CN116004330A - Foam cleaning agent with sterilization performance and preparation method thereof - Google Patents
Foam cleaning agent with sterilization performance and preparation method thereof Download PDFInfo
- Publication number
- CN116004330A CN116004330A CN202211528549.9A CN202211528549A CN116004330A CN 116004330 A CN116004330 A CN 116004330A CN 202211528549 A CN202211528549 A CN 202211528549A CN 116004330 A CN116004330 A CN 116004330A
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- bactericide
- surfactant
- foam cleaning
- stabilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000006260 foam Substances 0.000 title claims abstract description 71
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 64
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 53
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title abstract description 21
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 53
- 239000003899 bactericide agent Substances 0.000 claims abstract description 48
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 47
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 44
- 239000003381 stabilizer Substances 0.000 claims abstract description 44
- -1 modified alkyl glycoside Chemical class 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229920000962 poly(amidoamine) Polymers 0.000 claims abstract description 36
- 229930182470 glycoside Natural products 0.000 claims abstract description 30
- 239000002904 solvent Substances 0.000 claims abstract description 30
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 26
- 229920001661 Chitosan Polymers 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract 3
- 238000003756 stirring Methods 0.000 claims description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 11
- 229920000570 polyether Polymers 0.000 claims description 11
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 8
- NCEFRBSXBILZPP-UHFFFAOYSA-M azanium;potassium;sulfate Chemical compound [NH4+].[K+].[O-]S([O-])(=O)=O NCEFRBSXBILZPP-UHFFFAOYSA-M 0.000 claims description 8
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 6
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 5
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 5
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- RZHBMYQXKIDANM-UHFFFAOYSA-N dioctyl butanedioate;sodium Chemical compound [Na].CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC RZHBMYQXKIDANM-UHFFFAOYSA-N 0.000 claims description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 36
- 238000004140 cleaning Methods 0.000 abstract description 20
- 125000002091 cationic group Chemical group 0.000 abstract description 6
- 125000000129 anionic group Chemical group 0.000 abstract description 4
- 239000003599 detergent Substances 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 125000000524 functional group Chemical group 0.000 abstract description 2
- 229920000587 hyperbranched polymer Polymers 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 27
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 26
- 238000001556 precipitation Methods 0.000 description 23
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical group COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 22
- 230000032798 delamination Effects 0.000 description 19
- 239000004094 surface-active agent Substances 0.000 description 12
- 125000003277 amino group Chemical group 0.000 description 7
- 239000000693 micelle Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 description 6
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 6
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 6
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 5
- 210000000170 cell membrane Anatomy 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 5
- 125000003368 amide group Chemical group 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229940095731 candida albicans Drugs 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 230000009881 electrostatic interaction Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical group CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229940044120 2-n-octyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical group [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000001516 effect on protein Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002455 scale inhibitor Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical group CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a foam cleaning agent with sterilization performance and a preparation method thereof, and belongs to the field of cleaning agents. The composition comprises the following components in percentage by mole: 1-20% of cationic surfactant, 1-20% of anionic surfactant, 1-20% of nonionic surfactant, 0.01-0.5% of bactericide, 0.1-2% of stabilizer, 1-10% of solvent, 0-20% of pH regulator and the balance of water; the bactericide is any one of hyperbranched polyamidoamine, hyperbranched polyamidoamine modified chitosan and hyperbranched polyamidoamine modified alkyl glycoside. The bactericide is hyperbranched polymer, the molecular surface of the bactericide not only has functional groups, but also has surface activity, so that the surface tension can be reduced, the detergent forms rich and fine foam, and the detergent forms synergistic effect with anionic, cationic and nonionic surfactants, thereby greatly improving the surface activity of each component and improving the cleaning effect and the sterilizing effect.
Description
Technical Field
The invention relates to the field of cleaning agents, in particular to a foam cleaning agent with sterilization performance and a preparation method thereof.
Background
Foam cleaning agents mainly generate abundant foam and surface activity through surfactants and are used for removing stains which are difficult to remove in common, such as greasy dirt, fat, protein, polysaccharide, inorganic salt deposits and the like on hard surfaces. The prior foam cleaning agent mainly comprises an alkaline foam cleaning agent and an acidic alkaline foam cleaning agent, and mainly aims at cleaning, but for some special scenes, sterilization and disinfection are needed during cleaning. Most of the existing foam cleaning agents only add any one or a combination of three surfactants of anions, cations and non-ions. Cationic surfactants such as quaternary ammonium salts among the surfactants have a certain sterilizing effect, but are used in foam cleaning agents as cleaning components, and sterilizing performance is impaired.
