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CN108623883A - A kind of refractory polyethylene track CABLE MATERIALS and preparation method thereof - Google Patents

A kind of refractory polyethylene track CABLE MATERIALS and preparation method thereof Download PDF

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Publication number
CN108623883A
CN108623883A CN201810469816.7A CN201810469816A CN108623883A CN 108623883 A CN108623883 A CN 108623883A CN 201810469816 A CN201810469816 A CN 201810469816A CN 108623883 A CN108623883 A CN 108623883A
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Prior art keywords
parts
track cable
cable materials
polyethylene
density polyethylene
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CN201810469816.7A
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Chinese (zh)
Inventor
夏江平
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Magnificent Macromolecular Material Science And Technology Ltd In Anhui
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Magnificent Macromolecular Material Science And Technology Ltd In Anhui
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Priority to CN201810469816.7A priority Critical patent/CN108623883A/en
Publication of CN108623883A publication Critical patent/CN108623883A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2231Oxides; Hydroxides of metals of tin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of refractory polyethylene track CABLE MATERIALSs and preparation method thereof.One of which refractory polyethylene track CABLE MATERIALS, raw material are formed by following parts by weight:30~50 parts of high density polyethylene (HDPE), 20~30 parts of fire-retardant fireproof quartz fibre filler, 30~40 parts of low density polyethylene (LDPE), 8~10 parts of tin oxide, 8~10 parts of alumina silicate, 5~7 parts of coupling agent, 0.5~1.5 part of silane crosslinker, 1~2 part of heat stabilizer, 1~3 part of antioxidant, 3~5 parts of plasticizer, 4~6 parts of lubricant.The present invention significantly improves the high temperature resistance of polyethylene, and remains preferable processability, which is used for cable, can dramatically increase the high temperature resistance of cable.

