Point groups in three dimensions

The symmetry group operations (symmetry operations) are the isometries of three-dimensional space R³ that leave the origin fixed, forming the group O(3). These operations can be categorized as:

• The direct (orientation-preserving) symmetry operations, which form the group SO(3):
  • The identity operation, denoted by E or the identity matrix I.
  • Rotation about an axis through the origin by an angle θ. Rotation by θ = 360°/n for any positive integer n is denoted C_n (from the Schoenflies notation for the group C_n that it generates). The identity operation, also written C₁, is a special case of the rotation operator.
• The indirect (orientation-reversing) operations:
  • Inversion, denoted i or C_i, that is, rotation by 180° about a coordinate axis followed by a reflection in the orthogonal coordinate plane. The matrix notation is −I.
  • Reflection in a plane through the origin, denoted σ.
  • Improper rotation, also called rotation-reflection: rotation about an axis by an angle θ, combined with reflection in the plane through the origin perpendicular to the axis. Rotation-reflection by θ = 360°/n for any positive integer n is denoted S_n (from the Schoenflies notation for the group S_n that it generates if n is even).

Inversion is a special case of rotation-reflection (i = S₂), as is reflection (σ = S₁), so these operations are often considered to be improper rotations.

A circumflex is sometimes added to the symbol to indicate an operator, as in Ĉ_n and Ŝ_n.

When comparing the symmetry type of two objects, the origin is chosen for each separately, i.e. they need not have the same center. Moreover, two objects are considered to be of the same symmetry type if their symmetry groups are conjugate subgroups of O(3) (two subgroups H₁, H₂ of a group G are conjugate, if there exists g ∈ G such that H₁ = g⁻¹H₂g ).

For example, two 3D objects have the same symmetry type:

• if both have mirror symmetry, but with respect to a different mirror plane
• if both have 3-fold rotational symmetry, but with respect to a different axis.

In the case of multiple mirror planes and/or axes of rotation, two symmetry groups are of the same symmetry type if and only if there is a rotation mapping the whole structure of the first symmetry group to that of the second. (In fact there will be more than one such rotation, but not an infinite number as when there is only one mirror or axis.) The conjugacy definition would also allow a mirror image of the structure, but this is not needed, the structure itself is achiral. For example, if a symmetry group contains a 3-fold axis of rotation, it contains rotations in two opposite directions. (The structure is chiral for 11 pairs of space groups with a screw axis.)

There are many infinite isometry groups; for example, the "cyclic group" (meaning that it is generated by one element – not to be confused with a torsion group) generated by a rotation by an irrational number of turns about an axis. We may create non-cyclical abelian groups by adding more rotations around the same axis. The set of points on a circle at rational numbers of degrees around the circle illustrates a point group requiring an infinite number of generators. There are also non-abelian groups generated by rotations around different axes. These are usually (generically) free groups. They will be infinite unless the rotations are specially chosen.

All the infinite groups mentioned so far are not closed as topological subgroups of O(3). We now discuss topologically closed subgroups of O(3).

 

The whole O(3) is the symmetry group of spherical symmetry; SO(3) is the corresponding rotation group. The other infinite isometry groups consist of all rotations about an axis through the origin, and those with additionally reflection in the planes through the axis, and/or reflection in the plane through the origin, perpendicular to the axis. Those with reflection in the planes through the axis, with or without reflection in the plane through the origin perpendicular to the axis, are the symmetry groups for the two types of cylindrical symmetry. Any 3D shape (subset of R³) having infinite rotational symmetry must also have mirror symmetry for every plane through the axis. Physical objects having infinite rotational symmetry will also have the symmetry of mirror planes through the axis, but vector fields may not, for instance the velocity vectors of a cone rotating about its axis, or the magnetic field surrounding a wire.^[1]

There are seven continuous groups which are all in a sense limits of the finite isometry groups. These so called limiting point groups or Curie limiting groups are named after Pierre Curie who was the first to investigate them.^[1][2] The seven infinite series of axial groups lead to five limiting groups (two of them are duplicates), and the seven remaining point groups produce two more continuous groups. In international notation, the list is ∞, ∞2, ∞/m, ∞mm, ∞/mm, ∞∞, and ∞∞m.^[3] Not all of these are possible for physical objects, for example objects with ∞∞ symmetry also have ∞∞m symmetry. See below for other designations and more details.

