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47 pages, 2266 KiB  
Review
Hand Gesture Recognition on Edge Devices: Sensor Technologies, Algorithms, and Processing Hardware
by Elfi Fertl, Encarnación Castillo, Georg Stettinger, Manuel P. Cuéllar and Diego P. Morales
Sensors 2025, 25(6), 1687; https://doi.org/10.3390/s25061687 (registering DOI) - 8 Mar 2025
Abstract
Hand gesture recognition (HGR) is a convenient and natural form of human–computer interaction. It is suitable for various applications. Much research has already focused on wearable device-based HGR. By contrast, this paper gives an overview focused on device-free HGR. That means we evaluate [...] Read more.
Hand gesture recognition (HGR) is a convenient and natural form of human–computer interaction. It is suitable for various applications. Much research has already focused on wearable device-based HGR. By contrast, this paper gives an overview focused on device-free HGR. That means we evaluate HGR systems that do not require the user to wear something like a data glove or hold a device. HGR systems are explored regarding technology, hardware, and algorithms. The interconnectedness of timing and power requirements with hardware, pre-processing algorithm, classification, and technology and how they permit more or less granularity, accuracy, and number of gestures is clearly demonstrated. Sensor modalities evaluated are WIFI, vision, radar, mobile networks, and ultrasound. The pre-processing technologies stereo vision, multiple-input multiple-output (MIMO), spectrogram, phased array, range-doppler-map, range-angle-map, doppler-angle-map, and multilateration are explored. Classification approaches with and without ML are studied. Among those with ML, assessed algorithms range from simple tree structures to transformers. All applications are evaluated taking into account their level of integration. This encompasses determining whether the application presented is suitable for edge integration, their real-time capability, whether continuous learning is implemented, which robustness was achieved, whether ML is applied, and the accuracy level. Our survey aims to provide a thorough understanding of the current state of the art in device-free HGR on edge devices and in general. Finally, on the basis of present-day challenges and opportunities in this field, we outline which further research we suggest for HGR improvement. Our goal is to promote the development of efficient and accurate gesture recognition systems. Full article
(This article belongs to the Special Issue Multimodal Sensing Technologies for IoT and AI-Enabled Systems)
35 pages, 7059 KiB  
Review
Recent Advances in Nanostructured Conversion-Type Cathodes: Fluorides and Sulfides
by Mobinul Islam, Md. Shahriar Ahmed, Sua Yun, Basit Ali, Hae-Yong Kim and Kyung-Wan Nam
Nanomaterials 2025, 15(6), 420; https://doi.org/10.3390/nano15060420 (registering DOI) - 8 Mar 2025
Viewed by 8
Abstract
This review paper explores the emerging field of conversion cathode materials, which hold significant promises for advancing the performance of lithium-ion (LIBs) and lithium–sulfur batteries (LSBs). Traditional cathode materials of LIBs, such as lithium cobalt oxide, have reached their limits in terms of [...] Read more.
This review paper explores the emerging field of conversion cathode materials, which hold significant promises for advancing the performance of lithium-ion (LIBs) and lithium–sulfur batteries (LSBs). Traditional cathode materials of LIBs, such as lithium cobalt oxide, have reached their limits in terms of energy density and capacity, driving the search for alternatives that can meet the increasing demands of modern technology, including electric vehicles and renewable energy systems. Conversion cathodes operate through a mechanism involving complete redox reactions, transforming into different phases, which enables the storage of more lithium ions and results in higher theoretical capacities compared to conventional intercalation materials. This study examines various conversion materials, including metal oxides, sulfides, and fluorides, highlighting their potential to significantly enhance energy density. Despite their advantages, conversion cathodes face numerous challenges, such as poor conductivity, significant volume changes during cycling, and issues with reversibility and stability. This review discusses current nanoengineering strategies employed to address these challenges, including nano structuring, composite formulation, and electrolyte optimization. By assessing recent research and developments in conversion cathode technology, this paper aims to provide a comprehensive overview of their potential to revolutionize lithium-ion batteries and contribute to the future of energy storage solutions. Full article
(This article belongs to the Special Issue Nanomaterials for Battery Applications)
21 pages, 10680 KiB  
Article
A Long-Range, High-Efficiency Resonant Wireless Power Transfer via Imaginary Turn Ratio Air Voltage Transformer
by Hsien-Chung Tang, Chun-Hao Chen, Edward-Yi Chang, Da-Jeng Yao, Wei-Hua Chieng and Jun-Ying He
Energies 2025, 18(6), 1329; https://doi.org/10.3390/en18061329 (registering DOI) - 8 Mar 2025
Viewed by 6
Abstract
This paper presents a resonant wireless power transfer method that leverages a 90-degree voltage phase shift between the transmitting and receiving coils to enhance efficiency and maximize power transfer. When the resonant coupling is achieved, the secondary coil with an adjustable capacitor forms [...] Read more.
This paper presents a resonant wireless power transfer method that leverages a 90-degree voltage phase shift between the transmitting and receiving coils to enhance efficiency and maximize power transfer. When the resonant coupling is achieved, the secondary coil with an adjustable capacitor forms a tuned LC circuit. If the primary coil is driven at the resonant frequency of both the primary and secondary sides, the system can transmit 250W of power between the coils over a distance of 50 cm. Using a single power transmitting unit (PTU) board with multiple paralleled gallium nitride high-electron-mobility transistors (GaN HEMTs), the system achieves a maximum power transfer efficiency of 88%, highlighting the effectiveness of the design in high-efficiency, long-distance wireless power transmission. The key to the success of high-power, high-efficiency RWPT is in exhibiting the imaginary turn ratio presented on the air transformer. The imaginary turn ratio can realize the negative impedance conversion that converts the positive resistance on the power-receiving unit into a negative one, and thus, the damping of the resonance oscillation becomes negative and positively encourages more power to be delivered to the power-receiving unit (PRU) load. This paper derives the theory of the imaginary turn ratio and demonstrates the implementation of the RWPT system that exhibits the imaginary turn ratio effect. Full article
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Figure 1
<p>Long distance, high-power transfer RWPT schematic diagram.</p>
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<p>RWPT transformer model.</p>
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<p>Inductance change due to coupling coefficient <span class="html-italic">k</span> where <math display="inline"><semantics> <mrow> <mi>b</mi> </mrow> </semantics></math> is the back iron distance.</p>
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<p>Magnetic flux gain due to back iron distance <math display="inline"><semantics> <mrow> <mi>b</mi> </mrow> </semantics></math>.</p>
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<p>Core loss resistance <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>c</mi> </mrow> </msub> <mo>(</mo> <mi>b</mi> <mo>)</mo> </mrow> </semantics></math> and coil resistance <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>T</mi> </mrow> </msub> </mrow> </semantics></math> due to back iron distance <math display="inline"><semantics> <mrow> <mi>b</mi> </mrow> </semantics></math>.</p>
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<p>FEM analysis of the flux linkage intensity via back iron distance <span class="html-italic">b</span>. The red circles indicate the flux density in the flux linkage direction toward the PRU.</p>
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<p>RWPT transformer model.</p>
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<p>Switching power supply: (<b>a</b>) class-E amplifier and (<b>b</b>) multiple paralleled high-frequency D-mode GaN HEMT configuration.</p>
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<p>Standard waveforms of the switching power supply.</p>
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<p>PRU resonator with rectified clipper circuit.</p>
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<p>Circuit simulation of the RWPT system: (<b>a</b>) SPICE circuit and (<b>b</b>) simulation result.</p>
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<p>Experiment layout.</p>
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<p>Waveforms of the air transformer and GaN HEMTs: (<b>a</b>) PTU and (<b>b</b>) PRU.</p>
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<p>Waveforms of the air transformer and GaN HEMTs: (<b>a</b>) PTU and (<b>b</b>) PRU.</p>
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<p>Power and efficiency vs. (<b>a</b>) input voltage <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>V</mi> </mrow> <mrow> <mi>D</mi> <mi>D</mi> </mrow> </msub> </mrow> </semantics></math> and (<b>b</b>) input current <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>I</mi> </mrow> <mrow> <mi>i</mi> <mi>n</mi> </mrow> </msub> </mrow> </semantics></math> (=<math display="inline"><semantics> <mrow> <msub> <mrow> <mi>I</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math>) @ <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>V</mi> </mrow> <mrow> <mi>D</mi> <mi>D</mi> </mrow> </msub> <mo>=</mo> <mn>36</mn> <mo> </mo> <mi mathvariant="normal">V</mi> </mrow> </semantics></math>.</p>
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<p>Power loss budget chart.</p>
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16 pages, 2722 KiB  
Article
Evaluation of Sentinel-2 Deep Resolution 3.0 Data for Winter Crop Identification and Organic Barley Yield Prediction
by Milen Chanev, Ilina Kamenova, Petar Dimitrov and Lachezar Filchev
Remote Sens. 2025, 17(6), 957; https://doi.org/10.3390/rs17060957 (registering DOI) - 8 Mar 2025
Viewed by 3
Abstract
Barley is an ecologically adaptable crop widely used in agriculture and well suited for organic farming. Satellite imagery from Sentinel-2 can support crop monitoring and yield prediction, optimising production processes. This study compares two types of Sentinel-2 data—standard (S2) data with 10 m [...] Read more.