The existing general cleaning agent is a low-foam cleaning agent which is disclosed in publication No. CN112481045A and a preparation method and application thereof, wherein the low-foam cleaning agent comprises 10-30% of surfactant, 10-20% of alkaline substance, 5-15% of greasy dirt solvent, 5-20% of alkaloid, 2-5% of bactericide, 0.1-0.5% of scale inhibitor and the balance of water. Wherein the bactericide is one or more of 1, 2-benzisothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one and 5-chloro-2-methyl-4-isothiazolin-3-one. An efficient antibacterial protective cleaning agent disclosed in publication No. CN108179072A, wherein the bactericide is caprylin. The foam cleaning agent with disinfection and cleaning functions disclosed in publication No. CN111440676A and a preparation method thereof are disclosed, wherein three types of anionic surfactant, cationic surfactant and nonionic surfactant are adopted for mixing, wherein the cationic surfactant is one or more of amine salt type cationic surfactant, quaternary ammonium salt type cationic surfactant and heterocyclic type cationic surfactant, specifically, decamethyiammonium bromide and dodecyl trimethyl ammonium chloride, and decamethyiammonium bromide is a common cationic bactericide.
In summary, most of the existing cleaning agents are mainly used as bactericides by adding nonionic and anionic, and the cationic has a certain influence on the cleaning effect of the cleaning agents, and if a good cleaning effect is required, the amount of the surfactant to be added is large, so that the cost is increased. Therefore, there is a need for a foam cleaning agent which can improve the cleaning effect of the foam cleaning agent, has high-efficiency sterilization performance, and has low surfactant consumption.
Disclosure of Invention
In order to solve the problems, the invention provides a foam cleaning agent with sterilization performance, which can reduce the use amount of a surfactant, promote the cleaning effect of the foam cleaning agent and improve the foam stability and sterilization performance.
In order to achieve the above object, the present invention is achieved by the following technical scheme:
a foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 1-20% of cationic surfactant, 1-20% of anionic surfactant, 1-20% of nonionic surfactant, 0.01-0.5% of bactericide, 0.1-2% of stabilizer, 1-10% of solvent, 0-20% of pH regulator and the balance of water;
the bactericide is any one of hyperbranched polyamidoamine, hyperbranched polyamidoamine modified chitosan and hyperbranched polyamidoamine modified alkyl glycoside.
Further, the foam cleaning agent comprises the following components in percentage by mole: 2-10% of cationic surfactant, 2-10% of anionic surfactant, 5-10% of nonionic surfactant, 0.05-0.1% of bactericide, 0.5-1.5% of stabilizer, 5-8% of solvent, 0-20% of pH regulator and the balance of water.
Preferably, the foam cleaning agent comprises the following components in mole percent: 2-5% of cationic surfactant, 2-5% of anionic surfactant, 5-7% of nonionic surfactant, 0.05-0.1% of bactericide, 0.8-1.2% of stabilizer, 5-8% of solvent, 0-20% of pH regulator and the balance of water.
Further, the cationic surfactant is any one or more of dodecyl trimethyl ammonium chloride, dodecyl trimethyl ammonium bromide, dodecyl trimethyl potassium sulfate ammonium, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide and cetyl trimethyl potassium sulfate ammonium.
Further, the anionic surfactant is one or more of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium alkenyl sulfonate, sodium laureth sulfate and sodium dioctyl succinate.
Further, the nonionic surfactant is any one or more of laurinol polyoxyethylene ether, alkyl glycoside and EO-PO block polyether.
Further, the stabilizer is long-chain carbon alcohol.
Further, the long-chain carbon alcohol is C8-C14 alcohol.
The invention discloses a preparation method of a foam cleaning agent with sterilization performance, which comprises the following steps:
(1) Adding an anionic surfactant into water according to the mass percentage, and stirring until the anionic surfactant is completely dissolved to obtain a primary mixed solution;
(2) Adding the nonionic surfactant and the bactericide into the primary mixed solution under the stirring state, stirring uniformly, adding the cationic surfactant, the stabilizer and the solvent, and continuously stirring to obtain the foam cleaning agent.
The foam cleaning agent with sterilization performance and the preparation method thereof have the beneficial effects that:
(1) According to the invention, three surfactants, namely the cationic surfactant, the anionic surfactant and the nonionic surfactant, are compounded, so that the surface activity is greatly increased under the condition that both the anionic surfactant and the cationic surfactant exist, and therefore, the ultra-low oil-water interfacial tension and the lower critical micelle concentration are easy to form, the surface viscosity of a foam liquid film can be effectively increased, and when the surface viscosity is maximum, the stability of the foam is strongest. The invention adds non-ionic surfactant which can effectively prevent the precipitation and suspension generated by the reaction of anionic surfactant and cationic surfactant in the system, thereby enhancing the stability of the whole system
(2) The added long-chain alcohol with the stability of C8-C14 can promote the dissolution of the anionic surfactant, the cationic surfactant and the nonionic surfactant in the solvent and the stabilizer, the stabilizer is insoluble in water and is mixed with water to form micelles, the solution stability is better, the distribution of the surfactant is more uniform, the layering phenomenon is avoided, and therefore the cleaning effect of the product and the foam wall-hanging time are improved.