Symmetries in 3D that leave the origin fixed are fully characterized by symmetries on a sphere centered at the origin. For finite 3D point groups, see also spherical symmetry groups.

Up to conjugacy, the set of finite 3D point groups consists of:

• § The seven infinite series of axial groups, which have at most one more-than-2-fold rotation axis; they are the finite symmetry groups on an infinite cylinder, or equivalently, those on a finite cylinder. They are sometimes called the axial or prismatic point groups.
• § The seven remaining point groups, which have multiple 3-or-more-fold rotation axes; these groups can also be characterized as point groups having multiple 3-fold rotation axes. The possible combinations are:
  • Four 3-fold axes (the three tetrahedral symmetries T, T_h, and T_d)
  • Four 3-fold axes and three 4-fold axes (octahedral symmetries O and O_h)
  • Ten 3-fold axes and six 5-fold axes (icosahedral symmetries I and I_h)

According to the crystallographic restriction theorem, only a limited number of point groups are compatible with discrete translational symmetry: 27 from the 7 infinite series, and 5 of the 7 others. Together, these make up the 32 so-called crystallographic point groups.

The infinite series of axial or prismatic groups have an index n, which can be any integer; in each series, the nth symmetry group contains n-fold rotational symmetry about an axis, i.e. symmetry with respect to a rotation by an angle 360°/n. n=1 covers the cases of no rotational symmetry at all. There are four series with no other axes of rotational symmetry (see cyclic symmetries) and three with additional axes of 2-fold symmetry (see dihedral symmetry). They can be understood as point groups in two dimensions extended with an axial coordinate and reflections in it. They are related to the frieze groups;^[4] they can be interpreted as frieze-group patterns repeated n times around a cylinder.

The following table lists several notations for point groups: Hermann–Mauguin notation (used in crystallography), Schönflies notation (used to describe molecular symmetry), orbifold notation, and Coxeter notation. The latter three are not only conveniently related to its properties, but also to the order of the group. The orbifold notation is a unified notation, also applicable for wallpaper groups and frieze groups. The crystallographic groups have n restricted to 1, 2, 3, 4, and 6; removing crystallographic restriction allows any positive integer. The series are:

Intl		Schoenflies	Orbifold	Coxeter	Frieze	Struct.	Order	Example	Comments
Even n	Odd n				(cylinder)
n		Cn	nn	[n]+	p1	Zn	n		n-fold rotational symmetry
2n	n	S2n	n×	[2n+,2+]	p11g	Z2n	2n		2n-fold rotoreflection symmetry
n/m	2n	Cnh	n*	[n+,2]	p11m	Zn×Z2	2n
nmm	nm	Cnv	*nn	[n]	p1m1	Dihn	2n		Pyramidal symmetry; in biology, biradial symmetry
n22	n2	Dn	22n	[n,2]+	p211	Dihn	2n		Dihedral symmetry
2n2m	nm	Dnd	2*n	[2n,2+]	p2mg	Dih2n	4n		Antiprismatic symmetry
n/mmm	2n2m	Dnh	*22n	[n,2]	p2mm	Dihn×Z2	4n		Prismatic symmetry

For odd n we have Z_2n = Z_n × Z₂ and Dih_2n = Dih_n × Z₂.

The groups C_n (including the trivial C₁) and D_n are chiral, the others are achiral.

The terms horizontal (h) and vertical (v), and the corresponding subscripts, refer to the additional mirror plane, that can be parallel to the rotation axis (vertical) or perpendicular to the rotation axis (horizontal).

The simplest nontrivial axial groups are equivalent to the abstract group Z₂:

• C_i (equivalent to S₂) – inversion symmetry
• C₂ – 2-fold rotational symmetry
• C_s (equivalent to C_1hand C_1v) – reflection symmetry, also called bilateral symmetry.

 

The second of these is the first of the uniaxial groups (cyclic groups) C_n of order n (also applicable in 2D), which are generated by a single rotation of angle 360°/n. In addition to this, one may add a mirror plane perpendicular to the axis, giving the group C_nh of order 2n, or a set of n mirror planes containing the axis, giving the group C_nv, also of order 2n. The latter is the symmetry group for a regular n-sided pyramid. A typical object with symmetry group C_n or D_n is a propeller.

