CN105294911A - Preparation method of styrene-butyl acrylate/montmorillonoid composite emulsion - Google Patents
Preparation method of styrene-butyl acrylate/montmorillonoid composite emulsion Download PDFInfo
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- CN105294911A CN105294911A CN201510856601.7A CN201510856601A CN105294911A CN 105294911 A CN105294911 A CN 105294911A CN 201510856601 A CN201510856601 A CN 201510856601A CN 105294911 A CN105294911 A CN 105294911A
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- styrene
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- acrylate
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- 239000000839 emulsion Substances 0.000 title claims abstract description 38
- 239000002131 composite material Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- TUZBYYLVVXPEMA-UHFFFAOYSA-N butyl prop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C=C TUZBYYLVVXPEMA-UHFFFAOYSA-N 0.000 title abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 60
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003999 initiator Substances 0.000 claims abstract description 20
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 19
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 238000004945 emulsification Methods 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 29
- 150000002148 esters Chemical class 0.000 claims description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 11
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 10
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 10
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 238000009413 insulation Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000004160 Ammonium persulphate Substances 0.000 claims description 5
- 239000004159 Potassium persulphate Substances 0.000 claims description 5
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 5
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 230000031709 bromination Effects 0.000 claims description 4
- 238000005893 bromination reaction Methods 0.000 claims description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- HQVFKSDWNYVAQD-UHFFFAOYSA-N n-hydroxyprop-2-enamide Chemical compound ONC(=O)C=C HQVFKSDWNYVAQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 229920000058 polyacrylate Polymers 0.000 abstract description 4
- 239000002689 soil Substances 0.000 abstract description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
Abstract
The invention discloses a preparation method of styrene-butyl acrylate/montmorillonoid composite emulsion. The preparation method comprises the steps of dissolving styrene, butyl acrylate, part of an emulsifier and initiator, Na-montmorillonite and a modifier into 40mL of water, then sequentially placing into a reactor for stirring, and performing pre-emulsification for 1h; then dropwise adding pre-emulsion into itaconic acid and the remaining emulsifer and initiator, heating up and reacting for 1h, and adjusting the pH by using weak aqua ammonia after cooling a discharged material, so as to obtain the styrene-butyl acrylate/montmorillonoid composite emulsion. According to the method, in-situ polymerization is adopted, through modifying montmorillonoid, the treated montmorillonoid has better affinity to styrene-butyl acrylate polymer emulsion, the waterproof and anti-soil performances, mechanical property and the like of the composite emulsion are improved, and better fire resistance is realized, and the composite emulsion has potential application valve in the field of fire-proof materials.
Description
Technical field
The invention belongs to building coating field, be specifically related to a kind of preparation method of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
Background technology
Styrene And Butyl-acrylate polymer emulsion is mainly used in rubber and paint field, have with low cost, production technique is simple, easy to use, the advantage such as non-toxic and safe, environmentally safe; But also there is the shortcoming cold-resistant, water-fast, thermotolerance is poor, limit its use range.Be compounded to form matrix material with inorganic mineral and polymkeric substance, the mechanical strength of material and other performance can be improved as electroconductibility, scale resistance etc.Polyalcohol intercalation layered silicate is a kind of effective ways of preparation nano composite material, wherein has most the layered silicate of using value to be polynite.Polynite is at occurring in nature aboundresources, cheap, and sheet interlayer contains a large amount of mineral ion (Na
+, Ca
2+deng), there is stronger ion-exchange capacity, but also make polynite present hydrophilic oleophobic property simultaneously, can not be well compatible with hydrophobic polymkeric substance, for its practical application brings larger difficulty.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion, the method adopts situ aggregation method, by carrying out modification or modification to polynite, the polynite after processing is made to have better affinity for Styrene And Butyl-acrylate polymer emulsion.
