CN115232683A - Wiper condensation bead containing water repellent and preparation method thereof - Google Patents
Wiper condensation bead containing water repellent and preparation method thereof Download PDFInfo
- Publication number
- CN115232683A CN115232683A CN202210846908.9A CN202210846908A CN115232683A CN 115232683 A CN115232683 A CN 115232683A CN 202210846908 A CN202210846908 A CN 202210846908A CN 115232683 A CN115232683 A CN 115232683A
- Authority
- CN
- China
- Prior art keywords
- water
- wiper
- ether
- agent
- portions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 99
- 230000002940 repellent Effects 0.000 title claims abstract description 48
- 239000005871 repellent Substances 0.000 title claims abstract description 48
- 239000011324 bead Substances 0.000 title claims abstract description 39
- 238000009833 condensation Methods 0.000 title claims abstract description 37
- 230000005494 condensation Effects 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 52
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 16
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 12
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- 206010063659 Aversion Diseases 0.000 claims abstract description 9
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- 239000008233 hard water Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims description 55
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 42
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 30
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 22
- -1 siloxane quaternary ammonium salts Chemical class 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 229910052731 fluorine Inorganic materials 0.000 claims description 17
- 239000011737 fluorine Substances 0.000 claims description 17
- 239000000080 wetting agent Substances 0.000 claims description 16
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
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- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 11
- VHLJDTBGULNCGF-UHFFFAOYSA-N Limonin Natural products CC1(C)OC2CC(=O)OCC23C4CCC5(C)C(CC(=O)C6OC56C4(C)C(=O)CC13)c7cocc7 VHLJDTBGULNCGF-UHFFFAOYSA-N 0.000 claims description 10
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 claims description 10
- KBDSLGBFQAGHBE-MSGMIQHVSA-N limonin Chemical compound C=1([C@H]2[C@]3(C)CC[C@H]4[C@@]([C@@]53O[C@@H]5C(=O)O2)(C)C(=O)C[C@@H]2[C@]34COC(=O)C[C@@H]3OC2(C)C)C=COC=1 KBDSLGBFQAGHBE-MSGMIQHVSA-N 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
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- LAVARTIQQDZFNT-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-yl acetate Chemical compound COCC(C)OCC(C)OC(C)=O LAVARTIQQDZFNT-UHFFFAOYSA-N 0.000 claims description 2
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- 239000001606 7-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-5-hydroxy-2-(4-hydroxyphenyl)chroman-4-one Substances 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- 239000001263 FEMA 3042 Substances 0.000 claims description 2
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- RNFAKTRFMQEEQE-UHFFFAOYSA-N Tripropylene glycol butyl ether Chemical compound CCCCOC(CC)OC(C)COC(O)CC RNFAKTRFMQEEQE-UHFFFAOYSA-N 0.000 claims description 2
- VWTINHYPRWEBQY-UHFFFAOYSA-N denatonium Chemical compound [O-]C(=O)C1=CC=CC=C1.C=1C=CC=CC=1C[N+](CC)(CC)CC(=O)NC1=C(C)C=CC=C1C VWTINHYPRWEBQY-UHFFFAOYSA-N 0.000 claims description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/2068—Ethers
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/32—Amides; Substituted amides
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11D3/40—Dyes ; Pigments
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Abstract
The invention discloses a wiper condensation bead containing a water repellent and a preparation method thereof, and relates to the field of detergents. The wiper condensation bead comprises a content and a water-soluble film, wherein the content is coated in the water-soluble film and comprises the following components: 0.5 to 5 portions of water repellent agent, 0.5 to 1.5 portions of fluorocarbon auxiliary agent, 5 to 30 portions of nonionic surfactant, 30 to 50 portions of solvent, 10 to 40 portions of cosolvent, 0.1 to 0.5 portion of preservative, 0.5 to 3 portions of hard water repellent agent, 0.1 to 0.5 portion of aversion agent, 0.1 to 0.5 portion of essence and 0.1 to 0.5 portion of pigment according to the mass portion. The invention uses the water-soluble film bead technology to be different from the traditional bottled or bagged product, optimizes the water repellent agent and the formula, has better hydrophobicity, washing effect and cleanliness than similar products in the market, is more convenient and quicker to use, does not generate redundant packaging wastes, is more environment-friendly, reduces the use requirement of the product on water quality, has higher safety and aesthetic property, and provides excellent smell experience for users.