If both horizontal and vertical reflection planes are added, their intersections give n axes of rotation through 180°, so the group is no longer uniaxial. This new group of order 4n is called D_nh. Its subgroup of rotations is the dihedral group D_n of order 2n, which still has the 2-fold rotation axes perpendicular to the primary rotation axis, but no mirror planes.

Note: in 2D, D_n includes reflections, which can also be viewed as flipping over flat objects without distinction of frontside and backside; but in 3D, the two operations are distinguished: D_n contains "flipping over", not reflections.

There is one more group in this family, called D_nd (or D_nv), which has vertical mirror planes containing the main rotation axis, but instead of having a horizontal mirror plane, it has an isometry that combines a reflection in the horizontal plane and a rotation by an angle 180°/n. D_nh is the symmetry group for a "regular" n-gonal prism and also for a "regular" n-gonal bipyramid. D_nd is the symmetry group for a "regular" n-gonal antiprism, and also for a "regular" n-gonal trapezohedron. D_n is the symmetry group of a partially rotated ("twisted") prism.

The groups D₂ and D_2h are noteworthy in that there is no special rotation axis. Rather, there are three perpendicular 2-fold axes. D₂ is a subgroup of all the polyhedral symmetries (see below), and D_2h is a subgroup of the polyhedral groups T_h and O_h. D₂ occurs in molecules such as twistane and in homotetramers such as Concanavalin A. The elements of D₂ are in 1-to-2 correspondence with the rotations given by the unit Lipschitz quaternions.

The group S_n is generated by the combination of a reflection in the horizontal plane and a rotation by an angle 360°/n. For n odd this is equal to the group generated by the two separately, C_nh of order 2n, and therefore the notation S_n is not needed; however, for n even it is distinct, and of order n. Like D_nd it contains a number of improper rotations without containing the corresponding rotations.

All symmetry groups in the 7 infinite series are different, except for the following four pairs of mutually equal ones:

• C_1h and C_1v: group of order 2 with a single reflection (C_s )
• D₁ and C₂: group of order 2 with a single 180° rotation
• D_1h and C_2v: group of order 4 with a reflection in a plane and a 180° rotation through a line in that plane
• D_1d and C_2h: group of order 4 with a reflection in a plane and a 180° rotation through a line perpendicular to that plane.

S₂ is the group of order 2 with a single inversion (C_i ).

"Equal" is meant here as the same up to conjugacy in space. This is stronger than "up to algebraic isomorphism". For example, there are three different groups of order two in the first sense, but there is only one in the second sense. Similarly, e.g. S_2n is algebraically isomorphic with Z_2n.

The groups may be constructed as follows:

• C_n. Generated by an element also called C_n, which corresponds to a rotation by angle 2π/n around the axis. Its elements are E (the identity), C_n, C_n², ..., C_nⁿ⁻¹, corresponding to rotation angles 0, 2π/n, 4π/n, ..., 2(n − 1)π/n.
• S_2n. Generated by element C_2nσ_h, where σ_h is a reflection in the direction of the axis. Its elements are the elements of C_n with C_2nσ_h, C_2n³σ_h, ..., C_2n²ⁿ⁻¹σ_h added.
• C_nh. Generated by element C_n and reflection σ_h. Its elements are the elements of group C_n, with elements σ_h, C_nσ_h, C_n²σ_h, ..., C_nⁿ⁻¹σ_h added.
• C_nv. Generated by element C_n and reflection σ_v in a direction in the plane perpendicular to the axis. Its elements are the elements of group C_n, with elements σ_v, C_nσ_v, C_n²σ_v, ..., C_nⁿ⁻¹σ_v added.
• D_n. Generated by element C_n and 180° rotation U = σ_hσ_v around a direction in the plane perpendicular to the axis. Its elements are the elements of group C_n, with elements U, C_nU, C_n²U, ..., C_n^n − 1U added.
• D_nd. Generated by elements C_2nσ_h and σ_v. Its elements are the elements of group C_n and the additional elements of S_2n and C_nv, with elements C_2nσ_hσ_v, C_2n³σ_hσ_v, ..., C_2n^2n − 1σ_hσ_v added.
• D_nh. Generated by elements C_n, σ_h, and σ_v. Its elements are the elements of group C_n and the additional elements of C_nh, C_nv, and D_n.

