CN117183404A - Production technology and boards of continuous fiber prepreg mesh fabric reinforced wood-plastic materials - Google Patents
Production technology and boards of continuous fiber prepreg mesh fabric reinforced wood-plastic materials Download PDFInfo
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- 239000000835 fiber Substances 0.000 title claims abstract description 86
- 239000004744 fabric Substances 0.000 title claims abstract description 52
- 229920003023 plastic Polymers 0.000 title claims abstract description 37
- 239000004033 plastic Substances 0.000 title claims abstract description 37
- 239000000463 material Substances 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 27
- 239000002023 wood Substances 0.000 claims abstract description 24
- 239000000945 filler Substances 0.000 claims abstract description 13
- 238000009941 weaving Methods 0.000 claims abstract description 8
- 238000005470 impregnation Methods 0.000 claims abstract description 6
- 238000001125 extrusion Methods 0.000 claims description 26
- -1 polyethylene Polymers 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920002530 polyetherether ketone Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 3
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 3
- 241001330002 Bambuseae Species 0.000 claims description 3
- 229920002748 Basalt fiber Polymers 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 claims description 3
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 3
- 239000004760 aramid Substances 0.000 claims description 3
- 229920006231 aramid fiber Polymers 0.000 claims description 3
- 239000011425 bamboo Substances 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229920005610 lignin Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 238000003892 spreading Methods 0.000 claims description 3
- 239000010902 straw Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 abstract description 10
- 230000002787 reinforcement Effects 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000032798 delamination Effects 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 238000009954 braiding Methods 0.000 abstract 2
- 229920001587 Wood-plastic composite Polymers 0.000 description 5
- 239000011155 wood-plastic composite Substances 0.000 description 5
- 230000003014 reinforcing effect Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
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- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
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Abstract
Description
技术领域Technical field
本申请涉及木塑复合材料领域,具体而言涉及一种连续纤维预浸网格织物增强木塑材料的生产工艺及其板材。The present application relates to the field of wood-plastic composite materials, specifically to a production process of continuous fiber pre-impregnated grid fabric-reinforced wood-plastic material and its board.
背景技术Background technique
木塑复合材料是一种主要以木材或纤维素与塑料制成的复合材料,通过纤维共挤对木塑复合材料进行力学增强已被行业广泛运用。现有技术中一般采用短切纤维,短切纤维在木塑复合材料中呈无序态,导致其对木塑复合材料的增强效果局部不可控,质量难以保证。Wood-plastic composite material is a composite material mainly made of wood or cellulose and plastic. The mechanical reinforcement of wood-plastic composite material through fiber co-extrusion has been widely used in the industry. In the existing technology, chopped fibers are generally used. Chopped fibers are in a disordered state in wood-plastic composite materials, resulting in partially uncontrollable reinforcing effects on wood-plastic composite materials and making it difficult to guarantee quality.
因此,需要一种连续纤维预浸网格织物增强木塑材料的生产工艺及其板材以至少部分地解决以上问题。Therefore, there is a need for a production process of continuous fiber prepreg mesh fabric-reinforced wood-plastic materials and its boards to at least partially solve the above problems.
发明内容Contents of the invention
在发明内容部分中引入了一系列简化形式的概念,这将在具体实施方式部分中进一步详细说明。本申请的发明内容部分并不意味着要试图限定出所要求保护的技术方案的关键特征和必要技术特征,更不意味着试图确定所要求保护的技术方案的保护范围。This summary introduces a series of concepts in a simplified form that are further described in detail in the detailed description. The invention summary part of this application is not intended to limit the key features and necessary technical features of the claimed technical solution, nor is it intended to determine the protection scope of the claimed technical solution.
为至少部分地解决上述问题,本申请的第一方面提供了一种连续纤维预浸网格织物增强木塑材料的生产工艺,所述生产工艺包括以下步骤:In order to at least partially solve the above problems, the first aspect of the present application provides a production process of continuous fiber prepreg mesh fabric reinforced wood plastic materials, the production process includes the following steps:
步骤一:使连续纤维通过预浸工序被第一热塑性树脂包覆,制得包覆纤维;Step 1: Coat the continuous fiber with the first thermoplastic resin through a prepreg process to prepare coated fiber;
步骤二:利用编织设备将所述包覆纤维编织成网格织物,将所述网格织物引入共挤出模具中;Step 2: Use weaving equipment to weave the coated fiber into a mesh fabric, and introduce the mesh fabric into a co-extrusion die;
步骤三:将第二热塑性树脂及木质填料添加入所述共挤出模具内,通过共挤工艺得到连续纤维预浸网格织物增强木塑材料。Step 3: Add the second thermoplastic resin and wood filler into the co-extrusion mold, and obtain a continuous fiber prepreg mesh fabric reinforced wood-plastic material through a co-extrusion process.