Description
Technical Field
The invention relates to the technical field of cleaning agents, in particular to wiper condensation beads containing a water repellent agent and a preparation method thereof.
Background
With the rapid development of economy, automobiles become common transportation means for people, and with the improvement of living standard of people, people pay more and more attention to automobile maintenance and nursing. During the running process of an automobile, the automobile body is full of dust, a lot of dirt is adhered to the window glass, and the main components of the dirt are silt, dust, gum, lacca, oil dirt generated by the combustion of gasoline and diesel oil, insect remains and the like. The automobile windshield is an eye of an automobile in the driving process, and the cleanliness of the automobile windshield plays an important role in driving safety. The wiper essence is also called wiper water and automobile glass cleaning agent, is a concentrated automobile windshield cleaning agent, is one of the largest consumables for maintaining automobiles, can be used in combination with a wiper on an automobile to clean the windshield, can quickly remove stubborn dirt, oil stain, water stain and the like on the windshield, keeps the driving visual field wide and bright, and ensures the driving safety.
Chinese patent document CN201810842113.4 discloses a special effect wiper essence for brightening a vehicle and a preparation process thereof in 2020, 2, 7.s, wherein the wiper essence comprises the following components: 0.1-0.5 part of pigment, 3-5 parts of coconut diethanolamide, 1.0-4.5 parts of nonionic fluorine surfactant, 5-8 parts of high-polymerization-degree alkyl glycoside, 0.1-3 parts of polyether silicone oil, 5-8 parts of linear alkyl benzene sodium sulfonate, 0.01-0.1 part of lauryl alcohol polyoxyethylene ether, 2-7 parts of ethylene glycol, 0.01-0.1 part of nonylphenol polyoxyethylene ether and 2-6 parts of isopropanol, and has strong cleaning performance: the dust, dirt and the like on the windshield can be effectively removed, the windshield is kept in the optimal transparent state, frost can be quickly dissolved, and meanwhile, a protective film is formed on the surface of the windshield, so that the formation of fog drops is prevented, and the windshield is ensured to be clear and transparent; and has good antistatic performance: the charge on the surface of the glass can be effectively eliminated, and the antistatic effect is achieved; chinese patent document CN 107488525A discloses a hydrophobic wiper essence and a preparation method thereof in 2017, 12.19.A, the wiper essence is a mixed liquid obtained by stirring and mixing deionized water, amino modified polydimethylsiloxane, an alcohol solvent, glacial acetic acid and a nonionic surfactant, the amino modified polydimethylsiloxane with hydrophobic effect and the nonionic surfactant with good decontamination capability are adopted to prepare the water-based concentrated wiper essence with hydrophobic effect by a special preparation process, the cleaning effect of the common wiper essence is achieved, and effective components of the wiper essence can form a hydrophobic film on the surface of an automobile windshield after use, so that the automobile windshield has the effects of water resistance and self-cleaning, the visual field in the driving process can be kept clear, and the driving safety in rainy days is improved; chinese patent document CN109504553A discloses a glass cleaner for an automobile and a preparation method thereof in 2019, 3 and 22, wherein raw materials comprise a solvent, an anionic surfactant, a nonionic surfactant, a spice, an auxiliary agent, a preservative, a corrosion inhibitor, a dye, a pH regulator and water, the raw materials with high flash point and low residue are compounded, and the glass cleaner achieves the effects of effectively cleaning glass, no corrosion, low residue and no trace on the premise that the flash point of a product is higher than 61 ℃ and the freezing point of the product is lower than-8 ℃.
But the wiper essence widely used at home and abroad mainly has two forms of bottled or bagged liquid and solid effervescent tablets. The existing hydrophobic glass cleaning agent generally takes silicone resin or silicone oil compounds as main components, and is difficult to prepare into a solid effervescent tablet form, the packaged articles of bottled or bagged liquid wiper essence products are discarded after use to form garbage, and the silicone resin or silicone oil hydrophobic agent is gathered on the surface of glass to form an oil film which is difficult to remove in the long-term use process, so that the driving sight is influenced, and potential safety hazards are caused.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides the wiper condensation bead containing the water repellent agent, the water-soluble film condensation bead technology is different from the traditional bottled or bagged product, and the water repellent agent and the formula are optimized, so that the hydrophobicity and the washing effect are superior to those of similar products in the market.