In order to achieve the above object, the technical scheme that the present invention takes is:
A preparation method for Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion, comprises the following steps:
(1) by 48-60 part vinylbenzene and 20-27.5 part Butyl acrylate, 1/3 compound emulsifying agent, 4/5 initiator, 1.44-4 part sodium-based montmorillonite, puts into reactor successively after 3.2-5.17 part properties-correcting agent is dissolved in 40mL water and stirs, pre-emulsification 1h, for subsequent use;
(2) 50mL water is added in the reactor, be heated to 70 ~ 80 DEG C, add 0.32-0.52 part methylene-succinic acid, remaining 2/3 compound emulsifying agent and 1/5 initiator, be warmed up to 85 DEG C, starts to drip pre-emulsion, time for adding controls to drip off at 1.5 ~ 2h, 90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
As specializing, described vinylbenzene and the mass ratio of butyl acrylate are (2 ~ 3): 1.
As specializing, the consumption of described sodium-based montmorillonite is 2% ~ 5% of vinylbenzene and butyl acrylate total amount.
As specializing, described emulsifying agent is sodium lauryl sulphate, polyoxyethylene nonylphenol ether, and wherein the mass ratio of sodium lauryl sulphate and polyoxyethylene nonylphenol ether is 2:1.
As specializing, described initiator is the one in ammonium persulphate, Potassium Persulphate.
As specializing, described properties-correcting agent is the one in N-hydroxyacrylamide, trolamine, bromination allyl group triethyl ammonium, and the consumption of properties-correcting agent is 4% ~ 6.5% of vinylbenzene and butyl acrylate total amount.
Beneficial effect of the present invention:
Adopt situ aggregation method, by carrying out modification or modification to polynite, the polynite after processing is made to have better affinity for Styrene And Butyl-acrylate polymer emulsion, improve the water proof anti-soil and mechanical property etc. of composite emulsion, and there is good flame retardant resistance, in fire-retardant material field, there is potential using value.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described.
Embodiment 1
By 52.5g vinylbenzene and 23g Butyl acrylate, 5mL compound emulsifying agent (0.5g sodium lauryl sulphate+0.25g polyoxyethylene nonylphenol ether is dissolved in 15mL deionized water), 8mL initiator (0.5g ammonium persulphate is dissolved in 10mL water), 2.27g sodium-based montmorillonite, 4.2gN-hydroxyacrylamide is put into reactor successively and is stirred after being dissolved in 40mL water, pre-emulsification 1h, for subsequent use.
Add 50mL water in the reactor, be heated to 70 ~ 80 DEG C, add methylene-succinic acid 0.42g, remaining 10mL compound emulsifying agent and 2mL initiator.Be warmed up to 85 DEG C, start to drip pre-emulsion, time for adding controls to drip off at 1.5h.90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
Embodiment 2
By 50g vinylbenzene and 20g Butyl acrylate, 5mL compound emulsifying agent (0.4g sodium lauryl sulphate+0.2g polyoxyethylene nonylphenol ether is dissolved in 15mL deionized water), 8mL initiator (0.4g Potassium Persulphate is dissolved in 10mL water), 1.75g sodium-based montmorillonite, 3.5g trolamine is put into reactor successively and is stirred after being dissolved in 40mL water, pre-emulsification 1h, for subsequent use.
Add 50mL water in the reactor, be heated to 70 ~ 80 DEG C, add methylene-succinic acid 0.35g, remaining 10mL compound emulsifying agent and 2mL initiator.Be warmed up to 85 DEG C, start to drip pre-emulsion, time for adding controls to drip off at 2h.90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
Embodiment 3
By 55g vinylbenzene and 27.5g Butyl acrylate, 5mL compound emulsifying agent (0.8g sodium lauryl sulphate+0.4g polyoxyethylene nonylphenol ether is dissolved in 15mL deionized water), 8mL initiator (0.6g ammonium persulphate is dissolved in 10mL water), 3.3g sodium-based montmorillonite, put into reactor successively after 4.95g bromination allyl group triethyl ammonium is dissolved in 40mL water to stir, pre-emulsification 1h, for subsequent use.
