,3-butanediol ( C7) PO ₁ ; 2-isopropyl-1,3-butanediol (C7)n-BO _2-4 ; 2-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ) ; 2-methyl-1,3-butanediol (C5)PO ₄ ; 2-propyl-1,3-butanediol (C7)E _2-9 ; 2-propyl-1,3-butanediol Alcohol (C7) PO ₁ ; 2-propyl-1,3-butanediol (C7) n-BO _1-3 ; 3-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ); 3-methyl-1,3-butanediol (C5)PO ₄ ; 1,4-butanediol (C4) 2 (MeE _2-4 ); 1,4-butanediol (C4)PO _{4 -5} ; 1,4-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,4-butanediol (C7)E _2-9 ; 2,2,3-trimethyl -1,4-butanediol (C7)PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _1-3 ; 2,2-dimethyl-1 , 4-butanediol (C6) (MeE _1-6 ); 2,2-dimethyl-1,4-butanediol (C6)PO ₂ ; 2,2-dimethyl-1,4-butane Diol (C6) BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _1-6 ); 2,3-dimethyl-1,4-butanediol (C6 )PO ₂ ; 2,3-dimethyl-1,4-butanediol (C6)BO ₁ ; 2-ethyl-1,4-butanediol (C6)(MeE _{1 -4} ); 2-ethane Base-1,4-butanediol (C6)PO ₂ ; 2-Ethyl-1,4-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7) E _1-7 ; 2-Ethyl-2-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7 )n-BO _1-2 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)E _1-7 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,4-butanediol (C7)n-BO _1-2 ; 2-isopropyl-1,4-butanediol (C7)E _1-7 ; 2-isopropyl-1,4-butanediol (C7)PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO _1-2 ; 2-methyl -1,4-butanediol (C5) (MeE _6-10 ); 2-methyl-1,4-butanediol (C5) 2 (MeE ₁ ); 2-methyl-1,4-butanediol Alcohol (C5)PO ₃ ; 2-methyl-1,4-butanediol (C5)BO ₁ ; 2-propyl-1,4-butanediol (C7)E _{1 -5} ; 2-propyl- 1,4-butanediol (C7)n-BO _1-2 ; 3-ethyl-1-methyl-1,4-butanediol (C7)E _2-9 ; 3-ethyl-1-methyl Base-1,4-butanediol (C7)PO ₁ ; 3-ethyl-1-methyl-1,4-butanediol (C7)n-BO _1-3 ; 2,3-butanediol ( C4) (MeE _6-10 ); 2,3-butanediol (C4) 2 (MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-dimethyl-2,3-butanediol (C6)E _3-9 ; 2,3-dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3 -Dimethyl-2,3-butanediol (C6)n-BO _1-3 ; 2-methyl-2,3-butanediol (C5)(MeE _1-5 ); 2-Methyl-2 , 3-butanediol (C5) PO ₂ ; 2-methyl-2,3-butanediol (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol (C5) n-BO _2-3 ; 2-methyl Base-1,2-pentanediol (C6) E _{1- 3} ; 2-methyl-1,2-pentanediol (C6)n-BO ₁ ; 2-methyl-1,2-pentanediol ( C6)BO ₁ ; 3-methyl-1,2-pentanediol (C6)E _1-3 ; 3-methyl-1,2-pentanediol (C6)n-BO ₁ ; 4-methyl- 1,2-pentanediol (C6) E _1-3 ; 4-methyl-1,2-pentanediol (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (MeE _{1- 2} ); 1,3-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,3-pentanediol (C7) (MeE ₁ ); 2,2-dimethyl-1 , 3-pentanediol (C7) PO ₁ ; 2,2-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,3-pentane Diol (C7) (Me-E ₁ ); 2,3-dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,3-pentanediol (C7 )n-BO _2-4 ; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 2,4-dimethyl-1,3-pentanediol (C7 )PO ₁ ; 2,4-Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,-Ethyl-1,3-pentanediol (C7)E _2-9 ; 2-Ethyl-1,3-pentanediol (C7)PO ₁ ; 2-Ethyl-1,3-pentanediol (C7)n-BO _1-3 ; 2-methyl-1,3-pentane Diol (C6) 2 (MeE _{1- 6} ); 2-methyl-1,3-pentanediol (C6)PO _2-3 ; 2-methyl-1,3-pentanediol (C6)BO ₁ ; 3,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 3,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4 -Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 3-methyl-1,3-pentanediol (C6)(Me-E _1-6 ); 3-methyl -1,3-pentanediol (C6)PO _2-3 ; 3-methyl-1,3-pentanediol (C6)BO ₁ ; 4,4-dimethyl-1,3-pentanediol ( C7)(Me-E ₁ ); 4,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7)n- BO _2-4 ; 4-methyl-1,3-pentanediol (C6) (MeE _1-6 ); 4-methyl-1,3-pentanediol (C6)PO _2-3 ; 4-methanol Base-1,3-pentanediol (C6)BO ₁ ; 1,4-pentanediol (C5) 2 (MeE _{1- 2} ); 1,4-pentanediol (C5)PO _3-4 ; 2, 2-Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,2-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,2-dimethyl Base-1,4-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,3-dimethyl Base-1,4-pentanediol (C7)PO ₁ ; 2,3-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2,4-Dimethyl-1, 4-pentanediol (C7) (Me-E ₁ ); 2,4-dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,4-dimethyl-1,4-pentanediol Alcohol (C7) n-BO _2-4 ; 2-methyl-1,4-pentanediol (C6) (MeE _1-6 ); 2-methyl-1,4-pentanediol (C6)PO _{2 -3} ; 2-methyl-1,4-pentanediol (C6)BO ₁ ; 3,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,3- Dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 3,4-Dimethyl- 1,4-pentanediol (C7) (Me-E ₁ ); 3,4-dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,4- Pentylene glycol (C7) n-BO _2-4 ; 3-methyl-1,4-pentanediol (C6) 2 (Me-E _1-6 ); 3-methyl-1,4-pentanediol (C6)PO _{2 -3} ; 3-methyl-1,4-pentanediol (C6)BO ₁ ; 4-methyl-1,4-pentanediol (C6)2(Me-E _1-6 ) ; 4-methyl-1,4-pentanediol (C6) PO _2-3 ; 4-methyl-1,4-pentanediol (C6) BO ₁ ; 1,5-pentanediol (C5) ( Me-E _4-10 ); 1,5-pentanediol (C5) 2 (MeE ₁ ); 1,5-pentanediol (C5)PO ₃ ; 2,2-dimethyl-1,5-pentane Diol (C7) E _1-7 ; 2,2-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-dimethyl-1,5-pentanediol (C7)n -BO _1-2 ; 2,3-dimethyl-1,5-pentanediol (C7)E _1-7 ; 2,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2,4-dimethyl-1,5-pentanediol (C7)E _1-7 ; 2, 4-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2-Ethyl-1 , 5-pentanediol (C7) E _1-5 ; 2-ethyl-1,5-pentanediol (C7) n-BO _1-2 ; 2-methyl-1,5-pentanediol (C6 )(Me-E _1-4 ); 2-methyl-1,5-pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _1-7 ; 3,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 3,3-dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 3-form Base-1,5-pentanediol (C6) (Me-E _1-4 ); 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) ( Me-E _1-3 ); 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6)E _1-7 ; 2-methyl-2,3- pentanediol (C6)PO ₁ ; 2-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 3-methyl-2,3-pentanediol (C6)E _1-7 ; 3-methyl-2,3-pentanediol (C6)PO ₁ ; 3-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 4-methyl-2,3- pentanediol (C6) E _1-7 ; 4-methyl-2,3-pentanediol (C6)PO ₁ ; 4-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 2,4-pentanediol (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol ( C7) (Me-E _1-4 ); 2,3-Dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-Dimethyl-2,4-pentanediol (C7) (Me-E _1-4 ); 2,4-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2-methyl-2,4-pentanediol (C7)(Me-E _{5 -10} ); 2-methyl-2,4-pentanediol (C7)PO ₃ ; 3,3-dimethyl-2,4-pentanediol (C7)(Me-E _1-4 ); 3 , 3-dimethyl-2,4-pentanediol (C7)PO ₂ ; 3-methyl-2,4-pentanediol (C6) (Me-E _5-10 ); 3-methyl-2 , 4-pentanediol (C6) PO ₃ ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _2-9 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _1-3 ; 2-methyl-1,3-hexanediol (C7)BO ₁ ; 3-methyl-1,3-hexanediol (C7)E _2-9 ; 3-methyl- 1,3-hexanediol (C7)PO ₁ ; 3-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,3-hexanediol (C7) E _2-9 ; 4-methyl-1,3-hexanediol (C7)PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 5-methyl- 1,3-hexanediol (C7)E _2-9 ; 5-methyl-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n- BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7) E _2-9 ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 3-methyl-1,4-hexanediol (C7)E _2-9 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3- Methyl-1,4-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,4-hexanediol (C7)E _2-9 ; 4-methyl-1,4-hexane Diol (C7) PO ₁ ; 4-methyl-1,4-hexanediol (C7) n-BO _1-3 ; 5-methyl-1,4-hexanediol (C7) E _2-9 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6)PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7) E _2-9 ; 2-methyl-1,5-hexanediol (C7)PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 3-methyl- 1,5-hexanediol (C7)E _2-9 ; 3-methyl-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n- BO _1-3 ; 4-methyl-1,5-hexanediol (C7)E _2-9 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1, 5-hexanediol (C7)n-BO _1-3 ; 5-methyl-1,5-hexanediol (C7)E _2-9 ; 5-methyl-1,5-hexanediol (C7) PO ₁ ; 5-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 1,6-hexanediol (C6)(Me-E _1-2 ); 1,6-hexanediol Alcohol (C6) PO _1-2 ; 1,6-Hexanediol (C6) n-BO ₄ ; 2-Methyl-1,6-Hexanediol (C7) E _1-5 ; 2-Methyl-1 , 6-hexanediol (C7) n-BO _1-2 ; 3-methyl-1,6-hexanediol (C7) E _1-5 ; 3-methyl-1,6-hexanediol (C7 )n-BO _1-2 ; 2,3-hexanediol (C6)E _1-5 ; 2,3-hexanediol (C6)n-BO ₁ ; 2,3-hexanediol (C6)BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6)PO ₃ ; 2-methyl-2,4-hexanediol (C7) (Me -E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4-hexanediol (C7)(Me-E _1-2 ) ; 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 4-methyl- 2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _1-2 ); 5-methyl-2,4-hexanediol Alcohol (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-methyl-2,5- Hexylene glycol (C7) (Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol (C6)EO _1-5 ; 3,4-hexanediol Alcohol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-Heptanediol (C7) E _1-7 ; 1,3-Heptanediol (C7)PO ₁ ; 1,3-Heptanediol (C7)n-BO _1-2 ; 1,4 -Heptanediol (C7) E _1-7 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO _1-2 ; 1,5-Heptanediol ( C7)E _1-7 ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO _1-2 ; 1,6-heptanediol (C7)E _{1- 7} ; 1,6-heptanediol (C7)PO ₁ ; 1,6-heptanediol (C7)n-BO _1-2 ; 1,7-heptanediol (C7)E _1-2 ; 1,7 -Heptanediol (C7)n-BO ₁ ; 2,4-Heptanediol (C7)E _3-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol Alcohol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me- E ₁ ); 2,5-heptanediol (C7)PO ₁ ; 2,5-heptanediol (C7)n-BO ₃ ; 2,6-heptanediol (C7)E _3-10 ; 2,6 - Heptanediol (C7) (Me-E ₁ ); 2,6-Heptanediol (C7)PO ₁ ; 2,6-Heptanediol (C7)n-BO ₃ ; 3,5-Heptanediol ( C7)E _3-10 ; 3,5-heptanediol (C7)(Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ; 6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 - Isopropyl-1,3-butanediol (C8) n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8) n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl-2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptane Diol (C8)n- _BO1 ; 3-methyl-2,4-heptanediol (C8)n- _BO1 ; 4-methyl-2,4-heptanediol (C8)n- _BO1 ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl-2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptane Diol (C8)n- _BO1 ; 3-methyl-2,5-heptanediol (C8)n- _BO1 ; 4-methyl-2,5-heptanediol (C8)n- _BO1 ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl-2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptane Diol (C8)n- _BO1 ; 3-methyl-2,6-heptanediol (C8)n- _BO1 ; 4-methyl-2,6-heptanediol (C8)n- _BO1 ; 2-Methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)E _1-3 ; 2-Ethylene Base-2,3-dimethyl-1,3-butanediol (C8) E _1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8) E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8) E _1-3 ; 5-methyl-2,5-heptanediol (C8) E _1-3 ; 6-methyl-2,5-heptanediol (C8) E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; and IX. their mixtures; The following specific compounds are exceptions: 2,7-dimethyl-3,7-octadiene-2,5-diol; 3,5-dimethyl-4,6-octadiene-1,2 -diol; 3,5-dimethyl-4,6-octadiene-1,2-diol; 3,5-dimethyl-4,6-octadiene-1,2-diol; 3,5-Dimethyl-4,6-octadiene-1,2-diol; 3,5-dimethyl-4,6-octadiene-1,2-diol; 5,5- Dimethyl-1-hexene-3,4-diol; 4-methyl-6-heptene-1,4-diol; 4-octene-3,6-diol; 4-octene- 3,6-diol; 3-octene-1,2-diol; 3-nonene-2,5-diol; 7-nonene-4,5-diol; 7-nonene-4, 5-diol; 6-nonene-2,3-diol; 5-methyl-6-heptene-2,4-diol; 7-methyl-3-methylene-6-octene- 1,2-diol; 2,6-dimethyl-2,7-octadiene-1,6-diol; 2-(2-methylenepentyl)-1,3-propanediol; 2, 6-Dimethyl-3-heptene-2,6-diol; 2,6-dimethyl-3-heptene-2,6-diol; 3,5-dimethyl-5-hexene -2,4-diol; 2,5-dimethyl-4-hexene-1,2-diol; 2,5-dimethyl-4-hexene-1,2-diol; 7- Octene-1,6-diol; 2,5-Dimethyl-2-hexene-1,4-diol; 2,5-Dimethyl-2-hexene-1,4-diol; 5-methyl-2-methylene-1,4-hexanediol; 4-octene-2,3-diol; nonene-1,4-diol; 4-methyl-6-heptene -1,4-diol; 4-methyl-6-octene-3,5-diol; 2,6-dimethyl-2,6-octadiene-1,8-diol; (8 -hydroxygeraniol); 2,4-dimethyl-1-heptene-3,5-diol; 5-methyl-3-methylene-2,4-hexanediol; 5-methyl -3-methylene-2,4-hexanediol; 3-vinyl-2,5-dimethyl-5-hexene-2,4-diol; 3-vinyl-2,5-diol Methyl-5-hexene-2,4-diol; 5-methyl-6-heptene-2,4-diol; 4,9-decadiene-1,8-diol; 2,4 -Dimethyl-5-hexene-1,3-diol; 2-methyl-7-octene-1,3-diol; 2,6-dimethyl-5-heptene-3-d -1,2-diol; 2,6-dimethyl-5-heptene-3-d-1,2-diol; 4-nonene-2,8-diol; 4-nonene-2 ,8-diol; 2,3-dimethyl-5-hexene-2,3-diol; 2-butyl-2-butene-1,4-diol; 3-(1,1- Dimethylethyl)-2,4-hexadiene-1,6-diol; 7-methyl-6-octene-1,4-diol; 5,6-dimethyl-6-heptene ene-1,4-diol; 5,6-dimethyl-6-heptene-1,4-diol; 7-methyl-7-octene-2,5-diol; 7-methyl -7-octene-2,5-diol; 2,4-dimethyl-4-hexene-1,3-diol; 4-octene-2,7-diol; 4-octene- 2,7-diol; 5-methyl-3-heptene-1,2-diol; 5-methyl-3-heptene-1,2-diol; 2,6-dimethyl-3 , 7-octadiene-2,6-diol; 8-nonene-1,7-diol; 3,7-dimethyl-2,6-octadiene-1,4-diol (Isorosiridol ); 2,4-dimethyl-5-hexene-1,4-diol; 6-methyl-1-heptene-3,4-diol; 4,6-dimethyl-3-heptene ene-1,5-diol; 4-methyl-3-octene-1,5-diol; 3,9-decadiene-1,2-diol; 2-methyl-7-octene -2,3-diol; 2-methyl-7-octene-2,3-diol; 6-nonene-2,3-diol; 3-methyl-4-methylene-2, 5-hexanediol; 2-methyl-6-heptene-1,4-diol; 6-octene-1,5-diol; 1-octene-3,4-diol; Base-7-octene-1,6-diol; 5-methyl-7-octene-1,6-diol; 2-methyl-2-(1-methylvinyl)-1,3 -Butanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 4-methylene-3,5-octanediol; 4-methylene-3,5- Octanediol; 2-methyl-6-heptene-2,3-diol; 2,6-dimethyl-6-heptene-2,3-diol; 2-methyl-6-heptene -2,3-diol; 4-methyl-7-octene-1,3-diol; 2-methyl-2-(1-methyl-2-propenyl)-1,3-butanediol Alcohol; 2,6-Dimethyl-5-heptene-1,2-diol; 1-nonene-3,4-diol; 3-methyl-5-heptene-1,2-diol ; 2,6-Dimethyl-3,7-octadiene-2,6-diol; 2,2-Dimethyl-6-heptene-1,3-diol; 4-nonene-1 , 3-diol; 3-methyl-2-(2-propenyl)-1,4-pentanediol; 1-nonene-3,4-diol; 8-nonene-1,2-diol Alcohol; 3-octene-1,2-diol; 1,9-decadiene-4,6-diol; 1,9-decadiene-4,6-diol; 2,2-dimethyl 2-(1-pentenyl)-1,3-propanediol; 2-(3-methyl-1-butenyl)-1,3-propanediol ; 2-(3-methyl-1-butenyl)-1,3-propanediol; 8-nonene-1,3-diol; 2,7-dimethyl-2,4-octadiene- 1,8-diol; 6-methyl-5-heptene-1,2-diol; 3,9-decadiene-1,2-diol; 3-nonene-1,2-diol ; 6-nonene-1,2-diol; 2,4-dimethyl-4-hexene-1,3-diol; 3,7-dimethyl-2,4-octadiene-1 ,7-diol; 3,4-dimethyl-4-hexene-2,3-diol; 3,4-dimethyl-4-hexene-2,3-diol; 3,4- Dimethyl-4-hexene-2,3-diol; 3,4-dimethyl-4-hexene-2,3-diol; 3,4-dimethyl-5-hexene-2 ,3-diol; 3,4-dimethyl-5-hexene-2,3-diol; 3,4-dimethyl-5-hexene-2,3-diol; 2-methyl -2-(2-propenyl)-1,3-butanediol; 4,6-dimethyl-6-heptene-2,5-diol; 6-methyl-6-heptene-1, 5-diol; 4,6-dimethyl-6-heptene-2,5-diol; 2-(2-propenyl)-1,5-pentanediol; 3,5-dimethyl- 5-Hexene-2,3-diol; 3,5-Dimethyl-5-hexene-2,3-diol; Nonanediol; Octanediol; 3,5-Dimethyl-5- Hexene-1,3-diol; 4-nonene-1,8-diol; 4-nonene-1,7-diol; 4-nonene-1,6-diol; 6-nonene -1,4-diol; 2-nonene-1,4-diol; 8-nonene-2,5-diol; 2-vinyl-6-methyl-5-heptene-1,2 -diol; 2,5-dimethyl-4-hexene-2,3-diol; 2,6-dimethyl-5-heptene-2,3-diol; 2,6-dimethyl Dimethyl-1-heptene-3,5-diol; 2,6-dimethyl-1-heptene-3,5-diol; 7-methyl-7-octene-1,3-diol ; 2-methyl-2-(3-methyl-3-butenyl)-1,3-propanediol; 2,6-dimethyl-5-heptene-1,2-diol; 2,6 -Dimethyl-5,7-octadiene-2,3-diol; 2,6-dimethyl-5,7-octadiene-2,3-diol; 2-ethyl-5- Hexene-1,2-diol; 6-methyl-2,4-nonadiene-4-d-1,7-diol; 6-methyl-2,4-nonadiene-1,6 , 7-d3-1,7-diol; 6-methyl-2,4-nonadiene-1,7-diol; 2-methyl-6-methylene-7-octene-2, 3-diol; 3-methyl-2-(4-pentenylene)-1,3-butanediol; 3-methyl-2-(4-pentenylene)-1,3-butane Diol; 5,5-dimethyl-2-hexene-1,4-diol; 5,5-dimethyl-2-hexene-1,4-diol; 2-nonene-1, 4-diol; 2-nonene-1,4-diol; 2-methyl-6-methylene-7-nonene-2,3-diol; 5-octene-1,3-diol Alcohol; 2-methyl-7-octene-1,3-diol; 2-methyl-4-heptene-1,3-diol; 4-octene-2,3-d2-1,2 -diol; 4-octene-2,3-d2-1,2-diol; 3-methyl-5-heptene-1,2-diol; 5-octene-1,2-diol ;2,6-Dimethyl-3,7-octadiene-1,6-diol; 2,6-Dimethyl-5-heptene-1,2-diol; 4,5-dimethyl Base-1,7-octadiene-4,5-diol; 4,5-dimethyl-1,7-octadiene-4,5-diol; 2-methyl-5-heptene- 1,3-diol; 2-methyl-5-heptene-1,3-diol; 3,4-dimethyl-3-hexene-1,6-diol; 3,4-dimethyl Base-3-hexene-1,6-diol; 2,6-dimethyl-2,6-octadiene-1-t-1,8-diol; 2,6-dimethyl-2 , 6-octadiene-1-t-1,8-diol; 2,6-dimethyl-2,6-octadiene-1-d-1,8-diol; 2,6-diol Methyl-2,6-octadiene-1-d-1-t-1,8-diol; 2,6-dimethyl-2,6-octadiene-1-d-1-t- 1,8-diol; 2,6-dimethyl-2,6-octadiene-1-d-1,8-diol; 6-methyl-2-heptene-1,5-diol ; 6-methyl-2-heptene-1,5-diol; 8,9-decadiene-3,5-diol; 8,9-decadiene-3,5-diol; 8- Methyl-4,6-nonadiene-1,3-diol; 8-methyl-3,5-nonadiene-1,7-diol; 2,4-dimethyl-5-heptene -1,3-diol; 2-nonene-1,9-diol; 2-nonene-1,9-diol; 2-ethyl-2-(2-propenyl)-1,3- Butanediol; 6-methyl-3-heptene-1,5-diol; 2-vinyl-4-methyl-1,3-pentanediol; 2-vinyl-4-methyl-1 , 3-pentanediol; 3,4-dimethyl-5-hexene-2,3-diol; 2,3,4-trimethyl-5-hexene-2,3-diol; 2 , 3,3-trimethyl-4-pentene-1,2-diol; 2-(2-methyl-2-propenyl)-2-(2-propenyl)-1,3-propanediol; 2-(2-butenyl)-2-(2-propenyl)-1,3-propanediol; 2-ethyl-5-hexene-1,2-diol; 2-(4-methyl- 3-pentenylene)-1,4-butanediol; (β-Acaridiol); 2-methyl-6-heptene-1,3-diol; 2,6-dimethyl-2,6 -octadiene-1,8-diol-2-13C; 5,5-dimethyl-1-hexene-3,4-diol; 5,5-dimethyl-1-hexene-3 ,4-diol; 1-nonene-3,4-diol; 8-nonene-2,4-diol; 8-nonene-2,4-diol; 2-methyl-7-octane ene-1,2-diol; 1-nonene-3,5-diol; 2,6-dimethyl-2,7-octadiene-1,6-diol; 7-octene-1 , 2-diol; 7-octene-1,2-diol; 3,7-dimethyl-2,5-octadiene-1,7-diol; 2-(2,2-dimethyl propylene)-1,3-propanediol; 7-methyl-3-methylene-6-octene-1,2-diol; 2,8-decadiene-1,10-diol; 7-methyl-6-octene-1,5-diol; 2-(1-ethyl-1-propenyl)-1,3-butanediol; 4-ethyl-3-methyl-4 -Hexene-1,2-diol; 8-nonene-1,3-diol; 2-(3-methyl-2-butenyl)-3-methylene-1,4-butanediol Alcohol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol Alcohol; 8-nonene-2,4-diol; 4-methylene-2,6-heptanediol; 2,5-dimethyl-3-hexene-3,4-diol; 4- Octene-4,5-diol; 2,3-dimethyl-5-hexene-1,2-diol; 2-vinyl-2,5-dimethyl-3-hexene-1, 6-diol; 2,4-dimethyl-3-hexene-1,5-diol; 2,4-dimethyl-3-hexene-1,5-diol; 2,6-diol Methyl-3,7-octadiene-2,6-diol; 3,7-dimethyl-3,6-octadiene-1,2-diol; 6-methyl-7-octene -2,3-diol; 6-methyl-7-octene-2,3-diol; 6-methyl-7-octene-2,3-diol; 3,7-dimethyl- 2,5-octadiene-1,7-diol; 7-methyl-6-octene-1,3-diol; decadiene-diol; 2,3-dimethyl-6-heptene -1,2-diol; 3,5-dimethyl-4-hexene-1,3-diol; 2-(1,1-dimethylethyl)-4-pentene-1,3 -diol; 2-(1,1-dimethylethyl)-4-pentene-1,3-diol; 6,6-dimethyl-1-heptene-3,5-diol; 6,6-Dimethyl-1-heptene-3,5-diol; 5-methyl-4-methylene-1,3-hexanediol; 4-octene-1,2-diol ; 3-vinyl-2,3-heptanediol; 3-vinyl-2,3-heptanediol; 2,4-dimethyl-5-hexene-1,3-diol; 2,4 -Dimethyl-5-hexene-1,3-diol; 3,7-dimethyl-2,6-octadiene-1-t-1,8-diol; 8-nonene-2 , 4-diol; 8-nonene-2,4-diol; 2-methylene-1,3-octanediol; 8-nonene-1,3-diol; 3,6-dimethyl Dimethyl-5-heptene-1,4-diol; 2,6-dimethyl-5-heptene-1,4-diol; 4-octene-2,3-diol; 4-octene -2,3-diol; 2,7-dimethyl-5,7-octadiene-1,4-diol; 7-methyl-7-octene-1,3-diol; 5- Ethyl-2-heptene-1,5-diol; 5-ethyl-2-heptene-1,5-diol; 2-vinyl-3-ethyl-1,3-pentanediol; 2,3-Dimethyl-5-heptene-2,4-diol; 2,3-Dimethyl-5-heptene-2,4-diol; 8-nonene-3,4-diol Alcohol; 8-nonene-3,4-diol; 4,5-dimethyl-5-hexene-1,3-diol; 4,5-dimethyl-5-hexene-1,3 -diol; 3,7-dimethyl-4,6-octadiene-2,3-diol; 2,2-diallyl-1,3-butanediol; 1,9-decanediol ene-3,8-diol; 5,6-dimethyl-2-heptene-1,4-diol; 5-methyl-2-heptene-1,4-diol; 5,6- Dimethyl-2-heptene-1,4-diol; 5-methyl-2-heptene-1,4-diol; 2,8-decadiene-5,6-diol; 2, 6-Dimethyl-2,7-octadiene-1,6-diol (8-hydroxylinalool); 2-methyl-6-heptene-1,2-diol; 2,3- Dimethyl-5-hexene-1,3-diol; 6-methyl-2-(methyl-13C)-2,6-octadiene-1,8-diol; 2-(5- Hexenyl)-1,3-propanediol; 8-nonene-3,4-diol; 3-ethyl-5-hexene-1,3-diol; 7-octene-3,4-diol Alcohol; 2-methyl-6-heptene-1,2-diol; 4-(2-propenyl)-6-heptene-2,4-diol; 3,7-dimethyl-2, 6-octadiene-1,4-diol (Rosiridol); 8-nonene-3,4-diol; 6-methyl-6-heptene-2,3-diol; 2,6-diol Methyl-6-heptene-2,3-diol; 2,5-dimethyl-4-hexene-2,3-diol; 2,6-dimethyl-4,6-octadiene -2,3-diol; 2-methyl-6-methylene-7-octene-2,3-diol; 6-methyl-7-octene-2,3-diol; 2, 6-Dimethyl-4,6-octadiene-2,3-diol; 6-methyl-5-methylene-1,4-heptanediol; 2-(4-methyl-3- Pentenyl)-2-butene-1,4-diol (α-Acaridiol); 4-octene-1,2-diol; 4-octene-1,2-diol; 7-octene -2,4-diol; 3-methyl-6-heptene-2,4-diol; 3-methyl-6-heptene-2,4-diol; 2,4-dimethyl- 3-heptene-2,5-diol; 2-(3-methyl-2-butenyl)-1,3-butanediol; 2-methyl-7-octene-3,5-diol Alcohol; 2-methyl-7-octene-3,5-diol; 5,5-dimethyl-6-heptene-2,4-diol; 5,5-dimethyl-6-heptene ene-2,4-diol; 2-methyl-2-(2-methylallyl)-1,3-propanediol; 6-methyl-2-heptene-1,6-diol; 2 -Allyl-3-methyl-1,3-butanediol; 2-nonene-1,4-diol; 4-vinyl-2,5-dimethyl-5-hexene-2, 3-diol; 4-vinyl-2,5-dimethyl-5-hexene-2,3-diol; 2-nonene-1,4-diol; 3,6-dimethyl- 5-heptene-1,3-diol; 2-(1-methylvinyl)-1,5-hexanediol; and 2-(1-pentenyl)-1,3-propanediol. 