CN105754200A - High-strength high-elasticity fiber reinforced POE (polyolefin elastomer) material and preparation method thereof - Google Patents
High-strength high-elasticity fiber reinforced POE (polyolefin elastomer) material and preparation method thereof Download PDFInfo
- Publication number
- CN105754200A CN105754200A CN201610139289.4A CN201610139289A CN105754200A CN 105754200 A CN105754200 A CN 105754200A CN 201610139289 A CN201610139289 A CN 201610139289A CN 105754200 A CN105754200 A CN 105754200A
- Authority
- CN
- China
- Prior art keywords
- poe
- fiber
- elasticity
- strength high
- dispersant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 57
- 239000000463 material Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 229920006124 polyolefin elastomer Polymers 0.000 title abstract 8
- 239000002270 dispersing agent Substances 0.000 claims abstract description 27
- 229920001778 nylon Polymers 0.000 claims abstract description 26
- 229920000728 polyester Polymers 0.000 claims abstract description 26
- 239000003963 antioxidant agent Substances 0.000 claims description 27
- 230000003078 antioxidant effect Effects 0.000 claims description 27
- 230000002787 reinforcement Effects 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- -1 photostabilizer Substances 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 1
- 241000283898 Ovis Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-strength high-elasticity fiber reinforced POE (polyolefin elastomer) material and a preparation method thereof.By adding both nylon fiber and polyester fiber, the POE material is imparted high strength and high elasticity as well as excellent light resistance; POE-g-MAH or POE-g-GMA compatilizer is added in order to improve bonding power between POE and fiber; a dispersant is added to promote dispersion of the fiber in base resin, a light resistant is added to light resistance of the POE material, and the high-strength high-elasticity fiber reinforced POE material of low cost is obtained accordingly.
Description
Technical field
The present invention relates to technical field of polymer materials, especially a kind of high-strength high-elasticity fiber reinforcement POE material and preparation method thereof.
Background technology
POE is a kind of ethylene octane copolymer, can be used as thermoplastic elastomer (TPE), can be used as again anti-impact modifier and the toughener of plastics, be widely used in modified toughened, the various fields such as electric wire is industrial, medical tool, household electrical appliance and packing film of automobile special material.But both needed high resiliency at some, and needing again the parts of high intensity, POE can only meet its high resiliency, and the nylon fiber that the present invention uses has superior elasticity, its elastic recovery rate can match in excellence or beauty Pilus Caprae seu Ovis, separately its tool rotproofness, it is not afraid of and damages by worms, be not afraid of mouldy advantage, but its light resistance is poor；And polyester fiber can be acidproof, chemical stability is high, and has good light fastness.The present invention is simultaneously introduced nylon fiber and polyester fiber, makes POE material have the light resistance of excellence while having high-strength high-elasticity.
Summary of the invention
It is an object of the invention to: a kind of high-strength high-elasticity fiber reinforcement POE material and preparation method thereof is provided, it can be obviously enhanced the adhesion between matrix resin POE and nylon fiber and polyester fiber, thus obtain the fiber reinforcement POE material with excellent properties, to overcome the deficiencies in the prior art.
The present invention is achieved in that high-strength high-elasticity fiber reinforcement POE material, calculate according to the mass fraction, including 40-70 part POE, 10-20 part nylon fiber, 10-20 part polyester fiber, 4-6 part compatilizer, 2-3 part photostabilizer, 0.4-0.6 part antioxidant and 0.8-1.2 part dispersant.
The a length of 4-12mm of described nylon fiber.
The a length of 4-12mm of described polyester fiber.
Described compatilizer is POE-g-MAH or POE-g-GMA.
Described antioxidant is antioxidant UV-531.
Described dispersant is dispersant A N923CP, and described photostabilizer is photostabilizer VK-TN01.
The preparation method of high-strength high-elasticity fiber reinforcement POE material, takes each component by above-mentioned parts by weight, comprises the steps:
1) POE and compatilizer are dried 5h in the baking oven of 50 DEG C, nylon fiber and polyester fiber are dried 5h in the baking oven of 80 DEG C；
2) by uniform to dried POE, compatilizer, nylon fiber, polyester fiber, photostabilizer, antioxidant and dispersant；
3) by step 2) in the material of mix homogeneously be 200 r/min with main-machine screw rotating speed; temperature is respectively 155 DEG C; 160 DEG C; 165 DEG C; the processing technique of 170 DEG C and 180 DEG C is extruded on parallel dual-screw extruding machine, then carries out cooling down, pelletizing obtains high-strength high-elasticity fiber reinforcement POE material.