Groups with continuous axial rotations are designated by putting ∞ in place of n. Note however that C_∞ here is not the same as the infinite cyclic group (also sometimes designated C_∞), which is isomorphic to the integers. The following table gives the five continuous axial rotation groups. They are limits of the finite groups only in the sense that they arise when the main rotation is replaced by rotation by an arbitrary angle, so not necessarily a rational number of degrees as with the finite groups. Physical objects can only have C_∞v or D_∞h symmetry, but vector fields can have the others.

H–M	Schönflies	Orbifold	Coxeter		Limit of	Abstract group
∞	C∞	∞∞	[∞]+		Cn	SO(2)
∞, ∞/m	C∞h	∞*	[2,∞+]		Cnh, S2n	SO(2)×Z2
∞m	C∞v	*∞∞	[∞]		Cnv	O(2)
∞2	D∞	22∞	[2,∞]+		Dn	O(2)
∞m, ∞/mm	D∞h	*22∞	[2,∞]		Dnh, Dnd	O(2)×Z2

The remaining point groups are said to be of very high or polyhedral symmetry because they have more than one rotation axis of order greater than 2. Here, C_n denotes an axis of rotation through 360°/n and S_n denotes an axis of improper rotation through the same. On successive lines are the orbifold notation, the Coxeter notation and Coxeter diagram, and the Hermann–Mauguin notation (full, and abbreviated if different) and the order (number of elements) of the symmetry group. The groups are:

T, (332) [3,3]+ (     ) 23 order 12	chiral tetrahedral symmetry	The three-fold rotational axes (C3) of a tetrahedron.   The two-fold rotational axes (C2) of a tetrahedron. There are four C3 axes, each through two vertices of a circumscribing cube (red cube in images), or through one vertex of a regular tetrahedron, and three C2 axes, through the centers of the cube's faces, or the midpoints of the tetrahedron's edges. This group is isomorphic to A4, the alternating group on 4 elements, and is the rotation group for a regular tetrahedron. It is a normal subgroup of Td, Th, and the octahedral symmetries. The elements of the group correspond 1-to-2 to the rotations given by the 24 unit Hurwitz quaternions (the "binary tetrahedral group").
Td, (*332) [3,3] (     ) 43m order 24	full tetrahedral symmetry	A mirror plane of a tetrahedron.   A four-fold rotation-reflection axis (S4) of a tetrahedron. This group is the symmetry group of a regular tetrahedron. This group has the same rotation axes as T, and the C2 axes are now D2d axes, whereas the four three-fold axes now give rise to four C3v subgroups. This group has six mirror planes, each containing two edges of the cube or one edge of the tetrahedron, a single S4 axis, and two C3 axes. Td is isomorphic to S4, the symmetric group on 4 letters, because there is a 1-to-1 correspondence between the elements of Td and the 24 permutations of the four 3-fold axes. An object of C3v symmetry under one of the 3-fold axes gives rise under the action of Td to an orbit consisting of four such objects, and Td corresponds to the set of permutations of these four objects. Td is a normal subgroup of Oh. See also the isometries of the regular tetrahedron.
Th, (3*2) [3+,4] (     ) 2/m3, m3 order 24	pyritohedral symmetry	This group has the same rotation axes as T, with mirror planes parallel to the cube faces. The C3 axes become S6 axes, and there is inversion symmetry. The two-fold axes give rise to three D2h subgroups. Th is isomorphic to A4 × Z2 (since T and Ci are both normal subgroups), and not to the symmetric group S4. It is the symmetry of a cube with on each face a line segment dividing the face into two equal rectangles, such that the line segments of adjacent faces do not meet at the edge. The symmetries correspond to the even permutations of the body diagonals and the same combined with inversion. It is also the symmetry of a pyritohedron, which is similar to the cube described, with each rectangle replaced by a pentagon with one symmetry axis and 4 equal sides and 1 different side (the one corresponding to the line segment dividing the cube's face); i.e., the cube's faces bulge out at the dividing line and become narrower there. It is a subgroup (but not a normal subgroup) of the full icosahedral symmetry group (as isometry group, not just as abstract group), with 4 of the 10 3-fold axes. It is a normal subgroup of Oh. In spite of being called Th, it does not apply to a tetrahedron.
O, (432) [4,3]+ (     ) 432 order 24	chiral octahedral symmetry	This group is like T, but the C2 axes are now C4 axes, and additionally there are two-fold rotation axes through the midpoints of the edges of the cube, giving rise to three D2 subgroups. The three-fold axes now give rise to four D3 subgroups. This group is also isomorphic to S4 because its elements are in 1-to-1 correspondence to the 24 permutations of the 3-fold axes, as with T. An object of D3 symmetry under one of the 3-fold axes gives rise under the action of O to an orbit consisting of four such objects, and O corresponds to the set of permutations of these four objects. It is the rotation group of the cube and octahedron. Representing rotations with quaternions, O is made up of the 24 unit Hurwitz quaternions and the 24 Lipschitz quaternions of squared norm 2 normalized by dividing by ${\displaystyle {\sqrt {2}}}$ . As before, this is a 1-to-2 correspondence.
Oh, (*432) [4,3] (     ) 4/m32/m, m3m order 48	full octahedral symmetry	This group has the same rotation axes as O, but with mirror planes, comprising both the mirror planes of Td and Th. The three-fold axes give rise to four D3d subgroups. The three perpendicular four-fold axes of O now give D4h subgroups, while the six two-fold axes give six D2h subgroups. This group is isomorphic to S4 × Z2 (because both O and Ci are normal subgroups), and is the symmetry group of the cube and octahedron. See also the isometries of the cube.
I, (532) [5,3]+ (     ) 532 order 60	chiral icosahedral symmetry	This is the rotation group of the icosahedron and the dodecahedron. It is a normal subgroup of index 2 in the full group of symmetries Ih. The group contains 10 versions of D3 and 6 versions of D5 (rotational symmetries like prisms and antiprisms). It also contains five versions of T (see Compound of five tetrahedra). The group I is isomorphic to A5, the alternating group on 5 letters, since its elements correspond 1-to-1 with even permutations of the five T symmetries (or the five tetrahedra just mentioned). Representing rotations with quaternions, I is made up of the 120 unit icosians. As before, this is a 1-to-2 correspondence.
Ih, (*532) [5,3] (     ) 532/m, 53m order 120	full icosahedral symmetry	This is the symmetry group of the icosahedron and the dodecahedron. The group Ih is isomorphic to A5 × Z2 because I and Ci are both normal subgroups. The group contains 10 versions of D3d, 6 versions of D5d (symmetries like antiprisms), and 5 versions of Th.

