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CN104130032B - A kind of manufacture method of glazed tile and products thereof - Google Patents

A kind of manufacture method of glazed tile and products thereof Download PDF

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Publication number
CN104130032B
CN104130032B CN201410377858.XA CN201410377858A CN104130032B CN 104130032 B CN104130032 B CN 104130032B CN 201410377858 A CN201410377858 A CN 201410377858A CN 104130032 B CN104130032 B CN 104130032B
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glaze
adobe
layer
manufacture method
glazed tile
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CN104130032A (en
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王华明
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Fengcheng Dongpeng Ceramic Co., Ltd.
Foshan Dongpeng Ceramic Co Ltd
Guangdong Dongpeng Holdings Co Ltd
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FENGCHENG DONGPENG CERAMIC Co Ltd
Foshan Dongpeng Ceramic Co Ltd
Guangdong Dongpeng Holdings Co Ltd
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Publication of CN104130032A publication Critical patent/CN104130032A/en
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Abstract

A kind of manufacture method of glazed tile and products thereof, method comprises the following steps:A, compacting forms adobe after feed proportioning ball milling being carried out into mist projection granulating, and ground-coat enamel is applied in the adobe after drying;B, stamp and after drying in the adobe after the step A, applies protection glaze;C, biscuiting;D, last layer clear frit is applied again in the adobe after the step C, then dry;E, after after the adobe kiln-firing after the step D non-resilient module being used to carry out rubbing down, packaging and storage.Product after the firing of the present invention and because the protection glaze layer in printed layer and transparent glazed thickness are thicker and smooth thus can be using non-resilient module progress rubbing down so as to ensure that the super gentle mirror effect on its surface.

