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CN103943650B - Organic electroluminescent display device and mask plate thereof - Google Patents

Organic electroluminescent display device and mask plate thereof Download PDF

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Publication number
CN103943650B
CN103943650B CN201310062710.2A CN201310062710A CN103943650B CN 103943650 B CN103943650 B CN 103943650B CN 201310062710 A CN201310062710 A CN 201310062710A CN 103943650 B CN103943650 B CN 103943650B
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emission layer
green
red
pixel region
layer
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CN103943650A (en
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蔡韬
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Tianma Microelectronics Co Ltd
Shanghai Tianma Microelectronics Co Ltd
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Tianma Microelectronics Co Ltd
Shanghai Tianma Microelectronics Co Ltd
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Abstract

The organic electroluminescent display device provided by the invention has the advantages that the pixels are specially distributed, the size of the opening of the adopted evaporation mask is greatly increased, and the organic electroluminescent display device can be suitable for the pixel design criterion with higher resolution under the same mask design criterion, so that the display device with higher resolution is manufactured. The invention realizes four-color display by using three-color stacking on the premise of not increasing process complexity and process procedure. Thereby realizing the reduction of defects caused by hole blockage, deformation and the like of the mask plate.

Description

A kind of organic elctroluminescent device and mask plate thereof
Technical field
The present invention relates to technical field of flat panel display, particularly relate to a kind of ORGANIC ELECTROLUMINESCENCE DISPLAYS (OLED) Device and be exclusively used in the mask plate of this display device.
Background technology
OLED, i.e. ORGANIC ELECTROLUMINESCENCE DISPLAYS (Organic Electroluminesence Display, OLED), Also referred to as Organic Light Emitting Diode (Organic Light-Emitting Diode).OLED Display Technique with Traditional LCD display mode is different, it is not necessary to backlight, uses the thinnest coating of organic material and glass base Plate, when there being electric current to pass through, these organic materials will be luminous.And OLED display screen can be made more Light thinner, visible angle is bigger, can save significantly on electric energy.OLED by multiple light emitting pixels according to matrix structure Being arranged in a combination, light emitting pixel each for color OLED includes again red sub-pixels, green sub-pixel and Lan Zi Pixel, can also include white sub-pixel for WOLED.
Fig. 1 is the pixel schematic diagram of prior art OLED device.As it is shown in figure 1, OLED 101 includes multiple Pixel P, each pixel " P " includes red green and blue sub-pixels region " SPr ", " SPg " and " SPb ". Each pixel " P " has rectangular shape, thus has width F and height H.Red green and blue sub-pixels district Territory is disposed in each pixel along horizontal direction or vertical direction.Such as, red green and blue sub-pixels district Territory " SPr ", " SPg " and " SPb " respectively has the width of 1/3 of the width " F " corresponding to pixel " P " Height with the height " H " corresponding to pixel " P ".
Red (R), green (G) and blue (B) emission layer 102,103 and 104 are not formed at red, green and blue sub-picture In element region " SPr ", " SPg " and " SPb ".This red, green and blue emission layer 102,103 and 104 and One electrode constitutes light emitting diode together with the second electrode (not shown).In the prior art, OLED uses The trichroism independent ray structure of RGB, uses evaporation masking process in processing procedure, i.e. uses evaporation mask plate respectively Block, form the trichroism structure of R, G, B.Red green and blue sub-pixels region " SPr ", " SPg " and " SPb " Between be spaced apart first distance " a ", the value of a is by shadow problem (shadow problem) and covers The impact of lamina membranacea precision.Therefore, emission layer red green and blue sub-pixels region " SPr ", " SPg " and " SPb " Respectively there is width " W " and height " h ", and be spaced apart from each other by the first distance " a ".Described red, Green and blue emission layer 102,103 and 104 is formed by using shield mask heat deposition.In FIG, red, green It is the lap of the first electrode and the second electrode with blue emission layer 102,103 and 104.