The continuous groups related to these groups are:

• ∞∞, K, or SO(3), all possible rotations.
• ∞∞m, K_h, or O(3), all possible rotations and reflections.

As noted above for the infinite isometry groups, any physical object having K symmetry will also have K_h symmetry.

Fundamental domains of 3D Coxeter groups

A3, [3,3],	B3, [4,3],	H3, [5,3],
6 mirrors	3+6 mirrors	15 mirrors
2A1, [1,2],	3A1, [2,2],	A1A2, [2,3],
2 mirrors	3 mirrors	4 mirrors
A1, [1],	2A1, [2],	A2, [3],
1 mirror	2 mirrors	3 mirrors

The reflective point groups in three dimensions are also called Coxeter groups and can be given by a Coxeter-Dynkin diagram and represent a set of mirrors that intersect at one central point. Coxeter notation offers a bracketed notation equivalent to the Coxeter diagram, with markup symbols for rotational and other subsymmetry point groups. In Schoenflies notation, the reflective point groups in 3D are C_nv, D_nh, and the full polyhedral groups T, O, and I.

The mirror planes bound a set of spherical triangle domains on the surface of a sphere. A rank n Coxeter group has n mirror planes. Coxeter groups having fewer than 3 generators have degenerate spherical triangle domains, as lunes or a hemisphere. In Coxeter notation these groups are tetrahedral symmetry [3,3], octahedral symmetry [4,3], icosahedral symmetry [5,3], and dihedral symmetry [p,2]. The number of mirrors for an irreducible group is nh/2, where h is the Coxeter group's Coxeter number, n is the dimension (3).^[5]

Weyl group	Coxeter notation		Order	Coxeter number (h)	Mirrors (m)
Polyhedral groups
A3		[3,3]	24	4	6
B3		[4,3]	48	6	3+6
H3		[5,3]	120	10	15
Dihedral groups
2A1		[1,2]	4		1+1
3A1		[2,2]	8		2+1
I2(p)A1		[p,2]	4p		p+1
Cyclic groups
2A1		[2]	4		2
I2(p)		[p]	2p		p
Single mirror
A1		[ ]	2		1

The rotation groups, i.e. the finite subgroups of SO(3), are: the cyclic groups C_n (the rotation group of a canonical pyramid), the dihedral groups D_n (the rotation group of a uniform prism, or canonical bipyramid), and the rotation groups T, O and I of a regular tetrahedron, octahedron/cube and icosahedron/dodecahedron.