(3) The bactericide is added in the invention, and the main hyperbranched polyamidoamine and the derivatives thereof, the hyperbranched polyacrylate and the derivatives thereof, after hyperbranched, the bactericide has a large number of amino groups on the molecular surface, and the positively charged amino groups are combined with the negatively charged bacterial cell membrane through electrostatic interaction to destroy the material exchange inside and outside the membrane, so as to cause the disintegration of the cell membrane and achieve the sterilization effect.
(4) The bactericide is hyperbranched polymer, the molecular surface of the bactericide not only has functional groups, but also has surface activity, so that the surface tension can be reduced, the detergent forms rich and fine foam, and the bactericide and the anionic, cationic and nonionic surfactants form synergistic effect, so that the surface activity of each component is greatly improved, and the cleaning effect is improved.
Detailed Description
In order that the manner in which the invention may be better understood, a more particular description of the invention will be rendered by reference to specific embodiments thereof which are illustrated in the appended drawings. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention provides a foam cleaning agent with sterilization performance, which comprises the following components in percentage by mole: 1-20% of cationic surfactant, 1-20% of anionic surfactant, 1-20% of nonionic surfactant, 0.01-0.5% of bactericide, 0.1-2% of stabilizer, 1-10% of solvent, 0-20% of pH regulator and the balance of water.
In a preferred embodiment, the foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 2-10% of cationic surfactant, 2-10% of anionic surfactant, 5-10% of nonionic surfactant, 0.05-0.1% of bactericide, 0.5-1.5% of stabilizer, 5-8% of solvent, 0-20% of pH regulator and the balance of water.
In a preferred embodiment, the foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 5% of cationic surfactant, 8% of anionic surfactant, 8% of nonionic surfactant, 0.1% of bactericide, 1.2% of stabilizer and 8% of solvent; the pH regulator is used for regulating the pH value to 3-11, and the balance is water. Wherein, the bactericide in the invention is preferably hyperbranched polyamidoamine modified alkyl glycoside.
Cationic surfactants
The cationic surfactant is one or more of dodecyl trimethyl ammonium chloride, dodecyl trimethyl ammonium bromide, dodecyl trimethyl potassium sulfate ammonium, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide and cetyl trimethyl potassium sulfate ammonium. The cationic surfactant basically belongs to quaternary ammonium surfactants, has certain sterilization performance, good emulsifying property and good wetting property, is more favorable for infiltration of hard surface substances, and improves cleaning and sterilization effects. The invention can not coexist with anionic surfactant under the existing general condition, and the anionic surfactant and the cationic surfactant can coexist due to the existence of the stabilizer and the nonionic surfactant, and meanwhile, the anionic surfactant and the cationic surfactant are mutually synergistic, so that the mutual surface activity is improved, and the foaming and sterilizing effects are better.
Anionic surfactants
The anionic surfactant is one or more of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium alkenyl sulfonate, sodium laureth sulfate and sodium dioctyl succinate.
In the invention, the sodium dodecyl sulfate has HLB value of 40, belongs to hydrophilic group surfactant, and has excellent surface activity, emulsifying property and foaming property.
In the invention, the sodium dodecyl benzene sulfonate has the HLB value of 10.638, strong foaming power, high detergency and good wettability, and has obvious decontamination effect on protein dirt and oily dirt, and the decontamination effect is enhanced along with the rise of temperature. The water-resistant modified polyurethane foam is compounded with a stabilizer, a cationic surfactant and a nonionic surfactant, so that the water resistance is better, and the applicability is stronger.
In the invention, the anionic surfactant with low surface tension, high foam and good hydrolytic stability of the sodium alkenyl sulfonate,
in the invention, dioctyl sodium sulfosuccinate has good wettability, permeability, emulsifying property and foamability and good washing effect.
Nonionic surfactant
The nonionic surfactant of the invention is mainly polyether and alkyl glycoside, has good foamability, emulsibility and wettability, and can prevent the balance of the anionic surfactant and the cationic surfactant in a system after being mixed with the anionic surfactant and the cationic surfactant, thereby promoting the surface activity of the anionic surfactant and the cationic surfactant, further reducing the surface tension, improving the wettability and the permeability and promoting the cleaning of the hard surface by the system.
