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14 pages, 7052 KiB  
Article
Effect of Subsurface Drainpipe Parameters on Soil Water and Salt Distribution in a Localized Arid Zone: A Field-Scale Study
by Hui Wang, Qianqian Zhu, Yuzhuo Pan, Xiaopeng Ma, Feng Ding, Wanli Xu, Yanbo Fu, Qingyong Bian and Mushajiang Kade
Agronomy 2025, 15(3), 678; https://doi.org/10.3390/agronomy15030678 (registering DOI) - 11 Mar 2025
Abstract
The salt distribution characteristics in arid areas are directly related to the sustainable development of agriculture. We study the characteristics of spatial changes of soil water and salt in farmland under the full anniversary of different culvert pipe arrangements and optimize the salt [...] Read more.
The salt distribution characteristics in arid areas are directly related to the sustainable development of agriculture. We study the characteristics of spatial changes of soil water and salt in farmland under the full anniversary of different culvert pipe arrangements and optimize the salt drainage parameters of underground drains suitable for the local area so as to promote the management of saline and alkaline land in Xinjiang. A subsurface drainpipe salinity test was conducted in the Yanqi Basin (Bayingoleng Mongolian Autonomous Prefecture, Xinjiang Uygur Autonomous Region, China) to analyze changes in soil water and salt dynamics before and after irrigation-induced salt flushing, assessing the impact of drainpipe deployment parameters. It was found that at a 1.4 m depth of burial, the maximum desalination rates of soil in different soil layers from the subsurface drainpipes in 20, 30, and 40 m spacing plots were 78.28%, 50.91%, and 54.52%, respectively. At a 1.6 m depth of burial, the maximum desalination rates of soil in different soil layers from the subsurface drainpipes in 20, 30, and 40 m spacing plots were 70.94%, 61.27%, and 44.12%. Reasonable deployment of subsurface drainpipes can effectively reduce soil salinity, increase the desalination rate, and improve soil water salinity condition. This study reveals the influence of the laying parameters of subsurface drainpipes on soil water salinity distribution characteristics in arid zones, which provides theoretical support and practical guidance for the management of soil salinization in arid zones. Full article
(This article belongs to the Section Water Use and Irrigation)
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<p>Schematic diagram of the underground drainage pipe arrangement and oil sunflower planting.</p>
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<p>Changes in soil water content under each treatment. The black error bar is the standard error plus or minus deviation value of three repeated samples. D1 and D2 represent the 1.4 m burial depth treatment and 1.6 m burial depth treatment, respectively. The 20 m (S1) horizontal sampling points are located at 0, 5, and 10 m from the treatment center drain, the 30 m (S2) horizontal sampling points are located at 0, 7.5, and 15 m from the treatment center drain, and the 40 m (S3) horizontal sampling points are located at 0, 10, and 20 m from the treatment center drain, i.e., directly above the center drain, at 1/4B and 1/2B.</p>
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<p>Changes in soil salinity under each treatment. The black error bar is the standard error plus or minus the deviation value of three repeated samples. D1 and D2 represent the 1.4 m burial depth treatment and 1.6 m burial depth treatment, respectively. The 20 m (S1) horizontal sampling points are located at 0, 5, and 10 m from the treatment center drain, the 30 m (S2) horizontal sampling points are located at 0, 7.5, and 15 m from the treatment center drain, and the 40 m (S3) horizontal sampling points are located at 0, 10, and 20 m from the treatment center drain, i.e., directly above the center drain, at 1/4B and 1/2B.</p>
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<p>Variation of soil salinity with different subsurface drainpipe spacings at depths of 1.4 m (<b>left</b>) and 1.6 m (<b>right</b>). * Indicates significant differences between treatments at the 0.05 level. ns means not significant.</p>
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20 pages, 7740 KiB  
Article
Sediment Provenance and Distribution on the Northwest African Continental Shelf
by Hasnaa Nait-Hammou, Khalid El Khalidi, Otmane Khalfaoui, Ahmed Makaoui, Melissa Chierici, Chaimaa Jamal, Mohammed Idrissi and Bendahhou Zourarah
J. Mar. Sci. Eng. 2025, 13(3), 537; https://doi.org/10.3390/jmse13030537 (registering DOI) - 11 Mar 2025
Abstract
This study analyzes the mineralogical and geochemical composition of 38 surface sediment samples from the northwest African continental shelf between Cap Boujdour (26.5° N) and Cap Blanc (20.5° N). Using a multiproxy approach, sediment characteristics were assessed through grain size, calcium carbonate (CaCO [...] Read more.
This study analyzes the mineralogical and geochemical composition of 38 surface sediment samples from the northwest African continental shelf between Cap Boujdour (26.5° N) and Cap Blanc (20.5° N). Using a multiproxy approach, sediment characteristics were assessed through grain size, calcium carbonate (CaCO3), and organic carbon (Corg) measurements, along with X-ray diffraction (XRD) and X-ray fluorescence (XRF) for geochemical analysis. Bottom water properties, including temperature, salinity, and dissolved oxygen, were measured at various stations using a Conductivity, Temperature, and Depth (CTD) sensor. The results reveal that the inner shelf sediments are primarily mud, with high concentrations of terrigenous elements such as iron (Fe), silicon (Si), rubidium (Rb), and potassium (K), with Fe and Si concentrations ranging from 2.1 to 4.3 wt%. The middle and outer shelf sediments are dominated by biogenic carbonates, with CaCO3 levels approaching 65%, and elevated calcium (Ca) and strontium (Sr) content. These areas also exhibit the highest bottom water temperatures (up to 16 °C), salinity (36%), and moderate oxygen levels (2–4 mL/L). Slope sediments are enriched with mud and montmorillonite, and aeolian contributions are more pronounced south of Dakhla, as indicated by elevated quartz levels (up to 20%) and the presence of illite, aluminum oxide (Al2O3), and iron oxide (Fe2O3). This study provides valuable new insights into sedimentary processes on the northwest African shelf, offering implications for regional environmental management and resource exploration. Full article
(This article belongs to the Section Geological Oceanography)
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<p>Geographic position of the study area and spatial distribution of the collected samples (General Bathymetric Chart of the Oceans).</p>
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<p>Distribution of hydrological parameters in the bottom water: (<b>a</b>) temperature (°C), (<b>b</b>) salinity (psu), and (<b>c</b>) dissolved oxygen (mL/L).</p>
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<p>Facies (<b>a</b>) and grain-size spatial distribution ((<b>b</b>): gravel%; (<b>c</b>): sand%; and (<b>d</b>): mud%) of collected samples.</p>
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<p>Spatial distribution of (<b>a</b>) calcium carbonate (CaCO<sub>3</sub>%), (<b>b</b>) organic carbon (Corg%), (<b>c</b>) calcium oxide (CaO%), (<b>d</b>) potassium oxide (K<sub>2</sub>O%), (<b>e</b>) strontium (Sr%), and (<b>f</b>) zirconium (Zr%) in the study area.</p>
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<p>Mineral composition percentage of collected samples organized according to depth (m).</p>
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<p>Spatial distribution of the main mineral phases in the study area with respect to (<b>a</b>) calcite%, (<b>b</b>) aragonite%, (<b>c</b>) dolomite%, and (<b>d</b>) quartz%.</p>
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<p>PCA results illustrating the main compositional trends in collected continental surface sediments. (<b>a</b>): Factor 1; (<b>b</b>): Factor 2; (<b>c</b>): PCA.</p>
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21 pages, 6757 KiB  
Article
Research on the Method of Extracting Water Body Information in Central Asia Based on Google Earth Engine
by Kai Chang, Wendie Yue, Hongzhi Wang, Kaijun Tan, Xinyu Liu, Xiaoyi Cao and Wenqian Chen
Water 2025, 17(6), 804; https://doi.org/10.3390/w17060804 (registering DOI) - 11 Mar 2025
Abstract
This study evaluates water body changes in Central Asia (2000–2019) using Landsat 7 data on Google Earth Engine, comparing the Modified Normalized Difference Water Index (MNDWI), OTSU algorithm, and random forest (RF). The random forest algorithm demonstrated the best overall performance in water [...] Read more.
