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CN102700014A - Diamond micro-powder plated titanium, nickel-phosphorous and nickel composite diamond wire saw as well as preparation method thereof - Google Patents

Diamond micro-powder plated titanium, nickel-phosphorous and nickel composite diamond wire saw as well as preparation method thereof Download PDF

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Publication number
CN102700014A
CN102700014A CN2012101914542A CN201210191454A CN102700014A CN 102700014 A CN102700014 A CN 102700014A CN 2012101914542 A CN2012101914542 A CN 2012101914542A CN 201210191454 A CN201210191454 A CN 201210191454A CN 102700014 A CN102700014 A CN 102700014A
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China
Prior art keywords
nickel
diadust
diamond
phosphorus
titanizing
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CN2012101914542A
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Chinese (zh)
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CN102700014B (en
Inventor
徐君
陈伟恩
陈信儒
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Shanghai Jiangxin Ultrahard Material Co., Ltd.
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SHANGHAI FINE ABRASIVES GRINDING TOOLS CO Ltd
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Priority to CN201210191454.2A priority Critical patent/CN102700014B/en
Publication of CN102700014A publication Critical patent/CN102700014A/en
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Publication of CN102700014B publication Critical patent/CN102700014B/en
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  • Electroplating Methods And Accessories (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

The invention provides a diamond micro-powder plated titanium, nickel-phosphorous and nickel composite diamond wire saw as well as a preparation method thereof, belonging to the technical field of an ultra-hard material tool. A composite structure of diamond micro-powder plated titanium, nickel-phosphorous and nickel is adhered or supported on a diamond wire saw; the composite structure of the diamond micro-powder plated titanium, the nickel-phosphorous and the nickel is provided with the diamond micro-powder on the diamond surface; a titanium (Ti) layer is arranged on the diamond micro-powder; a nickel-phosphorous (NiP) alloy layer is arranged on the Ti layer; and a pure nickel (Ni) layer is arranged on the NiP alloy layer. By creatively improving aiming at the production process of the diamond wire saw, the efficiency of the diamond wire saw in rapid production can be improved. Compared with the normal sanding speed about 2 hours of the traditional electric-plated product tool, the sanding speed is about 0.25 meters per second that the traditional electric-plated product tool cannot reach, after the method provided by the invention is used. Therefore, the wire saw cannot be produced by the traditional process.

