Abstract
Researchers and practitioners have focused on MCDM methodologies for analyzing, rating, and ranking alternatives in a variety of industries. In this paper, acetaldehyde is oxidized in several solvents, including CF, DCE, DCM, DMSO, ACETONE, and DMF, with BIFC, BPCC, PCC, MCC, and QFC. Due to uncertainty and ambiguity in measuring at different temperatures, it is not possible to classify the situation as crisp. We used a fuzzy approach to deal with the scenario. The TOPSIS technique is used to select the strongest solvent from a large number of available alternatives. With the help of the TOPSIS technique, we discovered that the declining sequence of solvents for rapid reactions is DMSO > DMF > DCE > ACETONE > DCM > CF.
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References
Corey, E.J., Suggs, W.J.: Pyridinium chlorochromate. An efficient reagent for oxidation of primary and secondary alcohols to carbonyl compounds. Tetrahedron Lett. 2647 (1975)
Guziec, F.S., Luzio, F.A.: Aquachloroiridium (III)-catalyzed oxidation of some unsaturated acids in acetone by acidic quinolinium fluorochromate. Synthesis 691 (1980)
Bhattacharjee, M.N., Choudhuri, M.K., Dasgupta, H.S., Roy, N., Khathing, D.T.: Pyridinium fluorochromate; a new and efficient oxidant for organic substrates. Synthesis 588 (1982)
Balasubramanian, K., Prathiba, V.: Quinolinium dichromate—A new reagent for oxidation of alcohols. Indian J. Chem. 25B, 326 (1986)
Pandurangan, A., Murugesan, V., Palamichamy, P.: Quinolinium bromochromate: A new, selective and efficient reagent for the oxidation of alcohols in anhydrous acetic acid. J. Indian Chem. Soc. 72, 479 (1995)
Agarwal, S., Choudhary, K., Banerji, K.K.: Kinetics and mechanism of the oxidation of the aromatic aldehydes by pyridinium fluorochromate. J. Org. Chem. 56, 5111 (1991)
Vadera, K., Yajurvedi, D., Purohit, P., Mishra, P., Sharma, P.K.: Structure-rate relationship in the oxidation of substituted benzaldehydes by pyridinium bromochromate: A Kinetic and mechanistic study. Proc. React. Kinet. Mech. 35, 265 (2010)
Gehlot, M., Prasadrao, P., Sharma, V.: Structure-reactivity correlation in the oxidation of substituted benzaldehydes by tetraethylammonium chlorochromate. Asian J. Chem. 23(3), 1173 (2011)
Pohani, S., Sharma, D., Panchariya, P., Sharma, P.K.: Structure-reactivity correlation in the oxidation of substituted benzaldehydes by quinolinium bromochromate. J. Ind. Council Chem. 27(2), 122 (2010)
Purohit, T., Banerji, J., Kotai, L., Banerji, K.K., Sharma, P.K.: Kinetics and mechanism of the oxidation of substituted benzaldehydes with bis-(pyridine) silver permanganate. J. Indian Chem. Soc. 89(8), 1045 (2012)
Barthora, S., Baghmar, D., Gilla, M., Choudhary, A., Sharma, V.: Structure-reactivity correlation in the oxidation of substituted benzaldehydes by benzyltriethylammonium chlorochromate. J. Chem. Biol. Phys. Sc. 1(1), 07 (2011)
Daiya, A., Purohit, P., Kumbhat, R., Kotai, L., Sharma, V.: Structure-rate-reactivity correlation in the oxidation of substituted benzaldehydes by imidazolium fluorochromate. Int. J. Chem. 1(2), 230 (2012)
Chouhan, K., Prasadrao, P., Sharma, P.K.: The kinetics and mechanism of oxidation of aliphatic aldehydes by benzyltriethylammonium chlorochromate. J. Indian Chem. Soc. 83, 191 (2006)
Kumbhat, R., Sharma, V., Banerji, K.K.: Kinetics and mechanism of oxidation of aliphatic aldehydes by quinolinium bromochromate. Oxid. Commun. 30(1), 97 (2007)