OLED 101 utilizes red, green and blue emission layer 102,103 and 104 in red green and blue sub-pixels district Display full-color image in territory " SPr ", " SPg " and " SPb ".In order to meet high-resolution demand, The area of one pixel " P " and red green and blue sub-pixels region " SPr ", " SPg " and the face of " SPb " Amass and be increasingly reduced within a few seconds, thus the area of red, green and blue emission layer 102,103 and 104 is also reduced.But, Being limited by mask plate processing technology, a has a ultimate value, limits the limit of pixel typesetting density. It addition, the pixel design of elongate so that in use, agglomerated materials is at mask in the perforate of mask plate Deposit on plate, easily cause blocking.
It addition, OLED can also use white light parts to add color membrane process to realize colour picture in prior art. WOLED uses white light parts as luminous source, and the general fashion of employing is blue yellow two-color device, coordinates color film Realize colour picture, but the transmitance of color film is lost, and colour gamut is limited relatively by white light parts light source light spectrum Narrow.
Summary of the invention
Therefore, the present invention is by providing a kind of ORGANIC ELECTROLUMINESCENCE DISPLAYS (OLED) device and being exclusively used in this and show Show the mask plate of device, its effectively prevent due to the restriction of prior art and defect cause one or more Ground problem.
A kind of organic elctroluminescent device, including:
Multiple pixels, each described pixel includes the first pixel region and the second pixel region;
Described first pixel region is arranged on line n, and described second pixel region is arranged on the (n+1)th row, n More than or equal to 1;
Described first pixel region includes that subpixel area red, white, green, described second pixel region include indigo plant Subpixel area;
Red emission layer, described red emission layer is formed in described red sub-pixels region and white sub-pixel region;
Green emission layer, described green emission layer is formed in described green subpixel area and white sub-pixel region;
Blue emission layer, described blue emission layer is formed in described blue subpixel area and white sub-pixel region;
White emission layer, described white emission layer is formed by described red emission layer, green emission layer, blue emission layer stacking.
Preferably, in each described first pixel region each subpixel area put in order identical.
Preferably, putting in order as red sub-pixels district from left to right in described the first adjacent pixel region Territory, white sub-pixel region, green subpixel area.
Preferably, in described first pixel region not light-emitting zone between adjacent subpixels region by digging Anode metal or the cathodic metal in this region empty are formed.
Preferably, in described first pixel region not light-emitting zone between adjacent subpixels region by setting The organic membrane pattern putting projection is formed.
Preferably, described red emission layer, green emission layer, blue emission layer are formed by mask evaporation process.
Preferably, the spacing of emission layer adjacent in described first pixel region is the first distance, adjacent Described first pixel region in emission layer and the emission layer in the second pixel region between distance be Two distances, described first distance and described second distance are all higher than equal to the first ultimate value.
Preferably, the height of the mask plate perforate for forming described red emission layer or green emission layer is equal to Red emission layer or the width of green emission layer;The width of described mask plate perforate is equal to red emission layer or green emission layer Width plus the width of white emission layer plus the first distance.
Preferably, Part I and second are included for forming the mask plate perforate of described blue emission layer Point, the width of described Part I equal to 2 times of described red emission layer or green emission layer width plus described the One distance 2 times plus the width of described white emission layer, the height of described Part I and red emission layer or green The height penetrating layer is equal;The width of described Part II is equal to the width of white emission layer, described Part II Highly add second distance equal to the height of described red emission layer.
A kind of mask plate, it is characterised in that described mask plate is for forming the Organic Electricity described in any of the above-described item Emission layer in electroluminescent display part.
Compared with prior art, the invention have the advantages that
The organic elctroluminescent device that the present invention provides, carries out specified arrangement to pixel, by indigo plant emission layer It is arranged in the second pixel region with the first pixel region different rows at emission layer place red, white, green, convenient Increase the service life of blue pixel, and the method used realizes the bore size of evaporation mask plate significantly Increase, under same mask plate design criteria, go for the pixel design criteria of higher resolution, Thus the display device realizing higher resolution makes.The present invention is not increasing process complexity, manufacturing process On the premise of, by utilizing trichroism stacking, it is achieved that four colors show.Thus realize reduce mask plate plug-hole, The defect that deformation brings.
Accompanying drawing explanation
Some embodiment with reference to accompanying drawing and invention is described the above and other feature of the present invention.
Fig. 1 is the pixel schematic diagram of OLED in prior art.
