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CN108051944A - A kind of method and colored filter of the colored filter for preparing low segment difference - Google Patents

A kind of method and colored filter of the colored filter for preparing low segment difference Download PDF

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Publication number
CN108051944A
CN108051944A CN201711482264.5A CN201711482264A CN108051944A CN 108051944 A CN108051944 A CN 108051944A CN 201711482264 A CN201711482264 A CN 201711482264A CN 108051944 A CN108051944 A CN 108051944A
Authority
CN
China
Prior art keywords
barricade
colored filter
ink layer
black matrix
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711482264.5A
Other languages
Chinese (zh)
Inventor
唐敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TCL China Star Optoelectronics Technology Co Ltd
Original Assignee
Shenzhen China Star Optoelectronics Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen China Star Optoelectronics Technology Co Ltd filed Critical Shenzhen China Star Optoelectronics Technology Co Ltd
Priority to CN201711482264.5A priority Critical patent/CN108051944A/en
Publication of CN108051944A publication Critical patent/CN108051944A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133516Methods for their manufacture, e.g. printing, electro-deposition or photolithography
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133512Light shielding layers, e.g. black matrix

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Optical Filters (AREA)

Abstract

The colored filter for providing a kind of method of colored filter for preparing low segment difference and being obtained by this method.It the described method comprises the following steps:Black matrix" separated from one another is formed on substrate;On black matrix" coat barricade material and perform it is exposed and developed, to form barricade, wherein, barricade material be residual film ratio be less than 50% material;Ink is sprayed in the gap of black matrix", so as to form ink layer by inkjet printing;High temperature process is performed to the substrate for being formed with ink layer, to remove the solvent in ink layer and cure ink layer, and barricade is made to carry out the gentle film contracting of hot-fluid, so as to form colored filter on substrate.