The invention provides a wiper condensation bead containing a water repellent agent, which comprises a content and a water-soluble film, wherein the content is coated in the water-soluble film and comprises the following components: 0.5 to 5 portions of water repellent agent, 0.5 to 1.5 portions of fluorocarbon auxiliary agent, 5 to 30 portions of nonionic surfactant, 30 to 50 portions of solvent, 10 to 40 portions of cosolvent, 0.1 to 0.5 portion of preservative, 0.5 to 3 portions of hard water repellent agent, 0.1 to 0.5 portion of aversion agent, 0.1 to 0.5 portion of essence and 0.1 to 0.5 portion of pigment according to the mass portion.
Further, the proportion of the flooding agent, the fluorocarbon auxiliary agent and the nonionic surfactant is as follows: 1: (1-3): (6-10).
Further, the water-soluble film is one of polyvinyl alcohol PVA, modified polyvinyl alcohol and modified starch.
Further, the water repellent agent is a siloxane quaternary ammonium salt mixture with medium molecular weight, and the fluorocarbon auxiliary agent is an aqueous fluorine defoaming wetting agent.
Further, the nonionic surfactant is one or more of fatty alcohol polyoxyethylene ether, carbonyl alcohol polyoxyethylene ether, isomeric alcohol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid diethanolamide, APG, amine oxide and fatty acid methyl ester ethoxylate.
Further, the solvent is one or more of ethanol, ethylene glycol, polyethylene glycol, propylene glycol, isopropanol, glycerol, sorbitol, diethylene glycol and dipropylene glycol.
Further, the cosolvent is one or more of ethylene glycol butyl ether, ethylene glycol tertiary butyl ether, propylene glycol butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol butyl ether, diethylene glycol dimethyl ether, diethylene glycol hexyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol butyl ether, triethylene glycol methyl ether, triethylene glycol ethyl ether, tripropylene glycol butyl ether, ethylene glycol phenyl ether and propylene glycol propyl ether.
Further, the hard water resisting agent is EDTA-2 sodium, the preservative is Kathon, the essence is food-grade water-soluble essence, and the pigment is food-grade water-soluble pigment.
Further, the aversion agent is one of trans-8-methyl-N-vanillyl-6-nonenamide, denatonium benzoate, tannic acid, naringin, limonin and berberine.
The invention also provides a preparation method of the wiper condensation bead containing the water repellent agent, which is characterized by comprising the following steps:
s1, sequentially adding a water repellent agent, a fluorocarbon auxiliary agent and a nonionic surfactant into a dosing cylinder, starting stirring, and controlling the stirring speed to be 200-600 rpm;
s2, adding a solvent, a cosolvent, a hard water resisting agent and a preservative, and stirring until the materials are completely dissolved;
s3, sequentially adding the aversion agent and the essence, uniformly stirring, finally adding the pigment, and stirring for 15min at a stirring speed of 200-600 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a die through filling equipment to form a water-soluble film, so as to obtain the wiper condensation bead containing the water repellent.
The invention also provides a preparation method of the wiper condensation bead containing the water repellent, which is characterized by comprising the following steps:
s1, sequentially adding a water repellent agent, a fluorocarbon auxiliary agent and a nonionic surfactant into a mixing cylinder, starting stirring, and controlling the stirring speed to be 200-600 rpm;
s2, adding a solvent, a cosolvent, a hard water resisting agent and a preservative, and stirring until the materials are completely dissolved;
s3, sequentially adding the aversion agent and the essence, uniformly stirring, finally adding the pigment, and stirring for 15min at a stirring speed of 200-600 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a die through filling equipment to form a water-soluble film, so as to obtain the wiper condensation bead containing the water repellent.
Specifically, each technical index of the wiper condensation bead containing the water repellent agent is as follows:
the specification of the wiper condensation bead containing the water repellent is 10-20ml.
The appearance of the wiper condensation bead containing the water repellent agent is transparent liquid condensation beads with bright colors and wrapped by a water-soluble film.
The contact angle (hydrophobicity) of the surface of the automobile windshield glass cleaned by the wiper condensation bead containing the water repellent agent is more than or equal to 85 degrees.
The cleaning power of the wiper condensation bead containing the water repellent agent meets the technical requirement of cleaning power under the lowest use concentration of GB/T23436-2009.
