CN106966523B - Surplus aqueous ammonia oil water separator - Google Patents
Surplus aqueous ammonia oil water separator Download PDFInfo
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- CN106966523B CN106966523B CN201710398735.8A CN201710398735A CN106966523B CN 106966523 B CN106966523 B CN 106966523B CN 201710398735 A CN201710398735 A CN 201710398735A CN 106966523 B CN106966523 B CN 106966523B
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- water
- cooling
- ammonia water
- oil
- residual ammonia
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/40—Devices for separating or removing fatty or oily substances or similar floating material
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Physical Water Treatments (AREA)
Abstract
The invention belongs to the technical field of wastewater treatment, and provides a residual ammonia water oil-water separation device which comprises cooling separation equipment and air floatation separation equipment, wherein the cooling separation equipment reduces the temperature of residual ammonia water, and the principle that the solubility of phenolate oil in the ammonia water is gradually increased from low temperature to high temperature or the solubility is gradually reduced from high temperature to low temperature is utilized to separate out the phenolate oil partially dissolved in the ammonia water from water, so that partial separation is realized, and a part of the phenolate oil is separated through the air floatation separation equipment, so that the content of the phenolate oil in the residual ammonia water is reduced, and conditions are created for subsequent water treatment.
Description
Technical Field
The invention relates to the technical field of oil-water separation, in particular to a residual ammonia water oil-water separation device.
Background
The residual ammonia water is generated in the coal pyrolysis process in the coal chemical industry field, and contains a large amount of coal gas, coal tar and condensed water in the coal gas in the coal pyrolysis process, wherein the condensed water contains a large amount of phenols and other organic matters and ammonia, so that the part of water is ammonia water, and the ammonia water is taken as a medium for circulating and cooling the coal gas.
There are many oil-water separation technologies, namely, separating oil from water or separating water from oil, but the technologies are classified into filtration or separation with different oil-water densities, such as separation by hydrophobic and oleophilic filter materials or oil-water separation by different oil-water densities, no matter what scheme is adopted in the oil-water separation technologies. However, the removal of phenol oil is difficult to achieve by simply filtering the soluble phenol substances contained in the residual ammonia water produced in the coal chemical industry.
Disclosure of Invention
In view of the above, the present invention provides a residual ammonia water oil-water separation device, which aims at overcoming the defects of the prior art, and utilizes the principle that the solubility of the phenolate oil in the ammonia water gradually increases from low temperature to high temperature or the solubility gradually decreases from high temperature to low temperature to separate out the phenolate oil partially dissolved in the ammonia water from the water, so as to realize partial separation, and then separate a part of the phenolate oil by an air floatation separation device, thereby reducing the content of the phenolate oil in the residual ammonia water and creating conditions for the subsequent water treatment.
In order to solve the technical problems, the invention adopts the following technical scheme: the utility model provides a surplus aqueous ammonia water oil water separating device, includes cooling separation equipment, cooling separation equipment includes container shell, condenser, the condenser sets up in the container shell, the condenser is the snakelike cooling tube, be the cooling water in the cooling tube, the cooling water follows low high out principle, and surplus aqueous ammonia is in cooling separation equipment's shell side follows high out principle, cooling separation equipment container shell's bottom sets up heavy oil outlet pipe, cooling separation equipment container shell's upper portion sets up light oil outlet pipe, heavy oil outlet pipe is less than surplus aqueous ammonia outlet pipe, light oil outlet pipe is higher than surplus aqueous ammonia import pipeline.
Further, the residual ammonia water oil-water separation device further comprises an air floatation separation device, the residual ammonia water which is discharged from the cooling separation device enters the air floatation separation device, and after the residual ammonia water is subjected to further air floatation separation by the air floatation separation device, the residual ammonia water enters the wastewater treatment.
Further, the bottom of the container shell of the cooling separation device is a conical structure protruding inwards of the container, and the height of the conical protrusion is higher than that of the heavy oil outlet pipeline.
The invention has the advantages that: the method is characterized in that the principle that the solubility of the phenolate oil in the ammonia water is gradually increased from low temperature to high temperature or the solubility is gradually reduced from high temperature to low temperature is utilized to separate out the phenolate oil partially dissolved in the ammonia water from water, so that partial separation is realized, and a part of the phenolate oil is separated through an air floatation separation device, so that the content of the phenolate oil in the residual ammonia water is reduced, and conditions are created for subsequent water treatment.
In addition, the bottom of the container shell of the cooling separation device is a conical structure protruding into the container, and the height of the conical protrusion is higher than that of the heavy oil outlet pipeline.
Drawings
Fig. 1 is a schematic diagram of the overall structure of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more clear, the technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to fig. 1 of the embodiments of the present invention. It will be apparent that the described embodiments are some, but not all, embodiments of the invention. All other embodiments, which are obtained by a person skilled in the art based on the described embodiments of the invention, fall within the scope of protection of the invention.
Example 1
The utility model provides a surplus aqueous ammonia water oil water separator, includes cooling separation equipment 1, cooling separation equipment includes container housing 11, condenser 12 sets up in container housing 11, condenser 12 is the snakelike cooling tube, be cooling water in the cooling tube, the cooling water follows low high principle of going out, and surplus aqueous ammonia follows high low principle of going out in cooling separation equipment's shell side, and surplus aqueous ammonia import pipeline 13 sets up in cooling separation equipment 1's upper portion, surplus aqueous ammonia export pipeline 14 sets up in cooling separation equipment 1's lower part, cooling separation equipment container housing 11's bottom sets up heavy oil export pipeline 15, cooling separation equipment container housing 11's upper portion sets up light oil export pipeline 16, heavy oil export pipeline 15 is less than surplus aqueous ammonia export pipeline 14, light oil export pipeline 16 is higher than surplus aqueous ammonia import pipeline 13, heavy oil export pipeline 15 and light oil export pipeline 16 intercommunication empty slot.