Description

A kind of manufacture method of glazed tile and products thereof
Technical field
The present invention relates to Ceramic Tiles manufacturing field, more particularly, to a kind of manufacture method of glazed tile and products thereof.
Background technology
Glazed tile is also Full-glazed tile, is a kind of architectural pottery product emerging in recent years, and it has gathered polished bricks, modelled after an antique The advantage of three kinds of brick, ceramics products, product release the implicit property of glazed tile cloudy colour half-light completely, solve half throwing brick and easily hide dirt The defects of, possess glossiness, the porcelain hardness of polished bricks, while the high imitation fruit of the glaze paint for also possessing Antique Imitation Tiles, and ceramics The abundant printing effect of glaze paint.Existing glazed tile is that to apply on decorative layer 0.5~1.5mm after printed decoration layer in adobe saturating After bright glaze layer is fired, formed through elastic module rubbing down.Because transparent glaze layer is very thin, and use elastic module so that glazed layer with Modular surface contact is not complete, brick face waveform is produced, in overall paving in use, beautiful decoration and associative perception can be influenceed.
Patent No. CN201310137879.X discloses a kind of production for the super flat Full-glazed tile for adding transparent microcrystal fine powder Technique, comprise the following steps:Make base substrate, dedusting, water spray, leaching ground-coat enamel, stamp, print protection glaze, burn till brick body, polishing, waxing, Pack, obtain finished product, wherein, transparent microcrystal is added to brick body after the print protection glaze step and before burning till step Fine powder;The transparent microcrystal fine powder is printed onto in the form of powdered on brick body surface, and it is thin to form transparent microcrystal on brick body surface Bisque;Or the transparent microcrystal fine powder is mixed with glue and added in the form of starchy on brick body surface.Because glazed tile with The main distinction of Polished crystal tile is that the transparent glaze layer on surface is formed by being fired after micro-crystal powder cloth, or is printed by transparent glaze layer Fire and form after brush, such as use transparent microcrystal fine powder to be printed onto in the form of powdered on brick body surface, then referred to as Polished crystal tile, It is then glazed tile not to be, mixes with glue such as by transparent microcrystal fine powder and is added in the form of starchy on brick body surface, although It can be carried out by drenching the form of glaze, but crystallite fine powder can not be dissolved completely in water, or adobe surface is present in graininess, Thus it is equal to Polished crystal tile.
The content of the invention
It is an object of the invention to propose a kind of manufacture method of glazed tile, it can solve the problem that glazed tile surface wave shape wave Problem.
To use following technical scheme up to this purpose, the present invention:
A kind of manufacture method of glazed tile, step include successively:
A, ceramic powder is suppressed to form adobe, controls adobe temperature to apply bottom in the adobe at 65-75 DEG C after drying Glaze;
B, the stamp and after drying on the ground-coat enamel, control adobe temperature applies protection glaze more than 50 DEG C;
C, the biscuiting at 800-950 DEG C;
D, the adobe temperature is controlled to apply last layer clear frit more than 70 DEG C, then dry;
E, rubbing down is carried out after firing using non-resilient module.
The glaze volume for applying ground-coat enamel in the step A is 300-400g/m2
The stamp in the step B includes the one or more in screen printing, roller printing, inkjet printing stamp Combination.
The softening temperature of the protection glaze is 1070-1080 DEG C, and the softening temperature of the clear frit is 1100-1120 DEG C.
The glaze volume for applying protection glaze in the step B is 300-350g/m2
The glaze volume for applying clear frit in the step D is 1000-1050g/m2
Compared with prior art, protection glaze of the invention has the big characteristic of high temperature viscosity, and bottom gas can be prevented to arrange Go out, so as to solve the defects of glaze paint pin hole recessed glaze, glaze is preferably absorbed by biscuiting adobe glaze paint and reduces glaze layer gas Bubble, moisture organic matter volatilizees during biscuiting, and protection glaze softening range is 10 DEG C, relatively transparent glaze softening range 20 It is DEG C narrow, it can melt completely faster, and melted prior to clear frit, compacting is played to bottom gas in sintering procedure and is made With, avoid base substrate gas evaporation formed stomata;And base substrate moisture is reduced, cracked even prevented also from sintering process Fried base;Brick is more abundant in face of the absorption of glaze during leaching clear frit in addition, the recessed glaze of glaze layer can be also reduced, so as to solve serial life Production. art stability problem, and ensure that the smooth of glaze paint, the product after firing and due to the protection glaze layer in printed layer It is thicker and smooth with transparent glazed thickness thus non-resilient module can be used to carry out rubbing down so as to ensure that the super flat of its surface And mirror effect.
It is another object of the present invention to propose a kind of glazed tile manufactured by the above method, it is from bottom to top wrapped successively Include bottom base layer printed layer, protection glaze layer, transparent glaze layer.
The bottom base thickness degree is 6-9mm, and the printed layer thickness is to be less than 0.1mm, the protection glazed thickness 0.1-0.2mmmm, the transparent glazed thickness are 0.8-1.0mm.
Brief description of the drawings