This study evaluates water body changes in Central Asia (2000–2019) using Landsat 7 data on Google Earth Engine, comparing the Modified Normalized Difference Water Index (MNDWI), OTSU algorithm, and random forest (RF). The random forest algorithm demonstrated the best overall performance in water body extraction and was selected as the analysis tool. The results reveal a significant 11.25% decline in Central Asia’s total water area over two decades, with the Aral Sea shrinking by 72.13% (2000–2019) and southern Kyrgyzstan’s glaciers decreasing by 39.23%. Pearson correlations indicate strong links between water loss and rising temperatures (−0.5583) and declining precipitation (0.6872). Seasonal fluctuations and permanent degradation (e.g., dry riverbeds) highlight climate-driven vulnerabilities, exacerbated by anthropogenic impacts. These trends threaten regional water security and ecological stability, underscoring the urgent need for adaptive resource management. The RF-GEE framework proves effective for large-scale, long-term hydrological monitoring in arid regions, offering critical insights for climate resilience strategies. Full article
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<p>The scope of the Central Asian research area (The different background colors indicate different elevations).</p>
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<p>Flow Chart of This Study.</p>
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<p>Image of Water Body Extraction Using MNDWI.</p>
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<p>Image of Water Body Extraction Using OTSU Algorithm.</p>
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<p>Image of Water Body Extraction Using Random Forest Algorithm.</p>
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<p>Map of Water Body Area Changes in Central Asian Countries from 2000 to 2019.</p>
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<p>Changes in water area in the Aral Sea region.</p>
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<p>Map of changes in the area of various parts of the Aral Sea (It was not until 2003 that the East and West Aral Seas separated from the South Aral Sea).</p>
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<p>Changes in Glacier Area in Southern Kyrgyzstan.</p>
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<p>Annual variation chart of glacier cover area in southern Kyrgyzstan.</p>
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<p>Comparison Chart of Extraction Effects for Various Algorithms. (The research area for this study is selected from the northern part of the Aral Sea region).</p>
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<p>Annual variation chart of water area in Central Asia from 2000 to 2009 and correlation analysis chart of water area with annual average temperature and annual average precipitation, respectively.</p>
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17 pages, 4422 KiB  
Article
Effects of Microtopography on Neighborhood Diversity and Competition in Subtropical Forests
by Jianing Xu, Haonan Zhang, Yajun Qiao, Huanhuan Yuan, Wanggu Xu and Xin Xia
Plants 2025, 14(6), 870; https://doi.org/10.3390/plants14060870 - 11 Mar 2025
Viewed by 32
Abstract
Forests are complex systems in which subtle variations in terrain can reveal much about plant community structure and interspecific interactions. Despite a wealth of studies focusing on broad-scale environmental gradients, the role of fine-scale topographic nuances often remains underappreciated, particularly in subtropical settings. [...] Read more.
Forests are complex systems in which subtle variations in terrain can reveal much about plant community structure and interspecific interactions. Despite a wealth of studies focusing on broad-scale environmental gradients, the role of fine-scale topographic nuances often remains underappreciated, particularly in subtropical settings. In our study, we explore how minute differences in microtopography—encompassing local elevation, slope, aspect, terrain position index (TPI), terrain ruggedness index (TRI), and flow direction—affect neighborhood-scale interactions among plants. We established an 11.56-hectare dynamic plot in a subtropical forest at the northern margin of China’s subtropical zone, where both microtopographic factors and neighborhood indices (density, competition, diversity) were systematically measured using 5 m × 5 m quadrats. Parameter estimation and mixed-effects models were employed to examine how microtopography influences plant spatial patterns, growth, and competitive dynamics across various life stages. Our findings demonstrate that aspect and TPI act as key drivers, redistributing light and moisture to shape conspecific clustering, heterospecific competition, and tree growth. Remarkably, sun-facing slopes promoted sapling aggregation yet intensified competitive interactions, while shaded slopes maintained stable moisture conditions that benefited mature tree survival. Moreover, in contrast to broader-scale observations, fine-scale TRI was associated with reduced species richness, highlighting scale-dependent heterogeneity effects. The intensification of plant responses with life stage indicates shifting resource demands, where light is critical during early growth, and water becomes increasingly important for later survival. This study thus advances our multiscale understanding of forest dynamics and underscores the need to integrate fine-scale abiotic and biotic interactions into conservation strategies under global change conditions. Full article
(This article belongs to the Section Plant Ecology)
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<p>Parameter estimates for the effects of microtopographic factors (<b>a</b>–<b>f</b>) on seven neighborhood effect metrics at a scale of 5 m, with other test scales set at 2.5 m and 10 m; see <a href="#app1-plants-14-00870" class="html-app">Figure S1 in the Supplementary Files</a>. Dots represent estimated parameter effects, with error bars indicating standard errors. A semi-transparent gray dashed line indicates a null effect (parameter estimate of zero) in each subplot.</p>
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<p>Parameter estimates for the effects of microtopographic factors on conspecific neighborhood density (CND: <b>a</b>–<b>f</b>) and heterospecific neighborhood density (HND: <b>a1</b>–<b>f1</b>) across life stages at a scale of 5 m. Dots represent estimated coefficients, with error bars depicting standard errors. Positive coefficients indicate positive effects, while negative coefficients indicate negative effects. Significance levels: • <span class="html-italic">p</span> &lt; 0.1; * <span class="html-italic">p</span> &lt; 0.05; ** <span class="html-italic">p</span> &lt; 0.01; *** <span class="html-italic">p</span> &lt; 0.001. In the inset figure, R-squared values represent the regression coefficient for changes across life stages, and light gray lines illustrate the trend of effects across life stages. A semi-transparent gray dashed line indicates a null effect (parameter estimate of zero) in each subplot.</p>
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<p>Parameter estimates for the effects of microtopographic factors on individual tree diameter at breast height (DBH: <b>a</b>–<b>f</b>) and height (H: <b>a1</b>–<b>f1</b>) across life stages at a scale of 5 m. Dots represent estimated coefficients, with error bars depicting standard errors. Positive coefficients indicate positive effects, while negative coefficients indicate negative effects. Significance levels: • <span class="html-italic">p</span> &lt; 0.1; * <span class="html-italic">p</span> &lt; 0.05; ** <span class="html-italic">p</span> &lt; 0.01; *** <span class="html-italic">p</span> &lt; 0.001. In the inset figure, R-squared values represent the regression coefficient for changes across life stages, and light gray lines illustrate the trend of effects across life stages. A semi-transparent gray dashed line indicates a null effect (parameter estimate of zero) in each subplot.</p>
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<p>Parameter estimates for the effects of microtopographic factors on neighborhood species diversity (DBH: <b>a</b>–<b>f</b>), conspecific competition indices (H: <b>a1</b>–<b>f1</b>), and heterospecific competition indices (H: <b>a2</b>–<b>f2</b>) across life stages at a scale of 5 m. Dots represent estimated coefficients, with error bars depicting standard errors. Positive coefficients indicate positive effects, while negative coefficients indicate negative effects. Significance levels: • <span class="html-italic">p</span> &lt; 0.1; * <span class="html-italic">p</span> &lt; 0.05; ** <span class="html-italic">p</span> &lt; 0.01; *** <span class="html-italic">p</span> &lt; 0.001. In the inset figure, R-squared values represent the regression coefficient for changes across life stages, and light gray lines illustrate the trend of effects across life stages. A semi-transparent gray dashed line indicates a null effect (parameter estimate of zero) in each subplot.</p>
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<p>Microtopography of the monitoring plot and tree spatial distribution. This map presents the combined terrain factors, along with the fundamental elevation conditions, with black dots representing the spatial positions of individual trees.</p>
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<p>Spatial variation in the microtopographic predictor at the neighborhood scale: elevation (<b>a</b>), aspect (<b>b</b>), slope (<b>c</b>), terrain position index (<b>d</b>), terrain ruggedness index (<b>e</b>), and flow direction (<b>f</b>). The maps were generated using an Epanechnikov kernel with a bandwidth of 5, and the intensity values range from dark blue (low) to green (high).</p>
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22 pages, 5186 KiB  
Article
Microbial Metabolic Limitations and Their Relationships with Sediment Organic Carbon Across Lake Salinity Gradient in Tibetan Plateau
by Weizhen Zhang, Jianjun Wang, Yun Li, Chao Song, Yongqiang Zhou, Xianqiang Meng and Ruirui Chen
Microorganisms 2025, 13(3), 629; https://doi.org/10.3390/microorganisms13030629 (registering DOI) - 11 Mar 2025
Viewed by 189
Abstract
Inland lakes, contributing substantially to the global storage of sediment organic carbon (SOC), are subject to marked changes in salinity due to climate warming. The imbalance in the supply of resources, such as carbon, nitrogen, and phosphorus, in sediments leads to microbial metabolic [...] Read more.