Specifically, the wiper condensation bead containing the water repellent can be diluted with water (tap water or purified water) in a ratio of 1.
Compared with the prior art, the invention has the beneficial effects that:
1. the wiper concentrate containing the water repellent agent provided by the invention has the advantages that the water-soluble film is used for wrapping the wiper concentrate content containing the water repellent agent, and the water-soluble film can be quickly hydrolyzed when meeting water during use, so that the wiper concentrate containing the water repellent agent wrapped in the water-soluble film is dissolved in a water tank of a wiper of an automobile, the use is more convenient and quicker, and compared with the traditional wiper concentrate packaging mode, the wiper concentrate containing the water repellent agent is free of redundant packaging wastes, and is more environment-friendly;
2. the invention selects the siloxane quaternary ammonium salt mixture with medium molecular weight as the water repellent agent, has excellent beading and water running performances, and the water repellent agent, the fluorocarbon auxiliary agent and the nonionic surfactant are compounded in proportion, are easy to dissolve in water, can form microemulsion in the water and attach to the surface of the automobile windshield to provide hydrophobic, dustproof, anti-fouling and antistatic performances, can quickly wet the surface of the glass, avoids siloxane from accumulating into an oil film, has a defoaming function, avoids the generation of foam, ensures that the automobile windshield can keep clear vision in the driving process, and improves the driving safety;
3. the components are cooperated, the nonionic surfactant can be compounded with the water repellent, the cleaning effect is good, the solvent and the cosolvent are used in a matching manner, the components in the formula can be effectively dissolved, the performance requirements of the product are met, and the balance of the product cost performance is achieved; the anti-hard water agent can reduce the use requirement of the product on water quality, the preservative can prevent the deterioration of contents, the aversion agent can prevent people from eating by mistake and improve the safety, and the essence and the pigment endow the wiper concentrate bead with beautiful appearance and provide excellent smell experience for users.
Detailed Description
Experimental procedures for the invention not specifically indicated in the following examples are generally carried out under conventional conditions, or as recommended by the manufacturer. The various chemicals used in the examples are commercially available.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
The terms "comprising" and "having," and any variations thereof, are intended to cover non-exclusive inclusions. For example, a process, method, apparatus, article, or device that comprises a list of steps is not limited to only those steps or modules listed, but may alternatively include other steps not listed or inherent to such process, method, article, or device.
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It is to be understood that these descriptions are only illustrative and are not intended to limit the scope of the present invention. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present invention.
The invention is further described in the following examples, which are not intended to limit the scope of the invention.
The reagents used in the invention are all common reagents which can be purchased from conventional reagent production and sale companies,
the water repellent used in the embodiment of the invention is a glass water repellent CPL-1099 purchased from Zhongshan Kebang chemical material technology Limited and a glass hydrophobic brightener CA-809 purchased from Zhongshan Wenkang scientific and technology Limited; the water-based fluorine defoaming wetting agent is purchased from China bear New materials, inc. in Jiangmen city, and the product name is water-based fluorine defoaming wetting agent HW2142.
Example 1 wiper condensation beads containing water repellent agent of the invention and preparation thereof
The formula is as follows: consists of contents and a water-soluble film, wherein the contents consist of the following components: 5kg of siloxane quaternary ammonium salt mixture, 1.5kg of water-based fluorine defoaming wetting agent, 15kg of fatty alcohol polyoxyethylene ether, 15kg of isomeric alcohol polyoxyethylene ether, 47.6kg of propylene glycol, 15kg of diethylene glycol monobutyl ether, 0.1kg of cason, 0.5kg of EDTA-2 sodium, 0.1kg of limonin, 0.1kg of food-grade water-soluble lemon essence and 0.1kg of food-grade water-soluble lemon yellow; the water-soluble film is modified polyvinyl alcohol;
the preparation process comprises the following steps:
s1, sequentially adding a siloxane quaternary ammonium salt mixture, a water-based fluorine defoaming wetting agent, fatty alcohol polyoxyethylene ether and isomeric alcohol polyoxyethylene ether into a proportioning cylinder, starting stirring, and controlling the stirring speed to be 200 rpm;
s2, adding propylene glycol, diethylene glycol monobutyl ether, EDTA-2 sodium and carbazone, and stirring until the materials are completely dissolved;
s3, sequentially adding the limonin and the food-grade water-soluble lemon essence, uniformly stirring, finally adding the food-grade water-soluble lemon yellow, and stirring for 15min at a stirring speed of 200 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a mold to form a water-soluble film, so as to obtain the wiper condensation bead containing the water repellent agent.
