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Steinhart–Hart equation

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The Steinhart–Hart equation is a model relating the varying electrical resistance of a semiconductor to its varying temperatures. The equation is

where

is the temperature (in kelvins),
is the resistance at (in ohms),
, , and are the Steinhart–Hart coefficients, which are characteristics specific to the bulk semiconductor material over a given temperature range of interest.

Application

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When applying a thermistor device to measure temperature, the equation relates a measured resistance to the device temperature, or vice versa.

Finding temperature from resistance and characteristics

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The equation model converts the resistance actually measured in a thermistor to its theoretical bulk temperature, with a closer approximation to actual temperature than simpler models, and valid over the entire working temperature range of the sensor. Steinhart–Hart coefficients for specific commercial devices are ordinarily reported by thermistor manufacturers as part of the device characteristics.

Finding characteristics from measurements of resistance at known temperatures

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Conversely, when the three Steinhart–Hart coefficients of a specimen device are not known, they can be derived experimentally by a curve fitting procedure applied to three measurements at various known temperatures. Given the three temperature-resistance observations, the coefficients are solved from three simultaneous equations.

Inverse of the equation

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To find the resistance of a semiconductor at a given temperature, the inverse of the Steinhart–Hart equation must be used. See the Application Note, "A, B, C Coefficients for Steinhart–Hart Equation".

 

where

 

Steinhart–Hart coefficients

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To find the coefficients of Steinhart–Hart, we need to know at-least three operating points. For this, we use three values of resistance data for three known temperatures.

 

With  ,   and   values of resistance at the temperatures  ,   and  , one can express  ,   and   (all calculations):

 

History

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The equation was developed by John S. Steinhart and Stanley R. Hart, who first published it in 1968.[1]

Derivation and alternatives

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The most general form of the equation can be derived from extending the B parameter equation to an infinite series:

 
 
 

  is a reference (standard) resistance value. The Steinhart–Hart equation assumes   is 1 ohm. The curve fit is much less accurate when it is assumed   and a different value of   such as 1 kΩ is used. However, using the full set of coefficients avoids this problem as it simply results in shifted parameters.[2]

In the original paper, Steinhart and Hart remark that allowing   degraded the fit.[1] This is surprising as allowing more freedom would usually improve the fit. It may be because the authors fitted   instead of  , and thus the error in   increased from the extra freedom.[3] Subsequent papers have found great benefit in allowing  .[4]

The equation was developed through trial-and-error testing of numerous equations, and selected due to its simple form and good fit.[1] However, in its original form, the Steinhart–Hart equation is not sufficiently accurate for modern scientific measurements. For interpolation using a small number of measurements, the series expansion with   has been found to be accurate within 1 mK over the calibrated range. Some authors recommend using  .[4] If there are many data points, standard polynomial regression can also generate accurate curve fits. Some manufacturers have begun providing regression coefficients as an alternative to Steinhart–Hart coefficients.[5]

References

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  1. ^ a b c John S. Steinhart, Stanley R. Hart, Calibration curves for thermistors, Deep-Sea Research and Oceanographic Abstracts, Volume 15, Issue 4, August 1968, Pages 497–503, ISSN 0011-7471, doi:10.1016/0011-7471(68)90057-0.
  2. ^ Matus, Michael (October 2011). Temperature Measurement in Dimensional Metrology – Why the Steinhart–Hart Equation works so well (PDF). MacroScale 2011. Wabern, Switzerland.
  3. ^ Hoge, Harold J. (1 June 1988). "Useful procedure in least squares, and tests of some equations for thermistors". Review of Scientific Instruments. 59 (6): 975–979. doi:10.1063/1.1139762. ISSN 0034-6748.
  4. ^ a b Rudtsch, Steffen; von Rohden, Christoph (1 December 2015). "Calibration and self-validation of thermistors for high-precision temperature measurements". Measurement. 76: 1–6. doi:10.1016/j.measurement.2015.07.028. ISSN 0263-2241. Retrieved 8 July 2020.
  5. ^ "Comments on the Steinhart–Hart Equation" (PDF). Building Automation Products Inc. 11 November 2015. Retrieved 8 July 2020.
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