In the invention, laurinol polyoxyethylene ether is obtained by the reaction between dodecanol and ethylene oxide. Wherein the alkyl in the dodecanol is a hydrophobic group, the polyoxyethylene group is a hydrophilic group, the emulsion, dispersion, wetting and solubilisation of the laurinol polyoxyethylene ether are better, the foaming power is strong, the cleaning effect is good, and the generated foam is favorable for the flushing of later water and reduces the water consumption.
In the invention, EO-PO block polyether contains polyoxyethylene group and polyoxypropylene group, the polyoxyethylene group is hydrophilic group, the polyoxypropylene group is lipophilic, the lipophilic and hydrophilic mixed structure is easier to form micelle in aqueous solution on one hand, so that the surface tension is larger, in addition, the hydrophilic and lipophilic groups are alternately mixed and arranged, the spaces are mutually blocked, a large number of gaps between liquid films are formed, the strength of the liquid film is weakened, and finally, the formed foam film wall is easier to break, so that the foam film has low foam characteristics. The low-foam surfactant is mixed with the high-foam cationic surfactant and the high-foam anionic surfactant, so that the surface tension of the whole system can be properly increased, the foam is rich to reach a certain balance value, the wall hanging of the foam is facilitated, the later water flushing is facilitated, and the water consumption is reduced.
Bactericide
The bactericide is mainly hyperbranched polyamide amine and derivatives thereof, hyperbranched polyacrylate and derivatives thereof, and after hyperbranched, the bactericide has a large number of amino groups on the molecular surface, and the amino groups with positive charges are combined with bacterial cell membranes with negative charges through electrostatic interaction to destroy the material exchange inside and outside the membranes, so as to cause the disintegration of the cell membranes and achieve the sterilization effect.
In the invention, hyperbranched polyamidoamine has the structural formula:
The preparation method of the hyperbranched polyamidoamine modified chitosan comprises the following steps: adding polyamide amine into the aqueous solution, uniformly mixing, and then adding a pH regulator to adjust the pH of the solution to 11-13; adding chitosan and halogen into the solution, fully stirring, and reacting to obtain hyperbranched polyamidoamine modified chitosan. In the hyperbranched polyamidoamine modified chitosan synthesis reaction, the amido in the polyamidoamine and the hydroxyl in the chitosan are subjected to polymerization reaction, so that the obtained compound contains a large amount of amido, ether bond and amino, and the polymer forms a hyperbranched structure, thereby greatly increasing the sterilization effect. The hyperbranched polyamidoamine modified chitosan has the performance of an anionic surfactant and the performance of a cationic surfactant according to the u, so that the wettability of a system and the stability of foam can be greatly improved, and the cleaning effect is improved.
In the invention, the preparation method of hyperbranched polyamidoamine modified alkyl glycoside comprises the following steps: adding polyamide amine into the aqueous solution, uniformly mixing, and then adding a pH regulator to adjust the pH of the solution to 11-13; adding alkyl glycoside and halogen into the solution, fully stirring, and reacting to obtain the hyperbranched polyamidoamine modified alkyl glycoside. In the synthesis reaction of hyperbranched polyamidoamine modified alkyl glycoside, the amido in polyamidoamine and hydroxyl in alkyl glycoside are polymerized to form hyperbranched structure, a large amount of amino and long-chain alkyl exist, the system surface tension formed by anionic surfactant and cationic surfactant is balanced, the wettability of the system and the stability of foam can be greatly improved, and therefore the cleaning effect and the sterilization performance are improved.
Stabilizing agent
The stabilizers according to the invention are long-chain alcohols of C8-C14, preferably C10 alcohols, C12 alcohols and C14 alcohols. The alcohol has low solubility in water, and can form micelle in the whole system after being mixed with cationic surfactant and anionic surfactant, so that the stability of the system is improved, and the cationic surfactant and the anionic surfactant can cooperate to improve the surface activity of the cationic surfactant and the anionic surfactant while keeping the surface activity of the cationic surfactant and the anionic surfactant, thereby improving the effect of the cleaning agent.
Solvent(s)
The solvent is propylene glycol methyl ether or diethylene glycol butyl ether, which can dissolve cationic surfactant and anionic surfactant to promote reaction.
PH regulator
The pH regulator comprises an acid regulator and an alkaline regulator, wherein the acid regulator is phosphoric acid, nitric acid, sulfuric acid, acetic acid, citric acid, sorbic acid, maleic acid, lactic acid, tartaric acid and the like; the alkaline regulator is sodium hydroxide, potassium hydroxide, sodium bicarbonate, sodium dihydrogen phosphate, etc.
Example 1
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 2% of dodecyl trimethyl ammonium chloride, 2% of sodium dodecyl sulfate, 5% of laurinol polyoxyethylene ether, 0.01% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 2% of stabilizer dodecanol, 10% of solvent propylene glycol methyl ether and the balance of water.