Fig. 2 is the pixel schematic diagram of OLED in the present invention.
Fig. 3 is the sectional view of the subpixel area of OLED in the present invention.
Fig. 4 (a) is to form the schematic diagram of red emission layer the first mask plate in the present embodiment.
Fig. 4 (b) is the schematic diagram forming the present embodiment medium green emission layer the first mask plate.
Fig. 5 is to be exclusively used in the schematic diagram of second mask plate forming blue emission layer of OLED in the present invention.
Detailed description of the invention
Understandable for enabling the above-mentioned purpose of the present invention, feature and advantage to become apparent from, below in conjunction with the accompanying drawings to this The detailed description of the invention of invention is described in detail.
As shown in Figure 2 and Figure 3, it is provided that substrate 201, the first pixel region 202 it is provided with on the substrate 201 With the second pixel region 203, described first pixel region 202 includes red sub-pixels region " SPr ", green son Pixel region " SPg " and white sub-pixel region " SPw ", described second pixel region 203 includes Lan Zi picture Element region " SPb ".Described first pixel region 202 is arranged on line n, described second pixel region 203 Being arranged on the (n+1)th row, n is the natural number more than or equal to 1.Preferably, adjacent described first pixel region Red sub-pixels region " SPr ", white sub-pixel region " SPw ", green subpixel area " SPg " in territory 202 Setting alternating with each other.Each subpixel area includes launch site E and non-emission region.Non-emission region be corresponding to Region outside the E of launch site.Red emission layer 215R, green emission layer 215G, white emission layer 215W and blue Penetrate a layer 215B to be both formed in the E of launch site.Described red emission layer 215R is included in red sub-pixels region SRr In red emission layer Part I 215Rx, and the red emission layer Part II 215Ry in white sub-pixel region. The green emission layer Part I 215Gx that green emission layer 215G is included in green subpixel area SRg, and Green emission layer Part II 215Gy in white sub-pixel region.Described blue emission layer 215B includes being formed at Blue emission layer Part I 215Bx in blue subpixel area SPb and the indigo plant including white sub-pixel region SPw Emission layer Part II 215By.Described white emission layer 215W is by red emission layer 215R, green emission layer 215G Formed with blue emission layer 215B stacking.
As it is shown on figure 3, the dot structure of the present invention includes that substrate 201, described substrate 201 can be glass Substrate, plastic or quartz substrate.Cushion 204 can be formed on substrate 201, semiconductor layer On the cushion 204 that 205 are formed in non-emission region, semiconductor layer 205 can be by non-crystalline silicon or polysilicon Formed.Preferably, semiconductor layer 205 is formed by polysilicon.Can be by forming amorphous on the substrate 201 Silicon and crystallize this non-crystalline silicon obtain polysilicon semiconductor layer 205. can utilize metal induced crystallisation technique, gold Belong to induction lateral crystallization process, quasi-molecule laser annealing technique or continuously transverse solidifying technique and realize non-crystalline silicon Crystallization.
Gate insulation layer 206 can be formed on semiconductor layer 205, and grid 207 can be formed at gate insulation layer On 206.Foreign ion can utilize grid 206 to mix semiconductor layer 205 as mask, is thus partly leading Body layer 205 is formed source region 208a and drain region 208b.Can be in source region 208a and leakage Channel region 208c is defined between the 208b of territory, polar region.Between insulating barrier 209 can be formed on grid 207.Source Pole 210a and drain electrode 210b can be formed on an insulating barrier 209.Source electrode 210a can pass through the first mistake Hole contacts with source region 208a, and drain electrode 210b can be contacted with drain region 208b by the second via. Passivation layer 211 can be formed at source electrode 210a and drain electrode 210b on, passivation layer 211 can be organic layer, The combination of inorganic layer or organic layer and inorganic layer.Pixel electrode 212 can be formed on passivation layer 211, and And can be contacted with drain electrode 210b by the 3rd via.Pixel electrode 212 can be male or female.When When pixel electrode 212 is anode, can be made up of tin indium oxide (ITO) or indium zinc oxide (IZO).When When pixel electrode 212 is negative electrode, can be made up of Mg, Ca, Al, Ag, Ba or its alloy.Each picture Element electrode 212 is positioned at red sub-pixels region " SPr ", green subpixel area " SPg " and white sub-pixel region In one of " SPw ", blue subpixel area " SPb ".