Inland lakes, contributing substantially to the global storage of sediment organic carbon (SOC), are subject to marked changes in salinity due to climate warming. The imbalance in the supply of resources, such as carbon, nitrogen, and phosphorus, in sediments leads to microbial metabolic limitations (MMLs). This, in turn, triggers the secretion of extracellular enzymes by microorganisms to mine for deficient resources by decomposing complex organic carbon. This process is a rate-limiting step in the degradation of organic carbon and, as a result, has the potential to regulate organic carbon stocks. However, the general understanding of MML patterns and their relationships with SOC content along lake salinity gradients remains elusive. This study examined 25 lakes on the Tibetan Plateau with salinity ranging from 0.13‰ to 31.06‰, analyzing MMLs through enzymatic stoichiometry. The results showed that sediment microbial metabolism was mainly limited by carbon and nitrogen, with stronger limitations at higher salinity. Water salinity and sediment pH were the main factors influencing microbial limitations, either directly or indirectly, through their effects on nutrients and microbial diversity. Additionally, the SOC content was negatively correlated with microbial carbon limitation, a relationship weakened when salinity and pH were controlled. These findings suggest that the decrease in SOC with increased salinity or pH could be driven by stronger microbial carbon limitations, offering insights into the impact of salinity changes on SOC stocks in inland lakes due to climate change. Full article
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<p>Sampling sites of lake sediments in Tibetan Plateau. Dark green, light green, orange, and red points represent freshwater (salinity &lt; 0.5‰), subsaline (salinity = 0.5‰~3‰), hyposaline (salinity = 3‰~20‰), and mesosaline (salinity &gt; 20‰), respectively. Elevation is also shown according to color gradients.</p>
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<p>The linear regressions of the log-transformed water salinity with the SOC, TN, TP, SOC:TN, SOC:TP and TN:TP, and TP in the surface sediment (<b>a</b>–<b>f</b>). Only the significant fitted linear regressions are plotted with 95% confidence intervals filled in gray. Dark green, light green, orange, and red points represent freshwater (salinity &lt; 0.5‰), subsaline (salinity = 0.5‰~3‰), hyposaline (salinity = 3‰~20‰), and mesosaline (salinity &gt; 20‰), respectively. SOC: sediment organic carbon. TN: total nitrogen. TP: total phosphorus. The adjusted R<sup>2</sup> values of the linear models are denoted. * <span class="html-italic">p</span> &lt; 0.05, *** <span class="html-italic">p</span>&lt; 0.001.</p>
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<p>The stoichiometry of the enzymes C:(C+N) ratio (<b>a</b>) and enzymes C:(C+P) ratio (<b>b</b>), the vector analysis of enzymatic stoichiometry (<b>c</b>), a box plot comparing microbial C or N/P limitations among different salinity levels (<b>d</b>,<b>f</b>), and the linear correlations of logarithmically transformed lake salinity with logarithmically transformed microbial C limitation (<b>e</b>) and microbial N/P limitation (<b>g</b>) of lakes sediments in the Tibetan Plateau. BG, β-1,4-glucosidase; CBH, β-D-cellobiosidase; NAG, β-1,4-N-acetylglucosaminidase; LAP, L-leucine aminopeptidase; AP, alkaline phosphatase. A 1:1 dotted line is superimposed (<b>a</b>–<b>c</b>), which indicates equal investments into the compared element acquisition EEAs on the x and y axis. The letters above or below the boxes denote significances of differences in microbial C or N/P limitations among different salinity levels (<b>d</b>,<b>f</b>). A y = ln(45) dotted line is added (<b>g</b>) to estimate microbial N/P limitation, dots below (or above) are identified as N (or P) limitation. Dark green, light green, orange, and red points represent freshwater (salinity &lt; 0.5‰), subsaline (salinity = 0.5‰~3‰), hyposaline (salinity = 3‰~20‰), and mesosaline (salinity &gt; 20‰), respectively. The adjusted R<sup>2</sup> values of the linear models are denoted. *** <span class="html-italic">p</span> &lt; 0.001.</p>
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<p>The contributions of abiotic factors on microbial community attributes. The panels include random forest analyses of the richness of bacteria (<b>a</b>) and fungi (<b>b</b>), and multiple regression on dissimilarity matrices of bacterial (<b>c</b>) and fungal (<b>d</b>) communities. The columns filled with grey, green, orange, and red indicate climatic, geographic, nutrient variables, and pH and salinity, respectively. MAT: mean annual temperature. MAP: mean annual precipitation. SOC: sediment organic carbon. TN: total nitrogen. TP: total phosphorus. DOC: dissolved organic carbon. NH<sub>4</sub><sup>+</sup>: ammonia nitrogen. NO<sub>3</sub><sup>−</sup>: nitrate nitrogen. DIP: dissolved inorganic phosphorus. Chl-<span class="html-italic">a</span>: chlorophyll-<span class="html-italic">a</span>. The significance of each variable is shown above the column. * <span class="html-italic">p</span> &lt; 0.05, ** <span class="html-italic">p</span> &lt; 0.01, *** <span class="html-italic">p</span> &lt; 0.001.</p>
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<p>The effects of abiotic factors and microbial diversity on microbial metabolic limitations based on random forest analyses (<b>a</b>,<b>d</b>), variance partitioning analyses (<b>b</b>,<b>e</b>), and partial least squares path modeling (PLS-PM) (<b>c</b>,<b>f</b>). The total effects of nutrients, pH and salinity and microbial diversity on the microbial C and N/P limitations according to the PLS-PMs are shown in the top-left corners of panels (<b>c</b>) and (<b>f</b>), respectively. The path coefficients indicating the effect sizes are shown adjacent to the arrows with the arrow width proportional to the path coefficients and arrow color (red/blue) representing correlation directions (positive/negative), and the goodness of fit for PLS-PMs are denoted (<b>c</b>,<b>f</b>). The abiotic factors include climate factors, elevation, nutrients, and pH and salinity. Climate factors include MAT (mean annual temperature) and MAP (mean annual precipitation). Nutrients include Chl-<span class="html-italic">a</span>, TN, TP, and TN:TP ratio in water and TN, TP, SOC, NH<sub>4</sub><sup>+</sup>, NO<sub>3</sub><sup>−</sup>, DIP, DOC, SOC:TN, SOC:TP, and TN:TP in sediments. Microbial diversity includes the richness of bacteria and fungi, and the community structures of bacteria and fungi reflected by the DCA1 (first axis of detrended correspondence analysis of the community). The columns filled with grey, green, red, orange, and blue indicate climate factors, elevation, pH and salinity, nutrients, and microbial diversity, respectively. Since climate factors and elevation had nonsignificant effects on microbial C or N/P limitations (<b>a</b>,<b>d</b>), these two factors were excluded in the PLS-PM and variance partitioning analyses (<b>b</b>,<b>c</b>,<b>e</b>,<b>f</b>). For panels (<b>a</b>) and (<b>d</b>), the significance of each variable is shown above the column, * <span class="html-italic">p</span> &lt; 0.05, ** <span class="html-italic">p</span> &lt; 0.01. MAT: mean annual temperature. MAP: mean annual precipitation. SOC: sediment organic carbon. TN: total nitrogen. TP: total phosphorus. DOC: dissolved organic carbon. NH<sub>4</sub><sup>+</sup>: ammonia nitrogen. NO<sub>3</sub><sup>−</sup>: nitrate nitrogen. DIP: dissolved inorganic phosphorus. Chl-<span class="html-italic">a</span>: chlorophyll-<span class="html-italic">a</span>.</p>
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<p>Relationships of SOC (sediment organic carbon) content with microbial resource limitations, including linear regressions between logarithmically transformed SOC and microbial C (<b>a</b>,<b>d</b>) or N/P limitation (<b>b</b>,<b>e</b>) and partial linear regressions between logarithmically transformed SOC and microbial C limitation when respectively controlling for water salinity (<b>c</b>) and sediment pH (<b>f</b>). Dark green, light green, orange, and red dots represent freshwater (salinity &lt; 0.5‰), subsaline (salinity = 0.5‰~3‰), hyposaline (salinity = 3‰~20‰), and mesosaline (salinity &gt; 20‰) sampling sites, respectively. For (<b>d</b>) and (<b>e</b>), dot colors represent pH values with deeper grey indicating higher pH. Only significant fitted linear regressions are plotted with 95% confidence intervals filled in gray. Adjusted R<sup>2</sup> values of linear models are denoted. ** <span class="html-italic">p</span> &lt; 0.01, * <span class="html-italic">p</span> &lt; 0.05.</p>
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18 pages, 3517 KiB  
Article
Synthesis and Characterization of Novel Non-Isocyanate Polyurethanes Derived from Adipic Acid: A Comprehensive Study
by Maria Angeliki G. Ntrivala, Evangelia D. Balla, Panagiotis A. Klonos, Apostolos Kyritsis and Dimitrios N. Bikiaris
Polymers 2025, 17(6), 728; https://doi.org/10.3390/polym17060728 - 10 Mar 2025
Viewed by 150
Abstract
The increasing quest for greener and more sustainable polymeric materials has gained interest in the past few decades. Non-isocyanate polyurethanes (NIPUs) have attracted attention considering that they are produced through less toxic methods compared to the conventional polyurethanes (PUs) obtained from petroleum resources [...] Read more.
