CN104328259B - GCr15 high carbon chromium bearing steel on-line rapid spheroidizing annealing technology - Google Patents
GCr15 high carbon chromium bearing steel on-line rapid spheroidizing annealing technology Download PDFInfo
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 23
- 239000010959 steel Substances 0.000 title claims abstract description 23
- 238000000137 annealing Methods 0.000 title claims abstract description 21
- 238000005516 engineering process Methods 0.000 title description 2
- FXNGWBDIVIGISM-UHFFFAOYSA-N methylidynechromium Chemical group [Cr]#[C] FXNGWBDIVIGISM-UHFFFAOYSA-N 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract description 26
- 150000001247 metal acetylides Chemical class 0.000 claims abstract description 19
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 17
- 239000011651 chromium Substances 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 13
- 230000006835 compression Effects 0.000 claims abstract description 9
- 238000007906 compression Methods 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 229910001566 austenite Inorganic materials 0.000 claims description 4
- 238000010583 slow cooling Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 230000000717 retained effect Effects 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 5
- 239000011159 matrix material Substances 0.000 abstract description 4
- 238000004321 preservation Methods 0.000 abstract description 4
- 238000010791 quenching Methods 0.000 abstract description 3
- 229910000859 α-Fe Inorganic materials 0.000 abstract description 3
- 230000000171 quenching effect Effects 0.000 abstract description 2
- 238000005496 tempering Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- 238000005275 alloying Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
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Abstract
一种GCr15高碳铬轴承钢在线快速球化退火工艺,属材料工程领域。所述GCr15轴承钢按质量比组成为:C:0.95~1.05%,Cr:1.30~1.65%,Mn:0.20~0.40%,Si:0.15~0.35%,S≤0.015%,P≤0.02%,余量为Fe。工艺步骤如下:随炉升温至1150~1250℃保温;快速降温至920~960℃的范围内施加应力发生40~60%压缩变形;接着快速降温至740~780℃,发生30~50%压缩变形;再以0.3~0.5℃/s的冷速缓慢冷却至500~600℃范围;最后快冷至室温。本发明工艺简单,热变形后,组织为铁素体基体上弥散分布着细小、均匀的球状碳化物,适合于后续的加工,为最终的淬火+回火做好组织准备。
An online rapid spheroidizing annealing process for GCr15 high-carbon chromium bearing steel belongs to the field of material engineering. The GCr15 bearing steel is composed by mass ratio: C: 0.95-1.05%, Cr: 1.30-1.65%, Mn: 0.20-0.40%, Si: 0.15-0.35%, S≤0.015%, P≤0.02%, remainder The amount is Fe. The process steps are as follows: heating up to 1150-1250°C with the furnace for heat preservation; rapid cooling to 920-960°C and 40-60% compression deformation due to applied stress; then rapid cooling to 740-780°C, 30-50% compression deformation ; Then slowly cool to the range of 500-600°C at a cooling rate of 0.3-0.5°C/s; finally quickly cool to room temperature. The process of the invention is simple, and after thermal deformation, the microstructure is fine and uniform spherical carbides dispersed on the ferrite matrix, which is suitable for subsequent processing and prepares microstructure for final quenching+tempering.
Description
技术领域:Technical field:
本发明属于轧钢领域,涉及一种GCr15高碳铬轴承钢热轧棒线材的在线快速球化退火工艺。The invention belongs to the field of steel rolling and relates to an online rapid spheroidizing annealing process for hot-rolled rods and wires of GCr15 high-carbon chromium bearing steel.
背景技术:Background technique:
球化退火的目的是得到球化组织,这种组织具有最佳塑形和最低硬度,钢铁材料经过球化退火处理,可以对碳化物的分布和形态进行改性,降低材料硬度,提高材料塑形,降低材料的变形抗力,提高可加工性,为后续热处理做好组织准备。The purpose of spheroidizing annealing is to obtain spheroidized structure, which has the best shape and the lowest hardness. After spheroidizing annealing, the distribution and shape of carbides can be modified to reduce the hardness of the material and improve the plasticity of the material. shape, reduce the deformation resistance of the material, improve the machinability, and prepare the tissue for subsequent heat treatment.
