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CN107488784A - A kind of blast furnace ironmaking superfluxed pellets and its production method - Google Patents

A kind of blast furnace ironmaking superfluxed pellets and its production method Download PDF

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CN107488784A
CN107488784A CN201710794596.0A CN201710794596A CN107488784A CN 107488784 A CN107488784 A CN 107488784A CN 201710794596 A CN201710794596 A CN 201710794596A CN 107488784 A CN107488784 A CN 107488784A
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CN107488784B (en
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杨佳龙
杨建�
郭其飞
李家新
佘文文
杨乐彪
汪志鹏
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Anhui University of Technology AHUT
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/2406Binding; Briquetting ; Granulating pelletizing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/02Roasting processes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/242Binding; Briquetting ; Granulating with binders
    • C22B1/243Binding; Briquetting ; Granulating with binders inorganic

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Abstract

本发明公开了一种高炉炼铁用高碱度球团矿及其生产方法,属于钢铁冶金技术领域。本发明的一种高炉炼铁用高碱度球团矿,该球团矿是以精矿粉、精炼渣和膨润土为原料制成的,且各组分的质量百分比分别为:精矿粉60‑76%、精炼渣22‑38%、膨润土1.5‑2.5%;本发明的高碱度球团矿的生产方法,其步骤为:原料配加、生球形成、生球预热、生球焙烧、球团冷却。本发明以精矿粉和精炼渣为原料,生产出的合格球团碱度高达2.0以上,能够完全替代高碱度烧结矿作为主要入炉原料,且实现了废渣的内部消耗,解决了废弃物的堆放和污染问题,在降低球团生产和废渣处理成本的同时降低了能源消耗和污染排放,且生产出的球团抗压强度大、S含量低、冶金性能优良。

The invention discloses a high-alkalinity pellet for blast furnace ironmaking and a production method thereof, belonging to the technical field of iron and steel metallurgy. A high-alkalinity pellet for blast furnace ironmaking according to the present invention, the pellet is made of concentrate powder, refining slag and bentonite as raw materials, and the mass percentages of each component are respectively: concentrate powder 60 ‑76%, refining slag 22‑38%, bentonite 1.5‑2.5%; the production method of high alkalinity pellets of the present invention, the steps are: raw material addition, green pellet formation, green pellet preheating, green pellet roasting , Pellet cooling. The invention uses fine ore powder and refining slag as raw materials to produce qualified pellets with an alkalinity of over 2.0, which can completely replace high-basicity sintered ore as the main raw material for furnace feeding, and realizes the internal consumption of waste slag, which solves the problem of waste It reduces the cost of pellet production and waste slag treatment while reducing energy consumption and pollution emissions, and the produced pellets have high compressive strength, low S content, and excellent metallurgical properties.

Description

一种高炉炼铁用高碱度球团矿及其生产方法High-alkalinity pellets for blast furnace ironmaking and production method thereof

技术领域technical field

本发明属于钢铁冶金技术领域,更具体地说,涉及一种利用精矿粉和精炼渣生产高碱度球团矿的方法。The invention belongs to the technical field of iron and steel metallurgy, and more specifically relates to a method for producing high-alkalinity pellets by utilizing fine ore powder and refining slag.

背景技术Background technique

在钢铁生产中,BF-BOF流程一直占据着主导地位,而高炉炼铁是铁水的主要来源,占总生铁产量的90%以上。高炉炼铁原料主要有铁矿石、燃料、熔剂以及鼓风等,我国高炉炉料结构是采用以高碱度烧结矿为主,酸性球团矿和块矿为辅的炉料结构,为高炉提供了含铁原料。烧结矿和球团矿碱度的控制也利于高炉造渣,保证炉渣碱度和流动性,利于高炉脱硫和出铁。但在整个钢铁生产BF-BOF流程中,烧结工艺能耗占7.4%,球团工艺占比1.2%;烧结工艺产生的环境污染也远远超过球团工艺。伴随着钢铁行业竞争的加剧和环保压力的日益加大,降本增效、环境友好的生产方式越来越受到行业的广泛关注。因此,生产高碱度球团矿,以替代高能耗高污染的烧结矿将成为未来含铁原料生产发展的新方向。In steel production, the BF-BOF process has always occupied a dominant position, while blast furnace ironmaking is the main source of molten iron, accounting for more than 90% of the total pig iron production. The raw materials for blast furnace ironmaking mainly include iron ore, fuel, flux, and blast. Iron-containing raw materials. The control of the basicity of sinter and pellets is also beneficial to blast furnace slagging, ensuring the basicity and fluidity of slag, which is beneficial to blast furnace desulfurization and iron tapping. However, in the entire BF-BOF process of steel production, the energy consumption of the sintering process accounts for 7.4%, and the pelletizing process accounts for 1.2%. The environmental pollution caused by the sintering process is far more than that of the pelletizing process. With the intensification of competition in the steel industry and the increasing pressure on environmental protection, cost reduction, efficiency enhancement, and environmentally friendly production methods have attracted more and more attention from the industry. Therefore, the production of high-alkalinity pellets to replace sinters with high energy consumption and high pollution will become a new direction for the production and development of iron-containing raw materials in the future.