The increasing quest for greener and more sustainable polymeric materials has gained interest in the past few decades. Non-isocyanate polyurethanes (NIPUs) have attracted attention considering that they are produced through less toxic methods compared to the conventional polyurethanes (PUs) obtained from petroleum resources and toxic isocyanates. In this context, adipic acid, glycerol carbonate, 1,2-ethylenediamine, and 1,6-hexamethylenediamine, were used to synthesize NIPU_ethyl and NIPU_hexa, respectively. The obtained NIPUs were characterized using nuclear magnetic resonance spectroscopy (H-NMR spectra) and Fourier-transform infrared spectroscopy (FTIR) analysis, which verified the structures of the intermediate and final products. Calorimetric and dielectric studies provided direct and indirect support for the facilitated thermal stability of NIPU_ethyl and NIPU_hexa. Compared to the intermediate product, the NIPUs exhibit elevated glass transition temperatures, suggesting the formation of more rigid structures. The NIPUs were also tested in terms of swelling properties, and the results indicated that NIPU_hexa absorbs and withholds increased amounts of water for longer time periods compared to NIPU_ethyl, and their hydrolysis and enzymatic hydrolysis confirmed that NIPU_hexa is more stable in aqueous environments than NIPU_ethyl. Therefore, the successful production of adipic-acid-based NIPUs through a novel perspective of the polyaddition path is reported and complemented by the characterization of the obtained materials with several techniques. Full article
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Graphical abstract
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<p>First-step reaction leading to the formation of the intermediate product (ester), and second-step reaction leading to the formation of NIPU_ethyl and NIPU_hexa.</p>
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<p>H-NMR spectra of adipic acid and the intermediate.</p>
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<p>H-NMR spectra of NIPU_ethyl and NIPU_hexa.</p>
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<p>FTIR spectra of adipic acid, the intermediate product, NIPU_ethyl, and NIPU_hexa.</p>
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<p>Comparative DSC traces for all the samples and scans performed. The heat flow is presented upon normalization to each sample’s mass.</p>
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<p>Comparative DSC traces for all the samples during heating in (<b>a</b>) scan 1 and (<b>b</b>) scan 2. The heat flow has been normalized to the sample’s mass.</p>
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<p>Comparative isochronal ε”(T) plots for all the samples, shown at (<b>a</b>) a relatively low frequency of 100 mHz, namely, closer to the equivalent frequency of the DSC at T<sub>g</sub>, and (<b>b</b>) a higher frequency of ~3 kHz to suppress the extensive contribution of the conductivity at the higher T. Marked in both figures are the values of the calorimetric T<sub>g</sub> for heating in scan 2.</p>
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<p>TGA thermogram (mass loss (%)–temperature (°C)) graphs for adipic acid, the intermediate, NIPU_ethyl, and NIPU_hexa.</p>
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<p>(<b>Left</b>) DTG–temperature (°C) and (<b>right</b>) heat flow–temperature graphs (thermograms) for adipic acid, the intermediate, NIPU_ethyl, and NIPU_hexa.</p>
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<p>Hydrolysis and enzymatic hydrolysis of NIPU_ethyl and NIPU_hexa.</p>
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<p>Swelling capacity in terms of the water contents of NIPU_ethyl and NIPU_hexa.</p>
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<p>Weights of NIPU_ethyl and NIPU_hexa at various pH levels.</p>
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27 pages, 6566 KiB  
Article
Climate Change and Its Impact on Natural Resources and Rural Livelihoods: Gendered Perspectives from Naryn, Kyrgyzstan
by Azamat Azarov, Maksim Kulikov, Roy C. Sidle and Vitalii Zaginaev
Climate 2025, 13(3), 57; https://doi.org/10.3390/cli13030057 - 10 Mar 2025
Viewed by 204
Abstract
Climate change poses significant threats to rural communities in Kyrgyzstan, particularly for agriculture, which relies heavily on natural resources. In Naryn Province, rising temperatures and increasing natural hazards amplify vulnerabilities, especially in high mountain areas. Addressing these challenges requires understanding both environmental factors [...] Read more.
Climate change poses significant threats to rural communities in Kyrgyzstan, particularly for agriculture, which relies heavily on natural resources. In Naryn Province, rising temperatures and increasing natural hazards amplify vulnerabilities, especially in high mountain areas. Addressing these challenges requires understanding both environmental factors and the perceptions of affected communities, as these shape adaptive responses. This study enhances understanding of climate change impacts on communities in Naryn Province by combining environmental and social assessments through a gendered lens, with a particular focus on women. Environmental data, including air temperature, precipitation, river discharge, and satellite-derived vegetation indices, were analyzed to evaluate changes in vegetation and water resources. Social data were collected through interviews with 298 respondents (148 women and 150 men) across villages along the Naryn River, with chi-square analysis used to examine gender-specific perceptions and impacts on livelihoods. The results indicated a noticeable rise in temperatures and a slight decline in precipitation over recent decades, affecting vegetation and grazing areas near settlements. While respondents of both genders reported similar observations, differences emerged in how changes affect their roles and activities, with localized variations linked to household and agricultural responsibilities. The findings highlight the need for inclusive adaptation strategies that address diverse experiences and priorities, providing a foundation for equitable and effective climate resilience measures. Full article
(This article belongs to the Section Climate Adaptation and Mitigation)
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<p>Research area in the Naryn River valley, Kyrgyzstan. (Sources: OSM, ESRI).</p>
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<p>Different land use land cover classes in the study area.</p>
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<p>Monthly distribution of (<b>a</b>) discharge, (<b>b</b>) precipitation, and (<b>c</b>) temperature (2000–2023) in the Naryn River basin (green triangle refers to the mean value).</p>
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<p>Land use classes in the Naryn River basin. (Sources: OSM, ESRI, ESA).</p>
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<p>Monthly NDVI distribution of different land use classes (2000–2023).</p>
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<p>Linear trend of NDVI in the Naryn River basin. (Sources: OSM, ESRI, and ESA). The pixels with <span class="html-italic">p</span>-value &gt; 0.05 are shaded in blue.</p>
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<p>Seasonal and trend decomposition of the Naryn River discharge data (1940–2023).</p>
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<p>Seasonal and trend decomposition of temperature data in Naryn town (1940–2023).</p>
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<p>Seasonal and trend decomposition of precipitation data in Naryn town (1940–2023).</p>
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<p>Gender profile of respondents by age and education level.</p>
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<p>Respondents’ perceptions of increased hazards and their impacts.</p>
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<p>Perceptions of the impact of climate change on various household aspects.</p>
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22 pages, 4291 KiB  
Article
Experimental Study on the Evolution Law of Loess Cracks Under Dry–Wet Cycle Conditions
by Chunyan Zhang, Dantong Lin, Guizhang Zhao, Zhenzhen Qi, Kui Suo, Hao Liu and Chengyang Jiang
Water 2025, 17(6), 796; https://doi.org/10.3390/w17060796 - 10 Mar 2025
Viewed by 94
Abstract
The experiment of loess crack development under dry–wet cycle conditions is of great significance for the study of groundwater preferential flow channels and the prevention and control of infrastructure engineering disasters in loess areas. The loess samples in Chencang District of Baoji City, [...] Read more.
