CN109569609A - A kind of preparation method of novel nickel-base composite material - Google Patents
A kind of preparation method of novel nickel-base composite material Download PDFInfo
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- CN109569609A CN109569609A CN201811391969.0A CN201811391969A CN109569609A CN 109569609 A CN109569609 A CN 109569609A CN 201811391969 A CN201811391969 A CN 201811391969A CN 109569609 A CN109569609 A CN 109569609A
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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Abstract
The present invention provides a kind of preparation method of novel nickel-base composite material, method includes the following steps: mixed solution is made after (1) measures DMF, methanol and deionization mixing respectively；(2) nickel salt and 2,5-Dihydroxyterephthalic acid are taken respectively, is placed in mixed solution A, are ultrasonically treated, are obtained mixed solution B；(3) dry carbon cloth and solution B is taken to be transferred together in the stainless steel water heating kettle of teflon lined, then incubation water heating reaction is carried out, it is cooled to room temperature to reaction kettle, take out carbon cloth, air drying is stand-by, removes the upper solution in reaction kettle, centrifugation, again with methanol or ethyl alcohol repeatedly wash, and gained sample is dried in vacuo to obtain sample Ni-MOF-74；(4) carbon cloth for taking air drying stand-by, is placed in porcelain boat, and 350~1000 DEG C are calcined 1~5 hour, is cooled to room temperature, novel nickel-base composite material is made.
Description
Technical field
The present invention relates to a kind of preparation methods of composite material, and in particular to a kind of preparation side of novel nickel-base composite material
Method.
Background technique
In recent years, the environmental problem as caused by the rapid exhausted and greenhouse gas emission of fossil fuel, the whole world is to can
The demand of the renewable sources of energy is increasingly urgent to.Carbon material, especially carbon cellulose, nanofiber and Cellulose nanocrystal, exist in recent years
Emerging application field achieves major progress, is especially used widely in catalyst carrier field, the present invention is with carbon fiber
Cloth is carrier of the raw material as catalyst, can give full play to effect of the carbon fiber as catalyst carrier, conducive to point of catalyst
It dissipates, the more metallic sites of exposure.
Metal-organic framework material (Metal-Organic Frameworks, abbreviation MOFs) be it is a kind of by metal ion with
The novel porous mesh material that organic ligand is connected to form by coordination.It is to utilize organic ligand and metal ion or gold
Belong to cluster by having one-dimensional, two-dimentional or three-dimensional infinite network knot made of coordinate bond or intermolecular interaction self assembly
The crystalline material of structure.Metal ion in MOFs structure is coupled by organic ligand and high degree of dispersion is isolated, while these organic are matched
Body in thermal decomposition process height carbonization can barrier metal reunion, thus be hopeful be made high dispersive, partial size it is small and
Uniform metal or metal oxide nanoparticles, these nanoparticles can be used as active catalytic center.In addition, MOFs heat point
Solution prepares metal or metal oxide also has the advantage that, i.e. the porous carbon of the organic matter pyrolysis generation of ligand or filling,
Meeting portion envelops live metallic particles, to improve the stability of catalyst.
Porous carbon materials have chemical stability height, adsorption capacity strong, acidproof, and alkaline-resisting, heat resistance is strong and more regular
The advantages that gap structure, makes it be used widely in fields such as catalyst carrier, adsorbent and electrochemical energy storages.
The combination of MOFs material derived metallic catalyst and carbon cloth, metallic catalyst can be dispersed in carbon cloth
Surface is conducive to the more catalytic sites of metallic catalyst exposure, is more advantageous to the raising of the mass transfer effect of fluid, make its be forced with
Metallic catalyst derived from MOFs comes into full contact with and reacts.Therefore the novel nickel-base composite material Ni CFC that the present invention synthesizes
It is expected to the new catalyst as function admirable.
