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CN103526629B - Pulping process of waste paper with high wet strength - Google Patents

Pulping process of waste paper with high wet strength Download PDF

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CN103526629B
CN103526629B CN201310504684.4A CN201310504684A CN103526629B CN 103526629 B CN103526629 B CN 103526629B CN 201310504684 A CN201310504684 A CN 201310504684A CN 103526629 B CN103526629 B CN 103526629B
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waste paper
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CN103526629A (en
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杨桂花
王宝斌
吴芹
陈嘉川
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Qilu University of Technology
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Abstract

本发明公开了一种高湿强度废纸的制浆工艺,包括以下步骤:(1)将高湿强度废纸处理成8~10cm×2~3cm的纸料,用ClO2进行处理;(2)将上述经过ClO2处理的纸料通过水力碎浆机进行常规疏解;(3)将上述疏解后的浆料进行第二段ClO2处理;(4)上述经过第二段ClO2处理的浆料经过高频疏解机进行常规疏解;(5)将上述疏解后的浆料通过真空洗浆机进行洗涤;(6)上述洗涤后的浆料通过压力筛进行筛选,得到纤维分散好的废纸浆料。本发明改善了高湿强度废纸纤维的制浆性能,提高了纤维的回收利用率,使高湿强度废纸的利用价值大大提高,可解决困扰我国造纸工业发展的资源和环境问题。The invention discloses a high-wet-strength waste paper pulping process, which comprises the following steps: (1) treating the high-wet-strength waste paper into 8-10 cm×2-3 cm paper stock, and treating it with ClO 2 ; (2) ) The above-mentioned paper stock treated with ClO 2 is conventionally decomposed by a hydropulper; (3) The above-mentioned decomposed pulp is subjected to the second stage of ClO 2 treatment; (4) The above-mentioned pulp treated with the second stage of ClO 2 (5) Wash the above-mentioned pulp after being decompressed by a vacuum pulp washer; (6) Screen the above-mentioned washed pulp through a pressure sieve to obtain waste paper with dispersed fibers slurry. The invention improves the pulping performance of high-wet-strength waste paper fibers, improves the recycling rate of fibers, greatly increases the utilization value of high-wet-strength waste paper, and can solve resource and environmental problems that plague the development of my country's paper industry.

Description

A kind of pulping process of high wet strength waste paper
Technical field
The present invention relates to the pulping process of wet strong waste paper, particularly relate to a kind of pulping process of high wet strength waste paper.
Background technology
At present, China is the first in the world pulping and paper-making producing country, but there is the problem of forest reserves scarcity in China, cause pulping and paper-making fibre resources wretched insufficiency, thus China uses non-wood-fiber (as wheat straw, bagasse, reed etc.) to carry out pulping and paper-making in a large number, recycle domestic waste paper and from a large amount of waste paper of external import, to solve the problem of China's fibre resources wretched insufficiency simultaneously.Day by day perfect along with Waste Paper Recycle Technique, waste paper has received the concern of countries in the world as a kind of fibre resources.In recent years, because in China's waste paper, grass fiber ratio is higher, fiber recovery utilization rate was lower, and fiber quality is poor, and thus the more good imported waste papers (as high wet strength waste paper) of fiber quality receive the favor of papermaking enterprise.The paper of high wet strength waste paper is pure, filler is few, without deinking, and raw fiber composition is the good needle-leaved wood fibre of quality and cotton pulp fiber, this type of waste paper can be joined through the fiber of slurrying reuse and copied high-grade paper kind, thus, the slurrying again of high wet strength waste paper fibre utilizes the very big attention having obtained papermaking enterprise, and has good development and application prospect.
The wet strength of general high wet strength paper is higher than its dry strength by more than 30%, this adds increased the recovery difficult of wet strong waste paper fibre.Traditional wet strong waste paper fibre process for reclaiming has Mechanical Method, thermochemical method and Re Fa, there is the problems such as energy consumption is high, process waste water poisonous organohalogen compounds (AOX) content is high, dispersion effect difference discongested by fiber, fiber recovery utilization rate is low in these methods, thus limits the reuse of wet strong waste paper fibre.Therefore need to research and develop the pulping process being applicable to wet strong waste paper, discongest dispersion effect difference, problem that fiber recovery utilization rate is low, to improve the value of wet strong waste paper to solve wet strong waste paper.