Owing to have employed technique scheme, compared with prior art, the present invention is by being simultaneously introduced nylon fiber and polyester fiber, POE material is made while having high-strength high-elasticity, to have the light resistance of excellence, and in order to strengthen the cohesive force between POE and fiber, with the addition of POE-g-MAH or POE-g-GMA compatilizer, thus obtain the fiber reinforcement POE material of the high-strength high-elasticity of low cost.The present invention is simple, material source is extensive, with low cost, using effect is good.
Detailed description of the invention
Embodiments of the invention 1: high-strength high-elasticity fiber reinforcement POE material, calculate according to the mass fraction, including 60 parts of POE, 15 parts of nylon fibers, 15 parts of polyester fibers, 5 parts of compatilizers, 2 parts of photostabilizers, 0.5 part of antioxidant and 1 part of dispersant；The a length of 4mm of described nylon fiber；The a length of 4mm of described polyester fiber；Described compatilizer is POE-g-MAH；Described antioxidant is antioxidant UV-531；Described dispersant is dispersant A N923CP, and described photostabilizer is photostabilizer VK-TN01.
The preparation method of high-strength high-elasticity fiber reinforcement POE material, by above-mentioned parts by weight, comprises the steps: 1) POE and compatilizer are dried 5h, nylon fiber and polyester fiber in the baking oven of 50 DEG C in the baking oven of 80 DEG C, it are dried 5h；
2) by uniform to dried POE, compatilizer, nylon fiber, polyester fiber, photostabilizer, antioxidant and dispersant；
3) by step 2) in the material of mix homogeneously be 200 r/min with main-machine screw rotating speed; temperature is respectively 155 DEG C; 160 DEG C; 165 DEG C; the processing technique of 170 DEG C and 180 DEG C is extruded on parallel dual-screw extruding machine, then carries out cooling down, pelletizing obtains high-strength high-elasticity fiber reinforcement POE material.
Embodiments of the invention 2: high-strength high-elasticity fiber reinforcement POE material, calculate according to the mass fraction, including 40 parts of POE, 20 parts of nylon fibers, 10 parts of polyester fibers, 4 parts of compatilizers, 3 parts of photostabilizers, 0.6 part of antioxidant and 0.8 part of dispersant；The a length of 8mm of described nylon fiber；The a length of 8mm of described polyester fiber；Described compatilizer is POE-g-GMA；Described antioxidant is antioxidant UV-531；Described dispersant is dispersant A N923CP, and described photostabilizer is photostabilizer VK-TN01.
Preparation method is with embodiment 1.
Embodiments of the invention 3: high-strength high-elasticity fiber reinforcement POE material, calculate according to the mass fraction, including 70 parts of POE, 10 parts of nylon fibers, 20 parts of polyester fibers, 6 parts of compatilizers, 2 parts of photostabilizers, 0.4 part of antioxidant and 1.2 parts of dispersants；The a length of 12mm of described nylon fiber；The a length of 12mm of described polyester fiber；Described compatilizer is POE-g-MAH；Described antioxidant is antioxidant UV-531；Described dispersant is dispersant A N923CP, and described photostabilizer is photostabilizer VK-TN01.
Preparation method is with embodiment 1.
Comparative example 1: high-strength high-elasticity fiber reinforcement POE material, calculates according to the mass fraction, including 60 parts of POE, 15 parts of nylon fibers, 15 parts of polyester fibers, 2 parts of photostabilizers, 0.5 part of antioxidant and 1 part of dispersant；The a length of 4mm of described nylon fiber；The a length of 4mm of described polyester fiber；Described antioxidant is antioxidant UV-531；Described dispersant is dispersant A N923CP, and described photostabilizer is photostabilizer VK-TN01.
Preparation method is with embodiment 1.
Comparative example 2: high-strength high-elasticity fiber reinforcement POE material, calculates according to the mass fraction, including 40 parts of POE, 20 parts of nylon fibers, 10 parts of polyester fibers, 4 parts of compatilizers, 3 parts of photostabilizers, 0.6 part of antioxidant；The a length of 8mm of described nylon fiber；The a length of 8mm of described polyester fiber；Described compatilizer is POE-g-MAH；Described antioxidant is antioxidant UV-531；Described photostabilizer is photostabilizer VK-TN01.
Preparation method is with embodiment 1.