GCr15钢是一种应用最广泛的高碳铬轴承钢,主要用于制作各种轴承套圈和滚动体,有时也用来制造工具,通常要求具有高的强度、高的弹性极限和高的耐磨性等。GCr15轴承钢加工性中等,切削性能一般,容易淬火开裂和形成回火脆性,所以棒线材热轧后,后续的塑性加工、淬火等都需要经过球化退火处理,从而软化材料,降低变形抗力。另外,改善轴承钢碳化物的形态和分布也可延长GCr15钢制轴承的使用寿命,球化退火工艺恰恰起到了使珠光体中的片层状碳化物熔断球化的作用。人们对球化退火进行了大量的研究,现有的球化退火处理往往周期长,要消耗大量的能源和资源,还污染环境。如传统的球化退火工艺是在略高于的温度保温后随炉缓慢冷却至650℃以下出炉空冷。该工艺处理时间长(20h以上),且退火后碳化物颗粒不均匀,影响以后的冷加工及最终热处理的组织和性能。为此,提出一种新的利用余热进行在线快速球化退火处理工艺很有必要。GCr15 steel is the most widely used high-carbon chromium bearing steel. It is mainly used to make various bearing rings and rolling elements, and sometimes used to make tools. It usually requires high strength, high elastic limit and high durability. Grinding etc. GCr15 bearing steel has moderate machinability, average cutting performance, and is easy to quench and crack and form temper brittleness. Therefore, after the rod and wire are hot-rolled, the subsequent plastic processing and quenching need to undergo spheroidizing annealing to soften the material and reduce deformation resistance. In addition, improving the shape and distribution of carbides in bearing steel can also prolong the service life of GCr15 steel bearings. The spheroidizing annealing process just plays the role of melting and spheroidizing the lamellar carbides in pearlite. People have done a lot of research on spheroidizing annealing, but the existing spheroidizing annealing treatment often takes a long period, consumes a lot of energy and resources, and pollutes the environment. For example, the traditional spheroidizing annealing process is slightly higher than After heat preservation, it is slowly cooled to below 650°C with the furnace and air-cooled. The processing time of this process is long (more than 20h), and the carbide particles are not uniform after annealing, which affects the structure and performance of the subsequent cold working and final heat treatment. Therefore, it is necessary to propose a new on-line rapid spheroidizing annealing process using waste heat.
发明内容:Invention content:
本发明要解决的技术问题是提供一种GCr15高碳铬轴承钢在线快速球化退火工艺,该工艺流程简单,效率高,节省能源和资源,经过该球化退火工艺处理的GCr15轴承钢热轧棒线材的退火硬度和球化组织比例得到明显改善,且球状碳化物分布均匀。The technical problem to be solved by the present invention is to provide an online rapid spheroidizing annealing process for GCr15 high-carbon chromium bearing steel. The process flow is simple, the efficiency is high, and energy and resources are saved. The annealed hardness and spheroidized structure ratio of rods and wires are significantly improved, and the spherical carbides are evenly distributed.
为解决上述技术问题,本发明的技术方案如下:In order to solve the problems of the technologies described above, the technical solution of the present invention is as follows:
一种GCr15高碳铬轴承钢在线快速球化退火工艺,所述GCr15轴承钢成分按质量比组成为:C:0.95%~1.05%,Cr:1.30%~1.65%,Mn:0.20%~0.40%,Si:0.15%~0.35%,S≤0.015%,P≤0.02%,余量为Fe。An online rapid spheroidizing annealing process for GCr15 high-carbon chromium bearing steel. The components of the GCr15 bearing steel are composed of: C: 0.95% to 1.05%, Cr: 1.30% to 1.65%, and Mn: 0.20% to 0.40%. , Si: 0.15% to 0.35%, S≤0.015%, P≤0.02%, and the balance is Fe.