Define layer 213 with pixel to be formed on pixel electrode 212.Pixel defines layer 213 and includes exposing pixel The opening 213a of electrode 212, opening 213a define launch site E.Pixel defines layer 213 can be by inorganic Insulant, as silicon oxide or silicon nitride are formed, or by organic insulation, such as phenylpropyl alcohol cyclobutane or propylene Acid resin is formed.Then, the first electric charge injection/transport layer 214 is formed at the substrate with opening 213a On 201.First electric charge injection/transport layer 214 can be single one layer or more electric charge injection/transport layer.Work as picture When element electrode 212 is anode, the first electric charge injection/transport layer 214 is hole injection/transport layer;Work as pixel When electrode 212 is negative electrode, the first electric charge injection/transport layer 214 is electronics injection/transport layer.
Red, green, blue, white emission layer 215R, 215G, 215B and 215W are formed at the first electric charge and inject/pass On defeated layer 214.
Second electric charge injection/transport layer 216 can be formed at red, green, blue, white emission layer On 215R, 215G, 215B and 215W.Second electric charge injection/transport layer 216 can utilize spin coating proceeding or Blanket depositing operation is formed.When pixel electrode 212 is anode, the second electric charge injection/transport layer 216 is Electronics injection/transport layer;When pixel electrode 212 is negative electrode, the second electric charge injection/transport layer 216 is empty Cave injection/transport layer.
Comparative electrode 217 is formed in the second electric charge injection/transport layer 216.When pixel electrode 212 is sun During pole, comparative electrode 217 is negative electrode, and comparative electrode 217 can be formed by Al;When pixel electrode 212 When being negative electrode, comparative electrode 217 is anode, and comparative electrode can be formed by ITO.
Pixel electrode 212, the first electric charge injects/transmits 214, each emission layer 215R, 215G, 215B, 215W, Second electric charge injection/transport layer 216 and comparative electrode 217 form light emitting diode.Described red emission layer 215R is formed in described red sub-pixels region and white sub-pixel region;Described green emission layer 215G is formed at In described green subpixel area and white sub-pixel region;Described blue emission layer 215B is formed at the sub-picture of described indigo plant In element region and white sub-pixel region.
In the present embodiment, the red emission layer 215R can being initially formed in the first pixel region 202 and green Penetrate a layer 215G, then form the blue emission layer 215B in the second pixel region 203.Second can also be initially formed Blue emission layer 215B in pixel region 203, then form the red emission layer 215R in the first pixel region 202 With green emission layer 215G.White emission layer 215W is by red emission layer 215R, green emission layer 215G and blue transmitting Layer 215B stacking is formed.
Fig. 4 (a) is to form the schematic diagram of the first mask plate of red emission layer in the present embodiment.
Fig. 4 (b) is the schematic diagram of the first mask plate forming the present embodiment medium green emission layer.
As shown in Fig. 4 (a), Fig. 4 (b), the first mask plate 401 be used for being formed red emission layer 215R or Green emission layer 215G.Described first mask plate 401 includes the first perforate 402.
It is different from for being formed green for forming the alignment position of first mask plate 401 of red emission layer 215R The alignment position of first mask plate 401 of emission layer 215G.I.e. first mask plate 401 is along horizontal direction Mobile to form in red emission layer 215R and green emission layer 215G, form red emission layer the most again Another in 215R and green emission layer 215G.
In the first pixel region 202, each described first opening portion 402 is corresponding to red emission layer 215R or green emission layer 215G.Red emission layer 215R is included in red emission layer in the SRr of red sub-pixels region A part of 215Rx, and the 215Ry in white sub-pixel region.Green emission layer 215G is included in green sub-pixel Green emission layer Part I 215Gx in the SRg of region, and the green emission layer second in white sub-pixel region Part 215Gy.