5. The substance according to claim 1, which is a mixture of compounds A, B and/or C. 6. The substance of claim 1, which is a mixture of eight-carbon-diol isomers consisting essentially of the following compounds: 2,2,4-trimethyl-1,3-pentanediol; 2-ethyl -1,3-hexanediol; 2,2-dimethyl-1,3-hexanediol; 2-ethyl-4-methyl-1,3-pentanediol; 2-ethyl-3- Methyl-1,3-pentanediol; 3,5-octanediol; 2,2-dimethyl-2,4-hexanediol; 2-methyl-3,5-heptanediol; and/ or 3-methyl-3,5-heptanediol, the content of any single diol isomer being less than about 90% of any mixture. 7. The material of claim 6, wherein the content of any individual diol isomer is less than about 80% of any mixture. 8. The material of claim 6, wherein the content of any individual diol isomer is less than about 70% of any mixture. 9. The material of claim 6, wherein the content of any individual diol isomer is less than about 60% of any mixture. 10. The material of claim 6, wherein the content of any individual diol isomer is less than about 50% of any mixture. 11. An aqueous stable fabric softener composition comprising: A. about 2% to about 80% of a fabric softener active selected from the group consisting of: 1. A fabric softener compound having the formula: [(R) _4-m -N ⁽⁺⁾ -[(CH ₂ ) _n -YR ¹ ] _m ]X ^(-) (1) wherein each R substituent is H, or short chain C _1-6 alkyl or hydroxyalkyl, benzyl, or mixtures thereof; each m is 2 or 3; each n is 1 to about 4; each Y is -O-(O)C-, -(R)N-(O)C-, -C(O)-N(R)-, or -C(O)-O-, but not -OC( O)O-; the sum of the carbon numbers in each R ¹ or YR ¹ when Y is -O-(O)C- or -(R)N-(O)C- is C _6-22 , but when When the sum of the carbon numbers in one ^R1 or ^YR1 is less than about 12, the sum of the carbon numbers in the other ^R1 or ^YR1 is at least about 16, wherein each ^R1 is a long chain hydrocarbyl, or a substituted hydrocarbyl substituting group, and for R ¹ , or YR ¹ , a C _16-20 hydrocarbyl or substituted hydrocarbyl substituent, the iodine value of the YR ¹ fatty acid containing the R ¹ group is from about 20 to about 140, and for R ¹ , or YR ¹ , a C _8-14 hydrocarbyl or substituted hydrocarbyl substituent, the iodine value of the fatty acid containing the R ¹ group is about 10 or lower; 2. A fabric softener compound having the formula:

wherein Y, R, R ¹ , and X ^(-) each have the same meaning as previously described; and 3. Mixtures thereof; B. Less than about 40% by weight of the composition of a primary solvent having a ClogP value of from about 0.15 to about 0.64 and having at least some degree of asymmetry, said primary solvent Contains insufficient amounts of solvents selected from the group consisting of: 2,2,4-Trimethyl-1,3-pentanediol; ethoxylates of 2,2,4-trimethyl-1,3-pentanediol , diethoxylate, or triethoxylate derivatives; and/or 2-ethylhexyl-1,3-diol, to provide an aqueous stable composition containing them; C. optional effective amount Low molecular weight water-soluble solvents such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, and propylene carbonate sufficient to improve transparency, said water-soluble solvents are present at levels that do not form a transparent composition; D . Optionally, an effective amount of a clarity-improving water-soluble calcium and/or magnesium salt; and E. a balancing amount of water. 12. The aqueous stable fabric softener composition of claim 11 comprising: A. from about 13% to about 75% of a fabric softener active selected from the group consisting of: 1. A fabric softener compound having the formula: [(R) _4-m -N ⁽⁺⁾ -[(CH ₂ ) _n -YR ¹ ] _m ]X ^(-) (1) wherein each R substituent is H, or short chain _C1-3 alkyl or hydroxyalkyl, benzyl, or mixtures thereof; each m is 2; each n is 2 to about 3; each Y is -O-(O)C-; each R ¹ is a long chain C _9-19 hydrocarbyl, and for R ¹ C _15-19 hydrocarbyl or substituted hydrocarbyl substituents, the iodine value of the corresponding fatty acid containing the R ¹ group is about 50 to about 130; and for RC _7-13 or a substituted hydrocarbyl substituent, the iodine value of the corresponding fatty acid containing the ^R group is about 10 or less; 2. A fabric softener compound having the formula: wherein Y, R, R ¹ , and X ^(-) each have the same meaning as previously described; and 3. mixtures thereof; B. from about 10% to about 35% by weight of the composition of said primary solvent having a ClogP value from about 0.25 to about 0.62; C. optionally from about 1% to about 10 % of low molecular weight water-soluble solvents such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, and propylene carbonate sufficient to improve transparency, said water-soluble solvents are present at levels that do not form a transparent composition; D. Optionally 0% to about 2% of a water-soluble calcium and/or magnesium salt sufficient to improve clarity, to obtain a desired viscosity, or to improve clarity and to obtain a desired viscosity; and E. From about 10% to about 80% of water. 13. The aqueous stable fabric softener composition of claim 12 comprising: A. about 17% to about 70% of a fabric softener active selected from the group consisting of: 1. A fabric softener compound having the formula: [(R) _4-m -N ⁽⁺⁾ -[(CH ₂ ) _n -YR ¹ ] _m ]X ^(-) (1) wherein each R substituent is H, or short chain _C1-3 alkyl or hydroxyalkyl, benzyl, or mixtures thereof; each m is 2; each n is 2 to about 3; each Y is -O-(O)C-; each R ¹ is a long chain C _7-17 hydrocarbyl, or substituted hydrocarbyl substituent, and for R ¹ C _15-17 hydrocarbyl or substituted hydrocarbyl substituents, containing the R ¹ group The iodine value of the corresponding fatty acid of the group is about 70 to about 115; and for R ¹ C _7-13 hydrocarbyl or substituted hydrocarbyl substituent, the iodine value of the corresponding fatty acid containing the R ¹ group is about 5 or lower; 2. A fabric softener compound having the formula:

wherein Y, R, R ¹ , and X ^(-) each have the same meaning as previously described; and 3. Mixtures thereof; B. from about 12% to about 35% by weight of the composition of said primary solvent having a ClogP value of from about 0.40 to about 0.60; C. optionally from about 2% to 8% Low molecular weight water-soluble solvents such as ethanol, isopropanol, propylene glycol, 1,3-propanediol, and propylene carbonate sufficient to improve clarity; D. Optionally from about 0.05% to about 0.5% are sufficient to improve clarity to obtain the desired viscosity, or a water-soluble calcium and/or magnesium salt to improve clarity and obtain the desired viscosity; and E. from about 20% to about 80% water. 14. The aqueous stable fabric softener composition of claim 13 comprising: A. from about 19% to about 65% by weight of the composition of said fabric softener: 1. A fabric softener compound having the formula: [(R) _4-m -N ⁽⁺⁾ -[(CH ₂ ) _n -YR ¹ ] _m ]X ^(-) (1) wherein each R substituent is methyl, ethyl, propyl, hydroxyethyl, benzyl, or mixtures thereof; each n is 2; ^each R is a long chain _C13-17 linear alkyl or Alkylene, and for R ¹ C _15-17 hydrocarbyl or substituted hydrocarbyl substituents, the iodine value of the corresponding fatty acid containing the R ¹ group is from about 70 to about 115; B. is from about 14% by weight of the composition to About 35% of said main solvent, which has a ClogP value of about 0.40 to about 0.60; C. optional about 2% to 8% of low molecular weight water-soluble solvents sufficient to improve clarity such as ethanol, isopropanol, Propylene glycol, 1,3-propanediol, and propylene carbonate; D. optionally from about 0.1% to about 0.25% of water-soluble calcium or magnesium chloride, acetate, or nitrate; and E. from about 30% to about 70% water. 15. The composition of claim 11, wherein said ClogP value is from about 0.25 to about 0.62. 16. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: n-propanol; 2-butanol; 2-methyl-2-propanol; and mixtures thereof. 17. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 2,3-dimethyl-2,3-butanediol; 2,3-dimethyl-1,2 -Butanediol; 3,3-dimethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3-pentanediol; 4-methyl Base-2,3-pentanediol; 2,3-hexanediol; 3,4-hexanediol; 2-ethyl-1,2-butanediol; 2-methyl-1,2-pentanediol Alcohols; 3-methyl-1,2-pentanediol; 4-methyl-1,2-pentanediol; 1,2-hexanediol; and mixtures thereof. 18. The composition of claim 17, wherein the primary solvent is selected from the group consisting of: 2,3-dimethyl-1,2-butanediol; 3,3-dimethyl-1,2-butanediol; 2 -Methyl-2,3-pentanediol; 3-methyl-2,3-pentanediol; 4-methyl-2,3-pentanediol; 2,3-hexanediol; 3,4- Hexylene glycol; 2-ethyl-1,2-butanediol; 2-methyl-1,2-pentanediol; 3-methyl-1,2-pentanediol; 4-methyl-1, 2-pentanediol; 1,2-hexanediol; and mixtures thereof. 19. The composition of claim 18, wherein the primary solvent is selected from the group consisting of: 2-ethyl-1,2-butanediol; 2-methyl-1,2-pentanediol; 3-methyl-1, 2-pentanediol; 4-methyl-1,2-pentanediol; and 1,2-hexanediol; and mixtures thereof. 20. The composition of claim 19, wherein said primary solvent is 1,2-hexanediol. 21. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 2-butyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2- (1-methylpropyl)-1,3-propanediol; 2-(2-methylpropyl)-1,3-propanediol; 2-methyl-2-propyl-1,3-propanediol; 2, 3,3-trimethyl-1,2-propanediol; 2-ethyl-2-methyl-1,4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-Propyl-1,4-butanediol; 2-isopropyl-1,4-butanediol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl -1,5-pentanediol; 2,4-dimethyl-1,5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2 , 3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3 -pentanediol; 2,3-dimethyl-3,4-pentanediol; 2-ethyl-1,5-pentanediol; 2-methyl-1,6-hexanediol; Base-1,6-hexanediol; 2-methyl-2,3-hexanediol; 3-methyl-2,3-hexanediol; 4-methyl-2,3-hexanediol; 5 -Methyl-2,3-hexanediol; 2-methyl-3,4-hexanediol; 3-methyl-3,4-hexanediol; 1,3-heptanediol; 1,4- Heptanediol; 1,5-Heptanediol; 1,6-Heptanediol; and mixtures thereof. 22. The composition of claim 21, wherein said primary solvent is selected from the group consisting of: 2-butyl-1,3-propanediol; 2-propyl-1,4-butanediol; 2-ethyl-1,5- Pentylene glycol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol Alcohol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol; 2-methyl-1,6-hexanediol; 3-methyl 1,6-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; 1,6-heptanediol; and mixtures thereof. 23. The composition of claim 22, wherein the primary solvent is selected from the group consisting of: 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3 , 4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol; and their mixture. 24. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 2-(2-methylbutyl)-1,3-propanediol; 2-(1,1-dimethyl Propyl)-1,3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-( 1-methylbutyl)-1,3-propanediol; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2-(3-methylbutyl)-1,3-propanediol ; 2-butyl-2-methyl-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1,3-propanediol; 2-methyl-2-(1-methylpropyl)-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl- 2-methyl-1,3-propanediol; 2,2-diethyl-1,3-butanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-butyl -1,3-butanediol; 2-ethyl-2,3-dimethyl-1,3-butanediol; 2-(1,1-dimethylethyl)-1,3-butanediol Alcohol; 2-(2-methylpropyl)-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 2-methyl-2-propyl- 1,3-butanediol; 3-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-di Ethyl-1,4-butanediol; 2-methyl-2-propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2- Ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1-dimethyl Ethyl)-1,4-butanediol; 2-(2-methylpropyl)-1,4-butanediol; 2-methyl-3-propyl-1,4-butanediol; 3 -Methyl-2-isopropyl-1,4-butanediol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3- Pentylene glycol; 2,3,4-trimethyl-1,3-pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3,4,4-trimethyl- 1,3-pentanediol; 2,2,3-trimethyl-1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3- Trimethyl-1,4-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 3,3,4-trimethyl-1,4-pentanediol; 2, 2,3-Trimethyl-1,5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-1,5-pentanediol Alcohol; 2,3,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-2,4-pentanediol; 2,3,4-trimethyl-2, 4-pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 2-ethyl-4-methanol Base-1,3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl -3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-3-methyl-1,5- Pentylene glycol; 2-ethyl-4-methyl-1,5-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl- 2,4-pentanediol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2 -Propyl-1,4-pentanediol; 3-isopropyl-1,4-pentanediol; 2-isopropyl-1,5-pentanediol; 3-propyl-2,4-pentanediol Diol; 2,2-dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol ;2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol;4 , 4-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3 -Dimethyl-1,4-hexanediol; 2,4-dimethyl-1,4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-di Methyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,5-dimethyl -1,4-hexanediol; 5,5-dimethyl-1,4-hexanediol; 2,2-dimethyl-1,5-hexanediol; 2,3-dimethyl-1 ,5-hexanediol; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-1,5 -hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol Diol; 2,2-Dimethyl-1,6-hexanediol; 2,3-Dimethyl-1,6-hexanediol; 2,4-Dimethyl-1,6-hexanediol ; 2,5-dimethyl-1,6-hexanediol; 3,3-dimethyl-1,6-hexanediol; 3,4-dimethyl-1,6-hexanediol; 2 , 3-dimethyl-2,4-hexanediol; 2,4-dimethyl-2,4-hexanediol; 2,5-dimethyl-2,4-hexanediol; 3,3 -Dimethyl-2,4-hexanediol; 3,4-dimethyl-2,4-hexanediol; 3,5-dimethyl-2,4-hexanediol; 4,5-di Methyl-2,4-hexanediol; 5,5-dimethyl-2,4-hexanediol; 2,3-dimethyl-2,5-hexanediol; 2,4-dimethyl -2,5-hexanediol; 2,5-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,5-hexanediol; 3,4-dimethyl-2 , 5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol; 4-ethyl-1,3-hexanediol; 2 -Ethyl-1,4-hexanediol; 4-ethyl-1,4-hexanediol; 2-ethyl-1,5-hexanediol; 3-ethyl-2,4-hexanediol ;4-Ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-1,3-heptanediol; 3-methyl-1,3-heptanediol Diol; 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 2-methyl-1,4 -Heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol; 5-methyl-1,4-heptanediol; 6-methyl-1 , 4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4-methyl-1,5-heptanediol; 5-methyl -1,5-heptanediol; 6-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4- Methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol; 2-methyl-2,4-heptanediol; 3-Methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol Alcohol; 2-methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5- Heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2, 6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl- 3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; 3, 6-octanediol; and mixtures thereof. 25. The composition of claim 24, wherein the primary solvent is selected from the group consisting of: 2-(1,1-dimethylpropyl)-1,3-propanediol; 2-(1,2-dimethylpropyl) -1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2-ethyl-2 -Isopropyl-1,3-propanediol; 2-methyl-2-(1-methylpropyl)-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1 , 3-propanediol; 2-tert-butyl-2-methyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2-(1-methylpropyl)-1,3 -Butanediol; 2-butyl-1,3-butanediol; 2-ethyl-2,3-dimethyl-1,3-butanediol; 2-(1,1-dimethylethyl base)-1,3-butanediol; 2-(2-methylpropyl)-1,3-butanediol; 2-methyl-2-propyl-1,3-butanediol; 2- Methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1,4-butanediol ; 2-ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1- Dimethylethyl)-1,4-butanediol; 3-methyl-2-isopropyl-1,4-butanediol; 2,2,3-trimethyl-1,3-pentanediol Alcohol; 2,2,4-trimethyl-1,3-pentanediol; 2,3,4-trimethyl-1,3-pentanediol; 2,4,4-trimethyl-1, 3-pentanediol; 3,4,4-trimethyl-1,3-pentanediol; 2,2,3-trimethyl-1,4-pentanediol; 2,2,4-trimethyl Base-1,4-pentanediol; 2,3,3-trimethyl-1,4-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 3,3, 4-Trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol; 2,3,3-Trimethyl-1,5-pentanediol; 2,3,4-trimethyl-2,4-pentanediol; 2-ethyl-2-methyl-1,3- Pentylene glycol; 2-ethyl-3-methyl-1,3-pentanediol; 2-ethyl-4-methyl-1,3-pentanediol; 3-ethyl-2-methyl- 1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-4 -Methyl-1,4-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2- Isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1,4-pentanediol Alcohol; 3-isopropyl-1,4-pentanediol; 3-propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol; 2,3-diol Methyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl -1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol; 4,4-dimethyl-1,3-hexanediol; 4,5-dimethyl-1 , 3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol; 2,4-dimethyl-1,4 -hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol Diol; 3,5-Dimethyl-1,4-hexanediol; 4,5-Dimethyl-1,4-hexanediol; 5,5-Dimethyl-1,4-hexanediol ; 2,2-dimethyl-1,5-hexanediol; 2,3-dimethyl-1,5-hexanediol; 2,4-dimethyl-1,5-hexanediol; 2 , 5-dimethyl-1,5-hexanediol; 3,3-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5 -Dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 2-ethyl- 1,3-hexanediol; 4-ethyl-1,3-hexanediol; 2-ethyl-1,4-hexanediol; 4-ethyl-1,4-hexanediol; 2-ethane Base-1,5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2 -Methyl-1,3-heptanediol; 3-methyl-1,3-heptanediol; 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol ;6-Methyl-1,3-heptanediol; 2-methyl-1,4-heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol Diol; 5-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1,5 -Heptanediol; 4-methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 6-methyl-1,5-heptanediol; 2-methyl-1 , 6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 6-methyl -1,6-heptanediol; 2-methyl-2,4-heptanediol; 3-methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; Methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-Methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol Alcohol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5- Heptanediol; 4-methyl-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3 , 5-octanediol; 3,6-octanediol; and mixtures thereof. 