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CA2264700C - Alkylation process using zeolite beta - Google Patents

Alkylation process using zeolite beta Download PDF

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Publication number
CA2264700C
CA2264700C CA002264700A CA2264700A CA2264700C CA 2264700 C CA2264700 C CA 2264700C CA 002264700 A CA002264700 A CA 002264700A CA 2264700 A CA2264700 A CA 2264700A CA 2264700 C CA2264700 C CA 2264700C
Authority
CA
Canada
Prior art keywords
benzene
stream
ethylene
olefin
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002264700A
Other languages
English (en)
French (fr)
Other versions
CA2264700A1 (en
Inventor
Dan E. Hendriksen
James R. Lattner
Mechilium J. G. Janssen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of CA2264700A1 publication Critical patent/CA2264700A1/en
Application granted granted Critical
Publication of CA2264700C publication Critical patent/CA2264700C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/06—Reactor-distillation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CA002264700A 1996-09-06 1997-09-05 Alkylation process using zeolite beta Expired - Lifetime CA2264700C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US2557796P 1996-09-06 1996-09-06
US60/025,577 1996-09-06
PCT/US1997/015684 WO1998009928A2 (en) 1996-09-06 1997-09-05 Alkylation process using zeolite beta

Publications (2)

Publication Number Publication Date
CA2264700A1 CA2264700A1 (en) 1998-03-12
CA2264700C true CA2264700C (en) 2006-11-21

Family

ID=21826869

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002264700A Expired - Lifetime CA2264700C (en) 1996-09-06 1997-09-05 Alkylation process using zeolite beta

Country Status (9)

Country Link
US (1) US6002057A (zh)
EP (1) EP0929502B1 (zh)
JP (1) JP4275739B2 (zh)
CN (1) CN1088050C (zh)
AU (1) AU743095B2 (zh)
CA (1) CA2264700C (zh)
DE (1) DE69705958T2 (zh)
ES (1) ES2162327T3 (zh)
WO (1) WO1998009928A2 (zh)

