[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Zatolochnaya et al., 2018 - Google Patents

Copper-catalyzed asymmetric hydrogenation of 2-substituted ketones via dynamic kinetic resolution

Zatolochnaya et al., 2018

View HTML
Document ID
10921129919383314331
Author
Zatolochnaya O
Rodríguez S
Zhang Y
Lao K
Tcyrulnikov S
Li G
Wang X
Qu B
Biswas S
Mangunuru H
Rivalti D
Sieber J
Desrosiers J
Leung J
Grinberg N
Lee H
Haddad N
Yee N
Song J
Kozlowski M
Senanayake C
Publication year
Publication venue
Chemical Science

External Links

Snippet

A new class of tunable heterophosphole dimeric ligands have been designed and synthesized. These ligands have enabled the first examples of Cu-catalyzed hydrogenation of 2-substituted-1-tetralones and related heteroaryl ketones via dynamic kinetic resolution …
Continue reading at pubs.rsc.org (HTML) (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/04—Substitution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms

Similar Documents

Publication Publication Date Title
Zatolochnaya et al. Copper-catalyzed asymmetric hydrogenation of 2-substituted ketones via dynamic kinetic resolution
Sehnal et al. Emergence of palladium (IV) chemistry in synthesis and catalysis
Meiries et al. Large yet Flexible N‐Heterocyclic Carbene Ligands for Palladium Catalysis
Lafrance et al. Mild and efficient palladium-catalyzed intramolecular direct arylation reactions
Nagamoto et al. Catalytic [3+ 2] annulation of ketimines with alkynes via C–H activation by a cationic iridium (cod) complex
Chen et al. Iridium‐Catalyzed Enantioselective Allylic Substitution of Unstabilized Enolates Derived from α, β‐Unsaturated Ketones
Huang et al. Regio-and enantioselective allylic alkylation of terminal alkynes by synergistic Rh/Cu catalysis
Wen et al. Enantioselective organocatalytic phospha-Michael reaction of α, β-unsaturated ketones
Xu et al. Rhodium-catalyzed regio-and enantioselective allylic amination of racemic 1, 2-disubstituted allylic phosphates
Lee et al. Well-defined palladium (0) complexes bearing N-heterocyclic carbene and phosphine moieties: efficient catalytic applications in the Mizoroki–Heck reaction and direct C–H functionalization
Ge et al. Manganese (I)-catalyzed access to 1, 2-bisphosphine ligands
Singh et al. One-pot tandem hiyama alkynylation/cyclizations by palladium (II) acyclic diaminocarbene (ADC) complexes yielding biologically relevant benzofuran scaffolds
Chew et al. Enantioselective phospha-Michael addition of diarylphosphines to β, γ-unsaturated α-ketoesters and amides
Jiang et al. Rhodium (iii)-catalyzed sp 2 C–H bond addition to CF 3-substituted unsaturated ketones
Wong et al. The recent development of phosphine ligands derived from 2-phosphino-substituted heterocycles and their applications in palladium-catalyzed cross-coupling reactions
Li et al. Nickel-catalyzed substitution reactions of propargyl halides with organotitanium reagents
Huang et al. Palladium-catalyzed asymmetric 1, 6-addition of diphenylphosphine to (4-aryl-1, 3-butadienylidene) bis (phosphonates) for the synthesis of chiral phosphines
Yang et al. Mono-and Dinuclear Pincer Nickel Catalyzed Activation and Transformation of C–Cl, C–N, and C–O Bonds
Khiar et al. “Sulfolefin”: Highly modular mixed S/Olefin ligands for enantioselective Rh-catalyzed 1, 4-addition
Wang et al. Asymmetric imino-acylation of alkenes enabled by HAT-photo/nickel cocatalysis
CN110105305B (en) Transition metal catalyzed C-H activation/cyclization synthesis 1,2-benzothiazine derivative green synthesis method
Manjón‐Mata et al. Regioselective Iron‐Catalysed Cross‐Coupling Reaction of Aryl Propargylic Bromides and Aryl Grignard Reagents
Snead et al. Bis (2-alkylpyrrolidin-1-yl) methylidenes as chiral acyclic diaminocarbene ligands
Hagemann et al. A General Method for the Enantioselective Hydrogenation of β‐Keto Esters using Monodentate Binaphthophosphepine Ligands
Álvarez-Casao et al. Pyridine–hydrazone ligands in enantioselective palladium-catalyzed Suzuki–Miyaura cross-couplings