Summary of the invention
For above-mentioned prior art, in order to improve the pulpability of high wet strength waste paper, improving the utilization rate of its fibre resources, the invention provides one ClO 2the pulping process of process high wet strength waste paper, thus solve high wet strength waste paper fibre and discongest dispersion effect difference, problem that fiber recovery utilization rate is low.
The present invention is achieved by the following technical solutions:
A pulping process for high wet strength waste paper, adopts chlorine dioxide (ClO 2) carry out double diffusion, then the mechanical force high efficiency dispersion of hydrabrusher and defiberizing machine is utilized to discongest fiber, the secondary stock that fiber dispersion is good and whiteness is high is obtained after screening, thus improve the pulpability of high wet strength waste paper, improve paper pulp yield, increase the value of high wet strength waste paper fibre.Specifically comprise the following steps:
(1) in order to improve the uniformity of slurrying, high wet strength waste paper being processed into the paper stock of 8 ~ 10cm × 2 ~ 3cm through paper cutter, using ClO 2carry out processing (first paragraph ClO 2preliminary treatment), utilize ClO 2strong oxidizing property carry out wet extensive chemical medicament in oxidation dissolution waste paper and destroy the hydrogen bond formed between fiber, thus make waste paper fibre be easy to discongest and be dispersed into paper pulp; Processing mode is: by ClO 2join in slurry, with NaOH solution adjust ph to 4 ~ 5, under the condition of 50 ~ 70 DEG C, carry out first paragraph ClO 2preliminary treatment;
(2) by above-mentioned through ClO 2the paper stock of process carries out routine by hydrabrusher and discongests;
(3) slurry after above-mentioned discongesting is carried out second segment ClO 2process, processes under 50 ~ 70 DEG C of conditions (using NaOH solution adjust ph) with pH value 4 ~ 5;
(4) above-mentioned through second segment ClO 2the slurry of process carries out routine through deflaker and discongests;
(5) slurry after above-mentioned discongesting is washed by vacuum pulp washing machine;
(6) slurry after above-mentioned washing is screened by pressurized screen, obtains the waste paper pulp that fiber dispersion is good.
In described step (1), carry out first paragraph ClO 2pretreated parameter is: the slurry of paper stock is dense is 5wt%, ClO 2consumption is 1 ~ 1.5%, and the processing time is 50 ~ 70min.
In described step (2), the parameter discongested is: the slurry of slurry is dense is 5wt%, and the time of discongesting is 60min.
In described step (3), carry out second segment ClO 2the parameter of process is: the slurry of slurry is dense is 5wt%, ClO 2consumption is 0.5%, and the processing time is 10 ~ 20min.
In described step (4), the parameter that deflaker carries out discongesting is: the slurry of slurry is dense is 4wt%, and the time of discongesting is 10min.
In described step (5), when vacuum pulp washing machine washs, the slurry of slurry is dense is 2.5wt%, and wash time is 30min.
In described step (6), when pressurized screen screens, the slurry of slurry is dense is 4wt%, and sieve seam width is 0.3mm.
The pulping process of high wet strength waste paper of the present invention, high wet strength waste paper is after cutting, and carry out two sections of impregnation process with chemicals, discongest after impregnation process completes, the slurry after discongesting enters washing and screening operation.Conventional waste paper pulp-making technology first adopts clorox (NaClO) to process, and then carries out discongesting of wastepaper as raw material.In the present invention, adopt strong oxidizer chlorine dioxide in conjunction with mechanical force to high wet strength Waste Paper Handling, through two sections of chlorine dioxide treatment in conjunction with mechanical force, carry out dispersion fully to high wet strength waste paper fibre to discongest, obtain secondary stock through washing and screening again, secondary stock can be delivered directly to copy paper operation and carry out copy paper.
