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Search Results (14,452)

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Keywords = resource utilization

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16 pages, 4947 KiB  
Article
SC-ResNeXt: A Regression Prediction Model for Nitrogen Content in Sugarcane Leaves
by Zihao Lu, Cuimin Sun, Junyang Dou, Biao He, Muchen Zhou and Hui You
Agronomy 2025, 15(1), 175; https://doi.org/10.3390/agronomy15010175 (registering DOI) - 13 Jan 2025
Abstract
In agricultural production, the nitrogen content of sugarcane is assessed with precision and the economy, which is crucial for balancing fertilizer application, reducing resource waste, and minimizing environmental pollution. As an important economic crop, the productivity of sugarcane is significantly influenced by various [...] Read more.
In agricultural production, the nitrogen content of sugarcane is assessed with precision and the economy, which is crucial for balancing fertilizer application, reducing resource waste, and minimizing environmental pollution. As an important economic crop, the productivity of sugarcane is significantly influenced by various environmental factors, especially nitrogen supply. Traditional methods based on manually extracted image features are not only costly but are also limited in accuracy and generalization ability. To address these issues, a novel regression prediction model for estimating the nitrogen content of sugarcane, named SC-ResNeXt (Enhanced with Self-Attention, Spatial Attention, and Channel Attention for ResNeXt), has been proposed in this study. The Self-Attention (SA) mechanism and Convolutional Block Attention Module (CBAM) have been incorporated into the ResNeXt101 model to enhance the model’s focus on key image features and its information extraction capability. It was demonstrated that the SC-ResNeXt model achieved a test R2 value of 93.49% in predicting the nitrogen content of sugarcane leaves. After introducing the SA and CBAM attention mechanisms, the prediction accuracy of the model improved by 4.02%. Compared with four classical deep learning algorithms, SC-ResNeXt exhibited superior regression prediction performance. This study utilized images captured by smartphones combined with automatic feature extraction and deep learning technologies, achieving precise and economical predictions of the nitrogen content in sugarcane compared to traditional laboratory chemical analysis methods. This approach offers an affordable technical solution for small farmers to optimize nitrogen management for sugarcane plants, potentially leading to yield improvements. Additionally, it supports the development of more intelligent farming practices by providing precise nitrogen content predictions. Full article
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<p>Field experiment.</p>
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<p>Comparison before and after image background removal: (<b>a</b>) before removal; (<b>b</b>) after removal.</p>
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<p>SC-ResNeXt model architecture.</p>
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<p>Structure of ResNeXt101.</p>
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<p>Structure diagram of CBAM.</p>
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<p>Structure diagram of self-attention.</p>
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<p>The training process of SC-ResNeXt: (<b>a</b>) loss convergence; (<b>b</b>) R<sup>2</sup> convergence.</p>
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<p>Grad-CAM heatmaps of SC-ResNeXt Layer4.</p>
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<p>The t-SNE feature maps: (<b>a</b>) the output of the first convolutional layer; (<b>b</b>) before the attention mechanism; (<b>c</b>) after the attention mechanism.</p>
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<p>Regression prediction results of different backbones.</p>
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<p>Ablation experiment results: (<b>a</b>) ResNeXt101; (<b>b</b>) ResNeXt50.</p>
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<p>Test results of different algorithms.</p>
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25 pages, 2421 KiB  
Article
Depicting Soybean Diversity via Complementary Application of Three Marker Types
by Vesna Perić, Natalija Kravić, Marijenka Tabaković, Snežana Mladenović Drinić, Valentina Nikolić, Marijana Simić and Ana Nikolić
Plants 2025, 14(2), 201; https://doi.org/10.3390/plants14020201 (registering DOI) - 12 Jan 2025
Abstract
Driven by the growing demands for plant-based protein in Europe and attempts of soybean breeding programs to improve the productivity of created varieties, this study aimed to enhance genetic resource utilization efficiency by providing information relevant to well-focused breeding targets. A set of [...] Read more.
Driven by the growing demands for plant-based protein in Europe and attempts of soybean breeding programs to improve the productivity of created varieties, this study aimed to enhance genetic resource utilization efficiency by providing information relevant to well-focused breeding targets. A set of 90 accessions was subjected to a comprehensive assessment of genetic diversity in a soybean working collection using three marker types: morphological descriptors, agronomic traits, and SSRs. Genotype grouping patterns varied among the markers, displaying the best congruence with pedigree data and maturity for SSRs and agronomic traits, respectively. The clear origin-related grouping pattern was not observed for any of the marker types. For the diversity assessed by morphological descriptors, Homogeneity Analysis by Means of Alternating Least Squares (HOMALS) yielded the most efficient classification by identifying the traits with the highest discriminative power and separating the genotypes into homogeneous groups. According to genetic distances (GDs), the highest diversity was found for morphological descriptors (GD = 517), followed by SSRs (GD = 0.317) and agronomic traits (GD = 0.244). The analysis of molecular variance (AMOVA) revealed a weak differentiation between geographic groups (ΦST = 0.061), emphasizing the highest differentiation for Canadian genotypes (ΦST = 0.148 **). A low correlation was found between molecular and morphological, i.e., agronomic trait-based matrices (0.061 *, i.e., –0.027, respectively). The overall assessed diversity highlighted the importance of introducing new sources of variation to promote long-term improvement in soybean breeding. Full article
(This article belongs to the Special Issue Germplasm Resources and Molecular Breeding of Soybean)