26. The composition of claim 25, wherein the primary solvent is selected from the group consisting of: 2-(1,1-dimethylpropyl)-1,3-propanediol; 2-(1,2-dimethylpropyl) -1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2-ethyl-2 -Isopropyl-1,3-propanediol; 2-methyl-2-(1-methylpropyl)-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1 , 3-propanediol; 2-tert-butyl-2-methyl-1,3-propanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-(2-methylpropyl )-1,3-butanediol; 2-butyl-1,3-butanediol; 2-methyl-2-propyl-1,3-butanediol; 3-methyl-2-propyl -1,3-butanediol; 2,2-diethyl-1,4-butanediol; 2-ethyl-2,3-dimethyl-1,4-butanediol; 2-ethyl -3,3-Dimethyl-1,4-butanediol; 2-(1,1-dimethylethyl)-1,4-butanediol; 2,3,4-trimethyl-1 , 3-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 2,2,3-trimethyl-1,5-pentanediol; 2,2,4-tri Methyl-1,5-pentanediol; 2,3,3-trimethyl-1,5-pentanediol; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethane Base-3-methyl-1,3-pentanediol; 2-ethyl-4-methyl-1,3-pentanediol; 3-ethyl-2-methyl-1,3-pentanediol ; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl-1,4-pentanediol; 2-ethyl-4-methyl-1,4 -pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol; 2-isopropyl-1,3 -Pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1,4-pentanediol; 3-isopropyl -1,4-pentanediol; 3-propyl-2,4-pentanediol; 2,2-dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3- Hexylene glycol; 2,4-dimethyl-1,3-hexanediol; 2,5-dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol Alcohol; 3,5-dimethyl-1,3-hexanediol; 4,4-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol; 2,4-dimethyl-1,4-hexanediol; 2, 5-Dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4-hexanediol; 3,5- Dimethyl-1,4-hexanediol; 4,5-dimethyl-1,4-hexanediol; 5,5-dimethyl-1,4-hexanediol; 2,2-dimethyl Base-1,5-hexanediol; 2,3-dimethyl-1,5-hexanediol; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl- 1,5-hexanediol; 3,3-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1, 5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol ;4-Ethyl-1,3-Hexanediol; 2-Ethyl-1,4-Hexanediol; 4-Ethyl-1,4-Hexanediol; 2-Ethyl-1,5-Hexane Diol; 3-ethyl-2,4-hexanediol; 4-ethyl-2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-1,3 -Heptanediol; 3-methyl-1,3-heptanediol; 4-methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1 , 3-heptanediol; 2-methyl-1,4-heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol; 5-methyl -1,4-heptanediol; 6-methyl-1,4-heptanediol; 2-methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4- Methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol; 6-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1,6-heptanediol; 5-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol Alcohol; 2-methyl-2,4-heptanediol; 3-methyl-2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4- Heptanediol; 6-methyl-2,4-heptanediol; 2-methyl-2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl-2, 5-heptanediol; 5-methyl-2,5-heptanediol; 6-methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl- 2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 4-methyl Base-3,5-heptanediol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; and/or 3,6-octanediol; and mixtures thereof. 27. The composition of claim 26, wherein the primary solvent is selected from the group consisting of 2,3,3,4-tetramethyl-2,4-pentanediol; 3-tert-butyl-2,4-pentanediol; 2,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2,4-hexanediol; 3,3,5-trimethyl-2,4- Hexylene glycol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl- 2,5-hexanediol; 3,3,5-trimethyl-2,5-hexanediol; and mixtures thereof. 28. The composition of claim 27, wherein the primary solvent is 2,3,3,4-tetramethyl-2,4-pentanediol. 29. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 3-(n-pentyloxy)-1,2-propanediol; 3-(2-pentyloxy)-1 , 2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3-(2-methyl-1-butoxy)-1,2-propanediol; 3-(isoamyloxy) -1,2-propanediol; 3-(3-methyl-2-butoxy)-1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohexyl -1-alkenyloxy)-1,2-propanediol; 2-(pentyloxy)-1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentane oxy)-1,3-propanediol; 2-(2-methyl-1-butoxy)-1,3-propanediol; 2-(isoamyloxy)-1,3-propanediol; 2-(3 -Methyl-2-butoxy)-1,3-propanediol; 2-(cyclohexyloxy)-1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3 - propylene glycol; triethoxylated 3-(butoxy)-1,2-propanediol; tetraethoxylated 3-(butoxy)-1,2-propanediol; pentaethoxylated 3-(butoxy)-1,2-propanediol; -(butoxy)-1,2-propanediol; hexaethoxylated 3-(butoxy)-1,2-propanediol; heptaethoxylated 3-(butoxy)-1,2 - propylene glycol; octaethoxylated 3-(butoxy)-1,2-propanediol; nonaethoxylated 3-(butoxy)-1,2-propanediol; 3-phenoxy-1 , 2-propanediol; 3-benzyloxy-1,2-propanediol; 3-(2-phenylethoxy)-1,2-propanediol; 3-(1-phenyl-2-propoxy)- 1,2-propanediol; 2-phenoxy-1,3-propanediol; 2-(m-tolyloxy)-1,3-propanediol; 2-(p-tolyloxy)-1,3-propanediol; 2 -Benzyloxy-1,3-propanediol; 2-(2-phenylethoxy)-1,3-propanediol; 2-(1-phenylethoxy)-1,3-propanediol; two (2 -hydroxybutyl) ether; bis(2-hydroxycyclopentyl) ether; and mixtures thereof. 30. The composition of claim 29, wherein the primary solvent is selected from the group consisting of: 3-(n-pentyloxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3 -(3-pentyloxy)-1,2-propanediol; 3-(2-methyl-1-butoxy)-1,2-propanediol; 3-(isoamyloxy)-1,2-propanediol ; 3-(3-methyl-2-butoxy)-1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy )-1,2-propanediol; 2-(pentyloxy)-1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1, 3-propanediol; 2-(2-methyl-1-butoxy)-1,3-propanediol; 2-(isoamyloxy)-1,3-propanediol; 2-(3-methyl-2- Butoxy)-1,3-propanediol; 2-(cyclohexyloxy)-1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; pentaethoxy 3-(butoxy)-1,2-propanediol hexaethoxylate; 3-(butoxy)-1,2-propanediol hexaethoxylate; 3-(butoxy) heptaethoxylate -1,2-propanediol; octaethoxylated 3-(butoxy)-1,2-propanediol; nonaethoxylated 3-(butoxy)-1,2-propanediol; 3-benzene Oxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3-(2-phenylethoxy)-1,2-propanediol; 2-(m-tolyloxy)-1 , 3-propanediol; 2-(p-tolyloxy)-1,3-propanediol; 2-benzyloxy-1,2-propanediol; 2-(2-phenylethoxy)-1,3-propanediol; bis(2-hydroxybutyl) ether; bis(2-hydroxycyclopentyl) ether; and mixtures thereof. 31. The composition of claim 30, wherein the primary solvent is selected from the group consisting of: 3-(n-pentyloxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3 -(3-pentyloxy)-1,2-propanediol; 3-(2-methyl-1-butoxy)-1,2-propanediol; 3-(isoamyloxy)-1,2-propanediol ; 3-(3-methyl-2-butoxy)-1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy )-1,2-propanediol; 2-(pentyloxy)-1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1, 3-propanediol; 2-(2-methyl-1-butoxy)-1,3-propanediol; 2-(isoamyloxy)-1,3-propanediol; 2-(3-methyl-2- Butoxy)-1,3-propanediol; 2-(cyclohexyloxy)-1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; pentaethoxy 3-(butoxy)-1,2-propanediol hexaethoxylate; 3-(butoxy)-1,2-propanediol hexaethoxylate; 3-(butoxy) heptaethoxylate -1,2-propanediol; octaethoxylated 3-(butoxy)-1,2-propanediol; nonaethoxylated 3-(butoxy)-1,2-propanediol; 3-benzene Oxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3-(2-phenylethoxy)-1,2-propanediol; 2-(m-tolyloxy)-1 , 3-propanediol; 2-(p-tolyloxy)-1,3-propanediol; 2-(2-phenylethoxy)-1,3-propanediol; two (2-hydroxybutyl) ether; two ( 2-hydroxycyclopentyl) ether; and mixtures thereof. 32. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1, 2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-Dimethyl-1,2-cyclopentadiol; 1,4-Dimethyl-1,2-cyclopentadiol; 2,4,5-trimethyl-1,3-cyclopentadiol Diol; 3,3-Dimethyl-1,2-cyclopentanediol; 3,4-Dimethyl-1,2-cyclopentanediol; 3,5-Dimethyl-1,2-cyclo Pentylene glycol; 3-ethyl-1,2-cyclopentanediol; 4,4-dimethyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1 , 1-bis(hydroxymethyl)cyclohexane; 1,2-bis(hydroxymethyl)cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-bis( hydroxymethyl)cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxy-cyclohexaneethanol ; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1,3- Cyclohexanediol; 2,3-Dimethyl-1,4-cyclohexanediol; 2,4-Dimethyl-1,3-cyclohexanediol; 2,5-Dimethyl-1,3 -Cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2-hydroxyethyl -1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexyl ethanol; 3-hydroxymethylcyclohexanol; 3-methyl- 1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl -1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl- 1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2 -Methyl-1,3-cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3- Cycloheptanediol; 5-Methyl-1,4-Cycloheptanediol; 6-Methyl-1,4-Cycloheptanediol; 1,3-Cyclooctanediol; 1,4-Cyclooctanediol ; 1,5-cyclooctanediol; 1,2-cyclohexanediol diethoxylate; 1,2-cyclohexanediol triethoxylate; 1,2-cyclohexanediol tetraethoxylate Compound; 1,2-cyclohexanediol pentaethoxylate; 1,2-cyclohexanediol hexaethoxylate; 1,2-cyclohexanediol heptaethoxylate; 1,2-cyclohexane Glycol octaethoxylate; 1,2-cyclohexanediol nonaethoxylate; 1,2-cyclohexanediol monopropoxylate; 1,2-cyclohexanediol monobutoxylate; 1,2-Cyclohexanediol Dibutylidene Oxide; 1,2-Cyclohexanediol Tributylidene Oxide; 1-Vinyl-2-Ethyl-1,2-Cyclobutanediol; 1,2 , 3,4-tetramethyl-3-cyclobutene-1,2-diol; 3,4-diethyl-3-cyclobutene-1,2-diol; 3-(1,1- Dimethylethyl)-3-cyclobutene-1,2-diol; 3-butyl-3-cyclobutene-1,2-diol; 1,2-dimethyl-4-methylene Base-1,2-cyclopentadiol; 1-ethyl-3-methylene-1,2-cyclopentadiol; 4-(1-propenyl)-1,2-cyclopentadiol; 1 -Ethyl-3-methyl-3-cyclopentene-1,2-diol; 1-vinyl-1,2-cyclohexanediol; 1-methyl-3-methylene-1,2 -Cyclohexanediol; 1-methyl-4-methylene-1,2-cyclohexanediol; 3-vinyl-1,2-cyclohexanediol; 4-vinyl-1,2-cyclohexanediol Hexylene glycol; 2,6-dimethyl-3-cyclohexene-1,2-diol; 6,6-dimethyl-3-cyclohexene-1,2-diol; 3,6- Dimethyl-4-cyclohexene-1,2-diol; 4,5-dimethyl-4-cyclohexene-1,2-diol; 3-cyclooctene-1,2-diol ; 4-cyclooctene-1,2-diol; 5-cyclooctene-1,2-diol; and mixtures thereof. 33. The composition of claim 32, wherein the primary solvent is selected from the group consisting of: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol ;3-Propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl Base-1,2-cyclopentadiol; 1,4-dimethyl-1,2-cyclopentadiol; 3,3-dimethyl-1,2-cyclopentadiol; 3,4-di Methyl-1,2-cyclopentadiol; 3,5-dimethyl-1,2-cyclopentadiol; 3-ethyl-1,2-cyclopentadiol; 4,4-dimethyl -1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis(hydroxymethyl)cyclohexane; 1,2-bis(hydroxymethyl)cyclohexane Alkane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-di(hydroxymethyl)cyclohexane; 1-hydroxy-cyclohexanemethanol; 1-methyl-1,2 -cyclohexanediol; 3-hydroxymethylcyclohexanol; 3-methyl-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5- Dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl- 1-cyclohexanol; 4-hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 1,2-cycloheptanediol; 1,2-cyclohexanediol pentaethoxy Compound; 1,2-cyclohexanediol hexaethoxylate; 1,2-cyclohexanediol heptaethoxylate; 1,2-cyclohexanediol octaethoxylate; 1,2-cyclohexane Diol nonaethoxylate; 1,2-cyclohexanediol monopropoxylate; 1,2-cyclohexanediol monobutoxylate; 1,2-cyclohexanediol dibutoxylate; and their mixtures. 34. The composition of any one of claims 11-15, wherein the primary solvent is selected from: 1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1,2-propanediol (C3)PO ₄ ; 2-methyl-1,2-propanediol (C4) (Me-E _{4- 10} ); 2-methyl-1,2-propanediol (C4) 2 (Me-E ₁ ); 2-methyl-1,2-propanediol (C4)PO ₃ ; 2-methyl-1,2-propanediol (C4)BO ₁ ; 1,3-propanediol (C3)2(Me-E _6-8 ); 1,3-propanediol (C3)PO _5-6 ; 2,2-diethyl-1,3-propanediol (C7) E _1-7 ; 2,2-diethyl-1,3-propanediol (C7)PO ₁ ; 2,2-diethyl-1,3-propanediol (C7)n-BO _1-2 ; 2,2-dimethyl-1,3-propanediol (C5) 2 (MeE _1-2 ); 2,2-dimethyl-1,3-propanediol (C5)PO _3-4 ; 2-(1- Methylpropyl)-1,3-propanediol (C7) E _1-7 ; 2-(1-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methylpropyl )-1,3-propanediol (C7)n-BO _1-2 ; 2-(2-methylpropyl)-1,3-propanediol (C7)E _1-7 ; 2-(2-methylpropyl )-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1,3-propanediol (C7)n-BO _1-2 ; 2-ethyl-1,3-propanediol ( C5)(MeE _6-10 ); 2-Ethyl-1,3-propanediol (C5)2( _MeE1 ); 2-Ethyl-1,3-propanediol (C5)PO3; 2-Ethyl- ₂ -Methyl-1,3-propanediol (C6) (MeE _1-6 ); 2-Ethyl-2-methyl-1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl- 1,3-propanediol (C6)BO ₁ ; 2-isopropyl-1,3-propanediol (C6) (MeE _{1 -6} ); 2-isopropyl-1,3-propanediol (C6)PO ₂ ; 2 -Isopropyl-1,3-propanediol (C6)BO ₁ ; 2-methyl-1,3-propanediol (C4)2(MeE _2-5 ); 2-methyl-1,3-propanediol (C4) PO _4-5 ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)E _2-9 ; 2-methyl- 2-isopropyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)n-BO _1-3 ; 2-methyl-2- Propyl-1,3-propanediol (C7) E _1-7 ; 2-methyl-2-propyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-propyl-1,3 -Propylene glycol (C7)n-BO _1-2 ; 2-Propyl-1,3-propanediol (C6) (MeE _1-4 ); 2-Propyl-1,3-propanediol (C6)PO ₂ ; 2- Propyl-1,3-propanediol (C6) _BO1 ; 2. 1,2-butanediol (C4) (Me-E _2-8 ); 1,2-butanediol (C4)PO _2-3 ; 1,2-butanediol (C4)BO ₁ ; 2 , 3-dimethyl-1,2-butanediol (C6) E _1-6 ; 2,3-dimethyl-1,2-butanediol (C6) n-BO _1-2 ; 2-ethane Base-1,2-butanediol (C6) E _1-3 ; 2-ethyl-1,2-butanediol (C6)n-BO ₁ ; 2-methyl-1,2-butanediol ( C5)(Me-E _1-2 ); 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _{1- 6} ; 3,3-dimethyl-1,2-butanediol (C6)n-BO _{1- 2} ; 3-methyl-1,2-butanediol (C5) (MeE _1-2 ); 3 -Methyl-1,2-butanediol (C5)PO ₁ ; 1,3-butanediol (C4) 2 (MeE _3-6 ); 1,3-butanediol (C4)PO ₅ ; 1, 3-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,3-butanediol (C7) (MeE _1-3 ); 2,2,3-trimethyl-1, 3-butanediol (C7)PO _1-2 ; 2,2-dimethyl-1,3-butanediol (C6) (MeE ₃ -8); 2,2-dimethyl-1,3- Butanediol (C6)PO ₃ ; 2,3-dimethyl-1,3-butanediol (C6) (MeE _3-8 ); 2,3-dimethyl-1,3-butanediol ( C6) PO ₃ ; 2-Ethyl-1,3-butanediol (C6) (MeE _1-6 ); 2-Ethyl-1,3-butanediol (C6)PO _2-3 ; 2-Ethyl Base-1,3-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,3-butanediol (C7)(MeE ₁ ); 2-Ethyl-2-methyl- 1,3-butanediol (C7)PO ₁ ; 2-ethyl-2-methyl-1,3-butanediol (C7)n-BO _2-4 ; 2-ethyl-3-methyl- 1,3-butanediol (C7) (MeE ₁ ); 2-ethyl-3-methyl-1,3-butanediol (C7)PO ₁ ; 2-ethyl-3-methyl-1, 3-butanediol (C7) n-BO _2-4 ; 2-isopropyl-1,3-butanediol (C7) (MeE ₁ ); 2-isopropyl-1,3-butanediol ( C7) PO ₁ ; 2-isopropyl-1,3-butanediol (C7)n-BO _2-4 ; 2-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ) ; 2-methyl-1,3-butanediol (C5)PO ₄ ; 2-propyl-1,3-butanediol (C7)E _2-9 ; 2-propyl-1,3-butanediol Alcohol (C7) PO ₁ ; 2-propyl-1,3-butanediol (C7) n-BO _1-3 ; 3-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ); 3-methyl-1,3-butanediol (C5)PO ₄ ; 1,4-butanediol (C4) 2 (MeE _2-4 ); 1,4-butanediol (C4)PO _{4 -5} ; 1,4-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,4-butanediol (C7)E _2-9 ; 2,2,3-trimethyl -1,4-butanediol (C7)PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _1-3 ; 2,2-dimethyl-1 , 4-butanediol (C6) (MeE _1-6 ); 2,2-dimethyl-1,4-butanediol (C6)PO ₂ ; 2,2-dimethyl-1,4-butane Diol (C6) BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _{1- 6} ); 2,3-dimethyl-1,4-butanediol (C6 )PO ₂ ; 2,3-dimethyl-1,4-butanediol (C6)BO ₁ ; 2-ethyl-1,4-butanediol (C6)(MeE _{1 -4} ); 2-ethane Base-1,4-butanediol (C6)PO ₂ ; 2-Ethyl-1,4-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7) E _1-7 ; 2-Ethyl-2-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7 )n-BO _1-2 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)E _1-7 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,4-butanediol (C7)n-BO _1-2 ; 2-isopropyl-1,4-butanediol (C7)E _1-7 ; 2-isopropyl-1,4-butanediol (C7)PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO _1-2 ; 2-methyl -1,4-butanediol (C5) (MeE _6-10 ); 2-methyl-1,4-butanediol (C5) 2 (MeE ₁ ); 2-methyl-1,4-butanediol Alcohol (C5)PO ₃ ; 2-methyl-1,4-butanediol (C5)BO ₁ ; 2-propyl-1,4-butanediol (C7)E _{1 -5} ; 2-propyl- 1,4-butanediol (C7)n-BO _1-2 ; 3-ethyl-1-methyl-1,4-butanediol (C7)E _2-9 ; 3-ethyl-1-methyl Base-1,4-butanediol (C7)PO ₁ ; 3-ethyl-1-methyl-1,4-butanediol (C7)n-BO _1-3 ; 2,3-butanediol ( C4) (MeE _6-10 ); 2,3-butanediol (C4) 2 (MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-dimethyl-2,3-butanediol (C6)E _3-9 ; 2,3-dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3 -Dimethyl-2,3-butanediol (C6)n-BO _1-3 ; 2-methyl-2,3-butanediol (C5)(MeE _1-5 ); 2-Methyl-2 , 3-butanediol (C5) PO ₂ ; 2-methyl-2,3-butanediol (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol (C5) n-BO _2-3 ; 2-methyl Base-1,2-pentanediol (C6) E _{1- 3} ; 2-methyl-1,2-pentanediol (C6)n-BO ₁ ; 2-methyl-1,2-pentanediol ( C6)BO ₁ ; 3-methyl-1,2-pentanediol (C6)E _1-3 ; 3-methyl-1,2-pentanediol (C6)n-BO ₁ ; 4-methyl- 1,2-pentanediol (C6) E _1-3 ; 4-methyl-1,2-pentanediol (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (MeE _{1- 2} ); 1,3-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,3-pentanediol (C7) (MeE ₁ ); 2,2-dimethyl-1 , 3-pentanediol (C7) PO ₁ ; 2,2-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,3-pentane Diol (C7) (Me-E ₁ ); 2,3-dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,3-pentanediol (C7 )n-BO _2-4 ; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 2,4-dimethyl-1,3-pentanediol (C7 )PO ₁ ; 2,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2-ethyl-1,3-pentanediol (C7)E _2-9 ; 2 -Ethyl-1,3-pentanediol (C7)PO ₁ ; 2-Ethyl-1,3-pentanediol (C7)n-BO _1-3 ; 2-methyl-1,3-pentanediol Alcohol (C6) 2 (MeE _{1- 6} ); 2-methyl-1,3-pentanediol (C6)PO _2-3 ; 2-methyl-1,3-pentanediol (C6)BO ₁ ; 3,4-Dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 3,4-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4- Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 3-methyl-1,3-pentanediol (C6)(Me-E _1-6 ); 3-methyl- 1,3-pentanediol (C6)PO _2-3 ; 