Bailey et al., 2017 - Google Patents
Decomposition of olefin metathesis catalysts by brønsted base: metallacyclobutane deprotonation as a primary deactivating eventBailey et al., 2017
- Document ID
- 18269963308706371422
- Author
- Bailey G
- Lummiss J
- Foscato M
- Occhipinti G
- McDonald R
- Jensen V
- Fogg D
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
Brønsted bases of widely varying strength are shown to decompose the metathesis-active Ru intermediates formed by the second-generation Hoveyda and Grubbs catalysts. Major products, in addition to propenes, are base· HCl and olefin-bound, cyclometalated dimers …
- 239000003054 catalyst 0 title abstract description 176
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/002—Osmium compounds
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