Description

Diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw and preparation method
Technical field
The present invention relates to a kind of diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw and preparation method, belong to the tool made of superhard material technical field.
Background technology
Diamond is used more and more widely in industry, and especially in the sudden emergence of LED, these new industries of solar energy now, diamond has replaced the effect of conventional abrasives carborundum (SiC) in these operations, obtains more importantly status.Particularly on environmental issue, obtained breakthrough.Traditional abrasive material carborundum (SiC) has the characteristics of highly energy-consuming, high pollution, and diamond then has its low power consuming, low pollution, long service life, repeatedly used advantage.
Summary of the invention
The present invention solves electroplating diamond wire saw in producing fast, to make diadust also can hold knot fast on metal wire, reaches the purpose of quick production.
The preparation method of diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw utilizes the characteristic of magnetic to make that the high magnetic diadust of three layers of coating is arranged in scroll saw production, holds knot fast on metal wire; Contain following steps: outside titanium layer, plate earlier the nickel (not having magnetic because of nickel-phosphorus alloy has only hardness and fragility) of one deck nickel-phosphorus alloy so in cutting, can not produce very big resistance, and then plating one deck pure nickel.
The present invention utilizes scroll saw that the nickel plating diamond makes in cutting silicon and sapphire process, owing to the reason of pure nickel can produce bigger cutting resistance, influence cutting speed and scroll saw and ruptures.For addressing this problem, nickel dam is changed.Outside titanium layer, plate earlier the nickel (not having magnetic because of nickel-phosphorus alloy has only hardness and fragility) of one deck nickel-phosphorus alloy so in cutting, can not produce very big resistance, and then plating one deck pure nickel.So promptly reduced resistance, the magnetic of having got back, thus obtained the purpose of quick production.
For realizing this purpose; Design of the present invention; Diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw; Adhere to or hold knot has diadust titanizing and nickel phosphorus and nickel on diamond fretsaw composite construction, the composite construction of diadust titanizing and nickel phosphorus and nickel is that diamond surface has diadust; One titanium (Ti) layer is arranged on described diadust; One nickel-phosphorus alloy (NiP) layer is arranged on titanium layer; One pure nickel (Ni) layer is arranged on ni-p alloy coating.
Diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw, diadust surface titanizing layer, nickel plating phosphorus on titanium layer, plating one deck pure nickel on nickel phosphorus again; And then to high magnetic on the diadust that three layers of coating are arranged.
Diadust titanizing, nickel phosphorus and nickel complex are attached on the diamond fretsaw.
The composite construction of a kind of diadust titanizing and nickel phosphorus and nickel, there is diadust on diamond 1 surface; One titanium (Ti) layer 2 is arranged on described diadust; One nickel-phosphorus alloy (NiP) layer 3 is arranged on titanium layer 2; One pure nickel (Ni) layer 4 is arranged on ni-p alloy coating 3.
Diadust is a graininess.
High magnetic on the diadust that three layers of coating (nickel dam and ni-p alloy coating and pure-nickel-layer) arranged.Diadust titanizing, nickel phosphorus and nickel composite construction be attached on the diamond fretsaw, after adhering to, and diamond and metal wire on the metallic nickel coated metal line.
Technique effect of the present invention:
The technical effect of the present invention, the diamond wire saw for the creation of the production process to be improved to solve the diamond wire saw rapid production efficiency of the conventional electroplating products are not possible to achieve such a degree of sand on Lai, the normal speed on the sand for about 2 hours, and method of the present invention, the second speed of about 0.25 meters of sand, with the conventionally arts is Ji production of a wire saw.
Description of drawings
When combining accompanying drawing to consider; Through with reference to following detailed, can more completely understand the present invention better and learn wherein many attendant advantages easily, but accompanying drawing described herein is used to provide further understanding of the present invention; Constitute a part of the present invention; Illustrative examples of the present invention and explanation thereof are used to explain the present invention, do not constitute improper qualification of the present invention, like figure wherein:
Fig. 1 diadust granule partial of the present invention cross-sectional view.
Fig. 2 structural representation of the present invention.
The specific embodiment
Embodiment 1: like Fig. 1, shown in Figure 2, the composite construction 6 of diadust titanizing of the present invention and nickel phosphorus and nickel: there is a diadust on diadust 1 surface; One titanium (Ti) layer 2 is arranged on described diadust layer; One nickel-phosphorus alloy (NiP) layer 3 is arranged on titanium layer 2; One pure nickel (Ni) layer 4 is arranged on ni-p alloy coating 3, adhere to or hold knot on diamond fretsaw 5, describedly adhere to or hold that to become magnetic bonding, metallic nickel 7 parcel diadust titanizings and the composite construction 6 of nickel phosphorus and nickel and the surface of diamond fretsaw 5.
Embodiment 2: the composite construction of diadust titanizing of the present invention and nickel phosphorus and nickel: diadust 1 is a graininess; Irregular scraggly type looks surface is arranged; Described titanium (Ti) layer 2, nickel-phosphorus alloy (NiP) layer 3, pure nickel (Ni) layer 4; Form composite bed according to diamond 1 irregular scraggly type looks surface, parcel diamond 1 holds knot on diamond fretsaw; Describedly adhere to or hold that to become magnetic bonding, metallic nickel is enclosed with the diamond fretsaw of the composite construction of diadust titanizing and nickel phosphorus and nickel; The surface of the diamond fretsaw 5 of the composite construction 6 of metallic nickel 7 coated magnetic bonding diamond micro mist titanizings and nickel phosphorus and nickel.
The preparation method of diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw, contain following steps:
Step 1, at first outside diadust, plate titanium, nickel, phosphorus, plate pure nickel again;
Step 2, put into electroplating bath with the diadust that has plated titanium nickel and stir, simultaneously fast deposition (Ф 0.12-Ф 0.36) on wire with electrolyte.The principle of fast deposition is because the plated film diadust has strong magnetic, utilizes strong magnetic to be attached to (translational speed of line is per minute 10m-15m, so need fast) on the Buddha's warrior attendant line;
Step 3, after diamond is adsorbed on the metal wire, again with galvanoplastic metallic nickel wrap (bag to about degree 70%-50%) at the diamond on the metal wire, play fixation.At this moment, line has just been accomplished.
Generally speaking, mainly be through the diamond coated diamond band magnetic that makes, lean on magnetic to come absorption fast then.Its speed of production is per minute 10m-15m when producing diamond fretsaw, so need absorption fast.
As stated, embodiments of the invention have been carried out explanation at length, but as long as not breaking away from inventive point of the present invention and effect in fact can have a lot of distortion, this will be readily apparent to persons skilled in the art.Therefore, such variation also all is included within protection scope of the present invention.