高碱度球团矿生产工艺的开发和发展有助于节能减排、降本增效。当前国内生产的球团矿大部分为酸性球团矿,熔剂型球团矿生产一直没有工业规模,只有小部分企业生产低碱度的熔剂型球团矿。熔剂型球团矿是在造球过程中,直接在含铁物料中加入CaO、MgO等助熔剂,使其含有一定的碱度,从而改善球团矿的冶金性能。经过长期高炉冶炼实践探索,我国生产出的球团碱度CaO/SiO2=0.9-1.2、MgO=2.7-3.5%,具有还原度高、膨胀率低、软熔温度高、软熔温度区间窄等良好的冶金性能。但由于MgO熔剂来源少、原料成本高、脱硫能力较差,且高炉生产中需加入一定量CaO以调节炉渣碱度、流动性,因此一般企业不使用含镁原料作为球团来生产添加熔剂。含钙原料(主要为CaO和CaCO3)来源广泛,生产成本低廉,但CaO会大量吸水,在干燥预热或焙烧过程中易发生膨胀,致使球团裂开,因此现有技术中一般仅使用CaO来生产碱度在0.9-1.2之间的低碱度球团矿。而采用CaCO3作为熔剂时,在高炉中会发生C的熔损反应,加速炉内焦炭的消耗,因此工业中一般不采用CaCO3作为球团生产用熔剂。因此,探寻新型助熔剂,实现高碱度球团矿的生产是炼铁工作者追求的目标。The development and development of high-alkalinity pellet production technology is helpful for energy saving, emission reduction, cost reduction and efficiency increase. At present, most of the pellets produced in China are acid pellets, and the production of flux-type pellets has never been on an industrial scale. Only a small number of enterprises produce low-alkalinity flux-type pellets. Flux-type pellets are directly added CaO, MgO and other fluxes to iron-containing materials during the pelletizing process to make them contain a certain alkalinity, thereby improving the metallurgical properties of the pellets. After long-term practice and exploration of blast furnace smelting, the basicity of the pellets produced in China is CaO/SiO 2 =0.9-1.2, MgO=2.7-3.5%, which has high reduction degree, low expansion rate, high reflow temperature and narrow reflow temperature range. And other good metallurgical properties. However, due to the lack of sources of MgO flux, high raw material cost, poor desulfurization ability, and a certain amount of CaO needs to be added in blast furnace production to adjust slag alkalinity and fluidity, general enterprises do not use magnesium-containing raw materials as pellets to produce added flux. Calcium-containing raw materials (mainly CaO and CaCO 3 ) have a wide range of sources and low production costs, but CaO will absorb a lot of water and tend to expand during drying, preheating or roasting, causing the pellets to crack. Therefore, in the prior art, only CaO to produce low-alkalinity pellets with an alkalinity between 0.9-1.2. When CaCO 3 is used as a flux, the melting loss reaction of C will occur in the blast furnace, which will accelerate the consumption of coke in the furnace. Therefore, CaCO 3 is generally not used as a flux for pellet production in the industry. Therefore, it is the goal pursued by iron smelters to explore new fluxes and realize the production of high-basicity pellets.

通过专利检索,目前已有相关的球团生产方法公开。如中国专利申请号CN201110275404.8公开了一种利用金矿尾渣和褐铁矿生产氧化球团的方法,该申请案中氧化球团生产方法是将金矿尾渣、褐铁矿和磁铁矿的粉料按重量百分比分别为40%、30%和30%的比例混合,制成生球团,然后在链篦机中预热,通过延长生球预热时间提高球团爆裂温度,改善球团冶金性能,再进入回转窑烧制成型,最后通过环冷机冷却,制成氧化球团。该方法采用了金矿尾渣作为原料之一,进行了废物利用,且通过温度控制小幅提高生球爆裂性能,但其生产所得产品仍是酸性球团,没有从根本上提高球团碱度,生产高碱度的自熔性球团矿,应用范围有限。专利申请号CN201410007020.1公开了一种富钛球团及其生产方法,该申请案中提供了富钛球团的生产方法,生产过程中向原料中添加含钛原料,生球TiO2含量在10-15%,TFe在40-55%,该申请案制备的富钛球团同样是酸性球团,只是在冶金性能方面作了改进,不能从本质上替代高能耗高污染的高碱度烧结矿作为高炉入炉主要原料。Through patent retrieval, relevant pellet production methods have been disclosed at present. For example, Chinese Patent Application No. CN201110275404.8 discloses a method for producing oxidized pellets using gold ore tailings and limonite. The ore powder is mixed according to the proportion of 40%, 30% and 30% by weight respectively, and made into green pellets, and then preheated in the chain grate machine, and the bursting temperature of the pellets is increased by prolonging the preheating time of the green balls to improve The metallurgical properties of the pellets are improved, and then enter the rotary kiln to be fired and shaped, and finally cooled by the ring cooler to make oxidized pellets. This method uses gold ore tailings as one of the raw materials for waste utilization, and slightly improves the bursting performance of green pellets through temperature control, but the product produced is still acidic pellets, and the alkalinity of pellets is not fundamentally improved. Production of self-fluxing pellets with high alkalinity, limited application range. Patent application number CN201410007020.1 discloses a titanium-rich pellet and its production method. The application provides a production method for titanium-rich pellets. During the production process, titanium-containing raw materials are added to the raw materials. The content of TiO 2 in the green pellets is 10-15%, TFe is 40-55%, the titanium-rich pellets prepared in this application are also acidic pellets, only improved in metallurgical properties, and cannot essentially replace high-energy-consumption and high-pollution high-alkalinity sintering Ore is used as the main raw material for the blast furnace.

又如,中国专利201610027266.4公开了一种利用钢渣制备碱性球团矿的方法及由该方法制得的产品,该申请案将钢渣粉与铁精粉按质量比(12-30):(70-88)混匀得混合料,然后依次对所述混合料进行造球、干燥、预热、焙烧及环冷处理,即得碱性球团矿。该申请案采用钢渣(即转炉渣)作为添加物,由于钢渣碱度低,一般只有1.0-3.0之间,且其中含有的S、P等杂质含量高。如采用需大量加入,需要消耗大量热量,而高炉冶金焦资源匮乏,价格高,加入大量钢渣进入球团后,消耗燃料,生产成本上升。此外高炉生产对S、P以及碱金属等成分要求高,大量钢渣的加入造成炉内杂质元素过多,影响生铁质量。因此,从生产成本和产品质量方面考虑,均不适用采用钢渣作为添加物。As another example, Chinese patent 201610027266.4 discloses a method of using steel slag to prepare alkaline pellets and the products obtained by the method. In this application, the mass ratio of steel slag powder to iron concentrate powder (12-30): (70 -88) Mix evenly to obtain a mixture, and then sequentially perform pelletizing, drying, preheating, roasting and ring cooling on the mixture to obtain alkaline pellets. This application uses steel slag (ie, converter slag) as an additive. Due to the low alkalinity of steel slag, it is generally only between 1.0-3.0, and the content of impurities such as S and P contained therein is high. If it needs to be added in a large amount, it needs to consume a lot of heat, but the metallurgical coke resources of the blast furnace are scarce and the price is high. After adding a large amount of steel slag into the pellets, the fuel will be consumed and the production cost will increase. In addition, blast furnace production has high requirements on S, P, and alkali metals. The addition of a large amount of steel slag causes too many impurity elements in the furnace, which affects the quality of pig iron. Therefore, from the aspects of production cost and product quality, it is not suitable to use steel slag as an additive.