The invention has the beneficial effects as follows:
(1) by chlorine dioxide to the dipping of high wet strength wastepaper as raw material and hydrabrusher, the mechanical force of defiberizing machine, weaken the self-crosslinking of wet strength agent self and the co-crosslinking effect between wet strength agent and fiber, be conducive to the removal of wet strength agent in wastepaper as raw material, improve the efficiency of mechanical force, reduce energy consumption;
(2) by the maceration of chlorine dioxide, reduce chemicals consumption in high wet strength Waste Paper Handling, reduce production cost;
(3) chlorine dioxide is a kind of strong oxidizer, is the main drift agent in pulp and paper industry cleaning and bleaching operation, while to wet strength agent effect, paper pulp raw material is had to the effect of bleaching purification;
(4) present invention improves the pulpability of high wet strength waste paper fibre, improve the recovery utilization rate of fiber, the value of high wet strength waste paper is improved greatly, the resources and environment problem of puzzlement China Paper Industry Development can be solved.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Apart from outside special instruction, all percentages involved in embodiment are mass percent.
Embodiment of the present invention high wet strength waste paper used is imported from America high wet strength Waste paper strip, and whiteness is 76.2%ISO.
Embodiment 1 high wet strength waste paper utilization tradition pulping process carries out slurrying
High wet strength waste paper carries out slurrying according to the following steps after cut paper:
1. high wet strength waste paper is after cutting, and with clorox one section process, treatment conditions are temperature 65 ~ 75 DEG C, time 70min, and pH value 1 ~ 3, NaClO consumption 3%, starches dense 5%;
2. by processing gained waste paper material in above-mentioned steps 1, discongested by hydrabrusher, condition of discongesting is for slurry dense 5%, time 60min;
3. discongested by deflaker by the slurry processing gained in above-mentioned steps 3, discongesting slurry dense is 4%;
4. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 4, detergent milk is dense is 2.5%;
5. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 5, detergent milk is dense is 4%, is then screened by pressurized screen again, and sieve seam width is 0.3mm, obtains wet strong secondary stock.
Result: through Performance Detection, the secondary stock whiteness 78.9%ISO of above-mentioned conventional processing steps gained, yield 89.2%, length 1.049mm.
Embodiment 2 high wet strength waste paper utilization pulping process of the present invention carries out slurrying
High wet strength waste paper carries out slurrying according to the following steps after cut paper:
1. high wet strength waste paper is after cutting, carries out first paragraph process with chlorine dioxide, and treatment conditions are temperature 50 ~ 55 DEG C, time 50min, pH value 4 ~ 5, ClO 2consumption 1%, starches dense 5%;
2. by processing gained waste paper material in above-mentioned steps 1, discongested by hydrabrusher, condition of discongesting is for slurry dense 5%, time 60min;
3. the slurry processing gained in above-mentioned steps 2 is carried out second segment chlorine dioxide treatment, treatment conditions are temperature 50 ~ 55 DEG C, time 10min, pH value 4 ~ 5, ClO 2consumption 0.5%, starches dense 5%;
4. discongested by deflaker by the slurry processing gained in above-mentioned steps 3, discongesting slurry dense is 4%, and the time is 10min;
5. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 4, detergent milk is dense is 2.5%, and the time is 30min;
6. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 5, detergent milk is dense is 4%, is then screened by pressurized screen again, and sieve seam width is 0.3mm, obtains wet strong secondary stock.
Result: through Performance Detection, the secondary stock whiteness 82.1%ISO of above-mentioned treatment step gained, yield 97.1%, length 1.083mm.Compared with the secondary stock (embodiment 1) of the conventional NaClO process under same treatment process conditions, pulp brightness improves 4.1%ISO, and paper pulp yield improves 8.9%, and average fiber length improves 3.2%.
Embodiment 3 high wet strength waste paper utilization pulping process of the present invention carries out slurrying
High wet strength waste paper carries out slurrying more according to the following steps after cut paper:
1. the high wet strength waste paper after cutting first carries out first paragraph chlorine dioxide treatment, and treatment conditions are temperature 60 ~ 70 DEG C, time 50min, pH value 4 ~ 5, ClO 2consumption 1%, starches dense 5%;
2. by processing gained waste paper material in above-mentioned steps 1, discongested by hydrabrusher, condition of discongesting is for slurry dense 5%, time 60min;
3. the slurry processing gained in above-mentioned steps 2 is carried out second segment chlorine dioxide treatment, treatment conditions are temperature 60 ~ 70 DEG C, time 10min, pH value 4 ~ 5, ClO 2consumption 0.5%, starches dense 5%;
4. discongested by deflaker by the slurry processing gained in above-mentioned steps 3, discongesting slurry dense is 4%, and the time is 10min;
5. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 4, detergent milk is dense is 2.5%, and the time is 30min;
6. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 5, detergent milk is dense is 4%, is then screened by pressurized screen again, and sieve seam width is 0.3mm, obtains wet strong secondary stock.