Comparative example 3: high-strength high-elasticity fiber reinforcement POE material, calculates according to the mass fraction, including 70 parts of POE, 6 parts of compatilizers, 2 parts of photostabilizers, 0.4 part of antioxidant and 1.2 parts of dispersants；Described compatilizer is POE-g-GMA；Described antioxidant is antioxidant UV-531；Described dispersant is dispersant A N923CP, and described photostabilizer is photostabilizer VK-TN01.
Preparation method is with embodiment 1.
Main performance is tested: the product produced makes standard testing batten according to standard, carries out every test, and its performance test results is as shown in table 1.
In order to verify that prepared by the present invention learns according to table 1, the present invention adds the POE material property of nylon fiber and polyester fiber and is greatly improved, and the fiber added is the longest, and hot strength and the bending strength of POE material are the highest；It addition, it is better than the POE material not adding compatilizer and dispersant to add the POE material combination property after compatilizer and dispersant.
It is to be appreciated that the invention is not limited in above-mentioned particular implementation, those skilled in the art can make various deformation or amendment within the scope of the claims, and this has no effect on the flesh and blood of the present invention.
Claims (7)
1. a high-strength high-elasticity fiber reinforcement POE material, it is characterized in that: calculate according to the mass fraction, including 40-70 part POE, 10-20 part nylon fiber, 10-20 part polyester fiber, 4-6 part compatilizer, 2-3 part photostabilizer, 0.4-0.6 part antioxidant and 0.8-1.2 part dispersant.
High-strength high-elasticity fiber reinforcement POE material the most according to claim 1, it is characterised in that: a length of 4-12mm of described nylon fiber.
High-strength high-elasticity fiber reinforcement POE material the most according to claim 1, it is characterised in that: a length of 4-12mm of described polyester fiber.
High-strength high-elasticity fiber reinforcement POE material the most according to claim 1, it is characterised in that: described compatilizer is POE-g-MAH or POE-g-GMA.
High-strength high-elasticity fiber reinforcement POE material the most according to claim 1, it is characterised in that: described antioxidant is antioxidant UV-531.
High-strength high-elasticity fiber reinforcement POE material the most according to claim 1, it is characterised in that: described dispersant is dispersant A N923CP, and described photostabilizer is photostabilizer VK-TN01.
7. the preparation method of a high-strength high-elasticity fiber reinforcement POE material as claimed in claim 1, it is characterised in that: take each component by above-mentioned parts by weight, comprise the steps:
1) POE and compatilizer are dried 5h in the baking oven of 50 DEG C, nylon fiber and polyester fiber are dried 5h in the baking oven of 80 DEG C；
2) by uniform to dried POE, compatilizer, nylon fiber, polyester fiber, photostabilizer, antioxidant and dispersant；
3) by step 2) in the material of mix homogeneously be 200 r/min with main-machine screw rotating speed; temperature is respectively 155 DEG C; 160 DEG C; 165 DEG C; the processing technique of 170 DEG C and 180 DEG C is extruded on parallel dual-screw extruding machine, then carries out cooling down, pelletizing obtains high-strength high-elasticity fiber reinforcement POE material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610139289.4A CN105754200A (en) | 2016-03-13 | 2016-03-13 | High-strength high-elasticity fiber reinforced POE (polyolefin elastomer) material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610139289.4A CN105754200A (en) | 2016-03-13 | 2016-03-13 | High-strength high-elasticity fiber reinforced POE (polyolefin elastomer) material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105754200A true CN105754200A (en) | 2016-07-13 |
Family
ID=56332955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610139289.4A Pending CN105754200A (en) | 2016-03-13 | 2016-03-13 | High-strength high-elasticity fiber reinforced POE (polyolefin elastomer) material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105754200A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922673A (en) * | 2019-12-13 | 2020-03-27 | 常州威材新材料科技有限公司 | Scratch-resistant POE/PA6 alloy composite material for cast film and preparation method thereof |
| CN111255788A (en) * | 2020-01-16 | 2020-06-09 | 芜湖强振汽车紧固件有限公司 | Transmission separation shifting fork supporting bolt with POE (polyolefin elastomer) ball head part and preparation method thereof |