申请号为201510447174.7的专利公开了一种防粘结碱性球团及其制造方法,其防粘结碱性球团的化学成分质量份数为:TFe:59~66份;MgO:0.8~2.0份;SiO2:0.5~3.5份;CaO/SiO2为0.6-1.8。该申请案通过向铁精矿中配入粘结剂、含钙的添加剂和含镁的添加剂,经表面处理、造球、烧结即得到成品防粘结碱性球团。但由于碱性球团中添加0.8-2.0%的MgO,因此大大提高了球团原料量大的钢铁企业生产成本,且其含钙添加剂为生石灰或生石灰与石灰石的混合物,没有解决生石灰(主要成分是CaO)吸水后,在焙烧过程中膨胀开裂的问题,加入的石灰石(主要成分是CaCO3)也会加速高炉内焦炭的熔损。The patent application No. 201510447174.7 discloses an anti-adhesive alkaline pellet and its manufacturing method. The chemical composition of the anti-adhesive alkaline pellet is: TFe: 59-66 parts; MgO: 0.8-2.0 parts; SiO 2 : 0.5-3.5 parts; CaO/SiO 2 : 0.6-1.8. In this application, a binding agent, a calcium-containing additive and a magnesium-containing additive are added to the iron concentrate, and the finished anti-caking alkaline pellets are obtained through surface treatment, pelletizing and sintering. However, due to the addition of 0.8-2.0% MgO in the alkaline pellets, the production cost of iron and steel enterprises with a large amount of raw materials for the pellets has been greatly increased, and the calcium-containing additive is a mixture of quicklime or quicklime and limestone, which does not solve the problem of quicklime (main component) After CaO) absorbs water, it expands and cracks during the roasting process, and the added limestone (the main component is CaCO 3 ) will also accelerate the melting loss of coke in the blast furnace.

申请号为2006100012540的申请案公开了一种熔剂型铁矿粉复合球团的生产方法,该申请案采用多次造球方式来生产单球双碱度复合熔剂型球团,并通过控制第一次造球过程中CaO与MgO的量,从而能够有效控制球团的二元碱度为0.5-2.0之间。该申请案采用二次造球的生产方法,以生产较高碱度的合格球团,增加了企业生产的基建成本和管理成本,且添加一定量的MgO作为原料,增加了高炉铁水的生产成本。同时二次造球时加入的石灰石和白云石进入高炉后分解,与炉内的焦炭反应,加速了焦炭的熔损,破坏了焦炭的料柱骨架作用,不利于高炉的透气性和炉况稳定。The application with application number 2006100012540 discloses a production method of flux-type iron ore powder composite pellets. The amount of CaO and MgO in the secondary pelletizing process can effectively control the binary alkalinity of the pellets to be between 0.5-2.0. This application adopts the production method of secondary pelletizing to produce qualified pellets with higher alkalinity, which increases the capital construction cost and management cost of the enterprise's production, and adds a certain amount of MgO as raw material, which increases the production cost of blast furnace molten iron . At the same time, the limestone and dolomite added during the secondary pelletizing enter the blast furnace and decompose, react with the coke in the furnace, accelerate the melting loss of the coke, and destroy the coke's material column skeleton, which is not conducive to the air permeability of the blast furnace and the stability of the furnace condition .

综上所述,现有的球团生产工艺均采用含铁物料为原料,再经过生球干燥、预热、焙烧和冷却,进行球团生产,或配加少量添加剂改善球团冶金性能,生产出的产品大多是酸性球团矿或是低碱度球团矿,不能从根本上改变高碱度烧结矿配加酸性球团矿、块矿的炉料结构,从而对高炉炼铁工艺存在的铁前系统能耗和环境污染问题不能进行有效解决。To sum up, the existing pellet production processes all use iron-containing materials as raw materials, and then go through green pellet drying, preheating, roasting and cooling to produce pellets, or add a small amount of additives to improve the metallurgical properties of pellets, and produce pellets. Most of the products produced are acid pellets or low-alkalinity pellets, which cannot fundamentally change the charge structure of high-basic sinter with acid pellets and lump ore, so that the iron existing in the blast furnace ironmaking process will be affected. The problems of energy consumption and environmental pollution of the former system cannot be effectively solved.

发明内容Contents of the invention

1.发明要解决的技术问题1. The technical problem to be solved by the invention

本发明的目的在于克服采用现有球团生产工艺无法生产得到满足要求的高碱度球团矿,从而导致高炉炼铁工艺存在严重的铁前系统能耗和环境污染问题的不足,提供了一种高炉炼铁用高碱度球团矿及其生产方法。采用本发明的技术方案能够生产得到高碱度球团矿,从而解决现有球团生产工艺存在的不足,且得到的球团成分和质量完全符合高炉炼铁的要求。The purpose of the present invention is to overcome the deficiency that the existing pellet production process cannot produce high-alkalinity pellets that meet the requirements, which leads to serious problems of energy consumption and environmental pollution in the blast furnace ironmaking process, and provides a Disclosed are high-basicity pellets for blast furnace ironmaking and a production method thereof. The technical scheme of the invention can produce high-alkalinity pellets, thereby solving the shortcomings of the existing pellet production process, and the composition and quality of the obtained pellets fully meet the requirements of blast furnace ironmaking.

2.技术方案2. Technical solution

为达到上述目的,本发明提供的技术方案为:In order to achieve the above object, the technical scheme provided by the invention is:

本发明的一种高炉炼铁用高碱度球团矿,该球团矿是以精矿粉、精炼渣和膨润土为原料制成的,且各组分的质量百分比分别为:精矿粉60-76%、精炼渣22-38%、膨润土1.5-2.5%。A high-alkalinity pellet for blast furnace ironmaking according to the present invention, the pellet is made of concentrate powder, refining slag and bentonite as raw materials, and the mass percentages of each component are respectively: concentrate powder 60 -76%, refining slag 22-38%, bentonite 1.5-2.5%.