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<p>Discriminative power of 15 morphological descriptors according to HOMALS analysis. Abbreviations: HIPC—hypocotyl colour; H—habitus; GT—growth type; PUBC—pubescence colour; LB—leaf blistering; LLSh—shape of lateral leaflet; LLS—size of lateral leaflet; ILC—intensity of the green colour of the leaf; FC—flower colour; IPC—intensity of the brown colour of the pod; SSh–seed shape; SCC—seed coat colour; SL—seed coat lustre; HILC—hilum colour; CHF—colour of hilum funicle.</p>
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<p>Grouping of genotypes derived by HOMALS analysis based on 15 morphological descriptors. Roman numbers in red represent groups of genotypes with a similar morphological profile.</p>
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<p>Dendrogram of UPGMA cluster analysis of 90 soybean genotypes based on 15 morphological descriptors. Genotypes labelled by geographic origin: DOM—domestic; Serbia and Croatia; USA—United States of America; EEA—Europe and Euro-Asia; CAN—Canada; EXO—exotic; China and Japan.</p>
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<p>PCA biplot of 90 soybean genotypes based on 8 agronomic traits. Abbreviations: MG—maturity group; PH—plant height; NN—node number; PN—pod number; SN—seed number per plant; SYP—seed yield per plant; PROT—protein content; OIL—oil content.</p>
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<p>Dendrogram of UPGMA cluster analysis of 90 soybean genotypes based on 8 agronomic traits: (<b>a</b>) genotypes labelled by geographic origin: DOM—domestic; Serbia and Croatia; USA—United States of America; EEA—Europe and Euro-Asia; CAN—Canada; EXO—exotic; China and Japan; (<b>b</b>) genotypes labelled by maturity group (MG).</p>
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<p>Dendrogram of UPGMA cluster analysis of 90 soybean genotypes based on SSR markers. Genotypes labelled by geographic origin: DOM– domestic; Serbia and Croatia; USA—United States of America; EEA—Europe and Euro-Asia; CAN—Canada; EXO—exotic; China and Japan.</p>
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<p>PCoA of the genetic structure of 90 soybean genotypes based on SSR markers.</p>
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26 pages, 6989 KiB  
Article
Innovative Approaches of Optimization Methods Used in Geothermal Power Plants: Artificial Neural Networks and Genetic Algorithms
by Özgür Özer and Harun Kemal Öztürk
Energies 2025, 18(2), 311; https://doi.org/10.3390/en18020311 (registering DOI) - 12 Jan 2025
Abstract
In this study, a general description of geothermal power plants is provided, and the optimization methods used are summarized. Following the review of these optimization methods, the advantages of heuristic methods and the success of the developed models are demonstrated. The challenges in [...] Read more.
In this study, a general description of geothermal power plants is provided, and the optimization methods used are summarized. Following the review of these optimization methods, the advantages of heuristic methods and the success of the developed models are demonstrated. The challenges in optimizing geothermal systems, including the limitations due to their complexity and the use of multiple parameters, are discussed. Heuristic methods, particularly the widely used artificial neural networks and genetic algorithms, are explained in general terms. Recent studies highlight that the combined use of artificial neural networks and genetic algorithms can produce faster and more consistent results. This demonstrates the benefits of using advanced methods for geothermal resource utilization and power plant optimization. An innovative optimization method has been developed using the operational data of an ORC geothermal power plant in the city of Izmir. The computational method, using genetic algorithms with artificial neural networks as the fitness function, has identified the optimal operating conditions, achieving a 39.41% increase in net power output. The plant’s gross power generation has increased from 4943 kW to 6624 kW. Full article
(This article belongs to the Section H2: Geothermal)
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<p>(<b>a</b>) Dry steam GPP; (<b>b</b>) flash steam GPP; and (<b>c</b>) binary cycle GPP [<a href="#B18-energies-18-00311" class="html-bibr">18</a>].</p>
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<p>The schematic diagram of optimization method classifications [<a href="#B20-energies-18-00311" class="html-bibr">20</a>].</p>
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<p>The schematic diagram of artificial neural networks [<a href="#B36-energies-18-00311" class="html-bibr">36</a>].</p>
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<p>The schematic diagram of neuron cells [<a href="#B37-energies-18-00311" class="html-bibr">37</a>].</p>
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<p>Genetic algorithm flowchart diagram [<a href="#B44-energies-18-00311" class="html-bibr">44</a>].</p>
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<p>Calculated and predicted efficiencies of ANNs and actual data.</p>
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<p>Variation in actual and ANN-based estimated net power generation.</p>
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<p>ORC geothermal power plant flow diagram.</p>
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<p>Flow diagram of calculation model.</p>
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<p>Comparison of power plant and developed model operating data.</p>
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<p>Critical thermodynamic results obtained after the optimization process.</p>
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<p>Exergy efficiency improvements and LP turbine power production results.</p>
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<p>Overall power and efficiency results.</p>
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20 pages, 6013 KiB  
Article
Sustainable Utilization of Dewatering Sludge for the Development of Reinforcement Grouting Materials in Downhole Applications
by Xianxiang Zhu, Yanhui Du and Song Li
Water 2025, 17(2), 192; https://doi.org/10.3390/w17020192 (registering DOI) - 12 Jan 2025
Abstract
The mining and processing of coal resources generate substantial coal-based solid wastes, such as coal gangue and slag, which pose environmental challenges, occupy land, and are difficult to manage. However, utilizing these wastes for the stabilization and solidification (S/S) of municipal sludge containing [...] Read more.