The experiment of loess crack development under dry–wet cycle conditions is of great significance for the study of groundwater preferential flow channels and the prevention and control of infrastructure engineering disasters in loess areas. The loess samples in Chencang District of Baoji City, Shaanxi Province, were taken as the samples in the test. The multiple humidification and dehumidification tests were used to simulate multiple rainfall evaporation, and the moisture content changes in the loess samples during the dry–wet cycle were calculated. With the help of digital image technology, the fracture parameters of the loess samples were extracted, and the variation law of crack parameters was analyzed by combining fractal dimension, Bayesian factor, and Pearson correlation coefficient. The findings indicate that variations in soil moisture content and the number of dry and wet cycles contribute to fluctuations in soil evaporation rates, resulting in varying degrees of soil cracking development. The increase in the number of dry and wet cycles leads to evident soil shrinkage, an accelerated water evaporation process, pronounced surface deterioration, and a higher degree of crack development. The rate of crack propagation varies at different locations, with a higher rate observed in the horizontal plane compared to the vertical plane. The influence of temperature and humidity varies due to the different dimensions of cracks (horizontal and vertical). Horizontal crack development is primarily influenced by temperature, while vertical crack development is primarily influenced by humidity. Temperature and humidity inhibit each other. When one factor is dominant, the other indirectly affects crack development by influencing the dominant factor. The research findings can serve as a valuable reference for effectively mitigating and minimizing the impact of crack development-induced disasters. Full article
(This article belongs to the Section Soil and Water)
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<p>Schematic diagram of experimental device.</p>
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<p>Process diagram of dry and wet cycle.(Color note: The yellow arrow is sunlight; The blue color in the bottom three circles indicates more water. The soil from wet to dry to wet is regarded as a dry and wet cycle.)</p>
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<p>Moisture content variations during dry–wet cycling process.</p>
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<p>Original image and processed image of crack.</p>
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<p>Horizontal crack development diagram of dry and wet cycle, (<b>a<sub>1</sub></b>–<b>a<sub>5</sub></b>), (<b>b<sub>1</sub></b>–<b>b<sub>5</sub></b>), (<b>c<sub>1</sub></b>–<b>c<sub>5</sub></b>), (<b>d<sub>1</sub></b>–<b>d<sub>5</sub></b>), which are, respectively, cycle 1 to 4 times of horizontal fracture. (Color note: Diverse colors are utilized in PCAS software to distinguish various crack angles, such as micro-tensile cracks, as indicated below).</p>
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<p>Vertical crack development diagram of dry and wet cycle (<b>a<sub>1</sub></b>–<b>a<sub>5</sub></b>), (<b>b<sub>1</sub></b>–<b>b<sub>5</sub></b>), (<b>c<sub>1</sub></b>–<b>c<sub>5</sub></b>), (<b>d<sub>1</sub></b>–<b>d<sub>5</sub></b>), which are, respectively, cycle 1 to 4 times of vertical fracture.(Color note: Diverse colors are utilized in PCAS software to distinguish various crack angles, such as micro-tensile cracks, as indicated below).</p>
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<p>Relationship between moisture content and crack ratio. (<b>a</b>–<b>d</b>) show relationship between crack ratio and moisture content in 1st to 4th cycles, respectively. (<b>e</b>,<b>f</b>) are error bar graphs of horizontal cracks and vertical cracks under condition of 4th cycles, respectively.</p>
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<p>Relationship between moisture content and fractal dimension. (<b>a</b>) (a<sub>1</sub>–a<sub>4</sub>) are fractal dimension graphs of horizontal cracks in which four groups of parallel dry–wet cycle experiments were carried out. (<b>b</b>) (b<sub>1</sub>–b<sub>4</sub>) are fractal dimension graphs of vertical cracks in which four groups of parallel dry–wet cycle experiments were carried out.</p>
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<p>Relationship between moisture content and fractal dimension. (<b>a</b>) (a<sub>1</sub>–a<sub>4</sub>) are fractal dimension graphs of horizontal cracks in which four groups of parallel dry–wet cycle experiments were carried out. (<b>b</b>) (b<sub>1</sub>–b<sub>4</sub>) are fractal dimension graphs of vertical cracks in which four groups of parallel dry–wet cycle experiments were carried out.</p>
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<p>Paired Bayesian correlation heat maps of temperature, humidity, and dry and wet cycle for cracks in different directions: (<b>a</b>) is heat map of Bayesian factor inference, and (<b>b</b>,<b>c</b>) are heat maps of mode and average value in posterior distribution characteristics of paired correlation, respectively.</p>
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<p>Paired Bayesian correlation heat maps of temperature, humidity, and dry and wet cycle for cracks in different directions: (<b>a</b>) is heat map of Bayesian factor inference, and (<b>b</b>,<b>c</b>) are heat maps of mode and average value in posterior distribution characteristics of paired correlation, respectively.</p>
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24 pages, 8336 KiB  
Article
Optimal Site Selection for Wind and Solar Parks in Karpathos Island Using a GIS-MCDM Model
by Maria Margarita Bertsiou, Aimilia Panagiota Theochari, Dimitrios Gergatsoulis, Michalis Gerakianakis and Evangelos Baltas
ISPRS Int. J. Geo-Inf. 2025, 14(3), 125; https://doi.org/10.3390/ijgi14030125 - 10 Mar 2025
Viewed by 118
Abstract
This research paper examines how to assess potential locations for wind turbines and photovoltaic modules by combining Geographic Information Systems (GIS) with multi-criteria decision-making (MCDM). These potential locations depend on the current legislation, where many areas are buffer zones due to limitations. The [...] Read more.
This research paper examines how to assess potential locations for wind turbines and photovoltaic modules by combining Geographic Information Systems (GIS) with multi-criteria decision-making (MCDM). These potential locations depend on the current legislation, where many areas are buffer zones due to limitations. The study area is Karpathos, which faces energy and water scarcity. The need to increase the penetration rate of renewable energy sources (RES) by 2030 can help this island to fulfill both its energy and water needs through RES. To apply the weighted linear combination technique, this approach considers all eligibility criteria according to the legislation. After classifying them into four zones, the MCDM results in a suitability map that displays the spatial distribution of the final score, ranging from sites that are not appropriate to areas that are highly suitable. In the photovoltaic module scenario, the buffer zone corresponds to 61% of the island, while in the wind turbine scenario, this number increases to 85%, highlighting the difficulty of finding suitable sites. A sensitivity analysis is performed to determine the impact of the criteria on the suitability of a site for both scenarios. Full article
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<p>The island of Karpathos (digital elevation model by the National Cadastre and Mapping Agency S.A. after editing with ArcMap).</p>
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<p>Workflow chart of the methodology.</p>
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<p>(<b>a</b>) Wind speeds; (<b>b</b>) Solar radiation.</p>
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<p>Level of: (<b>a</b>) settlements; (<b>b</b>) beaches; (<b>c</b>) archeological sites; (<b>d</b>) holy monasteries; (<b>e</b>) mobile network antennas; (<b>f</b>) airports; (<b>g</b>) Natura; (<b>h</b>) wildlife sanctuaries; and (<b>i</b>) road networks.</p>
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<p>Buffer zones for each constraint: (<b>a</b>) settlements; (<b>b</b>) beaches; (<b>c</b>) archeological sites; (<b>d</b>) holy monasteries; (<b>e</b>) mobile network antennas; and (<b>f</b>) road networks.</p>
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<p>Buffer zones for each constraint: (<b>a</b>) settlements; (<b>b</b>) beaches; (<b>c</b>) archeological sites; (<b>d</b>) holy monasteries; (<b>e</b>) mobile network antennas; and (<b>f</b>) road networks.</p>
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<p>Standardized criteria for WT optimal site selection: (<b>a</b>) wind potential; (<b>b</b>) altitudes; (<b>c</b>) terrain slopes; (<b>d</b>) settlements; (<b>e</b>) beaches; (<b>f</b>) archeological sites; (<b>g</b>) holy monasteries; (<b>h</b>) mobile network antennas; (<b>i</b>) airports; (<b>j</b>) Natura areas; (<b>k</b>) wildlife sanctuaries; and (<b>l</b>) road networks.</p>
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<p>Standardized criteria for WT optimal site selection: (<b>a</b>) wind potential; (<b>b</b>) altitudes; (<b>c</b>) terrain slopes; (<b>d</b>) settlements; (<b>e</b>) beaches; (<b>f</b>) archeological sites; (<b>g</b>) holy monasteries; (<b>h</b>) mobile network antennas; (<b>i</b>) airports; (<b>j</b>) Natura areas; (<b>k</b>) wildlife sanctuaries; and (<b>l</b>) road networks.</p>
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<p>Standardized criteria for PV optimal site selection: (<b>a</b>) solar potential; (<b>b</b>) settlements; (<b>c</b>) beaches; (<b>d</b>) archeological sites; (<b>e</b>) holy monasteries; and (<b>f</b>) road networks.</p>
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<p>Final score map for WT site selection.</p>
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<p>Final score mar for PV site selection.</p>
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<p>Sensitivity analysis for the WT site selection for changes in the weight of the wind potential: (<b>a</b>) −20%, (<b>b</b>) −10%, (<b>c</b>) +10%, and (<b>d</b>) +20%.</p>
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<p>Sensitivity analysis for the WT site selection for changes in the weight of the mobile network antennas: (<b>a</b>) −20%, (<b>b</b>) −10%, (<b>c</b>) +10%, and (<b>d</b>) +20%.</p>
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<p>Sensitivity analysis for the PV site selection for changes in the weight of the solar potential: (<b>a</b>) −20%, (<b>b</b>) −10%, (<b>c</b>) +10%, and (<b>d</b>) +20%.</p>
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<p>Sensitivity analysis for the PV site selection for changes in the weight of the holy monasteries: (<b>a</b>) −20%, (<b>b</b>) −10%, (<b>c</b>) +10%, and (<b>d</b>) +20%.</p>
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20 pages, 21648 KiB  
Article
Spatial–Temporal Heterogeneity of Wetlands in the Alpine Mountains of the Shule River Basin on the Northeastern Edge of the Qinghai–Tibet Plateau
by Shuya Tai, Donghui Shangguan, Jinkui Wu, Rongjun Wang and Da Li
Remote Sens. 2025, 17(6), 976; https://doi.org/10.3390/rs17060976 - 10 Mar 2025
Viewed by 88
Abstract
Alpine wetland ecosystems, as important carbon sinks and water conservation areas, possess unique ecological functions. Driven by climate change and human activities, the spatial distribution changes in alpine wetlands directly affect the ecosystems and water resource management within a basin. To further refine [...] Read more.