Example 2
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 10% of dodecyl trimethyl ammonium bromide, 10% of sodium dodecyl benzene sulfonate, 20% of EO-PO block polyether, 0.5% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.5% of stabilizer dodecanol, 10% of solvent diethylene glycol butyl ether and the balance of water.
Example 3
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 5% of dodecyl trimethyl potassium ammonium sulfate, 5% of sodium alkenyl sulfonate, 10% of alkyl glycoside, 0.05% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 0.5% of stabilizer dodecanol, 8% of solvent propylene glycol methyl ether and the balance of water.
Example 4
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: cetyl trimethyl ammonium chloride 5%, sodium laureth sulfate 5%, EO-PO block polyether 10%, bactericide hyperbranched polyamidoamine modified alkyl glycoside 0.1%, stabilizer tetradecyl alcohol 1%, solvent propylene glycol methyl ether 8%, and the balance water.
Example 5
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 8% of cetyl trimethyl ammonium bromide, 8% of dioctyl sodium sulfosuccinate, 8% of laureth, 0.1% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.2% of stabilizer dodecanol, 8% of solvent diethylene glycol butyl ether and the balance of water.
Example 6
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 6% of ammonium cetyl trimethyl potassium sulfate, 6% of sodium dodecyl sulfate, 5% of EO-PO block polyether, 0.08% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.2% of stabilizer dodecanol, 10% of solvent propylene glycol methyl ether and the balance of water.
Example 7
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 5% of dodecyl trimethyl ammonium chloride, 5% of sodium dodecyl sulfate, 8% of laureth, 0.06% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.2% of stabilizer dodecanol, 10% of solvent diethylene glycol butyl ether and the balance of water.
Example 8
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 10% of dodecyl trimethyl ammonium bromide, 10% of sodium dodecyl benzene sulfonate, 5% of alkyl glycoside, 0.1% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.0% of stabilizer tetradecyl alcohol, 10% of solvent propylene glycol methyl ether and the balance of water.
Example 9
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 5% of dodecyl trimethyl potassium ammonium sulfate, 5% of sodium alkenyl sulfonate, 6% of EO-PO block polyether, 0.08% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.0% of stabilizer dodecanol, 8% of solvent diethylene glycol butyl ether and the balance of water.
Example 10
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: cetyl trimethyl ammonium chloride 5%, sodium laureth sulfate 5%, laureth 8%, sterilizing agent hyperbranched polyamidoamine modified alkyl glycoside 0.08%, stabilizer dodecanol 1.0%, solvent propylene glycol methyl ether 8% and the balance water.
Example 11
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: cetyl trimethyl ammonium bromide 5%, dioctyl sodium sulfosuccinate 5%, alkyl glycoside 8%, bactericide hyperbranched polyamidoamine modified alkyl glycoside 0.08%, stabilizer tetradecyl alcohol 1.0%, solvent propylene glycol methyl ether 8% and the balance water.
Example 12
A foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 8% of cetyl trimethyl ammonium bromide, 8% of dioctyl sodium sulfosuccinate, 8% of EO-PO block polyether, 0.1% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.2% of stabilizer dodecanol, 8% of solvent propylene glycol methyl ether, and the balance of water, wherein the pH value of the pH regulator is adjusted to 7-7.5.
Example 13
An acidic foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 5% of cetyl trimethyl ammonium bromide, 5% of dioctyl sodium sulfosuccinate, 8% of EO-PO block polyether, 0.1% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.2% of stabilizer dodecanol, 8% of solvent propylene glycol methyl ether and the balance of water;
the pH regulator regulates the pH value of the system to 3.
Example 14
An alkaline foam cleaning agent with sterilization performance comprises the following components in percentage by mole: 3% of cetyl trimethyl ammonium bromide, 3% of dioctyl sodium sulfosuccinate, 8% of EO-PO block polyether, 0.1% of bactericide hyperbranched polyamidoamine modified alkyl glycoside, 1.2% of stabilizer dodecanol, 8% of solvent propylene glycol methyl ether and the balance of water;
the pH regulator regulates the pH of the system to 11.
Example 15
A preparation method of a foam cleaning agent with sterilization performance comprises the following steps:
(1) Adding an anionic surfactant into water according to the formula described in examples 1-12, and stirring until the anionic surfactant is completely dissolved to obtain a primary mixed solution;
(2) Adding a nonionic surfactant and a bactericide into the primary mixed solution under the stirring state, stirring uniformly, adding a cationic surfactant, a stabilizer and a solvent, continuously stirring, and regulating the pH value of the system to any required pH value in 3-12 by using a pH regulator after stirring uniformly to obtain the foam cleaning agent.
Comparative example 1
The same components and preparation method as in example 12 are used, except that no bactericide is used.
Comparative example 2
The same components and preparation method as in example 12 are used, except that the bactericide is decamethyibromoammonium.
