Gillette et al., 1989 - Google Patents
Lewis base adducts to diorganosilylenesGillette et al., 1989
- Document ID
- 5726854494349679604
- Author
- Gillette G
- Noren G
- West R
- Publication year
- Publication venue
- Organometallics
External Links
Snippet
Silylenes 2a-d were generated photolytically at 77 K in 3-MP matrices doped with ethers, amines, sulfides, phosphines, and alcohols. The initially formed free silylenes react upon annealing of the matrix to give acid-base complexes observed by electronic spectroscopy …
- 239000002879 Lewis base 0 title description 5
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C-Si linkages
- C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C-Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C-Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C-Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
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