更进一步的,该球团矿的碱度为1.9-2.6,抗压强度为3100-5000N。Furthermore, the pellets have an alkalinity of 1.9-2.6 and a compressive strength of 3100-5000N.

更进一步的,所述精矿粉中TFe的质量分数为65-70%,CaO和SiO2的质量分数分别为1-1.5%、3-3.3%;所述精炼渣中含CaO 45-50%,含SiO2 8-15%;所述膨润土中含CaO2-3%,含SiO2 68-70%。Furthermore, the mass fraction of TFe in the concentrate powder is 65-70%, the mass fractions of CaO and SiO are 1-1.5%, 3-3.3 % respectively; the refining slag contains 45-50% of CaO , containing 8-15% of SiO 2 ; the bentonite contains 2-3% of CaO and 68-70% of SiO 2 .

本发明的高炉炼铁用高碱度球团矿的生产方法,所述高碱度球团矿是以精矿粉、精炼渣和膨润土为原料,经造球、预热和焙烧处理得到的,具体包括以下步骤:The production method of the high-alkalinity pellets for blast furnace ironmaking of the present invention, the high-alkalinity pellets are obtained by pelletizing, preheating and roasting with ore concentrate powder, refining slag and bentonite as raw materials, Specifically include the following steps:

步骤一、原料配加Step 1. Adding raw materials

将生球的造球原料精矿粉、精炼渣和膨润土研磨成粉料后进行烘干,然后按原料配比配料并混合均匀,得到混合料;Grinding raw pelletizing raw materials concentrate powder, refining slag and bentonite into powder, drying, and then mixing according to the ratio of raw materials to obtain a mixture;

步骤二、造球Step two, ball making

将所得混合料进行造球得到生球团,并筛选出粒径为10-16mm的合格球团;Pelletizing the obtained mixture to obtain raw pellets, and screening qualified pellets with a particle size of 10-16mm;

步骤三、生球预热Step 3. Preheating the raw balls

将造好的生球团先置于100-200℃温度下进行干燥,干燥时间为7-10min,然后置于500-1000℃温度下进行预热,预热时间为12-20min;The prepared green pellets are first dried at a temperature of 100-200°C for 7-10 minutes, and then preheated at a temperature of 500-1000°C for 12-20 minutes;

步骤四、生球焙烧Step 4. Green ball roasting

将预热后的球团继续升温,于900-1300℃温度下进行焙烧,焙烧时间为25-40min,然后随炉冷却后取出,即得到合格的高碱度球团矿。Continue to heat up the preheated pellets and roast them at 900-1300°C for 25-40 minutes, then take them out after cooling in the furnace to obtain qualified high-alkalinity pellets.

更进一步的,所述步骤一中粉料烘干温度为90-110℃,烘干时间为2h。Furthermore, in the step 1, the drying temperature of the powder is 90-110° C., and the drying time is 2 hours.

更进一步的,所述步骤二中采用圆盘造球机进行造球处理,圆盘造球机转速为6-8rad/min,圆盘倾角为45-48°。Furthermore, in the second step, a disc pelletizer is used for pelletizing treatment, the rotating speed of the disc pelletizer is 6-8 rad/min, and the disc inclination angle is 45-48°.

更进一步的,步骤二中所得球团的落下强度为3-5次,抗压强度为7-11N。Furthermore, the drop strength of the pellets obtained in the second step is 3-5 times, and the compressive strength is 7-11N.

更进一步的,所述球团的干燥、预热及焙烧过程均在电炉中进行,整个过程通过程序设定升温方式完成。Furthermore, the drying, preheating and roasting of the pellets are all carried out in an electric furnace, and the whole process is completed by setting the temperature in a programmed manner.

3.有益效果3. Beneficial effect

采用本发明提供的技术方案,与现有技术相比,具有如下显著效果:Compared with the prior art, the technical solution provided by the invention has the following remarkable effects:

(1)本发明的一种高炉炼铁用高碱度球团矿,是以精矿粉、精炼渣和膨润土为原料制成的,本发明通过采用富含助熔剂CaO的精炼渣作为原料之一,可生产出高碱度球团矿,该球团矿能够替代高能耗高污染的高碱度烧结矿作为高炉主要炉料,从而可有效改善现有高炉炉料结构存在的铁前系统能耗和环境污染问题。(1) A kind of high-basicity pellets for blast furnace ironmaking of the present invention is made of fine ore powder, refining slag and bentonite as raw materials. The present invention uses refining slag rich in flux CaO as one of the raw materials. 1. It can produce high-alkalinity pellets, which can replace high-energy-consumption and high-pollution high-alkalinity sintered ore as the main charge of the blast furnace, thereby effectively improving the energy consumption and Environmental Pollution.

(2)本发明的一种高炉炼铁用高碱度球团矿的生产方法,该方法以精矿粉、精炼渣和膨润土为原料,经造球、预热和焙烧处理能够生产得到高碱度球团矿,通过对球团矿的原料组成及配比进行优化设计,所得球团矿的碱度高达2.0以上,打破了现有球团生产技术中合格球团碱度不超过1.0的技术认知,使高碱度球团矿能够完全替代高碱度烧结矿,配以酸性球团矿,实现100%球团入炉,相对于现有高炉炉料结构,大大降低了能耗和污染排放,节约了生产成本的同时降低了污染、有效地保护了环境。(2) A kind of production method of high alkalinity pellets for blast furnace ironmaking of the present invention, this method is raw material with fine ore powder, refining slag and bentonite, can produce high alkalinity through pelletizing, preheating and roasting treatment High-strength pellets, by optimizing the raw material composition and proportion of the pellets, the resulting pellets have an alkalinity as high as 2.0 or more, breaking the existing pellet production technology where the alkalinity of qualified pellets does not exceed 1.0 Recognition, so that high-basicity pellets can completely replace high-basicity sinter, together with acid pellets, to achieve 100% pellets into the furnace, compared with the existing blast furnace charge structure, greatly reducing energy consumption and pollution emissions , saving production costs while reducing pollution and effectively protecting the environment.