The mining and processing of coal resources generate substantial coal-based solid wastes, such as coal gangue and slag, which pose environmental challenges, occupy land, and are difficult to manage. However, utilizing these wastes for the stabilization and solidification (S/S) of municipal sludge containing chromium (Cr) and nickel (Ni) offers an effective solution for mitigating environmental and groundwater pollution while enabling sustainable waste treatment and resource utilization. This study applied an alkali-activated coal gangue–S95 granulated blast furnace slag-based binder (CGS) to the S/S treatment of municipal sludge. The effects of the liquid-to-solid ratio, alkali activator dosage, sludge content, and incineration on compressive strength and the leaching of Cr and Ni were analyzed. The results showed that compressive strength decreased with increases in the sludge content and liquid-to-solid ratio, while incinerated sludge (ESA) samples exhibited better strength than raw sludge (ES). Incineration decomposed the calcite (CaCO3) into CaO, which facilitated the oxidation of Cr(III) to Cr(VI) and increased Cr leaching in the ESA. However, the ESA samples demonstrated superior heavy metal stabilization, as CGS reduced Cr(VI) to Cr(III) and immobilized it through the formation of chromite phases. Using ESA as a binder in CGS provides a safe, efficient approach for resource recovery and heavy metal stabilization, offering a novel solution for the environmental management and utilization of coal-based solid wastes. Full article
(This article belongs to the Special Issue Engineering Hydrogeology Research Related to Mining Activities)
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<p>Sludge particle size, SEM image and XRD image: (<b>a</b>) ES; and (<b>b</b>) ESA.</p>
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<p>Particle size morphology of CG (<b>a</b>); and GGBS (<b>b</b>).</p>
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<p>Experimental process.</p>
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<p>Effects of different sludge dosages on compressive strength (<b>a</b>); alkali exciter dosage (<b>b</b>); and liquid–solid ratio (<b>c</b>).</p>
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<p>Leaching concentrations of heavy metals from raw materials.</p>
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<p>Weight metal leaching concentration and curing efficiency of 25% ESA-doped stones.</p>
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<p>Effect of different dosages of ESA (<b>a</b>); and ES (<b>b</b>) on the leaching concentration and curing efficiency of Cr and Ni.</p>
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<p>Effect of different alkali exciter dosages on Cr and Ni leaching concentrations (<b>a</b>); and curing efficiency (<b>b</b>).</p>
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<p>Effects of different water–ash ratios on Cr and Ni leaching concentrations (<b>a</b>); and curing efficiency (<b>b</b>).</p>
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<p>SEM images of: 0% ESA (<b>a</b>); 10% ESA (<b>b</b>); 25% ESA (<b>c</b>); and 6% alkali exciter (<b>d</b>) specimens.</p>
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<p>XRD patterns of 0%, 10% and 25% ESA-doped stone bodies.</p>
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<p>Variations in leaching solution pH with time (<b>a</b>); and XRD pattern after leaching test with 10% ESA-doped stone bodies (<b>b</b>).</p>
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19 pages, 3300 KiB  
Article
Impact of Spatial Evolution of Cropland Pattern on Cropland Suitability in Black Soil Region of Northeast China, 1990–2020
by Long Kang and Kening Wu
Agronomy 2025, 15(1), 172; https://doi.org/10.3390/agronomy15010172 (registering DOI) - 12 Jan 2025
Abstract
Agricultural land resources are essential for food production, and thus it is vital to examine the spatiotemporal changes in these resources and their impacts on land suitability to optimize resource allocation. In this study, we investigated the spatial evolution of cropland resources through [...] Read more.
Agricultural land resources are essential for food production, and thus it is vital to examine the spatiotemporal changes in these resources and their impacts on land suitability to optimize resource allocation. In this study, we investigated the spatial evolution of cropland resources through land use change analysis by utilizing four periods of land use data from 1990 to 2020 in the black soil region of northeast China (BSRNC). Employing niche theory, we developed a cultivability evaluation model tailored to the BSRNC, which was used to assess the impact of the spatial changes in cropland patterns over the past 30 years on land suitability. Our key findings are as follows: (1) Cropland resources have generally tended to expand in the BSRNC, with an increase of 7.16 × 103 km2 in the cultivated area and a northeastward shift in the cropland center by 52.94 km, indicating significant changes in the spatial configuration of the land. (2) The region’s cultivable land resources were substantial, covering 694.06 × 103 km2, or 55.78% of the total area, with notable spatial variability, influenced by the regional climate and topography. (3) The land cultivability has slightly improved, as shown by a 0.10 increase in the cultivability index, but a significant declining trend in the cultivability of cropland was observed after 2000. Our findings provide valuable insights to help accurately assess land productivity in the BSRNC and facilitate the sustainable use and conservation of black soil. Full article
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<p>Location (<b>a</b>), administrative subdivisions (<b>b</b>), and soil types (<b>c</b>) in the black soil region of northeast China (BSRNC).</p>
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<p>Spatial changes in cropland gravity center.</p>
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<p>Hotspots for cropland change from 1990 to 2020.</p>
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<p>Spatial distribution of cultivable land in the BSRNC.</p>
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<p>Relationships between actual crop yields and simulated cultivability scores for different cities in the BSRNC.</p>
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<p>Suitability of cropland resources in the BSRNC (<b>a</b>) and changes in single-factor suitability (<b>b</b>).</p>
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<p>Cropland cultivation levels across years (<b>a</b>) and factors contributing to unsuitability for cultivation in the BSRNC (<b>b</b>).</p>
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<p>Spatial distribution of cropland reserves in the BSRNC (<b>a</b>) and coupling of reserves with current land use across various cultivability levels (<b>b</b>).</p>
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26 pages, 585 KiB  
Article
The Evolution of Policies for the Resource Utilization of Livestock Manure in China
by Haoyu Lin, Hongchao Jiao, Hai Lin and Xuanguo Xu
Agriculture 2025, 15(2), 153; https://doi.org/10.3390/agriculture15020153 (registering DOI) - 12 Jan 2025
Abstract
With the continuous development of animal husbandry, the harmless handling and resource utilization of livestock manure has gradually become a bottleneck problem in sustainable agriculture and livestock production in China. This study evaluates the policies related to manure handling and utilization in different [...] Read more.
With the continuous development of animal husbandry, the harmless handling and resource utilization of livestock manure has gradually become a bottleneck problem in sustainable agriculture and livestock production in China. This study evaluates the policies related to manure handling and utilization in different economic development periods in China. The decreased pollutant discharge from livestock manure indicates the effectiveness of the strategy aiming to encourage the construction of manure treatment facilities and resource utilization in cropland and to establish a sound legal system for pollutant discharge. New policies and measures should be introduced to promote the coupling of intensive livestock breeding and crop planting, with the direction of nutrient management planning and the incorporation of a service platform for the resource utilization of manure. Technological innovation in green livestock breeding should be supported by policies to achieve source reduction in pollutants in breeding waste. Full article
(This article belongs to the Special Issue Agricultural Policies toward Sustainable Farm Development)
21 pages, 5838 KiB  
Article
FPGA-QNN: Quantized Neural Network Hardware Acceleration on FPGAs
by Mustafa Tasci, Ayhan Istanbullu, Vedat Tumen and Selahattin Kosunalp
Appl. Sci. 2025, 15(2), 688; https://doi.org/10.3390/app15020688 (registering DOI) - 12 Jan 2025
Viewed by 99
Abstract
Recently, convolutional neural networks (CNNs) have received a massive amount of interest due to their ability to achieve high accuracy in various artificial intelligence tasks. With the development of complex CNN models, a significant drawback is their high computational burden and memory requirements. [...] Read more.