Fig. 1 is the structure chart of the glazed tile of one of embodiment of the present invention.
Wherein:Bottom base layer 1, printed layer 2, protection glaze layer 3, transparent glaze layer 4.
Embodiment
Technical scheme is further illustrated below by embodiment.Its glaze of embodiments of the invention Use commercially available Dow company glaze.
Embodiment 1
As shown in figure 1, a kind of glazed tile of the present embodiment, it from bottom to top includes bottom base layer 1, printed layer 2, protection successively Glaze layer 3 and transparent glaze layer 4, its thickness of midsole base layer 1 are 8.5mm, and printed layer thickness is 0.05mm, and protection glazed thickness is 0.2mm, transparent glazed thickness are 0.8mm.
The glazed tile manufacture method that specification as described above is 1000*1000mm, step include successively:
A, ceramic powder is suppressed to form adobe, control adobe temperature applies 380g bottoms at 65 DEG C in the adobe after drying Glaze forms bottom base layer 1;
B, printed layer 2 is formed after on the bottom base layer 1 after the step A by screen printing and drying, controls brick Base temperature applies protection glaze 350g and forms protection glaze layer 3, the softening temperature for protecting glaze is 1070 DEG C, chemical composition Si at 55 DEG C: 70%, Al:13.7%, Ca:12.5%, Mg:1.24%, K:0.5%, Na:5.8%;
C, adobe enters kiln biscuiting at 900 DEG C;
D, control adobe temperature to apply the clear frit 1000g that one layer of softening temperature is 1100 DEG C again at 75 DEG C, then dry;
E, the adobe after the step D is entered after carrying out rubbing down using non-resilient module after kiln is fired at 1200 DEG C, Packaging and storage.
Protection glaze in the present embodiment has the big characteristic of high temperature viscosity, bottom gas can be prevented to discharge, so as to solve The defects of glaze paint pin hole recessed glaze, glaze is preferably absorbed by biscuiting adobe glaze paint and reduces glaze layer bubble, the mistake of biscuiting Moisture organic matter is volatilized in journey, and protection glaze softening temperature is low, is first melted in sintering procedure, and compacting is played to bottom gas and is made With, avoid base substrate gas evaporation formed stomata;And base substrate moisture is reduced, cracked even prevented also from sintering process Fried base;Brick is more abundant in face of the absorption of glaze during leaching clear frit in addition, the recessed glaze of glaze layer can be also reduced, so as to solve serial life Production. art stability problem, and ensure that the smooth of glaze paint, the product after firing and due to the protection glaze layer in printed layer It is thicker and smooth with transparent glazed thickness thus non-resilient module can be used to carry out rubbing down so as to ensure that the super flat of its surface And mirror effect.
Embodiment 2
As shown in figure 1, a kind of glazed tile of the present embodiment, it from bottom to top includes bottom base layer 1, printed layer 2, protection successively Glaze layer 3 and transparent glaze layer 4, its thickness of midsole base layer 1 are 6mm, and printed layer thickness is 0.08mm, and protection glazed thickness is 0.1mm, Transparent glazed thickness is 1.0mm.
The glazed tile manufacture method that specification as described above is 1000*1000mm, step include successively:
A, will feed proportioning ball milling carry out mist projection granulating after compacting form adobe, controlled after drying adobe temperature 75 DEG C 300g ground-coat enamels are applied in the adobe and form bottom base layer 1;
B, printed layer 2, control are formed by inkjet printing stamp on the bottom base layer 1 after the step A and after drying Brickmaking base temperature applies protection glaze 300g and forms protection glaze layer 3, the chemical composition for protecting glaze is Si at 60 DEG C:58%, Al:13%, Ca:12%, Mg:1.2%, K:0.6%, Na:6%, softening temperature is 1080 DEG C;
C, the adobe after the step B is entered into kiln biscuiting at 950 DEG C;
D, control adobe temperature to apply the clear frit 1050g that one layer of softening temperature is 1120 DEG C again at 78 degree, then dry;
E, the adobe after the step D is entered after carrying out rubbing down using non-resilient module after kiln is fired at 1200 DEG C, Packaging and storage.
Protection glaze in the present embodiment has the big characteristic of high temperature viscosity, bottom gas can be prevented to discharge, so as to solve The defects of glaze paint pin hole recessed glaze, glaze is preferably absorbed by biscuiting adobe glaze paint and reduces glaze layer bubble, the mistake of biscuiting Moisture organic matter is volatilized in journey, and protection glaze softening temperature is low, is first melted in sintering procedure, and compacting is played to bottom gas and is made With, avoid base substrate gas evaporation formed stomata;And base substrate moisture is reduced, cracked even prevented also from sintering process Fried base;Brick is more abundant in face of the absorption of glaze during leaching clear frit in addition, the recessed glaze of glaze layer can be also reduced, so as to solve serial life Production. art stability problem, and ensure that the smooth of glaze paint.
Embodiment 3
As shown in figure 1, a kind of glazed tile of the present embodiment, it from bottom to top includes bottom base layer 1, printed layer 2, protection successively Glaze layer 3 and transparent glaze layer 4, its thickness of midsole base layer 1 are 9mm, and printed layer thickness is 0.06mm, and protection glazed thickness is 0.15mm, transparent glazed thickness are 0.9mm.
The glazed tile manufacture method that specification as described above is 1000*1000mm, step include successively:
A, will feed proportioning ball milling carry out mist projection granulating after compacting form adobe, controlled after drying adobe temperature 70 DEG C 400g ground-coat enamels are applied in the adobe and form bottom base layer 1;