Result: through Performance Detection, the secondary stock whiteness 84.2%ISO of above-mentioned treatment step gained, yield 96.5%, length 1.078mm.Compared with the secondary stock of the conventional NaClO process under same treatment process conditions, pulp brightness improves 7.5%, and paper pulp yield improves 8.2%, and average fiber length improves 2.8%.
Embodiment 4 high wet strength waste paper utilization pulping process of the present invention carries out slurrying
The strong waste paper of high humidity carries out slurrying more according to the following steps after cut paper:
1. the strong waste paper of the high humidity after cutting first carries out first paragraph chlorine dioxide treatment, and treatment conditions are temperature 60 ~ 70 DEG C, time 60min, pH value 4 ~ 5, ClO 2consumption 1%, starches dense 5%;
2. by processing gained waste paper material in above-mentioned steps 1, discongested by hydrabrusher, condition of discongesting is for slurry dense 5%, time 60min;
3. carry out second segment chlorine dioxide treatment by processing gained slurry in above-mentioned steps 2, treatment conditions are temperature 60 ~ 70 DEG C, time 20min, pH value 4 ~ 5, ClO 2consumption 0.5%, starches dense 5%;
4. discongested by deflaker by the slurry processing gained in above-mentioned steps 3, discongesting slurry dense is 4%, and the time is 10min;
5. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 4, detergent milk is dense is 2.5%, and the time is 30min;
6. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 5, detergent milk is dense is 4%, is then screened by pressurized screen again, and sieve seam width is 0.3mm, obtains wet strong secondary stock.
Result: through Performance Detection, the secondary stock whiteness 84.8%ISO of above-mentioned treatment step gained, yield 95.9%, length 1.072mm.Compared with the secondary stock of the conventional NaClO process under same treatment process conditions, pulp brightness improves 8.5%, and paper pulp yield improves 7.5%, and average fiber length improves 2.2%.
Embodiment 5 high wet strength waste paper utilization pulping process of the present invention carries out slurrying
High wet strength waste paper carries out slurrying more according to the following steps after cut paper:
1. the high wet strength waste paper after cutting first carries out first paragraph chlorine dioxide treatment, and treatment conditions are temperature 60 ~ 70 DEG C, time 60min, pH value 4 ~ 5, ClO 2consumption 1.5%, starches dense 5%;
2. by processing gained waste paper material in above-mentioned steps 1, discongested by hydrabrusher, condition of discongesting is for slurry dense 5%, time 60min;
3. the slurry processing gained in above-mentioned steps 2 is carried out second segment chlorine dioxide treatment, treatment conditions are temperature 60 ~ 70 DEG C, time 20min, pH value 4 ~ 5, ClO 2consumption 0.5%, starches dense 5%;
4. discongested by deflaker by the slurry processing gained in above-mentioned steps 3, discongesting slurry dense is 4%, and the time is 10min;
5. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 4, detergent milk is dense is 2.5%, and the time is 30min;
6. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 5, detergent milk is dense is 4%, is then screened by pressurized screen again, and sieve seam width is 0.3mm, obtains wet strong secondary stock.
Result: through Performance Detection, the secondary stock whiteness 85.9%ISO of above-mentioned treatment step gained, yield 93.2%, length 1.062mm.Compared with the secondary stock of the conventional NaClO process under same treatment process conditions, pulp brightness improves 10.3%, and paper pulp yield improves 4.5%, and average fiber length improves 1.2%.