The size phase of described red emission layer Part I 215Rx and described green emission layer Part I 215Gx With, there is the first width W and first height L;Described red emission layer Part II 215Ry with described green Penetrate the equivalently-sized of layer Part II 215Gy, and equivalently-sized with white emission layer 215W, have Two width X and first height L.The distance between emission layer adjacent in described first pixel region 202 Be the first distance be a, if the distance between red emission layer Part I 215Rx and white emission layer 215W is the One distance " a ", the distance of white emission layer 215W and green emission layer Part II 215Gy is the first distance " a ". Preferably, described second width X is more than described first distance " a ".
Each described first perforate 402 has the first aperture widths U, and described first aperture widths U is equal to The second width X and first of the first width W and white emission layer 215W of red emission layer Part I 215Rx Distance a sum, described first perforate 402 has the first perforate length, and described first perforate length is equal to institute State the first height L.
Fig. 5 is to form the schematic diagram of the second mask plate of blue emission layer in the present embodiment.
As it is shown in figure 5, the second mask plate is used for forming blue emission layer 215B.Described second mask plate includes Second perforate 502, described second perforate 502 includes the second perforate Part I 502a, and the second perforate Two parts 502b.
Described blue emission layer 215B includes the blue emission layer Part I being formed in blue subpixel area SPb 215Bx and the blue emission layer Part II 215By including white sub-pixel region SPw.
Described second perforate Part I 502a corresponding to blue emission layer Part I 215Bx, described second Perforate Part II 502b is corresponding to blue emission layer Part II 215By.
The width of described second perforate Part I 502a is N, described second perforate Part I 502a's Width " N " is substantially equal to 2 times of add described first distance " a " 2 times of the first width " W " and adds Described second width " X ", i.e. N=2W+2a+X, the length of described second perforate Part I 502a is equal to Described first height " L ".The width of described second perforate Part II 502b is equal to described second width " X ", The length " V " of described second perforate Part II 502b is equal to described first height " L " and second distance " d " sum, described second distance " d " is the emission layer in adjacent described first subpixel area 202 And distance between emission layer in the second subpixel area 203.
The adjacent distance between emission layer is affected by shadow problem and mask plate precision, there is the first pole Limit value, described first distance " a " and second distance " d " all could be arranged to more than or equal to this first pole Limit value.
Described red emission layer 215R, green emission layer 215G and blue emission layer 215B are by using mask plate to steam Plating and formed, described white emission layer 215W is by red emission layer 215R, green emission layer 215G and blue emission layer 215B stacks formation.Described red emission layer 215R, green emission layer 215G, blue emission layer 215B and poliosis are penetrated Layer 215W respective pixel electrode 212 and the lap of comparative electrode 217.As in figure 2 it is shown, first Between the adjacent emitting layer of pixel region and each pixel words spoken by an actor from offstage emission layer 215W and blue emission layer first Dividing and arrange not light-emitting zone J between 215Bx, light-emitting zone J is not that the opening portion of mask plate is with non-emissive The region that district is overlapping.In Fig. 2, not light-emitting zone between adjacent emitting layer can use and hollow out this area pixel Electrode or comparative electrode realize, it would however also be possible to employ realize in methods such as forming protruding organic membrane pattern.
In the present embodiment, the distributing order in the first subpixel area 202 is red sub-pixels region, white chessman Pixel region, green subpixel area, protection scope of the present invention is not limited to this, the row in the first sub-pixel 202 Cloth order can also be green subpixel area, white sub-pixel region, red sub-pixels region.
In the present embodiment, the first subpixel area 202 is positioned at the top of the second subpixel area 203, In other embodiments of the invention, it is also possible to the second subpixel area is positioned at the top of the first subpixel area.
Specified arrangement is formed, due to the steaming used after utilizing above-mentioned evaporation mask plate that pixel is deposited with The bore size of plating mask plate is significantly increased, and under same mask plate design criteria, goes for higher The pixel design criteria of resolution, thus the display device realizing higher resolution makes.The present invention is not increasing On the premise of adding process complexity, manufacturing process, by utilizing trichroism stacking, it is achieved that four colors show.From And realize reducing the defect that mask plate plug-hole, deformation etc. bring.