Add 50mL water in the reactor, be heated to 70 ~ 80 DEG C, add methylene-succinic acid 0.5g, remaining 10mL compound emulsifying agent and 2mL initiator.Be warmed up to 85 DEG C, start to drip pre-emulsion, time for adding controls to drip off at 1.5h.90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
Embodiment 4
By 58g vinylbenzene and 21.5g Butyl acrylate, 5mL compound emulsifying agent (0.6g sodium lauryl sulphate+0.3g polyoxyethylene nonylphenol ether is dissolved in 15mL deionized water), 8mL initiator (0.8g Potassium Persulphate is dissolved in 10mL water), 3.58g sodium-based montmorillonite, 5.17gN-hydroxyacrylamide is put into reactor successively and is stirred after being dissolved in 40mL water, pre-emulsification 1h, for subsequent use.
Add 50mL water in the reactor, be heated to 70 ~ 80 DEG C, add methylene-succinic acid 0.52g, remaining 10mL compound emulsifying agent and 2mL initiator.Be warmed up to 85 DEG C, start to drip pre-emulsion, time for adding controls to drip off at 2h.90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
Embodiment 5
By 48g vinylbenzene and 24g Butyl acrylate, 5mL compound emulsifying agent (0.3g sodium lauryl sulphate+0.15g polyoxyethylene nonylphenol ether is dissolved in 15mL deionized water), 8mL initiator (0.3g ammonium persulphate is dissolved in 10mL water), 1.44g sodium-based montmorillonite, put into reactor successively after 3.24g bromination allyl group triethyl ammonium is dissolved in 40mL water to stir, pre-emulsification 1h, for subsequent use.
Add 50mL water in the reactor, be heated to 70 ~ 80 DEG C, add methylene-succinic acid 0.32g, remaining 10mL compound emulsifying agent and 2mL initiator.Be warmed up to 85 DEG C, start to drip pre-emulsion, time for adding controls to drip off at 2h.90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
Embodiment 6
By 60g vinylbenzene and 20g Butyl acrylate, 5mL compound emulsifying agent (1.0g sodium lauryl sulphate+0.5g polyoxyethylene nonylphenol ether is dissolved in 15mL deionized water), 8mL initiator (1.0g Potassium Persulphate is dissolved in 10mL water), 4g sodium-based montmorillonite, 3.2g trolamine is put into reactor successively and is stirred after being dissolved in 40mL water, pre-emulsification 1h, for subsequent use.
Add 50mL water in the reactor, be heated to 70 ~ 80 DEG C, add methylene-succinic acid 0.32g, remaining 10mL compound emulsifying agent and 2mL initiator.Be warmed up to 85 DEG C, start to drip pre-emulsion, time for adding controls to drip off at 1.5h.90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
The performance of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion obtained for embodiment 1,2,3,4,5,6 tested, result is as shown in table 1 below.
Table 1
The above, it is only present pre-ferred embodiments, not technical scope of the present invention is imposed any restrictions, thus every above embodiment is done according to technical spirit of the present invention any trickle amendment, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (6)
1. a preparation method for Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion, is characterized in that comprising the following steps:
(1) by 48-60 part vinylbenzene and 20-27.5 part Butyl acrylate, 1/3 compound emulsifying agent, 4/5 initiator, 1.44-4 part sodium-based montmorillonite, puts into reactor successively after 3.2-5.17 part properties-correcting agent is dissolved in 40mL water and stirs, pre-emulsification 1h, for subsequent use;
(2) 50mL water is added in the reactor, be heated to 70 ~ 80 DEG C, add 0.32-0.52 part methylene-succinic acid, remaining 2/3 compound emulsifying agent and 1/5 initiator, be warmed up to 85 DEG C, starts to drip pre-emulsion, time for adding controls to drip off at 1.5 ~ 2h, 90 DEG C of insulation reaction 1h, regulate pH to be 7 ~ 8 with weak ammonia after discharging cooling, obtain Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion.
2. the preparation method of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion according to claim 1, is characterized in that: described vinylbenzene and the mass ratio of butyl acrylate are (2 ~ 3): 1.
3. the preparation method of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion according to claim 1, is characterized in that: the consumption of described sodium-based montmorillonite is 2% ~ 5% of vinylbenzene and butyl acrylate total amount.