可选地,所述步骤一还包括,在所述预浸工序之前将所述连续纤维进行展纱工序;并且/或者Optionally, the step one also includes subjecting the continuous fibers to a spreading process before the prepreg process; and/or
所述连续纤维包括玻璃纤维、玄武岩纤维、碳纤维、芳纶纤维、木素纤维和涤纶纤维中的一种或多种。The continuous fibers include one or more of glass fibers, basalt fibers, carbon fibers, aramid fibers, lignin fibers and polyester fibers.
可选地,所述木质填料包括木粉、竹粉以及植物秸秆粉中的至少一种。Optionally, the wood filler includes at least one of wood powder, bamboo powder and plant straw powder.
可选地,所述第一热塑性树脂和所述第二热塑性树脂能够彼此相融。Optionally, the first thermoplastic resin and the second thermoplastic resin can be melted with each other.
可选地,所述第一热塑性树脂包括聚乙烯、聚丙烯、聚酰胺、聚亚苯基硫醚或聚醚醚酮中的至少一种;并且/或者Optionally, the first thermoplastic resin includes at least one of polyethylene, polypropylene, polyamide, polyphenylene sulfide or polyether ether ketone; and/or
所述第二热塑性树脂包括聚乙烯、聚丙烯、聚酰胺、聚亚苯基硫醚或聚醚醚酮中的至少一种。The second thermoplastic resin includes at least one of polyethylene, polypropylene, polyamide, polyphenylene sulfide or polyether ether ketone.
可选地,所述共挤出模具设置有注入口,所述步骤三还包括,所述第二热塑性树脂和所述木质填料从所述注入口添加入所述共挤出模具中。Optionally, the co-extrusion mold is provided with an injection port, and step three further includes adding the second thermoplastic resin and the wood filler into the co-extrusion mold from the injection port.
可选地,在所述步骤二还包括,将至少两层所述网格织物以预定间隔引入所述共挤出模具。Optionally, step two further includes introducing at least two layers of mesh fabric into the co-extrusion die at predetermined intervals.
可选地,所述网格织物的网孔尺寸为2~20mm。Optionally, the mesh size of the mesh fabric is 2 to 20 mm.
可选地,所述步骤一还包括:所述预浸工序之前在所述连续纤维外包覆枝接剂。Optionally, the step one further includes: coating the continuous fiber with a grafting agent before the pre-impregnation process.
根据本申请的连续纤维预浸网格织物增强木塑材料的生产工艺,通过使连续纤维先浸渍后编织,保证了复合材料中连续纤维的浸润性;通过使增强连续纤维呈编织态,实现了复合材料的强度在各个方向均能增强;通过使纤维织物呈网格态,使得树脂通过网格状的连续纤维彼此交联,有效抑制了复合材料分层。根据本申请的生产工艺流程少、结构简单、操作精简,能生产出增强效果好、结构均匀、强度高的木塑材料。According to the production process of continuous fiber pre-impregnated mesh fabric reinforced wood-plastic materials of the present application, by impregnating the continuous fibers first and then weaving, the wettability of the continuous fibers in the composite material is ensured; by making the reinforced continuous fibers in a braided state, it is achieved The strength of the composite material can be enhanced in all directions; by making the fiber fabric into a mesh pattern, the resins are cross-linked with each other through the mesh-like continuous fibers, effectively inhibiting the delamination of the composite material. The production process according to the present application has few processes, simple structure and streamlined operation, and can produce wood-plastic materials with good reinforcing effect, uniform structure and high strength.
本申请的第二方面提供了一种连续纤维预浸网格织物增强木塑板材,由根据本申请第一方面的连续纤维预浸网格织物增强木塑材料的生产工艺生产。The second aspect of the present application provides a continuous fiber prepreg mesh fabric reinforced wood-plastic board, produced by the production process of the continuous fiber prepreg mesh fabric reinforced wood-plastic material according to the first aspect of the application.