(3)本发明的一种高炉炼铁用高碱度球团矿的生产方法,通过选用精炼渣作为原料之一,且该精炼渣的碱度高、S杂质含量低,与原矿S含量基本持平,从而降低了高炉的脱硫负担,保证了铁水中较低的S含量,同时辅以生产工艺参数的优化,能够有效解决现有高碱度球团在预热和焙烧中易裂开的问题,生产出的球团抗压强度大、S含量低、冶金性能优良,能够有效满足高炉炼铁的工艺要求。(3) A kind of production method of high-basicity pellets for blast furnace ironmaking of the present invention, by selecting refining slag as one of raw materials, and the basicity of this refining slag is high, S impurity content is low, and raw ore S content is basically Balanced, thereby reducing the desulfurization burden of the blast furnace, ensuring a low S content in molten iron, and supplemented by the optimization of production process parameters, it can effectively solve the problem that the existing high-alkalinity pellets are easy to crack during preheating and roasting , the produced pellets have high compressive strength, low S content and excellent metallurgical properties, which can effectively meet the technological requirements of blast furnace ironmaking.

(4)本发明的一种高炉炼铁用高碱度球团矿的生产方法,采用精矿粉和精炼渣为原料,充分利用了精炼过程产生的废弃物精炼渣,从而节约了球团生产原料,大大降低球团生产成本,对于企业降本增效具有重大意义;同时以精炼渣作为添加剂进行废物利用,还实现了废渣的内部消耗,解决了废弃物的堆放和污染问题,节约了废渣占地和处理成本,且保护了环境,因此该方法适于推广应用。(4) A kind of production method of high-basicity pellets for blast furnace ironmaking of the present invention adopts fine ore powder and refining slag as raw materials, fully utilizes the waste refining slag produced in the refining process, thereby saving pellet production raw materials, greatly reducing the production cost of pellets, which is of great significance for enterprises to reduce costs and increase efficiency; at the same time, using refining slag as an additive for waste utilization also realizes the internal consumption of waste residues, solves the problems of waste stacking and pollution, and saves waste residues Occupying land and processing costs, and protecting the environment, so this method is suitable for popularization and application.

附图说明Description of drawings

图1为本发明的一种高炉炼铁用高碱度球团矿的生产方法的工艺流程简图。Fig. 1 is a schematic process flow diagram of a production method of high-basicity pellets for blast furnace ironmaking of the present invention.

具体实施方式detailed description

针对现有“高碱度烧结矿+酸性球团矿”高炉炉料结构存在的高能耗高污染问题,碱性球团矿的生产研究成了近几年冶金工作者的一个研究热点。现有技术中大多都是通过CaO或MgO的添加来提高球团的碱性,但MgO的来源相对较少、原料成本高,且其脱硫能力较差;而使用CaO作为球团矿的碱性添加剂时,当其添加量较多时,则所得球团的强度明显下降,且球团在生产过程中极易裂开,未能得到推广应用。因此,现有工艺生产出的碱性球团矿的碱度相对较低,不能用来替代高能耗高污染的烧结矿。此外,现有碱性球团矿的抗压强度相对较低,在高炉炼铁工艺中极易发生破裂和粉化,随着球团矿碱度的提高,这种问题就更加严重。Aiming at the problems of high energy consumption and high pollution in the existing "high alkalinity sinter + acid pellet" blast furnace charge structure, research on the production of alkaline pellets has become a research hotspot for metallurgists in recent years. Most of the existing technologies increase the alkalinity of the pellets by adding CaO or MgO, but MgO has relatively few sources, high raw material costs, and poor desulfurization ability; while CaO is used as the alkaline In the case of additives, when the addition amount is large, the strength of the obtained pellets will obviously decrease, and the pellets are very easy to crack during the production process, so they have not been popularized and applied. Therefore, the alkalinity of the alkaline pellets produced by the existing process is relatively low, and cannot be used to replace sintered ore with high energy consumption and high pollution. In addition, the compressive strength of the existing alkaline pellets is relatively low, and they are prone to cracking and pulverization in the blast furnace ironmaking process. With the increase of the alkalinity of the pellets, this problem becomes more serious.

本发明通过以精矿粉和精炼渣为原料,经配混造球、干燥预热、焙烧冷却等工艺,并对各原料的组成、混合比例及具体生产工艺参数进行优化设计,从而可以生产得到高碱度的球团矿,所得球团矿的碱度甚至高达2.0以上,该高碱度球团矿可替代高能耗高污染的高碱度烧结矿作为高炉主要炉料,大大降低了能耗和污染排放,节约了生产成本的同时保护了环境,且得到的球团成分和质量完全符合要求。同时,采用本发明的技术方案还显著提高了所得球团矿的抗压强度,所得球团矿的S含量低,能够有效避免高炉炼铁过程中发生粉化和破裂现象,进而能够保证所得铁水的冶炼性能。此外,本发明通过控制配加的精矿粉和精炼渣的质量分数即可实现对球团碱度的有效控制,球团碱度调节简单。The present invention uses fine ore powder and refining slag as raw materials, undergoes processes such as compounding and pelletizing, drying and preheating, roasting and cooling, and optimizes the composition, mixing ratio and specific production process parameters of each raw material, so that it can produce High alkalinity pellets, the alkalinity of the obtained pellets is even as high as 2.0 or more, the high alkalinity pellets can replace high energy consumption and high pollution high alkalinity sintered ore as the main charge of the blast furnace, greatly reducing energy consumption and Pollution discharge saves production cost and protects the environment at the same time, and the composition and quality of the obtained pellets fully meet the requirements. At the same time, the adoption of the technical solution of the present invention also significantly improves the compressive strength of the obtained pellets, and the obtained pellets have a low S content, which can effectively avoid pulverization and cracking during the blast furnace ironmaking process, thereby ensuring that the obtained molten iron is smelting performance. In addition, the present invention can effectively control the basicity of the pellets by controlling the mass fractions of the added concentrate powder and refining slag, and the adjustment of the basicity of the pellets is simple.