Barley is an ecologically adaptable crop widely used in agriculture and well suited for organic farming. Satellite imagery from Sentinel-2 can support crop monitoring and yield prediction, optimising production processes. This study compares two types of Sentinel-2 data—standard (S2) data with 10 m and 20 m resolution and Sentinel-2 Deep Resolution 3 (S2DR3) data with 1 m resolution—to assess their (i) relationship with yield in organically grown barley and (ii) utility for winter crop mapping. Vegetation indices were generated and analysed across different phenological phases to determine the most suitable predictors of yield. The results indicate that using 10 × 10 m data, the BBCH-41 phase is optimal for yield prediction, with the Green Chlorophyll Vegetation Index (GCVI; r = 0.80) showing the strongest correlation with yield. In contrast, S2DR3 data with a 1 × 1 m resolution demonstrated that Transformed the Chlorophyll Absorption in Reflectance Index (TCARI), TO, and Normalised Difference Red Edge Index (NDRE1) were consistently reliable across all phenological stages, except for BBCH-51, which showed weak correlations. These findings highlight the potential of remote sensing in organic barley farming and emphasise the importance of selecting appropriate data resolutions and vegetation indices for accurate yield prediction. With the use of three-date spectral band stacks, the Random Forest (RF) and Support Vector Classification (SVC) methods were used to differentiate between wheat, barley, and rapeseed. A five-fold cross-validation approach was applied, training data were stratified with 200 points per crop, and classification accuracy was assessed using the User’s and Producer’s accuracy metrics through pixel-by-pixel comparison with a reference raster. The results for S2 and S2DR3 were very similar to each other, confirming the significant potential of S2DR3 for high-resolution crop mapping. Full article
(This article belongs to the Section Remote Sensing in Agriculture and Vegetation)
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Figure 1
<p>(<b>A</b>) The overall location of the study area in Bulgaria. The image data used in this study correspond to Sentinel-2 tile T35TLG shown as a red square. (<b>B</b>) Sentinel-2 Deep Resolution 3.0 imagery in natural colours from 30 April 2023 obtained over tile T35TLG. The red rectangle and dot indicate the location of the area used for crop classification and the field used for collecting crop yield data, respectively. Closer looks at these two sites are shown in (<b>C</b>,<b>D</b>), respectively. (<b>E</b>) Subsets of Sentinel-2 Deep Resolution 3.0 (top, 1 m spatial resolution) and Sentinel-2 (10 m spatial resolution) obtained over an arbitrary agricultural area (location shown with arrow on (<b>C</b>); 30 April 2023; natural colours).</p>
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<p>Correlation between yield of organic barley from S2DR3 data (blue) and S2 data (orange) in phase BBCH-41.</p>
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<p>Correlation between yield of organic barley from S2DR3 data (blue) and S2 data (orange) in phase BBCH-51.</p>
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<p>Correlation between yield of organic barley from S2DR3 data (blue) and S2 data (orange) in phase BBCH-77.</p>
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<p>Maps showing the distribution of the three winter crops according to the SVC classifications of the Sentinel-2 (S2; left) and Sentinel-2 Deep Resolution 3.0 (S2DR3; middle) multitemporal datasets and the reference vector data (IACS/GSA; right). The areas indicated with “A” and “B” illustrate two typical error patterns (see text for more details). The maps cover Site 2 (see <a href="#remotesensing-17-00957-f001" class="html-fig">Figure 1</a>C for its location).</p>
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<p>Spectral profiles of the three winter crops for the two image types, S2DR3 and S2, and the three dates. Dots represent the mean and error bars represent the standard deviation of 50 randomly selected pixels for each crop. Pixels were sampled at image native resolution, i.e., 1 m for S2DR3 and 10 m/20 m for S2. Sampling locations were the same for S2DR3 and S2.</p>
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18 pages, 3050 KiB  
Article
Nanoscale “Chessboard” Pattern Lamellae in a Supramolecular Perylene-Diimide Polydiacetylene System
by Ian J. Martin, Francis Kiranka Masese, Kuo-Chih Shih, Mu-Ping Nieh and Rajeswari M. Kasi
Molecules 2025, 30(6), 1207; https://doi.org/10.3390/molecules30061207 - 7 Mar 2025
Viewed by 169
Abstract
The rational design of ordered chromogenic supramolecular polymeric systems is critical for the advancement of next-generation stimuli-responsive, optical, and semiconducting materials. Previously, we reported the design of a stimuli-responsive, lamellar self-assembled platform composed of an imidazole-appended perylene diimide of varying methylene spacer length [...] Read more.
The rational design of ordered chromogenic supramolecular polymeric systems is critical for the advancement of next-generation stimuli-responsive, optical, and semiconducting materials. Previously, we reported the design of a stimuli-responsive, lamellar self-assembled platform composed of an imidazole-appended perylene diimide of varying methylene spacer length (n = 3, 4, and 6) and a commercially available diacid-functionalized diacetylene monomer, 10, 12 docosadiynedioic acid, in a 1:1 molar ratio. Herein, we expound on the importance of the composition of the imidazole-appended perylene diimide of varying methylene spacer length (n = 3, 4, and 6) and 10, 12 docosadiynedioic acid in the ratio of 2:1 to the supramolecular self-assembly, final morphology, and properties. Topochemical polymerization of the drop-cast films by UV radiation yielded blue-phase polydiacetylene formation, and subsequent thermal treatment of the films produced a thermoresponsive blue-to-red phase transformation. Differential scanning calorimetry (DSC) studies revealed a dual dependence of the methylene spacer length and stimuli treatment (UV and/or heat) on the thermal transitions of the films. Furthermore, small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS) showed well-defined hierarchical semiconducting nanostructures with interconnected “chessboard”-patterned lamellar stacking. Upon doping with an ionic liquid, the 2:1 platform showed higher ionic conductivity than the previous 1:1 one. The results presented here illustrate the importance of the composition and architecture to the ionic domain connectivity and ionic conductivity, which will have far-reaching implications for the rational design of semiconducting polymers for energy applications including fuel cells, batteries, ion-exchange membranes, and mixed ionic conductors. Full article
21 pages, 2174 KiB  
Article
Deep Learning Ensemble Approach for Predicting Expected and Confidence Levels of Signal Phase and Timing Information at Actuated Traffic Signals
by Seifeldeen Eteifa, Amr Shafik, Hoda Eldardiry and Hesham A. Rakha
Sensors 2025, 25(6), 1664; https://doi.org/10.3390/s25061664 - 7 Mar 2025
Viewed by 77
Abstract
Predicting Signal Phase and Timing (SPaT) information and confidence levels is needed to enhance Green Light Optimal Speed Advisory (GLOSA) and/or Eco-Cooperative Adaptive Cruise Control (Eco-CACC) systems. This study proposes an architecture based on transformer encoders to improve prediction performance. This architecture is [...] Read more.