Summary of the invention
The present invention relates to a kind of preparation method of novel nickel-base composite material, it is through the following steps that carry out:
(1) after measuring DMF, methanol and deionization mixing respectively, mixed solution A is made, wherein DMF, methanol and deionization
The volume ratio of water is (0.5~50): 1:1；
(2) nickel salt and 2,5-Dihydroxyterephthalic acid are taken respectively, are placed in mixed solution A obtained by step (1), in ultrasound
Frequency is the condition of 50~100kHz, is ultrasonically treated 30~60 minutes, obtains mixed solution B；
(3) dry carbon cloth and step (2) acquired solution B is taken to be transferred together the stainless steel of teflon lined
In water heating kettle, incubation water heating reaction is then carried out, hydro-thermal reaction 3~72 hours under conditions of temperature is 100~200 DEG C, to
Reaction kettle is cooled to room temperature, and takes out carbon cloth, and air drying is stand-by, removes the upper solution in reaction kettle, centrifugation, then use first
Alcohol or ethyl alcohol repeatedly wash, and gained sample is dried in vacuo to obtain sample Ni-MOF-74；
(4) carbon cloth that air drying is stand-by in step (3) is taken, is placed in porcelain boat, 350~1000 DEG C of calcinings 1~5 are small
When, it is cooled to room temperature, novel nickel-base composite material is made.
Solution temperature in preferred step (2) the of the present invention ultrasonication is no more than 40 DEG C.
Preferably the molar ratio of step (2) the of the present invention nickel salt and 2,5-Dihydroxyterephthalic acid is 0.5~20:1,
Nickel salt is nickel acetate tetrahydrate or nickel chloride or Nickelous nitrate hexahydrate.
Preferred nickel salt of the present invention is nickel acetate tetrahydrate, nickel acetate tetrahydrate and 2,5-Dihydroxyterephthalic acid
Molar ratio be (1~10): 1.
Preferred nickel salt of the present invention is Nickelous nitrate hexahydrate, Nickelous nitrate hexahydrate and 2,5-Dihydroxyterephthalic acid
Molar ratio is (0.5~20): 1.
Preferred nickel salt of the present invention is nickel chloride, nickel chloride and 2,5-Dihydroxyterephthalic acid molar ratio be (1~
15):1。
Under conditions of supersonic frequency described in preferred step (2) of the present invention is 60kHz, it is ultrasonically treated 30 minutes.
Preferred step (4) of the present invention is in logical N2Under the conditions of carry out, until its temperature is cooled to room temperature.
The present invention include it is following the utility model has the advantages that
The present invention is auxiliary with hydrothermal synthesis method, so that the Ni-MOF-74 of synthesis is supported on the surface of carbon cloth, then is passed through
Carbonization is crossed, is made and loads a kind of novel Ni-based multiple of the derivative metallic catalyst of Ni-MOF-74 by catalyst carrier of carbon cloth
Condensation material Ni@CFC, and optimize technological reaction condition, significantly simplified synthesis technology and reduce experimental cost.
Detailed description of the invention
Fig. 1: for the XRD spectrum of Ni-MOF-74 made from embodiment 1；
Fig. 2: for the SEM shape appearance figure of Ni-MOF-74 made from embodiment 1；
Fig. 3: for the XRD spectrum of Ni@CFC made from embodiment 1；
Fig. 4: for the SEM shape appearance figure of Ni@CFC made from embodiment 1.
Specific embodiment
Embodiment 1: the preparation method of novel nickel-base composite material includes the following steps
(1) mixed solution A is made after measurement DMF (45mL), methanol (3mL) and deionized water (3mL) mixing respectively,
The volume ratio of middle DMF, methanol and deionized water are 15:1:1；
(2) 0.5514g Nickelous nitrate hexahydrate and 0.1125g 2,5-Dihydroxyterephthalic acid are weighed respectively, and one is placed in
In mixed solution A obtained by step 1, in the condition that supersonic frequency is 60kHz, it is ultrasonically treated 30 minutes, obtains mixed solution B；Its
The molar ratio of middle Nickelous nitrate hexahydrate and 2,5- dihydric para-phthalic acid are 3.34:1；
(3) carbon cloth (carbon fiber cloth (CFC)) and step 2 acquired solution B mono- for taking a fritter dry
With being transferred in the stainless steel water heating kettle of teflon lined, incubation water heating reaction is then carried out, the item for being 100 DEG C in temperature
Hydro-thermal reaction 24 hours, are cooled to room temperature to reaction kettle under part, take out carbon cloth, and air drying is stand-by；It is anti-with methanol replacement
The solvent in kettle is answered, it is primary every displacement in 10 hours, it replaces 4 times；Gained sample is dried in vacuo under conditions of temperature is 100 DEG C
8 hours, sample Ni-MOF-74 is made；
(4) carbon cloth obtained by step (3) is taken out, is placed in porcelain boat, in logical N2Under conditions of, 600 DEG C are calcined 3 hours,
Novel nickel-base composite material Ni CFC is made.