Recently, convolutional neural networks (CNNs) have received a massive amount of interest due to their ability to achieve high accuracy in various artificial intelligence tasks. With the development of complex CNN models, a significant drawback is their high computational burden and memory requirements. The performance of a typical CNN model can be enhanced by the improvement of hardware accelerators. Practical implementations on field-programmable gate arrays (FPGA) have the potential to reduce resource utilization while maintaining low power consumption. Nevertheless, when implementing complex CNN models on FPGAs, these may may require further computational and memory capacities, exceeding the available capacity provided by many current FPGAs. An effective solution to this issue is to use quantized neural network (QNN) models to remove the burden of full-precision weights and activations. This article proposes an accelerator design framework for FPGAs, called FPGA-QNN, with a particular value in reducing high computational burden and memory requirements when implementing CNNs. To approach this goal, FPGA-QNN exploits the basics of quantized neural network (QNN) models by converting the high burden of full-precision weights and activations into integer operations. The FPGA-QNN framework comes up with 12 accelerators based on multi-layer perceptron (MLP) and LeNet CNN models, each of which is associated with a specific combination of quantization and folding. The outputs from the performance evaluations on Xilinx PYNQ Z1 development board proved the superiority of FPGA-QNN in terms of resource utilization and energy efficiency in comparison to several recent approaches. The proposed MLP model classified the FashionMNIST dataset at a speed of 953 kFPS with 1019 GOPs while consuming 2.05 W. Full article
(This article belongs to the Special Issue Advancements in Deep Learning and Its Applications)
21 pages, 6628 KiB  
Article
Efficient Generative-Adversarial U-Net for Multi-Organ Medical Image Segmentation
by Haoran Wang, Gengshen Wu and Yi Liu
J. Imaging 2025, 11(1), 19; https://doi.org/10.3390/jimaging11010019 (registering DOI) - 12 Jan 2025
Viewed by 81
Abstract
Manual labeling of lesions in medical image analysis presents a significant challenge due to its labor-intensive and inefficient nature, which ultimately strains essential medical resources and impedes the advancement of computer-aided diagnosis. This paper introduces a novel medical image-segmentation framework named Efficient Generative-Adversarial [...] Read more.
Manual labeling of lesions in medical image analysis presents a significant challenge due to its labor-intensive and inefficient nature, which ultimately strains essential medical resources and impedes the advancement of computer-aided diagnosis. This paper introduces a novel medical image-segmentation framework named Efficient Generative-Adversarial U-Net (EGAUNet), designed to facilitate rapid and accurate multi-organ labeling. To enhance the model’s capability to comprehend spatial information, we propose the Global Spatial-Channel Attention Mechanism (GSCA). This mechanism enables the model to concentrate more effectively on regions of interest. Additionally, we have integrated Efficient Mapping Convolutional Blocks (EMCB) into the feature-learning process, allowing for the extraction of multi-scale spatial information and the adjustment of feature map channels through optimized weight values. Moreover, the proposed framework progressively enhances its performance by utilizing a generative-adversarial learning strategy, which contributes to improvements in segmentation accuracy. Consequently, EGAUNet demonstrates exemplary segmentation performance on public multi-organ datasets while maintaining high efficiency. For instance, in evaluations on the CHAOS T2SPIR dataset, EGAUNet achieves approximately 2% higher performance on the Jaccard metric, 1% higher on the Dice metric, and nearly 3% higher on the precision metric in comparison to advanced networks such as Swin-Unet and TransUnet. Full article
17 pages, 1377 KiB  
Article
Adaptation of Diverse Maize Germplasm to Spring Season Conditions in Northeast China
by Yi Li, Zhiyuan Yang, Yong Shao, Zhenguo Jin, Li Gao, Yang Yu, Fengyi Zhang, Yuxing Zhang, Yuantao Nan, Mingshun Li, Degui Zhang, Zhuanfang Hao, Jianfeng Weng, Xinhai Li and Hongjun Yong
Agronomy 2025, 15(1), 170; https://doi.org/10.3390/agronomy15010170 (registering DOI) - 12 Jan 2025
Viewed by 121
Abstract
Northeast China (NEC) is a major spring maize (Zea mays L.) growing belt, and the outputs substantially influence national grain production. However, the maize grain yield per unit area has little changes in recent years, partially due to the lack of elite [...] Read more.