In particular, the dihedral groups D₃, D₄ etc. are the rotation groups of plane regular polygons embedded in three-dimensional space, and such a figure may be considered as a degenerate regular prism. Therefore, it is also called a dihedron (Greek: solid with two faces), which explains the name dihedral group.

• An object having symmetry group C_n, C_nh, C_nv or S_2n has rotation group C_n.
• An object having symmetry group D_n, D_nh, or D_nd has rotation group D_n.
• An object having a polyhedral symmetry (T, T_d, T_h, O, O_h, I or I_h) has as its rotation group the corresponding one without a subscript: T, O or I.

The rotation group of an object is equal to its full symmetry group if and only if the object is chiral. In other words, the chiral objects are those with their symmetry group in the list of rotation groups.

Given in Schönflies notation, Coxeter notation, (orbifold notation), the rotation subgroups are:

The rotation group SO(3) is a subgroup of O(3), the full point rotation group of the 3D Euclidean space. Correspondingly, O(3) is the direct product of SO(3) and the inversion group C_i (where inversion is denoted by its matrix −I):

O(3) = SO(3) × { I , −I }

Thus there is a 1-to-1 correspondence between all direct isometries and all indirect isometries, through inversion. Also there is a 1-to-1 correspondence between all groups H of direct isometries in SO(3) and all groups K of isometries in O(3) that contain inversion:

K = H × { I , −I }

H = K ∩ SO(3)

where the isometry ( A, I ) is identified with A.

For finite groups, the correspondence is:

If a group of direct isometries H has a subgroup L of index 2, then there is a corresponding group that contains indirect isometries but no inversion:

${\displaystyle M=L\cup ((H\setminus L)\times \{-I\})}$ 

For example, H = C₄ corresponds to M = S₄.

Thus M is obtained from H by inverting the isometries in ${\displaystyle H\setminus L}$ . This group M is, when considered as an abstract group, isomorphic to H. Conversely, for all point groups M that contain indirect isometries but no inversion we can obtain a rotation group H by inverting the indirect isometries.

For finite groups, the correspondence is:

In 2D, the cyclic group of k-fold rotations C_k is for every positive integer k a normal subgroup of O(2) and SO(2). Accordingly, in 3D, for every axis the cyclic group of k-fold rotations about that axis is a normal subgroup of the group of all rotations about that axis. Since any subgroup of index two is normal, the group of rotations (C_n) is normal both in the group (C_nv) obtained by adding to (C_n) reflection planes through its axis and in the group (C_nh) obtained by adding to (C_n) a reflection plane perpendicular to its axis.

There are two discrete point groups with the property that no discrete point group has it as proper subgroup: O_h and I_h. Their largest common subgroup is T_h. The two groups are obtained from it by changing 2-fold rotational symmetry to 4-fold, and adding 5-fold symmetry, respectively.

There are two crystallographic point groups with the property that no crystallographic point group has it as proper subgroup: O_h and D_6h. Their maximal common subgroups, depending on orientation, are D_3d and D_2h.

Below the groups explained above are arranged by abstract group type.

The smallest abstract groups that are not any symmetry group in 3D, are the quaternion group (of order 8), Z₃ × Z₃ (of order 9), the dicyclic group Dic₃ (of order 12), and 10 of the 14 groups of order 16.

The column "# of order 2 elements" in the following tables shows the total number of isometry subgroups of types C₂, C_i, C_s. This total number is one of the characteristics helping to distinguish the various abstract group types, while their isometry type helps to distinguish the various isometry groups of the same abstract group.