Description

A kind of method and colored filter of the colored filter for preparing low segment difference
Technical field
The present invention relates to a kind of colored filters of low segment difference, and in particular, to a kind of colorized optical filtering for preparing low segment difference The method of piece and the colored filter obtained by this method.
Background technology
In recent years, inkjet printing technology is used to make colored filter.In general, it prevents from making using barricade The ink colour mixture problem of the colors such as red, green and blue in journey.In red, green and blue ink, solvent composition account for the 60wt% of ink~ 80wt%, therefore the thickness for curing cephacoria (red, green and blue film) is about 5 μm~6 μm, and with solvent volatilization when curing, it is remaining The thickness of film (the red, green and blue film after curing) is about 1.0 μm~2.0 μm.Ink colour mixture during inkjet printing is asked in order to prevent Topic, the height of barricade is usually arranged as 4 μm~6 μm, thus the segment difference between the RGB film and barricade after curing for 3.5 μm~ 4.5μm。
The content of the invention
The present invention provides it is a kind of using inkjet printing technology make with low segment difference colored filter method, effectively Solve the problems, such as that above-mentioned segment difference is higher.
The exemplary embodiment of the present invention provides a kind of methods for the colored filter for preparing low segment difference, and the method can To comprise the following steps:Black matrix" separated from one another is formed on substrate;Barricade material is coated on black matrix" and is held Row is exposed and developed, to form barricade, wherein, barricade material is the material that residual film ratio is less than 50%;In the gap of black matrix" Middle spraying ink, so as to form ink layer by inkjet printing;High temperature process is performed to the substrate for being formed with ink layer, with removal Solvent in ink layer simultaneously cures ink layer, and barricade is made to carry out the gentle film contracting of hot-fluid, colored so as to be formed on substrate Optical filter.
Exemplary embodiment according to the present invention, the glass transition temperature of barricade material can 150 DEG C~200 DEG C it Between.
Exemplary embodiment according to the present invention performs after developing on black matrix" and is performing inkjet printing Before step, hard baking processing is not carried out to barricade.
Exemplary embodiment according to the present invention, can be by toasting 20 minutes~30 points of substrate at 200 DEG C~230 DEG C Clock performs the high temperature process.
Exemplary embodiment according to the present invention, the thickness of barricade is 4 μm~5 μm before high temperature process, the thickness of barricade Degree is 2.0 μm~2.5 μm after high temperature process, and the thickness of ink layer is 1 μm~2 μm after high temperature process.
Exemplary embodiment according to the present invention, the thickness of black matrix" is about 0.5 μm~1.5 μm.
Exemplary embodiment according to the present invention, the segment difference of the colored filter is 1.5 μm~2.0 μm.
Exemplary embodiment according to the present invention, the method further include:After high temperature process is performed, the shape on substrate Into covering barricade and the upper coating of ink layer.
Exemplary embodiment according to the present invention, the thickness of the upper coating are 2.0 μm~2.5 μm, segment difference for 0.2 μm~ 0.3μm。
The exemplary embodiment of the present invention provides a kind of colored filter of low segment difference, the segment differences of the colored filter It can be 1.5 μm~2.0 μm.
The exemplary embodiment of the present invention provides a kind of colored filter of low segment difference, the segment differences of the colored filter It can be 0.2 μm~0.3 μm.
Description of the drawings
Fig. 1 to Fig. 4 is cuing open for each step for the method that exemplary embodiment according to the present invention prepares colored filter View.
Fig. 5 shows the sectional view of colored filter in accordance with an alternative illustrative embodiment of the present invention.
Fig. 6 is the sectional view of the colored filter prepared according to the prior art.
Specific embodiment
The present invention can be changed changeably and can have various embodiments, be will be illustrated in the drawings and retouched in detail State the specific example of the present invention.It will be understood, however, that without departing from the scope and spirit of the present invention, the present invention Specifically disclosed form is not limited to, but including all modifications, equivalent and replacement.
The embodiment of the present invention is reference will now be made in detail to now, the example of the embodiment is shown in the drawings, wherein, it is identical Label refers to identical component always.It will illustrate the embodiment by referring to accompanying drawing below, to explain the present invention.
Fig. 1 to Fig. 4 is cuing open for each step for the method that exemplary embodiment according to the present invention prepares colored filter View.
With reference to Fig. 1, the black matrix" 110 separated at a predetermined interval is formed on the substrate 100.Such as photoetching may be employed Black matrix" 110 is formed etc. any suitable method.Exemplary embodiment according to the present invention, the thickness of black matrix" 110 It it is about 0.5 μm~1.5 μm, for example, can be preferably 1 μm.Substrate 100 can be glass substrate, quartz base plate or transparent tree Aliphatic radical plate etc., the material of black matrix" 110 can be lighttight photoresist, for example, lighttight resin etc..However, this Invent it is without being limited thereto, those skilled in the art can select under the teachings of the present invention suitable material be used as substrate and black square Battle array.
With reference to Fig. 2, barricade (or being " block piece ") 120 is formed on black matrix" 110.It is according to the present invention exemplary Barricade material can be coated on black matrix" 110, however development is exposed to it by embodiment first, so as in black The barricade 120 of predetermined thickness is formed on matrix 110.As shown in Fig. 2, the barricade 120 formed has predetermined thickness (that is, barricade 120 height) t1, exemplary embodiment according to the present invention, the thickness t1 of barricade 120 can in the range of 4 μm~6 μm, Preferably at 4 μm~5 μm.