Claims (6)

1. diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw; It is characterized in that: adhere to or hold knot has diadust titanizing and nickel phosphorus and nickel on diamond fretsaw composite construction, the composite construction of diadust titanizing and nickel phosphorus and nickel is that diamond surface has diadust; One titanium (Ti) layer is arranged on described diadust; One nickel-phosphorus alloy (NiP) layer is arranged on titanium layer; One pure nickel (Ni) layer is arranged on ni-p alloy coating.
2. diadust titanizing according to claim 1, nickel phosphorus and nickel complex diamond fretsaw is characterized in that: diadust is a graininess.
3. diadust titanizing according to claim 1, nickel phosphorus and nickel complex diamond fretsaw is characterized in that: three layers of coating are being arranged, high magnetic on the diadust of nickel dam and ni-p alloy coating and pure-nickel-layer.
4. according to the described diadust titanizing of claim 1-3, nickel phosphorus and nickel complex diamond fretsaw; It is characterized in that: describedly adhere to or hold that to become magnetic bonding, metallic nickel parcel diadust titanizing and the composite construction of nickel phosphorus and nickel and the surface of diamond fretsaw.
5. the preparation method of diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw is characterized in that in scroll saw production, utilizing the characteristic of magnetic to make that the high magnetic diadust of three layers of coating is arranged, and holds knot fast on metal wire; Contain following steps: outside titanium layer, plate earlier the nickel of one deck nickel-phosphorus alloy, and then plating one deck pure nickel.
6. the preparation method of diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw is characterized in that:
Step 1, at first outside diadust, plate titanium, nickel, phosphorus, plate pure nickel again;
Step 2, put into electroplating bath with the diadust that has plated titanium nickel and stir, simultaneously fast deposition (Ф 0.12-Ф 0.36) on wire with electrolyte; Utilize strong magnetic to be attached on the Buddha's warrior attendant line, the translational speed of line is per minute 10m-15m, so need fast;
Step 3, after diamond is adsorbed on the metal wire, wrap metallic nickel to diamond on metal wire with galvanoplastic again, bag plays fixation to degree 70%-50%.
CN201210191454.2A 2012-06-11 2012-06-11 Diadust titanizing, nickel phosphorus and nickel complex diamond fretsaw and preparation method Active CN102700014B (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103173840A (en) * 2013-03-12 2013-06-26 白鸽磨料磨具有限公司 Method for producing grinding electroplated diamond wheel
CN103213201A (en) * 2013-05-07 2013-07-24 湖北银天钻石科技有限公司 Diamond cutter head cutting top-grade marble
CN104088000A (en) * 2013-05-09 2014-10-08 吴红平 Diamond wire production method
CN104789931A (en) * 2015-04-29 2015-07-22 富耐克超硬材料股份有限公司 Titanizing process for superhard material micro powder
CN106894075A (en) * 2017-03-23 2017-06-27 南京三超新材料股份有限公司 Diamond surface magnetic coating and its coating method
CN109267130A (en) * 2018-08-23 2019-01-25 信丰崇辉科技有限公司 The electroplating system and electro-plating method of diamond cutting secant
CN110079801A (en) * 2019-06-04 2019-08-02 泉州华大超硬工具科技有限公司 A kind of functionalization diamond of coating surface complex metal layer
CN112063874A (en) * 2020-09-21 2020-12-11 广东省科学院新材料研究所 Diamond composite material and preparation method and application thereof
CN112322938A (en) * 2020-09-21 2021-02-05 北京科技大学 Nickel-based composite material based on additive manufacturing, preparation method and forming method thereof
CN117067419A (en) * 2023-10-16 2023-11-17 江苏三超金刚石工具有限公司 High-hardness diamond wire saw and processing technology thereof

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CN85100286A (en) * 1985-04-01 1986-08-27 林增栋 The technology of diamond surface metallization
JPS6464717A (en) * 1987-09-04 1989-03-10 Kanai Hiroyuki Wire for wire saw
CN1332663A (en) * 1998-03-11 2002-01-23 诺顿公司 Superabrasive wire saw and method for making the saw
US20040107648A1 (en) * 2002-09-24 2004-06-10 Chien-Min Sung Superabrasive wire saw and associated methods of manufacture
CN101905447A (en) * 2009-05-01 2010-12-08 信越化学工业株式会社 Method and jig assembly for manufacturing outer blade cutting wheel
CN101998894A (en) * 2008-04-11 2011-03-30 联合材料公司 Electrodeposited wire tool and method of producing same
CN101838838B (en) * 2010-04-26 2011-12-07 长沙岱勒新材料科技有限公司 Preparation method of composite diamond fretsaw
WO2011158834A1 (en) * 2010-06-15 2011-12-22 新日本製鐵株式会社 Saw wire
WO2012020947A2 (en) * 2010-08-09 2012-02-16 Iljin Diamond Co.,Ltd. Wire tool
CN202727134U (en) * 2012-06-11 2013-02-13 上海精研磨料磨具有限公司 Diamond micropowder titanium, nickel-phosphorous and nickel plated diamond jigsaw