B, printed layer 2 is formed after on the bottom base layer 1 after the step A by roller printing and drying, controls brick Base temperature applies protection glaze 320g and forms protection glaze layer 3, the chemical composition for protecting glaze is Si at 55 DEG C:65%, Al:14%, Ca: 13%, Mg:1.3%, K:0.2%, Na:5.5%, softening temperature is 1070 DEG C;
C, the adobe after the step B is entered into kiln biscuiting at 850 DEG C;
D, control adobe temperature to apply the clear frit 1030g that one layer of softening temperature is 1110 DEG C again at 75 degree, then dry;
E, the adobe after the step D is entered after carrying out rubbing down using non-resilient module after kiln is fired at 1250 DEG C, Packaging and storage.
Protection glaze in the present embodiment has the big characteristic of high temperature viscosity, bottom gas can be prevented to discharge, so as to solve The defects of glaze paint pin hole recessed glaze, glaze is preferably absorbed by biscuiting adobe glaze paint and reduces glaze layer bubble, the mistake of biscuiting Moisture organic matter is volatilized in journey, and protection glaze softening temperature is low, is first melted in sintering procedure, and compacting is played to bottom gas and is made With, avoid base substrate gas evaporation formed stomata;And base substrate moisture is reduced, cracked even prevented also from sintering process Fried base;Brick is more abundant in face of the absorption of glaze during leaching clear frit in addition, the recessed glaze of glaze layer can be also reduced, so as to solve serial life Production. art stability problem, and ensure that the smooth of glaze paint.
Embodiment 4
As shown in figure 1, a kind of glazed tile of the present embodiment, it from bottom to top includes bottom base layer 1, printed layer 2, protection successively Glaze layer 3 and transparent glaze layer 4, its thickness of midsole base layer 1 are 7.8mm, and the thickness of printed layer 2 is 0.03mm, and the protection thickness of glaze layer 3 is 0.18mm, the transparent thickness of glaze layer 4 are 0.8mm.
The glazed tile manufacture method that specification as described above is 1000*1000mm, step include successively:
A, will feed proportioning ball milling carry out mist projection granulating after compacting form adobe, controlled after drying adobe temperature 70 DEG C 370g ground-coat enamels are applied in the adobe and form bottom base layer 1;
B, formed by inkjet printing stamp and roller printing on the bottom base layer 1 after the step A and after drying Printed layer 2, control adobe temperature apply protection glaze 340g and form protection glaze layer 3, the chemical composition for protecting glaze is Si at 55 DEG C: 60%, Al13.6%, Ca:12.6%, Mg:1.25%, K:0.4%, Na:5.8%, softening temperature is 1075 DEG C;
C, the adobe after the step B is entered into kiln biscuiting at 880 DEG C;
D, control adobe temperature to apply the clear frit 1010g that one layer of softening temperature is 1105 DEG C again at 75 DEG C, then dry;
E, the adobe after the step D is entered after carrying out rubbing down using non-resilient module after kiln is fired at 1250 DEG C, Packaging and storage.
Protection glaze in the present embodiment has the big characteristic of high temperature viscosity, bottom gas can be prevented to discharge, so as to solve The defects of glaze paint pin hole recessed glaze, glaze is preferably absorbed by biscuiting adobe glaze paint and reduces glaze layer bubble, the mistake of biscuiting Moisture organic matter is volatilized in journey, and protection glaze softening temperature is low, is first melted in sintering procedure, and compacting is played to bottom gas and is made With, avoid base substrate gas evaporation formed stomata;And base substrate moisture is reduced, cracked even prevented also from sintering process Fried base;Brick is more abundant in face of the absorption of glaze during leaching clear frit in addition, the recessed glaze of glaze layer can be also reduced, so as to solve serial life Production. art stability problem, and the smooth of glaze paint is ensure that, and non-resilient module can be used to carry out rubbing down, surfacing Degree is high.
Embodiment 5:
A kind of Ceramic Tiles of the present embodiment, it includes bottom base layer 1, printed layer 2, transparent glaze layer 4 successively from bottom to top.
The Ceramic Tiles of the present embodiment are manufactured, its step includes successively:
A, will feed proportioning ball milling carry out mist projection granulating after compacting form adobe, controlled after drying adobe temperature 70 DEG C 370g ground-coat enamels are applied in the adobe and form bottom base layer 1;
B, formed by inkjet printing stamp and roller printing on the bottom base layer 1 after the step A and after drying Printed layer 2;
C, clear frit 1010g is applied, is then dried;
D, the adobe after the step C is entered after carrying out rubbing down using elastic module after kiln is fired at 1250 DEG C, bag Load storehouse.
The method of the present embodiment does not apply protection glaze, and carries out rubbing down using elastic module, and its product is due in sintering procedure Gas is produced, breaks through transparent glaze layer, thus has the defects of pin hole, brick faces the incomplete absorption of clear frit, recessed glaze occurs, and make Rubbing down is carried out with elastic module, brick face waveform inevitably occurs.
The technical principle of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain the present invention's Principle, and limiting the scope of the invention can not be construed in any way.Based on explanation herein, the technology of this area Personnel would not require any inventive effort the other embodiments that can associate the present invention, and these modes are fallen within Within protection scope of the present invention.