Northeast China (NEC) is a major spring maize (Zea mays L.) growing belt, and the outputs substantially influence national grain production. However, the maize grain yield per unit area has little changes in recent years, partially due to the lack of elite germplasm resources and innovation. Therefore, this study aimed to determine the performance of diverse populations in NEC to propose appropriate strategies for the utilization of elite germplasm to broaden the genetic base of Chinese germplasm. Fifteen diverse maize populations from the International Maize and Wheat Improvement Center (CIMMYT) and the U.S. were crossed to two local tester lines, representing Chinese heterotic groups Reid and Lancaster, for evaluating the combining ability and heterosis in three locations (Gongzhuling, Jilin Province, and Harbin and Suihua, Heilongjiang Province) in NEC over two years. The U.S. (BS13(S)C7 and BS31) and Chinese (Ji Syn A) populations exhibited more favorable alleles for high yield potential in all locations tested. Furthermore, the PH6WC × BS31 and PH6WC × Ji Syn A crosses had higher grain yields, and an appropriate number of days to silking, ear height, and resistance to lodging at Gongzhuling and Harbin in NEC. The best strategies for utilizing these diverse germplasms may be to develop new inbred lines from the existing elite populations or improve the grain yield and resistance to lodging of the elite line PH4CV for broadening the genetic base of the Chinese group Lancaster in NEC. Full article
(This article belongs to the Special Issue Maize Germplasm Improvement and Innovation)
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<p>Specific combining ability for 15 populations crossed with PH4CV (<b>a</b>) for DS, (<b>b</b>) for EH, (<b>c</b>) for GY, and PH6WC (<b>d</b>) for DS, (<b>e</b>) for EH, (<b>f</b>) for GY for days to silking (DS), ear height (EH), and grain yield (GY) in individual and combined environments (* indicate <span class="html-italic">p</span> value of 0.05).</p>
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<p>General combining ability for 15 populations for days to silking (<b>a</b>), ear height (<b>b</b>), stalk lodging (<b>c</b>), and grain yield (<b>d</b>) in individual and combined environments (* indicate <span class="html-italic">p</span> value of 0.05).</p>
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25 pages, 6206 KiB  
Article
Comparative Study on Environmental Impact of Electric Vehicle Batteries from a Regional and Energy Perspective
by Ruiqi Feng, Wei Guo, Chenjie Zhang, Yuxuan Nie and Jiajing Li
Batteries 2025, 11(1), 23; https://doi.org/10.3390/batteries11010023 (registering DOI) - 11 Jan 2025
Viewed by 557
Abstract
Against the backdrop of the global goal of “carbon neutrality”, the advancement of electric vehicles (EVs) holds substantial importance for diminishing the reliance on fossil fuels, mitigating vehicular emissions, and fostering the transition of the automotive sector towards a sustainable, low-carbon paradigm. The [...] Read more.
Against the backdrop of the global goal of “carbon neutrality”, the advancement of electric vehicles (EVs) holds substantial importance for diminishing the reliance on fossil fuels, mitigating vehicular emissions, and fostering the transition of the automotive sector towards a sustainable, low-carbon paradigm. The wide application of electric vehicles not only reduces the dependence on non-renewable resources such as oil, but also concurrently effectuates a substantial reduction in carbon emissions within the transportation sector. In the realm of electric vehicles, ternary lithium batteries (NCM) and lithium iron phosphate batteries (LFP) are two widely used batteries. This study examines the resource utilization and environmental repercussions associated with the production of 1 kW ternary lithium batteries and lithium iron phosphate batteries, employing a life cycle assessment (LCA) framework. The importance of clean energy in reducing environmental pollution and global warming potential is revealed by introducing five different power generation types and the regional power generation structure in China into the power battery production process. The findings of the investigation indicate that lithium iron phosphate batteries exhibit pronounced superiority in terms of environmental sustainability, while ternary lithium batteries are more advantageous in terms of performance. The mitigation of environmental pollution associated with battery production can be significantly achieved by the holistic integration of clean energy sources and the systematic optimization of manufacturing processes. Specific interventions encompass enhancing the energy efficiency of the production process, incorporating renewable energy sources for power generation, and minimizing the utilization of hazardous materials. By implementing these strategies, the battery sector can advance towards a more environmentally benign and sustainable trajectory. Full article
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<p>New energy vehicle production, sale, and market share, 2014–2035 (10,000 units).</p>
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<p>Emission reduction potential in power battery production phrase.</p>
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<p>Regional distribution of China’s power generation as a percentage.</p>
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<p>System boundary of LFP and NCM cells.</p>
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<p>Composition of NCM and LFP cells.</p>
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<p>Carbon footprint of LFP battery production stage.</p>
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<p>Carbon footprint of NCM cell production stage.</p>
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<p>Comparison of carbon emissions from battery production processes.</p>
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<p>Comparative analysis of ozone layer impacts: (<b>a</b>) ozone depletion potential, (<b>b</b>) human health ozone formation potential, (<b>c</b>) terrestrial ecosystem ozone formation potential.</p>
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<p>Comparative analysis of eutrophication impacts in aquatic systems, (<b>a</b>) freshwater eutrophication potential, (<b>b</b>) marine eutrophication potential.</p>
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<p>Comparison of eco-toxicity effects: (<b>a</b>) terrestrial eco-toxicity potential, (<b>b</b>) marine eco-toxicity potential, (<b>c</b>) freshwater eco-toxicity potential, (<b>d</b>) human carcinogenicity potential.</p>
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<p>Mainstream power generation in China by region [<a href="#B11-batteries-11-00023" class="html-bibr">11</a>].</p>
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<p>Comparison of carbon emissions from battery production processes.</p>
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<p>Comparative analysis of ozone layer impacts: (<b>a</b>) ozone depletion potential, (<b>b</b>) human health ozone formation potential, (<b>c</b>) terrestrial ecosystem ozone formation potential.</p>
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<p>Comparative analysis of eutrophication impacts in aquatic systems, (<b>a</b>) freshwater eutrophication potential, (<b>b</b>) marine eutrophication potential.</p>
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<p>Comparison of eco-toxicity effects: (<b>a</b>) terrestrial eco-toxicity potential, (<b>b</b>) marine eco-toxicity potential, (<b>c</b>) freshwater eco-toxicity potential, (<b>d</b>) human carcinogenicity potential.</p>
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28 pages, 16277 KiB  
Article
Urban Spatial Naturalness Degree in the Planning of Ultra-High-Density Cities: The Case of Urban Green Open Spaces in Macau
by Jitai Li, Fan Lin, Hongcan Cui, Shuai Yang and Yile Chen
Buildings 2025, 15(2), 206; https://doi.org/10.3390/buildings15020206 (registering DOI) - 11 Jan 2025
Viewed by 356
Abstract
This study deeply examines the livable environment in high-density cities like Macau, focusing on urban green spaces. The study introduces the “urban spatial naturalness degree” indicator, exploring its application with urban population growth and green space expansion. The research utilizes the planning indicator [...] Read more.