| CN112590157A (en) * | 2020-11-05 | 2021-04-02 | 江苏虹驰家居科技有限公司 | POE material-based bionic silkworm cocoon structure processing technology |
| CN117445512A (en) * | 2023-10-24 | 2024-01-26 | 上海唐科新材料科技有限公司 | Composite recyclable ton bag material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585346A (en) * | 2012-02-29 | 2012-07-18 | 江苏技术师范学院 | Halogen-free flame-retardant POE (Polyolefin Elastomer) compound material and preparation method thereof |
| CN105019256A (en) * | 2015-08-13 | 2015-11-04 | 长沙五犇新材料科技有限公司 | Flame-retarding composite floor leather resisting abrasion and skid and manufacturing technology and application thereof |
-
2016
- 2016-03-13 CN CN201610139289.4A patent/CN105754200A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585346A (en) * | 2012-02-29 | 2012-07-18 | 江苏技术师范学院 | Halogen-free flame-retardant POE (Polyolefin Elastomer) compound material and preparation method thereof |
| CN105019256A (en) * | 2015-08-13 | 2015-11-04 | 长沙五犇新材料科技有限公司 | Flame-retarding composite floor leather resisting abrasion and skid and manufacturing technology and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 肖长发: "《化学纤维概论 第3版》", 30 June 2015, 中国纺织出版社 * |
| 郭葆青 等: "《纺织材料性能及识别》", 30 September 2011, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922673A (en) * | 2019-12-13 | 2020-03-27 | 常州威材新材料科技有限公司 | Scratch-resistant POE/PA6 alloy composite material for cast film and preparation method thereof |
| CN111255788A (en) * | 2020-01-16 | 2020-06-09 | 芜湖强振汽车紧固件有限公司 | Transmission separation shifting fork supporting bolt with POE (polyolefin elastomer) ball head part and preparation method thereof |
| CN112590157A (en) * | 2020-11-05 | 2021-04-02 | 江苏虹驰家居科技有限公司 | POE material-based bionic silkworm cocoon structure processing technology |
| CN117445512A (en) * | 2023-10-24 | 2024-01-26 | 上海唐科新材料科技有限公司 | Composite recyclable ton bag material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105754200A (en) | High-strength high-elasticity fiber reinforced POE (polyolefin elastomer) material and preparation method thereof | |
| CN103351592B (en) | Anti-aging PC-ABS polyblend | |
| CN108070231A (en) | Plant fiber enhancing lactic acid composite material and products thereof | |
| CN104292741A (en) | ABS (acrylonitrile butadiene styrene copolymers) composite material and preparation method thereof | |
| CN106751678A (en) | A kind of low smell, it is low distribute, fire retardation PC/ABS composite material and preparation method thereof | |
| CN107118435A (en) | Polypropylene blending modified material and preparation method thereof | |
| CN105778400A (en) | Reinforced durable ABS plastic | |
| CN103289183B (en) | A kind of hot RPP and preparation method thereof | |
| CN103509342A (en) | Glass fiber reinforced polyphenylene sulfide resin and preparation method thereof | |
| CN105820537A (en) | PC/ABS alloy material with high welding strength | |
| CN106147032A (en) | A kind of low-shrinkage modified polypropylene composite material and preparation method thereof | |
| CN109486164A (en) | A kind of polyphenylene oxide/polyphenylsulfone composite material and preparation method | |
| CN105778364A (en) | Thermoplastic elastomer backing plate film and preparation method thereof | |
| CN110982175A (en) | High-low temperature resistant polypropylene material and preparation method and application thereof | |
| CN103578683A (en) | Rubber magnetic strip used under low temperature and preparation method thereof | |
| CN110343329B (en) | Halogen-free flame-retardant polypropylene material and preparation method thereof | |
| CN107603170B (en) | High-performance PBT/ABS alloy material and preparation method thereof | |
| CN106398191A (en) | Halogen-free flame-retardant long glass fiber enhanced nylon 6T composite material and preparation method thereof | |
| CN106700253B (en) | A kind of low-contraction low-density PP material and preparation method thereof | |
| CN104530574A (en) | Polypropylene composition with stress cracking resistance and low temperature impact resistance and preparation method thereof | |
| CN109354777A (en) | Low warpage PP composite material and preparation method thereof | |
| CN103351573B (en) | Anti-aging resistant ABS-PVC plastic alloy | |
| CN106905610A (en) | A kind of preparation method for being applied to polyacrylic damage resistant agent | |
| CN109942961A (en) | A kind of method of pair of copolymer polypropylene performance enhancement | |
| CN106496780A (en) | Polypropylene material with high heat resistance and high mechanical property, preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160713 |
|
| RJ01 | Rejection of invention patent application after publication |