3-methyl-1,3-pentanediol (C6)BO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7 )(Me-E ₁ ); 4,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 4-methyl-1,3-pentanediol (C6) (MeE _1-6 ); 4-methyl-1,3-pentanediol (C6)PO _2-3 ; 4-methyl -1,3-pentanediol (C6)BO ₁ ; 1,4-pentanediol (C5) 2 (MeE _{1- 2} ); 1,4-pentanediol (C5)PO _3-4 ; 2,2 - Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,2-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,2-Dimethyl -1,4-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,3-dimethyl -1,4-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2,4-dimethyl-1,4 - Pentanediol (C7) (Me-E ₁ ); 2,4-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2-methyl-1,4-pentanediol (C6) (MeE _1-6 ); 2-methyl-1,4-pentanediol (C6)PO _{2- 3} ; 2-methyl-1,4-pentanediol (C6)BO ₁ ; 3,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,3-di Methyl-1,4-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 3,4-Dimethyl-1 , 4-pentanediol (C7) (Me-E ₁ ); 3,4-dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,4-pentane Diol (C7) n-BO _2-4 ; 3-methyl-1,4-pentanediol (C6) 2 (Me-E _1-6 ); 3-methyl-1,4-pentanediol ( C6)PO _{2 -3} ; 3-methyl-1,4-pentanediol (C6)BO ₁ ; 4-methyl-1,4-pentanediol (C6)2(Me-E _1-6 ); 4-methyl-1,4-pentanediol (C6)PO _2-3 ; 4-methyl-1,4-pentanediol (C6)BO ₁ ; 1,5-pentanediol (C5)(Me -E _4-10 ); 1,5-pentanediol (C5) 2 (MeE ₁ ); 1,5-pentanediol (C5)PO ₃ ; 2,2-dimethyl-1,5-pentanediol Alcohol (C7) E _1-7 ; 2,2-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-Dimethyl-1,5-pentanediol (C7)n- BO _1-2 ; 2,3-dimethyl-1,5-pentanediol (C7) E _1-7 ; 2,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2 , 3-dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2,4-dimethyl-1,5-pentanediol (C7)E _1-7 ; 2,4 -Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2-Ethyl-1, 5-pentanediol (C7) E _1-5 ; 2-ethyl-1,5-pentanediol (C7) n-BO _1-2 ; 2-methyl-1,5-pentanediol (C6) (Me-E _1-4 ); 2-methyl-1,5-pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _1-7 ; 3,3-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 3-methyl -1,5-pentanediol (C6) (Me-E _1-4 ); 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) (Me -E _1-3 ); 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6)E _1-7 ; 2-methyl-2,3-pentane Diol (C6) PO ₁ ; 2-methyl-2,3-pentanediol (C6) n-BO _1-2 ; 3-methyl-2,3-pentanediol (C6) E _1-7 ; 3-methyl-2,3-pentanediol (C6)PO ₁ ; 3-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 4-methyl-2,3-pentane Diol (C6) E _1-7 ; 4-methyl-2,3-pentanediol (C6)PO ₁ ; 4-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 2,4-pentanediol (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol (C7 )(Me-E _1-4 ); 2,3-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-dimethyl-2,4-pentanediol (C7)( Me-E _1-4 ); 2,4-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2-methyl-2,4-pentanediol (C7) (Me-E _{5- 10} ); 2-methyl-2,4-pentanediol (C7)PO ₃ ; 3,3-dimethyl-2,4-pentanediol (C7) (Me-E _1-4 ); 3, 3-Dimethyl-2,4-pentanediol (C7)PO ₂ ; 3-methyl-2,4-pentanediol (C6) (Me-E _5-10 ); 3-methyl-2, 4-pentanediol (C6) _PO3 ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _2-9 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _1-3 ; 2-methyl-1,3-hexanediol (C7)BO ₁ ; 3-methyl-1,3-hexanediol (C7)E _2-9 ; 3-methyl- 1,3-hexanediol (C7)PO ₁ ; 3-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,3-hexanediol (C7) E _2-9 ; 4-methyl-1,3-hexanediol (C7)PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 5-methyl- 1,3-hexanediol (C7)E _2-9 ; 5-methyl-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n- BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7) E _2-9 ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 3-methyl-1,4-hexanediol (C7)E _2-9 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3- Methyl-1,4-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,4-hexanediol (C7)E _2-9 ; 4-methyl-1,4-hexane Diol (C7) PO ₁ ; 4-methyl-1,4-hexanediol (C7) n-BO _1-3 ; 5-methyl-1,4-hexanediol (C7) E _2-9 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6)PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7) E _2-9 ; 2-methyl-1,5-hexanediol (C7)PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 3-methyl- 1,5-hexanediol (C7)E _2-9 ; 3-methyl-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n- BO _1-3 ; 4-methyl-1,5-hexanediol (C7)E _2-9 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1, 5-hexanediol (C7)n-BO _1-3 ; 5-methyl-1,5-hexanediol (C7)E _2-9 ; 5-methyl-1,5-hexanediol (C7) PO ₁ ; 5-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 1,6-hexanediol (C6)(Me-E _1-2 ); 1,6-hexanediol Alcohol (C6) PO _1-2 ; 1,6-Hexanediol (C6) n-BO ₄ ; 2-Methyl-1,6-Hexanediol (C7) E _1-5 ; 2-Methyl-1 , 6-hexanediol (C7) n-BO _1-2 ; 3-methyl-1,6-hexanediol (C7) E _1-5 ; 3-methyl-1,6-hexanediol (C7 )n-BO _1-2 ; 2,3-hexanediol (C6)E _1-5 ; 2,3-hexanediol (C6)n-BO ₁ ; 2,3-hexanediol (C6)BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6)PO ₃ ; 2-methyl-2,4-hexanediol (C7) (Me -E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4-hexanediol (C7)(Me-E _1-2 ) ; 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 4-methyl- 2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _1-2 ); 5-methyl-2,4-hexanediol Alcohol (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-Methyl-2,5- Hexylene glycol (C7) (Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol (C6)EO _1-5 ; 3,4-hexanediol Alcohol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-Heptanediol (C7) E _1-7 ; 1,3-Heptanediol (C7)PO ₁ ; 1,3-Heptanediol (C7)n-BO _1-2 ; 1,4 -Heptanediol (C7) E _1-7 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO _1-2 ; 1,5-Heptanediol ( C7)E _1-7 ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO _1-2 ; 1,6-heptanediol (C7)E _{1- 7} ; 1,6-heptanediol (C7)PO ₁ ; 1,6-heptanediol (C7)n-BO _1-2 ; 1,7-heptanediol (C7)E _1-2 ; 1,7 -Heptanediol (C7)n-BO ₁ ; 2,4-Heptanediol (C7)E _3-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol Alcohol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me- E ₁ ); 2,5-heptanediol (C7)PO ₁ ; 2,5-heptanediol (C7)n-BO ₃ ; 2,6-heptanediol (C7)E _3-10 ; 2,6 - Heptanediol (C7) (Me-E ₁ ); 2,6-Heptanediol (C7)PO ₁ ; 2,6-Heptanediol (C7)n-BO ₃ ; 3,5-Heptanediol ( C7)E _3-10 ; 3,5-heptanediol (C7)(Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ; 6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 - Isopropyl-1,3-butanediol (C8) n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8) n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4-Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl- 2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptanediol (C8)n-BO ₁ ; 3-methyl-2,4-heptanediol (C8) n-BO ₁ ; 4-methyl-2,4-heptanediol (C8)n-BO ₁ ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl- 2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptanediol (C8)n-BO ₁ ; 3-methyl-2,5-heptanediol (C8) n-BO ₁ ; 4-methyl-2,5-heptanediol (C8)n-BO ₁ ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl- 2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptanediol (C8)n-BO ₁ ; 3-methyl-2,6-heptanediol (C8) n-BO ₁ ; 4-methyl-2,6-heptanediol (C8)n-BO ₁ ; 2-methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1, 2-Dimethylpropyl)-1,3-propanediol (C8) _E1-3 ; 2-Ethyl-2,3-dimethyl-1,3-butanediol (C8) _E1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8)E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8)E _{1- 3} ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8)E _1-3 ; 5-methyl-2,5-heptanediol (C8)E _1-3 ; 6-methyl-2,5-heptanediol (C8)E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; and 7. Their mixtures; 35. The composition of claim 34, wherein the primary solvent is selected from the group consisting of: 1. 1,2-propanediol (C3) 2 (Me-E _3-4 ); 1,2-propanediol (C3)PO ₄ ; 2-methyl-1,2-propanediol (C4) (Me-E _{8- 10} ); 2-methyl-1,2-propanediol (C4) 2 (Me-E ₁ ); 2-methyl-1,2-propanediol (C4)PO ₃ ; 1,3-propanediol (C3) 2 ( Me-E ₈ ); 1,3-propanediol (C3)PO ₆ ; 2,2-diethyl-1,3-propanediol (C7)E _4-7 ; 2,2-diethyl-1,3- Propylene glycol (C7) PO ₁ ; 2,2-diethyl-1,3-propanediol (C7)n-BO ₂ ; 2,2-dimethyl-1,3-propanediol (C5) 2 (MeE _1-2 ); 2,2-dimethyl-1,3-propanediol (C5)PO ₄ ; 2-(1-methylpropyl)-1,3-propanediol (C7)E _4-7 ; 2-(1- Methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methylpropyl)-1,3-propanediol (C7)n-BO ₂ ; 2-(2-methylpropyl )-1,3-propanediol (C7) E _4-7 ; 2-(2-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1, 3-propanediol (C7)n- _BO2 ; 2-ethyl-1,3-propanediol (C5) (MeE _9-10 ); 2-ethyl-1,3-propanediol (C5)2 ( _MeE1 ); 2-Ethyl-1,3-propanediol (C5)PO ₃ ; 2-Ethyl-2-methyl-1,3-propanediol (C6) (MeE _{3 -6} ); 2-Ethyl-2-methyl -1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl-1,3-propanediol (C6)BO ₁ ; 2-isopropyl-1,3-propanediol (C6) (MeE _{3 -6} ); 2-isopropyl-1,3-propanediol (C6)PO ₂ ; 2-isopropyl-1,3-propanediol (C6)BO ₁ ; 2-methyl-1,3-propanediol (C4 )2(MeE _4-5 ); 2-methyl-1,3-propanediol (C4)PO ₅ ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropane Base-1,3-propanediol (C7) E _6-9 ; 2-methyl-2-isopropyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-isopropyl-1, 3-propanediol (C7)n-BO _2-3 ; 2-methyl-2-propyl-1,3-propanediol (C7)E _4-7 ; 2-methyl-2-propyl-1,3- Propylene glycol (C7)PO ₁ ; 2-methyl-2-propyl-1,3-propanediol (C7)n-BO ₂ ; 2-propyl-1,3-propanediol (C6) (MeE _1-4 ); 2-Propyl-1,3-propanediol (C6) _PO2 ; 2. 1,2-butanediol (C4) (Me-E _6-8 ); 1,2-butanediol (C4)PO _2-3 ; 1,2-butanediol (C4)BO ₁ ; 2 , 3-dimethyl-1,2-butanediol (C6) E _2-6 ; 2,3-dimethyl-1,2-butanediol (C6) n-BO ₁ ; 2-ethyl- 1,2-butanediol (C6) E _1-3 ; 2-ethyl-1,2-butanediol (C6)n-BO ₁ ; 2-methyl-1,2-butanediol (C5) (Me-E _1-2 ); 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _2-5 ; 3,3-Dimethyl-1,2-butanediol (C6)n-BO ₁ ; 3-methyl-1,2-butanediol (C5)(MeE _1-2 ); 3-methyl- 1,2-butanediol (C5)PO ₁ ; 1,3-butanediol (C4) 2 (MeE _5-6 ); 1,3-butanediol (C4)BO ₂ ; 2,2,3- Trimethyl-1,3-butanediol (C7) (MeE _{1 -3} ); 2,2,3-trimethyl-1,3-butanediol (C7)PO ₂ ; 2,2-dimethyl Base-1,3-butanediol (C6) (MeE _6-8 ); 2,2-dimethyl-1,3-butanediol (C6)PO ₃ ; 2,3-dimethyl-1, 3-butanediol (C6) (MeE _{6 -8} ); 2,3-dimethyl-1,3-butanediol (C6)PO ₃ ; 2-ethyl-1,3-butanediol (C6 )(MeE _4-6 ); 2-ethyl-1,3-butanediol (C6)PO _{2 -3} ; 2-ethyl-1,3-butanediol (C6)BO ₁ ; 2-ethyl -2-Methyl-1,3-butanediol (C7) (MeE ₁ ); 2-Ethyl-2-methyl-1,3-butanediol (C7)PO ₁ ; 2-Ethyl-2 -Methyl-1,3-butanediol (C7)n-BO ₃ ; 2-Ethyl-3-methyl-1,3-butanediol (C7)(MeE ₁ ); 2-Ethyl-3 -Methyl-1,3-butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,3-butanediol (C7)n-BO ₃ ; 2-isopropyl-1, 3-butanediol (C7) (MeE ₁ ); 2-isopropyl-1,3-butanediol (C7)PO ₁ ; 2-isopropyl-1,3-butanediol (C7)n- BO ₃ ; 2-methyl-1,3-butanediol (C5) 2 (MeE _2-3 ); 2-methyl-1,3-butanediol (C5)PO ₄ ; 2-propyl-1 , 3-butanediol (C7) E _6-8 ; 2-propyl-1,3-butanediol (C7)PO ₁ ; 2-propyl-1,3-butanediol (C7) n-BO _2-3 ; 3-methyl-1,3-butanediol (C5) 2 (MeE _2-3 ); 3-methyl-1,3-butanediol (C5)PO ₄ ; 1,4-butane Diol (C4) 2 (MeE _3-4 ); 1,4-butanediol (C4)PO _4-5 ; 2,2,3-trimethyl-1,4-butanediol (C7)E _{6 -9} ; 2,2,3-trimethyl-1,4-butanediol (C7)PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _{2 -3} ; 2,2-dimethyl-1,4-butanediol (C6) (MeE _3-6 ); 2,2-dimethyl-1,4-butanediol (C6)PO ₂ ; 2 , 2-dimethyl-1,4-butanediol (C6)BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _{3- 6} ); 2,3-di Methyl-1,4-butanediol (C6)PO ₂ ; 2,3-dimethyl-1,4-butanediol (C6)BO ₁ ; 2-ethyl-1,4-butanediol ( C6)(MeE _{1 -4} ); 2-Ethyl-1,4-butanediol (C6)PO ₂ ; 2-Ethyl-2-methyl-1,4-butanediol (C7)E _{4- 7} ; 2-ethyl-2-methyl-1,4-butanediol (C7)PO ₁ ; 2-ethyl-2-methyl-1,4-butanediol (C7)n-BO ₂ ; 2-Ethyl-3-methyl-1,4-butanediol (C7) E _4-7 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)PO ₁ ; 2- Ethyl-3-methyl-1,4-butanediol (C7)n-BO ₂ ; 2-isopropyl-1,4-butanediol (C7)E _4-7 ; 2-isopropyl- 1,4-butanediol (C7)PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO ₂ ; 2-methyl-1,4-butanediol (C5)( MeE _9-10 ); 2-methyl-1,4-butanediol (C5) 2 (MeE ₁ ); 2-methyl-1,4-butanediol (C5)PO ₃ ; 2-propyl- 1,4-butanediol (C7)E _2-5 ; 2-propyl-1,4-butanediol (C7)n-BO ₁ ; 3-ethyl-1-methyl-1,4-butane Diol (C7) E _6-8 ; 3-Ethyl-1-methyl-1,4-butanediol (C7)PO ₁ ; 3-Ethyl-1-methyl-1,4-butanediol (C7)n-BO _2-3 ; 2,3-butanediol (C4)(MeE _9-10 ); 2,3-butanediol (C4)2(MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-dimethyl-2,3-butanediol (C6)E _{7 -9} ; 2,3-dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3-dimethyl-2,3-butanediol (C6)BO _2-3 ; 2-methyl-2,3-butanediol (C5) (MeE _{2 -5} ); 2-form Base-2,3-butanediol (C5)PO ₂ ; 2-methyl-2,3-butanediol (C5)BO ₁ ; 3. 1,2-pentanediol (C5) E _7-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol (C5) n-BO ₃ ; 2-methyl- 1,2-pentanediol (C6) E _1-3 ; 2-methyl-1,2-pentanediol (C6)n-BO ₁ ; 3-methyl-1,2-pentanediol (C6) E _1-3 ; 3-methyl-1,2-pentanediol (C6) n-BO ₁ ; 4-methyl-1,2-pentanediol (C6) E _1-3 ; 4-methyl- 1,2-pentanediol (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (MeE _1-2 ); 1,3-pentanediol (C5)PO _3-4 ; 2, 2-Dimethyl-1,3-pentanediol (C7) (MeE ₁ ); 2,2-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,2-Dimethyl- 1,3-pentanediol (C7)n-BO ₃ ; 2,3-dimethyl-1,3-pentanediol (C7)(Me-E ₁ ); 2,3-dimethyl-1, 3-pentanediol (C7) PO ₁ ; 2,3-dimethyl-1,3-pentanediol (C7) n-BO ₃ ; 2,4-dimethyl-1,3-pentanediol ( C7)(Me-E ₁ ); 2,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,4-dimethyl-1,3-pentanediol (C7)n- BO ₃ ; 2-ethyl-1,3-pentanediol (C7) E _6-8 ; 2-ethyl-1,3-pentanediol (C7)PO ₁ ; 2-ethyl-1,3- Pentanediol (C7) n-BO _2-3 ; 2-methyl-1,3-pentanediol (C6) 2 (MeE _4-6 ); 2-methyl-1,3-pentanediol (C6 )PO _2-3 ; 3,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 3,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,3-pentanediol (C7)n- _BO3 ; 3-methyl-1,3-pentanediol (C6)2(Me- _E4-6 ); 3-methyl-1,3-pentanediol (C6)PO _2-3 ; 4,4-dimethyl-1,3-pentanediol (C7)(Me-E ₁ ); 4,4-di Methyl-1,3-pentanediol (C7)PO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7)n-BO ₃ ; 4-methyl-1,3-pentanediol Alcohol (C6) 2 (MeE _4-6 ); 4-methyl-1,3-pentanediol (C6)PO _2-3 ; 1,4-pentanediol (C5) 2 (MeE _1-2 ); 1,4-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,2-dimethyl-1, 4-pentanediol (C7) PO ₁ ; 2,2-dimethyl-1,4-pentanediol (C7) n-BO ₃ ; 2,3-dimethyl-1,4-pentanediol ( C7)(Me-E ₁ ); 2,3-dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,4-pentanediol (C7)n- BO ₃ ; 2,4-Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,4-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2 , 4-dimethyl-1,4-pentanediol (C7)n-BO ₃ ; 2-methyl-1,4-pentanediol (C6) (MeE _4-6 ); 2-methyl-1 ,4-pentanediol (C6)PO _2-3 ; 3,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,3-dimethyl-1,4 -pentanediol (C7)PO ₁ ; 3,3-dimethyl-1,4-pentanediol (C7)n-BO ₃ ; 3,4-dimethyl-1,4-pentanediol (C7 )(Me-E ₁ ); 3,4-dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,4-pentanediol (C7)n-BO ₃ ; 3-methyl-1,4-pentanediol (C6) 2 (Me-E _4-6 ); 3-methyl-1,4-pentanediol (C6)PO _2-3 ; 4-methyl Base-1,4-pentanediol (C6) 2 (Me-E _4-6 ); 4-methyl-1,4-pentanediol (C6)PO _2-3 ; 1,5-pentanediol ( C5) (Me-E _8-10 ); 1,5-pentanediol (C5) 2 (MeE ₁ ); 1,5-pentanediol (C5)PO ₃ ; 2,2-dimethyl-1, 5-pentanediol (C7) E _4-7 ; 2,2-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-dimethyl-1,5-pentanediol ( C7)n-BO ₂ ; 2,3-dimethyl-1,5-pentanediol (C7)E _4-7 ; 2,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,5-pentanediol (C7)n-BO ₂ ; 2,4-dimethyl-1,5-pentanediol (C7)E _4-7 ; 2,4 -Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,5-pentanediol (C7)n-BO ₂ ; 2-Ethyl-1,5- Pentylene glycol (C7) E _2-5 ; 2-ethyl-1,5-pentanediol (C7) n-BO ₁ ; 2-methyl-1,5-pentanediol (C6) (Me-E _1-4 ); 2-methyl-1,5-pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _4-7 ; 3,3- Dimethyl-1,5-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,5-pentanediol (C7)n-BO ₂ ; 3-methyl-1,5-pentane Diol (C6) (Me-E _{1 -4} ); 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) (Me-E _1-3 ) ; 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6)E _4-7 ; 2-methyl-2,3-pentanediol (C6)PO ₁ ; 2-methyl-2,3-pentanediol (C6)n-BO ₂ ; 3-methyl-2,3-pentanediol (C6)E _4-7 ; 3-methyl-2,3 - pentanediol (C6) PO ₁ ; 3-methyl-2,3-pentanediol (C6) n-BO ₂ ; 4-methyl-2,3-pentanediol (C6) E _4-7 ; 4-methyl-2,3-pentanediol (C6) PO ₁ ; 4-methyl-2,3-pentanediol (C6) n-BO ₂ ; 2,4-pentanediol (C5) 2 ( Me-E _2-4 ); 2,4-pentanediol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol (C7) (Me-E _2-4 ); 2, 3-Dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-Dimethyl-2,4-pentanediol (C7) (Me-E _2-4 ); 2,4- Dimethyl-2,4-pentanediol (C7)PO ₂ ; 2-methyl-2,4-pentanediol (C7) (Me-E _8-10 ); 2-methyl-2,4- Pentylene glycol (C7) PO ₃ ; 3,3-dimethyl-2,4-pentanediol (C7) (Me-E _2-4 ); 3,3-dimethyl-2,4-pentanediol Alcohol (C7)PO ₂ ; 3-methyl-2,4-pentanediol (C6) (Me-E _8-10 ); 3-methyl-2,4-pentanediol (C6)PO ₃ ; 4. 1,3-hexanediol (C6) (Me-E _2-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _6-8 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _2-3 ; 3-methyl-1,3-hexanediol (C7)E _6-8 ; 3-methyl-1,3-hexanediol (C7)PO ₁ ; 3-methyl- 1,3-hexanediol (C7) n-BO _2-3 ; 4-methyl-1,3-hexanediol (C7) E _6-8 ; 4-methyl-1,3-hexanediol ( C7) PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _2-3 ; 5-methyl-1,3-hexanediol (C7)E _6-8 ; 5-methyl Base-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n-BO _2-3 ; 1,4-hexanediol (C6)(Me- E _2-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7)E _{6- 8} ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _2-3 ; 3-methyl-1,4 -Hexanediol (C7) E _6-8 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3-methyl-1,4-hexanediol (C7)n-BO _{2- 3} ; 4-methyl-1,4-hexanediol (C7) E _6-8 ; 4-methyl-1,4-hexanediol (C7)PO ₁ ; 4-methyl-1,4-hexane Diol (C7) n-BO _2-3 ; 5-methyl-1,4-hexanediol (C7)E _6-8 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _2-3 ; 1,5-hexanediol (C6) (Me-E _2-5 ); 1,5-hexanediol (C6 )PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7)E _6-8 ; 2-methyl-1,5-hexanediol ( C7) PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _2-3 ; 3-methyl-1,5-hexanediol (C7)E _6-8 ; 3-methanol Base-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n-BO _2-3 ; 4-methyl-1,5-hexanediol ( C7) E _6-8 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1,5-hexanediol (C7)n-BO _2-3 ; 5-methyl Base-1,5-hexanediol (C7) E _6-8 ; 5-methyl-1,5-hexanediol (C7)PO ₁ ; 5-methyl-1,5-hexanediol (C7) n-BO _2-3 ; 1,6-hexanediol (C6) (Me-E _1-2 ); 1,6-hexanediol (C6)PO _1-2 ; 1,6-hexanediol (C6 )n-BO ₄ ; 2-methyl-1,6-hexanediol (C7)E _2-5 ; 2-methyl-1,6-hexanediol (C7)n-BO ₁ ; 3-methyl -1,6-hexanediol (C7) E _2-5 ; 3-methyl-1,6-hexanediol (C7) n-BO ₁ ; 2,3-hexanediol (C6) E _2-5 ; 2,3-hexanediol (C6) n-BO ₁ ; 2,4-hexanediol (C6) (Me-E _5-8 ); 2,4-hexanediol (C6)PO ₃ ; 2- Methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4 -hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7 )(Me-E _1-2 ); 4-methyl-2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _{1 -2} ); 5-methyl-2,4-hexanediol (C7)PO _1-2 ; 2,5-hexanediol (C6) (Me-E _5-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-methyl-2,5-hexanediol (C7)(Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol Alcohol (C6) EO _2-5 ; 3,4-Hexanediol (C6) n-BO ₁ ; 5. 