为进一步了解本发明的内容,现结合具体实施例对本发明作详细描述。In order to further understand the content of the present invention, the present invention will be described in detail in conjunction with specific embodiments.

实施例1Example 1

本实施例的一种高炉炼铁用高碱度球团矿的生产方法,其工艺流程简图如图1所示,其具体步骤为:A kind of production method of high-basicity pellets for blast furnace ironmaking of the present embodiment, its technological process diagram is as shown in Figure 1, and its concrete steps are:

步骤一、原料配加Step 1. Adding raw materials

将生球的造球原料精矿粉、精炼渣和膨润土研磨制成粉料,本实施例中的自熔性球团由如下质量百分比含量的组分组成:精矿粉71.8%、精炼渣26.2%、粘结剂膨润土2%,其中本实施例中精矿粉、精炼渣及膨润土的成分组成见表1-表3所示。将混合料置于烘箱中,在110℃温度下烘干2h后混匀,直至混合充分,得到混合料。Grind raw pelletizing raw material concentrate powder, refining slag and bentonite to make powder. The self-fluxing pellets in this embodiment are composed of the following components in mass percentage: concentrate powder 71.8%, refining slag 26.2% %, binder bentonite 2%, wherein the composition of concentrate powder, refining slag and bentonite in this embodiment is shown in Table 1-Table 3. The mixture was placed in an oven, dried at 110° C. for 2 hours, and then mixed until fully mixed to obtain the mixture.

表1 精矿粉成分表(%)Table 1 Concentrate powder composition list (%)

表2 精炼渣成分表(%)Table 2 Composition of refining slag (%)

表3 膨润土成分表(%)Table 3 Bentonite composition list (%)

步骤二、生球形成Step 2. Green ball formation

将充分混匀的混合料在圆盘造球机上造球,圆盘造球机转速为7rad/min,圆盘倾角为45°,制成生球团,并筛选出粒径在10-16mm的合格球团,所得球团的平均落下强度为3.2次,抗压强度为8.21N。Pellet the well-mixed mixture on a disc pelletizer with a rotating speed of 7rad/min and a disc inclination of 45° to make green pellets, and screen out the pellets with a particle size of 10-16mm. Qualified pellets, the average drop strength of the obtained pellets is 3.2 times, and the compressive strength is 8.21N.

步骤三、生球预热Step 3. Preheating the raw balls

将造好的生球团置于电炉中,在200℃温度下进行干燥,干燥时间为8min,再在1000℃温度下对球团进行预热,预热时间为12min。The prepared green pellets were placed in an electric furnace and dried at a temperature of 200°C for 8 minutes, and then the pellets were preheated at a temperature of 1000°C for 12 minutes.

步骤四、生球焙烧Step 4. Green ball roasting

将预热后的球团在电炉中继续升温,在1200℃温度下进行焙烧,焙烧时间为35min。Continue to heat up the preheated pellets in an electric furnace, and roast them at a temperature of 1200° C. for 35 minutes.

步骤五、球团冷却Step 5. Pellet Cooling

将焙烧后的球团随炉冷却后取出,焙烧后球团为高碱度球团矿,球团碱度为2.1,抗压强度为4470N,得到合格的高碱度球团。The roasted pellets are taken out after being cooled in the furnace. The roasted pellets are high-basicity pellets with a basicity of 2.1 and a compressive strength of 4470N, and qualified high-basicity pellets are obtained.

实施例2Example 2

本实施例的一种利用精矿粉和精炼渣生产高碱度球团矿的方法,其具体步骤为:A kind of method of utilizing fine ore powder and refining slag to produce high alkalinity pellets of the present embodiment, its specific steps are:

步骤一、原料配加Step 1. Adding raw materials

将生球的造球原料精矿粉、精炼渣和膨润土研磨制成粉料,本实施例中的自熔性球团由如下质量百分比含量的组分组成:精矿粉60.5%、精炼渣37.5%、粘结剂膨润土2%,本实施例中精矿粉、精炼渣及膨润土的成分组成同实施例1。将混合料置于烘箱中,在110℃温度下烘干2h后混匀,直至混合充分,得到混合料。Grind raw pelletizing raw material concentrate powder, refining slag and bentonite to make powder. The self-fluxing pellets in this embodiment are composed of the following components in mass percentage: concentrate powder 60.5%, refining slag 37.5% %, binder bentonite 2%, the composition of concentrate powder, refining slag and bentonite is the same as embodiment 1 in the present embodiment. The mixture was placed in an oven, dried at 110° C. for 2 hours, and then mixed until fully mixed to obtain the mixture.

步骤二、生球形成Step 2. Green ball formation

将充分混匀的混合料在圆盘造球机上造球,圆盘造球机转速为7rad/min,圆盘倾角为45°,制成生球团,并筛选出粒径在10-16mm的合格球团,所得球团的平均落下强度为3.4次,抗压强度为10.01N。Pellet the well-mixed mixture on a disc pelletizer with a rotating speed of 7rad/min and a disc inclination of 45° to make green pellets, and screen out the pellets with a particle size of 10-16mm. Qualified pellets, the average drop strength of the obtained pellets is 3.4 times, and the compressive strength is 10.01N.

步骤三、生球预热Step 3. Preheating the raw balls

将造好的生球团置于电炉中,在100℃温度下进行干燥,干燥时间为8min,再在900℃温度下对球团进行预热,预热时间为15min。The prepared green pellets were placed in an electric furnace and dried at a temperature of 100°C for 8 minutes, and then preheated at a temperature of 900°C for 15 minutes.

步骤四、生球焙烧Step 4. Green ball roasting

将预热后的球团在电炉中继续升温,在1300℃温度下进行焙烧,焙烧时间为25min。Continue to heat up the preheated pellets in an electric furnace, and roast them at a temperature of 1300° C. for 25 minutes.

步骤五、球团冷却Step 5. Pellet Cooling

将焙烧后的球团随炉冷却后取出,焙烧后球团为高碱度球团矿,球团碱度为2.6,抗压强度为3160N,得到合格的高碱度球团。The roasted pellets are taken out after being cooled in the furnace. The roasted pellets are high-basicity pellets with a basicity of 2.6 and a compressive strength of 3160N, and qualified high-basicity pellets are obtained.