Alpine wetland ecosystems, as important carbon sinks and water conservation areas, possess unique ecological functions. Driven by climate change and human activities, the spatial distribution changes in alpine wetlands directly affect the ecosystems and water resource management within a basin. To further refine the evolution processes of different types of alpine wetlands in different zones of a basin, this study combined multiple field surveys, unmanned aerial vehicle (UAV) flights, and high-resolution images. Based on the Google Earth Engine (GEE) cloud platform, we constructed a Random Forest model to identify and extract alpine wetlands in the Shule River Basin over a long-term period from 1987 to 2021. The results indicated that the accuracy of the extraction based on this method exceeded 90%; the main wetland types are marsh, swamp meadow, and river and lake water bodies; and the spatial–temporal distribution of each wetland type has obvious heterogeneity. In total, 90% of the swamp meadows areas were mainly scattered throughout the study area’s section 3700 to 4300 m above sea level (a.s.l.), and 80% of the marshes areas were concentrated in the Dang River source 3200 m above sea level. From 1987 to 2021, the alpine wetland in the study area showed an overall expansion trend. The total area of the wetland increased by 51,451.8 ha and the area increased by 53.5%. However, this expansion mainly occurred in the elevation zone below 4000 m after 2004, and low-altitude marsh wetland primarily dominated the expansion. The analysis of the spatial–temporal heterogeneity of alpine wetlands can provide a scientific basis for the attribution analysis of the change in alpine wetlands in inland water conservation areas, as well as for protection and rational development and utilization, and promote the healthy development of ecological environments in nature reserves. Full article
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<p>A study area diagram showing the following: (<b>a</b>) the location of the Shule River Basin in China, the dashed line indicates the coastline of China; (<b>b</b>) the location of the study area on the Shule River Basin; (<b>c</b>) study area information and field samples taken with a UAV and digital camera. The towns Suli (SL), Yanchiwan (YCW), and Changma (CM) are indicated by the red pentagram.</p>
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<p>A workflow for wetland mapping.</p>
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<p>Wetland types (the red lines show the example areas). (<b>a</b>,<b>b</b>) classification maps of the examples; (<b>c</b>,<b>d</b>) higher-resolution images of the examples; (<b>e</b>,<b>f</b>) UAV images of the examples; (<b>g</b>,<b>h</b>) field photos of the examples corresponding to the red line areas.</p>
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<p>Land cover distribution of the study area in 2021 and the proportion of different land cover types, the proportion of different wetland types in the study area.</p>
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<p>Elevation distribution of wetlands in 2021. Lines in corresponding colors indicate the fitted lines of the columnar distribution.</p>
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<p>Spatial distribution characteristics of wetlands in typical areas in 1987, 2003, and 2021.</p>
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<p>Trends in the marsh at different altitudes.</p>
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<p>Trends in swamp meadows at different altitudes.</p>
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<p>Spatial consistency analysis: (<b>a</b>) SL classification results vs. Globeland30 and GLC_FCS30; (<b>b</b>) SL classification results vs. ESA worldcover and FROM_GLC; (<b>c</b>) YCW classification results vs. Globeland30 and GLC_FCS30; (<b>d</b>) YCW classification results vs. ESA worldcover and FROM_GLC.</p>
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<p>Annual average temperature (<b>a</b>) and precipitation (<b>b</b>) in Tuole National Meteorological Station and Dangchengwan Hydrology Station from the 1987 to 2021.</p>
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15 pages, 2156 KiB  
Review
A Mini Review of Research Trends of Phytoplankton in Chinese Reservoirs: Based on CiteSpace’s Analysis of Bibliometrics
by Zhihui Liu, Huiying Wu, Qi Chen, Weizhu Deng and Heng Liu
Water 2025, 17(6), 797; https://doi.org/10.3390/w17060797 - 10 Mar 2025
Viewed by 209
Abstract
This study employs bibliometric analysis and knowledge mapping to examine trends in research on phytoplankton in Chinese reservoirs from 2004 to 2024. Utilizing the Web of Science Core Collection Database, the analysis focuses on studies related to reservoirs, phytoplankton, and cyanophytes in China. [...] Read more.
This study employs bibliometric analysis and knowledge mapping to examine trends in research on phytoplankton in Chinese reservoirs from 2004 to 2024. Utilizing the Web of Science Core Collection Database, the analysis focuses on studies related to reservoirs, phytoplankton, and cyanophytes in China. Three distinct stages in the evolution of phytoplankton research are identified: initial studies on lakes and eutrophication (2004–2010), a shift towards cyanobacteria blooms and their ecological impacts (2010–2015), and a recent focus on phytoplankton communities, carbon cycles, and nutrient cycles (2015–2024). Key hotspots such as nitrogen stable isotopes, reservoir management, lakes, and cyanobacterial blooms are identified. This study highlights a growing interest in environmental factors influencing ecosystems, biodiversity conservation, and nutrient status assessment. These findings provide a comprehensive understanding of phytoplankton research in Chinese reservoirs, revealing research hotspots, regional differences, and future directions. A collaboration network analysis among institutions and authors underscores significant contributions from the Chinese Academy of Sciences and key researchers. This study provides a foundation for future research, emphasizing the importance of addressing eutrophication, phytoplankton community dynamics, and ecosystem degradation in reservoirs. Full article
(This article belongs to the Special Issue Research on the Dynamics of Phytoplankton in Eutrophic Water)
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<p>The geographical distribution of relevant research articles in China at the province level. The color ranges in the figure legend from white to dark blue, indicating that the number of studies ranges from few to many. Dark blue areas indicate a higher number of studies, light blue areas indicate fewer studies, and white areas indicate no studies.</p>
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<p>Trends in the number of publications on phytoplankton in Chinese reservoirs from 2004 to 2024.</p>
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<p>(<b>A</b>) Time zone view map for the keywords in Web of Science articles from 2004 to 2024 (generated by CiteSpace). (<b>B</b>) Network fisheye diagram of timeline co-occurrence keywords. Concentric circles at each node represent the history of the tree ring.</p>
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<p>Top 25 keywords with strongest citation bursts.</p>
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17 pages, 3600 KiB  
Article
Analyzing the Source of Sulfate in Karst Groundwater Based on a Bayesian Stable Isotope Mixing Model: A Case Study of Xujiagou Spring Area, Northern China
by Yun Lin, Yiyang Wang, Yazun Wu and Boyang Xu
Water 2025, 17(6), 794; https://doi.org/10.3390/w17060794 - 10 Mar 2025
Viewed by 164
Abstract
The source of sulfate in the groundwater of karst springs in the northern Taihang Mountains remains unclear due to the influence of multiple factors. To investigate this, 33 sampling points were selected in August 2022 across the exposed, covered, and buried areas of [...] Read more.