Embodiment 2: the preparation method of novel nickel-base composite material includes the following steps
(1) mixed solution A is made after measurement DMF (17mL), methanol (17mL) and deionized water (17mL) mixing respectively,
Wherein the volume ratio of DMF, methanol and deionized water is 1:1:1；
(2) 0.33g Nickelous nitrate hexahydrate and 0.1125g 2,5-Dihydroxyterephthalic acid are weighed respectively, and one is placed in step
In rapid gained mixed solution A, in the condition that supersonic frequency is 60kHz, it is ultrasonically treated 30 minutes, obtains mixed solution B；Wherein
The molar ratio of Nickelous nitrate hexahydrate and 2,5- dihydric para-phthalic acid are 2:1；
(3) carbon cloth (carbon fiber cloth (CFC)) and step 2 acquired solution B mono- for taking a fritter dry
With being transferred in the stainless steel water heating kettle of teflon lined, incubation water heating reaction is then carried out, the item for being 110 DEG C in temperature
Hydro-thermal reaction 24 hours, are cooled to room temperature to reaction kettle under part, take out carbon cloth, and air drying is stand-by；It is anti-with ethyl alcohol replacement
The solvent in kettle is answered, it is primary every displacement in 12 hours, it replaces 4 times；Gained sample is dried in vacuo under conditions of temperature is 80 DEG C
10 hours, sample Ni-MOF-74 is made；
(4) carbon cloth obtained by step (3) is taken out, is placed in porcelain boat, in logical N2Under conditions of, 550 DEG C are calcined 4 hours,
Novel nickel-base composite material Ni CFC is made.
Embodiment 3: the preparation method of novel nickel-base composite material includes the following steps
(1) mixed solution A is made after measurement DMF (45mL), methanol (5mL) and deionized water (5mL) mixing respectively,
The volume ratio of middle DMF, methanol and deionized water are 9:1:1；
(2) 0.66g Nickelous nitrate hexahydrate and 0.1125g 2,5-Dihydroxyterephthalic acid are weighed respectively, and one is placed in step
In rapid gained mixed solution A, in the condition that supersonic frequency is 100kHz, it is ultrasonically treated 20 minutes, obtains mixed solution B；Its
The molar ratio of middle Nickelous nitrate hexahydrate and 2,5- dihydric para-phthalic acid are 4:1；
(3) carbon cloth (carbon fiber cloth (CFC)) and step 2 acquired solution B mono- for taking a fritter dry
With being transferred in the stainless steel water heating kettle of teflon lined, incubation water heating reaction is then carried out, the item for being 130 DEG C in temperature
Hydro-thermal reaction 12 hours, are cooled to room temperature to reaction kettle under part, take out carbon cloth, and air drying is stand-by；It is anti-with methanol replacement
The solvent in kettle is answered, it is primary every displacement in 12 hours, it replaces 5 times；Gained sample is dried in vacuo under conditions of temperature is 60 DEG C
12 hours, sample Ni-MOF-74 is made；
(4) carbon cloth obtained by step (3) is taken out, is placed in porcelain boat, in logical N2Under conditions of, 700 DEG C are calcined 3 hours,
Novel nickel-base composite material Ni CFC is made.