实施例3Example 3

本实施例的一种利用精矿粉和精炼渣生产高碱度球团矿的方法,其具体步骤为:A kind of method of utilizing fine ore powder and refining slag to produce high alkalinity pellets of the present embodiment, its specific steps are:

步骤一、原料配加Step 1. Adding raw materials

将生球的造球原料精矿粉、精炼渣和膨润土研磨制成粉料,本实施例中的自熔性球团由如下质量百分比含量的组分组成:精矿粉76%、精炼渣22%、粘结剂2%,其中精矿粉、精炼渣及膨润土的成分组成见下表4-表6。将混合料置于烘箱中,在90℃温度下烘干2h后混匀,直至混合充分,得到混合料。Grind raw pelletizing raw material concentrate powder, refining slag and bentonite to make powder. The self-fluxing pellets in this embodiment are composed of the following components in mass percentage: concentrate powder 76%, refining slag 22% %, binder 2%, wherein the composition of concentrate powder, refining slag and bentonite is shown in Table 4-Table 6 below. The mixture was placed in an oven, dried at 90° C. for 2 hours, and then mixed until fully mixed to obtain the mixture.

表4 精矿粉成分表(%)Table 4 Concentrate powder composition table (%)

表5 精炼渣成分表(%)Table 5 Composition of refining slag (%)

表6 膨润土成分表(%)Table 6 Bentonite composition table (%)

步骤二、生球形成Step 2. Green ball formation

将充分混匀的混合料在圆盘造球机上造球,圆盘造球机转速为6rad/min,圆盘倾角为48°,制成生球团,并筛选出粒径在10-16mm的合格球团,所得球团的平均落下强度为5次,抗压强度为11N。The well-mixed mixture is pelletized on a disc pelletizer, the disc pelletizer rotates at 6rad/min, and the disc inclination is 48° to make green pellets, and the particles with a particle size of 10-16mm are screened out. Qualified pellets, the average drop strength of the obtained pellets is 5 times, and the compressive strength is 11N.

步骤三、生球预热Step 3. Preheating the raw balls

将造好的生球团置于电炉中,在175℃温度下进行干燥,干燥时间为7min,再在500℃温度下对球团进行预热,预热时间为20min。The prepared green pellets were placed in an electric furnace and dried at a temperature of 175°C for 7 minutes, and then preheated at a temperature of 500°C for 20 minutes.

步骤四、生球焙烧Step 4. Green ball roasting

将预热后的球团在电炉中继续升温,在900℃温度下进行焙烧,焙烧时间为40min。Continue to heat up the preheated pellets in an electric furnace, and roast them at a temperature of 900° C. for 40 minutes.

步骤五、球团冷却Step 5. Pellet Cooling

将焙烧后的球团随炉冷却后取出,焙烧后球团为高碱度球团矿,球团碱度为1.9,抗压强度为3400N,得到合格的高碱度球团。The roasted pellets are taken out after being cooled in the furnace. The roasted pellets are high-basicity pellets with a basicity of 1.9 and a compressive strength of 3400N, and qualified high-basicity pellets are obtained.

实施例4Example 4

本实施例的一种利用精矿粉和精炼渣生产高碱度球团矿的方法,其具体步骤为:A kind of method of utilizing fine ore powder and refining slag to produce high alkalinity pellets of the present embodiment, its specific steps are:

步骤一、原料配加Step 1. Adding raw materials

将生球的造球原料精矿粉、精炼渣和膨润土研磨制成粉料,本实施例中的自熔性球团由如下质量百分比含量的组分组成:精矿粉65%、精炼渣32.5%、粘结剂2.5%,其中精矿粉、精炼渣及膨润土的成分组成见下表7-表9。将混合料置于烘箱中,在103℃温度下烘干2h后混匀,直至混合充分,得到混合料。Grind raw pelletizing raw material concentrate powder, refining slag and bentonite to make powder. The self-fluxing pellets in this embodiment are composed of the following components in mass percentage: concentrate powder 65%, refining slag 32.5% %, binder 2.5%, wherein the composition of concentrate powder, refining slag and bentonite is shown in Table 7-9 below. The mixture was placed in an oven, dried at 103° C. for 2 hours, and then mixed until fully mixed to obtain a mixture.

表7 精矿粉成分表(%)Table 7 Concentrate powder composition table (%)

表8 精炼渣成分表(%)Table 8 Composition of refining slag (%)

表9 膨润土成分表(%)Table 9 Bentonite composition table (%)

步骤二、生球形成Step 2. Green ball formation

将充分混匀的混合料在圆盘造球机上造球,圆盘造球机转速为8rad/min,圆盘倾角为46°,制成生球团,并筛选出粒径在10-16mm的合格球团,所得球团的平均落下强度为3次,抗压强度为7N。Pellet the well-mixed mixture on a disc pelletizer with a rotating speed of 8 rad/min and a disc inclination of 46° to make green pellets, and screen out particles with a particle size of 10-16mm. Qualified pellets, the average drop strength of the obtained pellets is 3 times, and the compressive strength is 7N.

步骤三、生球预热Step 3. Preheating the raw balls

将造好的生球团置于电炉中,在120℃温度下进行干燥,干燥时间为10min,再在750℃温度下对球团进行预热,预热时间为17min。The prepared green pellets were placed in an electric furnace and dried at a temperature of 120°C for 10 minutes, and then preheated at a temperature of 750°C for 17 minutes.

步骤四、生球焙烧Step 4. Green ball roasting

将预热后的球团在电炉中继续升温,在1050℃温度下进行焙烧,焙烧时间为30min。Continue to heat up the preheated pellets in an electric furnace, and roast them at a temperature of 1050° C. for 30 minutes.

步骤五、球团冷却Step 5. Pellet Cooling

将焙烧后的球团随炉冷却后取出,焙烧后球团为高碱度球团矿,球团碱度为2.4,抗压强度为5000N,得到合格的高碱度球团。The roasted pellets are taken out after being cooled in the furnace, and the roasted pellets are high-basicity pellets with a basicity of 2.4 and a compressive strength of 5000N, and qualified high-basicity pellets are obtained.