Predicting Signal Phase and Timing (SPaT) information and confidence levels is needed to enhance Green Light Optimal Speed Advisory (GLOSA) and/or Eco-Cooperative Adaptive Cruise Control (Eco-CACC) systems. This study proposes an architecture based on transformer encoders to improve prediction performance. This architecture is combined with different deep learning methods, including Multilayer Perceptrons (MLP), Long-Short-Term Memory neural networks (LSTM), and Convolutional Long-Short-Term Memory neural networks (CNNLSTM) to form an ensemble of predictors. The ensemble is used to make data-driven predictions of SPaT information obtained from traffic signal controllers for six different intersections along the Gallows Road corridor in Virginia. The study outlines three primary tasks. Task one is predicting whether a phase would change within 20 s. Task two is predicting the exact change time within 20 s. Task three is assigning a confidence level to that prediction. The experiments show that the proposed transformer-based architecture outperforms all the previously used deep learning methods for the first two prediction tasks. Specifically, for the first task, the transformer encoder model provides an average accuracy of 96%. For task two, the transformer encoder models provided an average mean absolute error (MAE) of 1.49 s, compared to 1.63 s for other models. Consensus between models is shown to be a good leading indicator of confidence in ensemble predictions. The ensemble predictions with the highest level of consensus are within one second of the true value for 90.2% of the time as opposed to those with the lowest confidence level, which are within one second for only 68.4% of the time. Full article
(This article belongs to the Special Issue AI and Smart Sensors for Intelligent Transportation Systems)
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Figure 1
<p>The 6 intersections with Gallows Road in Northern Virginia from which data were collected.</p>
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<p>Different variables in SmarterRoads data.</p>
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<p>MLP Neural Network Architecture.</p>
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<p>LSTM Neural Network Architecture.</p>
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<p>CNN LSTM Neural Network Architecture.</p>
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<p>Transformer encoder-based architecture.</p>
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<p>Encoder block architecture.</p>
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<p>MAPE as a function of the level of consensus with a 5% tolerance level for all 6 intersections.</p>
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<p>The error distributions (<b>a</b>) consensus values 1 to 3. (<b>b</b>) consensus values 4 to 6. (<b>c</b>) consensus values 7 to 9. (<b>d</b>) consensus values 10 to 12.</p>
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<p>Percentage of outlier predictions with an error greater than 10 s.</p>
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<p>Effect of level of consensus on fuel savings.</p>
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23 pages, 5483 KiB  
Article
A Study on Tantalum Alloying Layer and Its Performance on the Surface of 316LSS in Harsh Environments
by Qinghua Li, Zhehang Fan, Xiaohu Chen, Xiaoyong Tao, Ruian Ni, Kai Zhang, Aqib Mashood Khan, Syed Muhammad Raza, Yiming Wen and Hongyan Wu
Coatings 2025, 15(3), 313; https://doi.org/10.3390/coatings15030313 - 7 Mar 2025
Viewed by 70
Abstract
Tantalum diffusion layers were fabricated on 316L stainless steel substrates using the double glow plasma surface alloying technology (DGPSAT). The optimization rules of the Fe-Ta diffusion layer under varying alloying times were investigated, focusing on the effects of processing parameters on the phase [...] Read more.
Tantalum diffusion layers were fabricated on 316L stainless steel substrates using the double glow plasma surface alloying technology (DGPSAT). The optimization rules of the Fe-Ta diffusion layer under varying alloying times were investigated, focusing on the effects of processing parameters on the phase structure and microstructure. The results indicate that, as the alloying time increases, the surface wrinkled structure in the Fe-Ta alloy layer gradually transforms into a nanoscale acicular α-Ta structure, improving surface roughness and water contact angle. The surface microstructure influenced by the alloying time enhanced mechanical properties significantly, increasing Vickers hardness from 152 HV0.2 to 970 HV0.2, improving bonding strength, and reducing the friction coefficient to 0.5. Electrochemical testing showed that the corrosion rate of the tantalum diffusion layer was significantly reduced from 1.04 × 10−2 mm/a to 2.83 × 10−4 mm/a, demonstrating the excellent corrosion resistance. The island growth pattern during the formation of alloy layers was simulated by molecular dynamics. Replacing bulk materials with tantalum diffusion layers can economize rare metals, reduce costs, and be of great significant for the special equipment applications in harsh environments. Full article
19 pages, 4849 KiB  
Article
Impact of Supercritical Carbon Dioxide on Pore Structure and Gas Transport in Bituminous Coal: An Integrated Experiment and Simulation
by Kui Dong, Zhiyu Niu, Shaoqi Kong and Bingyi Jia
Molecules 2025, 30(6), 1200; https://doi.org/10.3390/molecules30061200 - 7 Mar 2025
Viewed by 182
Abstract
The injection of CO2 into coal reservoirs occurs in its supercritical state (ScCO2), which significantly alters the pore structure and chemical composition of coal, thereby influencing the adsorption and diffusion behavior of methane (CH4). Understanding these changes is [...] Read more.