This study deeply examines the livable environment in high-density cities like Macau, focusing on urban green spaces. The study introduces the “urban spatial naturalness degree” indicator, exploring its application with urban population growth and green space expansion. The research utilizes the planning indicator of “urban spatial naturalness degree”, and then explores the application paradigm of matching increments between urban population growth and green open space and a bottom-line planning indicator suitable for Macau. Among them, the “USND” indicator is defined as “the visual perception rate of blue and green natural elements in the three-dimensional space of urban land”, which is specifically expressed as “the average function of the occupation rate of urban green open space and the visibility rate of blue–green space of main street scenes”. Based on this, this paper estimates the incremental planning indicators of green open space in Macau and various urban areas during the implementation of the Master Plan of Macau (2020–2040). The results show the following: (1) The study found that the land increment in green open space in Macau basically matches the potential of reserve resources. (2) For Class I and Class II urban areas in Macau, the USND value is estimated to be 42.96% and 32.62% in 2040, respectively. These values are expected to reach the international excellent level. (3) For Class III and Class IV urban areas, the USND values could reach 20.14% and 15.14%, respectively, which are considered to be at the international middle level in 2040. Full article
(This article belongs to the Special Issue Research on Health, Wellbeing and Urban Design)
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<p>Territory of the Macau Peninsula and Macau outlying islands. The small amount of Chinese text is from Zhuhai City, but it is not within the scope of this study. (Image source: the author’s annotations are based on Google satellite images).</p>
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<p>Macau Peninsula urban area 6 km × 6 km framed comparative study area. In this figure, “Nossa Senhora de Fátima”, “Santo António”, “São Lourenço”, “Sé”, etc. are the names of parishes in Macau and have no specific meanings. (Image source: the author’s annotations are based on OpenStreetMap images).</p>
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<p>Example of a 6 km × 6 km boxed comparative study area in the central London area. (Image source: the author’s annotations are based on OpenStreetMap images).</p>
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<p>Example of sampling points for BGVR measurement in Guangzhou. In this Chinese map, the Chinese characters shown are just street names and place names without any specific meaning. (Image source: the author’s annotations are based on OpenStreetMap images).</p>
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<p>Example of sampling points for BGVR quantification in Sydney. The small print in the map is English place names with no specific meaning. (Image source: the author’s annotations are based on OpenStreetMap images).</p>
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<p>Illustration of BGOR measurement in the sample city center area. (<b>a</b>) Guangzhou BGOR = 19.0%; (<b>b</b>) Sydney BGOR = 30.2%. (Image source: the author’s annotations are based on OpenStreetMap images).</p>
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<p>Illustration of BGVR value quantification in the sample city center area. (<b>a</b>) Guangzhou average BGVR = 44.9%; (<b>b</b>) Sydney average BGVR = 25.1% (Image source: the author’s annotations are based on street view image information of Google Maps 2020–2021).</p>
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<p>Illustration of BGVR value quantification in the sample city center area. (<b>a</b>) Guangzhou average BGVR = 44.9%; (<b>b</b>) Sydney average BGVR = 25.1% (Image source: the author’s annotations are based on street view image information of Google Maps 2020–2021).</p>
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<p>Residential cluster plan of Macau new reclamation area A. (Image source: Macau Land and Urban Construction Bureau).</p>
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<p>Potential incremental space for three-dimensional greening at Rua dos Hortelãos in Areia Preta e Iao Hon district. (Image source: the author’s annotations are based on street view image information of Google Maps 2020–2021).</p>
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23 pages, 8113 KiB  
Article
Artificial Neural Networks as a Tool for High-Accuracy Prediction of In-Cylinder Pressure and Equivalent Flame Radius in Hydrogen-Fueled Internal Combustion Engines
by Federico Ricci, Massimiliano Avana and Francesco Mariani
Energies 2025, 18(2), 299; https://doi.org/10.3390/en18020299 (registering DOI) - 11 Jan 2025
Viewed by 295
Abstract
The automotive industry is under increasing pressure to develop cleaner and more efficient technologies in response to stringent emission regulations. Hydrogen-powered internal combustion engines represent a promising alternative, offering the potential to reduce carbon-based emissions while improving efficiency. However, the accurate estimation of [...] Read more.
The automotive industry is under increasing pressure to develop cleaner and more efficient technologies in response to stringent emission regulations. Hydrogen-powered internal combustion engines represent a promising alternative, offering the potential to reduce carbon-based emissions while improving efficiency. However, the accurate estimation of in-cylinder pressure is crucial for optimizing the performance and emissions of these engines. While traditional simulation tools such as GT-POWER are widely utilized for these purposes, recent advancements in artificial intelligence provide new opportunities for achieving faster and more accurate predictions. This study presents a comparative evaluation of the predictive capabilities of GT-POWER and an artificial neural network model in estimating in-cylinder pressure, with a particular focus on improvements in computational efficiency. Additionally, the artificial neural network is employed to predict the equivalent flame radius, thereby obviating the need for repeated tests using dedicated high-speed cameras in optical access research engines, due to the resource-intensive nature of data acquisition and post-processing. Experiments were conducted on a single-cylinder research engine operating at low-speed and low-load conditions, across three distinct relative air–fuel ratio values with a range of ignition timing settings applied for each air excess coefficient. The findings demonstrate that the artificial neural network model surpasses GT-POWER in predicting in-cylinder pressure with higher accuracy, achieving an RMSE consistently below 0.44% across various conditions. In comparison, GT-POWER exhibits an RMSE ranging from 0.92% to 1.57%. Additionally, the neural network effectively estimates the equivalent flame radius, maintaining an RMSE of less than 3%, ranging from 2.21% to 2.90%. This underscores the potential of artificial neural network-based approaches to not only significantly reduce computational time but also enhance predictive precision. Furthermore, this methodology could subsequently be applied to conventional road engines exhibiting characteristics and performance similar to those of a specific optical engine used as the basis for the machine learning analysis, offering a practical advantage in real-time diagnostics. Full article
(This article belongs to the Special Issue Advancements in Hydrogen Application for Internal Combustion Engines)