4. the preparation method of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion according to claim 1, it is characterized in that: described emulsifying agent is sodium lauryl sulphate, polyoxyethylene nonylphenol ether, wherein the mass ratio of sodium lauryl sulphate and polyoxyethylene nonylphenol ether is 2:1.
5. the preparation method of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion according to claim 1, is characterized in that: described initiator is the one in ammonium persulphate, Potassium Persulphate.
6. the preparation method of Styrene And Butyl-acrylate/ester/montmorillonite composite emulsion according to claim 1, it is characterized in that: described properties-correcting agent is the one in N-hydroxyacrylamide, trolamine, bromination allyl group triethyl ammonium, and the consumption of properties-correcting agent is 4% ~ 6.5% of vinylbenzene and butyl acrylate total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510856601.7A CN105294911A (en) | 2015-11-30 | 2015-11-30 | Preparation method of styrene-butyl acrylate/montmorillonoid composite emulsion |
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|---|---|---|---|
| CN201510856601.7A CN105294911A (en) | 2015-11-30 | 2015-11-30 | Preparation method of styrene-butyl acrylate/montmorillonoid composite emulsion |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110342872A (en) * | 2019-07-09 | 2019-10-18 | 卓冠（江苏）新材料科技有限公司 | Flame-retarded light composite insulation boards and its processing method is blended in a kind of novel cement-based particle |
| CN111794012A (en) * | 2020-06-24 | 2020-10-20 | 杭州华旺新材料科技股份有限公司 | High-strength water-resistant flame-retardant plain colored paper and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1475509A (en) * | 2003-07-11 | 2004-02-18 | 中国科学院广州化学研究所 | Preparation Method of Polymer/Layered Silicate Nano-intercalation Composite |
| CN101033266A (en) * | 2007-04-13 | 2007-09-12 | 华南理工大学 | Polymer/organic montmorillonite nano composite flame-proof masterbatch, its preparing method and application |
| CN101381425A (en) * | 2008-09-16 | 2009-03-11 | 沈阳工业大学 | A kind of nano-montmorillonite composite latex for automobile interior blanket and preparation method thereof |
| CN102206395A (en) * | 2011-03-31 | 2011-10-05 | 广东工业大学 | Preparation method and application of nano-montmorillonite/polyacrylate composite material |
-
2015
- 2015-11-30 CN CN201510856601.7A patent/CN105294911A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1475509A (en) * | 2003-07-11 | 2004-02-18 | 中国科学院广州化学研究所 | Preparation Method of Polymer/Layered Silicate Nano-intercalation Composite |
| CN101033266A (en) * | 2007-04-13 | 2007-09-12 | 华南理工大学 | Polymer/organic montmorillonite nano composite flame-proof masterbatch, its preparing method and application |
| CN101381425A (en) * | 2008-09-16 | 2009-03-11 | 沈阳工业大学 | A kind of nano-montmorillonite composite latex for automobile interior blanket and preparation method thereof |
| CN102206395A (en) * | 2011-03-31 | 2011-10-05 | 广东工业大学 | Preparation method and application of nano-montmorillonite/polyacrylate composite material |
Non-Patent Citations (2)
| Title |
|---|
| 甘春芳等: "原位乳液聚合法制备聚苯乙烯-丙烯酸酯/纳米蒙脱土复合乳液", 《化工技术与开发》 * |
| 葛金龙等: "苯乙烯-丙烯酸丁酯／蒙脱土复合乳液制备及涂层耐蚀性研究", 《化工新型材料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110342872A (en) * | 2019-07-09 | 2019-10-18 | 卓冠（江苏）新材料科技有限公司 | Flame-retarded light composite insulation boards and its processing method is blended in a kind of novel cement-based particle |
| CN111794012A (en) * | 2020-06-24 | 2020-10-20 | 杭州华旺新材料科技股份有限公司 | High-strength water-resistant flame-retardant plain colored paper and preparation method thereof |
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Application publication date: 20160203 |