The injection of CO2 into coal reservoirs occurs in its supercritical state (ScCO2), which significantly alters the pore structure and chemical composition of coal, thereby influencing the adsorption and diffusion behavior of methane (CH4). Understanding these changes is crucial for optimizing CH4 extraction and improving CO2 sequestration efficiency. This study aims to investigate the effects of ScCO2 on the pore structure, chemical bonds, and CH4 diffusion mechanisms in bituminous coal to provide insights into coal reservoir stimulation and CO2 storage. By utilizing high-pressure CO2 injection adsorption, low-pressure CO2 gas adsorption (LP-CO2-GA), Fourier-transform infrared spectroscopy (FTIR), and reactive force field molecular dynamics (ReaxFF-MD) simulations, this study examines the multi-scale changes in coal at the nano- and molecular levels. The following results were found: Pore Structure Evolution: After ScCO2 treatment, micropore volume increased by 19.1%, and specific surface area increased by 11.2%, while mesopore volume and specific surface area increased by 14.4% and 5.7%, respectively. Chemical Composition Changes: The content of aromatic structures, oxygen-containing functional groups, and hydroxyl groups decreased, while aliphatic structures increased. Specific molecular changes included an increase in (CH2)n, 2H, 1H, and secondary alcohol (-C-OH) and phenol (-C-O) groups, while Car-Car and Car-H bonds decreased. Mechanisms of Pore Volume Changes: The pore structure evolves through three distinct phases: Swelling Phase: Breakage of low-energy bonds generates new micropores. Aromatic structure expansion reduces intramolecular spacing but increases intermolecular spacing, causing a decrease in micropore volume and an increase in mesopore volume. Early Dissolution Phase: Continued bond breakage increases micropore volume, while released aliphatic and aromatic structures partially occupy these pores, converting some mesopores into micropores. Later Dissolution Phase: Minimal chemical bond alterations occur, but weakened π-π interactions and van der Waals forces between aromatic layers result in further mesopore volume expansion. Impact on CH4 Diffusion: Changes in pore volume directly affect CH4 migration. In the early stages of ScCO2 interaction, pore shrinkage reduces the mean square displacement (MSD) and self-diffusion coefficient of CH4. However, as the reaction progresses, pore expansion enhances CH4 diffusion, ultimately improving gas extraction efficiency. This study provides a fundamental understanding of how ScCO2 modifies coal structure and CH4 transport properties, offering theoretical guidance for enhanced CH4 recovery and CO2 sequestration strategies. Full article
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Figure 1
<p>ScCO<sub>2</sub> and TL interaction mechanism analysis flow chart.</p>
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<p>(<b>a</b>) Macromolecular structure of TL; (<b>b</b>) geometric optimization model of TL; (<b>c</b>) supramolecular structure of TL; and (<b>d</b>) ScCO<sub>2</sub> injection model (C: gray; H: white; O: red; S: yellow; N: blue).</p>
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<p>Relationship between the absolute adsorption capacity of TL coal and CO<sub>2</sub> injection pressure.</p>
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<p>FTIR change characteristics before and after ScCO<sub>2</sub> treatment.</p>
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<p>Characteristics of chemical bond changes in TL samples during ScCO<sub>2</sub> treatment.</p>
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<p>The process of new micropore formation during ScCO<sub>2</sub> reactions (C: gray; O: red; N: blue; S: Yellow).</p>
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<p>The process of micropore deformation during ScCO<sub>2</sub> reactions (C: gray; O: red).</p>
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<p>The process of mesopore deformation during ScCO<sub>2</sub> reactions (C: gray; O: red; N: blue).</p>
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<p>Changes in MSD of CH4 during ScCO<sub>2</sub> reaction.</p>
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<p>Self-diffusion coefficients change during the ScCO<sub>2</sub> reaction.</p>
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23 pages, 1939 KiB  
Article
Enhancing Mobile App Development for Sustainability: Designing and Evaluating the SBAM Design Cards
by Chiara Tancredi, Roberta Presta, Laura Mancuso and Roberto Montanari
Sustainability 2025, 17(6), 2352; https://doi.org/10.3390/su17062352 - 7 Mar 2025
Viewed by 85
Abstract
Behavioral changes are critical for addressing sustainability challenges, which have become increasingly urgent due to the growing impact of global greenhouse gas emissions on ecosystems and human livelihoods. However, translating awareness into meaningful action requires practical tools to bridge this gap. Mobile applications, [...] Read more.
Behavioral changes are critical for addressing sustainability challenges, which have become increasingly urgent due to the growing impact of global greenhouse gas emissions on ecosystems and human livelihoods. However, translating awareness into meaningful action requires practical tools to bridge this gap. Mobile applications, utilizing strategies from human–computer interaction (HCI) such as gamification, nudging, and persuasive technologies, have proven to be powerful in promoting sustainable behaviors. To support designers in developing effective apps of this kind, theory-based design guidelines were created, drawing on established theories and design approaches aimed at shaping and encouraging virtuous user behaviors fostering sustainability. To make these guidelines more accessible and enhance their usability during the design phase, this study presents their transformation into the SBAM card deck, a deck of 11 design cards. The SBAM cards aim to simplify theoretical concepts, stimulate creativity, and provide structured support for design discussions, helping designers generate solutions tailored to specific project contexts. This study also evaluates the effectiveness of the SBAM cards in the design process through two workshops with design students. Results show that the cards enhance ideation, foster creativity, and improve designers’ perceived self-efficacy compared to the exploitation of the same design guidelines information presented in traditional textual formats. This paper discusses the SBAM cards design and evaluation methodology, findings, and implications, offering insights into how the SBAM design cards can bridge the gap between theory and practice in sustainability-focused mobile app development. To ensure broader accessibility, the SBAM cards have been made available to the public through a dedicated website. Full article
(This article belongs to the Special Issue Environmental Behavior and Climate Change)
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<p>SBAM cards, developed based on the SBAM guidelines proposed by Tancredi et al. [<a href="#B17-sustainability-17-02352" class="html-bibr">17</a>], aimed at supporting the design of mobile apps fostering sustainable behaviors.</p>
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<p>Participants using the SBAM cards during the workshop.</p>
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<p>Comparison of self-efficacy scores (Entry and Exit) for the control group (<b>on the left</b>) and for the experimental group (<b>on the right</b>) in the first and second workshops. The experimental group in both workshops shows significant increases in Exit scores compared to Entry scores.</p>
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<p>Comparison of CSI scores between experimental and control groups across the first and second workshops. The experimental group consistently outperformed the control group, with significant differences observed in both workshops.</p>
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<p>Comparison of SUS scores between experimental and control groups across the first and second workshops. The experimental group consistently scored higher than the control group, with significant differences in both workshops.</p>
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<p>Comparison of perceived usefulness scores between experimental and control groups in the first and second workshops. The experimental group achieved higher scores in both workshops, but the differences were not statistically significant.</p>
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<p>Comparison of scores for the Theoretical grounding and Creativity dimensions between experimental and control groups, as rated by the design quality evaluators. Both differences are statistically significant.</p>
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<p>First slide of the PowerPoint template.</p>
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<p>Second slide of the PowerPoint template.</p>
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<p>Third slide of the PowerPoint template.</p>
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<p>Fourth slide of the PowerPoint template.</p>
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<p>Fifth slide of the PowerPoint template.</p>
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19 pages, 17724 KiB  
Article
Analysis of Typical Inclusion Evolution and Formation Mechanism in the Smelting Process of W350 Non-Oriented Silicon Steel
by Jiagui Shi, Libin Yang, Bowen Peng, Guoqiang Wei and Yibo Yuan
Materials 2025, 18(6), 1188; https://doi.org/10.3390/ma18061188 - 7 Mar 2025
Viewed by 172
Abstract
The production of silicon steel involves complex metallurgical processes, where the kind, composition, size, and quantity of the inclusions generated affect the silicon steel properties. This article is based on the smelting process for W350 non-oriented silicon steel produced by a certain factory. [...] Read more.