Example 2 wiper condensation beads containing water repellent agent of the present invention and preparation thereof
The formula is as follows: consists of contents and a water-soluble film, wherein the contents consist of the following components: 2.5kg of siloxane quaternary ammonium salt mixture, 1.0kg of aqueous fluorine defoaming wetting agent, 5kg of fatty amine polyoxyethylene ether, 5kg of fatty acid diethanolamide, 5kg of APG, 50kg of propylene glycol, 27kg of dipropylene glycol methyl ether, 0.5kg of karson, 3kg of EDTA-2 sodium, 0.5kg of trans-8-methyl-N-vanillyl-6-nonenamide (capsaicin), 0.3kg of food-grade water-soluble cherry essence and 0.2kg of food-grade water-soluble allure red; the water-soluble film is modified starch;
the preparation process comprises the following steps:
s1, adding a siloxane quaternary ammonium salt mixture, a water-based fluorine defoaming wetting agent, fatty amine polyoxyethylene ether, fatty acid diethanolamide and APG into a batching cylinder in sequence, starting stirring, and controlling the stirring speed to be between 400 rpm;
s2, adding propylene glycol, dipropylene glycol methyl ether, EDTA-2 sodium and carson, and stirring until the materials are completely dissolved;
s3, sequentially adding trans-8-methyl-N-vanillyl-6-nonenamide and food-grade water-soluble cherry essence, uniformly stirring, finally adding food-grade water-soluble allure red, and stirring for 15min at the stirring speed of 400 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a mold to form a water-soluble film, so as to obtain the wiper condensation bead containing the water repellent agent.
Example 3 wiper condensation beads containing water repellent agent and preparation thereof
The formula is as follows: consists of contents and a water-soluble film, wherein the contents consist of: 0.5kg of siloxane quaternary ammonium salt mixture, 0.5kg of water-based fluorine element defoaming wetting agent, 3kg of isomeric alcohol polyoxyethylene ether, 1kg of fatty acid diethanolamide, 1kg of fatty acid methyl ester ethoxylate, 25kg of propylene glycol, 25kg of isopropanol, 20kg of diethylene glycol butyl ether, 20kg of dipropylene glycol methyl ether, 0.5kg of cason, 3kg of EDTA-2 sodium, 0.5kg of berberine, 0.3kg of food-grade water-soluble lavender essence and 0.2kg of food-grade water-soluble brilliant blue; the water-soluble film is polyvinyl alcohol (PVA);
the preparation process comprises the following steps:
s1, sequentially adding a siloxane quaternary ammonium salt mixture, a water-based fluorine defoaming wetting agent, isomeric alcohol polyoxyethylene ether, fatty acid diethanolamide and fatty acid methyl ester ethoxylate into a mixing cylinder, starting stirring, and controlling the stirring speed to be 600 rpm;
s2, adding propylene glycol, isopropanol, diethylene glycol butyl ether, dipropylene glycol methyl ether, EDTA-2 sodium and carbazone, and stirring until the materials are completely dissolved;
s3, sequentially adding berberine and food-grade water-soluble lavender essence, uniformly stirring, finally adding food-grade water-soluble brilliant blue, and stirring for 15min at a stirring speed of 600 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a mold through filling equipment to form a water-soluble film, so as to obtain the wiper condensation bead containing the water repellent agent.
Comparative example 1
The formula is as follows: 5kg of siloxane quaternary ammonium salt mixture, 1.5kg of water-based fluorine defoaming wetting agent, 15kg of fatty alcohol polyoxyethylene ether, 15kg of isomeric alcohol polyoxyethylene ether, 47.6kg of propylene glycol, 15kg of diethylene glycol monobutyl ether, 0.1kg of cason, 0.5kg of EDTA-2 sodium, 0.1kg of limonin, 0.1kg of food-grade water-soluble lemon essence and 0.1kg of food-grade water-soluble lemon yellow;
the preparation process comprises the following steps:
s1, sequentially adding a siloxane quaternary ammonium salt mixture, a water-based fluorine defoaming wetting agent, fatty alcohol polyoxyethylene ether and isomeric alcohol polyoxyethylene ether into a proportioning cylinder, starting stirring, and controlling the stirring speed to be 200 rpm;
s2, adding propylene glycol, diethylene glycol monobutyl ether, EDTA-2 sodium and cason, and stirring until the materials are completely dissolved;
and S3, sequentially adding limonin and food-grade water-soluble lemon essence, uniformly stirring, finally adding food-grade water-soluble lemon yellow, and stirring for 15min at a stirring speed of 200rpm to obtain the wiper essence.