Comparative example 3
The same components and preparation method as in example 12 are different in that the bactericide is benzalkonium chloride.
Comparative example 4
The same components and preparation method as in example 12 were used, except that the stabilizer was propanol.
Comparative example 5
The same components and preparation method as in example 12 are used, except that the stabilizer is hexanol.
Comparative example 6
The same components and preparation method as in example 12 were used, except that the stabilizer was cetyl alcohol.
Comparative example 7
The same components and preparation method as in example 12 were used, except that no cationic surfactant was used.
Comparative example 8
The same components and preparation method as in example 12 were used, except that no anionic surfactant was used.
Comparative example 9
The same components and preparation method as in example 12 were used, except that no nonionic surfactant was used.
Example 10
The same components and preparation method as in example 12 were used, except that the nonionic surfactant and the stabilizer were not used.
Evaluation of Performance
1. Cleaning ability test: the foam cleaners with disinfecting and cleaning functions provided in examples 1 to 12 and comparative examples 1 to 9 were tested according to the JB/T4323.2-1999 cleaning agent test method, and the results obtained are shown in Table 1:
table 1 cleaning agent Performance test results
| Group of | Appearance (35 ℃ for 90 days visual inspection) | Detergency (%) |
| Example 1 | Uniform and transparent, no delamination and no precipitation | 95.4 |
| Example 2 | Uniform and transparent, no delamination and no precipitation | 97.3 |
| Example 3 | Uniform and transparent, no delamination and no precipitation | 96.1 |
| Example 4 | Uniform and transparent, no delamination and no precipitation | 98.0 |
| Example 5 | Uniform and transparent, no delamination and no precipitation | 98.7 |
| Example 6 | Uniform and transparent, no delamination and no precipitation | 99.2 |
| Example 7 | Uniform and transparent, no delamination and no precipitation | 96.3 |
| Example 8 | Uniform and transparent, no delamination and no precipitation | 95.9 |
| Example 9 | Uniform and transparent, no delamination and no precipitation | 96.2 |
| Example 10 | Uniform and transparent, no delamination and no precipitation | 96.8 |
| Example 11 | Uniform and transparent, no delamination and no precipitation | 97.2 |
| Example 12 | Uniform and transparentNo delamination and no precipitation | 99.6 |
| Example 13 | Uniform and transparent, no delamination and no precipitation | 99.4 |
| Example 14 | Uniform and transparent, no delamination and no precipitation | 99.1 |
| Comparative example 1 | Uniform and transparent, no delamination and no precipitation | 98.6 |
| Comparative example 2 | Uniform and transparent, no delamination and no precipitation | 98.4 |
| Comparative example 3 | Uniform and transparent, no delamination and no precipitation | 98.8 |
| Comparative example 4 | Uniform and transparent, partially aggregated micelle, no precipitation | 89.3 |
| Comparative example 5 | Uniform and transparent, partially aggregated micelle, no precipitation | 91.4 |
| Comparative example 6 | Uniform and transparent, partially aggregated micelleNo precipitate | 87.1 |
| Comparative example 7 | Uniform and transparent, no delamination and no precipitation | 86.3 |
| Comparative example 8 | Uniform and transparent, no delamination and no precipitation | 91.6 |
| Comparative example 9 | Uniform and transparent, partially aggregated micelle, no precipitation | 93.3 |
| Comparative example 10 | Uniform and transparent, layered, and no precipitate | 82.3 |
As can be seen from Table 1, the detergency of the cleaning agent of the present invention was 95% or more, and the detergency was as high as 99%.
As can be seen from the example 12 and the comparative example 1, the invention has a certain improvement of the detergency after adding the bactericide hyperbranched polyamidoamine modified alkyl glycoside.
As can be seen from the examples 12 and 4.5.6, the stabilizer has a large influence on the appearance and cleaning effect of the system, and the stabilizer adopted by the invention can improve the stability of the system at high temperature and greatly improve the cleaning effect.
It can be seen from example 12 and comparative example 7.8.9 that the combination of cationic and anionic surfactants (comparative example 9) is effective in improving detergency, which is much better than that of the mere anionic/non-system, or cationic/non-system.
As can be seen from comparative examples 9 and 10, the stabilizer has a significant effect on the stability of the solution, and the presence of the stabilizer can maintain the stability of the female/male system and improve detergency.