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<p>Test engine: (<b>a</b>) real and (<b>b</b>) schematic view.</p>
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<p>Test equipment.</p>
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<p>VEO-E Phantom 310-L high-speed camera, equipped with a Nikon 55 mm f/2.8 lens.</p>
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<p>GT-POWER engine model configuration.</p>
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<p>GT-POWER engine model validation: logP-logV curves for numerical (green) and experimental (black) data at <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 2.0 and IT = −13 CAD aTDC.</p>
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<p>Conceptual layout of the BPANN [<a href="#B54-energies-18-00299" class="html-bibr">54</a>].</p>
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<p>(<b>a</b>) Dataset 1 structure; (<b>b</b>) input–output structure of the BPANN model; (<b>c</b>) data partitioning.</p>
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<p>(<b>a</b>) Dataset 2 structure; (<b>b</b>) input–output structure of the BPANN model; (<b>c</b>) data partitioning.</p>
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<p>(<b>a</b>) Dataset 3 structure; (<b>b</b>) input–output structure of the BPANN model; (<b>c</b>) data partitioning.</p>
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<p>BPANN prediction of in-cylinder pressure for <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 1.6 and IT = −11 CAD aTDC.</p>
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<p>BPANN prediction of in-cylinder pressure for <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 2.0 and IT = −13 CAD aTDC.</p>
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<p>BPANN prediction of in-cylinder pressure for <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 2.3 and IT = −15 CAD aTDC.</p>
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<p>BPANN and GT-POWER P<sub>cyl, avg</sub> prediction performance for (<b>a</b>) <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 1.6 and IT = −9 CAD aTDC, (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 2.0 and IT = −15 CAD aTDC, and (<b>c</b>) <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 2.3 and IT = −13 CAD aTDC.</p>
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<p>Radar charts which compare the prediction performance of BPANN and GT-POWER in terms of P<sub>cyl, avg</sub>, ERR P<sub>max</sub>, and ERR AP<sub>max</sub> for (<b>a</b>) <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 1.6, (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 2.0, and (<b>c</b>) <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 2.3.</p>
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<p>BPANN prediction of in-cylinder pressure (<b>a</b>) and equivalent flame radius (<b>b</b>) for <math display="inline"><semantics> <mrow> <mi>λ</mi> </mrow> </semantics></math> = 1.6 and IT = −11 CAD aTDC.</p>
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12 pages, 4096 KiB  
Article
Benzo[1,2-b:6,5-b’]Dithiophene-4,5-Diamine: A New Fluorescent Probe for the High-Sensitivity and Real-Time Visual Monitoring of Phosgene
by Yingzhen Zhang, Jun Xiao, Ruiying Peng, Xueliang Feng, Haimei Mao, Kunming Liu, Zhenzhong Liu and Chunxin Ma
Sensors 2025, 25(2), 407; https://doi.org/10.3390/s25020407 (registering DOI) - 11 Jan 2025
Viewed by 263
Abstract
The detection of highly toxic chemicals such as phosgene is crucial for addressing the severe threats to human health and public safety posed by terrorist attacks and industrial mishaps. However, timely and precise monitoring of phosgene at a low cost remains a significant [...] Read more.
The detection of highly toxic chemicals such as phosgene is crucial for addressing the severe threats to human health and public safety posed by terrorist attacks and industrial mishaps. However, timely and precise monitoring of phosgene at a low cost remains a significant challenge. This work is the first to report a novel fluorescent system based on the Intramolecular Charge Transfer (ICT) effect, which can rapidly detect phosgene in both solution and gas phases with high sensitivity by integrating a benzo[1,2-b:6,5-b’]dithiophene-4,5-diamine (BDTA) probe. Among existing detecting methods, this fluorescent system stands out as it can respond to phosgene within a mere 30 s and has a detection limit as low as 0.16 μM in solution. Furthermore, the sensing mechanism was rigorously validated through high-resolution mass spectrometry (HRMS) and density functional theory (DFT) calculations. As a result, this fluorescent probing system for phosgene can be effectively adapted for real-time, high-sensitivity sensing and used as a test strip for visual monitoring without the need for specific equipment, which will also provide a new strategy for the fluorescent detection of other toxic materials. Full article
(This article belongs to the Collection Collection:Fluorescent Biosensors)
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<p>(<b>a</b>) Fluorescence emission spectra of the sensing system containing BDTA (100 μM), with or without BTC (200 μM) in indicated solvents; (<b>b</b>) the effect of ACN content on the probes under DMSO-ACN (λem = 490 nm, slits: 10/10 nm), rt for 30 s.</p>
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<p>(<b>a</b>) The fluorescence intensity of the system in the presence and absence of BTC in ACN at the indicated time. (<b>b</b>) Fluorescence emission spectra of BDTA in DMSO before and after the addition of BTC at the incubation time of 30 s. The detection concentration is 100 μM for BDTA in DMSO and 200 μM for BTC in ACN (λem = 490 nm, slits: 10/10 nm).</p>
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<p>(<b>a</b>) Fluorescence spectra of BDTA (100 μM) in response to different concentrations of BTC (0–200 μM), inset: photograph of 100 μM of BDTA with 0–200 μM of BTC 365 nm UV light; (<b>b</b>) linear relationship between BDTA and BTC (λem = 490 nm, slits: 10/10 nm).</p>
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<p>BDTA (100 μM) with various interfering substances (200 μM) and with or without BTC fluorescence response (λem = 490 nm, slits: 10/10 nm).</p>
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<p>Fluorescence changes of BDTA test strip without (<b>a</b>) and with (<b>b</b>) 10 mM BTC solution.</p>
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<p>(<b>a</b>) Schematic representation of phosgene detection using test strips. (<b>b</b>) Photos of BDTA (10 mM)-loaded paper strips exposed to various concentrations of phosgene.</p>
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<p>Frontier molecular orbitals of <b>BDTA</b> (<b>a</b>) and <b>BDTA-CO</b> (<b>b</b>) in DMSO by DFT at the B3LYP/6-31G.</p>
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<p>Detection principle of <b>BDTA</b> for phosgene determination.</p>
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17 pages, 6969 KiB  
Article
Comparative Study of Digital Twin Developed in Unity and Gazebo
by Maulshree Singh, Jayasekara Kapukotuwa, Eber Lawrence Souza Gouveia, Evert Fuenmayor, Yuansong Qiao, Niall Murray and Declan Devine
Electronics 2025, 14(2), 276; https://doi.org/10.3390/electronics14020276 (registering DOI) - 11 Jan 2025
Viewed by 140
Abstract
Digital twin (DT) technology has become a cornerstone in the simulation and analysis of real-world systems, offering unparalleled insights into the lifecycle management of physical assets. By providing a real-time synchronized replica of the physical entity, DTs enable predictive maintenance, performance optimization, and [...] Read more.