The above, be only presently preferred embodiments of the present invention, not makees the present invention any pro forma Limit.Although the present invention is disclosed above with preferred embodiment, but it is not limited to the present invention.Any Those of ordinary skill in the art, without departing under technical solution of the present invention ambit, may utilize above-mentioned Technical solution of the present invention is made many possible variations and modification, or amendment by the method disclosed and technology contents Equivalent embodiments for equivalent variations.Therefore, every content without departing from technical solution of the present invention, according to this The technical spirit of invention, to any simple modification made for any of the above embodiments, equivalent variations and modification, the most still belongs to In the range of technical solution of the present invention is protected.

Claims (10)

1. an organic elctroluminescent device, including:
Multiple pixels, each described pixel includes the first pixel region and the second pixel region;
Described first pixel region is arranged on line n, and described second pixel region is arranged on the (n+1)th row, n More than or equal to 1;
Described first pixel region includes that subpixel area red, white, green, described second pixel region include indigo plant Subpixel area;
Red emission layer, described red emission layer is formed in described red sub-pixels region and white sub-pixel region;
Green emission layer, described green emission layer is formed in described green subpixel area and white sub-pixel region;
Blue emission layer, described blue emission layer is formed in described blue subpixel area and white sub-pixel region;
White emission layer, described white emission layer is formed by described red emission layer, green emission layer, blue emission layer stacking.
2. organic elctroluminescent device as claimed in claim 1, it is characterised in that each described the In one pixel region each subpixel area put in order identical.
3. organic elctroluminescent device as claimed in claim 2, it is characterised in that each described the Putting in order as red sub-pixels region, white sub-pixel region, green son from left to right in one pixel region Pixel region.
4. organic elctroluminescent device as claimed in claim 1, it is characterised in that at described first picture Between the adjacent emitting layer in element region and in each described pixel white emission layer with in blue subpixel area Between blue emission layer, not light-emitting zone is set, described not light-emitting zone by hollow out this region anode metal or Cathodic metal is formed.
5. organic elctroluminescent device as claimed in claim 1, it is characterised in that at described first picture Between the adjacent emitting layer in element region and in each described pixel white emission layer with in blue subpixel area Arranging not light-emitting zone between blue emission layer, described not light-emitting zone comes by arranging the organic membrane pattern of projection Formed.
6. organic elctroluminescent device as claimed in claim 1, it is characterised in that described red emission layer, Green emission layer, blue emission layer are formed by mask evaporation process.
7. organic elctroluminescent device as claimed in claim 1, it is characterised in that described first pixel The spacing of emission layer adjacent in region is the first distance, the adjacent transmitting in described first pixel region Layer and the second pixel region in emission layer between distance be second distance, between adjacent emission layer away from From there is one first ultimate value, described first distance and described second distance are all higher than equal to described first limit Value.
8. a mask plate, it is characterised in that described mask plate is used for being formed any one of claim 1 to 7 institute Emission layer in the organic elctroluminescent device stated.
9. mask plate as claimed in claim 8, it is characterised in that comprise for forming red emission layer or green Penetrating the first mask plate of layer, the length of described first mask plate perforate is equal to red emission layer or the height of green emission layer Degree;The width of described first mask plate perforate adds white emission layer equal to the width of red emission layer or green emission layer Width plus the first distance.
10. mask plate as claimed in claim 8, it is characterised in that comprise for forming described blue emission layer Second mask plate, described second mask plate perforate includes Part I and Part II, described Part I Width adds described equal to 2 times of described red emission layer or green emission layer width plus described first distance 2 times The width of white emission layer, the height of described Part I is equal with the height of red emission layer or green emission layer;Institute Stating the width width equal to white emission layer of Part II, the height of described Part II is equal to described red transmitting The height of layer is plus second distance.
CN201310062710.2A 2013-02-28 2013-02-28 Organic electroluminescent display device and mask plate thereof Active CN103943650B (en)

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CN104882465A (en) 2015-05-27 2015-09-02 京东方科技集团股份有限公司 Display panel, manufacturing method and display apparatus
CN110071217B (en) * 2019-03-29 2023-12-12 武汉华星光电半导体显示技术有限公司 Mask plate, manufacturing method of display panel and display device
WO2023197115A1 (en) * 2022-04-11 2023-10-19 Guangdong Oppo Mobile Telecommunications Corp., Ltd. Display system

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