The production of silicon steel involves complex metallurgical processes, where the kind, composition, size, and quantity of the inclusions generated affect the silicon steel properties. This article is based on the smelting process for W350 non-oriented silicon steel produced by a certain factory. By systematically sampling, at key nodes of the converter–RH refining–tundish smelting process, the change in cleanliness of molten steel in the whole smelting process, the evolution of typical inclusions, and the transformation rules for the precipitated phase were analyzed by means of SEM-EDS, ASPEX, and Thermal-Calc. The results indicate that the total oxygen mass fraction in the steel decreases by more than 95% after deoxidation alloying, and the average oxygen mass fraction in the RH outbound steel is 0.0012%. While the nitrogen mass fraction shows a rising trend as a whole, the average nitrogen mass fraction in the tundish steel reaches approximately 0.0014%. Before RH refining, large Al2O3–CaO–SiO2 and Al2O3–CaO–SiO2–MgO composite inclusions are the main inclusions. MnO and Al2O3–SiO2–MnO inclusions are the main inclusions after RH inlet and RH decarburization. After RH deoxidation with aluminum, the inclusions were almost entirely transformed into Al2O3 inclusions. After RH alloying, with the content of Si and Mn increased, the inclusions transformed into Al2O3–SiO2–MnO inclusions. The number of inclusions from RH desulfurization to the RH outbound stage declined significantly, and composite inclusions containing CaS and precipitates such as AlN and MnS began to appear. The inclusions’ main types were Al2O3–MgO–CaS, AlN–MnS, AlN, and Al2O3–MgO. The inclusions inside the tundish were the same, but the numbers were slightly increased due to the secondary oxidation of molten steel. More than 80% of the oxide inclusions in the whole process were between 1 μm and 5 μm in size. The average size and the number of inclusions per unit area reached 5.45 μm and 63.1 per mm2, respectively, after RH deoxidation, and respectively decreased to 3.71 μm and 1.9 per mm2 during the RH outbound stage, but both increased slightly in the tundish. Thermodynamic calculation shows that Al2O3–MgO inclusions are formed when w([Mg]) > 0.0033% in molten steel at 1873 K. Under the actual temperature of 1828K and w([Al]s) = 0.6515%, the range of w([Mg]) corresponding to the stable existence of Al2O3–MgO is between 0.0053% and 0.1676%. The liquidus temperature of W350 non-oriented silicon steel is 1489 °C. MnS and AlN inclusions are precipitated successively with the solidification of molten steel, and the precipitation temperatures are 1460.7 °C and 1422.2 °C, respectively. As the temperature decreases, the sequence of inclusion precipitation calculated in liquid was as follows: Al2O3–CaO → 2Al2O3–CaO + MnS → 6Al2O3–CaO → Al2O3 + AlN + MnS + CaS. Full article
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<p>Sampling scheme for the whole smelting process of W350 non-oriented silicon steel.</p>
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<p>Schematic diagram of sample machining.</p>
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<p>Variation in total oxygen and nitrogen mass fraction in molten steel during smelting (T ≥ 2000 °C, relative standard deviation ≈ 1%): (<b>a</b>) the end-point of converter blowing; (<b>b</b>) argon blowing station; (<b>c</b>) RH inlet; (<b>d</b>) after RH decarburization; (<b>e</b>) after RH deoxygenation and alloying; (<b>f</b>) RH desulfurization; (<b>g</b>) RH outbound; (<b>h</b>) tundish.</p>
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<p>Typical inclusions before RH refining (at room temperature): (<b>a1</b>–<b>a3</b>) the end-point of converter blowing; (<b>b1</b>–<b>b3</b>) argon blowing station.</p>
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<p>Typical inclusions during the RH refining process (at room temperature): (<b>a1</b>–<b>a4</b>) RH inlet; (<b>b1</b>–<b>b3</b>) RH decarburization for 3 min; (<b>c1</b>–<b>c3</b>) RH adding aluminum deoxygenation for 3 min; (<b>d1</b>,<b>d2</b>) RH for the first batch of alloying for 4 min; (<b>e1</b>–<b>e3</b>) RH desulfurization for 3 min; (<b>f1</b>–<b>f4</b>) RH outbound.</p>
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<p>Typical inclusions during the RH refining process (at room temperature): (<b>a1</b>–<b>a4</b>) RH inlet; (<b>b1</b>–<b>b3</b>) RH decarburization for 3 min; (<b>c1</b>–<b>c3</b>) RH adding aluminum deoxygenation for 3 min; (<b>d1</b>,<b>d2</b>) RH for the first batch of alloying for 4 min; (<b>e1</b>–<b>e3</b>) RH desulfurization for 3 min; (<b>f1</b>–<b>f4</b>) RH outbound.</p>
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<p>Typical inclusions in the tundish (at room temperature).</p>
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<p>Distribution of oxide inclusions in different production processes: (<b>a</b>) before RH refining; (<b>b</b>) after RH decarbonization; (<b>c</b>) after RH deoxygenation; (<b>d</b>) after RH alloying; (<b>e</b>) RH outbound; (<b>f</b>) tundish.</p>
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<p>Variation in size and quantity of inclusions in molten steel under different production processes: (<b>a</b>) the end-point of converter blowing; (<b>b</b>) argon blowing station; (<b>c</b>) RH inlet; (<b>d</b>) after RH decarbonization; (<b>e</b>) after RH deoxygenation; (<b>f</b>) after RH alloying; (<b>g</b>) after RH desulfurization; (<b>h</b>) RH outbound; (<b>i</b>) tundish.</p>
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<p>Phase equilibrium diagram of MgO/Al<sub>2</sub>O<sub>3</sub>–MgO/Al<sub>2</sub>O<sub>3</sub> at RH outbound.</p>
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<p>Transformation of precipitates during solidification process: (<b>a</b>) phase transition; (<b>b</b>) compositional transformation.</p>
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26 pages, 11365 KiB  
Article
Angle Estimation Based on Wave Path Difference Rate of Change Ambiguity Function
by Jianye Xu, Maozhong Fu and Zhenmiao Deng
Remote Sens. 2025, 17(5), 943; https://doi.org/10.3390/rs17050943 - 6 Mar 2025
Viewed by 113
Abstract
Modern radar systems commonly utilize monopulse angle estimation techniques for target angle estimation, with the phase comparison method being one of the most widely adopted approaches. While the phase comparison method achieves high estimation precision, it is highly susceptible to noise and exhibits [...] Read more.
Modern radar systems commonly utilize monopulse angle estimation techniques for target angle estimation, with the phase comparison method being one of the most widely adopted approaches. While the phase comparison method achieves high estimation precision, it is highly susceptible to noise and exhibits a suboptimal performance under low Signal-to-Noise Ratio (SNR) conditions, leading to a high SNR threshold. Moreover, conventional monopulse angle estimation methods provide limited target information, as a single measurement cannot reveal the target’s motion direction. To address these shortcomings, a novel approach based on the phase comparison method is proposed in this study, with the variation in the wave path difference modeled as a first-order motion model. By accumulating the conjugate-multiplied signals over multiple time steps, the Wave Path Difference Rate of Change Ambiguity Function (WPD-ROC AF) is constructed. A fast algorithm employing the 2D Chirp-Z Transform (2D-CZT) is proposed, enabling multi-pulse angle estimation through the identification of frequency and phase values corresponding to spectral peaks. Simulation results validate that the proposed method outperforms traditional monopulse angle estimation techniques under low-SNR conditions and effectively suppresses static clutter interference. Furthermore, the sign of the WPD-ROC AF is shown to be correlated with the target’s motion direction, providing practical utility for determining the direction of movement in remote sensing scenarios. Full article
(This article belongs to the Section Remote Sensing Image Processing)
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<p>The schematic of the radar antenna array plane [<a href="#B22-remotesensing-17-00943" class="html-bibr">22</a>].</p>
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<p>Phase comparison angle estimation method principle diagram.</p>
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<p>The impact of conjugate multiplication on SNR. (<b>a</b>) The relationship between the SNR before and after conjugate multiplication; (<b>b</b>) the relationship between SNR loss and the original input SNR.</p>
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<p>The spectrum of the conjugate cross-correlation signal at eight consecutive time instances.</p>
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<p>The WPD-ROC AF obtained by accumulating eight conjugate cross-correlation signals. (<b>a</b>) WPD-ROC AF; (<b>b</b>) the cross-sectional plot of WPD-ROC AF.</p>
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<p>2D-FFT spectrum.</p>
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<p>2D-CZT spectrum.</p>