Sterilization performance test
Sterilizing test with comparative examples 1-10 as sample, adjusting sample concentration to 0.01% at 25deg.C, culturing bacteria in culture dish with Escherichia coli, staphylococcus aureus and Candida albicans as test targets to obtain live bacteria with average concentration of Escherichia coli 4.65X10 6 Staphylococcus aureus 3.39X10 6 Candida albicans 3.95×10 6 The sample amount was 5ml and the action time was 5min, and the obtained sterilization rate was shown in Table 2;
TABLE 2 Sterilization test results
As can be seen from Table 2, the sterilization performance of the present invention can be improved to more than 95%, and the sterilization effect of the cleaning agent obtained in example 12 can reach 99%, while the sterilization effect of the disinfectants in comparative examples 1 to 10 is greatly reduced in the same time and at a low concentration.
As can be seen from the data of comparative examples 4-6 and 10, the stabilizer has a greater effect on the bactericidal effect of the system, and the stabilizer of the present invention can enhance the bactericidal effect of the cationic surfactant.
By combining tables 1 and 2, the cleaning agent of the present invention was excellent in detergency and bactericidal effect. The dosage of the anionic surfactant and the cationic surfactant can be reduced, and the dosage of the cleaning agent can be reduced, so that the detergency and the sterilization effect are good under the condition of smaller dosage, and the cost is greatly solved.
Reference herein to "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment may be included in at least one embodiment of the invention. The appearances of such phrases in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Those of skill in the art will explicitly and implicitly appreciate that the embodiments described herein may be combined with other embodiments.
Finally, it should be noted that: the embodiment of the invention is disclosed only as a preferred embodiment of the invention, and is only used for illustrating the technical scheme of the invention, but not limiting the technical scheme; although the invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art will understand that; the technical scheme recorded in the various embodiments can be modified or part of technical features in the technical scheme can be replaced equivalently; such modifications and substitutions do not depart from the spirit and scope of the corresponding technical solutions.
Claims (8)
1. A foam cleaning agent with sterilization performance is characterized in that: the composition comprises the following components in percentage by mole: 1-20% of cationic surfactant, 1-20% of anionic surfactant, 1-20% of nonionic surfactant, 0.01-0.5% of bactericide, 0.1-2% of stabilizer, 1-10% of solvent, 0-20% of pH regulator and the balance of water;
the bactericide is any one of hyperbranched polyamidoamine, hyperbranched polyamidoamine modified chitosan and hyperbranched polyamidoamine modified alkyl glycoside.
2. The foam cleaning agent with sterilization performance according to claim 1, wherein: the composition comprises the following components in percentage by mole: 2-10% of cationic surfactant, 2-10% of anionic surfactant, 5-10% of nonionic surfactant, 0.05-0.1% of bactericide, 0.5-1.5% of stabilizer, 5-8% of solvent, 0-20% of pH regulator and the balance of water.
3. The foam cleaning agent with sterilization performance according to claim 1, wherein: the cationic surfactant is one or more of dodecyl trimethyl ammonium chloride, dodecyl trimethyl ammonium bromide, dodecyl trimethyl potassium sulfate ammonium, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide and cetyl trimethyl potassium sulfate ammonium.
4. The foam cleaning agent with sterilization performance according to claim 1, wherein: the anionic surfactant is one or more of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium alkenyl sulfonate, sodium laureth sulfate and sodium dioctyl succinate.
5. The foam cleaning agent with sterilization performance according to claim 1, wherein: the nonionic surfactant is any one or more of laurinol polyoxyethylene ether, alkyl glycoside and EO-PO block polyether.
6. The foam cleaning agent with sterilization performance according to claim 1, wherein: the stabilizer is long-chain carbon alcohol.
7. The foam cleaning agent with bactericidal property according to claim 6, wherein: the long-chain carbon alcohol is C8-C14 alcohol.