Exemplary embodiment according to the present invention, barricade material are that residual film ratio (film thickness before film thickness ÷ cures after curing) is less than 50% material, also, the glass transition temperature (Tg) of barricade material is between 150 DEG C~200 DEG C, when temperature is higher than Tg When, the mobility of barricade material is preferable.Barricade material can be any suitable material for meeting above-mentioned condition.
With reference to Fig. 3, after development is carried out to barricade material and forms barricade 120, sprayed in the gap of black matrix" 110 Ink (for example, conventional red, green and blue ink), to carry out inkjet printing, so as to be formed on the substrate 100 through barricade 120 The ink layer 130 separated.It is worth noting that, in this step, barricade material is carried out development formed barricade 120 it Afterwards, the step of hard baking not being performed to barricade 120 and directly performing inkjet printing so that 120 He of barricade in subsequent high temperature processing procedure Ink layer 130 cures simultaneously.Exemplary embodiment according to the present invention, the ink that execution inkjet printing is sprayed can be according to reality It needs to make choice, however it is not limited to red, green and blue ink.
In figure 3, for clarity of illustration, an ink layer being located between two adjacent barricades is illustrated only 130, exemplary embodiment according to the present invention forms multiple ink layers between adjacent black matrix" 110 and barricade 120 (referring for example to shown in Fig. 5).The thickness t2 of the ink layer of inkjet printing is about 5 μm~6 μm, i.e., with the thickness of barricade and black square The sum of the thickness of battle array approximately equal, but it is slightly less than the sum of the thickness of barricade and the thickness of black matrix".
With reference to Fig. 4, after inkjet printing completion, high temperature process is carried out to substrate 100.Specifically, 200 DEG C~230 The substrate 100 for being formed with barricade 120 and ink layer 130 is toasted 20 minutes~30 minutes at a temperature of DEG C, makes barricade 120 and oil The heat cure together of layer of ink 130.Exemplary embodiment according to the present invention, high temperature process can remove the solvent in ink layer and make It cures, and can make the gentle film contracting of 120 hot-fluid of barricade, i.e. makes barricade material solidification.Since the temperature of high temperature process is higher than The glass transition temperature of barricade material, so the molecule segment motility of barricade material is preferable in high temperature process, barricade material Material can the steady mulch contracting under levelling effect.Therefore, after high temperature process, the thickness t22 of the ink layer 130 after curing is 1 μm~2 μm, for example, it is preferred at 1.5 μm or so.The thickness t11 of barricade 120 after curing is 2.0 μm~2.5 μm, so that The segment difference t3 obtained between finally formed ink layer 130 and barricade 120 can be contracted to 1.5 μm~2.0 μm.
Therefore, exemplary embodiment according to the present invention, by the way that material of the residual film ratio less than 50% is selected to be used as barricade, together When do not perform after the display baking and innovated in technological process so that pass through inkjet printing technology formed colored filter Segment difference be obviously reduced.
Fig. 5 shows colored filter in accordance with an alternative illustrative embodiment of the present invention.As shown in figure 5, in order into one Step reduces segment difference, can be with the upper coating 140 of formation on the substrate 100 shown in Fig. 4 for being formed with colored filter.According to this hair Bright exemplary embodiment, upper coating 140 can have 2.0 μm~2.5 μm of thickness and barricade 120 and oil are completely covered Layer of ink 130.Therefore, the segment difference of gained colored filter can be contracted to 0.2 μm~0.3 μm.Since upper coating 140 uses levelling Property good material, it is possible to segment difference is filled and led up in coating procedure, i.e. upper coating may be used as a kind of planarization layer.Upper painting The material of layer 140 can be any suitable transparent resin.Can upper coating 140 be formed by coating and hard baking, it can also Upper coating is formed by other suitable modes, the invention is not limited thereto.
Fig. 6 is the sectional view of the colored filter prepared according to the prior art.It is as shown in fig. 6, made according to the prior art The segment difference t3 ' of standby colored filter is 3.5 μm~4.5 μm, it will influences the display quality of device.This is because according to existing Technology prepare the method for colored filter caused by, according to prior art preparation method using general barricade material black Barricade is formed in colour moment battle array and hard baking is carried out to barricade, the thickness of barricade is made to be fixed as 4 μm~5 μm, subsequent ink-jet printing ink Layer of ink (for example, red, green and blue ink of spraying routine) simultaneously makes its heat cure, and the thickness of the ink layer after heat cure is 1.0 μm ~2.0 μm, so as to 3.5 μm~4.5 μm of segment difference occur.Also, even if the coating in the coating of this colorized optical filtering on piece, also can Cause lateral light leak since the thickness of upper coating is too big, and increase the cost of manufacture of colored filter.
However, according to above-mentioned example embodiment and description it is known that the system of exemplary embodiment according to the present invention The method of standby colored filter is less than 50% barricade material using residual film ratio, and ink-jet printing ink layer of ink simultaneously makes barricade and ink layer Heat cure is carried out together, so as to obtain the colored filter of low segment difference (referring to figs. 1 to Fig. 4), is efficiently solved existing The problems such as segment difference in technology is higher.In addition, as shown in figure 5, there is upper painting when prepared by exemplary embodiment according to the present invention During the colored filter of layer, the segment difference of gained colored filter is only 0.2 μm~0.3 μm, is efficiently solved in the prior art Segment difference it is higher the problem of and eliminate light leak.
The present invention selects the material of low residual film ratio to do barricade, and makes the heat cure together of barricade and ink layer, in technique It is innovated in flow, successfully solves the higher problem of printing inkjet color optical filter segment difference.Colour according to the present invention Optical filter can be applied to liquid crystal display or organic light emitting display etc..