This comparative example is different from example 1 in that there is no water-soluble film and there is no operation of step S4.
Comparative example 2
The formula is as follows: consists of contents and a water-soluble film, wherein the contents consist of: 5kg of siloxane quaternary ammonium salt mixture, 20kg of aqueous fluorine defoaming wetting agent, 12kg of fatty alcohol-polyoxyethylene ether, 13kg of isomeric alcohol polyoxyethylene ether, 47.6kg of propylene glycol, 15kg of diethylene glycol monobutyl ether, 0.1kg of kason, 0.5kg of EDTA-2 sodium, 0.1kg of limonin, 0.1kg of food-grade water-soluble lemon essence and 0.1kg of food-grade water-soluble lemon yellow; the water-soluble film is modified polyvinyl alcohol;
the preparation process comprises the following steps:
s1, sequentially adding a siloxane quaternary ammonium salt mixture, a water-based fluorine defoaming wetting agent, fatty alcohol polyoxyethylene ether and isomeric alcohol polyoxyethylene ether into a proportioning cylinder, starting stirring, and controlling the stirring speed to be 200 rpm;
s2, adding propylene glycol, diethylene glycol monobutyl ether, EDTA-2 sodium and cason, and stirring until the materials are completely dissolved;
s3, sequentially adding the limonin and the food-grade water-soluble lemon essence, uniformly stirring, finally adding the food-grade water-soluble lemon yellow, and stirring for 15min at a stirring speed of 200 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a mold through filling equipment to form a water-coating film so as to obtain the wiper condensation bead.
The difference between the comparative example and the example 1 is that the mass ratio of the water repellent agent, the fluorocarbon auxiliary agent and the nonionic surfactant is as follows: 1:4:5.
comparative example 3
The formula is as follows: consists of contents and a water-soluble film, wherein the contents consist of the following components: 5kg of amino modified polydimethylsiloxane, 1.5kg of water-based fluorine defoaming wetting agent, 15kg of fatty alcohol-polyoxyethylene ether, 15kg of isomeric alcohol polyoxyethylene ether, 47.6kg of propylene glycol, 15kg of diethylene glycol monobutyl ether, 0.1kg of cason, 0.5kg of EDTA-2 sodium, 0.1kg of limonin, 0.1kg of food-grade water-soluble lemon essence and 0.1kg of food-grade water-soluble lemon yellow; the water-soluble film is modified polyvinyl alcohol;
the preparation process comprises the following steps:
s1, sequentially adding amino modified polydimethylsiloxane, a water-based fluorine defoaming wetting agent, fatty alcohol polyoxyethylene ether and heterogeneous alcohol polyoxyethylene ether into a proportioning cylinder, starting stirring, and controlling the stirring speed to be 200 rpm;
s2, adding propylene glycol, diethylene glycol monobutyl ether, EDTA-2 sodium and carbazone, and stirring until the materials are completely dissolved;
s3, sequentially adding limonin and food-grade water-soluble lemon essence, uniformly stirring, finally adding food-grade water-soluble lemon yellow, and stirring for 15min at the stirring speed of 200 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a water-soluble film in a mould through filling equipment to obtain wiper condensation beads.
The comparative example differs from example 1 in that the water repellent is an amino-modified polydimethylsiloxane.