1,3-heptanediol (C7)E _3-6 ; 1,3-heptanediol (C7)PO ₁ ; 1,3-heptanediol (C7)n-BO ₂ ; 1,4-heptanediol Diol (C7) E _3-6 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO ₂ ; 1,5-Heptanediol (C7)E _{3 -6} ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO ₂ ; 1,6-heptanediol (C7)E _3-6 ; 1,6- Heptanediol(C7)PO ₁ ; 1,6-Heptanediol(C7)n-BO ₂ ; 1,7-Heptanediol(C7)E _1-2 ; 1,7-Heptanediol(C7)n -BO ₁ ; 2,4-Heptanediol (C7)E _7-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol (C7)PO ₁ ; 2 , 4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _7-10 ; 2,5-heptanediol (C7) (Me-E ₁ ); 2,5- Heptanediol (C7) PO ₁ ; 2,5-heptanediol (C7) n-BO ₃ ; 2,6-heptanediol (C7) E _7-10 ; 2,6-heptanediol (C7) ( Me-E ₁ ); 2,6-heptanediol (C7)PO ₁ ; 2,6-heptanediol (C7)n-BO ₃ ; 3,5-heptanediol (C7)E _7-10 ; 3 , 5-heptanediol (C7) (Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ; 6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 - Isopropyl-1,3-butanediol (C8) n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8) n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl-2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptane Diol (C8)n- _BO1 ; 3-methyl-2,4-heptanediol (C8)n- _BO1 ; 4-methyl-2,4-heptanediol (C8)n- _BO1 ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl-2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptane Diol (C8)n- _BO1 ; 3-methyl-2,5-heptanediol (C8)n- _BO1 ; 4-methyl-2,5-heptanediol (C8)n- _BO1 ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl-2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptane Diol (C8)n- _BO1 ; 3-methyl-2,6-heptanediol (C8)n- _BO1 ; 4-methyl-2,6-heptanediol (C8)n- _BO1 ; 2-Methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)E _1-3 ; 2-Ethylene Base-2,3-dimethyl-1,3-butanediol (C8) E _1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8) E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8) E _1-3 ; 5-methyl-2,5-heptanediol (C8) E _1-3 ; 6-methyl-2,5-heptanediol (C8) E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; and 7. Mixtures thereof. 36. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-benzene Base-1,2-propanediol; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3 -Propylene glycol; 2-methyl-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl- 1,4-butanediol; 2-phenyl-1,4-butanediol; 1-phenyl-2,3-butanediol; and mixtures thereof. 37. The composition of claim 36, wherein said primary solvent is selected from the group consisting of: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2- Propylene glycol; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3-propanediol; 2-methylphenyl Base-1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol alcohols; and mixtures thereof. 38. The composition of claim 37, wherein said primary solvent is selected from the group consisting of: 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3-propanediol; 2-methyl-1-phenyl-1,3-propanediol; and/or 1-phenyl-1,4-butanediol; and mixtures thereof. 39. The composition of any one of claims 11-15, wherein the main solvent is selected from the group consisting of solvents that are homologues or analogs of the following parent compounds, wherein one or more _CH groups are added, and for each One added _CH2 group removes two hydrogen atoms from adjacent carbon atoms in the molecule to form a carbon-carbon double bond, so that the number of hydrogen atoms in the molecule remains constant. The parent compound includes the following: I. Monohydric alcohols, including: a. n-propanol; and/or b. 2-butanol or 2-methyl-2-propanol; II. hexanediol isomers, including: 2,3-dimethyl-2,3-butanediol; 2,3-dimethyl Base-1,2-butanediol; 3,3-dimethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3-pentanediol Alcohol; 4-methyl-2,3-pentanediol; 2,3-hexanediol; 3,4-hexanediol; 2-ethyl-1,2-butanediol; 2-methyl-1 , 2-pentanediol; 3-methyl-1,2-pentanediol; 4-methyl-1,2-pentanediol; and/or 1,2-hexanediol; III. Heptanediol iso Constructs, including: 2-butyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2-(1-methylpropyl)-1,3-propanediol; 2-( 2-methylpropyl)-1,3-propanediol; 2-methyl-2-propyl-1,3-propanediol; 2,3,3-trimethyl-1,2-butanediol; 2- Ethyl-2-methyl-1,4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-propyl-1,4-butanediol; 2-iso Propyl-1,4-butanediol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4-dimethyl -1,5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2 , 3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4 -pentanediol; 2-ethyl-1,5-pentanediol; 2-methyl-1,6-hexanediol; 3-methyl-1,6-hexanediol; 2-methyl-2 , 3-hexanediol; 3-methyl-2,3-hexanediol; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl -3,4-hexanediol; 3-methyl-3,4-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; and/or 1 , 6-heptanediol; IV. octanediol isomers, including: 2-(2-methylbutyl)-1,3-propanediol; 2-(1,1-dimethylpropyl)-1 , 3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(1-methylbutyl base)-1,3-propanediol; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2-(3-methylbutyl)-1,3-propanediol; 2-butyl -2-methyl-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1,3-propanediol; 2-methyl- 2-(1-methylpropyl)-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl-2-methyl- 1,3-propanediol; 2,2-diethyl-1,3-butanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-butyl-1,3- Butanediol; 2-ethyl-2,3-dimethyl-1,3-butanediol; 2-(1,1-dimethylethyl)-1,3-butanediol; 2-( 2-methylpropyl)-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 2-methyl-2-propyl-1,3-butane Diol; 3-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1, 4-butanediol; 2-methyl-2-propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2-ethyl-2, 3-Dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1-dimethylethyl)-1 , 4-butanediol; 2-(2-methylpropyl)-1,4-butanediol; 2-methyl-3-propyl-1,4-butanediol; 3-methyl-2 - Isopropyl-1,4-butanediol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol; 2 , 3,4-trimethyl-1,3-pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3,4,4-trimethyl-1,3-pentanediol Diol; 2,2,3-trimethyl-1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1 , 4-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 3,3,4-trimethyl-1,4-pentanediol; 2,2,3-tri Methyl-1,5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-1,5-pentanediol; 2,3 ,4-Trimethyl-1,5-pentanediol; 2,3,3-trimethyl-2,4-pentanediol; 2,3,4-trimethyl-2,4-pentanediol ; 2-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 2-ethyl-4-methyl-1,3 -Pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl -1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol; 3-ethyl- 3-methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-3-methyl-1,5-pentanediol; 2 -Ethyl-4-methyl-1,5-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol Diol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1 , 4-pentanediol; 3-isopropyl-1,4-pentanediol; 2-isopropyl-1,5-pentanediol; 3-propyl-2,4-pentanediol; 2, 2-Dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5- Dimethyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol; 4,5-dimethyl Base-1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol; 2,4-dimethyl- 1,4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1, 4-hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,4-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,4- Hexylene glycol; 5,5-dimethyl-1,4-hexanediol; 2,2-dimethyl-1,5-hexanediol; 2,3-dimethyl-1,5-hexanediol Alcohol; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-1,5-hexanediol; 3,4-dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 2, 2-Dimethyl-1,6-hexanediol; 2,3-dimethyl-1,6-hexanediol; 2,4-dimethyl-1,6-hexanediol; 2,5- Dimethyl-1,6-hexanediol; 3,3-dimethyl-1,6-hexanediol; 3,4-dimethyl-1,6-hexanediol; 2,3-dimethyl Base-2,4-hexanediol; 2,4-dimethyl-2,4-hexanediol; 2,5-dimethyl-2,4-hexanediol; 3,3-dimethyl- 2,4-hexanediol; 3,4-dimethyl-2,4-hexanediol; 3,5-dimethyl-2,4-hexanediol; 4,5-dimethyl-2, 4-hexanediol; 5,5-dimethyl-2,4-hexanediol; 2,3-dimethyl-2,5-hexanediol; 2,4-dimethyl-2,5- Hexylene glycol; 2,5-dimethyl-2,5-hexanediol; 3,3-dimethyl-2,5-hexanediol; 3,4-dimethyl-2,5-hexanediol Alcohol; 3,3-dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol; 4-ethyl-1,3-hexanediol; 2-ethyl-1 , 4-hexanediol; 4-ethyl-1,4-hexanediol; 2-ethyl-1,5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl -2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-1,3-heptanediol; 3-methyl-1,3-heptanediol; 4- Methyl-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 2-methyl-1,4-heptanediol; 3-methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol; 5-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol Alcohol; 2-methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4-methyl-1,5-heptanediol; 5-methyl-1,5- Heptanediol; 6-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1, 6-heptanediol; 5-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol; 2-methyl-2,4-heptanediol; 3-methyl- 2,4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; Base-2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol; 6 -Methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol ;3-Methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; and/or 3,6- Octanediol; V. Nonanediol isomers, including: 2,3,3,4-tetramethyl-2,4-pentanediol; 3-tert-butyl-2,4-pentanediol; 2 , 5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2,4-hexanediol; 3,3,5-trimethyl-2,4-hexane Diol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2 , 5-hexanediol; and/or 3,3,5-trimethyl-2,5-hexanediol; VI. include the following glycerol ethers and/or di(hydroxyalkyl) ethers: 3-(n- -pentyloxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3-(2-methyl -1-butoxy)-1,2-propanediol; 3-(iso-pentyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy)-1,2- Propylene glycol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy)-1,3- Propylene glycol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1-butoxy)-1 , 3-propanediol; 2-(iso-pentyloxy)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-(cyclohexyloxy) -1,3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; triethoxylated 3-(butoxy)-1,2-propanediol; tetraethyl Oxylated 3-(butoxy)-1,2-propanediol; pentaethoxylated 3-(butoxy)-1,2-propanediol; hexaethoxylated 3-(butoxy )-1,2-propanediol; heptaethoxylated 3-(butoxy)-1,2-propanediol; octaethoxylated 3-(butoxy)-1,2-propanediol; nonaethoxylated 3-(butoxy)-1,2-propanediol; nonaethoxylated Oxylated 3-(butoxy)-1,2-propanediol; VII. includes the following saturated and unsaturated cycloaliphatic diols and their derivatives: (a) saturated diols and their derivatives, including: 1-isopropyl-1,2-cyclobutanediol; 3-ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3- Isopropyl-1,2-cyclobutanediol; 1-ethyl-1,2-cyclopentanediol; 1,2-dimethyl-1,2-cyclopentanediol; 1,4-dimethyl Base-1,2-cyclopentadiol; 2,4,5-trimethyl-1,3-cyclopentadiol; 3,3-dimethyl-1,2-cyclopentadiol; 3,4 -Dimethyl-1,2-cyclopentanediol; 3,5-dimethyl-1,2-cyclopentanediol; 3-ethyl-1,2-cyclopentanediol; 4,4-di Methyl-1,2-cyclopentanediol; 4-ethyl-1,2-cyclopentanediol; 1,1-bis(hydroxymethyl)cyclohexane; 1,2-bis(hydroxymethyl) Cyclohexane; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-di(hydroxymethyl)cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol Alcohol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxy-cyclohexaneethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol ; 1-methyl-1,2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2 , 4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-Ethyl-1,3-cyclohexanediol; 2-hydroxycyclohexaneethanol; 2-hydroxyethyl-1-cyclohexanol; 2-hydroxymethylcyclohexanol; 3-hydroxyethyl-1 -Cyclohexanol; 3-Hydroxycyclohexaneethanol; 3-Hydroxymethylcyclohexanol; 3-Methyl-1,2-cyclohexanediol; 4,4-Dimethyl-1,3-cyclohexyl Diol; 4,5-Dimethyl-1,3-cyclohexanediol; 4,6-Dimethyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol ;4-Hydroxyethyl-1-cyclohexanol; 4-Hydroxymethylcyclohexanol; 4-methyl-1,2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexyl Diol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3-cycloheptanediol; 2-methyl-1,4-cyclohexanediol Heptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; 5-methyl-1,4-cycloheptanediol; 6-methyl -1,4-Cycloheptanediol; 1,3-Cyclooctanediol; 1,4-Cyclooctanediol; 1,5-Cyclooctanediol; 1,2-Cyclohexanediol Diethoxylate ; 1,2-cyclohexanediol triethoxylate; 1,2-cyclohexanediol tetraethoxylate; 1,2-cyclohexanediol pentaethoxylate; 1,2-cyclohexanediol Alcohol hexaethoxylate; 1,2-cyclohexanediol heptaethoxylate; 1,2-cyclohexanediol octaethoxylate; 1,2-cyclohexanediol nonaethoxylate; 1 , 2-cyclohexanediol monopropoxylate; 1,2-cyclohexanediol monobutylidene oxide; 1,2-cyclohexanediol dibutylidene oxide; and/or 1,2-cyclohexane Diol tributylidene oxide; and (b) unsaturated cycloaliphatic diols including the following: 1-vinyl-2-ethyl-1,2-cyclobutanediol; 1,2,3,4- Tetramethyl-3-cyclobutene-1,2-diol; 3,4-diethyl-3-cyclobutene-1,2-diol; 3-(1,1-dimethylethyl )-3-cyclobutene-1,2-diol; 3-butyl-3-cyclobutene-1,2-diol; 1,2-dimethyl-4-methylene-1,2 -Cyclopentanediol; 1-ethyl-3-methylene-1,2-cyclopentadiol; 4-(1-propenyl)-1,2-cyclopentadiol; 1-ethyl-3 -Methyl-3-cyclopentene-1,2-diol; 1-vinyl-1,2-cyclohexanediol; 1-methyl-3-methylene-1,2-cyclohexanediol ; 1-methyl-4-methylene-1,2-cyclohexanediol; 3-vinyl-1,2-cyclohexanediol; 4-vinyl-1,2-cyclohexanediol; 2 , 6-dimethyl-3-cyclohexene-1,2-diol; 6,6-dimethyl-3-cyclohexene-1,2-diol; 3,6-dimethyl-4 -Cyclohexene-1,2-diol; 4,5-Dimethyl-4-cyclohexene-1,2-diol; 3-Cyclooctene-1,2-diol; 4-Cyclooctene ene-1,2-diol; and/or 5-cyclooctene-1,2-diol; VIII. _C3-8- diol alkoxylated derivatives, including: 1. 1,2-propanediol (C3) 2 (Me-E _11-14 ); 1,2-propanediol (C3)PO ₄ ; 1,2-propanediol (C3)BO ₁ ; 2-methyl-1,2 -Propanediol (C4) (Me-E _4-10 ); 2-Methyl-1,2-propanediol (C4)2(Me-E ₁ ); 2-Methyl-1,2-propanediol (C4)PO ₃ ; 2-methyl-1,2-propanediol (C4)n-BO _1-2 ; 1,3-propanediol (C3) 2 (Me-E _6-8 ); 1,3-propanediol (C3)PO _{5- 6} ; 2,2-diethyl-1,3-propanediol (C7) E _{1 -7} ; 2,2-diethyl-1,3-propanediol (C7)PO ₁ ; 2,2-diethyl- 1,3-propanediol (C7)n-BO _1-2 ; 2,2-dimethyl-1,3-propanediol (C5) 2 (MeE _1-2 ); 2,2-dimethyl-1,3 -Propanediol (C5)PO _{3- 4} ; 2-(1-methylpropyl)-1,3-propanediol (C7)E _1-7 ; 2-(1-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methylpropyl)-1,3-propanediol (C7)n-BO _1-2 ; 2-(2-methylpropyl)-1,3-propanediol (C7 )E _1-7 ; 2-(2-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1,3-propanediol (C7)n-BO _1-2 ; 2-ethyl-1,3-propanediol (C5) (MeE _6-10 ); 2-ethyl-1,3-propanediol (C5)2 (MeE ₁ ); 2-ethyl-1, 3-propanediol (C5) _PO3 ; 2-ethyl-1,3-propanediol (C5) _BO1 ; 2-ethyl-2-methyl-1,3-propanediol (C6) ( _MeE1-6 ); 2-Ethyl-2-methyl-1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl-1,3-propanediol (C6)BO ₁ ; 2-isopropyl-1, 3-propanediol (C6) (MeE _1-6 ); 2-isopropyl-1,3-propanediol (C6)PO ₂ ; 2-isopropyl-1,3-propanediol (C6)BO ₁ ; 2-methyl Base-1,3-propanediol (C4) 2 (MeE _2-5 ); 2-methyl-1,3-propanediol (C4)PO _4-5 ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropyl-1,3-propanediol (C7) E _2-9 ; 2-methyl-2-isopropyl-1,3-propanediol (C7)PO ₁ ; 2- Methyl-2-isopropyl-1,3-propanediol (C7)n-BO _1-3 ; 2-methyl-2-propyl-1,3-propanediol (C7)E _1-7 ; 2-methyl Base-2-propyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-propyl-1,3-propanediol (C7)n-BO _1-2 ; 2-propyl-1, 3-propanediol (C6) (MeE _11-14 ); 2-propyl-1,3-propanediol (C6)PO ₂ ; 2-propyl-1,3-propanediol (C6)BO ₁ ; 2. 1,2-butanediol (C4) (Me-E _2-8 ); 1,2-butanediol (C4)PO _2-3 ; 1,2-butanediol (C4)BO ₁ ; 2 , 3-Dimethyl-1,2-butanediol (C6)E _1-6 ; 2,3-Dimethyl-1,2-butanediol (C6)BO _1-2 ; 2-Ethyl- 1,2-butanediol (C6) E _1-3 ; 2-ethyl-1,2-butanediol (C6)BO ₁ ; 2-methyl-1,2-butanediol (C5) (Me -E _1-2 ); 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _1-6 ; 3, 3-dimethyl-1,2-butanediol (C6)BO _1-2 ; 3-methyl-1,2-butanediol (C5) (MeE _1-2 ); 3-methyl-1, 2-butanediol (C5) PO; 1,3-butanediol (C4) 2 (MeE _11-14 ); 1,3-butanediol (C4) PO ₅ ; 1,3-butanediol (C4 )BO ₂ ; 2,2,3-trimethyl-1,3-butanediol (C7) (MeE _1-3 ); 2,2,3-trimethyl-1,3-butanediol (C7 )PO _1-2 ; 2,2-dimethyl-1,3-butanediol (C6) (MeE _3-8 ); 2,2-dimethyl-1,3-butanediol (C6)PO ₃ ; 2,3-dimethyl-1,3-butanediol (C6) (MeE _{3 -8} ); 2,3-dimethyl-1,3-butanediol (C6)PO ₃ ; 2- Ethyl-1,3-butanediol (C6) (MeE _1-6 ); 2-Ethyl-1,3-butanediol (C6)PO _{2 -3} ; 2-Ethyl-1,3-butane Diol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,3-butanediol (C7) (MeE ₁ ); 2-Ethyl-2-methyl-1,3-butanediol (C7)PO ₁ ; 2-ethyl-2-methyl-1,3-butanediol (C7)n-BO _2-4 ; 2-ethyl-3-methyl-1,3-butanediol (C7)(MeE ₁ ); 2-Ethyl-3-methyl-1,3-butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,3-butanediol (C7 )n-BO _2-4 ; 2-isopropyl-1,3-butanediol (C7)(MeE ₁ ); 2-isopropyl-1,3-butanediol (C7)PO ₁ ; 2- Isopropyl-1,3-butanediol (C7)n-BO _2-4 ; 2-methyl-1,3-butanediol (C5)2(MeE _1-3 ); 2-methyl-1 , 3-butanediol (C5)PO ₄ ; 2-propyl-1,3-butanediol (C7)E _2-9 ; 2-propyl-1,3-butanediol (C7)PO ₁ ; 2-propyl-1,3-butanediol (C7)n-BO _1-3 ; 3-methyl-1,3-butanediol (C5)2(MeE _1-3 ); 3-methyl- 1,3-butanediol (C5)PO ₄ ; 1,4-butanediol (C4) 2 (MeE _2-4 ); 1,4-butanediol (C4)PO _4-5 ; 1,4- Butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,4-butanediol (C7)E _2-9 ; 2,2,3-trimethyl-1,4-butanediol Alcohol (C7) PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _1-3 ; 2,2-dimethyl-1,4-butanediol ( C6) (MeE _1-6 ); 2,2-dimethyl-1,4-butanediol (C6)PO ₂ ; 2,2-dimethyl-1,4-butanediol (C6)BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _1-6 ); 2,3-dimethyl-1,4-butanediol (C6)PO ₂ ; 2,3 -Dimethyl-1,4-butanediol (C6)BO ₁ ; 2-Ethyl-1,4-butanediol (C6) (MeE _11-14 ); 2-Ethyl-1,4-butane Diol (C6)PO ₂ ; 2-Ethyl-1,4-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7)E _1-7 ; 2-Ethyl-2-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7)n-BO _1-2 ; 2-Ethyl-3-methyl-1,4-butanediol (C7) E _1-7 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)PO ₁ ; 2 -Ethyl-3-methyl-1,4-butanediol (C7)n-BO _1-2 ; 2-isopropyl-1,4-butanediol (C7)E _1-7 ; 2-iso Propyl-1,4-butanediol (C7)PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO _{1 -2} ; 2-methyl-1,4-butanediol Alcohol (C5) (MeE _6-10 ); 2-methyl-1,4-butanediol (C5)2 (MeE ₁ ); 2-methyl-1,3-butanediol (C5)PO ₃ ; 2-methyl-1,4-butanediol (C5)BO ₁ ; 2-propyl-1,4-butanediol (C7)E _1-5 ; 2-propyl-1,4-butanediol (C7)n-BO _1-2 ; 3-ethyl-1-methyl-1,4-butanediol (C7)E _2-9 ; 3-ethyl-1-methyl-1,4-butane Diol (C7) PO ₁ ; 3-Ethyl-1-methyl-1,4-butanediol (C7)n-BO _1-3 ; 2,3-butanediol (C4) (MeE _1-6 ); 2,3-butanediol (C4) 2 (MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-butanediol (C4)BO ₁ ; 2,3- Dimethyl-2,3-butanediol (C6) E _3-9 ; 2,3-dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3-dimethyl-2, 3-butanediol (C6)BO _1-3 ; 