Embodiment 6 high wet strength waste paper utilization pulping process of the present invention carries out slurrying
High wet strength waste paper carries out slurrying more according to the following steps after cut paper:
1. the high wet strength waste paper after cutting first carries out first paragraph chlorine dioxide treatment, and treatment conditions are temperature 50 ~ 55 DEG C, time 70min, pH value 4 ~ 5, ClO 2consumption 1%, starches dense 5%;
2. by the waste paper material of process in above-mentioned steps 1, discongested by hydrabrusher, condition of discongesting is for slurry dense 5%, time 60min;
3. the slurry processing gained in above-mentioned steps 2 is carried out second segment chlorine dioxide treatment, treatment conditions are temperature 50 ~ 55 DEG C, time 20min, pH value 4 ~ 5, ClO 2consumption 0.5%, starches dense 5%;
4. discongested by deflaker by the slurry processing gained in above-mentioned steps 3, discongesting slurry dense is 4%, and the time is 10min;
5. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 4, detergent milk is dense is 2.5%, and the time is 30min;
6. washed by vacuum pulp washing machine by the slurry processing gained in above-mentioned steps 5, detergent milk is dense is 4%, is then screened by pressurized screen again, and sieve seam width is 0.3mm, obtains wet strong secondary stock.
Result: through Performance Detection, the secondary stock whiteness 83.3%ISO of above-mentioned treatment step gained, yield 96.1%, length 1.073mm.Compared with the secondary stock of the conventional NaClO process under same treatment process conditions, pulp brightness improves 6.1%, and paper pulp yield improves 7.8%, and average fiber length improves 2.3%.

Claims (1)

1. a pulping process for high wet strength waste paper, is characterized in that: comprise the following steps:
(1) high wet strength Waste Paper Handling is become the paper stock of 8 ~ 10cm × 2 ~ 3cm, use ClO 2process, processing mode is: by ClO 2join in slurry, with NaOH solution adjust ph to 4 ~ 5, under the condition of 50 ~ 70 DEG C, carry out first paragraph ClO 2preliminary treatment;
(2) by above-mentioned through ClO 2the paper stock of process carries out routine by hydrabrusher and discongests;
(3) slurry after above-mentioned discongesting is carried out second segment ClO 2process, processes under 50 ~ 70 DEG C of conditions with pH value 4 ~ 5;
(4) above-mentioned through second segment ClO 2the slurry of process carries out routine through deflaker and discongests;
(5) slurry after above-mentioned discongesting is washed by vacuum pulp washing machine;
(6) slurry after above-mentioned washing is screened by pressurized screen, obtains the waste paper pulp that fiber dispersion is good;
In described step (1), carry out first paragraph ClO 2pretreated parameter is: the slurry of paper stock is dense is 5wt%, ClO 2consumption is 1 ~ 1.5%, and the processing time is 50 ~ 70min;
In described step (2), the parameter discongested is: the slurry of slurry is dense is 5wt%, and the time of discongesting is 60min;
In described step (3), carry out second segment ClO 2the parameter of process is: the slurry of slurry is dense is 5wt%, ClO 2consumption is 0.5%, and the processing time is 10 ~ 20min;
In described step (4), the parameter that deflaker carries out discongesting is: the slurry of slurry is dense is 4wt%, and the time of discongesting is 10min;
In described step (5), when vacuum pulp washing machine washs, the slurry of slurry is dense is 2.5wt%, and wash time is 30min;
In described step (6), when pressurized screen screens, the slurry of slurry is dense is 4wt%, and sieve seam width is 0.3mm.
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Publication number Priority date Publication date Assignee Title
CN104947490A (en) * 2014-03-24 2015-09-30 上海嘉龙纸业有限公司 Regeneration method of special wastepaper and application of regenerated special wastepaper
CN104164805B (en) * 2014-06-27 2017-01-18 南京林业大学 A method of enhancing papermaking wet-end paper strength by applying betaine amphoteric cellulose
CN106337311A (en) * 2015-07-11 2017-01-18 陈福堂 Extraordinary wet-strength paper processing auxiliary agent and application method thereof
CN107881847A (en) * 2017-12-29 2018-04-06 安徽宏实光机电高科有限公司 A kind of method using wet strong waste paper manufacture regenerated paper pulp wrapping paper
CN115976867B (en) * 2023-01-11 2024-07-05 广东华凯科技股份有限公司 Composition capable of rapidly dissociating wet strength paper, and preparation method and application thereof

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