根据本申请的连续纤维预浸网格织物增强木塑板材通过使用编织态的网格纤维增强的生产工艺生产,成品力学强度高、结构均匀、增强质量好。The continuous fiber pre-impregnated mesh fabric reinforced wood-plastic board according to the present application is produced through a production process using woven mesh fiber reinforcement, and the finished product has high mechanical strength, uniform structure and good reinforcement quality.
附图说明Description of the drawings
本申请的下列附图在此作为本申请的一部分用于理解本申请。附图中示出了本申请的实施例及其描述,用来解释本申请的原理。The following drawings of this application are hereby incorporated by reference and are incorporated into the understanding of this application. The drawings illustrate embodiments of the present application and their descriptions to explain the principles of the present application.
附图中:In the attached picture:
图1为根据本申请的连续纤维预浸网格织物增强木塑材料的生产工艺的设备示意图。Figure 1 is a schematic diagram of the equipment for the production process of continuous fiber prepreg mesh fabric reinforced wood plastic materials according to the present application.
附图标记说明:Explanation of reference symbols:
1:放卷设备;1: Unwinding equipment;
2:网格织物;2: Mesh fabric;
3:共挤出模具;3: Co-extrusion mold;
4:注入口;4: Injection port;
5:木塑板材。5: Wood-plastic board.
具体实施方式Detailed ways
在下文的描述中,给出了大量具体的细节以便提供对本申请更为彻底的理解。然而,对于本领域技术人员而言显而易见的是,本申请可以无需一个或多个这些细节而得以实施。在其他的例子中,为了避免与本申请发生混淆,对于本领域公知的一些技术特征未进行描述。In the following description, numerous specific details are given in order to provide a thorough understanding of the present application. However, it will be apparent to one skilled in the art that the present application may be practiced without one or more of these details. In other examples, some technical features that are well known in the art are not described in order to avoid confusion with the present application.
应予以注意的是,这里所使用的术语仅是为了描述具体实施例,而非意图限制根据本申请的示例性实施例。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式。此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在所述特征、整体、步骤、操作、元件和/或组件,但不排除存在或附加一个或多个其他特征、整体、步骤、操作、元件、组件和/或它们的组合。It should be noted that the terminology used herein is for the purpose of describing specific embodiments only and is not intended to limit the exemplary embodiments according to the present application. As used herein, the singular forms are intended to include the plural forms as well, unless the context clearly indicates otherwise. Furthermore, it should also be understood that when the terms "comprises" and/or "includes" are used in this specification, they indicate the presence of said features, integers, steps, operations, elements and/or components but do not exclude the presence or Attaching one or more other features, integers, steps, operations, elements, components and/or combinations thereof.
本申请中所引用的诸如“第一”和“第二”的序数词仅仅是标识,而不具有任何其他含义,例如特定的顺序等。而且,例如,术语“第一部件”其本身不暗示“第二部件”的存在,术语“第二部件”本身不暗示“第一部件”的存在。需要说明的是,本文中所使用的术语“上”、“下”、“前”、“后”、“左”、“右”、“内”、“外”以及类似的表述只是为了说明目的,并非限制。Ordinal words such as "first" and "second" cited in this application are merely identifiers and do not have any other meaning, such as a specific order, etc. Furthermore, for example, the term "first component" does not by itself imply the presence of a "second component" and the term "second component" does not by itself imply the presence of a "first component". It should be noted that the terms "upper", "lower", "front", "back", "left", "right", "inner", "outer" and similar expressions used in this article are for illustrative purposes only. , not a restriction.
现在,将参照附图更详细地描述根据本申请的示例性实施例。Now, exemplary embodiments according to the present application will be described in more detail with reference to the accompanying drawings.