Embodiment 4: the preparation method of novel nickel-base composite material includes the following steps
(1) mixed solution A is made after measurement DMF (45mL), methanol (9mL) and deionized water (9mL) mixing respectively,
The volume ratio of middle DMF, methanol and deionized water are 5:1:1；
(2) 0.8254g Nickelous nitrate hexahydrate and 0.1125g 2,5-Dihydroxyterephthalic acid are weighed respectively, and one is placed in
In mixed solution A obtained by step 1, in the condition that supersonic frequency is 100kHz, it is ultrasonically treated 20 minutes, obtains mixed solution B；
Wherein the molar ratio of Nickelous nitrate hexahydrate and 2,5- dihydric para-phthalic acid are 5:1；
(3) carbon cloth (carbon fiber cloth (CFC)) and step 2 acquired solution B mono- for taking a fritter dry
With being transferred in the stainless steel water heating kettle of teflon lined, incubation water heating reaction is then carried out, the item for being 150 DEG C in temperature
Hydro-thermal reaction 12 hours, are cooled to room temperature to reaction kettle under part, take out carbon cloth, and air drying is stand-by；It is anti-with methanol replacement
The solvent in kettle is answered, it is primary every displacement in 12 hours, it replaces 5 times；Gained sample is dried in vacuo under conditions of temperature is 110 DEG C
6 hours, sample Ni-MOF-74 is made；
(4) carbon cloth obtained by step (3) is taken out, is placed in porcelain boat, in logical N2Under conditions of, 800 DEG C are calcined 2 hours,
Novel nickel-base composite material Ni CFC is made.
Embodiment 5: the preparation method of novel nickel-base composite material includes the following steps
(1) mixed solution is made after measurement DMF (50mL), methanol (2.5mL) and deionized water (2.5mL) mixing respectively
A, wherein the volume ratio of DMF, methanol and deionized water is 20:1:1；
(2) 0.99g Nickelous nitrate hexahydrate and 0.1125g 2,5-Dihydroxyterephthalic acid are weighed respectively, and one is placed in step
In rapid gained mixed solution A, in the condition that supersonic frequency is 80kHz, it is ultrasonically treated 30 minutes, obtains mixed solution B；Wherein
The molar ratio of Nickelous nitrate hexahydrate and 2,5- dihydric para-phthalic acid are 6:1；
(3) carbon cloth (carbon fiber cloth (CFC)) and step 2 acquired solution B mono- for taking a fritter dry
With being transferred in the stainless steel water heating kettle of teflon lined, incubation water heating reaction is then carried out, the item for being 160 DEG C in temperature
Hydro-thermal reaction 18 hours, are cooled to room temperature to reaction kettle under part, take out carbon cloth, and air drying is stand-by；It is anti-with methanol replacement
The solvent in kettle is answered, it is primary every displacement in 12 hours, it replaces 4 times；Gained sample is dried in vacuo under conditions of temperature is 100 DEG C
10 hours, sample Ni-MOF-74 is made；
(4) carbon cloth obtained by step (3) is taken out, is placed in porcelain boat, in logical N2Under conditions of, 400 DEG C are calcined 5 hours,
Novel nickel-base composite material Ni CFC is made.
The content of present invention is not limited only to the content of the respective embodiments described above, the group of one of them or several specific embodiments
The purpose of invention also may be implemented in contract sample.
The XRD spectrum for obtaining Ni-MOF-74 material by embodiment 1 is as shown in Figure 1, it was demonstrated that resulting sample is pure phase
Ni-MOF-74 crystal.
Ni-MOF-74 material SEM appearance figure is obtained as shown in Fig. 2, as can be seen from the figure according to experiment by embodiment 1
The Ni-MOF-74 of method preparation is ellipticity crystal.
The XRD spectrum of novel nickel-base composite material Ni CFC is obtained by embodiment 1, Ni-MOF-74 is obviously had found by Fig. 3
After charing, metallic nickel is highlighted, more conducively the raising of catalytic activity.
The SEM appearance figure of novel nickel-base composite material Ni CFC is obtained by embodiment 1 as shown in figure 4, can be with from figure
Find out that the Ni@CFC material prepared according to embodiment one, metallic catalyst derived from Ni-MOF-74 are supported on carbon cloth
Surface, dispersibility preferably, show the success of novel nickel-base composite material Ni CFC preparation.