2-methyl-2,3-butanediol (C5) (MeE _1-5 ); 2-methyl-2,3-butanediol (C5) 2PO ₂ ; 2-methyl-2,3-butanediol (C5)n-BO ₁ ; 2-methyl-2,3-butanediol (C5)BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol (C5) n-BO _2-3 ; 2-methyl Base-1,2-pentanediol (C6) E _{1- 3} ; 2-methyl-1,2-pentanediol (C6)n-BO ₁ ; 2-methyl-1,2-pentanediol ( C6)BO ₁ ; 3-methyl-1,2-pentanediol (C6)E _1-3 ; 3-methyl-1,2-pentanediol (C6)n-BO ₁ ; 3-methyl- 1,2-pentanediol (C6)BO ₁ ; 4-methyl-1,2-pentanediol (C6)E _1-3 ; 4-methyl-1,2-pentanediol (C6)n- BO ₁ ; 4-methyl-1,2-pentanediol (C6)BO ₁ ; 1,3-pentanediol (C5) 2 (MeE _1-2 ); 1,3-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,3-pentanediol (C7) (MeE ₁ ); 2,2-dimethyl-1,3-pentanediol (C7)PO ₁ ; 2, 2-Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,3-Dimethyl-1,3-pentanediol (C7)(Me-E ₁ ); 2, 3-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,3-Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,4-dimethyl Base-1,3-pentanediol (C7)(Me-E ₁ ); 2,4-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1, 3-pentanediol (C7)n-BO _2-4 ; 2-ethyl-1,3-pentanediol (C7)E _2-9 ; 2-ethyl-1,3-pentanediol (C7) PO ₁ ; 2-Ethyl-1,3-pentanediol (C7)n-BO _1-3 ; 2-methyl-1,3-pentanediol (C6)2(MeE _1-6 ); 2- Methyl-1,3-pentanediol (C6)PO _2-3 ; 2-methyl-1,3-pentanediol (C6)n-BO ₁ ; 2-methyl-1,3-pentanediol (C6)BO ₁ ; 3,4-dimethyl-1,3-pentanediol (C7)(Me-E ₁ ); 3,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,3-pentanediol (C7) n-BO _2-4 ; 3-methyl-1,3-pentanediol (C6) 2 (Me-E _1-6 ); 3-methyl-1,3-pentanediol (C6)PO _2-3 ; 3-methyl-1,3-pentanediol (C6)n-BO ₁ ; 3-methyl-1,3 -Pentanediol (C6)BO ₁ ; 4,4-Dimethyl-1,3-pentanediol (C7)(Me-E ₁ ); 4,4-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 4-methyl-1,3-pentanediol (C6) 2 (MeE _{1 -6} ); 4-methyl-1,3-pentanediol (C6)PO _2-3 ; 4-methyl-1,3-pentanediol (C6)BO ₁ ; 1,4-pentanediol ( C5)2(MeE _1-2 ); 1,4-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,2-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,2-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2,3- Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,3-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,3-Dimethyl- 1,4-pentanediol (C7)n-BO _2-4 ; 2,4-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,4-dimethyl- 1,4-pentanediol (C7)PO ₁ ; 2,4-dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2-methyl-1,4-pentanediol (C6)(MeE _1-6 ); 2-methyl-1,4-pentanediol (C6)PO _{4 -3} ; 2-methyl-1,4-pentanediol (C6)n-BO ₁ ; 2-Methyl-1,4-pentanediol (C6)BO ₁ ; 3,3-Dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,3-Dimethyl -1,4-pentanediol (C7)PO ₁ ; 3,3-dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 3,4-dimethyl-1,4 - Pentanediol (C7) (Me-E ₁ ); 3,4-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,4-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 3-methyl-1,4-pentanediol (C6) 2 (Me-E _1-6 ); 3-methyl-1,4-pentanediol (C6) PO _2-3 ; 3-methyl-1,4-pentanediol (C6)BO ₁ ; 4-methyl-1,4-pentanediol (C6)2(Me-E _1-6 ); 4- Methyl-1,4-pentanediol (C6)PO _{2 -3} ; 4-methyl-1,4-pentanediol (C6)BO ₁ ; 1,5-pentanediol (C5)(Me-E _4-10 ); 1,5-pentanediol (C5) 2 (MeE ₁ ); 1,5-pentanediol (C5)PO ₃ ; 2,2-dimethyl-1,5-pentanediol ( C7) E _1-7 ; 2,2-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-dimethyl-1,5-pentanediol (C7)n-BO _{1 -2} ; 2,3-dimethyl-1,5-pentanediol (C7) E _{1- 7} ; 2,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,3 -Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2,4-dimethyl-1,5-pentanediol (C7)E _1-7 ; 2,4-di Methyl-1,5-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2-Ethyl-1,5- Pentanediol (C7) E _1-5 ; 2-ethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2-methyl-1,5-pentanediol (C6) (Me -E _11-14 ); 2-methyl-1,5-pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _1-7 ; 3, 3-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 3-methyl-1 , 5-pentanediol (C6) (Me-E _11-14 ); 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) (Me-E _1-3 ); 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6)E _1-7 ; 2-methyl-2,3-pentanediol (C6)PO ₁ ; 2-methyl-2,3-pentanediol (C6)n-BO _1- 2 ; 3-methyl-2,3-pentanediol (C6)E _1-7 ; 3- Methyl-2,3-pentanediol (C6)PO ₁ ; 3-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 4-methyl-2,3-pentanediol (C6) E _1-7 ; 4-methyl-2,3-pentanediol (C6)PO ₁ ; 4-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 2, 4-pentanediol (C5) 2 (Me-E _11-14 ); 2,4-pentanediol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol (C7) ( Me-E _11-14 ); 2,3-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-dimethyl-2,4-pentanediol (C7)(Me- E _11-14 ); 2,4-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2-methyl-2,4-pentanediol (C7) (Me-E _5-10 ) ; 2-methyl-2,4-pentanediol (C7)PO ₃ ; 3,3-dimethyl-2,4-pentanediol (C7) (Me-E _11-14 ); 3,3- Dimethyl-2,4-pentanediol (C7)PO ₂ ; 3-methyl-2,4-pentanediol (C6) (Me-E _5-10 ); 3-methyl-2,4- Pentylene glycol (C6) PO ₃ ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _2-9 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _1-3 ; 2-methyl-1,3-hexanediol (C7)BO ₁ ; 3-methyl-1,3-hexanediol (C7)E _2-9 ; 3-methyl- 1,3-hexanediol (C7)PO ₁ ; 3-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,3-hexanediol (C7) E _2-9 ; 4-methyl-1,3-hexanediol (C7)PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 5-methyl- 1,3-hexanediol (C7)E _2-9 ; 5-methyl-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n- BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7) E _2-9 ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 3-methyl-1,4-hexanediol (C7)E _2-9 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3- Methyl-1,4-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,4-hexanediol (C7)E _2-9 ; 4-methyl-1,4-hexane Diol (C7) PO ₁ ; 4-methyl-1,4-hexanediol (C7) n-BO _1-3 ; 5-methyl-1,4-hexanediol (C7) E _2-9 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6)PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7) E _2-9 ; 2-methyl-1,5-hexanediol (C7)PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 3-methyl- 1,5-hexanediol (C7)E _2-9 ; 3-methyl-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n- BO _1-3 ; 4-methyl-1,5-hexanediol (C7)E _2-9 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1, 5-hexanediol (C7)n-BO _1-3 ; 5-methyl-1,5-hexanediol (C7)E _2-9 ; 5-methyl-1,5-hexanediol (C7) PO ₁ ; 5-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 1,6-hexanediol (C6)(Me-E _1-2 ); 1,6-hexanediol Alcohol (C6) PO _1-2 ; 1,6-Hexanediol (C6) n-BO ₄ ; 2-Methyl-1,6-Hexanediol (C7) E _1-5 ; 2-Methyl-1 , 6-hexanediol (C7) n-BO _1-2 ; 3-methyl-1,6-hexanediol (C7) E _1-5 ; 3-methyl-1,6-hexanediol (C7 )n-BO _1-2 ; 2,3-hexanediol (C6)E _1-5 ; 2,3-hexanediol (C6)n-BO ₁ ; 2,3-hexanediol (C6)BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6)PO ₃ ; 2-methyl-2,4-hexanediol (C7) (Me -E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4-hexanediol (C7)(Me-E _1-2 ) ; 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 4-methyl- 2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _1-2 ); 5-methyl-2,4-hexanediol Alcohol (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-Methyl-2,5- Hexylene glycol (C7) (Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol (C6)EO _1-5 ; 3,4-hexanediol Alcohol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-Heptanediol (C7) E _1-7 ; 1,3-Heptanediol (C7)PO ₁ ; 1,3-Heptanediol (C7)n-BO _1-2 ; 1,4 -Heptanediol (C7) E _1-7 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO _1-2 ; 1,5-Heptanediol ( C7)E _1-7 ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO _1-2 ; 1,6-heptanediol (C7)E _{1- 7} ; 1,6-heptanediol (C7)PO ₁ ; 1,6-heptanediol (C7)n-BO _1-2 ; 1,7-heptanediol (C7)E _1-2 ; 1,7 -Heptanediol (C7)n-BO ₁ ; 2,4-Heptanediol (C7)E _3-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol Alcohol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me- E ₁ ); 2,5-heptanediol (C7)PO ₁ ; 2,5-heptanediol (C7)n-BO ₃ ; 2,6-heptanediol (C7)E _3-10 ; 2,6 - Heptanediol (C7) (Me-E ₁ ); 2,6-Heptanediol (C7)PO ₁ ; 2,6-Heptanediol (C7)n-BO ₃ ; 3,5-Heptanediol ( C7)E _3-10 ; 3,5-heptanediol (C7)(Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ; 6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 -Isopropyl-1,4-butanediol (C8)n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl-2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptane Diol (C8)n- _BO1 ; 3-methyl-2,4-heptanediol (C8)n- _BO1 ; 4-methyl-2,4-heptanediol (C8)n- _BO1 ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl-2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptane Diol (C8)n- _BO1 ; 3-methyl-2,5-heptanediol (C8)n- _BO1 ; 4-methyl-2,5-heptanediol (C8)n- _BO1 ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl-2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptane Diol (C8)n- _BO1 ; 3-methyl-2,6-heptanediol (C8)n- _BO1 ; 4-methyl-2,6-heptanediol (C8)n- _BO1 ; 2-Methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)E _1-3 ; 2-Ethylene Base-2,3-dimethyl-1,3-butanediol (C8) E _1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8) E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 2} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8) E _1-3 ; 5-methyl-2,5-heptanediol (C8) E _1-3 ; 6-methyl-2,5-heptanediol (C8) E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; and 7. Their mixtures; IX. Including the following aromatic diols: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol ; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3-propanediol; 2-methyl -1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol ; 2-phenyl-1,4-butanediol; and/or 1-phenyl-2,3-butanediol; and X. Mixtures thereof. 40. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 2,2-di-2-propenyl-1,3-propanediol; 2-(1-pentenyl)- 1,3-propanediol; 2-(2-methyl-2-propenyl)-2-(2-propenyl)-1,3-propanediol; 2-(3-methyl-1-butenyl)- 1,3-propanediol; 2-(4-pentenyl)-1,3-propanediol; 2-ethyl-2-(2-methyl-2-propenyl)-1,3-propanediol; 2-ethane Base-2-(2-propenyl)-1,3-propanediol; 2-methyl-2-(3-methyl-3-butenyl)-1,3-propanediol; 2,2-allyl -1,3-butanediol; 2-(1-ethyl-1-propenyl)-1,3-butanediol; 2-(2-butenyl)-2-methyl-1,3- Butanediol; 2-(3-methyl-2-butenyl)-1,3-butanediol; 2-ethyl-2-(2-propenyl)-1,3-butanediol; 2 -Methyl-2-(1-methyl-2-propenyl)-1,3-butanediol; 2,3-bis(1-methylethylene)-1,4-butanediol; 2 -(3-methyl-2-butenyl)-3-methylene-1,4-butanediol; 2-(1,1-dimethylpropyl)-2-butene-1,4 -diol; 2-(1-methylpropyl)-2-butene-1,4-diol; 2-butyl-2-butene-1,4-diol; 2-vinyl-3 -Ethyl-1,3-pentanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1,4 -Pentanediol; 2-(1-propenyl)-1,5-pentanediol; 2-(2-propenyl)-1,5-pentanediol; 2-ethylidene-3-methyl- 1,5-pentanediol; 2-propylene-1,5-pentanediol; 3-ethylene-2,4-dimethyl-2,4-pentanediol; 2-(1,1 -Dimethylethyl)-4-pentene-1,3-diol; 2-ethyl-2,3-dimethyl-4-pentene-1,3-diol; 4-ethyl- 2-methylene-1,4-hexanediol; 2,3,5-trimethyl-1,5-hexadiene-3,4-diol; 5-ethyl-3-methyl-1 , 5-hexadiene-3,4-diol; 2-(1-methylvinyl)-1,5-hexanediol; 2-vinyl-1,6-hexanediol; 5,5- Dimethyl-1-hexene-3,4-diol; 5,5-dimethyl-1-hexene-3,4-diol; 4-vinyl-2,5-dimethyl-2 -Hexene-1,5-diol; 2-vinyl-2,5-dimethyl-3-hexene-1,6-diol; 2-ethyl-3-hexene-1,6- Diol; 3,4-Dimethyl-3-hexene-1,6-diol; 2,5-Dimethyl-4-hexene-2,3-diol; 3,4-Dimethyl -4-hexene-2,3-diol; 3-(2-propenyl)-5-hexene-1,3-diol; 2,3-dimethyl-5-hexene-2,3 -diol; 3,4-dimethyl-5-hexene-2,3-diol; 3,5-dimethyl-5-hexene-2,3-diol; 3-vinyl-2 , 5-dimethyl-5-hexene-2,4-diol; 6-methyl-5-methylene-1,4-heptanediol; 2,3-dimethyl-1,5- Heptadiene-3,4-diol; 2,5-Dimethyl-1,5-heptadiene-3,4-diol; 3,5-Dimethyl-1,5-heptadiene- 3,4-diol; 2,6-di(methylene)-1,7-heptanediol; 4-methylene-1,7-heptanediol; 2,4-dimethyl-1- Heptene-3,5-diol; 2,6-dimethyl-1-heptene-3,5-diol; 3-vinyl-5-methyl-1-heptene-3,5-diol alcohol; 6,6-dimethyl-1-heptene-3,5-diol; 4,6-dimethyl-2,4-heptadiene-2,6-diol; 4,4-diol Methyl-2,5-heptadiene-1,7-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 5,6-dimethyl -2-heptene-1,4-diol; 5-ethyl-2-heptene-1,5-diol; 2-methyl-2-heptene-1,7-diol; 4,6 -Dimethyl-3-heptene-1,5-diol; 3-methyl-6-methylene-3-heptene-1,7-diol; 2,4-dimethyl-3- Heptene-2,5-diol; 2,5-dimethyl-3-heptene-2,5-diol; 2,6-dimethyl-3-heptene-2,6-diol; 4,6-Dimethyl-3-heptene-2,6-diol; 2,4-dimethyl-5-heptene-1,3-diol; 3,6-dimethyl-5- Heptene-1,3-diol; 2,6-Dimethyl-5-heptene-1,4-diol; 3,6-Dimethyl-5-heptene-1,4-diol; 2,3-Dimethyl-5-heptene-2,4-diol; 2,2-dimethyl-6-heptene-1,3-diol; 4-(2-propenyl)-6 -Heptene-1,4-diol; 5,6-Dimethyl-6-heptene-1,4-diol; 2,4-Dimethyl-6-heptene-1,5-diol ; 2-Ethylene-6-methyl-6-heptene-1,5-diol; 4-(2-propenyl)-6-heptene-2,4-diol; 5,5-diol Methyl-6-heptene-2,4-diol; 4,6-dimethyl-6-heptene-2,5-diol; 5-vinyl-4-methyl-6-heptene- 2,5-diol; 2-methylene-1,3-octanediol; 2,6-dimethyl-1,6-octadiene-3,5-diol; 3,7-dimethyl Base-1,6-octadiene-3,5-diol; 2,6-dimethyl-1,7-octadiene-3,6-diol; 2,7-dimethyl-1, 7-octadiene-3,6-diol; 3,6-dimethyl-1,7-octadiene-3,6-diol; 3-vinyl-1-octene-3,6- Diol; 2,7-Dimethyl-2,4,6-octatriene-1,8-diol; 3,7-Dimethyl-2,4-octadiene-1,7-diol ; 2,6-Dimethyl-2,5-octadiene-1,7-diol; 3,7-Dimethyl-2,5-octadiene-1,7-diol; 3,7 -Dimethyl-2,6-octadiene-1,4-diol (Rosiridol); 2-methyl-2,6-octadiene-1,8-diol; 3,7-dimethyl -2,7-octadiene-1,4-diol; 2,6-dimethyl-2,7-octadiene-1,5-diol; 2,6-dimethyl-2,7 -octadiene-1,6-diol (8-hydroxylinalool); 2,7-dimethyl-2,7-octadiene-1,6-diol; 2-octene-1, 4-diol; 2-octene-1,7-diol; 2-methyl-6-methylene-2-octene-1,7-diol; 3,7-dimethyl-3, 5-octadiene-1,7-diol; 2,7-dimethyl-3,5-octadiene-2,7-diol; 4-methylene-3,5-octanediol; 2,6-Dimethyl-3,7-octadiene-1,6-diol; 2,7-dimethyl-3,7-octadiene-2,5-diol; 2,6- Dimethyl-3,7-octadiene-2,6-diol; 4-methyl-3-octene-1,5-diol; 5-methyl-3-octene-1,5- Diol; 2,2-Dimethyl-4,6-octadiene-1,3-diol; 2,6-Dimethyl-4,7-octadiene-2,3-diol; 2 , 6-Dimethyl-4,7-octadiene-2,6-diol; 7-methyl-4-octene-1,6-diol; 2,7-bis(methylene)- ;2-methylene-;2,7-dimethyl-5,7-octadiene-1,4-diol; 7-methyl-5,7-octadiene-1,4-diol ;5-octene-1,3-diol; 7-methyl-6-octene-1,3-diol; 7-methyl-6-octene-1,4-diol; 6-octene ene-1,5-diol; 7-methyl-6-octene-1,5-diol; 2-methyl-6-octene-3,5-diol; 4-methyl-6- Octene-3,5-diol; 2-methyl-7-octene-1,3-diol; 4-methyl-7-octene-1,3-diol; 7-methyl-7 -octene-1,3-diol; 7-octene-1,5-diol; 7-octene-1,6-diol; 5-methyl-7-octene-1,6-diol Alcohol; 2-methyl-6-methylene-7-octene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene ene-3,5-diol; 1-nonene-3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 8-methyl- 4,6-nonadiene-1,3-diol; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-nonene-2,4 -diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol; 1,9-decadiene - 4,6-diols; and mixtures thereof. 41. The composition of any one of claims 11-15, wherein the primary solvent is selected from the group consisting of: 2,2-allyl-1,3-butanediol; 2-(1-ethyl-1-propene base)-1,3-butanediol; 2-(2-butenyl)-2-methyl-1,3-butanediol; 2-(3-methyl-2-butenyl)-1 , 3-butanediol; 2-ethyl-2-(2-propenyl)-1,3-butanol; 2-methyl-2-(1-methyl-2-propenyl)-1,3 -Butanediol; 2,3-bis(1-methylethylene)-1,4-butanediol; 2-vinyl-3-ethyl-1,3-pentanediol; 2-vinyl -4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1,4-pentanediol; 2-(1,1-dimethylethane base)-4-pentene-1,3-diol; 2-ethyl-2,3-dimethyl-4-pentene-1,3-diol; 4-ethyl-2-methylene -1,4-hexanediol; 2,3,5-trimethyl-1,5-hexadiene-3,4-diol; 2-(1-methylvinyl)-1,5-hexane Diol; 4-vinyl-2,5-dimethyl-2-hexene-1,5-diol; 6-methyl-5-methylene-1,4-heptanediol; 4,6 -Dimethyl-2,4-heptadiene-2,6-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 5,6-diol Methyl-2-heptene-1,4-diol; 4,6-dimethyl-3-heptene-1,5-diol; 2,4-dimethyl-5-heptene-1, 3-diol; 3,6-dimethyl-5-heptene-1,3-diol; 2,6-dimethyl-5-heptene-1,4-diol; 3,6-diol Methyl-5-heptene-1,4-diol; 2,2-dimethyl-6-heptene-1,3-diol; 5,6-dimethyl-6-heptene-1, 4-Diol; 2,4-Dimethyl-6-heptene-1,5-diol; 2-Ethylene-6-methyl-6-heptene-1,5-diol; 4- (2-propenyl)-6-heptene-2,4-diol; 3-vinyl-1-octene-3,6-diol; 2,7-dimethyl-2,4,6- Octatriene-1,8-diol; 2,6-Dimethyl-2,5-octadiene-1,7-diol; 3,7-Dimethyl-2,5-octadiene- 1,7-diol; 3,7-dimethyl-2,6-octadiene-1,4-diol (Rosiridol); 2-methyl-2,6-octadiene-1,8- Diol; 3,7-Dimethyl-2,7-octadiene-1,4-diol; 2,6-Dimethyl-2,7-octadiene-1,5-diol; 2 , 6-Dimethyl-2,7-octadiene-1,6-diol (8-hydroxylinalool); 2,7-dimethyl-2,7-octadiene-1,6- Diol; 2-methyl-6-methylene-2-octene-1,7-diol; 2,7-dimethyl-3,5-octadiene-2,7-diol; 4 -methylene-3,5-octanediol; 2,6-dimethyl-3,7-octadiene-1,6-diol; 2-methylene-4-octene-1,8 -diol; 2-methyl-6-octene-3,5-diol; 4-methyl-6-octene-3,5-diol; 2-methyl-6-methylene-7 -octene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene-3,5-diol; 1-nonene- 3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 4-nonene-2,8-diol; 6,8-nonadiene -1,5-diol; 7-nonene-2,4-diol; 8-nonene-2,4-diol; 8-nonene-2,5-diol; 1,9-decanediol ene-3,8-diol; 1,9-decadiene-4,6-diol; and mixtures thereof. 42. The composition of any one of claims 11-15, wherein the softener active contains up to about 20% of wherein m is 2 and a YR ¹ is -OH, -N(R)H or -C(O) OH monoester compound. 43. The composition of any one of claims 11-15, wherein the weight ratio of softener active to primary solvent is from about 55:45 to about 85: 15; when with the water content of about 15% to about 70%, the weight ratio of softener active material and main solvent is about 45:55 to about 70:30; And when with the high water content of about 70% to about 80% When present, the weight ratio of softener active matter to primary solvent is about 30:70 to about 55:45. 44. The composition of claim 43, wherein when at a low water content of about 5% to about 15%, the weight ratio of softener active to primary solvent is about 60:40 to about 80:20; % to about 70% water content, the weight ratio of the softener active to the main solvent is about 55:45 to about 70:30; and when with a high water content of about 70% to about 80%, the softener active The weight ratio of the compound to the main solvent is from about 35:65 to about 45:55. 45. The composition of claim 11 , which is translucent or transparent at 25° C., the composition contains a solvent other than the main solvent B, the main solvent B being present in an amount of at least about 5% by weight of the composition, The composition was not translucent or transparent at 25°C without the main solvent B. 46. The composition of any one of claims 11-15, comprising one or more of the following optional ingredients: (a) a whitening agent in an amount of from about 0.005% to about 5%; (b) Dispersing aid at an amount from about 2% to about 25%; (c) soil release agent at an amount from 0% to about 10%; (d) scum dispersant at an amount from about 2% to about 10%; (e ) a stabilizer selected from the group consisting of antioxidants, reducing agents, chelating agents, and mixtures thereof in an amount of 0% to about 2%; (f) a bactericide in an amount of from about 0.005% to about 5%; and (g) an amount of from about 0.5% to about 10% of a chelating agent other than any chelating agent in (e). 