The source of sulfate in the groundwater of karst springs in the northern Taihang Mountains remains unclear due to the influence of multiple factors. To investigate this, 33 sampling points were selected in August 2022 across the exposed, covered, and buried areas of the spring basin, and water samples were collected. Hydrochemistry and sulfur–oxygen dual isotope methods were employed to examine the distribution characteristics of sulfate, δ18OSO4, and δ34SSO4. Based on the distinct characteristics of sulfur isotopes from different sources, the sources of sulfate in various environments were qualitatively analyzed. Additionally, the contribution rates of each source were quantitatively determined using a Bayesian stable isotope mixing model. The results showed that the sulfate content in karst groundwater ranged from 16.68 to 156.84 mg/L, with an average of 62.22 mg/L, and indicated an increasing trend from exposed to covered to buried areas. The δ34SSO4 values in karst groundwater ranged from 3.1‰ to 13.5‰, with an average of 6.49‰, while the δ18OSO4 values ranged from 2.9‰ to 10.3‰, with an average of 5.49‰. The δ34SSO4 values showed a general increasing trend across the exposed, covered, and buried areas, whereas the δ18OSO4 values remained relatively stable across these areas. The analysis revealed that the primary sulfate sources in the exposed area were atmospheric precipitation, soil sulfate, chemical fertilizer, and sewage, contributing 19.6%, 63.5%, 9.4%, and 7.5%, respectively. In the covered area, the main sources were atmospheric precipitation, sulfide oxidation, soil sulfate, and gypsum dissolution, with contributions of 16.5%, 58.7%, 15.9%, and 8.9%, respectively. In the buried area, the sulfate primary originated from atmospheric precipitation, sulfide oxidation, and gypsum dissolution, contributing 11.6%, 78.5%, and 9.9%, respectively. This study provides critical insights into the sulfate sources in different environments, enhancing the understanding of groundwater sulfate pollution in the study area. These findings provide a scientific foundation for managing groundwater pollutants and resources in the karst regions of northern China. Full article
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<p>Overview of the Xujiagou Spring area.</p>
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<p>Distribution map of sulfate content in karst groundwater of the spring area.</p>
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<p>Sulfate–sulfur isotope zoning of groundwater in the spring area. The horizontal line in the figure is the median line, and the red dot represents the average value.</p>
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<p>Oxygen sulfate isotope zoning of groundwater in the spring area. The horizontal line in the figure is the median line, and the red dot represents the average value.</p>
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<p>Relationship between SO<sub>4</sub><sup>2−</sup> and Ca<sup>2+</sup> content of groundwater in the spring area.</p>
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<p>Relationship between δ<sup>34</sup>S<sub>SO4</sub>, δ<sup>18</sup>O<sub>SO4</sub> of karst groundwater in the exposed area (<b>a</b>), covered area (<b>b</b>), and buried area (<b>c</b>) of the spring area.</p>
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<p>The sources and contributions of sulfate in groundwater under different occurrence environments.</p>
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<p>Comparison of groundwater from different sources in different occurrence environments.</p>
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<p>Patterns of sulfur transport and transformation in karst water in the mountain front.</p>
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16 pages, 5428 KiB  
Article
Basic Research on the Preparation of Electrolytic Manganese Residue–Red Mud–Ground Granulated Blast Furnace Slag–Calcium Hydroxide Composite Cementitious Material and Its Mechanical Properties
by Biao Peng, Lusen Wang, Zhonglin Li, Ye Xu, Weiguang Zhang and Yibing Li
Materials 2025, 18(6), 1218; https://doi.org/10.3390/ma18061218 - 10 Mar 2025
Viewed by 105
Abstract
A novel composite cementitious material was constructed by synergistically utilizing multiple industrial solid wastes, including electrolytic manganese residue (EMR), red mud (RM), and ground granulated blast furnace slag (GGBS), with calcium hydroxide [Ca(OH)2] as an alkaline activator. In addition, the mechanical [...] Read more.
A novel composite cementitious material was constructed by synergistically utilizing multiple industrial solid wastes, including electrolytic manganese residue (EMR), red mud (RM), and ground granulated blast furnace slag (GGBS), with calcium hydroxide [Ca(OH)2] as an alkaline activator. In addition, the mechanical properties of the composite cementitious materials were systematically analyzed under different raw material ratios, alkali activator dosages, and water-binder ratios. To further investigate the hydration products and mechanisms of the composite cementitious material, characterization methods, for instance, XRD, FT-IR, SEM-EDS, and TG-DTG, were employed to characterize the materials. To ensure that the composite cementitious material does not cause additional environmental pressure, it was analyzed for toxic leaching. The relevant experimental results indicate that the optimal ratio of the EMR–RM–GGBS–Ca(OH)2 components of the composite cementitious material is EMR content of 20%, RM content of 15%, GGBS content of 52%, calcium hydroxide as alkali activator content of 13%, and water-binder ratio of 0.5. Under the optimal ratio, the composite cementitious material at 28 days exhibited a compressive strength of 27.9 MPa, as well as a flexural strength of 7.5 MPa. The hydration products in the as-synthesized composite cementitious material system primarily encompassed ettringite (AFt) and hydrated calcium silicate (C-S-H), and their tight bonding in the middle and later curing stages was the main source of engineering mechanical strength. The heavy metal concentrations in the 28-day leaching solution of the EMR–RM–GGBS–Ca(OH)2 composite cementitious material fall within the limits prescribed by the drinking water hygiene standard (GB5749-2022), indicating that this composite material exhibits satisfactory safety performance. To sum up, it is elucidated that the novel process involved in this research provide useful references for the pollution-free treatment and resource utilization of solid wastes such as red mud and electrolytic manganese residue in the future. Full article
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<p>(<b>a</b>) Raw material XRD; (<b>b</b>) raw material particle size.</p>
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<p>SEM images of raw materials: (<b>a</b>) RM, (<b>b</b>) GGBS, and (<b>c</b>) EMR.</p>
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<p>Composite cementitious material mortar preparation process.</p>
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<p>Effect of various RM dosages on compressive strength (<b>a</b>) and rupture strength (<b>b</b>) of the EMR–RM–GGBS–Ca(OH)<sub>2</sub> materials.</p>
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<p>Effect of the amount of alkali exciter on the compressive strength (<b>a</b>) and rupture strength (<b>b</b>).</p>
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<p>The compressive strength (<b>a</b>) and rupture strength (<b>b</b>) of composite cementitious materials with various water-binder ratios.</p>
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<p>XRD patterns of net mortar specimens at different curing ages.</p>
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<p>FTIR patterns of net mortar specimens at different curing ages.</p>
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<p>TG-DTG curves at 3 d (<b>a</b>) and 28 d (<b>b</b>) in the net mortar specimens.</p>
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<p>SEM-EDS plots of net slurry specimens at different age of curing: (<b>a</b>) 3 d 2000×; (<b>b</b>) 3 d 5000×; (<b>c</b>) 7 d 2000×; (<b>d</b>) 7 d 5000×; (<b>e</b>) 28 d 2000×; and (<b>f</b>) 28 d 5000×.</p>
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<p>GGBS dosing and setting time.</p>
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<p>Toxic leaching concentrations for EMR and RM at different curing ages.</p>
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22 pages, 9859 KiB  
Article
Analysis of Interactions and Driving Factors in Subsystems of Regional Water Resource Carrying Capacity: A Case Study of Ningxia Hui Autonomous Region
by Heyuan Zhou, Suzhen Dang and Chengpeng Lu
Water 2025, 17(6), 792; https://doi.org/10.3390/w17060792 - 10 Mar 2025
Viewed by 80
Abstract
The sustainable utilization of water resources plays a crucial strategic role in regional economic development. The water resources carrying capacity (WRCC) is a multifaceted system influenced by diverse factors, where the interplay among water resources, societal factors, economic conditions, and ecological elements collectively [...] Read more.
The sustainable utilization of water resources plays a crucial strategic role in regional economic development. The water resources carrying capacity (WRCC) is a multifaceted system influenced by diverse factors, where the interplay among water resources, societal factors, economic conditions, and ecological elements collectively determines the overall WRCC. Combining relevant research results, this paper utilized an improved TOPSIS (Technique for Order Preference by Similarity to an Ideal Solution) and GRA (grey relational analysis)-based WRCC evaluation model, introduced the panel vector autoregressive (PVAR) model to analyze the effects of interactions among subsystems, and applied the geographically and temporally weighted regression (GTWR) model for the driving analysis of WRCC. Using Ningxia Hui Autonomous Region as a case study, this paper discusses the internal dynamic relationships and driving mechanisms of the WRCC system. It also provides a new perspective for discussing WRCC in water-scarce areas and provides novel approaches for optimizing water resource management and enhancing ecological protection. The results indicate that the water resources subsystem is central to the WRCC in Ningxia, with significant interconnections among the four subsystems. However, significant spatial and temporal heterogeneity is evident across different regions. The water resources system contributes significantly, with ecological development having a positive impact on water resources. However, social and economic development has a restrictive impact on water resources. Full article
(This article belongs to the Section Water Resources Management, Policy and Governance)
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<p>The schematic of the research methodology for WRCC index establishment and analysis.</p>
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<p>Location of Ningxia Hui Autonomous Region in China.</p>
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<p>Steps for building the PVAR model.</p>
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<p>Indicator weight results.</p>
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<p>WRCC levels across different cities.</p>
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<p>Impulse response results. The red line represents the average response of the impact variable to the response variable, the range of the blue and green lines represents the 95% confidence interval.</p>
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<p>Spatial distribution of subsystem driving strength in Ningxia’s cities.</p>
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<p>Evolution of the driving contribution of subsystems in Ningxia’s cities.</p>
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<p>Temporal dynamics of per capita water resources in Ningxia.</p>
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<p>Relationship diagram of subsystems.</p>
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23 pages, 13046 KiB  
Article
Design and Simulation Optimization for Hydrodynamic Fertilizer Injector Based on Axial-Flow Turbine Structure
by Chunlong Zhao, Yan Mo, Baozhong Zhang, Shuhui Liu, Qi Zhang, Juan Xiao and Yiteng Gong
Appl. Sci. 2025, 15(6), 2963; https://doi.org/10.3390/app15062963 - 10 Mar 2025
Viewed by 68
Abstract
This work involves the development of a hydrodynamic fertilizer injector (HFI), which uses an integrated axial-flow turbine (AFT) and a diaphragm pump to absorb liquid fertilizer. Three structural parameters—the number of impellers (M1), average number of blades per impeller (M2 [...] Read more.