实施例5Example 5

本实施例的一种利用精矿粉和精炼渣生产高碱度球团矿的方法,其具体步骤为:A kind of method of utilizing fine ore powder and refining slag to produce high alkalinity pellets of the present embodiment, its specific steps are:

步骤一、原料配加Step 1. Adding raw materials

将生球的造球原料精矿粉、精炼渣和膨润土研磨制成粉料,本实施例中的自熔性球团由如下质量百分比含量的组分组成:精矿粉63%、精炼渣35.5%、粘结剂1.5%,其中精矿粉的实施例4,精炼渣及膨润土的成分组成见下表10-表11。将混合料置于烘箱中,在98℃温度下烘干2h后混匀,直至混合充分,得到混合料。Grind raw pelletizing raw material concentrate powder, refining slag and bentonite to make powder. The self-fluxing pellets in this embodiment are composed of the following components in mass percentage: concentrate powder 63%, refining slag 35.5% %, binder 1.5%, wherein the embodiment 4 of concentrate powder, the composition of refining slag and bentonite is shown in Table 10-Table 11 below. The mixture was placed in an oven, dried at 98° C. for 2 hours, and then mixed until fully mixed to obtain the mixture.

表10 精炼渣成分表(%)Table 10 Composition of refining slag (%)

表11 膨润土成分表(%)Table 11 Bentonite composition table (%)

步骤二、生球形成Step 2. Green ball formation

将充分混匀的混合料在圆盘造球机上造球,圆盘造球机转速为8rad/min,圆盘倾角为47°,制成生球团,并筛选出粒径在10-16mm的合格球团,所得球团的平均落下强度为4.4次,抗压强度为10.5N。Pellet the well-mixed mixture on a disc pelletizer with a rotating speed of 8 rad/min and a disc inclination of 47° to make green pellets, and screen out particles with a particle size of 10-16mm. Qualified pellets, the average drop strength of the obtained pellets is 4.4 times, and the compressive strength is 10.5N.

步骤三、生球预热Step 3. Preheating the raw balls

将造好的生球团置于电炉中,在138℃温度下进行干燥,干燥时间为9min,再在850℃温度下对球团进行预热,预热时间为17min。The prepared green pellets were placed in an electric furnace and dried at a temperature of 138°C for 9 minutes, and then preheated at a temperature of 850°C for 17 minutes.

步骤四、生球焙烧Step 4. Green ball roasting

将预热后的球团在电炉中继续升温,在1000℃温度下进行焙烧,焙烧时间为25min。Continue to heat up the preheated pellets in an electric furnace, and roast them at a temperature of 1000° C. for 25 minutes.

步骤五、球团冷却Step 5. Pellet Cooling

将焙烧后的球团随炉冷却后取出,焙烧后球团为高碱度球团矿,球团碱度为2.2,抗压强度为4200N,得到合格的高碱度球团。The roasted pellets are taken out after being cooled in the furnace. The roasted pellets are high-basicity pellets with a basicity of 2.2 and a compressive strength of 4200N, and qualified high-basicity pellets are obtained.

Claims (9)

  1. A kind of 1. blast furnace ironmaking superfluxed pellets, it is characterised in that:The pellet is with fine ore, refining slag and bentonite For made of raw material, and the mass percent of each component is respectively:Fine ore 60-76%, refining slag 22-38%, bentonite 1.5-2.5%.
  2. A kind of 2. blast furnace ironmaking superfluxed pellets according to claim 1, it is characterised in that:The basicity of the pellet For 1.9-2.6, compression strength 3100-5000.
  3. A kind of 3. blast furnace ironmaking superfluxed pellets according to claim 1, it is characterised in that:In the fine ore TFe mass fraction is 65-70%, CaO and SiO2Mass fraction be respectively 1-1.5%, 3-3.3%;In the refining slag Containing CaO45-50%, containing SiO28-15%;2-3% containing CaO in the bentonite, containing SiO268-70%.
  4. 4. a kind of production method of blast furnace ironmaking superfluxed pellets as any one of claim 1-3, its feature It is:The superfluxed pellets is using fine ore, refining slag and bentonite as raw material, is obtained through pelletizing, preheating and calcination process Arrive.
  5. 5. the production method of a kind of blast furnace ironmaking superfluxed pellets according to claim 4, it is characterised in that specific Comprise the following steps:
    Step 1: raw material with addition of
    Dried after pelletizing raw material fine ore, refining slag and the bentonite of green-ball are ground into powder, then by raw material proportioning Dispensing is simultaneously well mixed, and obtains compound;
    Step 2: pelletizing
    Gained compound progress pelletizing is obtained into green pellets, and filters out the qualified pelletizing that particle diameter is 10-16mm;
    Step 3: green-ball preheats
    It is dried, drying time 7-10min, is subsequently placed at a temperature of the green pellets made first is placed in into 100-200 DEG C Preheated at a temperature of 500-1000 DEG C, preheating time 12-20min;
    Step 4: green-ball is calcined
    Pelletizing after preheating is continued to heat up, is calcined at a temperature of 900-1300 DEG C, roasting time 25-40min, then Taken out after furnace cooling, that is, obtain qualified superfluxed pellets.
  6. A kind of 6. production method of blast furnace ironmaking superfluxed pellets according to claim 5, it is characterised in that:It is described Powder drying temperature is 90-110 DEG C in step 1, drying time 2h.
  7. A kind of 7. production method of blast furnace ironmaking superfluxed pellets according to claim 5, it is characterised in that:It is described Pelletizing processing is carried out using disc balling machine in step 2, disc balling machine rotating speed is 6-8rad/min, disk tilt angle 45- 48°。
  8. A kind of 8. production method of blast furnace ironmaking superfluxed pellets according to claim 7, it is characterised in that:Step The drop strength of gained pelletizing is 3-5 times in two, compression strength 7-11N.
  9. 9. a kind of production method of blast furnace ironmaking superfluxed pellets according to any one of claim 5-8, it is special Sign is:Drying, preheating and the roasting process of the pelletizing are carried out in electric furnace.
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