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<p>Comparison of spectrum at high and low SNR. (<b>a</b>) Doppler transform spectrum at high SNR; (<b>b</b>) Doppler transform spectrum at low SNR; (<b>c</b>) two-dimensional transform spectrum at low SNR.</p>
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<p>Comparison of WPD-ROC AF with and without denoising. (<b>a</b>) WPD-ROC AF without denoising; (<b>b</b>) denoised WPD-ROC AF.</p>
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<p>Comparison of angle estimation precision with and without denoising.</p>
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<p>Joint angle estimation algorithm flowchart.</p>
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<p>Monopulse signals spectrum from each quadrant. (<b>a</b>) Monopulse signal spectrum of quadrant A; (<b>b</b>) monopulse signal spectrum of quadrant B.</p>
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<p>Monopulse cross-correlation signal spectrum.</p>
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<p>The 2D spectrum of the signals from each quadrant. (<b>a</b>) The 2D spectrum of quadrant A signal; (<b>b</b>) the 2D spectrum of quadrant B signal.</p>
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<p>The 2D spectrum of the echo signals from each quadrant with static clutter removal. (<b>a</b>) The 2D spectrum of quadrant A signal with static clutter removal; (<b>b</b>) the 2D spectrum of quadrant B signal with static clutter removal.</p>
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<p>The comparison of WPD-ROC AF spectrum with and without static clutter removal. (<b>a</b>) The WPD-ROC AF after static clutter removal; (<b>b</b>) the WPD-ROC AF without static clutter removal.</p>
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<p>Comparison of WPD-ROC AF spectrum with different target wave path difference rates. (<b>a</b>) WPD-ROC AF with the target wave path difference rate of 1 <math display="inline"><semantics> <mrow> <mi mathvariant="normal">m</mi> <mo>/</mo> <mi mathvariant="normal">s</mi> </mrow> </semantics></math>; (<b>b</b>) WPD-ROC AF with the target wave path difference rate of −1 <math display="inline"><semantics> <mrow> <mi mathvariant="normal">m</mi> <mo>/</mo> <mi mathvariant="normal">s</mi> </mrow> </semantics></math>.</p>
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<p>Simulation of first-order model approximation error impact. (<b>a</b>) WPD Variation with Constant Rate; (<b>b</b>) WPD Variation with Acceleration.</p>
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<p>The WPD estimation precision.</p>
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<p>The ROC estimation precision.</p>
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<p>The ROC estimation precision of phase comparison monopulse angle estimation method.</p>
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<p>The angle estimation precision.</p>
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<p>The angle estimation accuracy.</p>
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<p>The comparison of angle estimation precision.</p>
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<p>The comparison of angle estimation accuracy.</p>
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<p>The angle estimation precision under different quadrant array spacings.</p>
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19 pages, 7569 KiB  
Article
Vibration Analysis of Shape Memory Alloy Enhanced Multi-Layered Composite Beams with Asymmetric Material Behavior
by Kosar Samadi-Aghdam, Pouya Fahimi, Hamid Shahsavari, Davood Rahmatabadi and Mostafa Baghani
Materials 2025, 18(5), 1181; https://doi.org/10.3390/ma18051181 - 6 Mar 2025
Viewed by 116
Abstract
This study develops a finite element solution to analyze the vibration response of multi-layer shape memory alloy (SMA) composite beams. Using Euler–Bernoulli beam motion equations with tension–compression asymmetry, based on Poorasadion’s model, the Newmark method and Newton–Raphson technique are employed. Validating the model [...] Read more.
This study develops a finite element solution to analyze the vibration response of multi-layer shape memory alloy (SMA) composite beams. Using Euler–Bernoulli beam motion equations with tension–compression asymmetry, based on Poorasadion’s model, the Newmark method and Newton–Raphson technique are employed. Validating the model against ABAQUS/Standard results for a homogeneous SMA beam shows good agreement. This research explores the dynamic characteristics of bi-layer and tri-layer SMA beams, presenting deflection–time, stress–strain, and velocity–deflection profiles. SMAs’ hysteresis property effectively reduces early-stage vibration amplitudes, and their energy-dissipating feature during phase transformations makes them promising for controlling dynamic performance in engineering applications. Full article
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<p>A typical beam element with forces and moments to derive motion equations.</p>
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<p>Solution algorithm for the proposed formulation.</p>
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<p>Geometry of the beam and the cross-section.</p>
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<p>History of the maximum deflection (<b>a</b>,<b>b</b>) and velocity (<b>c</b>,<b>d</b>) for the ASYM and SYM models and also for the proposed model and finite element simulations.</p>
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<p>Schematic of the tri-layer composite beam.</p>
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<p>Free vibration analysis of tri-layer SMA composite beam, (<b>a</b>) time history of the tri-layer beam tip deflections, (<b>b</b>) time history of the velocity of the free end of the beam, (<b>c</b>) strain–stress diagram of a point with 5 mm distance from the clamped end of the beam, (<b>d</b>) phase portrait of the free end of the beam, (<b>e</b>) deflection of the beam four individual times.</p>
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<p>Free vibration analysis of tri-layer SMA composite beam, (<b>a</b>) time history of the tri-layer beam tip deflections, (<b>b</b>) time history of the velocity of the free end of the beam, (<b>c</b>) strain–stress diagram of a point with 5 mm distance from the clamped end of the beam, (<b>d</b>) phase portrait of the free end of the beam, (<b>e</b>) deflection of the beam four individual times.</p>
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<p>Contour plot of strain for ASPM and SSPM models.</p>
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<p>Size parameter effect on time history of the tri-layer beam tip deflections for size parameter <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mi>h</mi> <mi>L</mi> </mfrac> </mstyle> <mo>=</mo> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mn>1</mn> <mn>8</mn> </mfrac> </mstyle> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mi>h</mi> <mi>L</mi> </mfrac> </mstyle> <mo>=</mo> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mn>1</mn> <mrow> <mn>10</mn> </mrow> </mfrac> </mstyle> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mi>h</mi> <mi>L</mi> </mfrac> </mstyle> <mo>=</mo> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mn>1</mn> <mrow> <mn>12</mn> </mrow> </mfrac> </mstyle> </mrow> </semantics></math>.</p>
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<p>Schematic of the bi-layer SMA beam.</p>
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<p>Free vibration analysis of bi-layer SMA composite beam, (<b>a</b>) time history of the bi-layer beam tip deflections, (<b>b</b>) time history of the velocity of the free end of the beam, (<b>c</b>) strain–stress diagram of a point with 5 mm distance from the clamped end of the beam, (<b>d</b>) phase portrait of the free end of the beam, (<b>e</b>) deflection of the beam four individual times.</p>
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<p>Free vibration analysis of bi-layer SMA composite beam, (<b>a</b>) time history of the bi-layer beam tip deflections, (<b>b</b>) time history of the velocity of the free end of the beam, (<b>c</b>) strain–stress diagram of a point with 5 mm distance from the clamped end of the beam, (<b>d</b>) phase portrait of the free end of the beam, (<b>e</b>) deflection of the beam four individual times.</p>
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<p>Contour plots of the strain for ASPM and SSPM models.</p>
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<p>Time history of the bi-layer beam tip deflections for different amplitude of impulse loading.</p>
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14 pages, 653 KiB  
Article
Bifurcation and Dynamics Analysis of a Piecewise-Linear van der Pol Equation
by Wenke Li, Nanbin Cao and Xia Liu
Axioms 2025, 14(3), 197; https://doi.org/10.3390/axioms14030197 - 6 Mar 2025
Viewed by 111
Abstract
In this study, we examine the bifurcations and dynamics of a piecewise linear van der Pol equation—a model that captures self-sustained oscillations and is applied in various scientific disciplines, including electronics, neuroscience, biology, and economics. The van der Pol equation is transformed into [...] Read more.