Test example one, cleaning effect test of wiper blade
(1) Test samples: wiper extracts prepared in examples 1 to 3 and comparative examples 1 to 3;
(2) The test method comprises the following steps: selecting 10 vehicles of the same automobile model, wherein the windshields of the 10 vehicles have the same cleaning degree, respectively putting the wiper fine samples prepared in the embodiments 1-3 and the comparative examples 1-3 of the invention into wiper water tanks of 6 vehicles, observing the hydrolysis speed, starting a wiper liquid spraying mode after 15 minutes to carry out 10 times of spray washing and scraping on the automobile windshields, and then recording the wiper fine hydrolysis speed, defoaming, dewatering and next cleaning time;
(3) And (3) test results:
TABLE 1 cleaning effect test results of wiper blade
As can be seen from the table 1, the wiper concentrate prepared in the embodiments 1 to 3 of the invention has the advantages of high hydrolysis speed, good defoaming effect, good hydrophobic effect and lasting cleanliness, and can maintain the time for cleaning the next time for more than one month, while the hydrolysis speed, defoaming effect and hydrophobic effect of the wiper concentrate prepared in the comparative examples 1 to 3 are all affected due to the change of the formula or preparation process of the wiper concentrate.
Test example two, cleaning durability test of wiper blade cleaner
1. Test samples: the wiper blade concentrates prepared in the embodiments 1-3 and the comparative examples 1-3 of the invention;
2. the test method comprises the following steps: selecting 10 vehicles of the same automobile model, wherein the windshields of the 10 vehicles have the same cleanness degree, and respectively treating the windshields of the vehicles and the cleanness degree after one day in the same environment by using the wiper essences prepared in the embodiments 1-3 and the comparative examples 1-3 of the invention;
3. and (3) test results:
TABLE 2 duration of cleaning of wiper blade
As can be seen from Table 2, the wiper blade prepared in examples 1 to 3 can keep bright as new after being applied to the windshield of an automobile for 24 hours, does not absorb dust and oil stains, and has good dustproof and antifouling effects; compared with the comparative examples 1-3, the formula or the preparation process of the wiper essence is changed, so that the prepared wiper essence has little dirt when being used for the automobile windshield, the cleaning capability is not good enough, more dust is absorbed after 24 hours to generate more dirt, and the dustproof and antifouling effects are not good.
Third test example water contact angle test of wiper blade
(1) Test samples: wiper extracts prepared in examples 1 to 3 and comparative examples 1 to 3;
(2) The test method comprises the following steps: respectively putting the samples into wiper water tanks of 6 automobiles according to a using mode, filling tap water, starting a wiper liquid spraying mode after 15 minutes to carry out 10 times of spray cleaning and scraping on automobile windshields, carrying out a water contact angle test after the glass is dried, and carrying out a water contact angle test again after starting a wiper to scrape 50 times on the windshields after finishing the primary water contact angle test;
(3) And (3) test results:
TABLE 3 wiper Water contact Angle test
| Sample (I) | Water contact Angle/° (first order) | Water contact Angle/° (after scratching) |
| Example 1 | 117 | 109 |
| Example 2 | 105 | 104 |
| Example 3 | 110 | 102 |
| Comparative example 1 | 102 | 96 |
| Comparative example 2 | 97 | 91 |
| Comparative example 3 | 95 | 89 |
As can be seen from the results in Table 3, the wiper condensation beads prepared in examples 1 to 3 have high water contact angles, and the water contact angle change after 50 times of scraping is small, which indicates that the wiper condensation beads containing the hydrophobic agent prepared in the examples of the present invention can form a durable hydrophobic coating layer on the surface of the windshield, improve the problem that water drops are hung on the windshield, and maintain good sight, wherein the water contact angle of example 1 is the highest, which is the best example of the present invention; in contrast, in comparative examples 1 to 3, the formula or the preparation process of the wiper blade is changed, so that the water contact angle of the wiper blade prepared by the method is not as good as that of the wiper blade prepared by the examples 1 to 3.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. The wiper condensation bead containing the water repellent agent is characterized by comprising a content and a water-soluble film, wherein the content is coated in the water-soluble film and comprises the following components: 0.5 to 5 portions of water repellent agent, 0.5 to 1.5 portions of fluorocarbon auxiliary agent, 5 to 30 portions of nonionic surfactant, 30 to 50 portions of solvent, 10 to 40 portions of cosolvent, 0.1 to 0.5 portion of preservative, 0.5 to 3 portions of hard water repellent agent, 0.1 to 0.5 portion of aversion agent, 0.1 to 0.5 portion of essence and 0.1 to 0.5 portion of pigment according to the mass portion.
2. The water repellant containing wiper condensation bead of claim 1, wherein the ratio of the water repellant, fluorocarbon adjuvant and nonionic surfactant is 1: (1-3): (6-10).
