CN106318044A - High stability coating for electronic massager and preparing method thereof - Google Patents
High stability coating for electronic massager and preparing method thereof Download PDFInfo
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- CN106318044A CN106318044A CN201610662447.4A CN201610662447A CN106318044A CN 106318044 A CN106318044 A CN 106318044A CN 201610662447 A CN201610662447 A CN 201610662447A CN 106318044 A CN106318044 A CN 106318044A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 30
- 238000000576 coating method Methods 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 27
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims abstract description 9
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 9
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- QYQNGNWRVVGCMK-UHFFFAOYSA-N n-(trifluoro-$l^{4}-sulfanyl)ethanamine Chemical compound CCNS(F)(F)F QYQNGNWRVVGCMK-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 239000011259 mixed solution Substances 0.000 abstract 2
- -1 polypropylene Polymers 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 238000010923 batch production Methods 0.000 abstract 1
- 229920000620 organic polymer Polymers 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 230000008901 benefit Effects 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WIHIUTUAHOZVLE-UHFFFAOYSA-N 1,3-diethoxypropan-2-ol Chemical group CCOCC(O)COCC WIHIUTUAHOZVLE-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PSCXEUSWZWRCMQ-UHFFFAOYSA-N F[S](F)F Chemical compound F[S](F)F PSCXEUSWZWRCMQ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
The invention discloses a high stability coating for an electronic massager and a preparing method thereof. The coating is prepared from polypropylene resin, silicone acrylic emulsion, cellulosic resin, acrylic ester, terephthalic acid, talcum powder, propylene glycol, glycol ether, appropriate amount of water, catalyst, synergist, nano-silica, isobornyl acrylate and rosin resin; the preparing method comprises in sequence the steps of 1, preparing first mixed liquid; 2, obtaining intermediate solution; 3, obtaining mixed solution; 4, pouring the mixed solution obtained in the step 3 into a ball mill for grinding treatment, so that the finished product is obtained by sieving. According to the preparing method of the high stability coating for the electronic massager, stable property is scientific and reasonable, which increases stable property of the composition through adoption of organic polymer material with relatively good comprehensive property and conducting of optimized combination, and the method has low cost, short production period and is suitable for batch production.
Description
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of electric massager high stability coating and preparation thereof
Method.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition
Green economy globalization overall situation under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with
The environmental protection such as newly " environmental law " promulgates, country " environmental protection, beautiful China " advocate the most no longer to stay on slogan, but real
Execute execution, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water of environmental protection
Property coating etc. substitute, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, more environmentally friendly, more individual
Property has become as the pursuit direction of household electrical appliances coating.Before the market demand huge in the face of household electrical appliances coating and ever-increasing application
Scape, strengthens research and development capabilities, and updates and improving product performance, accelerates product quality upgrading, develops technically, cost
Above, the household electrical appliances coating more showing powerful competitive advantage in performance has the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of electric massager high stability
Coating and preparation method thereof, this coating products excellent performance, there are good stability, and energy-conserving and environment-protective, possess preferably
Economic benefit and social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of electric massager high stability coating, is prepared by the raw materials in: acrylic resin 35～45 parts,
Silicone acrylic emulsion 10～15 parts, celluosic resin 2～5 parts, acrylate 5～12 parts, p-phthalic acid 8～15 parts, Pulvis Talci 2～
6 parts, propylene glycol 1～3 parts, glycol ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, synergist 1.5～2.5 parts, nanometer
Silica 1～5 parts, isobornyl acrylate 5～10 parts, rosin resin 5～12 parts；
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, Pulvis Talci, propylene glycol, glycol ether, nano silicon and suitable quantity of water are joined reaction
In container, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of acrylic resin, silicone acrylic emulsion, celluosic resin, acrylate and isobornyl acrylate is added
In the first mixed liquid that step (1) obtains, it is heated to 65～80 DEG C, continues stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, synergist and rosin resin,
Mix and blend 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sodium sulfonate.