In this study, we examine the bifurcations and dynamics of a piecewise linear van der Pol equation—a model that captures self-sustained oscillations and is applied in various scientific disciplines, including electronics, neuroscience, biology, and economics. The van der Pol equation is transformed into a piecewise linear system to simplify the analysis of stability and controllability, which is particularly beneficial in engineering applications. This work explores the impact of increasing the number of linear segments on the system’s dynamics, focusing on the stability of the equilibria, phase portraits, and bifurcations. The findings reveal that while the bifurcation structure at critical values of the bifurcation parameter is complex, the topology of the piecewise linear model remains unaffected by an increase in the number of linear segments from three to four. This research contributes to our understanding of the dynamics of nonlinear systems with piecewise linear characteristics and has implications for the analysis and design of real-world systems exhibiting such behavior. Full article
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<p>Nullclines (<span class="html-italic">v</span>-nullcline and <span class="html-italic">w</span>-nullcline), linear line segments of <math display="inline"><semantics> <mrow> <msub> <mi>f</mi> <mrow> <mi>p</mi> <mi>w</mi> <mi>l</mi> </mrow> </msub> <mrow> <mo>(</mo> <mi>v</mi> <mo>)</mo> </mrow> </mrow> </semantics></math>, and the corresponding regions of the PWL model (<a href="#FD7-axioms-14-00197" class="html-disp-formula">7</a>)–(<a href="#FD8-axioms-14-00197" class="html-disp-formula">8</a>) with <math display="inline"><semantics> <mrow> <mi>ϵ</mi> <mo>=</mo> <mn>0.2</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>k</mi> <mo>=</mo> <mn>0.885</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mi>λ</mi> <mo>=</mo> <mn>0.8</mn> </mrow> </semantics></math>. From left to right, the slopes of <math display="inline"><semantics> <mrow> <msub> <mi>L</mi> <mrow> <mi>l</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> <mo>,</mo> <msub> <mi>L</mi> <mn>1</mn> </msub> <mo>,</mo> <msub> <mi>L</mi> <mn>2</mn> </msub> <mo>,</mo> <msub> <mi>L</mi> <mrow> <mi>r</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math> are <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mrow> <mi>l</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mn>1</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>1.27</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mrow> <mi>r</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>. The line segments <math display="inline"><semantics> <msub> <mi>L</mi> <mn>1</mn> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>L</mi> <mn>2</mn> </msub> </semantics></math> join at <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <msub> <mi>v</mi> <mn>1</mn> </msub> <mo>,</mo> <msub> <mi>w</mi> <mn>1</mn> </msub> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0</mn> <mo>,</mo> <mo>−</mo> <mn>0.385</mn> <mo>)</mo> </mrow> </mrow> </semantics></math>.</p>
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<p>A persistence bifurcation occurs when <math display="inline"><semantics> <mrow> <mi>λ</mi> <mo>=</mo> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math> for system (<a href="#FD7-axioms-14-00197" class="html-disp-formula">7</a>). The top row illustrates the transition of the equilibrium on <math display="inline"><semantics> <msub> <mi>L</mi> <mrow> <mi>l</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math> from a stable node (left) to an unstable node on <math display="inline"><semantics> <msub> <mi>L</mi> <mn>1</mn> </msub> </semantics></math> (right) as <math display="inline"><semantics> <mi>λ</mi> </semantics></math> varies. Meanwhile, a large-amplitude limit cycle appears for <math display="inline"><semantics> <mrow> <mi>λ</mi> <mo>&gt;</mo> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math>, traversing four distinct zones. The bottom row shows the equilibrium on <math display="inline"><semantics> <msub> <mi>L</mi> <mrow> <mi>l</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math> shifting from a stable node (left) to an unstable focus on <math display="inline"><semantics> <msub> <mi>L</mi> <mn>1</mn> </msub> </semantics></math> (right). Simultaneously, a small-amplitude limit cycle emerges when <math display="inline"><semantics> <mrow> <mi>λ</mi> <mo>&gt;</mo> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math>, passing through two specific zones, <math display="inline"><semantics> <msub> <mi>R</mi> <mn>1</mn> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>R</mi> <mrow> <mi>l</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math>. The representative parameter values are <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <mover accent="true"> <mi>v</mi> <mo stretchy="false">^</mo> </mover> <mo>,</mo> <mover accent="true"> <mi>w</mi> <mo stretchy="false">^</mo> </mover> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0</mn> <mo>,</mo> <mo>−</mo> <mn>0.385</mn> <mo>)</mo> </mrow> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mn>1</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>1.27</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>ϵ</mi> <mo>=</mo> <mn>0.2</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mi>k</mi> <mo>=</mo> <mn>0.885</mn> </mrow> </semantics></math>.</p>
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<p>System (<a href="#FD7-axioms-14-00197" class="html-disp-formula">7</a>) experiences a persistence bifurcation when <math display="inline"><semantics> <mrow> <mi>λ</mi> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>. The top row illustrates the transition of the equilibrium on <math display="inline"><semantics> <msub> <mi>L</mi> <mn>2</mn> </msub> </semantics></math> from an unstable focus (left) to a stable node located on <math display="inline"><semantics> <msub> <mi>L</mi> <mrow> <mi>r</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math> (right) as <math display="inline"><semantics> <mi>λ</mi> </semantics></math> varies. Meanwhile, a small-amplitude limit cycle appears for <math display="inline"><semantics> <mrow> <mi>λ</mi> <mo>&lt;</mo> <mn>1</mn> </mrow> </semantics></math>, passing through two zones, <math display="inline"><semantics> <msub> <mi>R</mi> <mn>2</mn> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>R</mi> <mrow> <mi>r</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math>. The bottom row shows the equilibrium on <math display="inline"><semantics> <msub> <mi>L</mi> <mn>2</mn> </msub> </semantics></math> shifting from an unstable node (left) to a stable node on <math display="inline"><semantics> <msub> <mi>L</mi> <mrow> <mi>r</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math> (right). Simultaneously, a large-amplitude limit cycle emerges when <math display="inline"><semantics> <mrow> <mi>λ</mi> <mo>&lt;</mo> <mn>1</mn> </mrow> </semantics></math>, traversing four distinct zones. The representative parameter values are the same as in <a href="#axioms-14-00197-f002" class="html-fig">Figure 2</a>.</p>
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<p>Schematic representations of five distinct phase portraits for system (<a href="#FD7-axioms-14-00197" class="html-disp-formula">7</a>). A small-amplitude limit cycle (red curve) exists when <math display="inline"><semantics> <mi>λ</mi> </semantics></math> is close to 1, which passes through two zones <math display="inline"><semantics> <msub> <mi>R</mi> <mn>2</mn> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>R</mi> <mrow> <mi>r</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math>. For all five cases, we take the value <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mn>1</mn> </msub> <mo>&lt;</mo> <msubsup> <mi>η</mi> <mrow> <mi>c</mi> <mi>r</mi> </mrow> <mo>−</mo> </msubsup> <mo>&lt;</mo> <msub> <mi>η</mi> <mn>2</mn> </msub> <mo>&lt;</mo> <mn>0</mn> </mrow> </semantics></math>.</p>
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<p>Schematic representations of five distinct phase portraits for system (<a href="#FD7-axioms-14-00197" class="html-disp-formula">7</a>). A large-amplitude limit cycle (red curve) exists when <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>1</mn> <mo>&lt;</mo> <mi>λ</mi> <mo>&lt;</mo> <msub> <mi>v</mi> <mn>1</mn> </msub> </mrow> </semantics></math>, which passes through four zones <math display="inline"><semantics> <msub> <mi>R</mi> <mrow> <mi>l</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math>, <math display="inline"><semantics> <msub> <mi>R</mi> <mn>1</mn> </msub> </semantics></math>, <math display="inline"><semantics> <msub> <mi>R</mi> <mn>2</mn> </msub> </semantics></math>, and <math display="inline"><semantics> <msub> <mi>R</mi> <mrow> <mi>r</mi> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math>.</p>
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<p>Illustrative phase portraits for the PWL VDP models, either with three or four linear segments, are presented. The top row depicts the VDP model comprising three linear segments, while the bottom row features the model with four linear segments. The phase portraits in the first column display a limit cycle, the second column shows a continuum of homoclinic orbits, and the last column demonstrates stable equilibrium. The representative parameter values are <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mn>1</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>1.27</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>ϵ</mi> <mo>=</mo> <mn>0.2</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mi>k</mi> <mo>=</mo> <mn>0.885</mn> </mrow> </semantics></math>.</p>
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12 pages, 7307 KiB  
Article
High Purity, Crystallinity and Electromechanical Sensitivity of Lead-Free (Ba0.85Ca0.15)(Zr0.10Ti0.90)O3 Synthesized Using an EDTA/glycerol Modified Pechini Method
by Laura Caggiu, Costantino Cau, Marzia Mureddu, Stefano Enzo, Fabrizio Murgia, Lorena Pardo, Sonia Lopez-Esteban, Jose F. Bartolomé, Gabriele Mulas, Roberto Orrù and Sebastiano Garroni
Materials 2025, 18(5), 1180; https://doi.org/10.3390/ma18051180 - 6 Mar 2025
Viewed by 74
Abstract
A single (Ba0.85Ca0.15)(Zr0.10Ti0.90)O3 phase material with a tetragonal structure is processed and synthesized with a modified Pechini method using ethylenediaminetetraacetic acid and glycerol as chelating and esterifying agents, respectively. The complete chemical transformation to [...] Read more.