3. The wiper concentrate containing the water repellant of claim 1 wherein the water soluble film is one of polyvinyl alcohol (PVA), modified polyvinyl alcohol, and modified starch.
4. The wiper concentrate containing water repellant of claim 1 wherein the water repellant is a mixture of medium molecular weight siloxane quaternary ammonium salts and the fluorocarbon adjuvant is an aqueous defoaming wetting agent for fluorine.
5. The wiper concentrate containing water repellant of claim 1 wherein the non-ionic surfactant is one or more of fatty alcohol polyoxyethylene ether, carbonyl alcohol polyoxyethylene ether, isomeric alcohol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid diethanolamide, APG, amine oxide, and fatty acid methyl ester ethoxylate.
6. The water repellant containing wiper condensation bead of claim 1, wherein the solvent is one or more of ethanol, ethylene glycol, polyethylene glycol, propylene glycol, isopropyl alcohol, glycerin, sorbitol, diethylene glycol, and dipropylene glycol.
7. The water repellant containing wiper condensation bead of claim 1, wherein the co-solvent is one or more of ethylene glycol butyl ether, ethylene glycol tertiary butyl ether, propylene glycol butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol butyl ether, diethylene glycol dimethyl ether, diethylene glycol hexyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol butyl ether, triethylene glycol methyl ether, triethylene glycol ethyl ether, tripropylene glycol butyl ether, ethylene glycol phenyl ether, and propylene glycol propyl ether.
8. The water repellant containing wiper condensation bead of claim 1, wherein the hard water repellant is EDTA-2 sodium, the preservative is kasong, the flavor is a food grade water soluble flavor, and the pigment is a food grade water soluble pigment.
9. The water repellant containing wiper condensation bead of claim 1, wherein the aversion agent is one of trans-8-methyl-N-vanillyl-6-nonenamide, denatonium benzoate, tannic acid, naringin, limonin, and berberine.
10. The method for preparing the water repellent agent-containing wiper condensation bead as claimed in any one of claims 1 to 9, comprising the steps of:
s1, adding a water repellent agent, a fluorocarbon auxiliary agent and a nonionic surfactant into a mixing cylinder in sequence, starting stirring, and controlling the stirring speed to be between 200 and 600 rpm;
s2, adding a solvent, a cosolvent, a hard water resisting agent and a preservative, and stirring until the materials are completely dissolved;
s3, sequentially adding the aversion agent and the essence, uniformly stirring, finally adding the pigment, and stirring for 15min at the stirring speed of 200-600 rpm;
and S4, filtering and defoaming the feed liquid, and injecting the filtered and defoamed feed liquid into a die through filling equipment to form a water-soluble film, so as to obtain the wiper condensation bead containing the water repellent.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199884A (en) * | 2015-10-28 | 2015-12-30 | 成都顺发消洗科技有限公司 | Environmentally friendly vehicle detergent |
| CN107711870A (en) * | 2017-09-30 | 2018-02-23 | 珠海国佳凝胶研究院有限公司 | The solidifying pearl of one kind sterilization and its application method |
| CN109810800A (en) * | 2019-02-02 | 2019-05-28 | 江苏云瀚股份有限公司 | Expelling water light self-emulsifying composition |
| CN210974598U (en) * | 2019-10-25 | 2020-07-10 | 程建锋 | Car washing liquid condensation bead |
| CN213036324U (en) * | 2020-08-03 | 2021-04-23 | 江苏华彩化学科技有限公司 | Glass water condensation bead |
-
2022
- 2022-07-19 CN CN202210846908.9A patent/CN115232683A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199884A (en) * | 2015-10-28 | 2015-12-30 | 成都顺发消洗科技有限公司 | Environmentally friendly vehicle detergent |
| CN107711870A (en) * | 2017-09-30 | 2018-02-23 | 珠海国佳凝胶研究院有限公司 | The solidifying pearl of one kind sterilization and its application method |
| CN109810800A (en) * | 2019-02-02 | 2019-05-28 | 江苏云瀚股份有限公司 | Expelling water light self-emulsifying composition |
| CN210974598U (en) * | 2019-10-25 | 2020-07-10 | 程建锋 | Car washing liquid condensation bead |
| CN213036324U (en) * | 2020-08-03 | 2021-04-23 | 江苏华彩化学科技有限公司 | Glass water condensation bead |
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