The residual ammonia water oil-water separation device further comprises an air floatation separation device 2, residual ammonia water which comes out of the cooling separation device 1 enters the air floatation separation device 2, after further air floatation separation by the air floatation separation device 2, floating oil flows out through a floating oil pipeline 21 which is arranged by the air floatation separation device 2, enters a subsurface emptying tank, and residual ammonia water is discharged through a residual ammonia water pipeline 22 which is arranged by the air floatation separation device 2 and then enters wastewater treatment.
In the embodiment, the principle that the solubility of the phenolate oil in the ammonia water is gradually increased from low temperature to high temperature or the solubility is gradually reduced from high temperature to low temperature is utilized to separate out the phenolate oil partially dissolved in the ammonia water from the water, so that partial separation is realized, and a part of the phenolate oil is separated through an air floatation separation device, so that the content of the phenolate oil in the residual ammonia water is reduced, and conditions are created for subsequent water treatment.
Embodiment two: it differs from embodiment one in that: the bottom 17 of the container housing 11 of the cooling separation device is a conical structure protruding into the container from the center, and the height of the conical protrusion is higher than that of the heavy oil outlet pipe 15.
In this embodiment, the bottom of the container housing of the cooling and separating device is a tapered structure protruding into the container from the center, and the height of the tapered protrusion is higher than that of the heavy oil outlet pipe, so that heavy oil is more easily concentrated, and separation and discharge of heavy oil are more facilitated.
While the foregoing is directed to the preferred embodiments of the present invention, it will be appreciated by those skilled in the art that various modifications and adaptations can be made without departing from the principles of the present invention, and such modifications and adaptations are intended to be comprehended within the scope of the present invention.
Claims (1)
1. The utility model provides a surplus aqueous ammonia water oil water separating device, includes cooling separation equipment, its characterized in that: the cooling separation equipment comprises a container shell and a condenser, wherein the condenser is arranged in the container shell, the condenser is a serpentine cooling pipe, cooling water is arranged in the cooling pipe, the cooling water follows the principle of low-inlet and high-outlet, residual ammonia water is arranged in the shell side of the cooling separation equipment and follows the principle of high-inlet and low-outlet, a heavy oil outlet pipeline is arranged at the bottom of the container shell of the cooling separation equipment, a light oil outlet pipeline is arranged at the upper part of the container shell of the cooling separation equipment, the heavy oil outlet pipeline is lower than the residual ammonia water outlet pipeline, and the light oil outlet pipeline is higher than the residual ammonia water inlet pipeline;
the residual ammonia water oil-water separation device further comprises an air floatation separation device, wherein residual ammonia water from the cooling separation device enters the air floatation separation device, and after being subjected to further air floatation separation by the air floatation separation device, the residual ammonia water enters the wastewater treatment;
the bottom of the container shell of the cooling separation device is a conical structure protruding inwards of the container, and the height of the conical protrusion is higher than that of the heavy oil outlet pipeline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710398735.8A CN106966523B (en) | 2017-05-31 | 2017-05-31 | Surplus aqueous ammonia oil water separator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710398735.8A CN106966523B (en) | 2017-05-31 | 2017-05-31 | Surplus aqueous ammonia oil water separator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106966523A CN106966523A (en) | 2017-07-21 |
| CN106966523B true CN106966523B (en) | 2023-07-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710398735.8A Active CN106966523B (en) | 2017-05-31 | 2017-05-31 | Surplus aqueous ammonia oil water separator |
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| Country | Link |
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| CN (1) | CN106966523B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108083559A (en) * | 2017-12-13 | 2018-05-29 | 河南龙成煤高效技术应用有限公司 | The phenol ammonia waste water processing method that pyrolysis of coal generates |
| CN112357994A (en) * | 2020-11-05 | 2021-02-12 | 华东理工大学 | Method and device for removing oil by air floatation with cold air |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073145A (en) * | 2013-02-01 | 2013-05-01 | 济钢集团有限公司 | System for recovering light oil from residual ammonia water |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101482378B (en) * | 2008-12-29 | 2011-08-10 | 清华大学 | Vapor-liquid separation method of segmented vapor-liquid phase change heat exchanger and phase change heat exchanger |
| CN104019592B (en) * | 2014-06-26 | 2016-06-01 | 吉首大学 | Ammonia refrigeration is except oil separator |
| CN204824404U (en) * | 2015-06-30 | 2015-12-02 | 甘肃宏汇能源化工有限公司 | Tar aqueous ammonia separation clean system |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073145A (en) * | 2013-02-01 | 2013-05-01 | 济钢集团有限公司 | System for recovering light oil from residual ammonia water |
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| CN106966523A (en) | 2017-07-21 |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20220616 Address after: 474571 industrial cluster of hongshiqiao village, HUICHE Town, Xixia County, Nanyang City, Henan Province Applicant after: HENAN LONGCHENG COAL HIGH EFFICIENCY TECHNOLOGY APPLICATION Co.,Ltd. Applicant after: HEBEI LONGCHENG COAL COMPREHENSIVE UTILIZATION Co.,Ltd. Address before: 474500 industrial cluster area, hongshiqiao village, HUICHE Town, Xixia County, Nanyang City, Henan Province Applicant before: HENAN LONGCHENG COAL HIGH EFFICIENCY TECHNOLOGY APPLICATION Co.,Ltd. Applicant before: HEBEI LONGCHENG COAL COMPREHENSIVE UTILIZATION Co.,Ltd. Applicant before: SHAANXI LONGCHENG COAL CLEAN AND HIGH EFFICIENCY UTILIZATION Co.,Ltd. |
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