A single (Ba0.85Ca0.15)(Zr0.10Ti0.90)O3 phase material with a tetragonal structure is processed and synthesized with a modified Pechini method using ethylenediaminetetraacetic acid and glycerol as chelating and esterifying agents, respectively. The complete chemical transformation to the desired phase is achieved at 900 °C, which is 300 °C lower than conventional synthesis methods. Its consolidation, reaching up to 91% relative density, is carried out at 1400 °C. It is clearly demonstrated that the use of ethylenediaminetetraacetic acid and glycerol reagents is particularly beneficial for inducing a homogeneous grain size distribution (10 μm), which leads to very promising electromechanical properties (d33 = 451 pC/N; d31 = 160 pC/N; kp = 0.40; ε33T = 4790 and Qm = 358) of the densified system. Full article
(This article belongs to the Special Issue Design and Processing of Piezoelectric/Ferroelectric Ceramics)
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<p>Scheme of the synthesis route. In the BC panel, barium carbonate and calcium acetate have been used as metal precursors. In the ZT panel, zirconium butoxide and TTIP have been used as metal precursors. A second synthesis attempt was performed replacing EDTA with citric acid.</p>
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<p>Experimental XRD patterns of the BCZT<sub>EDTA</sub> and BCZT<sub>CA</sub> calcined powders. Experimental points are indicated with red dots. BCZT, ZrO<sub>2</sub> and CaTiO<sub>3</sub> phases are reported using green, black, and blue full lines, respectively. RWp%: 7.6 (pattern BCZT<sub>EDTA</sub>). RWp%: 6.5 (pattern BCZT<sub>CA</sub>).</p>
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<p>(<b>a</b>) Sintered ceramics with the corresponding densities. (<b>b</b>) X-ray diffraction patterns of the ceramics produced from the powders synthesized with EDTA and CA. Green full lines indicate the Bragg reflections and profiles of the <span class="html-italic">P</span>4<span class="html-italic">mm</span> BCZT phase. The experimental pattern is represented by red dots. (<b>c</b>) Enlarged view of the peaks in the 102°–115° 2θ angular range. (<b>d</b>) 3D vista (obtained by VESTA software [<a href="#B28-materials-18-01180" class="html-bibr">28</a>]) of the elementary BCZT cell with a and c lattice parameters. Green, light blue, red, blue and yellow refer to barium, calcium, oxygen, titanium and zirconium atoms, respectively.</p>
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<p>SEM images acquired using a backscattered electron detector (BSDE) on the fracture surfaces of the sintered BCZT<sub>CAc</sub> (<b>a</b>,<b>b</b>) and BCZT<sub>EDTAc</sub> (<b>c</b>,<b>d</b>) pellets.</p>
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<p>EDX elemental mapping of BCZT<sub>CAc</sub> and BCZT<sub>EDTAc</sub> ceramics.</p>
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<p><b>Figure 6.</b> (R, G) plot, used in the calculation of material coefficients using the iterative automatic method [<a href="#B20-materials-18-01180" class="html-bibr">20</a>]. Symbols are the experimental data and lines are the reconstructed peaks after coefficients calculation. Fundamental radial mode of resonance of a thin disk of BCZT<sub>EDTAc</sub> ceramics.</p>
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<p>Dielectric permittivity vs. temperature for BCZT<sub>EDTAc</sub> ceramic.</p>
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11 pages, 4983 KiB  
Article
High-Sensitivity Magnetic Field Sensor Based on an Optoelectronic Oscillator with a Mach–Zehnder Interferometer
by Mingjian Zhu, Pufeng Gao, Shiyi Cai, Naihan Zhang, Beilei Wu, Yan Liu, Bin Yin and Muguang Wang
Sensors 2025, 25(5), 1621; https://doi.org/10.3390/s25051621 - 6 Mar 2025
Viewed by 128
Abstract
A high-sensitivity magnetic field sensor based on an optoelectronic oscillator (OEO) with a Mach–Zehnder interferometer (MZI) is proposed and experimentally demonstrated. The magnetic field sensor consists of a fiber Mach–Zehnder interferometer, with the lower arm of the interferometer wound around a magnetostrictive transducer. [...] Read more.
A high-sensitivity magnetic field sensor based on an optoelectronic oscillator (OEO) with a Mach–Zehnder interferometer (MZI) is proposed and experimentally demonstrated. The magnetic field sensor consists of a fiber Mach–Zehnder interferometer, with the lower arm of the interferometer wound around a magnetostrictive transducer. Due to the magnetostrictive effect, an optical phase shift induced by magnetic field variation is generated between two orthogonal light waves transmitted in the upper and lower arms of the MZI. The polarization-dependent property of a Mach–Zehnder modulator (MZM) is utilized to transform the magnetostrictive phase shift into the phase difference between the sidebands and optical carrier, which is mapped to the oscillating frequency upon the completion of an OEO loop. High-sensitivity magnetic field sensing is achieved by observing the frequency shift of the radio frequency (RF) signal. Temperature-induced cross-sensitivity is mitigated through precise length matching of the MZI arms. In the experiment, the high magnetic field sensitivity of 6.824 MHz/mT with a range of 25 mT to 25.3 mT is achieved and the sensing accuracy measured by an electrical spectrum analyzer (ESA) at “maxhold” mode is 0.002 mT. The proposed sensing structure has excellent magnetic field detection performance and provides a solution for temperature-insensitive magnetic field detection, which would have broad application prospects. Full article
(This article belongs to the Special Issue Advances in Microwave Photonics)
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<p>Schematic layout of an OEO-based magnetic field sensing system with enhanced sensitivity. Points a–e: the optical signals output from the PBS, PBC, MZM, PS-FBG and Pol, respectively.</p>
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<p>Optical spectral transformation of OEO. (<b>a</b>–<b>e</b>) the optical spectra of the signals emitted from the PBS, PBC, MZM, PS-FBG and Pol, respectively; Red and blue arrows: two optical signals with specific amplitudes and polarization states transmitted along the fiber.</p>
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<p>The schematic of the fiber’s various regions within the solenoid.</p>
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<p>(<b>a</b>) Optical spectrum at the Pol output; (<b>b</b>) electrical spectrum of the OEO’s 1.07536 GHz oscillation signal.</p>
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<p>(<b>a</b>) Spectra of temperature stability testing for the sensing system; (<b>b</b>) variation of oscillation frequency with temperature.</p>
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<p>(<b>a</b>) Superposition spectrum of the oscillating signals as the magnetic field incrementally rises; (<b>b</b>) variation of oscillation frequency with magnetic field.</p>
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<p>Frequency stability measurement for 5 min at “maxhold” mode.</p>
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