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* Cited by examiner, † Cited by third party
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CN85100286A (en) * 1985-04-01 1986-08-27 林增栋 The technology of diamond surface metallization
JPS6464717A (en) * 1987-09-04 1989-03-10 Kanai Hiroyuki Wire for wire saw
CN1332663A (en) * 1998-03-11 2002-01-23 诺顿公司 Superabrasive wire saw and method for making the saw
US20040107648A1 (en) * 2002-09-24 2004-06-10 Chien-Min Sung Superabrasive wire saw and associated methods of manufacture
CN101998894A (en) * 2008-04-11 2011-03-30 联合材料公司 Electrodeposited wire tool and method of producing same
CN101905447A (en) * 2009-05-01 2010-12-08 信越化学工业株式会社 Method and jig assembly for manufacturing outer blade cutting wheel
CN101838838B (en) * 2010-04-26 2011-12-07 长沙岱勒新材料科技有限公司 Preparation method of composite diamond fretsaw
WO2011158834A1 (en) * 2010-06-15 2011-12-22 新日本製鐵株式会社 Saw wire
WO2012020947A2 (en) * 2010-08-09 2012-02-16 Iljin Diamond Co.,Ltd. Wire tool
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103173840A (en) * 2013-03-12 2013-06-26 白鸽磨料磨具有限公司 Method for producing grinding electroplated diamond wheel
CN103173840B (en) * 2013-03-12 2015-10-21 白鸽磨料磨具有限公司 A kind of preparation method of grinding plated diamond grinding wheel
CN103213201A (en) * 2013-05-07 2013-07-24 湖北银天钻石科技有限公司 Diamond cutter head cutting top-grade marble
CN103213201B (en) * 2013-05-07 2015-09-16 湖北银天钻石科技有限公司 The high-grade marmorean diamond segment of a kind of cutting
CN104088000A (en) * 2013-05-09 2014-10-08 吴红平 Diamond wire production method
CN104088000B (en) * 2013-05-09 2016-08-17 江阴市宝能特种钢线有限公司 The production method of diamond wire
CN104789931A (en) * 2015-04-29 2015-07-22 富耐克超硬材料股份有限公司 Titanizing process for superhard material micro powder
CN106894075B (en) * 2017-03-23 2018-08-10 南京三超新材料股份有限公司 Diamond surface magnetism coating and its coating method
CN106894075A (en) * 2017-03-23 2017-06-27 南京三超新材料股份有限公司 Diamond surface magnetic coating and its coating method
CN109267130A (en) * 2018-08-23 2019-01-25 信丰崇辉科技有限公司 The electroplating system and electro-plating method of diamond cutting secant
CN110079801A (en) * 2019-06-04 2019-08-02 泉州华大超硬工具科技有限公司 A kind of functionalization diamond of coating surface complex metal layer
CN112063874A (en) * 2020-09-21 2020-12-11 广东省科学院新材料研究所 Diamond composite material and preparation method and application thereof
CN112322938A (en) * 2020-09-21 2021-02-05 北京科技大学 Nickel-based composite material based on additive manufacturing, preparation method and forming method thereof
CN112322938B (en) * 2020-09-21 2022-05-27 北京科技大学 Nickel-based composite material based on additive manufacturing, preparation method and forming method thereof
CN117067419A (en) * 2023-10-16 2023-11-17 江苏三超金刚石工具有限公司 High-hardness diamond wire saw and processing technology thereof
CN117067419B (en) * 2023-10-16 2024-02-13 江苏三超金刚石工具有限公司 High-hardness diamond wire saw and processing technology thereof

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Effective date of registration: 20170703

Address after: 200126, two building, 1251 lane, 31 South Road, Shanghai, Pudong New Area

Patentee after: Shanghai Jiangxin Ultrahard Material Co., Ltd.

Address before: 200126, 3 building, 1251 lane, 31 South Road, Shanghai, Pudong New Area

Patentee before: Shanghai Fine Abrasives Grinding Tools Co.,Ltd.