Description

A kind of refractory polyethylene track CABLE MATERIALS and preparation method thereof
Technical field
The invention belongs to track field of cables, are specifically related to a kind of refractory polyethylene track CABLE MATERIALS and its preparation side Method.
Background technology
Cable is to be fabricated to conductor thread core by twisted with one or more conducting wire, then corresponding insulation is imposed on conductor Layer, outside are wrapped sealing sheath and the conducting wire that is formed, are mainly made of core, insulating layer, shielded layer and restrictive coating.Cable has It occupies ground and space is few;Power supply safety is reliable, and electric shock possibility is small;Be conducive to improve the power factor of electric system;Operation, Maintenance work is simple and convenient;Be conducive to beautifying city, there is many advantages, such as confidentiality, is widely used in living and producing Every field.The effect of the coat layer of power cable is intrusion of the seal protection cable from introduced contaminants and moisture, prevents external force straight Connect damage cable insulation.Cable cover(ing) layer material not only requires good airproof performance, anti-corrosive properties height, high mechanical strength, good flame resistance, Should also have certain high temperature resistance.
Polyethylene is a kind of aggregated thermoplastic resin obtained of ethylene, because it has odorless, nontoxic, lower temperature resistance Many advantages, such as energy is good, and chemical stability is good, and good corrosion resistance, water imbibition is small, and electrical insulating property is excellent, impact resistance is good, makes to gather Ethylene becomes one of maximum cable material of usage amount, and existing cable cover(ing) layer material is mostly polythene material.With cable The application environment of application in more areas, cable also becomes increasingly complex, thus, the requirement to the properties of cable is also got over Come higher, the cable performance being prepared with single polythene material has been unable to meet the requirement of cable performance, uses cable Polythene material, which is modified, to necessitate.
High temperature resistance is one of the property that cable needs to have, and is continuously increased with the range of cable application, electricity Cable is also applied in more hot environments, thus, it is also higher and higher to the high temperature resistance requirement of cable, cable is used poly- The high temperature resistance of vinyl material requires also higher and higher.A variety of methods are also used in the prior art to improve polythene material Heat-resisting quantity, such as:Add inorganic filler and crosslinked method carried out to polyethylene, but due to the specific aim of raw material selection compared with Difference or the influence for polyethylene polymerization degree control etc. factor, obtained modified polyethylene material high temperature resistance is not There is the requirement for reaching anticipation or processability is good but heat-resisting quantity difference or the good processability of heat-resisting quantity are deteriorated, to serious Affect the production and application of cable.
Invention content
The present invention provides a kind of refractory polyethylene track CABLE MATERIALSs and preparation method thereof, are asked with solving above-mentioned technology Topic.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is:
A kind of refractory polyethylene track CABLE MATERIALS, is made of by weight following raw material:High density polyethylene (HDPE) 30~50 Part, 20~30 parts of fire-retardant fireproof quartz fibre filler, 30~40 parts of low density polyethylene (LDPE), 8~10 parts of tin oxide, alumina silicate 8~ 10 parts, 5~7 parts of coupling agent, 0.5~1.5 part of silane crosslinker, 1~2 part of heat stabilizer, 1~3 part of antioxidant, plasticizer 3 ~5 parts, 4~6 parts of lubricant.
Preferably, a kind of refractory polyethylene track CABLE MATERIALS, is made of by weight following raw material:High density polyethylene (HDPE) 30 parts, 20 parts of fire-retardant fireproof quartz fibre filler, 30 parts of low density polyethylene (LDPE), 8 parts of tin oxide, 8 parts of alumina silicate, coupling agent 5 Part, 0.5 part of silane crosslinker, 1 part of heat stabilizer, 1 part of antioxidant, 3 parts of plasticizer, 4 parts of lubricant.
Preferably, a kind of refractory polyethylene track CABLE MATERIALS, is made of by weight following raw material:High density polyethylene (HDPE) 40 parts, 25 parts of fire-retardant fireproof quartz fibre filler, 35 parts of low density polyethylene (LDPE), 9 parts of tin oxide, 9 parts of alumina silicate, 6 parts of coupling agent, 1 part of silane crosslinker, 1.5 parts of heat stabilizer, 2 parts of antioxidant, 4 parts of plasticizer, 5 parts of lubricant.
Preferably, a kind of refractory polyethylene track CABLE MATERIALS, is made of by weight following raw material:High density polyethylene (HDPE) 50 parts, 30 parts of fire-retardant fireproof quartz fibre filler, 40 parts of low density polyethylene (LDPE), 10 parts of tin oxide, 10 parts of alumina silicate, coupling agent 7 Part, 1.5 parts of silane crosslinker, 2 parts of heat stabilizer, 3 parts of antioxidant, 5 parts of plasticizer, 6 parts of lubricant.
Preferably, the lubricant is microcrystalline wax.
Preferably, the plasticizer phthalic acid two (2- ethyl hexyls) ester.
Preferably, the antioxidant chooses hindered phenol antioxidant.
A kind of preparation method of refractory polyethylene track CABLE MATERIALS, which is characterized in that include the following steps:
(1) fire-retardant fireproof quartz fibre filler is handled with coupling agent;
It (2) will treated that fire-retardant fireproof quartz fibre filler weighs each raw material component with other parts by weights uniformly mixes It closes;
(3) raw material of gained in step (2) is handled by kneader kneading;
(4) the raw material input double screw extruder of gained in step (3) is subjected to extruding pelletization;
(5) granulation of gained in step (4) is water cooled, air-dried, screening magnetic separation, metering, packaging are to get required resistance to height Warm polyethylene track CABLE MATERIALS.
Beneficial effects of the present invention:
A kind of refractory polyethylene track CABLE MATERIALS of present invention offer and preparation method thereof, significantly improves polyethylene High temperature resistance, and preferable processability is remained, which is used for cable, the high temperature resistant of cable can be dramatically increased Performance.
Specific implementation mode
The embodiment of the present invention is described in detail below, but what the present invention can be defined by the claims and cover Multitude of different ways is implemented.
Embodiment 1
A kind of refractory polyethylene track CABLE MATERIALS, is made of by weight following raw material:
30 parts of high density polyethylene (HDPE), 20 parts of fire-retardant fireproof quartz fibre filler, 30 parts of low density polyethylene (LDPE), 8 parts of tin oxide, 8 parts of alumina silicate, 5 parts of coupling agent, 0.5 part of silane crosslinker, 1 part of heat stabilizer, 1 part of antioxidant, 3 parts of plasticizer, lubricant 4 Part.
Above-mentioned lubricant is microcrystalline wax.
Above-mentioned plasticizer phthalic acid two (2- ethyl hexyls) ester.
Above-mentioned antioxidant chooses hindered phenol antioxidant.
A kind of preparation method of refractory polyethylene track CABLE MATERIALS, includes the following steps:
(1) fire-retardant fireproof quartz fibre filler is handled with coupling agent;
It (2) will treated that fire-retardant fireproof quartz fibre filler weighs each raw material component with other parts by weights uniformly mixes It closes;
(3) raw material of gained in step (2) is handled by kneader kneading;
(4) the raw material input double screw extruder of gained in step (3) is subjected to extruding pelletization;
(5) granulation of gained in step (4) is water cooled, air-dried, screening magnetic separation, metering, packaging are to get required resistance to height Warm polyethylene track CABLE MATERIALS.
Following embodiment is differed only in embodiment 1:
Embodiment 2
A kind of refractory polyethylene track CABLE MATERIALS, is made of by weight following raw material:
40 parts of high density polyethylene (HDPE), 25 parts of fire-retardant fireproof quartz fibre filler, 35 parts of low density polyethylene (LDPE), 9 parts of tin oxide, 9 parts of alumina silicate, 6 parts of coupling agent, 1 part of silane crosslinker, 1.5 parts of heat stabilizer, 2 parts of antioxidant, 4 parts of plasticizer, lubricant 5 Part.
Embodiment 3
A kind of refractory polyethylene track CABLE MATERIALS, is made of by weight following raw material:
50 parts of high density polyethylene (HDPE), 30 parts of fire-retardant fireproof quartz fibre filler, 40 parts of low density polyethylene (LDPE), tin oxide 10 Part, 10 parts of alumina silicate, 7 parts of coupling agent, 1.5 parts of silane crosslinker, 2 parts of heat stabilizer, 3 parts of antioxidant, 5 parts of plasticizer, profit 6 parts of lubrication prescription.
The embodiments of the present invention described above are not intended to limit the scope of the present invention, any in the present invention Spirit and principle within made by modifications, equivalent substitutions and improvements etc., should be included in the claim protection model of the present invention Within enclosing.