Digital twin (DT) technology has become a cornerstone in the simulation and analysis of real-world systems, offering unparalleled insights into the lifecycle management of physical assets. By providing a real-time synchronized replica of the physical entity, DTs enable predictive maintenance, performance optimization, and lifecycle extension, which are pivotal for industries aiming for digital transformation. This paper presents a comprehensive comparative study of DT development of a robotic arm using two prominent simulation platforms: Unity and Gazebo. Unity, with its roots in the gaming industry, offers robust real-time rendering and a user-friendly interface, making it a versatile choice for various industries. Gazebo, traditionally used in robotics, provides detailed physics simulations and sensor data emulation, which is ideal for precise engineering applications. We explored the performance of both platforms in creating accurate and dynamic digital replicas. Through qualitative and quantitative analyses, this study evaluates each platform’s strengths and limitations. The study assesses these platforms across key performance metrics such as accuracy, latency, graphic quality, and integration with the Robot Operating System (ROS). The DTs were developed using a consistent physical setup and communication layer to ensure fair comparisons. The results indicate that Unity performed better in terms of accurately mimicking the robotic arm with lower latency, making it ideal for applications requiring high-fidelity visualizations and real-time responsiveness. However, Gazebo excels in its ease of ROS integration and cost-effectiveness, making it a suitable choice for smaller robotics and automation projects. This study conducts an empirical comparison of these platforms in terms of their performance in creating DTs of robotic arms which is not readily available. This paper aims to guide developers and organizations in selecting the appropriate platform for their DT initiatives, ensuring efficient resource utilization and optimal outcomes. Full article
(This article belongs to the Special Issue Digital Twins in Industry 4.0, 2nd Edition)
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<p>Graph showing the number of publications related to Unity DT on Google Scholar, ScienceDirect, and Scopus from 2019 to 2024 (last checked 12 December 2024).</p>
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<p>DT implementation using Gazebo.</p>
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<p>Actual error of joints in Cycles (<b>a</b>) 1, (<b>b</b>) 2, and (<b>c</b>) 3, as indicated (<span class="html-italic">X</span>-axis: number of trajectories; <span class="html-italic">Y</span>-axis: actual error in degrees).</p>
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<p>Normalized error of joints in Cycles (<b>a</b>) 1, (<b>b</b>) 2, and (<b>c</b>) 3, as indicated (<span class="html-italic">X</span>-axis: number of trajectories; <span class="html-italic">Y</span>-axis: normalized Error in degrees).</p>
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<p>DT latency over 8000+ trajectory (<span class="html-italic">X</span>-axis: number of trajectories; <span class="html-italic">Y</span>-axis: latency in milliseconds).</p>
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<p>The contrast between the simulation graphics in Gazebo (<b>right</b>) and Unity (<b>left</b>).</p>
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14 pages, 690 KiB  
Article
A Study of Volatile Organic Compounds in Patients with Obstructive Sleep Apnea
by Chuan Hao Gui, Zhunan Jia, Zihao Xing, Fuchang Zhang, Fang Du, Alex Chengyao Tham, Ming Yann Lim, Yaw Khian Chong, Agnes Si Qi Chew and Khai Beng Chong
Metabolites 2025, 15(1), 42; https://doi.org/10.3390/metabo15010042 (registering DOI) - 11 Jan 2025
Viewed by 153
Abstract
Background: Obstructive Sleep Apnea (OSA) is a prevalent sleep disorder characterized by intermittent upper airway obstruction, leading to significant health consequences. Traditional diagnostic methods, such as polysomnography, are time-consuming and resource-intensive. Objectives: This study explores the potential of proton-transfer-reaction mass spectrometry [...] Read more.
Background: Obstructive Sleep Apnea (OSA) is a prevalent sleep disorder characterized by intermittent upper airway obstruction, leading to significant health consequences. Traditional diagnostic methods, such as polysomnography, are time-consuming and resource-intensive. Objectives: This study explores the potential of proton-transfer-reaction mass spectrometry (PTR-MS) in identifying volatile organic compound (VOC) biomarkers for the non-invasive detection of OSA. Methods: Breath samples from 89 participants, including 49 OSA patients and 40 controls, were analyzed using PTR-MS. Significance analysis was performed between OSA patients and controls to identify potential biomarkers for OSA. To as-sess the differences in VOC concentrations between OSA patients and control subjects,the Wilcoxon rank-sum test was employed. partial least squares discriminant analysis (PLS-DA) analysis and heatmap plot was conducted to visualize the differentiation between OSA patients and control subjects based on their VOC profiles.In order to further investigate the correlation between identified biomarkers and the severity of OSA measured by Apnea–Hypopnea Index (AHI), regression analysis was conducted between biomarkers and AHI Index. Results: The results identified specific VOCs, including m045 (acetaldehyde), m095.950, and m097.071, which showed significant differences between OSA patients and controls. Advanced statistical analyses, including PLS-DA and correlation mapping, highlighted the robustness of these biomarkers, with m045 (acetaldehyde) specifically emerging as a potential biomarker associated with the AHI Index. Conclusions: This study underscores the potential of VOCs as biomarkers for identifying patients with severe AHI levels. The analysis of VOCs using PTR-MS presents a rapid, non-invasive, and cost-effective method that could be seamlessly integrated into clinical practice, allowing clinicians to better stratify patients based on their need for polysomnography and prioritize those requiring earlier testing. Future studies are necessary to validate these findings in larger cohorts and to explore the integration of PTR-MS with other diagnostic modalities for improved accuracy and clinical utility. Full article
(This article belongs to the Section Endocrinology and Clinical Metabolic Research)
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