Within the possibilities of isometry groups in 3D, there are infinitely many abstract group types with 0, 1 and 3 elements of order 2, there are two with 4n + 1 elements of order 2, and there are three with 4n + 3 elements of order 2 (for each n ≥ 8 ). There is never a positive even number of elements of order 2.

The symmetry group for n-fold rotational symmetry is C_n; its abstract group type is cyclic group Z_n, which is also denoted by C_n. However, there are two more infinite series of symmetry groups with this abstract group type:

• For even order 2n there is the group S_2n (Schoenflies notation) generated by a rotation by an angle 180°/n about an axis, combined with a reflection in the plane perpendicular to the axis. For S₂ the notation C_i is used; it is generated by inversion.
• For any order 2n where n is odd, we have C_nh; it has an n-fold rotation axis, and a perpendicular plane of reflection. It is generated by a rotation by an angle 360°/n about the axis, combined with the reflection. For C_1h the notation C_s is used; it is generated by reflection in a plane.

Thus we have, with bolding of the 10 cyclic crystallographic point groups, for which the crystallographic restriction applies:

Order	Isometry groups	Abstract group	# of order 2 elements	Cycle diagram
1	C1	Z1	0
2	C2, Ci, Cs	Z2	1
3	C3	Z3	0
4	C4, S4	Z4	1
5	C5	Z5	0
6	C6, S6, C3h	Z6 = Z3 × Z2	1
7	C7	Z7	0
8	C8, S8	Z8	1
9	C9	Z9	0
10	C10, S10, C5h	Z10 = Z5 × Z2	1

etc.

In 2D dihedral group D_n includes reflections, which can also be viewed as flipping over flat objects without distinction of front- and backside.

However, in 3D the two operations are distinguished: the symmetry group denoted by D_n contains n 2-fold axes perpendicular to the n-fold axis, not reflections. D_n is the rotation group of the n-sided prism with regular base, and n-sided bipyramid with regular base, and also of a regular, n-sided antiprism and of a regular, n-sided trapezohedron. The group is also the full symmetry group of such objects after making them chiral by e.g. an identical chiral marking on every face, or some modification in the shape.

The abstract group type is dihedral group Dih_n, which is also denoted by D_n. However, there are three more infinite series of symmetry groups with this abstract group type:

• C_nv of order 2n, the symmetry group of a regular n-sided pyramid
• D_nd of order 4n, the symmetry group of a regular n-sided antiprism
• D_nh of order 4n for odd n. For n = 1 we get D₂, already covered above, so n ≥ 3.

Note the following property:

Dih_4n+2 ${\displaystyle \cong }$  Dih_2n+1 × Z₂

Thus we have, with bolding of the 12 crystallographic point groups, and writing D_1d as the equivalent C_2h:

Order	Isometry groups	Abstract group	# of order 2 elements	Cycle diagram
4	D2, C2v, C2h	Dih2 = Z2 × Z2	3
6	D3, C3v	Dih3	3
8	D4, C4v, D2d	Dih4	5
10	D5, C5v	Dih5	5
12	D6, C6v, D3d, D3h	Dih6 = Dih3 × Z2	7
14	D7, C7v	Dih7	7
16	D8, C8v, D4d	Dih8	9
18	D9, C9v	Dih9	9
20	D10, C10v, D5h, D5d	Dih10 = D5 × Z2	11

etc.

C_2n,h of order 4n is of abstract group type Z_2n × Z₂. For n = 1 we get Dih₂, already covered above, so n ≥ 2.

Thus we have, with bolding of the 2 cyclic crystallographic point groups:

Order	Isometry group	Abstract group	# of order 2 elements	Cycle diagram
8	C4h	Z4 × Z2	3
12	C6h	Z6 × Z2 = Z3 × Z22 = Z3 × Dih2	3
16	C8h	Z8 × Z2	3
20	C10h	Z10 × Z2 = Z5 × Z22 = Z5 × Dih2	3

etc.

D_nh of order 4n is of abstract group type Dih_n × Z₂. For odd n this is already covered above, so we have here D_2nh of order 8n, which is of abstract group type Dih_2n × Z₂ (n≥1).

Thus we have, with bolding of the 3 dihedral crystallographic point groups:

Order	Isometry group	Abstract group	# of order 2 elements	Cycle diagram
8	D2h	Z23	7
16	D4h	Dih4 × Z2	11
24	D6h	Dih6 × Z2 = Dih3 × Z22	15
32	D8h	Dih8 × Z2	19

etc.