Claims (8)

1. a kind of refractory polyethylene track CABLE MATERIALS, which is characterized in that be made of by weight following raw material:High-density polyethylene 30~50 parts of alkene, 20~30 parts of fire-retardant fireproof quartz fibre filler, 30~40 parts of low density polyethylene (LDPE), 8~10 parts of tin oxide, silicon 8~10 parts of sour aluminium, 5~7 parts of coupling agent, 0.5~1.5 part of silane crosslinker, 1~2 part of heat stabilizer, 1~3 part of antioxidant, 3~5 parts of plasticizer, 4~6 parts of lubricant.
2. refractory polyethylene track CABLE MATERIALS according to claim 1, which is characterized in that by weight by following raw material Composition:30 parts of high density polyethylene (HDPE), 20 parts of fire-retardant fireproof quartz fibre filler, 30 parts of low density polyethylene (LDPE), 8 parts of tin oxide, silicon 8 parts of sour aluminium, 5 parts of coupling agent, 0.5 part of silane crosslinker, 1 part of heat stabilizer, 1 part of antioxidant, 3 parts of plasticizer, lubricant 4 Part.
3. refractory polyethylene track CABLE MATERIALS according to claim 1, which is characterized in that by weight by following raw material Composition:40 parts of high density polyethylene (HDPE), 25 parts of fire-retardant fireproof quartz fibre filler, 35 parts of low density polyethylene (LDPE), 9 parts of tin oxide, silicon 9 parts of sour aluminium, 6 parts of coupling agent, 1 part of silane crosslinker, 1.5 parts of heat stabilizer, 2 parts of antioxidant, 4 parts of plasticizer, lubricant 5 Part.
4. refractory polyethylene track CABLE MATERIALS according to claim 1, which is characterized in that by weight by following raw material Composition:50 parts of high density polyethylene (HDPE), 30 parts of fire-retardant fireproof quartz fibre filler, 40 parts of low density polyethylene (LDPE), 10 parts of tin oxide, silicon 10 parts of sour aluminium, 7 parts of coupling agent, 1.5 parts of silane crosslinker, 2 parts of heat stabilizer, 3 parts of antioxidant, 5 parts of plasticizer, lubricant 6 Part.
5. refractory polyethylene track CABLE MATERIALS according to claim 1, which is characterized in that the lubricant is microlite Wax.
6. refractory polyethylene track CABLE MATERIALS according to claim 1, which is characterized in that the plasticizer is adjacent benzene two Formic acid two (2- ethyl hexyls) ester.
7. refractory polyethylene track CABLE MATERIALS according to claim 1, which is characterized in that the antioxidant choose by Hinder phenolic antioxidant.
8. the preparation method of the refractory polyethylene track CABLE MATERIALS as described in claim 1-4 any one, which is characterized in that Include the following steps:
(1) fire-retardant fireproof quartz fibre filler is handled with coupling agent;
It (2) will treated that fire-retardant fireproof quartz fibre filler weighs each raw material component with other parts by weights uniformly mixes;
(3) raw material of gained in step (2) is handled by kneader kneading;
(4) the raw material input double screw extruder of gained in step (3) is subjected to extruding pelletization;
(5) granulation of gained in step (4) is water cooled, air-dried, screening magnetic separation, metering, packaging are poly- to get required high temperature resistant Ethylene track CABLE MATERIALS.
CN201810469816.7A 2018-05-16 2018-05-16 A kind of refractory polyethylene track CABLE MATERIALS and preparation method thereof Pending CN108623883A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111635583A (en) * 2020-06-03 2020-09-08 中广核三角洲(太仓)检测技术有限公司 High-temperature-resistant environment-friendly polyethylene cable material and preparation method thereof
CN112992412A (en) * 2021-03-16 2021-06-18 杭州川口特种电线电缆有限公司 Special cable for flexible wear-resistant oil-resistant ink-jet printer

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111635583A (en) * 2020-06-03 2020-09-08 中广核三角洲(太仓)检测技术有限公司 High-temperature-resistant environment-friendly polyethylene cable material and preparation method thereof
CN112992412A (en) * 2021-03-16 2021-06-18 杭州川口特种电线电缆有限公司 Special cable for flexible wear-resistant oil-resistant ink-jet printer
CN112992412B (en) * 2021-03-16 2023-02-17 杭州川口特种电线电缆有限公司 Special cable for flexible wear-resistant oil-resistant ink-jet printer

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