具体工艺步骤如下:The specific process steps are as follows:
以10℃/s的加热速率升温至1150~1250℃,在此温度下进行高温保温60~120min;Raise the temperature to 1150-1250°C at a heating rate of 10°C/s, and keep the temperature at this temperature for 60-120 minutes;
快速降温至920~960℃后施加应力发生40~60%压缩变形,细化晶粒;After rapid cooling to 920-960°C, 40-60% compression deformation occurs when the stress is applied, and the grains are refined;
接着快速降温至740~780℃,施加应力发生30~50%压缩变形,使先共析碳化物破碎和残留奥氏体发生变形,有利于球状碳化物形成;Then rapidly cool down to 740-780°C, and 30-50% compression deformation occurs when the stress is applied, so that the pro-eutectoid carbides are broken and the retained austenite is deformed, which is conducive to the formation of spherical carbides;
再以0.3~0.5℃/s的冷速缓慢冷却至500~600℃,在不影响生产效率的情况下,增加球化碳化物量。Then slowly cool to 500-600°C at a cooling rate of 0.3-0.5°C/s to increase the amount of spheroidized carbides without affecting production efficiency.
最后快冷至室温。Finally cool to room temperature quickly.
由上述技术方案实施的GCr15高碳铬轴承钢在线快速球化退火工艺可以通过热变形驱动力和余热,实现碳化物的在线球化,大大缩短球化退火周期。球化组织为铁素体基体上弥散分布着球状碳化物颗粒,硬度为180~200HB。本发明工艺流程简单,易于实现,对设备要求不高,成本较低,大大缩短生产周期。The online rapid spheroidizing annealing process of GCr15 high-carbon chromium bearing steel implemented by the above technical scheme can realize the online spheroidizing of carbides through thermal deformation driving force and waste heat, and greatly shorten the spheroidizing annealing cycle. The spheroidized structure is that spherical carbide particles are dispersed on the ferrite matrix, and the hardness is 180-200HB. The technical process of the invention is simple, easy to implement, low in equipment requirements, low in cost, and greatly shortens the production cycle.
附图说明:Description of drawings:
图1为本发明所述工艺的工艺曲线示意图。Fig. 1 is a schematic diagram of the process curve of the process of the present invention.
图2为经本发明所述工艺处理后的试样金相组织图。Fig. 2 is the metallographic structure diagram of the sample after being processed by the process of the present invention.
具体实施方式:detailed description:
下面通过具体实例,结合附图,对本发明的内容进一步具体说明。如图1所示的一种GCr15高碳铬轴承钢在线快速球化退火工艺,处理后热轧件的显微组织为铁素体基体上弥散分布着细小、均匀的球状碳化物。The content of the present invention will be further specifically described below through specific examples in conjunction with the accompanying drawings. As shown in Figure 1, a GCr15 high-carbon chromium bearing steel online rapid spheroidizing annealing process, the microstructure of the hot-rolled piece after treatment is fine and uniform spherical carbides dispersed on the ferrite matrix.
将GCr15高碳铬轴承钢通过在线快速球化退火工艺处理,具体包括以下升温保温、两步快速降温加变形、缓冷、快速冷却几个步骤:The GCr15 high-carbon chromium bearing steel is processed through an online rapid spheroidizing annealing process, which specifically includes the following steps of heating and heat preservation, two-step rapid cooling and deformation, slow cooling, and rapid cooling:
1、升温保温。将GCr15高碳铬轴承钢以10℃/s的加热速率升温至1170℃,在此温度下进行高温保温80min。GCr15高碳铬轴承钢在1170℃进行高温保温能够保证碳化物的熔解和合金元素的再分配。1. Heat up and keep warm. The GCr15 high-carbon chromium bearing steel was heated up to 1170°C at a heating rate of 10°C/s, and held at this temperature for 80 minutes. GCr15 high-carbon chromium bearing steel at 1170°C for high temperature insulation can ensure the melting of carbides and the redistribution of alloying elements.