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IT1299035B1 (it) * 1998-04-07 2000-02-07 Enichem Spa Processo per la preparazione di composti aromatici monoalchilati
US5977423A (en) * 1998-06-19 1999-11-02 Netzer; David Mixed phase ethylation process for producing ethylbenzene
US6252126B1 (en) 1998-06-19 2001-06-26 David Netzer Method for producing ethylbenzene
US6783659B2 (en) * 2001-11-16 2004-08-31 Chevron Phillips Chemical Company, L.P. Process to produce a dilute ethylene stream and a dilute propylene stream
BR0214206B1 (pt) * 2001-11-16 2013-02-19 processo para a produÇço de um fluxo de etileno diluÍdo e um fluxo de propileno diluÍdo.
US6878327B2 (en) * 2002-04-19 2005-04-12 Fina Technology, Inc. Process of making polypropylene fibers
US7186873B2 (en) 2002-06-19 2007-03-06 Exxonmobil Chemical Patents Inc. Manufacture of xylenes by reactive distillation of reformate
US7119239B2 (en) 2002-06-19 2006-10-10 Exxonmobil Chemical Patents Inc. Manufacture of xylenes using reformate
WO2004000974A1 (en) 2002-06-19 2003-12-31 Exxonmobil Chemical Patents Inc. Manufacture of xylenes from reformate
EP1479663A1 (en) * 2003-05-17 2004-11-24 Haldor Topsoe A/S Process for catalytic alkylation of monocyclic aromatic compounds and composition of use therein
US7071369B2 (en) 2003-06-10 2006-07-04 Abb Lummus Global Inc. Process for the production of alkylbenzene with ethane stripping
US20040254414A1 (en) * 2003-06-11 2004-12-16 Hildreth James M. Process for production of propylene and ethylbenzene from dilute ethylene streams
US7259282B2 (en) * 2003-09-08 2007-08-21 Abb Lummus Global Inc. Process for production of ethylbenzene from dilute ethylene streams
EP1780786A4 (en) * 2004-06-07 2009-11-25 Nikon Corp STAGE DEVICE, EXPOSURE DEVICE AND EXPOSURE METHOD
TWI376361B (en) * 2004-08-13 2012-11-11 Exxonmobil Chem Patents Inc Process for producing phenol and methyl ethyl ketone
US7348465B2 (en) * 2005-02-08 2008-03-25 Shell Oil Company Selective alkylation of aromatic hydrocarbons
US7488861B2 (en) * 2005-03-17 2009-02-10 Catalytic Distillation Technologies Process for the co-production of cumene and secondary butyl benzene
US20060247479A1 (en) * 2005-04-29 2006-11-02 Nova Chemicals Inc. Ethyl benzene from refinery grade feedstocks
US7326815B2 (en) * 2005-12-27 2008-02-05 Exxonmobil Chemical Patents Inc. Selective oxidation of alkylbenzenes
EP1968919A4 (en) * 2006-01-07 2009-01-21 Fina Technology LIQUID PHASE ALKYLATION DILUTED
US9375706B2 (en) 2006-09-05 2016-06-28 Fina Technology, Inc. Use of swing preliminary alkylation reactors
US20080058566A1 (en) 2006-09-05 2008-03-06 Fina Technology, Inc. Processes for reduction of alkylation catalyst deactivation utilizing low silica to alumina ratio catalyst
DE602008005752D1 (de) * 2007-08-22 2011-05-05 Exxonmobil Chem Patents Inc Verfahren zur herstellung von sec.-butylbenzol
EP2098498A1 (en) 2008-03-04 2009-09-09 ExxonMobil Chemical Patents Inc. Selective oligomerization of isobutene
EP2110368A1 (en) 2008-04-18 2009-10-21 Total Petrochemicals France Alkylation of aromatic substrates and transalkylation process
WO2010027562A1 (en) * 2008-08-26 2010-03-11 Exxonmobil Chemical Patents Inc. Process for producing alkylbenzene hydroperoxides
US8865958B2 (en) * 2008-09-30 2014-10-21 Fina Technology, Inc. Process for ethylbenzene production
CN102177110A (zh) * 2008-10-10 2011-09-07 埃克森美孚化学专利公司 用于生产仲丁基苯的方法
CN102177126A (zh) 2008-10-10 2011-09-07 埃克森美孚化学专利公司 制备苯酚和甲乙酮的方法
JP5342652B2 (ja) 2008-12-15 2013-11-13 エクソンモービル ケミカル パテンツ インコーポレイテッド アルキル芳香族化合物の酸化
US8455383B2 (en) * 2009-09-28 2013-06-04 Fina Technology, Inc. Process for catalyst regeneration and extended use
RU2505515C1 (ru) * 2010-06-11 2014-01-27 Юоп Ллк Способ и устройство для снижения содержания бензола в бензине при алкилировании разбавленным этиленом
CN107922857B (zh) 2015-06-29 2021-05-25 沙特基础工业全球技术有限公司 用于从混合烃原料流生产枯烯和/或乙苯的方法
EP3347331B1 (en) * 2015-09-07 2019-08-21 SABIC Global Technologies B.V. Process for producing cumene and/or sec-butylbenzene using a mixed olefins stream as alkylation agent
CN111450662B (zh) * 2020-05-29 2022-08-02 山东京博石油化工有限公司 一种用于制乙苯的原料干气的净化方法及装置

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Also Published As

Publication number Publication date
EP0929502B1 (en) 2001-08-01
EP0929502A2 (en) 1999-07-21
US6002057A (en) 1999-12-14
JP4275739B2 (ja) 2009-06-10
WO1998009928A3 (en) 1999-04-15
DE69705958D1 (de) 2001-09-06
CN1239471A (zh) 1999-12-22
CA2264700A1 (en) 1998-03-12
AU4254797A (en) 1998-03-26
WO1998009928A2 (en) 1998-03-12
ES2162327T3 (es) 2001-12-16
AU743095B2 (en) 2002-01-17
DE69705958T2 (de) 2002-04-04
CN1088050C (zh) 2002-07-24
JP2001503025A (ja) 2001-03-06

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Effective date: 20170905