8. A method of preparing a foam cleaning agent according to any one of claims 1 to 7, characterized in that: the method comprises the following steps:
(1) Adding an anionic surfactant into water according to the mass percentage, and stirring until the anionic surfactant is completely dissolved to obtain a primary mixed solution;
(2) Adding the nonionic surfactant and the bactericide into the primary mixed solution under the stirring state, stirring uniformly, adding the cationic surfactant, the stabilizer and the solvent, and continuously stirring to obtain the foam cleaning agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211528549.9A CN116004330A (en) | 2022-11-30 | 2022-11-30 | Foam cleaning agent with sterilization performance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211528549.9A CN116004330A (en) | 2022-11-30 | 2022-11-30 | Foam cleaning agent with sterilization performance and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116004330A true CN116004330A (en) | 2023-04-25 |
Family
ID=86020546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211528549.9A Pending CN116004330A (en) | 2022-11-30 | 2022-11-30 | Foam cleaning agent with sterilization performance and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116004330A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107338121A (en) * | 2017-08-04 | 2017-11-10 | 北京长江脉医药科技有限责任公司 | Dairy processing instruments alkaline cleaning composition and preparation method thereof |
| CN111440676A (en) * | 2020-04-07 | 2020-07-24 | 湖南坤源生物科技有限公司 | Foam cleaning agent with disinfection and cleaning functions and preparation method thereof |
| CN112961345A (en) * | 2021-02-07 | 2021-06-15 | 威海金钰环保科技有限公司 | Chitosan-based hyperbranched polyamidoamine for demulsification of oil-in-water wastewater and quaternary ammonium salt thereof |
-
2022
- 2022-11-30 CN CN202211528549.9A patent/CN116004330A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107338121A (en) * | 2017-08-04 | 2017-11-10 | 北京长江脉医药科技有限责任公司 | Dairy processing instruments alkaline cleaning composition and preparation method thereof |
| CN111440676A (en) * | 2020-04-07 | 2020-07-24 | 湖南坤源生物科技有限公司 | Foam cleaning agent with disinfection and cleaning functions and preparation method thereof |
| CN112961345A (en) * | 2021-02-07 | 2021-06-15 | 威海金钰环保科技有限公司 | Chitosan-based hyperbranched polyamidoamine for demulsification of oil-in-water wastewater and quaternary ammonium salt thereof |
Non-Patent Citations (3)
| Title |
|---|
| 杨红梅 主编: "《药剂学》", 31 July 2020, 天津科学技术出版社, pages: 52 * |
| 潘卫三 主编: "《工业药剂学》", 31 August 2015, 中国医药科技出版社, pages: 64 - 65 * |
| 王中平 等编著: "《表面物理化学》", 30 September 2015, 同济大学出版社, pages: 257 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5547990A (en) | Disinfectants and sanitizers with reduced eye irritation potential | |
| US5739168A (en) | Germicidal-disinfectant detergent composition | |
| CN110903918B (en) | Antibacterial fabric detergent composition | |
| EP0841852B1 (en) | Biguanide composition and method for treating water | |
| CN112375631B (en) | Antibacterial laundry detergent and preparation method thereof | |
| MXPA04007122A (en) | Aqueous herbicidal concentrate comprising a betaine type surfactant. | |
| US5476615A (en) | Low foam sanitizers | |
| CN111440676A (en) | Foam cleaning agent with disinfection and cleaning functions and preparation method thereof | |
| CN113331186B (en) | Foam disinfectant and preparation method thereof | |
| JP2001519846A (en) | Composition effective for fabric softening and method for producing the same | |
| CA1202752A (en) | Fabric softening composition | |
| US8097265B2 (en) | Foam disinfectant | |
| EP0218608B1 (en) | Low-foaming compositions | |
| JP5718586B2 (en) | Detergent composition for textile products | |
| CN116004330A (en) | Foam cleaning agent with sterilization performance and preparation method thereof | |
| JP5322400B2 (en) | Biofilm control agent composition | |
| US20090253610A1 (en) | Fabric softening composition | |
| JP3253271B2 (en) | Liquid detergent composition | |
| CN115895790A (en) | Anion-cation surfactant compound cleaning agent and preparation method thereof | |
| CN104593169A (en) | Disinfectant cleaning agent containing guanidine salt and preparation method of disinfectant cleaning agent | |
| CN114561256A (en) | Bacteriostatic detergent composition | |
| CN113244129A (en) | Antibacterial hand sanitizer and preparation method thereof | |
| CN113163754B (en) | Stable iodine-containing antimicrobial teat dip compositions | |
| JP2002506795A (en) | Composition of tetrakis (hydroxymethyl) phosphonium salt and antifoam | |
| US20150184114A1 (en) | Method for bleaching a surface with a mesitylene sulfonate composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Country or region after: China Address after: No. 17, 2nd Floor, Building A, Building 1, No. 1480 Tianfu Avenue North Section, Chengdu High tech Zone, China (Sichuan) Pilot Free Trade Zone, Chengdu, Sichuan Province, 610000 Applicant after: Chengdu kehongda Chemical Co.,Ltd. Address before: No. 506, 507, 508, Floor 5, Unit 1, Building 1, No. 777, North Yizhou Avenue, Chengdu Hi tech Zone, China (Sichuan) Pilot Free Trade Zone, Chengdu 610000 Applicant before: Sichuan kehongda Group Co.,Ltd. Country or region before: China |
|
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Country or region after: China Address after: 21st Floor, Building 4, No. 11 Yangliu Avenue, Huayuan Street, Xinjin District, Chengdu City, Sichuan Province 610000 Applicant after: Chengdu kehongda Chemical Co.,Ltd. Address before: No. 17, 2nd Floor, Building A, Building 1, No. 1480 Tianfu Avenue North Section, Chengdu High tech Zone, China (Sichuan) Pilot Free Trade Zone, Chengdu, Sichuan Province, 610000 Applicant before: Chengdu kehongda Chemical Co.,Ltd. Country or region before: China |
|
| CB02 | Change of applicant information |