本申请提供了一种连续纤维预浸网格织物增强木塑材料的生产工艺,生产工艺包括以下步骤:This application provides a production process for continuous fiber prepreg mesh fabric reinforced wood plastic materials. The production process includes the following steps:
步骤一:使连续纤维通过预浸工序被第一热塑性树脂包覆,制得包覆纤维;Step 1: Coat the continuous fiber with the first thermoplastic resin through a prepreg process to prepare coated fiber;
步骤二:利用编织设备将包覆纤维编织成网格织物,将网格织物引入共挤出模具中;Step 2: Use weaving equipment to weave the coated fiber into a mesh fabric, and introduce the mesh fabric into the co-extrusion mold;
步骤三:将第二热塑性树脂及木质填料添加入共挤出模具内,通过共挤工艺得到连续纤维预浸网格织物增强木塑材料。Step 3: Add the second thermoplastic resin and wood filler into the co-extrusion mold, and obtain a continuous fiber prepreg mesh fabric reinforced wood-plastic material through the co-extrusion process.
根据本申请的连续纤维预浸网格织物增强木塑材料的生产工艺,通过使连续纤维先浸渍后编织,保证了复合材料中纤维的浸润性;通过使增强纤维呈编织态,实现了对复合材料的强度的均匀增强;通过使纤维织物呈网格态,使得树脂通过网格彼此交联,有效抑制了复合材料分层。根据本申请的生产工艺流程少、结构简单、操作精简,能生产出增强效果好、结构均匀、强度高的木塑材料。According to the production process of continuous fiber pre-impregnated mesh fabric reinforced wood-plastic materials of the present application, by impregnating the continuous fibers first and then weaving, the wettability of the fibers in the composite material is ensured; by making the reinforcing fibers in a braided state, the composite The strength of the material is uniformly enhanced; by making the fiber fabric into a mesh state, the resins are cross-linked with each other through the mesh, effectively suppressing the delamination of the composite material. The production process according to the present application has few processes, simple structure and streamlined operation, and can produce wood-plastic materials with good reinforcing effect, uniform structure and high strength.
在步骤一中,连续纤维包括玻璃纤维、玄武岩纤维、碳纤维、芳纶纤维、木素纤维和涤纶纤维中的一种或多种。预浸工序包括熔融浸渍工序。步骤一还包括,在预浸工序之前将连续纤维进行展纱工序。连续纤维可以通过振动、碾压方式进行展纱,展纱后的连续纤维通过熔融浸渍工序被第一热塑性树脂包覆,一束纤维被第一热塑性树脂包覆后得到包覆纤维。一束包覆纤维中包含1~1000根连续纤维丝。其中,第一热塑性树脂包括聚乙烯、聚丙烯、聚酰胺、聚亚苯基硫醚或聚醚醚酮中的至少一种。In step one, the continuous fibers include one or more of glass fibers, basalt fibers, carbon fibers, aramid fibers, lignin fibers and polyester fibers. The prepreg process includes a melt impregnation process. Step one also includes subjecting the continuous fibers to a spreading process before the prepreg process. The continuous fibers can be spread by vibration and rolling. The spread continuous fibers are coated with the first thermoplastic resin through a melt impregnation process. A bundle of fibers is coated with the first thermoplastic resin to obtain coated fibers. A bundle of coated fibers contains 1 to 1,000 continuous fiber filaments. Wherein, the first thermoplastic resin includes at least one of polyethylene, polypropylene, polyamide, polyphenylene sulfide or polyether ether ketone.
在其他实施例中,步骤一还包括:预浸工序之前在连续纤维外包覆枝接剂。In other embodiments, step one further includes: coating the continuous fiber with a grafting agent before the prepreg process.
制得包覆纤维后,在步骤二中,将包覆纤维通过编织设备编织成网格织物,将网格织物引入共挤出模具中。其中,网格织物的网孔尺寸为2~20mm。优选地,将至少两层网格织物以预定间隔引入共挤出模具中。After the coated fiber is produced, in step two, the coated fiber is woven into a mesh fabric through a weaving device, and the mesh fabric is introduced into the co-extrusion die. Among them, the mesh size of the mesh fabric is 2 to 20 mm. Preferably, at least two layers of mesh fabric are introduced into the coextrusion die at predetermined intervals.