Claims (8)
1. a kind of preparation method of novel nickel-base composite material, which is characterized in that method includes the following steps:
(1) after measuring DMF, methanol and deionization mixing respectively, mixed solution A is made, wherein DMF, methanol and deionized water
Volume ratio is (0.5~50): 1:1；
(2) nickel salt and 2,5-Dihydroxyterephthalic acid are taken respectively, are placed in mixed solution A obtained by step (1), in supersonic frequency
For the condition of 50~100kHz, it is ultrasonically treated 30~60 minutes, obtains mixed solution B；
(3) dry carbon cloth and step (2) acquired solution B is taken to be transferred together the stainless steel hydro-thermal of teflon lined
In kettle, incubation water heating reaction is then carried out, hydro-thermal reaction 3~72 hours under conditions of temperature is 100~200 DEG C, wait react
Kettle is cooled to room temperature, take out carbon cloth, air drying is stand-by, remove reaction kettle in upper solution, centrifugation, again with methanol or
Ethyl alcohol repeatedly washs, and gained sample is dried in vacuo to obtain sample Ni-MOF-74；
(4) carbon cloth that air drying is stand-by in step (3) is taken, is placed in porcelain boat, 350~1000 DEG C are calcined 1~5 hour,
It is cooled to room temperature, novel nickel-base composite material is made.
2. preparation method according to claim 1, which is characterized in that the solution in step (2) described ultrasonication
Temperature is no more than 40 DEG C.
3. preparation method according to claim 1, which is characterized in that step (2) nickel salt and 2,5- dihydroxy is to benzene
The molar ratio of dioctyl phthalate is (0.5~20): 1, nickel salt is nickel acetate tetrahydrate or nickel chloride or Nickelous nitrate hexahydrate.
4. preparation method according to claim 3, which is characterized in that the nickel salt is nickel acetate tetrahydrate, four hydration second
The molar ratio of sour nickel and 2,5- dihydric para-phthalic acid are (1~10): 1.
5. preparation method according to claim 3, which is characterized in that the nickel salt is Nickelous nitrate hexahydrate, six hydration nitre
Sour nickel and 2,5- dihydric para-phthalic acid's molar ratio are (0.5~20): 1.
6. preparation method according to claim 3, which is characterized in that the nickel salt is nickel chloride, nickel chloride and 2,5- bis-
Hydroxyterephthalic acid's molar ratio is (1~15): 1.
7. preparation method according to claim 1, which is characterized in that supersonic frequency described in step (2) is the item of 60kHz
Under part, it is ultrasonically treated 30 minutes.
8. preparation method according to claim 1, which is characterized in that step (4) is in logical N2Under the conditions of carry out, Zhi Daoqi
Temperature is cooled to room temperature.
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| CN112893858A (en) * | 2019-11-19 | 2021-06-04 | 中国科学院大连化学物理研究所 | Preparation method of nickel-carbon-based material |
| CN113600153A (en) * | 2021-08-27 | 2021-11-05 | 西安理工大学 | Preparation method and application of nickel-based metal organic framework loaded phenolic resin material |
| CN113652715A (en) * | 2021-08-13 | 2021-11-16 | 中南林业科技大学 | Preparation method of self-supporting electrocatalytic hydrogen production material without adhesive |
| CN114367313A (en) * | 2022-01-18 | 2022-04-19 | 安徽大学 | Preparation method and application of catalytic material based on Ni-MOF |
| CN114430076A (en) * | 2022-01-25 | 2022-05-03 | 中国石油大学(华东) | Full MOF flexible nickel-iron battery and preparation method thereof |
| CN114558578A (en) * | 2022-03-08 | 2022-05-31 | 中国石油大学(华东) | Novel nickel-carbon catalytic material with radial center and preparation method and application thereof |
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| CN114430076A (en) * | 2022-01-25 | 2022-05-03 | 中国石油大学(华东) | Full MOF flexible nickel-iron battery and preparation method thereof |
| CN114430076B (en) * | 2022-01-25 | 2024-05-28 | 中国石油大学(华东) | Full MOF flexible nickel-iron battery and preparation method thereof |
| CN114558578A (en) * | 2022-03-08 | 2022-05-31 | 中国石油大学(华东) | Novel nickel-carbon catalytic material with radial center and preparation method and application thereof |
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Application publication date: 20190405 |