Claims (10)

  1. A kind of 1. method for the colored filter for preparing low segment difference, which is characterized in that the described method comprises the following steps:
    Black matrix" separated from one another is formed on substrate;
    On black matrix" coat barricade material and perform it is exposed and developed, to form barricade, wherein, barricade material is residual film ratio Material less than 50%;
    Ink is sprayed in the gap of black matrix", so as to form ink layer by inkjet printing;
    High temperature process is performed to the substrate for being formed with ink layer, to remove the solvent in ink layer and cure ink layer, and Barricade is made to carry out the gentle film contracting of hot-fluid, so as to form colored filter on substrate.
  2. 2. according to the method described in claim 1, it is characterized in that, the glass transition temperature of barricade material is 150 DEG C~200 Between DEG C.
  3. 3. according to the method described in claim 1, it is characterized in that, on black matrix" perform development the step of after and Before the step of performing inkjet printing, hard baking processing is not carried out to barricade.
  4. 4. according to the method described in claim 1, it is characterized in that, by toasted at 200 DEG C~230 DEG C substrate 20 minutes~ Perform the high temperature process within 30 minutes.
  5. 5. according to the method described in claim 1, it is characterized in that, the thickness of barricade before high temperature process for 4 μm~5 μm, The thickness of barricade is 2.0 μm~2.5 μm after high temperature process, and the thickness of ink layer is 1 μm~2 μm after high temperature process.
  6. 6. according to the method described in claim 1, it is characterized in that, the thickness of black matrix" is 0.5 μm~1.5 μm.
  7. 7. according to the method described in claim 1, it is characterized in that, the segment difference of the colored filter is 1.5 μm~2.0 μm.
  8. 8. according to the method described in claim 1, it is characterized in that, the method further includes:After high temperature process is performed, The upper coating of covering barricade and ink layer is formed on substrate.
  9. 9. according to the method described in claim 8, it is characterized in that, the thickness of the upper coating be 2.0 μm~2.5 μm, segment difference For 0.2 μm~0.3 μm.
  10. 10. a kind of colored filter prepared by method according to claim 1 or 8.
CN201711482264.5A 2017-12-29 2017-12-29 A kind of method and colored filter of the colored filter for preparing low segment difference Pending CN108051944A (en)

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Application Number Priority Date Filing Date Title
CN201711482264.5A CN108051944A (en) 2017-12-29 2017-12-29 A kind of method and colored filter of the colored filter for preparing low segment difference

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711482264.5A CN108051944A (en) 2017-12-29 2017-12-29 A kind of method and colored filter of the colored filter for preparing low segment difference

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Publication Number Publication Date
CN108051944A true CN108051944A (en) 2018-05-18

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1877449A (en) * 2005-06-10 2006-12-13 东进世美肯株式会社 Negative light-sensitive resin composition
CN1880982A (en) * 2005-06-17 2006-12-20 鸿富锦精密工业(深圳)有限公司 Color filter and preparation method thereof
CN101008733A (en) * 2007-01-18 2007-08-01 友达光电股份有限公司 Color filter and manufacture method therefor
KR20090010158A (en) * 2006-05-18 2009-01-29 미쓰비시 가가꾸 가부시키가이샤 Curable composition, hardened | cured material, a color filter, and a liquid crystal display device
CN101681103A (en) * 2007-06-27 2010-03-24 三菱化学株式会社 Photosensitive composition, method, cured product and liquid crystal display device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1877449A (en) * 2005-06-10 2006-12-13 东进世美肯株式会社 Negative light-sensitive resin composition
CN1880982A (en) * 2005-06-17 2006-12-20 鸿富锦精密工业(深圳)有限公司 Color filter and preparation method thereof
KR20090010158A (en) * 2006-05-18 2009-01-29 미쓰비시 가가꾸 가부시키가이샤 Curable composition, hardened | cured material, a color filter, and a liquid crystal display device
CN101008733A (en) * 2007-01-18 2007-08-01 友达光电股份有限公司 Color filter and manufacture method therefor
CN101681103A (en) * 2007-06-27 2010-03-24 三菱化学株式会社 Photosensitive composition, method, cured product and liquid crystal display device

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Application publication date: 20180518