47. A premix of the components of any one of claims 11-15, consisting essentially of said biodegradable fabric softener active A; said primary solvent B; and optionally said water-soluble Solvent C composition. 48. An article of manufacture comprising the composition of claim 11 in a transparent bottle. 49. The article of claim 48, wherein the bottle has a bluish shade sufficient to compensate for any bluishness of the composition. 50. The article of claim 49, wherein the bottle has an ultraviolet light absorber incorporated into the wall of the bottle to protect the composition. 51. A composition comprising: A. about 2% to about 80% of a biodegradable fabric softener active selected from the group consisting of: 1. A softener having the following formula: [(R) _4-m -N ⁽⁺⁾ -[(CH ₂ ) _n -YR ¹ ] _m ]X ^(-) (1) wherein each R substituent is H, or short chain C _1-6 alkyl or hydroxyalkyl, benzyl, or mixtures thereof; each m is 2 or 3; each n is 1 to about 4; each Y is -O-(O)C-, -(R)N-(O)C-, -C(O)-N(R)-, or -C(O)-O-, each R ¹ or When Y is -O-(O)C- or -(R)N-(O)C-, the sum of the carbon numbers in YR ¹ plus 1 is C _6-22 , but when a R ¹ or YR ¹ When the sum of the carbon numbers of R1 or YR1 is less than about 12, the sum of the carbon numbers in the other ^R1 or ^YR1 is at least about 16, wherein each ^R1 is a long chain hydrocarbyl, or a substituted hydrocarbyl substituent, and for _C15 containing _-21 straight chain alkyl or alkylene R ¹ or YR ¹ , the iodine value of the fatty acid containing the R ¹ group is from about 20 to about 140, and wherein the counter ion X ^(-) can be any Tolerant anions; 2. A softener having the following formula: wherein Y, R, R ¹ , and X ^(-) each have the same meaning as previously described; and 3. Mixtures thereof; B. Less than about 40% by weight of the composition of a primary alcoholic solvent selected from the group consisting of: I. Monohydric alcohols, comprising: a. n-propanol; and/or b. 2-butanol and/or 2-methyl-2-propanol; II. Hexylene glycol isomers, including: 2,3-dimethyl-2,3-butanediol; 2,3-diol Methyl-1,2-butanediol; 3,3-dimethyl-1,2-butanediol; 2-methyl-2,3-pentanediol; 3-methyl-2,3-pentanediol Diol; 4-methyl-2,3-pentanediol; 2,3-hexanediol; 3,4-hexanediol; 2-ethyl-1,2-butanediol; 2-methyl- 1,2-pentanediol; 3-methyl-1,2-pentanediol; 4-methyl-1,2-pentanediol; and/or 1,2-hexanediol; III. Heptanediol Isomers, including: 2-butyl-1,3-propanediol; 2,2-diethyl-1,3-propanediol; 2-(1-methylpropyl)-1,3-propanediol; 2- (2-methylpropyl)-1,3-propanediol; 2-methyl-2-propyl-1,3-propanediol; 2,3,3-trimethyl-1,2-propanediol; 2-ethane 2-methyl-1,4-butanediol; 2-ethyl-3-methyl-1,4-butanediol; 2-propyl-1,4-butanediol; 2-isopropyl Base-1,4-butanediol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4-dimethyl- 1,5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2, 3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4- Pentylene glycol; 2-ethyl-1,5-pentanediol; 2-methyl-1,6-hexanediol; 3-methyl-1,6-hexanediol; 2-methyl-2, 3-hexanediol; 3-methyl-2,3-hexanediol; 4-methyl-2,3-hexanediol; 5-methyl-2,3-hexanediol; 2-methyl- 3,4-hexanediol; 3-methyl-3,4-hexanediol; 1,3-heptanediol; 1,4-heptanediol; 1,5-heptanediol; and/or 1, 6-heptanediol; IV. octanediol isomers, including: 2-(2-methylbutyl)-1,3-propanediol; 2-(1,1-dimethylpropyl)-1, 3-propanediol; 2-(1,2-dimethylpropyl)-1,3-propanediol; 2-(1-ethylpropyl)-1,3-propanediol; 2-(1-methylbutyl )-1,3-propanediol; 2-(2,2-dimethylpropyl)-1,3-propanediol; 2-(3-methylbutyl)-1,3-propanediol; 2-butyl- 2-methyl-1,3-propanediol; 2-ethyl-2-isopropyl-1,3-propanediol; 2-ethyl-2-propyl-1,3-propanediol; 2-methyl-2 -(1-methylpropyl)-1,3-propanediol; 2-methyl-2-(2-methylpropyl)-1,3-propanediol; 2-tert-butyl-2-methyl-1 , 3-propanediol; 2,2-diethyl-1,3-butanediol; 2-(1-methylpropyl)-1,3-butanediol; 2-butyl-1,3-butanediol Diol; 2-ethyl-2,3-dimethyl-1,3-butanediol; 2-(1,1-dimethylethyl)-1,3-butanediol; 2-(2 -methylpropyl)-1,3-butanediol; 2-methyl-2-isopropyl-1,3-butanediol; 2-methyl-2-propyl-1,3-butanediol Alcohol; 3-methyl-2-isopropyl-1,3-butanediol; 3-methyl-2-propyl-1,3-butanediol; 2,2-diethyl-1,4 -Butanediol; 2-methyl-2-propyl-1,4-butanediol; 2-(1-methylpropyl)-1,4-butanediol; 2-ethyl-2,3 -Dimethyl-1,4-butanediol; 2-ethyl-3,3-dimethyl-1,4-butanediol; 2-(1,1-dimethylethyl)-1, 4-butanediol; 2-(2-methylpropyl)-1,4-butanediol; 2-methyl-3-propyl-1,4-butanediol; 3-methyl-2- Isopropyl-1,4-butanediol; 2,2,3-trimethyl-1,3-pentanediol; 2,2,4-trimethyl-1,3-pentanediol; 2, 3,4-Trimethyl-1,3-pentanediol; 2,4,4-trimethyl-1,3-pentanediol; 3,4,4-trimethyl-1,3-pentanediol Alcohol; 2,2,3-trimethyl-1,4-pentanediol; 2,2,4-trimethyl-1,4-pentanediol; 2,3,3-trimethyl-1, 4-pentanediol; 2,3,4-trimethyl-1,4-pentanediol; 3,3,4-trimethyl-1,4-pentanediol; 2,2,3-trimethyl Base-1,5-pentanediol; 2,2,4-trimethyl-1,5-pentanediol; 2,3,3-trimethyl-1,5-pentanediol; 2,3, 4-Trimethyl-1,5-pentanediol; 2,3,3-trimethyl-2,4-pentanediol; 2,3,4-trimethyl-2,4-pentanediol; 2-Ethyl-2-methyl-1,3-pentanediol; 2-ethyl-3-methyl-1,3-pentanediol; 2-ethyl-4-methyl-1,3- pentanediol; 3-ethyl-2-methyl-1,3-pentanediol; 2-ethyl-2-methyl-1,4-pentanediol; 2-ethyl-3-methyl- 1,4-pentanediol; 2-ethyl-4-methyl-1,4-pentanediol; 3-ethyl-2-methyl-1,4-pentanediol; 3-ethyl-3 -Methyl-1,4-pentanediol; 2-ethyl-2-methyl-1,5-pentanediol; 2-ethyl-3-methyl-1,5-pentanediol; 2- Ethyl-4-methyl-1,5-pentanediol; 3-ethyl-3-methyl-1,5-pentanediol; 3-ethyl-2-methyl-2,4-pentanediol Alcohol; 2-isopropyl-1,3-pentanediol; 2-propyl-1,3-pentanediol; 2-isopropyl-1,4-pentanediol; 2-propyl-1, 4-pentanediol; 3-isopropyl-1,4-pentanediol; 2-isopropyl-1,5-pentanediol; 3-propyl-2,4-pentanediol; 2,2 -Dimethyl-1,3-hexanediol; 2,3-dimethyl-1,3-hexanediol; 2,4-dimethyl-1,3-hexanediol; 2,5-di Methyl-1,3-hexanediol; 3,4-dimethyl-1,3-hexanediol; 3,5-dimethyl-1,3-hexanediol; 4,5-dimethyl -1,3-hexanediol; 2,2-dimethyl-1,4-hexanediol; 2,3-dimethyl-1,4-hexanediol; 2,4-dimethyl-1 , 4-hexanediol; 2,5-dimethyl-1,4-hexanediol; 3,3-dimethyl-1,4-hexanediol; 3,4-dimethyl-1,4 -hexanediol; 3,5-dimethyl-1,4-hexanediol; 4,4-dimethyl-1,3-hexanediol; 4,5-dimethyl-1,4-hexanediol Diol; 5,5-Dimethyl-1,4-hexanediol; 2,2-Dimethyl-1,5-hexanediol; 2,3-Dimethyl-1,5-hexanediol ; 2,4-dimethyl-1,5-hexanediol; 2,5-dimethyl-1,5-hexanediol; 3,3-dimethyl-1,5-hexanediol; 3 ,4-Dimethyl-1,5-hexanediol; 3,5-dimethyl-1,5-hexanediol; 4,5-dimethyl-1,5-hexanediol; 2,2 -Dimethyl-1,6-hexanediol; 2,3-dimethyl-1,6-hexanediol; 2,4-dimethyl-1,6-hexanediol; 2,5-di Methyl-1,6-hexanediol; 3,3-dimethyl-1,6-hexanediol; 3,4-dimethyl-1,6-hexanediol; 2,3-dimethyl -2,4-hexanediol; 2,4-dimethyl-2,4-hexanediol; 2,5-dimethyl-2,4-hexanediol; 3,3-dimethyl-2 ,4-hexanediol; 3,4-dimethyl-2,4-hexanediol; 3,5-dimethyl-2,4-hexanediol; 4,5-dimethyl-2,4 -hexanediol; 5,5-dimethyl-2,4-hexanediol; 2,3-dimethyl-2,5-hexanediol; 2,4-dimethyl-2,5-hexanediol Diol; 2,5-Dimethyl-2,5-hexanediol; 3,3-Dimethyl-2,5-hexanediol; 3,4-Dimethyl-2,5-hexanediol ;3,3-Dimethyl-2,6-hexanediol; 2-ethyl-1,3-hexanediol; 4-ethyl-1,3-hexanediol; 2-ethyl-1, 4-hexanediol; 4-ethyl-1,4-hexanediol; 2-ethyl-1,5-hexanediol; 3-ethyl-2,4-hexanediol; 4-ethyl- 2,4-hexanediol; 3-ethyl-2,5-hexanediol; 2-methyl-1,3-heptanediol; 3-methyl-1,3-heptanediol; 4-methyl Base-1,3-heptanediol; 5-methyl-1,3-heptanediol; 6-methyl-1,3-heptanediol; 2-methyl-1,4-heptanediol; 3 -Methyl-1,4-heptanediol; 4-methyl-1,4-heptanediol; 5-methyl-1,4-heptanediol; 6-methyl-1,4-heptanediol ;2-Methyl-1,5-heptanediol; 3-methyl-1,5-heptanediol; 4-methyl-1,5-heptanediol; 5-methyl-1,5-heptanediol Diol; 6-methyl-1,5-heptanediol; 2-methyl-1,6-heptanediol; 3-methyl-1,6-heptanediol; 4-methyl-1,6 -Heptanediol; 5-methyl-1,6-heptanediol; 6-methyl-1,6-heptanediol; 2-methyl-2,4-heptanediol; 3-methyl-2 , 4-heptanediol; 4-methyl-2,4-heptanediol; 5-methyl-2,4-heptanediol; 6-methyl-2,4-heptanediol; 2-methyl -2,5-heptanediol; 3-methyl-2,5-heptanediol; 4-methyl-2,5-heptanediol; 5-methyl-2,5-heptanediol; 6- Methyl-2,5-heptanediol; 2-methyl-2,6-heptanediol; 3-methyl-2,6-heptanediol; 4-methyl-2,6-heptanediol; 3-Methyl-3,4-heptanediol; 2-methyl-3,5-heptanediol; 3-methyl-3,5-heptanediol; 4-methyl-3,5-heptanediol Alcohol; 2,4-octanediol; 2,5-octanediol; 2,6-octanediol; 2,7-octanediol; 3,5-octanediol; and/or 3,6-octanediol Diol; V. nonanediol isomers, including: 2,3,3,4-tetramethyl-2,4-pentanediol; 3-tert-butyl-2,4-pentanediol; 2, 5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2,4-hexanediol; 3,3,5-trimethyl-2,4-hexanediol Alcohol; 3,5,5-trimethyl-2,4-hexanediol; 4,5,5-trimethyl-2,4-hexanediol; 3,3,4-trimethyl-2, 5-hexanediol; and/or 3,3,5-trimethyl-2,5-hexanediol; VI. Glyceryl ethers and/or di(hydroxyalkyl)ethers including the following: 3-(n- pentyloxy)-1,2-propanediol; 3-(2-pentyloxy)-1,2-propanediol; 3-(3-pentyloxy)-1,2-propanediol; 3-(2-methyl -1-butoxy)-1,2-propanediol; 3-(isoamyloxy)-1,2-propanediol; 3-(3-methyl-2-butoxy)-1,2-propanediol; 3-(cyclohexyloxy)-1,2-propanediol; 3-(1-cyclohex-1-enyloxy)-1,2-propanediol; 2-(pentyloxy)-1,3-propanediol; 2-(2-pentyloxy)-1,3-propanediol; 2-(3-pentyloxy)-1,3-propanediol; 2-(2-methyl-1-butoxy)-1,3 -Propanediol; 2-(iso-pentyloxy)-1,3-propanediol; 2-(3-methyl-2-butoxy)-1,3-propanediol; 2-(cyclohexyloxy)-1 , 3-propanediol; 2-(1-cyclohex-1-enyloxy)-1,3-propanediol; triethoxylated 3-(butoxy)-1,2-propanediol; tetraethoxy Oxylated 3-(butoxy)-1,2-propanediol; Pentaethoxylated 3-(butoxy)-1,2-propanediol; Hexaethoxylated 3-(butoxy)- 1,2-propanediol; heptaethoxylated 3-(butoxy)-1,2-propanediol; octaethoxylated 3-(butoxy)-1,2-propanediol; nonaethoxylated Monopropoxylated 3-(butoxy)-1,2-propanediol; Monopropoxylated 3-(butoxy)-1,2-propanediol; Dibutylideneoxylated 3-(butoxy)- 1,2-propanediol; Tributylideneoxylated 3-(butoxy)-1,2-propanediol; 3-phenoxy-1,2-propanediol; 3-benzyloxy-1,2-propanediol; 3-(2-phenylethoxy)-1,2-propanediol; 3-(1-phenyl-2-propoxy)-1,2-propanediol; 2-phenoxy-1,3-propanediol ; 2-(m-tolyloxy)-1,3-propanediol; 2-(p-tolyloxy)-1,3-propanediol; Benzyloxy-1,3-propanediol; oxy)-1,3-propanediol; 2-(1-phenylethoxy)-1,3-propanediol; bis(2-hydroxybutyl) ether; and/or bis(2-hydroxycyclopentyl) Ether; VII. Including the following saturated and unsaturated alicyclic diols and their derivatives: (a) saturated diols and their derivatives, including: 1-isopropyl-1,2-cyclobutanediol; 3 -Ethyl-4-methyl-1,2-cyclobutanediol; 3-propyl-1,2-cyclobutanediol; 3-isopropyl-1,2-cyclobutanediol; 1-ethyl Base-1,2-cyclopentadiol; 1,2-dimethyl-1,2-cyclopentadiol; 1,4-dimethyl-1,2-cyclopentadiol; 2,4,5 - Trimethyl-1,3-cyclopentanediol; 3,3-dimethyl-1,2-cyclopentanediol; 3,4-dimethyl-1,2-cyclopentanediol; 3, 5-Dimethyl-1,2-cyclopentadiol; 3-ethyl-1,2-cyclopentadiol; 4,4-dimethyl-1,2-cyclopentadiol; 4-ethyl -1,2-cyclopentanediol; 1,1-bis(hydroxymethyl)cyclohexane; 1,2-bis(hydroxymethyl)cyclohexane; 1,2-dimethyl-1,3- Cyclohexanediol; 1,3-bis(hydroxymethyl)cyclohexane; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexane Diol; 1-hydroxy-cyclohexaneethanol; 1-hydroxy-cyclohexanemethanol; 1-ethyl-1,3-cyclohexanediol; 1-methyl-1,2-cyclohexanediol; 2 , 2-Dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-Dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1,3-cyclohexanediol; 2- Hydroxycyclohexaneethanol; 2-Hydroxyethyl-1-cyclohexanol; 3-Hydroxyethyl-1-cyclohexanol; 3-hydroxycyclohexaneethanol; 3-hydroxymethylcyclohexanol; Base-1,2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-di Methyl-1,3-cyclohexanediol; 4-ethyl-1,3-cyclohexanediol; 4-hydroxyethyl-1-cyclohexanol; 4-methyl-1,2-cyclohexanediol Alcohol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1,3-cyclohexanediol; 1,2-cycloheptanediol; 2-methyl-1,3 - Cycloheptanediol; 2-methyl-1,4-cycloheptanediol; 4-methyl-1,3-cycloheptanediol; 5-methyl-1,3-cycloheptanediol; Methyl-1,4-Cycloheptanediol; 6-Methyl-1,4-Cycloheptanediol; 1,3-Cyclooctanediol; 1,4-Cyclooctanediol; 1,5-Cyclooctanediol Diol; 1,2-cyclohexanediol diethoxylate; 1,2-cyclohexanediol triethoxylate; 1,2-cyclohexanediol tetraethoxylate; 1,2-cyclohexanediol Hexylene glycol pentaethoxylate; 1,2-cyclohexanediol hexaethoxylate; 1,2-cyclohexanediol heptaethoxylate; 1,2-cyclohexanediol octaethoxylate ; 1,2-cyclohexanediol nonaethoxylate; 1,2-cyclohexanediol monopropoxylate; 1,2-cyclohexanediol monobutylidene oxide; 1,2-cyclohexanediol and/or 1,2-cyclohexanediol tributoxylate; and (b) unsaturated cycloaliphatic diols including: 1-vinyl-2-ethyl-1 , 2-cyclobutanediol; 1,2,3,4-tetramethyl-3-cyclobutene-1,2-diol; 3,4-diethyl-3-cyclobutene-1,2 -diol; 3-(1,1-dimethylethyl)-3-cyclobutene-1,2-diol; 3-butyl-3-cyclobutene-1,2-diol; 1 , 2-Dimethyl-4-methylene-1,2-cyclopentadiol; 1-ethyl-3-methylene-1,2-cyclopentadiol; 4-(1-propenyl) -1,2-cyclopentanediol; 1-ethyl-3-methyl-3-cyclopentene-1,2-diol; 1-vinyl-1,2-cyclohexanediol; 1-methyl Base-3-methylene-1,2-cyclohexanediol; 1-methyl-4-methylene-1,2-cyclohexanediol; 3-vinyl-1,2-cyclohexanediol ; 4-vinyl-1,2-cyclohexanediol; 2,6-dimethyl-3-cyclohexene-1,2-diol; 6,6-dimethyl-3-cyclohexene- 1,2-diol; 3,6-dimethyl-4-cyclohexene-1,2-diol; 4,5-dimethyl-4-cyclohexene-1,2-diol; 3 - cyclooctene-1,2-diol; 4-cyclooctene-1,2-diol; and/or 5-cyclooctene-1,2-diol; VIII.C _3-8 diol alkane Oxylated derivatives, including: 1. 1,2-propanediol (C3) 2 (Me-E _1-4 ); 1,2-propanediol (C3)PO ₄ ; 2-methyl-1,2-propanediol (C4) (Me-E _{4- 10} ); 2-methyl-1,2-propanediol (C4) 2 (Me-E ₁ ); 2-methyl-1,2-propanediol (C4)PO ₃ ; 2-methyl-1,2-propanediol (C4)BO ₁ ; 1,3-propanediol (C3)2(Me-E _6-8 ); 1,3-propanediol (C3)PO _5-6 ; 2,2-diethyl-1,3-propanediol (C7) E _1-7 ; 2,2-diethyl-1,3-propanediol (C7)PO ₁ ; 2,2-diethyl-1,3-propanediol (C7)n-BO _1-2 ; 2,2-dimethyl-1,3-propanediol (C5) 2 (MeE _1-2 ); 2,2-dimethyl-1,3-propanediol (C5)PO _3-4 ; 2-(1- Methylpropyl)-1,3-propanediol (C7) E _1-7 ; 2-(1-methylpropyl)-1,3-propanediol (C7)PO ₁ ; 2-(1-methylpropyl )-1,3-propanediol (C7)n-BO _1-2 ; 2-(2-methylpropyl)-1,3-propanediol (C7)E _1-7 ; 2-(2-methylpropyl )-1,3-propanediol (C7)PO ₁ ; 2-(2-methylpropyl)-1,3-propanediol (C7)n-BO _1-2 ; 2-ethyl-1,3-propanediol ( C5)(MeE _6-10 ); 2-Ethyl-1,3-propanediol (C5)2( _MeE1 ); 2-Ethyl-1,3-propanediol (C5)PO3; 2-Ethyl- ₂ -Methyl-1,3-propanediol (C6) (MeE _1-6 ); 2-Ethyl-2-methyl-1,3-propanediol (C6)PO ₂ ; 2-Ethyl-2-methyl- 1,3-propanediol (C6)BO ₁ ; 2-isopropyl-1,3-propanediol (C6) (MeE _{1 -6} ); 2-isopropyl-1,3-propanediol (C6)PO ₂ ; 2 -Isopropyl-1,3-propanediol (C6)BO ₁ ; 2-methyl-1,3-propanediol (C4)2(MeE _2-5 ); 2-methyl-1,3-propanediol (C4) PO _4-5 ; 2-methyl-1,3-propanediol (C4)BO ₂ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)E _2-9 ; 2-methyl- 2-isopropyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-isopropyl-1,3-propanediol (C7)n-BO _1-3 ; 2-methyl-2- Propyl-1,3-propanediol (C7) E _1-7 ; 2-methyl-2-propyl-1,3-propanediol (C7)PO ₁ ; 2-methyl-2-propyl-1,3 -Propylene glycol (C7)n-BO _1-2 ; 2-Propyl-1,3-propanediol (C6) (MeE _1-4 ); 2-Propyl-1,3-propanediol (C6)PO ₂ ; 2- Propyl-1,3-propanediol (C6) _BO1 ; 2. 1,2-butanediol (C4) (Me-E _2-8 ); 1,2-butanediol (C4)PO _2-3 ; 1,2-butanediol (C4)BO ₁ ; 2 , 3-dimethyl-1,2-butanediol (C6) E _1-6 ; 2,3-dimethyl-1,2-butanediol (C6) n-BO _1-2 ; 2-ethane Base-1,2-butanediol (C6) E _1-3 ; 2-ethyl-1,2-butanediol (C6)n-BO ₁ ; 2-methyl-1,2-butanediol ( C5)(Me-E _1-2 ); 2-methyl-1,2-butanediol (C5)PO ₁ ; 3,3-dimethyl-1,2-butanediol (C6)E _{1- 6} ; 3,3-dimethyl-1,2-butanediol (C6)n-BO _{1- 2} ; 3-methyl-1,2-butanediol (C5) (MeE _1-2 ); 3 -Methyl-1,2-butanediol (C5)PO ₁ ; 1,3-butanediol (C4) 2 (MeE _3-6 ); 1,3-butanediol (C4)PO ₅ ; 1, 3-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,3-butanediol (C7) (MeE _1-3 ); 2,2,3-trimethyl-1, 3-Butanediol (C7)PO _1-2 ; 2,2-Dimethyl-1,3-butanediol (C6)(MeE _{3 -8} ); 2,2-Dimethyl-1,3- Butanediol (C6)PO ₃ ; 2,3-dimethyl-1,3-butanediol (C6) (MeE _3-8 ); 2,3-dimethyl-1,3-butanediol ( C6) PO ₃ ; 2-Ethyl-1,3-butanediol (C6) (MeE _1-6 ); 2-Ethyl-1,3-butanediol (C6)PO _2-3 ; 2-Ethyl Base-1,3-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,3-butanediol (C7)(MeE ₁ ); 2-Ethyl-2-methyl- 1,3-butanediol (C7)PO ₁ ; 2-ethyl-2-methyl-1,3-butanediol (C7)n-BO _2-4 ; 2-ethyl-3-methyl- 1,3-butanediol (C7) (MeE ₁ ); 2-ethyl-3-methyl-1,3-butanediol (C7)PO ₁ ; 2-ethyl-3-methyl-1, 3-butanediol (C7) n-BO _2-4 ; 2-isopropyl-1,3-butanediol (C7) (MeE ₁ ); 2-isopropyl-1,3-butanediol ( C7) PO ₁ ; 2-isopropyl-1,3-butanediol (C7)n-BO _2-4 ; 2-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ) ; 2-methyl-1,3-butanediol (C5)PO ₄ ; 2-propyl-1,3-butanediol (C7)E _2-9 ; 2-propyl-1,3-butanediol Alcohol (C7) PO ₁ ; 2-propyl-1,3-butanediol (C7) n-BO _1-3 ; 3-methyl-1,3-butanediol (C5) 2 (MeE _1-3 ); 3-methyl-1,3-butanediol (C5)PO ₄ ; 1,4-butanediol (C4) 2 (MeE _2-6 ); 1,4-butanediol (C4)PO _{4 -5} ; 1,4-butanediol (C4)BO ₂ ; 2,2,3-trimethyl-1,4-butanediol (C7)E _2-9 ; 2,2,3-trimethyl -1,4-butanediol (C7)PO ₁ ; 2,2,3-trimethyl-1,4-butanediol (C7)n-BO _1-3 ; 2,2-dimethyl-1 , 4-butanediol (C6) (MeE _1-6 ); 2,2-dimethyl-1,4-butanediol (C6)PO ₂ ; 2,2-dimethyl-1,4-butane Diol (C6) BO ₁ ; 2,3-dimethyl-1,4-butanediol (C6) (MeE _{1- 6} ); 2,3-dimethyl-1,4-butanediol (C6 )PO ₂ ; 2,3-dimethyl-1,4-butanediol (C6)BO ₁ ; 2-ethyl-1,4-butanediol (C6)(MeE _{1 -4} ); 2-ethane Base-1,4-butanediol (C6)PO ₂ ; 2-Ethyl-1,4-butanediol (C6)BO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7) E _1-7 ; 2-Ethyl-2-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-2-methyl-1,4-butanediol (C7 )n-BO _1-2 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)E _1-7 ; 2-Ethyl-3-methyl-1,4-butanediol (C7)PO ₁ ; 2-Ethyl-3-methyl-1,4-butanediol (C7)n-BO _1-2 ; 2-isopropyl-1,4-butanediol (C7)E _1-7 ; 2-isopropyl-1,4-butanediol (C7)PO ₁ ; 2-isopropyl-1,4-butanediol (C7)n-BO _1-2 ; 2-methyl -1,4-butanediol (C5) (MeE _6-10 ); 2-methyl-1,4-butanediol (C5) 2 (MeE ₁ ); 2-methyl-1,4-butanediol Alcohol (C5)PO ₃ ; 2-methyl-1,4-butanediol (C5)BO ₁ ; 2-propyl-1,4-butanediol (C7)E _{1 -5} ; 2-propyl- 1,4-butanediol (C7)n-BO _1-2 ; 3-ethyl-1-methyl-1,4-butanediol (C6)E _2-9 ; 3-ethyl-1-methyl Base-1,4-butanediol (C7)PO ₁ ; 3-ethyl-1-methyl-1,4-butanediol (C7)n-BO _1-3 ; 2,3-butanediol ( C4) (MeE _6-10 ); 2,3-butanediol (C4) 2 (MeE ₁ ); 2,3-butanediol (C4)PO _3-4 ; 2,3-butanediol (C4) BO ₁ ; 2,3-dimethyl-2,3-butanediol (C6)E _3-9 ; 2,3-dimethyl-2,3-butanediol (C6)PO ₁ ; 2,3 -Dimethyl-2,3-butanediol (C6)n-BO _1-3 ; 2-methyl-2,3-butanediol (C5)(MeE _1-5 ); 2-Methyl-2 , 3-butanediol (C5) PO ₂ ; 2-methyl-2,3-butanediol (C5) BO ₁ ; 3. 