This work involves the development of a hydrodynamic fertilizer injector (HFI), which uses an integrated axial-flow turbine (AFT) and a diaphragm pump to absorb liquid fertilizer. Three structural parameters—the number of impellers (M1), average number of blades per impeller (M2), and arrangement pattern (M3)—are considered, and 12 AFT designs are developed. Using a combination of CFD numerical simulations and hydraulic performance testing, the response of the AFT output power (P), blade negative pressure (NP), and fertilizer injection flow rate (Qinj) to structural parameters and inlet pressure (H) is investigated. The results show that the normalized root mean square error between the simulated outlet flow rate (Qs) and the measured flow rate (Qm) is 5.1%, indicating high accuracy in the grid motion simulation method. P increases first and then decreases with the increase in impeller speed (n). The maximum P (Pmax) ranges from 150.1 to 201.4 W. Pmax increases with H, decreases with increasing M1 and M2, and shows little change with M3. At H = 0.14 MPa, M1 and M2 have a significant influence, and at H ≥ 0.14 MPa, M1 becomes the most significant factor (p < 0.05). Low-speed flow and negative pressure cavitation zones at the leading edge of the blade suction surface cause flow blockage and affect the lifespan of the AFT. These regions decrease in size as H increases but increase with M1. The negative pressure (NP) decreases as M2 increases. When M1, M2, and M3 are 2, 3, and identical (D33), the Pmax of the AFT is maximized, increasing by 6.7% to 33.5% compared with those of the other combinations. The Qinj of D33, D34, D43, and D44 at H = 0.12~0.18 MPa range from 288.6 to 847.3 L/h, which is 38.7% to 461.0% higher than that of domestic and international venturi injectors. When considering cavitation issues and the manufacturing cost of the AFT mold, D44 may be chosen. Although its Qinj is 7.0% lower than that of D33, NP is reduced by 37.9%. These findings provide a basis for the development of the HFI with AFT as the driving unit. Full article
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<p>Schematic of the main components of the hydrodynamic fertilizer injector. 1—Inlet of K-shaped pipeline; 2—outlet of K-shaped pipeline; 3—shaft; 4—impeller group; 5—mechanical seal; 6—diaphragm plunger pump; 7—fertilizer suction port; 8—fertilizer injection port.</p>
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<p>Axial-flow turbine impeller structure top view (<b>a</b>), top view (<b>b</b>), front view (<b>c</b>), and right view (<b>d</b>).</p>
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<p>Schematic of the HFI hydraulic performance test platform. 1—Water storage barrel; 2—inlet valve; 3—centrifugal pump; 4—pressure relief valve; 5—ultrasonic flowmeter; 6—control valve; 7—inlet pressure gauge; 8—HFI device; 9—fertilization barrel; 10—suction tube; 11—outlet pressure gauge; 12—return valve.</p>
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<p>Fluid domain division and mesh generation of axial-flow turbine (<b>a</b>), boundary layer expansion (<b>b</b>), and impeller edge mesh refinement (<b>c</b>).</p>
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<p>Grid independence verification of the change rate of outlet flow (E) with the number of grids (N).</p>
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<p>Internal flow field of axial flow turbine (<b>a</b>) and blade surface pressure; (<b>b</b>) observation surface and data point diagram. Note: In the figure, the gray area is the observation surface of the internal flow field of the axial flow turbine; the red arrow on the blade surface is the force of water flow on the pressure surface of the blade; the blue arrow on the blade surface is the force of the fluid on the suction surface of the blade; the blue arrow in the gray area is the direction of water flow; the green line is the sampling line of the leaf BP curve; A1 is the leading edge of the suction surface; A2 is the leading edge of the pressure surface; B1 is the trailing edge of the pressure surface; and B2 is the suction surface inlet trailing edge. <span class="html-italic">x</span> is the horizontal distance between the data point on the A1B1 or A2B2 line and the leading edge of the blade; <span class="html-italic">x</span>/<span class="html-italic">L</span> is the relative position of the data point; <span class="html-italic">x</span>/<span class="html-italic">L</span> = 0 represents the position of A1 and A2; and <span class="html-italic">x</span>/<span class="html-italic">L</span> = 1 represents the position of B1 and B2.</p>
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<p>Design flow chart of hydrodynamic fertilizer injector based on CFD numerical simulation and hydraulic performance measurement.</p>
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<p>Comparison of the simulated value (<span class="html-italic">Q</span><sub>s</sub>) and measured value (<span class="html-italic">Q</span><sub>m</sub>) of AFT outlet flow.</p>
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<p>The output power (<span class="html-italic">P</span>) versus rotational speed (<span class="html-italic">n</span>) curves of different AFTs at <span class="html-italic">H</span> = 0.14 (<b>a</b>), 0.15 (<b>b</b>), 0.16 (<b>c</b>), 0.17 (<b>d</b>), and 0.18 MPa (<b>e</b>).</p>
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<p>The output power (<span class="html-italic">P</span>) versus rotational speed (<span class="html-italic">n</span>) curves of different AFTs at <span class="html-italic">H</span> = 0.14 (<b>a</b>), 0.15 (<b>b</b>), 0.16 (<b>c</b>), 0.17 (<b>d</b>), and 0.18 MPa (<b>e</b>).</p>
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<p>The internal flow velocity contours of 12 AFTs under the inlet pressure (<span class="html-italic">H</span>) of 0.18 MPa and the rotational speed (<span class="html-italic">n</span>) of 2500 rpm. Note: A1 is the leading edge of the suction surface, A2 is the leading edge of the pressure surface, B1 is the trailing edge of the pressure surface, and B2 is the trailing edge of the suction surface. The area surrounded by the red dotted line represents reg-hv, and the area surrounded by the black dotted line represents reg-lv.</p>
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<p>The internal flow velocity contours of 12 AFTs under the inlet pressure (<span class="html-italic">H</span>) of 0.18 MPa and the rotational speed (<span class="html-italic">n</span>) of 2500 rpm. Note: A1 is the leading edge of the suction surface, A2 is the leading edge of the pressure surface, B1 is the trailing edge of the pressure surface, and B2 is the trailing edge of the suction surface. The area surrounded by the red dotted line represents reg-hv, and the area surrounded by the black dotted line represents reg-lv.</p>
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<p>Internal flow velocity contours of D33 at <span class="html-italic">H</span> = 0.18 MPa with <span class="html-italic">n</span> = 2000 rpm (<b>a</b>), 2500 rpm (<b>b</b>), and 3000 rpm (<b>c</b>) and at <span class="html-italic">H</span> = 0.14 (<b>d</b>), at <span class="html-italic">H</span> = 0.16 MPa (<b>e</b>), and at <span class="html-italic">H</span> = 0.18 MPa (<b>b</b>) with <span class="html-italic">n</span> = 2500 rpm.</p>
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<p>The blade surface pressure curves of the first impeller (<b>a</b>) and the second impeller (<b>b</b>) along the inlet direction of four kinds of axial-flow turbines with M<sub>1</sub> = 2 at an inlet pressure (<span class="html-italic">H</span>) of 0.18 MPa and a rotational speed (<span class="html-italic">n</span>) of 2500 rpm are plotted.</p>
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<p>The blade surface pressure curves of the first impeller (<b>a</b>) and the second impeller (<b>b</b>) at an inlet pressure (<span class="html-italic">H</span>) of 0.18 MPa and a rotational speed (<span class="html-italic">n</span>) of 2000, 2500, and 3000 rpm are plotted.</p>
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<p>The blade surface pressure curves of the first impeller (<b>a</b>) and the second impeller (<b>b</b>) at an inlet pressure (<span class="html-italic">H</span>) of 0.14~0.18 MPa and a rotational speed (<span class="html-italic">n</span>) of 2500 rpm are plotted.</p>
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<p>Variation curves of the optimized axial-flow hydrodynamic fertilizer injectors (D33, D44) and the fertilizer injection flow (<span class="html-italic">Q</span><sub>inj</sub>) of the domestic and foreign venturi fertilizer injectors with the inlet pressure (<span class="html-italic">H</span>) [<a href="#B12-applsci-15-02963" class="html-bibr">12</a>,<a href="#B15-applsci-15-02963" class="html-bibr">15</a>,<a href="#B16-applsci-15-02963" class="html-bibr">16</a>,<a href="#B43-applsci-15-02963" class="html-bibr">43</a>].</p>
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