Preferably, described synergist is diethylin sulfur trifluoride.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and being optimized
Combination, improves the stability of compositions, and the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good,
The indexs such as hot strength are superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low,
Achieving making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production,
Possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of electric massager high stability coating, is prepared by the raw materials in: acrylic resin 35 parts, silicon third
Emulsion 10 parts, celluosic resin 2 parts, acrylate 5 parts, p-phthalic acid 8 parts, Pulvis Talci 2 parts, propylene glycol 1 part, glycol ether
6 parts, water is appropriate, catalyst 1.5 parts, synergist 1.5 parts, nano silicon 1 part, isobornyl acrylate 5 parts, rosin resin
5 parts；
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, Pulvis Talci, propylene glycol, glycol ether, nano silicon and suitable quantity of water are joined reaction
In container, it is heated to 50～65 DEG C, stirs 20 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of acrylic resin, silicone acrylic emulsion, celluosic resin, acrylate and isobornyl acrylate is added
In the first mixed liquid that step (1) obtains, it is heated to 65～80 DEG C, continues stirring 30 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, synergist and rosin resin,
Mix and blend 50 minutes, obtains mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of electric massager high stability coating, is prepared by the raw materials in: acrylic resin 45 parts, silicon third
Emulsion 15 parts, celluosic resin 5 parts, acrylate 12 parts, p-phthalic acid 15 parts, Pulvis Talci 6 parts, propylene glycol 3 parts, dihydroxylic alcohols
12 parts of ether, water are appropriate, catalyst 3 parts, synergist 2.5 parts, nano silicon 5 parts, isobornyl acrylate 10 parts, rosin tree
12 parts of fat；
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, Pulvis Talci, propylene glycol, glycol ether, nano silicon and suitable quantity of water are joined reaction
In container, it is heated to 50～65 DEG C, stirs 30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of acrylic resin, silicone acrylic emulsion, celluosic resin, acrylate and isobornyl acrylate is added
In the first mixed liquid that step (1) obtains, it is heated to 65～80 DEG C, continues stirring 40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, synergist and rosin resin,
Mix and blend 80 minutes, obtains mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sodium sulfonate；
Described synergist is diethylin sulfur trifluoride.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The stability of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength etc.
Index is superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low, it is achieved that resource
With making full use of of the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (3)
1. an electric massager high stability coating, it is characterised in that be prepared by the raw materials in: acrylic resin
35～45 parts, silicone acrylic emulsion 10～15 parts, celluosic resin 2～5 parts, acrylate 5～12 parts, p-phthalic acid 8～15 parts,
Pulvis Talci 2～6 parts, propylene glycol 1～3 parts, glycol ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, synergist 1.5～
2.5 parts, nano silicon 1～5 parts, isobornyl acrylate 5～10 parts, rosin resin 5～12 parts；
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, Pulvis Talci, propylene glycol, glycol ether, nano silicon and suitable quantity of water are joined reaction vessel
In, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) acrylic resin, silicone acrylic emulsion, celluosic resin, acrylate and isobornyl acrylate are mixed to join step
Suddenly in the first mixed liquid that (1) obtains, it is heated to 65～80 DEG C, continues stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, synergist and rosin resin, mixing
Stir 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of electric massager high stability coating the most according to claim 1, it is characterised in that described catalyst is sulphur
Acid sodium.
A kind of electric massager high stability coating the most according to claim 1, it is characterised in that described synergist is two
Ethylamino-sulfur trifluoride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662447.4A CN106318044A (en) | 2016-08-12 | 2016-08-12 | High stability coating for electronic massager and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662447.4A CN106318044A (en) | 2016-08-12 | 2016-08-12 | High stability coating for electronic massager and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106318044A true CN106318044A (en) | 2017-01-11 |
Family
ID=57740281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610662447.4A Pending CN106318044A (en) | 2016-08-12 | 2016-08-12 | High stability coating for electronic massager and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106318044A (en) |
-
2016
- 2016-08-12 CN CN201610662447.4A patent/CN106318044A/en active Pending
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Application publication date: 20170111 |