1,2-pentanediol (C5) E _3-10 ; 1,2-pentanediol (C5) PO ₁ ; 1,2-pentanediol (C5) n-BO _2-3 ; 2-methyl Base-1,2-pentanediol (C6) E _{1- 3} ; 2-methyl-1,2-pentanediol (C6)n-BO ₁ ; 2-methyl-1,2-pentanediol ( C6)BO ₁ ; 3-methyl-1,2-pentanediol (C6)E _1-3 ; 3-methyl-1,2-pentanediol (C6)n-BO ₁ ; 4-methyl- 1,2-pentanediol (C6) E _1-3 ; 4-methyl-1,2-pentanediol (C6) n-BO ₁ ; 1,3-pentanediol (C5) 2 (MeE _{1- 2} ); 1,3-pentanediol (C5)PO _3-4 ; 2,2-dimethyl-1,3-pentanediol (C7) (MeE ₁ ); 2,2-dimethyl-1 , 3-pentanediol (C7) PO ₁ ; 2,2-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,3-pentane Diol (C7) (Me-E ₁ ); 2,3-dimethyl-1,3-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,3-pentanediol (C7 )n-BO _2-4 ; 2,4-dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 2,4-dimethyl-1,3-pentanediol (C7 )PO ₁ ; 2,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 2-ethyl-1,3-pentanediol (C7)E _2-9 ; 2 -Ethyl-1,3-pentanediol (C7)PO ₁ ; 2-Ethyl-1,3-pentanediol (C7)n-BO _1-3 ; 2-methyl-1,3-pentanediol Alcohol (C6) 2 (MeE _{1- 6} ); 2-methyl-1,3-pentanediol (C6)PO _2-3 ; 2-methyl-1,3-pentanediol (C6)BO ₁ ; 3,4-Dimethyl-1,3-pentanediol (C7) (Me-E ₁ ); 3,4-Dimethyl-1,3-pentanediol (C7)PO ₁ ; 3,4- Dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 3-methyl-1,3-pentanediol (C6)(Me-E _1-6 ); 3-methyl- 1,3-pentanediol (C6)PO _2-3 ; 3-methyl-1,3-pentanediol (C6)BO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7 )(Me-E ₁ ); 4,4-dimethyl-1,3-pentanediol (C7)PO ₁ ; 4,4-dimethyl-1,3-pentanediol (C7)n-BO _2-4 ; 4-methyl-1,3-pentanediol (C6) (MeE _1-6 ); 4-methyl-1,3-pentanediol (C6)PO _2-3 ; 4-methyl -1,3-pentanediol (C6)BO ₁ ; 1,4-pentanediol (C5) 2 (MeE _{1- 2} ); 1,4-pentanediol (C5)PO _3-4 ; 2,2 - Dimethyl-1,4-pentanediol (C7) (Me-E ₁ ); 2,2-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,2-Dimethyl -1,4-pentanediol (C7)n-BO _2-4 ; 2,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 2,3-dimethyl -1,4-pentanediol (C7)PO ₁ ; 2,3-dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2,4-dimethyl-1,4 - Pentanediol (C7) (Me-E ₁ ); 2,4-Dimethyl-1,4-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 2-methyl-1,4-pentanediol (C6) (MeE _1-6 ); 2-methyl-1,4-pentanediol (C6)PO _{2- 3} ; 2-methyl-1,4-pentanediol (C6)BO ₁ ; 3,3-dimethyl-1,4-pentanediol (C7)(Me-E ₁ ); 3,3-di Methyl-1,4-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,4-pentanediol (C7)n-BO _2-4 ; 3,4-Dimethyl-1 , 4-pentanediol (C7) (Me-E ₁ ); 3,4-dimethyl-1,4-pentanediol (C7)PO ₁ ; 3,4-dimethyl-1,4-pentane Diol (C7) n-BO _2-4 ; 3-methyl-1,4-pentanediol (C6) 2 (Me-E _1-6 ); 3-methyl-1,4-pentanediol ( C6)PO _2-3 ; 3-methyl-1,4-pentanediol (C6)BO ₁ ; 4-methyl-1,4-pentanediol (C6)2(Me-E _1-6 ); 4-methyl-1,4-pentanediol (C6)PO _2-3 ; 4-methyl-1,4-pentanediol (C6)BO ₁ ; 1,5-pentanediol (C5)(Me -E _4-10 ); 1,5-pentanediol (C5) 2 (MeE ₁ ); 1,5-pentanediol (C5)PO ₃ ; 2,2-dimethyl-1,5-pentanediol Alcohol (C7) E _1-7 ; 2,2-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,2-Dimethyl-1,5-pentanediol (C7)n- BO _1-2 ; 2,3-dimethyl-1,5-pentanediol (C7) E _1-7 ; 2,3-dimethyl-1,5-pentanediol (C7)PO ₁ ; 2 , 3-dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2,4-dimethyl-1,5-pentanediol (C7)E _1-7 ; 2,4 -Dimethyl-1,5-pentanediol (C7)PO ₁ ; 2,4-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 2-Ethyl-1, 5-pentanediol (C7) E _1-5 ; 2-ethyl-1,5-pentanediol (C7) n-BO _1-2 ; 2-methyl-1,5-pentanediol (C6) (Me-E _1-4 ); 2-methyl-1,5-pentanediol (C6)PO ₂ ; 3,3-dimethyl-1,5-pentanediol (C7)E _1-7 ; 3,3-Dimethyl-1,5-pentanediol (C7)PO ₁ ; 3,3-Dimethyl-1,5-pentanediol (C7)n-BO _1-2 ; 3-methyl -1,5-pentanediol (C6) (Me-E _1-4 ); 3-methyl-1,5-pentanediol (C6)PO ₂ ; 2,3-pentanediol (C5) (Me -E _1-3 ); 2,3-pentanediol (C5)PO ₂ ; 2-methyl-2,3-pentanediol (C6)E _1-7 ; 2-methyl-2,3-pentane Diol (C6) PO ₁ ; 2-methyl-2,3-pentanediol (C6) n-BO _1-2 ; 3-methyl-2,3-pentanediol (C6) E _1-7 ; 3-methyl-2,3-pentanediol (C6)PO ₁ ; 3-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 4-methyl-2,3-pentane Diol (C6) E _1-7 ; 4-methyl-2,3-pentanediol (C6)PO ₁ ; 4-methyl-2,3-pentanediol (C6)n-BO _1-2 ; 2,4-pentanediol (C5) 2 (Me-E _1-4 ); 2,4-pentanediol (C5)PO ₄ ; 2,3-dimethyl-2,4-pentanediol (C7 )(Me-E _1-4 ); 2,3-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2,4-dimethyl-2,4-pentanediol (C7)( Me-E _1-4 ); 2,4-dimethyl-2,4-pentanediol (C7)PO ₂ ; 2-methyl-2,4-pentanediol (C7) (Me-E _{5- 10} ); 2-methyl-2,4-pentanediol (C7)PO ₃ ; 3,3-dimethyl-2,4-pentanediol (C7) (Me-E _1-4 ); 3, 3-Dimethyl-2,4-pentanediol (C7)PO ₂ ; 3-methyl-2,4-pentanediol (C6) (Me-E _5-10 ); 3-methyl-2, 4-pentanediol (C6) _PO3 ; 4. 1,3-hexanediol (C6) (Me-E _1-5 ); 1,3-hexanediol (C6)PO ₂ ; 1,3-hexanediol (C6)BO ₁ ; 2-methanol Base-1,3-hexanediol (C7) E _2-9 ; 2-methyl-1,3-hexanediol (C7)PO ₁ ; 2-methyl-1,3-hexanediol (C7) n-BO _1-3 ; 2-methyl-1,3-hexanediol (C7)BO ₁ ; 3-methyl-1,3-hexanediol (C7)E _2-9 ; 3-methyl- 1,3-hexanediol (C7)PO ₁ ; 3-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,3-hexanediol (C7) E _2-9 ; 4-methyl-1,3-hexanediol (C7)PO ₁ ; 4-methyl-1,3-hexanediol (C7)n-BO _1-3 ; 5-methyl- 1,3-hexanediol (C7)E _2-9 ; 5-methyl-1,3-hexanediol (C7)PO ₁ ; 5-methyl-1,3-hexanediol (C7)n- BO _1-3 ; 1,4-hexanediol (C6) (Me-E _1-5 ); 1,4-hexanediol (C6)PO ₂ ; 1,4-hexanediol (C6)BO ₁ ; 2-methyl-1,4-hexanediol (C7) E _2-9 ; 2-methyl-1,4-hexanediol (C7)PO ₁ ; 2-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 3-methyl-1,4-hexanediol (C7)E _2-9 ; 3-methyl-1,4-hexanediol (C7)PO ₁ ; 3- Methyl-1,4-hexanediol (C7)n-BO _1-3 ; 4-methyl-1,4-hexanediol (C7)E _2-9 ; 4-methyl-1,4-hexane Diol (C7) PO ₁ ; 4-methyl-1,4-hexanediol (C7) n-BO _1-3 ; 5-methyl-1,4-hexanediol (C7) E _2-9 ; 5-methyl-1,4-hexanediol (C7)PO ₁ ; 5-methyl-1,4-hexanediol (C7)n-BO _1-3 ; 1,5-hexanediol (C6) (Me-E _1-5 ); 1,5-hexanediol (C6)PO ₂ ; 1,5-hexanediol (C6)BO ₁ ; 2-methyl-1,5-hexanediol (C7) E _2-9 ; 2-methyl-1,5-hexanediol (C7)PO ₁ ; 2-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 3-methyl- 1,5-hexanediol (C7)E _2-9 ; 3-methyl-1,5-hexanediol (C7)PO ₁ ; 3-methyl-1,5-hexanediol (C7)n- BO _1-3 ; 4-methyl-1,5-hexanediol (C7)E _2-9 ; 4-methyl-1,5-hexanediol (C7)PO ₁ ; 4-methyl-1, 5-hexanediol (C7)n-BO _1-3 ; 5-methyl-1,5-hexanediol (C7)E _2-9 ; 5-methyl-1,5-hexanediol (C7) PO ₁ ; 5-methyl-1,5-hexanediol (C7)n-BO _1-3 ; 1,6-hexanediol (C6)(Me-E _1-2 ); 1,6-hexanediol Alcohol (C6) PO _1-2 ; 1,6-Hexanediol (C6) n-BO ₄ ; 2-Methyl-1,6-Hexanediol (C7) E _1-5 ; 2-Methyl-1 , 6-hexanediol (C7) n-BO _1-2 ; 3-methyl-1,6-hexanediol (C7) E _1-5 ; 3-methyl-1,6-hexanediol (C7 )n-BO _1-2 ; 2,3-hexanediol (C6)E _1-5 ; 2,3-hexanediol (C6)n-BO ₁ ; 2,3-hexanediol (C6)BO ₁ ; 2,4-hexanediol (C6) (Me-E _3-8 ); 2,4-hexanediol (C6)PO ₃ ; 2-methyl-2,4-hexanediol (C7) (Me -E _1-2 ); 2-methyl-2,4-hexanediol (C7)PO _1-2 ; 3-methyl-2,4-hexanediol (C7)(Me-E _1-2 ) ; 3-methyl-2,4-hexanediol (C7)PO _1-2 ; 4-methyl-2,4-hexanediol (C7) (Me-E _1-2 ); 4-methyl- 2,4-hexanediol (C7)PO _1-2 ; 5-methyl-2,4-hexanediol (C7)(Me-E _1-2 ); 5-methyl-2,4-hexanediol Alcohol (C7) PO _1-2 ; 2,5-hexanediol (C6) (Me-E _3-8 ); 2,5-hexanediol (C6)PO ₃ ; 2-Methyl-2,5- Hexylene glycol (C7) (Me-E _1-2 ); 2-methyl-2,5-hexanediol (C7)PO _1-2 ; 3-methyl-2,5-hexanediol (C7) (Me-E _1-2 ); 3-methyl-2,5-hexanediol (C7)PO _1-2 ; 3,4-hexanediol (C6)EO _1-5 ; 3,4-hexanediol Alcohol (C6) n-BO ₁ ; 3,4-hexanediol (C6) BO ₁ ; 5. 1,3-Heptanediol (C7) E _1-7 ; 1,3-Heptanediol (C7)PO ₁ ; 1,3-Heptanediol (C7)n-BO _1-2 ; 1,4 -Heptanediol (C7) E _1-7 ; 1,4-Heptanediol (C7)PO ₁ ; 1,4-Heptanediol (C7)n-BO _1-2 ; 1,5-Heptanediol ( C7)E _1-7 ; 1,5-heptanediol (C7)PO ₁ ; 1,5-heptanediol (C7)n-BO _1-2 ; 1,6-heptanediol (C7)E _{1- 7} ; 1,6-heptanediol (C7)PO ₁ ; 1,6-heptanediol (C7)n-BO _1-2 ; 1,7-heptanediol (C7)E _1-2 ; 1,7 -Heptanediol (C7)n-BO ₁ ; 2,4-Heptanediol (C7)E _3-10 ; 2,4-Heptanediol (C7)(Me-E ₁ ); 2,4-Heptanediol Alcohol (C7) PO ₁ ; 2,4-heptanediol (C7) n-BO ₃ ; 2,5-heptanediol (C7) E _3-10 ; 2,5-heptanediol (C7) (Me- E ₁ ); 2,5-heptanediol (C7)PO ₁ ; 2,5-heptanediol (C7)n-BO ₃ ; 2,6-heptanediol (C7)E _3-10 ; 2,6 - Heptanediol (C7) (Me-E ₁ ); 2,6-Heptanediol (C7)PO ₁ ; 2,6-Heptanediol (C7)n-BO ₃ ; 3,5-Heptanediol ( C7)E _3-10 ; 3,5-heptanediol (C7)(Me-E ₁ ); 3,5-heptanediol (C7)PO ₁ ; 3,5-heptanediol (C7)n-BO ₃ ; 6. 3-methyl-2-isopropyl-1,3-butanediol (C8)PO ₁ ; 2,3,3-trimethyl-2,4-pentanediol (C8)PO ₁ ; 2 , 2-diethyl-1,3-butanediol (C8) E _2-5 ; 2,3-dimethyl-2,4-hexanediol (C8) E _2-5 ; 2,4-two Methyl-2,4-hexanediol (C8) E _2-5 ; 2,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2 , 4-hexanediol (C8) E _{2 -5} ; 3,4-dimethyl-2,4-hexanediol (C8) E _2-5 ; 3,5-dimethyl-2,4-hexane Diol (C8) E _2-5 ; 4,5-dimethyl-2,4-hexanediol (C8) E _2-5 ; 5,5-dimethyl-2,4-hexanediol (C8 )E _2-5 ; 2,3-dimethyl-2,5-hexanediol (C8)E _2-5 ; 2,4-dimethyl-2,5-hexanediol (C8)E _{2- 5} ; 2,5-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3,3-dimethyl-2,5-hexanediol (C8) E _2-5 ; 3, 4-Dimethyl-2,5-hexanediol (C8) E _2-5 ; 3-methyl-3,5-heptanediol (C8) E _2-5 ; 2,2-diethyl-1 , 3-butanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 3,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 4,5-dimethyl-2,4-hexanediol (C8) n-BO _1-2 ; 5,5-dimethyl-2 , 4-hexanediol (C8) n-BO _1-2 ; 2,3-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 2,4-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 2,5-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3,3-dimethyl-2 , 5-hexanediol (C8) n-BO _1-2 ; 3,4-dimethyl-2,5-hexanediol (C8) n-BO _1-2 ; 3-methyl-3,5- Heptanediol (C8)n-BO _1-2 ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)n-BO ₁ ; 2-Ethyl-2,3-di Methyl-1,3-butanediol (C8)n-BO ₁ ; 2-methyl-2-isopropyl-1,3-butanediol (C8)n-BO ₁ ; 3-methyl-2 -Isopropyl-1,4-butanediol (C8)n-BO ₁ ; 2,2,3-trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,4,4-Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 3,4,4 -Trimethyl-1,3-pentanediol (C8)n-BO ₁ ; 2,2,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,2,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,3-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 3,3,4-Trimethyl-1,4-pentanediol (C8)n-BO ₁ ; 2,3,4 -Trimethyl-2,4-pentanediol (C8)n-BO ₁ ; 4-Ethyl-2,4-hexanediol (C8)n-BO ₁ ; 2-methyl-2,4-heptane Diol (C8)n- _BO1 ; 3-methyl-2,4-heptanediol (C8)n- _BO1 ; 4-methyl-2,4-heptanediol (C8)n- _BO1 ; 5-methyl-2,4-heptanediol (C8)n-BO ₁ ; 6-methyl-2,4-heptanediol (C8)n-BO ₁ ; 2-methyl-2,5-heptane Diol (C8)n- _BO1 ; 3-methyl-2,5-heptanediol (C8)n- _BO1 ; 4-methyl-2,5-heptanediol (C8)n- _BO1 ; 5-methyl-2,5-heptanediol (C8)n-BO ₁ ; 6-methyl-2,5-heptanediol (C8)n-BO ₁ ; 2-methyl-2,6-heptane Diol (C8)n- _BO1 ; 3-methyl-2,6-heptanediol (C8)n- _BO1 ; 4-methyl-2,6-heptanediol (C8)n- _BO1 ; 2-Methyl-3,5-heptanediol (C8)n-BO ₁ ; 2-(1,2-Dimethylpropyl)-1,3-propanediol (C8)E _1-3 ; 2-Ethylene Base-2,3-dimethyl-1,3-butanediol (C8) E _1-3 ; 2-methyl-2-isopropyl-1,3-butanediol (C8) E _1-3 ; 3-methyl-2-isopropyl-1,4-butanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,4,4-trimethyl-1,3-pentanediol (C8) E _{1- 3} ; 3,4,4-trimethyl-1,3-pentanediol (C8) E _1-3 ; 2,2,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,2,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 2,3,3-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-1,4-pentanediol (C8) E _1-3 ; 3,3,4-trimethyl-1,4-pentanediol (C8) E _{1- 3} ; 2,3,4-trimethyl-2,4-pentanediol (C8) E _1-3 ; 4-ethyl-2,4-hexanediol (C8) E _1-3 ; 2-methyl Base-2,4-heptanediol (C8) E _1-3 ; 3-methyl-2,4-heptanediol (C8) E _1-3 ; 4-methyl-2,4-heptanediol ( C8) E _1-3 ; 5-methyl-2,4-heptanediol (C8) E _1-3 ; 6-methyl-2,4-heptanediol (C8) E _1-3 ; 2-methyl Base-2,5-heptanediol (C8) E _1-3 ; 3-methyl-2,5-heptanediol (C8) E _1-3 ; 4-methyl-2,5-heptanediol ( C8) E _1-3 ; 5-methyl-2,5-heptanediol (C8) E _1-3 ; 6-methyl-2,5-heptanediol (C8) E _1-3 ; 2-methyl Base-2,6-heptanediol (C8) E _1-3 ; 3-methyl-2,6-heptanediol (C8) E _1-3 ; 4-methyl-2,6-heptanediol ( C8) E _1-3 ; and/or 2-methyl-3,5-heptanediol (C8) E _1-3 ; and 7. Their mixtures; IX. Including the following aromatic diols: 1-phenyl-1,2-ethanediol; 1-phenyl-1,2-propanediol; 2-phenyl-1,2-propanediol ; 3-phenyl-1,2-propanediol; 1-(3-methylphenyl)-1,3-propanediol; 1-(4-methylphenyl)-1,3-propanediol; 2-methyl -1-phenyl-1,3-propanediol; 1-phenyl-1,3-butanediol; 3-phenyl-1,3-butanediol; 1-phenyl-1,4-butanediol ; 2-phenyl-1,4-butanediol; and/or 1-phenyl-2,3-butanediol; X. has a ClogP value of about 0.15 to about 0.64 and is a homologue of the compound of the above structure or A solvent of analogues in which one or more _CH2 groups are added, and for each _CH2 group added, two hydrogen atoms are removed from adjacent carbon atoms in the molecule to form a carbon-carbon double bond such that The number of hydrogen atoms in the molecule remains unchanged, and they include: 2,2-di-2-propenyl-1,3-propanediol; 2-(1-pentenyl)-1,3-propanediol; 2-(2 -Methyl-2-propenyl)-2-(2-propenyl)-1,3-propanediol; 2-(3-methyl-1-butenyl)-1,3-propanediol; 2-(4 -pentenyl)-1,3-propanediol; 2-ethyl-2-(2-methyl-2-propenyl)-1,3-propanediol; 2-ethyl-2-(2-propenyl) -1,3-propanediol; 2-methyl-2-(3-methyl-3-butenyl)-1,3-propanediol; 2,2-diallyl-1,3-butanediol; 2-(1-Ethyl-1-propenyl)-1,3-butanediol; 2-(2-butenyl)-2-methyl-1,3-butanediol; 2-(3- Methyl-2-butenyl)-1,3-butanediol; 2-ethyl-2-(2-propenyl)-1,3-butanediol; 2-methyl-2-(1- Methyl-2-propenyl)-1,3-butanediol; 2,3-bis(1-methylethylene)-1,4-butanediol; 2-(3-methyl-2- Butenyl)-3-methylene-1,4-butanediol; 2-(1,1-dimethylpropyl)-2-butene-1,4-diol; 2-(1- Methylpropyl)-2-butene-1,4-diol; 2-butyl-2-butene-1,4-diol; 2-vinyl-3-ethyl-1,3-pentane Diol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1,4-pentanediol; 2-(1 -propenyl)-1,5-pentanediol; 2-(2-propenyl)-1,5-pentanediol; 2-ethylidene-3-methyl-1,5-pentanediol; 2 -Propylene-1,5-pentanediol; 3-Ethylene-2,4-dimethyl-2,4-pentanediol; 2-(1,1-dimethylethyl)-4 -pentene-1,3-diol; 2-ethyl-2,3-dimethyl-4-pentene-1,3-diol; 4-ethyl-2-methylene-1,4 -hexanediol; 2,3,5-trimethyl-1,5-hexadiene-3,4-diol; 5-ethyl-3-methyl-1,5-hexadiene-3, 4-diol; 2-(1-methylvinyl)-1,5-hexanediol; 2-vinyl-1,6-hexanediol; 5,5-dimethyl-1-hexene- 3,4-diol; 5,5-dimethyl-1-hexene-3,4-diol; 4-vinyl-2,5-dimethyl-2-hexene-1,5-diol Alcohol; 2-vinyl-2,5-dimethyl-3-hexene-1,6-diol; 2-ethyl-3-hexene-1,6-diol; 3,4-dimethyl Dimethyl-3-hexene-1,6-diol; 2,5-dimethyl-4-hexene-2,3-diol; 3,4-dimethyl-4-hexene-2,3 -diol; 3-(2-propenyl)-5-hexene-1,3-diol; 2,3-dimethyl-5-hexene-2,3-diol; 3,4-diol Methyl-5-hexene-2,3-diol; 3,5-dimethyl-5-hexene-2,3-diol; 3-vinyl-2,5-dimethyl-5- Hexene-2,4-diol; 6-methyl-5-methylene-1,4-heptanediol; 2,3-dimethyl-1,5-heptadiene-3,4-diol Alcohol; 2,5-dimethyl-1,5-heptadiene-3,4-diol; 3,5-dimethyl-1,5-heptadiene-3,4-diol; 2, 6-bis(methylene)-1,7-heptanediol; 4-methylene-1,7-heptanediol; 2,4-dimethyl-1-heptene-3,5-diol ;2,6-Dimethyl-1-heptene-3,5-diol; 3-vinyl-5-methyl-1-heptene-3,5-diol; 6,6-dimethyl -1-heptene-3,5-diol; 4,6-dimethyl-2,4-heptadiene-2,6-diol; 4,4-dimethyl-2,5-heptanediol ene-1,7-diol; 2,5,5-trimethyl-2,6-heptadiene-1,4-diol; 5,6-dimethyl-2-heptene-1,4 -diol; 5-ethyl-2-heptene-1,5-diol; 2-methyl-2-heptene-1,7-diol; 4,6-dimethyl-3-heptene -1,5-diol; 3-methyl-6-methylene-3-heptene-1,7-diol; 2,4-dimethyl-3-heptene-2,5-diol ; 2,5-Dimethyl-3-heptene-2,5-diol; 2,6-Dimethyl-3-heptene-2,6-diol; 4,6-Dimethyl-3 -Heptene-2,6-diol; 2,4-Dimethyl-5-heptene-1,3-diol; 3,6-Dimethyl-5-heptene-1,3-diol ; 2,6-Dimethyl-5-heptene-1,4-diol; 3,6-Dimethyl-5-heptene-1,4-diol; 2,3-Dimethyl-5 -heptene-2,4-diol; 2,2-dimethyl-6-heptene-1,3-diol; 4-(2-propenyl)-6-heptene-1,4-diol Alcohol; 5,6-Dimethyl-6-heptene-1,4-diol; 2,4-Dimethyl-6-heptene-1,5-diol; 2-Ethylene-6- Methyl-6-heptene-1,5-diol; 4-(2-propenyl)-6-heptene-2,4-diol; 5,5-dimethyl-6-heptene-2 , 4-diol; 4,6-dimethyl-6-heptene-2,5-diol; 5-vinyl-4-methyl-6-heptene-2,5-diol; 2- Methylene-1,3-octanediol; 2,6-dimethyl-1,6-octadiene-3,5-diol; 3,7-dimethyl-1,6-octadiene -3,5-diol; 2,6-dimethyl-1,7-octadiene-3,6-diol; 2,7-dimethyl-1,7-octadiene-3,6 -diol; 3,6-dimethyl-1,7-octadiene-3,6-diol; 3-vinyl-1-octene-3,6-diol; 2,7-dimethyl -2,4,6-octadiene-1,8-diol; 3,7-dimethyl-2,4-octadiene-1,7-diol; 2,6-dimethyl- 2,5-octadiene-1,7-diol; 3,7-dimethyl-2,5-octadiene-1,7-diol; 3,7-dimethyl-2,6- Octadiene-1,4-diol (Rosiridol); 2-methyl-2,6-octadiene-1,8-diol; 3,7-dimethyl-2,7-octadiene- 1,4-diol; 2,6-dimethyl-2,7-octadiene-1,5-diol; 2,6-dimethyl-2,7-octadiene-1,6- Diol (8-hydroxylinalool); 2,7-dimethyl-2,7-octadiene-1,6-diol; 2-octene-1,4-diol; 2-octene -1,7-diol; 2-methyl-6-methylene-2-octene-1,7-diol; 3,7-dimethyl-3,5-octadiene-1,7 -diol; 2,7-dimethyl-3,5-octadiene-2,7-diol; 4-methylene-3,5-octanediol; 2,6-dimethyl-3 , 7-octadiene-1,6-diol; 2,7-dimethyl-3,7-octadiene-2,5-diol; 2,6-dimethyl-3,7-octane Diene-2,6-diol; 4-methyl-3-octene-1,5-diol; 5-methyl-3-octene-1,5-diol; 2,2-dimethyl Base-4,6-octadiene-1,3-diol; 2,6-dimethyl-4,7-octadiene-2,3-diol; 2,6-dimethyl-4, 7-octadiene-2,6-diol; 7-methyl-4-octene-1,6-diol; 2,7-di(methylene)-; 2-methylene-;2 , 7-Dimethyl-5,7-octadiene-1,4-diol; 7-methyl-5,7-octadiene-1,4-diol; 5-octene-1,3 -diol; 7-methyl-6-octene-1,3-diol; 7-methyl-6-octene-1,4-diol; 6-octene-1,5-diol; 7-methyl-6-octene-1,5-diol; 2-methyl-6-octene-3,5-diol; 4-methyl-6-octene-3,5-diol ; 2-methyl-7-octene-1,3-diol; 4-methyl-7-octene-1,3-diol; 7-methyl-7-octene-1,3-diol Alcohol; 7-octene-1,5-diol; 7-octene-1,6-diol; 5-methyl-7-octene-1,6-diol; 2-methyl-6- Methylene-7-octene-2,4-diol; 7-methyl-7-octene-2,5-diol; 2-methyl-7-octene-3,5-diol; 1-nonene-3,5-diol; 1-nonene-3,7-diol; 3-nonene-2,5-diol; 8-methyl-4,6-nonadiene-1 , 3-diol; 4-nonene-2,8-diol; 6,8-nonadiene-1,5-diol; 7-nonene-2,4-diol; 8-nonene- 2,4-diol; 8-nonene-2,5-diol; 1,9-decadiene-3,8-diol; and/or 1,9-decadiene-4,6-diol Alcohols; and XI. Their mixtures, the main solvent contains a deficient amount of a solvent selected from the group consisting of: 2,2,4-trimethyl-1,3-pentanediol; 2,2,4-trimethyl ethoxylate, diethoxylate or triethoxylate derivatives of 1,3-pentanediol; and/or 2-ethylhexyl-1,3-diol to provide aqueous stable Product; C. Optional but preferred effective amount of low molecular weight water-soluble solvents such as ethanol, isopropanol, propylene glycol, 1,3-propylene glycol, and propylene carbonate, etc., sufficient to improve transparency, said water-soluble solvent present in an amount that does not form a clear composition; D. an optional but preferred effective amount of a water-soluble calcium and/or magnesium salt to improve clarity; preferably chloride; and E. the balance water. 52. A composition according to claim 51, wherein said principal solvent B is present in an effective amount, but in an amount lower than the amount required to obtain stability, the composition being rendered stable by adding another solvent which itself cannot obtain stability Stablize. 53. A method of producing a sheer fabric softening composition using the premix of claim 47 and adding said premix to an acid containing water; an acid that has a pH of from about 1.5 to about 5; and optionally an effective amount in the aqueous form of water-soluble calcium and/or magnesium salts. 54. A process for the preparation of a solvent mixture according to claim 6 containing butyraldehyde, isobutyraldehyde and/or methyl ethyl ketone (2-butanone) condensation products in the presence of a strongly basic catalyst followed by hydrogenation conversion, as long as butyraldehyde or isobutyraldehyde The aldehyde content was less than about 95% of the reaction mixture. 55. The method of claim 54, wherein the amount of butyraldehyde or isobutyraldehyde is less than about 85% of the reaction mixture. 56. The method of claim 54, wherein the amount of butyraldehyde or isobutyraldehyde is less than about 80% of the reaction mixture. 57. The mixture prepared by the method of claim 54.