Patel, M., Poonam, Jha, K., Baghmar, M., Kothari, A., Shastri, I., Sharma, P.K.: Oxidation of some aliphatic aldehydes by tetrakis(pyridine) silver dichromate. Kinetics and mechanism of the (TPSD). J. Indian Chem. Soc. 89(8), 1149 (2012)
Soni, U., Yajurvedi, D., Vyas, S., Prakash, O., Sharma, P.K.: Correlation analysis of reactivity in the oxidation of substituted benzaldehydes by bis[dipyridinesilver(i)]dichromate. Eur. Chem. Bull. 4(9), 442 (2015)
Sharma, D., Panchariya, P., Purohit, P., Sharma, P.K.: Oxidation of aliphatic aldehydes by imidazolium fluorochromate (IFC): A kinetic and mechanistic study. Oxid Commun. 35(4), 821 (2012)
Panwar, S., Pohani, S., Swami, P., Vyas, S., Sharma, P.K.: Kinetics and mechanism of the oxidation of aliphatic aldehydes quinolinium chlorochromate. Eur. Chem. Bull. 2(10), 904 (2013)
Swami, P., Malani, N., Agarawal, S., Sharma, P.K.: Oxidation of aliphatic aldehydes by tetraethylammonium chlorochromate: A kinetic study. Prog. React. Kinet. Mech. 35, 309 (2010)
Sharma, P.K.: Structure-reactivity correlation in the oxidation of substituted benzaldehydes by 2, 2′-bipyridinium chlorochromate. J. Indian Chem. Soc. 85, 1281 (2008)
Choudhary, A., Malani, N., Agarwal, S., Sharma, M., Sharma, V.: Correlation analysis of reactivity in the oxidation of substituted benzaldehydes by morpholinium chlorochromate. J. Indian Chem. Soc. 86, 927 (2009)
Khurana, M., Sharma, P.K., Banerji, K.K.: Kinetics and mechanism of oxidation of aliphatic aldehydes by quinolinium fluorochromate. React. Kinet. Catal. Lett. 67, 341 (1999)
Kumbhat, V., Sharma, P.K., Banerji, K.K.: Kinetics and mechanism of oxidation of aliphatic aldehydes by 2, 2′-bipyridinium chlorochromate. Indian J. Chem. 39A, 1169 (2000)
Saraswat, S., Sharma, V., Banerji, K.K.: Kinetics and mechanism of oxidation of aliphatic aldehydes by pyridinium chlorochromate. Indian J. Chem. 40A, 583 (2001)
Soni, N., Kumbhani, S., Shastri, I., Sharma, V.: Kinetics and mechanism of the oxidation of aliphatic aldehydes by morpholinium chlorochromate. J. Indian Chem. Soc. 85, 857 (2008)
Asghar, B.H., Mansoor, S.S., Hussain, A.M., Malik, V.S., Aswin, K., Sudhan, S.P.N.: Oxidation of aliphatic aldehydes by benzimidazolium fluorochromate in non aqueous medium—A kinetic and mechanistic study. Arab. J. Chem. 10, S2115 (2017)
Chu, T.C., Lin, Y.C.: A fuzzy TOPSIS method for robot selection. Int. J. Adv. Manuf. Technol. 21(4), 284–290 (2003)
Wang, Y.M., Elhag, T.M.: Fuzzy TOPSIS method based on alpha level sets with an application to bridge risk assessment. Expert Syst. Appl. 31(2), 309–319 (2006)
Ashtiani, B., Haghighirad, F., Makui, A., Montazer, G.A.: Extension of fuzzy TOPSIS method based on interval-valued fuzzy sets. Appl. Soft Comput. 9(2), 457–461 (2009)
Şengül, U., Eren, M., Shiraz, S.E., Gezder, V., Şengül, A.B.: Fuzzy TOPSIS method for ranking renewable energy supply systems in Turkey. Renew. Energy 75, 617–625 (2015)
Gündoğdu, F.K., Kahraman, C.: Spherical fuzzy sets and spherical fuzzy TOPSIS method. J. Intell. Fuzzy Syst. 36(1), 337–352 (2019)
Rao, A., Kumar, G.: Comparative study of solvent effect by TOPSIS method in the oxidation of acetaldehyde. J. Appl. Chem. 8(4), 1798–1804 (2019)
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Rao, A., Kumar, G. (2023). The Effect of Solvents on the Oxidation of Acetaldehyde Using TOPSIS Method in a Fuzzy Environment. In: Sahoo, L., Senapati, T., Yager, R.R. (eds) Real Life Applications of Multiple Criteria Decision Making Techniques in Fuzzy Domain. Studies in Fuzziness and Soft Computing, vol 420. Springer, Singapore. https://doi.org/10.1007/978-981-19-4929-6_13
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