2、快速冷却加变形。GCr15高碳铬轴承钢在1170℃高温保温后快速降温至920~960℃后施加应力发生50%压缩变形,在该温度区间变形能通过动态再结晶细化奥氏体晶粒,还能抑制晶粒的过分长大,避免出现晶界面积减小,可以增强碳化物的分散程度;接着快速降温至740~780℃,发生30%压缩变形,使先共析碳化物受到变形作用破碎和残留奥氏体发生变形,有利于球状碳化物形成,少部分碳化物组织可以直接断裂而形成颗粒状碳化物。2. Rapid cooling and deformation. GCr15 high-carbon chromium bearing steel is rapidly cooled to 920-960°C after heat preservation at 1170°C, and then 50% of the compression deformation occurs when the stress is applied. The deformation in this temperature range can refine the austenite grains through dynamic recrystallization, and can also inhibit the grain size. The excessive growth of the grains avoids the reduction of the grain boundary area, which can enhance the dispersion of the carbides; then rapidly cools to 740-780 ° C, and 30% compression deformation occurs, causing the pro-eutectoid carbides to be deformed and crushed and retained. The deformation of the tentenite is conducive to the formation of spherical carbides, and a small part of the carbide structure can be directly broken to form granular carbides.
3、缓冷、快冷。GCr15高碳铬轴承钢经过两次快冷变形后再缓慢冷却至550℃,在该温度范围缓慢冷却过程中,可以降低工件的出炉温度,减小热应力。另外,在该温度范围,碳化物组织可以在线缺陷密度高的位置析出,在部分区域内形成弥散分布的颗粒状碳化物,最终形成球化组织,且形成的碳化物颗粒尺寸细小,外形较为圆整均匀,分布弥散;最后快冷至室温。3. Slow cooling and quick cooling. GCr15 high-carbon chromium bearing steel undergoes two rapid cooling deformations and then slowly cools to 550°C. During the slow cooling process in this temperature range, the furnace temperature of the workpiece can be reduced and the thermal stress can be reduced. In addition, in this temperature range, the carbide structure can be precipitated at the position where the line defect density is high, forming dispersed granular carbides in some areas, and finally forming a spheroidized structure, and the formed carbide particles are small in size and relatively round in shape Evenly, the distribution is dispersed; finally cool to room temperature quickly.
本发明提供的一种GCr15高碳铬轴承钢在线快速球化退火工艺,工艺的关键是选择合适的加热温度、变形温度及变形量和冷却速率,该工艺可以大大缩短球化退火周期,获得铁素体基体上弥散分布着细、小、匀、圆的碳化物颗粒的组织,硬度为180~200HB。本发明能够保证被处理工件具有良好的塑形加工性和切削性能、从而提高产品的质量和使用性能。The present invention provides an online rapid spheroidizing annealing process for GCr15 high-carbon chromium bearing steel. The key to the process is to select a suitable heating temperature, deformation temperature, deformation amount and cooling rate. This process can greatly shorten the spheroidizing annealing cycle and obtain iron The structure of fine, small, uniform and round carbide particles dispersed on the body matrix, with a hardness of 180-200HB. The invention can ensure that the workpiece to be processed has good shaping processability and cutting performance, thereby improving the quality and service performance of the product.
以上所述,仅为本发明较佳的具体实施方式,本发明的保护范围并不仅限于此,因此任何依据本发明范围所作的同等替换或改变,都在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited thereto. Therefore, any equivalent replacement or change made according to the scope of the present invention is within the protection scope of the present invention.
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CN102433502B (en) * | 2011-12-23 | 2013-07-17 | 中冶南方(武汉)威仕工业炉有限公司 | Spheroidized annealing technology for GCr15 bearing steel |
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