在步骤三中,将熔融态、预混的第二热塑性树脂及木质填料添加入共挤出模具内,通过共挤工艺得到连续纤维预浸网格织物增强木塑材料。优选地,共挤出模具设置有注入口,步骤三还包括,第二热塑性树脂和木质填料从注入口添加入共挤出模具中。其中第二热塑性树脂和第一热塑性树脂能够彼此相融。第二热塑性树脂包括聚乙烯、聚丙烯、聚酰胺、聚亚苯基硫醚或聚醚醚酮中的至少一种。木质填料包括木粉、竹粉以及植物秸秆粉中的至少一种。In step three, the molten, premixed second thermoplastic resin and wood filler are added into the co-extrusion mold, and a continuous fiber prepreg mesh fabric reinforced wood-plastic material is obtained through the co-extrusion process. Preferably, the co-extrusion mold is provided with an injection port, and step three further includes adding the second thermoplastic resin and the wood filler into the co-extrusion mold from the injection port. The second thermoplastic resin and the first thermoplastic resin can be melted with each other. The second thermoplastic resin includes at least one of polyethylene, polypropylene, polyamide, polyphenylene sulfide or polyetheretherketone. The wood filler includes at least one of wood powder, bamboo powder and plant straw powder.
参考图1,网格织物2经收卷后,通过放卷设备1分别以预定间隔引入共挤出模具3中。共挤出模具3设置有注入口4,熔融态、预混的第二热塑性树脂和木质填料从注入口4同时添加入共挤出模具3中,与网格织物2通过共挤工艺得到连续纤维预浸网格织物增强木塑材料。Referring to Figure 1, after the mesh fabric 2 is rolled, it is introduced into the co-extrusion die 3 at predetermined intervals through the unwinding device 1. The co-extrusion die 3 is provided with an injection port 4. The molten, premixed second thermoplastic resin and wood filler are simultaneously added into the co-extrusion die 3 from the injection port 4, and are combined with the mesh fabric 2 through a co-extrusion process to obtain continuous fibers. Pre-impregnated mesh fabric reinforced wood plastic material.
本申请的第二方面提供了一种连续纤维预浸网格织物增强木塑板材,由根据本申请第一方面的连续纤维预浸网格织物增强木塑材料的生产工艺生产。The second aspect of the present application provides a continuous fiber prepreg mesh fabric reinforced wood-plastic board, produced by the production process of the continuous fiber prepreg mesh fabric reinforced wood-plastic material according to the first aspect of the application.
参照图1,网格织物2与第二热塑性树脂和木质填料通过共挤工艺得到木塑板材5。Referring to Figure 1, the mesh fabric 2, the second thermoplastic resin and the wood filler are co-extruded to obtain the wood-plastic board 5.
根据本申请的连续纤维预浸网格织物增强木塑板材通过使用编织态的网格纤维增强的生产工艺生产,成品力学强度高、结构均匀、增强质量好。The continuous fiber pre-impregnated mesh fabric reinforced wood-plastic board according to the present application is produced through a production process using woven mesh fiber reinforcement, and the finished product has high mechanical strength, uniform structure and good reinforcement quality.
上述的所有优选实施例中所述的流程、步骤仅是示例。除非发生不利的效果,否则可以按与上述流程的顺序不同的顺序进行各种处理操作。上述流程的步骤顺序也可以根据实际需要进行增加、合并或删减。The processes and steps described in all the above preferred embodiments are only examples. Unless adverse effects occur, various processing operations may be performed in an order different from that of the above flow. The sequence of steps in the above process can also be added, combined or deleted according to actual needs.
除非另有定义,本文中所使用的技术和科学术语与本申请的技术领域的技术人员通常理解的含义相同。本文中使用的术语只是为了描述具体的实施目的,不是旨在限制本申请。本文中在一个实施方式中描述的特征可以单独地或与其它特征结合地应用于另一个实施方式,除非该特征在该另一个实施方式中不适用或是另有说明。Unless otherwise defined, technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the technical field of this application. The terminology used herein is for the purpose of describing specific implementations only and is not intended to limit the application. Features described herein in one embodiment may be applied to another embodiment alone or in combination with other features, unless the feature is inapplicable in that other embodiment or otherwise stated.
本申请已经通过上述实施例进行了说明,但应当理解的是,上述实施例只是用于举例和说明的目的,本申请并不局限于上述实施例,根据本申请的教导还可以做出更多种的变型和修改,这些变型和修改均落在本申请所要求保护的范围以内。The present application has been described through the above-mentioned embodiments, but it should be understood that the above-mentioned embodiments are only for the purpose of illustration and illustration. The present application is not limited to the above-mentioned embodiments, and more can be made according to the teachings of the present application. Various variations and modifications, these variations and modifications all fall within the scope of protection claimed by this application.
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