Claims (7)

1. a kind of manufacture method of glazed tile, it is characterised in that step includes successively:
A, ceramic powder is suppressed to form adobe, ground-coat enamel is applied in the adobe after drying;
B, stamp and after drying, applies protection glaze;
C, biscuiting;
D, clear frit is applied, is then dried;
E, rubbing down is carried out after firing using non-resilient module;
The softening temperature of the protection glaze is 1070-1080 DEG C, and the softening temperature of the clear frit is 1100-1120 DEG C;It is described The temperature of the biscuiting in step C is 850-950 DEG C.
A kind of 2. manufacture method of glazed tile according to claim 1, it is characterised in that:Applied described in the step A The glaze volume of ground-coat enamel is 300-400g/m2
A kind of 3. manufacture method of glazed tile according to claim 1, it is characterised in that:The print in the step B Flower includes one or more combinations in screen printing, roller printing or inkjet printing stamp.
A kind of 4. manufacture method of glazed tile according to claim 1, it is characterised in that:Applied described in the step B The glaze volume for protecting glaze is 300-350g/m2
A kind of 5. manufacture method of glazed tile according to claim 1, it is characterised in that:Applied described in the step D The glaze volume of clear frit is 1000-1050g/m2
6. the product manufactured by a kind of manufacture method of glazed tile according to claim 1-5 any one, its feature exist In:From bottom to top include bottom base layer, printed layer, protection glaze layer and transparent glaze layer successively.
7. product according to claim 6, it is characterised in that:The bottom base thickness degree is 6-9mm;The printed layer thickness For less than 0.1mm;The protection glazed thickness is 0.1-0.2mm;The transparent glazed thickness is 0.8-1.0mm.
CN201410377858.XA 2014-08-01 2014-08-01 A kind of manufacture method of glazed tile and products thereof Active CN104130032B (en)

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Publication number Priority date Publication date Assignee Title
CN105036815B (en) * 2015-06-24 2017-11-28 佛山市东鹏陶瓷有限公司 A kind of production method of imitative hole stone glazed tile
CN105036814B (en) * 2015-06-24 2017-11-28 佛山市东鹏陶瓷有限公司 A kind of production method of natural cavity stone imitation glazed tile and its unfired brick structure of acquisition
CN106320622B (en) * 2016-08-08 2019-01-04 佛山市东鹏陶瓷有限公司 A kind of Ceramic Tiles and its production method of dry-pressing injection forming
CN107651971A (en) * 2017-09-30 2018-02-02 唐硕度 A kind of anti-bacteria ceramic thin plate and preparation method thereof
CN108675756A (en) * 2018-06-05 2018-10-19 陈太师 A kind of glazed tile and preparation method thereof
CN108558356B (en) * 2018-06-29 2021-05-18 佛山石湾鹰牌陶瓷有限公司 Thin microcrystal soft light brick and preparation method thereof
CN110423140A (en) * 2019-06-26 2019-11-08 景德镇欧神诺陶瓷有限公司 A kind of process using inkjet printing production Portoro
CN112707642B (en) * 2020-12-28 2022-09-02 丰城市东鹏陶瓷有限公司 Flash overglaze, preparation method thereof and preparation method of ceramic tile with flash effect

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CN103183529A (en) * 2013-04-19 2013-07-03 佛山瑭虹釉料科技有限公司 Production process of superflat full polished glazed brick added with transparent microcrystal fine powder

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Publication number Priority date Publication date Assignee Title
CN101497521A (en) * 2008-12-25 2009-08-05 萧华 Technique of preparing glaze color convexo-concave texture ornamental porcelain brick
CN103183529A (en) * 2013-04-19 2013-07-03 佛山瑭虹釉料科技有限公司 Production process of superflat full polished glazed brick added with transparent microcrystal fine powder

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