The remaining seven are, with bolding of the 5 crystallographic point groups (see also above):

Order	Isometry group	Abstract group	# of order 2 elements	Cycle diagram
12	T	A4	3
24	Td, O	S4	9
24	Th	A4 × Z2	7
48	Oh	S4 × Z2	19
60	I	A5	15
120	Ih	A5 × Z2	31

Disdyakis triacontahedron

The planes of reflection for icosahedral symmetry intersect the sphere on great circles, with right spherical triangle fundamental domains

The fundamental domain of a point group is a conic solid. An object with a given symmetry in a given orientation is characterized by the fundamental domain. If the object is a surface it is characterized by a surface in the fundamental domain continuing to its radial bordal faces or surface. If the copies of the surface do not fit, radial faces or surfaces can be added. They fit anyway if the fundamental domain is bounded by reflection planes.

For a polyhedron this surface in the fundamental domain can be part of an arbitrary plane. For example, in the disdyakis triacontahedron one full face is a fundamental domain of icosahedral symmetry. Adjusting the orientation of the plane gives various possibilities of combining two or more adjacent faces to one, giving various other polyhedra with the same symmetry. The polyhedron is convex if the surface fits to its copies and the radial line perpendicular to the plane is in the fundamental domain.

Also the surface in the fundamental domain may be composed of multiple faces.

The map Spin(3) → SO(3) is the double cover of the rotation group by the spin group in 3 dimensions. (This is the only connected cover of SO(3), since Spin(3) is simply connected.) By the lattice theorem, there is a Galois connection between subgroups of Spin(3) and subgroups of SO(3) (rotational point groups): the image of a subgroup of Spin(3) is a rotational point group, and the preimage of a point group is a subgroup of Spin(3). (Note that Spin(3) has alternative descriptions as the special unitary group SU(2) and as the group of unit quaternions. Topologically, this Lie group is the 3-dimensional sphere S³.)

The preimage of a finite point group is called a binary polyhedral group, represented as ⟨l,n,m⟩, and is called by the same name as its point group, with the prefix binary, with double the order of the related polyhedral group (l,m,n). For instance, the preimage of the icosahedral group (2,3,5) is the binary icosahedral group, ⟨2,3,5⟩.

The binary polyhedral groups are:

• ${\displaystyle A_{n}}$ : binary cyclic group of an (n + 1)-gon, order 2n
• ${\displaystyle D_{n}}$ : binary dihedral group of an n-gon, ⟨2,2,n⟩, order 4n
• ${\displaystyle E_{6}}$ : binary tetrahedral group, ⟨2,3,3⟩, order 24
• ${\displaystyle E_{7}}$ : binary octahedral group, ⟨2,3,4⟩, order 48
• ${\displaystyle E_{8}}$ : binary icosahedral group, ⟨2,3,5⟩, order 120

These are classified by the ADE classification, and the quotient of C² by the action of a binary polyhedral group is a Du Val singularity.^[6]

For point groups that reverse orientation, the situation is more complicated, as there are two pin groups, so there are two possible binary groups corresponding to a given point group.

Note that this is a covering of groups, not a covering of spaces – the sphere is simply connected, and thus has no covering spaces. There is thus no notion of a "binary polyhedron" that covers a 3-dimensional polyhedron. Binary polyhedral groups are discrete subgroups of a Spin group, and under a representation of the spin group act on a vector space, and may stabilize a polyhedron in this representation – under the map Spin(3) → SO(3) they act on the same polyhedron that the underlying (non-binary) group acts on, while under spin representations or other representations they may stabilize other polyhedra.

This is in contrast to projective polyhedra – the sphere does cover projective space (and also lens spaces), and thus a tessellation of projective space or lens space yields a distinct notion of polyhedron.

• Graphic overview of the 32 crystallographic point groups – form the first parts (apart from skipping n=5) of the 7 infinite series and 5 of the 7 separate 3D point groups
• Overview of properties of point groups
• Simplest Canonical Polyhedra of Each Symmetry Type (uses Java)
• Point Groups and Crystal Systems, by Yi-Shu Wei, pp. 4–6
• The Geometry Center: 10.1 Formulas for Symmetries in Cartesian Coordinates (three dimensions)